Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

13 13 2
Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

Đang tải... (xem toàn văn)

Tài liệu hạn chế xem trước, để xem đầy đủ mời bạn chọn Tải xuống

Thông tin tài liệu

SÑ 45B (1) pdf 45B, 2020 © 2020 Thành Khoa Công khí nguyenkhoatrieuiuh edu vn khóa N Abstract In this article, the authors synthesized and analyzed research papers that dealt with the fabrication and characterization of starch based bioplastics As the first step, some fruit seeds were investigated for starch supply ability Results revealed that compared to durian seed and avocado seed, jack fruit seed had the highest starch ratio Furthermore, it was not only easy to collect but also cheap or ev.

45B, 2020 Khoa Cơng khí nguyenkhoatrieu@iuh.edu.vn khóa N Abstract In this article, the authors synthesized and analyzed research papers that dealt with the fabrication and characterization of starch-based bioplastics As the first step, some fruit-seeds were investigated for starch supply ability Results revealed that compared to durian-seed and avocado-seed, jack fruit-seed had the highest starch ratio Furthermore, it was not only easy to collect but also cheap or even free of charge Afterward, a starch-based bioplastic fabrication procedure was synthesized from the literature review From preliminary tests, plasticizers were sufficiently selected, including H 2O, glycerol, natri bicarbonate and acid citric Four kinds of bioplastic utilizing different combinations of these plasticizers were then fabricated to study the effect of them as well as characterize the properties of the corresponding bioplastics After that, based on ASTM D412 type A standard, a mold and a cutting tool for dog-bone sample making were designed and fabricated Using these dog-bone samples, tensile results showed that the hardness of the fabricated bioplastic was positively proportional to the ratio of the starch It is worth noting that the plasticizing was not able to completely occur with too much percentage of starch While bioplastics were currently made with poor mechanical properties compared to petroleum-based resins, their environmental compatibility and high potential added value promise to be the materials of the future Keywords Bioplastic, Starch extraction, Jack-fruit seed, Plasticizer, Thermoplastic, Environmental compatibility [1] © 2020 Thành 58 NGHIÊN protein [1] [2, 3] [1, 3] [1] (CO2 [2] lo i polymer s n xu t t tài nguyên có th tái t o [1] [4, 5] [4] [2] [1, 2] © 2020 Thành 59 [4] [4] chúng PLA có [4] [6, 7] nh Favis [8] [10] [11] tác [12-14] [15, 16], [17, 18] [19, 20] [2, 21, 22] [23, 24] Lan [25] [26] ay HDPE [27] phosphate citrates Fridman Sorokina [28] [29] [30] [31] [32] t X Q Mo X Z Sun [33] [34] d [35] [36] [1] © 2020 Thành 60 NGHIÊN [37, 38] [39] - [41] Công [41] [41] nhiên [42] t cao V T LI 2.1 V t li u: a H t mít [2] Trong [2] Hàm l [2] ác nhóm hydroxyl [2] b Glycerol (292 C © 2020 n hóa q trình lipid hóa (triglyceride) thành acid béo Thành 61 [1] c Acid citric plasticized thermoplastic starch (SEM) acid citric (hình 2) Các [43] Hình Liên k t gi a phân t acid citric, glycerol tinh b t [43] © 2020 Thành 62 NGHIÊN cellulose glycerol, polyethylen glycol [44] d Baking soda natri metabisulfite (Na2S2O5 [45] 2.2 , B ng T l thành ph n nguyên li u m u nh a Thành ph n Tinh b t Acid citric Baking Soda Tinh b t Glycerol Tinh b t+Glycerol Tinh b t+Glycerol H 2O 3.0:1 12.5 2.75:1 100 100 100 3.5:1 T l 2.5:1 © 2020 Thành 63 B ng Kh Thành Ph n ng nguyên li u m u nh a Tinh b t h t mít (g) Glycerol (g) Acid citric (g) Baking Soda (g) H 2O (g) M u1 20 5.71 0.25 1.28 160 M u2 20 6.67 0.26 1.33 160 M u3 20 7.27 0.27 1.36 160 M u4 20 8.00 0.28 1.40 160 M u nh a [16] (SCILOGEX model MS-H-S) , © 2020 Thành 64 NGHIÊN Hình Khay nh c ph lên l p màng PE Hình Cho khay vào t s y 55 0C Hình H n h p nh a d c tráng b ng khay Hình Nh a sinh h c sau s y khô U - CAN DYNATEX INC TYPE UT a D p c t m u Hình M © 2020 Thành b M c d p máy t 65 K T QU VÀ TH O LU N , M u nh a t Nguyên nhân T l 2.5:1 T l 2.75:1 T l 3.0:1 T l 3.5:1 ng su 3.39 4.34 4.00 5.15 Bi n d 0.29 0.13 0.33 0.25 12.70 33.38 12.43 20.06 29.13 12.60 33.33 25.20 1.375 1.350 1.403 1.410 Thông s Mô- i E (MPa) giãn dài A (%) T tr ng Density (g/cm3) © 2020 Thành 66 NGHIÊN ngồi 30% glycerol Cịn c 4.87 K T LU N cellulose P © 2020 Thành 67 bên trong, [1] [2] [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] T Mekonnen, P Mussone, H Khalil, and D Bressler, "Progress in bio-based plastics and plasticizing modifications," Journal of Materials Chemistry A, vol 1, pp 13379-13398, 2013 R F Santana, R C F Bonomo, O R R Gandolfi, L B Rodrigues, L S Santos, A C dos Santos Pires, et al., "Characterization of starch-based bioplastics from jackfruit seed plasticized with glycerol," Journal of Food Science and Technology, vol 55, pp 278-286, 2018 M Rosseto, D D C Krein, N P Balbé, and A Dettmer, "Starch gelatin film as an alternative to the use of plastics in agriculture: a review," Journal of the Science of Food and Agriculture, vol 99, pp 6671-6679, 2019 R Cho (2017, 16/01/2020) The truth about bioplastics Available: https://phys.org/news/2017-12-truthbioplastics.html I D Posen, P Jaramillo, A E Landis, and W M Griffin, "Greenhouse gas mitigation for U.S plastics production: energy first, feedstocks later," Environmental Research Letters, vol 12, p 034024, 2017 N Laohakunjit and A Noomhorm, "Effect of Plasticizers on Mechanical and Barrier Properties of Rice Starch Film," Starch - Stärke, vol 56, pp 348-356, 2004 X Ma and J Yu, "Formamide as the plasticizer for thermoplastic starch," Journal of Applied Polymer Science, vol 93, pp 1769-1773, 2004 A Taghizadeh and B D Favis, "Effect of high molecular weight plasticizers on the gelatinization of starch under static and shear conditions," Carbohydrate Polymers, vol 92, pp 1799-1808, 2013 M Thunwall, A Boldizar, M Rigdahl, and V Kuthanová, "On the Stress-Strain Behavior of Thermoplastic Starch Melts," International Journal of Polymer Analysis and Characterization, vol 11, pp 419-428, 2006 R A Talja, H Helén, Y H Roos, and K Jouppila, "Effect of various polyols and polyol contents on physical and mechanical properties of potato starch-based films," Carbohydrate Polymers, vol 67, pp 288-295, 2007 E G Ozdamar and M Ates, "Rethinking sustainability: A research on starch based bioplastic," Journal of Sustainable Construction Materials and Technologies, vol 3, pp 249-260, 2018 V S Keziah, R Gayathri, and V V Priya, "Biodegradable plastic production from corn starch," Drug Invention Today, vol 10, pp 1315-1317, 2018 J F Mendes, R T Paschoalin, V B Carmona, A R Sena Neto, A C P Marques, J M Marconcini, et al., "Biodegradable polymer blends based on corn starch and thermoplastic chitosan processed by extrusion," Carbohydrate Polymers, vol 137, pp 452-458, 2016 O V López, C J Lecot, N E Zaritzky, and M A García, "Biodegradable packages development from starch based heat sealable films," Journal of Food Engineering, vol 105, pp 254-263, 2011 © 2020 Thành 68 [15] [16] [17] [18] [19] [20] [21] [22] [23] [24] [25] [26] [27] [28] [29] [30] [31] [32] © 2020 NGHIÊN E U Offiong and S L Ayodele, "Preparation and characterization of thermoplastic starch from sweet potato," International Journal of Scientific & Engineering Research, vol 7, pp 438-443, 2016 A H D Abdullah, S Pudjiraharti, M Karina, O D Putri, and R H Fauziyyah, "Fabrication and Characterization of Sweet Potato Starch-based Bioplastics Plasticized with Glycerol," Journal of Biological Sciences, vol 19, pp 57-64, 2019 O Udensi, E V Ikpeme, E A Uyoh, and E A Brisibe, "Evaluation of Starch Biodegradable Plastics Derived from Cassava and Their Rates of Degradation in Soil," Nigerian Journal of Biotechnology, vol 20, pp 28-33, 2009 N E Wahyuningtiyas and H Suryanto, "Analysis of Biodegradation of Bioplastics Made of Cassava Starch," Journal of Mechanical Engineering Science and Technology, vol 1, pp 24-31, 2017 M H S Ginting, R Hasibuan, M Lubis, F Alanjani, F A Winoto, and R C Siregar, "Supply of avocado starch (Persea americana mill) as bioplastic material," IOP Conference Series: Materials Science and Engineering, vol 309, p 012098, 2018 L Maulida, H M Bangun, G M H Sahputra, S Mora, and A Hidayatul, "Production of bioplastic from avocado seed starch reinforced with microcrystalline cellulose from sugar palm fibers," Journal of Engineering Science and Technology, vol 13, pp 381-393, 2018 A W M Kahar, M Lingeswarran, M Z Amirah Hulwani, and H Ismail, "Plasticized jackfruit seed starch: a viable alternative for the partial replacement of petroleum-based polymer blends," Polymer Bulletin, vol 76, pp 747-762, 2019 Maulida, M B Harahap, Alfarodo, A Manullang, and M H S Ginting, "Utilization of jackfruit seeds (Artocarpus heterophyllus) in the preparing of bioplastics by plasticizer ethylene glycol," ARPN Journal of Engineering and Applied Sciences, vol 13, pp 240-244, 2018 W Pimpa, C Pimpa, and P Junsangsree, "Development of Biodegradable Films Based on Durian Seed Starch," Advanced Materials Research, vol 506, pp 311-314, 2012 M H S Ginting, R Hasibuan, M Lubis, D S Tanjung, and N Iqbal, "Effect of Hydrochloric Acid Concentration as Chitosan Solvent on Mechanical Properties of Bioplastics from Durian Seed Starch (Durio Zibethinus) with Filler Chitosan and Plasticizer Sorbitol," IOP Conference Series: Materials Science and Engineering, vol 180, p 012126, 2017 N Lopattananon, C Thongpin, and N Sombatsompop, "Bioplastics from Blends of Cassava and Rice Flours: The Effect of Blend Composition," International Polymer Processing, vol 27, pp 334-340, 2012 K M Marichelvam, M Jawaid, and M Asim, "Corn and Rice Starch-Based Bio-Plastics as Alternative Packaging Materials," Fibers, vol 7, 2019 Z Stefan, K Stephan, R Hans-Joachim, and T Wodke, "Influence of External Plasticization on Rheological and Thermal Properties of Cellulose Acetate with Respect to Its Foamability," Journal of Materials Science & Engineering A, vol 2, pp 152-163, 2012 O A Fridman and A V Sorokina, "Criteria of efficiency of cellulose acetate plasticization," Polymer Science Series B, vol 48, pp 233-236, 2006 A K Mohanty, A Wibowo, M Misra, and L T Drzal, "Development of renewable resource based cellulose acetate bioplastic: Effect of process engineering on the performance of cellulosic plastics," Polymer Engineering & Science, vol 43, pp 1151-1161, 2003 A N Ghebremeskel, C Vemavarapu, and M Lodaya, "Use of surfactants as plasticizers in preparing solid dispersions of poorly soluble API: Selection of polymer surfactant combinations using solubility parameters and testing the processability," International Journal of Pharmaceutics, vol 328, pp 119-129, 2007 M Schilling, M Bouchard, H Khanjian, T Learner, A Phenix, and R Rivenc, "Application of Chemical and Thermal Analysis Methods for Studying Cellulose Ester Plastics," Accounts of Chemical Research, vol 43, pp 888-896, 2010 J Ballany, D Littlejohn, R A Pethrick, and A Quye, "Probing the Factors That Control Degradation in Museum Collections of Cellulose Acetate Artefacts," in Historic Textiles, Papers, and Polymers in Museums vol 779, ed: American Chemical Society, 2000, pp 145-165 Thành 69 [33] [34] [35] [36] [37] [38] [39] [40] X Mo and X Sun, "Plasticization of soy protein polymer by polyol-based plasticizers," Journal of the American Oil Chemists' Society, vol 79, pp 197-202, 2002/02/01 2002 A Ullah and J Wu, "Feather Fiber-Based Thermoplastics: Effects of Different Plasticizers on Material Properties," Macromolecular Materials and Engineering, vol 298, pp 153-162, 2013 M Pommet, A Redl, S Guilbert, and M.-H Morel, "Intrinsic influence of various plasticizers on functional properties and reactivity of wheat gluten thermoplastic materials," Journal of Cereal Science, vol 42, pp 8191, 2005 I Chiulan, A N Frone, C Brandabur, and D M Panaitescu, "Recent Advances in 3D Printing of Aliphatic Polyesters," Bioengineering (Basel, Switzerland), vol 5, p 2, 2017 A U B Queiroz and F P Collares-Queiroz, "Innovation and Industrial Trends in Bioplastics," Polymer Reviews, vol 49, pp 65-78, 2009/05/07 2009 Biostarch (2019, 18/01/2020) Available: https://biostarch.vn/thi-truong-nhuasinh-hoc/ A Phát (2018, 18/01/2020) Available: http://www.anphatbioplastics.com/new/phan-biet-dinh-nghia-tu-huy.html P T Tri [41] [42] [43] [44] [45] [46] Y Jiugao, W Ning, and M Xiaofei, "The Effects of Citric Acid on the Properties of Thermoplastic Starch Plasticized by Glycerol," Starch - Stärke, vol 57, pp 494-504, 2005 P G Seligra, C Medina Jaramillo, L Famá, and S Goyanes, "Biodegradable and non-retrogradable ecofilms based on starch glycerol with citric acid as crosslinking agent," Carbohydrate Polymers, vol 138, pp 66-74, 2016 (2018, 13/12/2019) Production Of A Bioplastic Out Of Saba Banana (Musaparadisiaca) Peels And Sweet Potato (Ipomoea Batatas) With Sodium Bicarbonate As Plasticizer Available: https://www.coursehero.com/file/p1tn5cp4/According-to-ProMusa-2018-there-were-about-91-million-tonsof-bananas-produced/ roperties of Bioplastic sheets made from different -2), pp 257-264 2016 10/02/2020 03/06/2020 © 2020 Thành ... Mo X Z Sun [33] [34] d [35] [36] [1] © 2020 Thành 60 NGHIÊN [37, 38] [39] - [41] Công [41] [41] nhiên [42] t cao V T LI 2.1 V t li u: a H t mít [2] Trong [2] Hàm l [2] ác nhóm hydroxyl [2] b Glycerol... (SCILOGEX model MS-H-S) , © 2020 Thành 64 NGHIÊN Hình Khay nh c ph lên l p màng PE Hình Cho khay vào t s y 55 0C Hình H n h p nh a d c tráng b ng khay Hình Nh a sinh h c sau s y khô U - CAN DYNATEX... (hình 2) Các [43] Hình Liên k t gi a phân t acid citric, glycerol tinh b t [43] © 2020 Thành 62 NGHIÊN cellulose glycerol, polyethylen glycol [44] d Baking soda natri metabisulfite (Na2S2O5 [45]

Ngày đăng: 30/06/2022, 10:57

Hình ảnh liên quan

acid citric (hình 2). - Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

acid.

citric (hình 2) Xem tại trang 5 của tài liệu.
Hình 5. Khay nh c ph lên lp màng PE Hình 6. Hn hp nh ad c tráng b ng trên khay - Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

Hình 5..

Khay nh c ph lên lp màng PE Hình 6. Hn hp nh ad c tráng b ng trên khay Xem tại trang 8 của tài liệu.
Hình 9. dp trên máy - Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

Hình 9..

dp trên máy Xem tại trang 8 của tài liệu.
Hình 7. Cho khay vào t sy 55 0C Hình 8. Nh asinh hc sau khi sy khô 3 - Nghiên cứu, chế tạo nhựa sinh học từ hạt mít

Hình 7..

Cho khay vào t sy 55 0C Hình 8. Nh asinh hc sau khi sy khô 3 Xem tại trang 8 của tài liệu.
U- CAN DYNATEX INC TYPE UT - Nghiên cứu, chế tạo nhựa sinh học từ hạt mít
U- CAN DYNATEX INC TYPE UT Xem tại trang 8 của tài liệu.

Tài liệu cùng người dùng

  • Đang cập nhật ...

Tài liệu liên quan