... (rad), λ the wavelength ofthe X-ray, θ the angle between the incident and diffracted beams (degree) and d the particle size ofthe sample (nm) (in Table 1) 3.2 FT-IR spectroscopy The band wavenumber ... of materials, the second term can take part of several tens percent of HC andthe last one whereas can only reach several hundreds of gauss Thus, the increasing of Co-concentration led tothe ... octahedral location That led to increasing of total magnetization ofa molecule Ni1-xCoxFe2O4 and hence there is increasing of MS (table 3) Another side, it is known that the magnetizing process of...
... immunomodulatory, antibacterial, antifungal and antiviral functions [1] SLPI and elafin ⁄ trappin-2 both have antimicrobial activity against Gram-negative and Gram-positive bacteria SLPI is active against ... well-characterized fungicidal activity against Aspergillus fumigatus and Candida albicans, in addition to its antibacterial properties [13] This has been attributed to its N-terminal domain and ... trappin-2 towards C albicans was time-dependent, reaching 92% after h and 98% after 18 h (Fig 5) Effect of NaCl and heparin on the antibacterial and antifungal activities of trappin-2 The antimicrobial...
... proteins Arrows indicate the direction of transcription genomic DNA using forward (5¢-GGAGGGATCCCATATG AAGTCTAAATTTAAATTAACG-3¢) and reverse (5¢-GC primers GTGCTCGAGCGATCCATGGAGCCGTA-3¢) that incorporated ... (orf-1, aauBEDA, orf-2, orf-3, orf-4 and hemE) all putatively transcribed in the same direction [7] The second and fifth genes (aauA and aauB) encode the large and small subunits of AADH, respectively ... TTQ-dependent AADH were obtained by fitting the Eyring equation tothe data and are summarized in Table Analysis ofthe temperature dependence of reaction rates with protiated and deuterated benzylamine...
... consisting of amino acids 7–22 of parabutoporin (an a- helical part having the four amino acids LAKK identical to mastoparan) andofthe first 28 amino acids ofthe opistoporins were synthesized and were ... bacteria and their activity was compared with the activity of melittin and mastoparan (Table 1) Parabutoporin inhibits the growth of all Gram-negative bacteria tested except S marcescens at a ... explain the higher antibacterial activity on Gram-negative bacteria for parabutoporin compared to opistoporin Also with magainin analogs, an increase in antibacterial activity against Gram-negative...
... similar to each other In particular, the parameters for VIHN complexes not deviate systematically from those of DAHam and DAHKam This means that the side chain carboxylate of Asp1 does not havea ... of Cu(II) and Ni(II) transport by albumins On the other hand, the direct thermodynamic and kinetic characterization of Ni(II) binding at site I in HSA and BSA was obtained These data can be very ... DAHKam is now much lower from those of albumins, andthe reaction of DAHam is much faster The reaction rates for albumins and DAHam are higher from the value for pure acid GGH dissociation The...
... typical peaks of Si and Pt andthe result from the quantitative estimation of peak areas gives 0,98% weight content of platinum This means that most of platinum was reduced and maintained on SBA-15 ... Synthesis and characterization of Bimetallic Pt-Au clusterderived catalyst Catalysis Today, 125, 269-274, 2006 [5] A. Corma and Hermenegilldo Garcia Nanoparticles and catalysis Wiley-VCH Verlag ... for a day The solution was aged for another day at room temperature After filtration, washing with distilled water and drying at 100oC, the sample was calcined at 550°C in ambient air for 5h and...
... occurring at K2 < [ibuprofen] < K3, and at K2 < K3 < [ibuprofen], respectively, and kỵ is the koff value obtained in the off absence of ibuprofen Data analysis Kinetic and thermodynamic data were analyzed ... that the allosteric modulation of tHSAheme and HSAheme reactivity by ibuprofen depends mainly on drug binding tothe secondary sites FA2 and FA6 rather than drug association with the FA3 FA4 ... affect the functional and structural propertiesof domains I and II [i.e ofthe 1382 region of (t)HSA] l The values ofthe Hill coefcients (n1, n2, and n3) for ibuprofen binding to tHSAheme and...
... contrast tothe class I and II peroxidases that have two Fe-Im bands resulting from the tautomerism ofthe imidazole Nd proton with respect tothe donor and acceptor atoms ofthe proximal His and ... protein Mutations of distal residues can give rise toa substantial reduction ofthe catalytic activity if they havea direct impact on the disposition ofthe catalytically important His42 and Arg38 ... binding of His42 tothe haem iron, i.e a major collapse or rearrangement ofthe distal cavity has taken place Hence, the overall conclusion that may be drawn is that modication ofthe proximal cavity...
... B and P atoms are at the smallest possible distance (2.00 A, top ˚ panel) or at the largest possible distance (10.60 A, bottom panel) for this nanocrystal A Gaussian broadening of 0.1 eV has been ... position of Fig 11), approaching asymptotically the value ofthe band-gap ofthe undoped Si-nw This is another indication of how doping can modify the electronic and optical propertiesofthe Si nanostructures ... absorption, the SS, can be lead back tothe relaxation ofthe Si-nc after the excitation process The new important features that appear in the emission many-body spectra are related tothe presence of...
... surface energy tothe distance from the centre of crystal tothe surface is constant Assuming that nanowire facets during the growth consist of clean surface, we have obtained that the ratio ofthe ... surface (insets of Fig 4), we find that the wave functions ofthe doubly-degenerate HO states and four LU states correspond tothe p-like bands of edge atoms andthe T Akiyama et al / Surface Science ... difference in atomic configuration causes the suppression of lattice relaxation for edge atoms Indeed, the p*-like bands for the edge atoms are located $0.2 eV above the p-like bands for the edge atoms,...
... mutation also introduces changes in the surface charge of Tm All the mutant amino acids are involved in interchain and intrachain interactions and therefore are important for the stabilization ofthe ... in the assay Mutant Tms were compared tothe wild type Tm in their ability to regulate the actomyosin S1 Mg2+ ATPase activity ATPase activity was first assayed by varying the concentration of ... parameters for the thermal-induced unfolding of wild type (WT) and mutant Tms The values are the mean ± standard deviation of at least three experiments Tm1 is the midpoint ofthe thermal transition...
... saturation magnetization MSt calculated with assuming that exchange interaction λab is strongest therefore magnetic moments ofAand B sublattices are antiparallel to each other and MSt increases ... showed that at this field the studied samples are nearly in saturation and saturation magnetization of samples is listed in Tab From the shape of measured M(T) curves, we should approximately suppose ... perform at high sintering temperature and eliminates the porosity of ferrite The magnetization curves of all samples havebeen measured at 110 K in maximal applied field of 13.5 kOe The results...
... H-bonding tothe ligated cyanide The van der Waals surfaces for the Tyr32(B10) Og andthe 10 tilted cyanide ligand are shown in Fig and establish that the Tyr Og and cyanide N are in van der Waals ... magnetic axes, the distance to iron via paramagnetic relaxation RFe, distance to Tyr66(E7) CdH(via NOESY cross peak intensity) and /O-H-N angle as a function ofthe CfO-H to aromatic plane dihedral angle, ... nitrogen, because a zero tilt angle would lead to an % 0.20.3 A overlap ofthe two van der Waals surfaces A moderate -to- strong H-bond [50] can occur when the donor/acceptor heteroatoms are separated...
... variational approach with a mixture of topological and symmetry constraints The advantage of our approach, as Figure indicates, is that it applies toa wide range of masses In sharp contrast with the ... none ofthe new solutions constructed by variational methods can totally discard this constraint A question for the variational approach, especially on planar problems, naturally arises: Are minimizing ... Alain Chenciner, andthe referees for valuable comments Many thanks to Don Wang and Maciej Wojtkowski for enlightening conversations and their hospitality during my visit tothe University of Arizona...
... (Fig 6) In fact, comparing permeabilization kinetics and SEM results, it would appear that the monomeric and dimeric forms havea similar capacity to affect a primary damage ofthe membrane, possibly ... with their axes parallel to its surface [14], in what is known as the ‘carpet’ mechanism, and can then variously affect membrane permeabilization or damage by the formation of ‘toroidal’ or ‘wormhole’ ... concentrations (Fig 5) Dimerization appears to somewhat slow permeabilization ofthe outer, but not the cytoplasmic, membrane The hydrolysis of ONPG proceeds at a rate comparable to that of PADAC,...
... pengkajian antioxidan yang digunakan ia/ah DPPH dan p-karoten yang dinyatakan sebagai ECso pada FRAP yang dinyatakan sebagai Fe2+ pada mmol/g; dan ABTS yang dinyatakan sebagai ntlai TEAC dalam j.Jmol/j.Jg ... seperti sayur Ada/ah diketahui bahawa tumbuhan ini mengandungi banyak flavonoid dan asid feno/ik fa juga merupakan satu sumber aktiviti antioxidan yang baik Kesan cara-cara pengeringan jents pe/arut ... etanol pengekstraktan pada 25 jam dan ntsbah sampe/ kepada pe/arut pada 1:19.98 Da/am keadaan sebeginl ni/ai anggaran l/ECso bagi DPPH ia/ah 1.997 mg/m/ Anggaran ni/ai Fe2+ bagi FRAP ia/ah 3214.51...
... Figure AFM and STEM images of GaSb/In0.53Ga0.47As QDs and histogram ofthe height of GaSb/In0.53Ga0.47As QDs (a) The AFM image of GaSb/In0.53Ga0.47As QDs, (b) histogram ofthe height of GaSb/In0.53Ga0.47As ... such as GaSb/GaAs [8-10], InAlAs/InP [11], InP/InGaP [12, 13], InP/GaAs [14], GaAsSb/GaAs [15], and InAs/GaSb [16, 17] The reason is that they offer comparatively large bandgap energies and provide ... in Figure 1a, the statistical data indicate that the density ofthe QDs is approximately × 109 cm−2 and that the shape of GaSb QDs is rectangular-shaped which is the same with GaSb/GaAs QDs [9]...
... increased mobility The EDS analysis reveals the presence of Ag, Zn, and O elements Quantitative analysis of EDS reveals that Ag concentrations are proportional to those ofthe targets, and measured ... A exp(−Ea /kT) (1) where Ea is the activation energy of PL emission for thermal quenching, I0 andA are scaling factors, and k is Boltzmann’s constant The activation energies ofthe A0 X formation ... low-temperature PL to find the exciton bound to natural acceptor in the all SZO NWs It indicates that the Ag dopant can act as a desirable acceptor in ZnO NWs The low temperature PL studies reveal that...
... in the system, the InAs material is preferred to grow vertically and form NWs The few large InAs islands and non-vertical InAs NWs observed in sample A, B, and C can be explained by the reoxidation ... can be attributed tothe LO andTO phonon mode of InAs NWs Except the downshift of their phonon frequency relative to InAs bulk material, the LO andTO phonon peaks of InAs NWs also show a larger ... 500 Raman shift (cm-1) (cm-1) Figure Raman spectra of InAs nanowires and temperature-dependent Raman shift (a) Micro-Raman spectra of InAs nanowires with an average diameter of 42 nm The black...
... additional phases In the 27-32° range, it shows various sharp peaks that are located above a broad band Figure Evolutions ofthe positions ofthe LO3 and TO3 peaks, andthe LO3 /TO3 intensity ratio, as ... assigned to Si-H bonds, disappears after annealing because ofthe hydrogen desorption Figure 2a shows the evolution ofthe positions ofthe LO3 and TO3 vibration modes, andthe LO3 /TO3 intensity ratio, ... chips The Nd content was monitored by the surface ratio between the Nd2O3 chips andthe SiO2 target The sputtering gas was a mixture of argon and hydrogen; the latter enables us to control the...