... prepared by mixing leady oxide with water, sulfuric acid, fiber and Na SO4 additive The paste compositions were 50 kg ball-mill leady oxide, 6000 cm3 water, 3500 cm3 sulfuric acid of 1.40 specific ... five cells in each group were tested with the average performance based on the results exhibited by five cells Six groups of cells were subjected to standard cycle-life testing: group A cells ... of electrode materials w10x, leading to a large capacity In this work, we studied the effect of Na SO4 additive in the positive electrode on the performance of VRLAcells for ES applications Experimental...
... Uric acid levels Lead is known to inhibit uric acid secretion thereby increasing serum uric acid levels Serum uric acid levels were therefore measured to use it as an indirect measure of lead ... there is no workplace regulation for lead exposure Therefore, workers at leadacid battery units of the studied transport enterprises are clearly at high risk of lead exposure (Fig 5), as 39% of ... Blood Lead Level to Induce Significant Increase in Urinary δ-Aminolevulinic Acid Level among Lead- Exposed Workers: A Statistical Approach Industrial Health 2000, 38:181-188 Lee BK: Occupational lead...
... electrolyte diffusion and paste conductivity on leadacid battery performance, J Power Sources 46 Ž1993 49–60 w12x D.B Edwards, P.W Appel, Modeling leadacid batteries that have positive electrodes ... the capacity of leadacid batteries, Adv Perform Mater Ž1996 43–45 w15x H Metzendor, The capacity limiting role of the electronic conductivity of the active material in leadacid batteries during ... conductivity model, to estimate leadacid battery performance over a wide range of discharge rates The model produces voltage vs time curves, percent material reaction curves, and acid concentration plots...
... coke Polyacene AS 0.5 0.5 0.5 0.5 0.5 LeadLeadLeadLeadLead Expanded graphite +AS (1:1) Lead paste Li2SO4 Electrolyte Expanded graphite + AS/LizSO4 1/1 Lead paste/ electrolyte paste paste paste ... and traces of Cd 2+, can improve the electrode behaviour and, consequently, the service life of lead/ acid batteries [5] Nevertheless, due to various factors, the above-mentioned additives have not ... consumption of the positive active material and its discharge behaviour Specimen Lead powder consumption (g/plate) Lead paste apparent density (g/ml) Coefficient of use at •=280 mA (%) Discharge...
... phenomenon leading to an acceleration of the capacity loss [12] This study proposes an innovative solution in order to improve both cycling life and performance of a very low cost leadacid battery ... Numerous kinds of additives [4] have already been tested in order to improve the performances of leadacid batteries and, despite a significant increase of the performances at the beginning of the ... The cells are composed of the assembly of three plates in which the modified one is surrounded by the two other polarities and the multi-layer separator is inserted between the plates The cells...
... and 0.01% for the VRLA type The action of antimony in extending the cycle life of the leadacid battery is explained in terms of the effect of antimony in the formation of lead sulfate upon discharge ... caused by the deposition of colloidal lead particles It is also possible that these lead accumulations have their origin in dissolved lead The solubility of lead sulfate undergoes a dramatic shift ... 259 Fig Solubility of lead sulfate in sulfuric acid at 258C The separator and additives Now the interaction between additives and the function of the separator in the leadacid battery is examined...
... [34] [35] [36] [1] H Bode, LeadAcid Batteries, John Wiley & Sons, New York, USA, 1977, p 243 [2] D.A.J Rand, P.T Moseley, J Garche, C.D Parker (Eds.), ValveregulatedLeadAcid Batteries, Elsevier, ... claims In suggesting that a carbon |lead acid HES device could offer improved performance over a standard VRLA battery, partly because of the replacement of the lead negative electrode with one ... performance of the carbon |lead acid HES device, due to the incorporation of lead into the carbon electrode, clearly makes it a stronger development proposition The presence of lead in the negative...
... R Flores, L.M Blancor Journal of Power Sources 78 (1999) 30–34 dynamic response of a leadacid battery negative plate has been reported by Saakes et al w11x Saakes and van Duin w12x also ... demonstrates high reliability in scaling-up to production levels 31 Table Paste formula Lead oxide Žg Water Žg Sulfuric acid, 1.400 relative density Žg Fibre Žg Expander according to formula 100 14.3 ... simple means to differentiate the impact of expanders on the performance of negative plates in leadacid batteries The resulting discharge and recharge transients show the effect of the expander...
... Sources 113 (2003) 382–387 383 Table OCP values (vs Hg/Hg2SO4; mV) of Pb and PbO2 electrodes in leadacid M H2SO4 with and without different mixed additives at 298 K Electrodes Pb PbO2 Cell: Pb–PbO2 ... additives The poor performance of the Pb electrode with picric acid and H3PO4 as additives seems to arise from the strong adsorption of picric acid at the electrode surface For the positive plate (PbO2) ... potentials From Table it seems that H3PO4 and SnSO4 may be a good additive combination for the leadacid battery The charging behaviour of the cell using H3PO4 and SnSO4 is very interesting The...
... after the addition of sulfuric acid solution (results and 2) Before the addition of sulfuric acid solution (result 1), the paste containing 1-naphthalenesulfonic acid sodium salt (NS) is both ... 60 64 52 74 32 60 64 52 77 26 57 57 54 81 14 NS: 1-naphthalenesulfonic acid sodium salt; NQS: 1,2-naphthoquinone-4-sulfonic acid sodium salt ing for Then, the stick insertion depth test was again ... Conclusions 3.1 Stick insertion depth test The density and hardness of the negative pastes of leadacid batteries, that contain organic compounds with or without quinone structures have been investigated...
... layers [15–17], although its role is not clear and alloying elements in lead positive electrode current collectors in leadacid batteries are known to improve battery performance [4,5,16] Hence, ... for the deposition of either lead or lead dioxide (except for lower current densities resulting from the higher viscosity of the medium) Moreover, SEM images of the lead deposits showed little ... effective levelling agent for lead in methanesulfonic acid media even when thick layers are deposited at relatively high rates The need for levelling of the electroplated lead appears to be greater...
... low rate capacity than a conventional VRLA automotive battery because of the improved grid designs The h capacity of the cells was 4.9 Ah 4523 A number of cells were subjected to a simplified HEV ... 4520–4524 Acknowledgements References The financial support of the Advanced LeadAcid Battery Consortium/International Lead Zinc Research Organisation is gratefully acknowledged Al Vincze, Victor ... designs [1] A Cooper, L.T Lam, P.T Moseley, D.A.J Rand, in: D.A.J Rand, al et (Eds.), ValveRegulated Lead- Acid Batteries, Elsevier BV, 2004, pp 549–565 [2] K Yamada, K Maeda, K Sasaki, T Hirasawa,...
... gives the best result for the leadacid system The reason is that the leadacid battery has a relatively high U0 (2.1 V) and a rather low specific resistance of sulfuric acid as the electrolyte (1.1 ... Nevertheless, the leadacid battery has a high power capability and, in spite of the high weight of lead, should be a very suitable system for a high power supply In addition, leadacid has a significant ... resistance For valve-regulated leadacid (VRLA) designs with antimonyfree grid alloys, the OCV has been raised to a slightly higher level over the years by an increase in sulfuric acid concentration from...
... professional systems) but incure significant cost due to maintenance frequency Valve regulated leadacid batteries (VRLA) using tubular gel technology require no maintenance, are as reliable as flooded ... electrolyte formulation was determined by taking into account the lead sulphate equilibrium in the acid This formulation was tested in cells and in different types of standard SLI ¯ooded batteries ... cycling of plates in cells with additives show that it is mainly colloidal silica and phosphoric acid that provide improved results in the accelerating test procedure in cells and give interesting...
... collaboration by the Advanced LeadAcid Battery Consortium ŽALABC The Advanced LeadAcid Battery Consortium The responsibility for ensuring that the best possible leadracid batteries become available ... valve-regulated leadracid battery, is described in Section 3 Advances in valve-regulated lead r acid electricvehicle battery technology The major advances in the development of valve-regulated leadracid ... to build a new generation of leadracid batteries As a starting point, it was decided that the electricvehicle battery must be maintenance free Thus, the flooded leadracid battery that was introduced...
... applicable in a leadacid battery This is mainly because of the relatively heavy requirement for good corrosion resistance in leadacid batteries (i.e., at up to 2.5 V per cell in a leadacid battery ... by 12 V, 30 Ah bipolar leadacid battery; sixteenth hour of PALC test Testing of 12 V 30 Ah bipolar leadacid battery using PALC schedule The 12 V, 30 Ah bipolar leadacid battery was discharged ... power-assist life cycle for 12 V, 30 Ah bipolar leadacid battery There are, however, some technical obstacles to overcome with respect to the bipolar leadacid battery before successful commercialization...
... discussion, it was noted that the balance of active materials in a lead/ acid cell influences the discharge performance For VRLA cells, the relative amounts of mate.rials also influences the efficiency ... its effect on the useful capacity To this, two distinctly different types of valve-regulated lead/ acid (VRLA) cell/battery are examined One is similar in plate design to the majority of units I ... situations where a cell/ battery case is ruptured, e.g as a result of an accident or collision For lead/ acid, VRLA technology meets this important criterion In this work, units A and B both utilize absorptive...
... individual cells was measured individually using Pt-100 thermo-resistors put into the cells after sealing the cells Filling of the cells was done after sealing using 1.28 g/ cm3 sulphuric acid solution ... bipolar leadacid battery is an attractive candidate Another advantage of the bipolar leadacid battery is the low cost of the components as well as the infrastructure available for recycling lead ... (upper curve) and t 10 s (lower curve) for a 12 V bipolar leadacid battery experiments, is a function of time For the 12 V bipolar leadacid battery we measured the discharge power at t and...
... of vacuum cooling Explanation Temperature peaks that lead to the production of burned lead come from points where the acid impacts on the lead oxide (Fig 4) At these points, the temperature rises ... production of burned lead (monobasic lead sulfate) in an air-cooled system with the production results of a vacuum system that replaced the conventional plant The proportion of burned lead, thus the ... Temperature course in a partial paste volume during the reaction of acid and oxide IS bitch 10 11 12 no Fig Dependence of burned -lead content on cooling system Again, this only depends upon the...
... Fig Nyquist plot of a 18 Ah flooded leadacid battery 858 J.C Hern´ ndez et al / Journal of Power Sources 162 (2006) 851–863 a Fig Nyquist plot of a 18 Ah gel VRLA battery Table Initial electrical ... kinetic study was carried out by measuring the penetration of lead balls (3 mm diameter) into the gel at different times SiO2 concentration, acid concentration and initial temperature were variables ... used in the manufacture of 15 Ah gel VRLA batteries for stand-by applications The battery design was based on former work on the development of high power VRLA batteries for UPS applications [9],...