Tổng hợp, biến tính và ứng dụng vật liệu khung hữu cơ - kim loại ZIF-67

ĐẠI HỌC HUẾ TRƯỜNG ĐẠI HỌC KHOA HỌC NGUYỄN THỊ THANH TÚ TỔNG HỢP, BIẾN TÍNH VÀ ỨNG DỤNG VẬT LIỆU KHUNG HỮU CƠ - KIM LOẠI ZIF-67 LUẬN ÁN TIẾN SĨ HÓA HỌC HUẾ - NĂM 2019 ĐẠI HỌC HUẾ TRƯỜNG ĐẠI HỌC KHOA HỌC NGUYỄN THỊ THANH TÚ TỔNG HỢP, BIẾN TÍNH VÀ ỨNG DỤNG VẬT LIỆU KHUNG HỮU CƠ - KIM LOẠI ZIF-67 Chuyên ngành: Hóa lý thuyết Hóa lý Mã số: 9440119 LUẬN ÁN TIẾN SĨ HÓA HỌC Người hướng dẫn khoa học: GS.TS Đinh Quang Khiếu TS Trần Vĩnh Thiện HUẾ - NĂM 2019 LỜI CAM ĐOAN Tôi xin cam đoan luận án cơng trình nghiên cứu riêng tơi hướng dẫn GS.TS Đinh Quang Khiếu, Khoa Hóa, Trường Đại học Khoa Học, Đại học Huế TS.Trần Vĩnh Thiện, Trường Đại học Tài nguyên Môi trường Các số liệu kết nghiên cứu luận án trung thực, đồng tác giả cho phép sử dụng chưa công bố cơng trình khác Tác giả Nguyễn Thị Thanh Tú LỜI CẢM ƠN Lời xin chân thành cảm ơn sâu sắc đến GS.TS Đinh Quang Khiếu, PGS.TS Nguyễn Hải Phong, TS Trần Vĩnh Thiện, người thầy tận tình giúp đỡ hướng dẫn suốt thời gian làm luận án Tơi xin chân thành cảm ơn Khoa Hóa học, Phịng đào tạo sau đại học, Trường Đại học Khoa học – Đại học Huế, Ban đào tạo – Đại học Huế tạo điều kiện cho tơi q trình học tập hồn thành luận án Tơi xin cảm ơn q Thầy/Cơ Bộ mơn Hóa lý, Hóa Phân tích, Khoa Hóa, Trường Đại học Khoa học – Đại học Huế giúp đỡ suốt thời gian làm luận án Tôi xin chân thành cảm ơn Khoa Hóa học Trường đại học Bách Khoa Đà Nẵng, Trường Đại học Khoa học Tự nhiên Hà Nội, Viện Khoa học Vật liệu Hà Nội hỗ trợ phân tích mẫu thí nghiệm luận án Tơi xin bày bỏ lòng biết ơn sâu sắc đến PGS.TS Phùng Chí Sỹ, Giám đốc Trung tâm Cơng nghệ Mơi trường, Viện trưởng Viện Khoa học Môi trường, Trường Đại học Nguyễn Tất thành tạo điều kiện giúp đỡ tơi suốt q trình thực luận án Cuối xin cảm ơn sâu sắc đến gia đình, Thầy/Cơ đồng nghiệp bạn bè động viên, giúp đỡ tơi suốt q trình học tập nghiên cứu Huế, tháng 12 năm 2019 Tác giả Nguyễn Thị Thanh Tú DANH MỤC CÁC CHỮ VIẾT TẮT, KÍ HIỆU AAS Phổ hấp thụ nguyên tử (Atomic Absorption Spectrophotometry) Abs Hấp thụ (Absorption) Ads Hấp phụ (adsorption) AIC Chuẩn số thông tin (Akaike’s Information Criterion) AICc Chuẩn số thông tin hiệu chỉnh (Akaike’s Information Criterion corrected) ASV Volt-ampere hòa tan anot (Anodic Stripping Voltammetry) BET Brunauer-Emmett-Teller B-RBS Dung dịch đệm Britton-Robinson (Britton-Robinson buffer solution) CB Vùng dẫn (conduction band) CGR Congo red CS Cộng CV Volt-ampere vòng (Cyclic Voltammetry) DPA DP Dopamine Xung vi phân (Differential Pulse) Eg Năng lượng vùng cấm (band gap energy) GCE Điện cực than thủy tinh (Glassy Carbon Electrode) Hmin IM LOD MB 2-methylimidazole Imidazole Giới hạn phát (Limit of detection) Methylene blue MO Methyl orange MOFs Vật liệu khung hữu kim loại (Metal-Organic Frameworks) Me Kim loại MW Vi sóng (microwave) Org Hợp chất hữu (organic) PRA Paracetamol p Giá trị xác suất ý nghĩa thống kê pHPZC pH điểm đẳng điện ( point zero charge) RSD Độ lệch chuẩn tương đối (Relative Standard Deviation) RhB Rhodamine B RT Nhiệt độ phòng (Room temperature) SBU Đơn vị xây dựng thứ cấp (Secondary Building Unit) SEM Hiển vi điện tử quét (Scanning Electron Microscopy) SOD Cấu trúc sodalide SV Volt-ampere hịa tan (Stripping Voltammetry) SSEs Tổng bình phương sai số ( Sum of the square Errors) ST Dung nhiệt (solvethermal) TG Biến đổi trọng lượng theo nhiệt độ (Thermogravimetry) UV-Vis DRS Phổ phản xạ khuếch tán tử ngoại khả kiến (UV-Visible diffuse reflectance spectroscopy) VB Vùng hóa trị (valence band) WE Điện cực làm việc (Working Electrode) XPS Phổ quang điện tử tia X (X-ray Photoelectron Spectroscopy) XRD Nhiễu xạ tia X (X-Ray Diffraction) ZIFs Khung imidazolate zeolite (Zeolitic Imidazolate Frameworks) MỤC LỤC Trang DANH MỤC BẢNG BIỂU DANH MỤC HÌNH VẼ, BIỂU ĐỒ, SƠ ĐỒ MỞ ĐẦU Chương TỔNG QUAN TÀI LIỆU 1.1 GIỚI THIỆU CHUNG VẬT LIỆU KHUNG HỮU CƠ KIM LOẠI (MOFs) 1.2 VẬT LIỆU KHUNG HỮU CƠ KIM LOẠI ZIF-67 1.3 PHƯƠNG PHÁP TỔNG HỢP ZIF-67 1.4 CÁC HƯỚNG BIẾN TÍNH VẬT LIỆU ZIF-67 VÀ CÁC ỨNG DỤNG .13 1.4.1 Ứng dụng vật liệu ZIF-67 làm chất xúc tác điện hóa .13 1.4.2 Ứng dụng quang xúc tác phân hủy chất nhiễm hữu khó phân hủy .16 1.4.3 Ứng dụng vật liệu ZIF-67 làm chất hấp phụ loại bỏ màu phẩm nhuộm dung dịch nước 23 1.5 MỘT SỐ VẤN ĐỀ TRONG PHÂN TÍCH CÁC THƠNG SỐ ĐỘNG HỌC VÀ ĐẲNG NHIỆT HẤP PHỤ 25 1.5.1 Một số vấn đề nghiên cứu trình hấp phụ 25 1.5.2 Biến thiên lượng tự Gibbs 29 Chương NỘI DUNG VÀ PHƯƠNG PHÁP NGHIÊN CỨU 36 2.1 NỘI DUNG NGHIÊN CỨU 36 2.1.1 Nghiên cứu tổng hợp ZIF-67 phương pháp vi sóng phương pháp dung môi nhiệt .36 2.1.2 Nghiên cứu khả hấp phụ phẩm nhuộm congo red nước ZIF-67 .36 2.1.3 Nghiên cứu biến tính điện cực GCE ZIF-67 để xác định dopamine paracetamol phương pháp volt-ampere hòa tan 36 2.1.4 Nghiên cứu tổng hợp (Zn/Co)ZIFs có hoạt tính xúc tác quang hóa 36 2.1.5 Nghiên cứu khả quang xúc tác (Zn/Co)ZIFs phân hủy màu thuốc nhuộm điều kiện ánh sáng khả kiến 36 2.2 PHƯƠNG PHÁP NGHIÊN CỨU 36 2.2.1 Các phương pháp nghiên cứu đặc trưng vật liệu .36 2.2.2 Phương pháp volt-ampere hòa tan (Stripping Voltammetry) 42 2.3 THỰC NGHIỆM 44 2.3.1 Hóa chất 44 2.3.2 Tổng hợp vật liệu .44 2.3.3 Xác định điểm đẳng điện vật liệu ZIF-67 (Zn/Co)ZIFs .46 2.3.4 Kiểm tra độ bền vật liệu ZIF-67 (Zn/Co)ZIFs 47 2.3.5 Hấp phụ phẩm nhuộm vật liệu ZIF-67 47 2.3.6 Biến tính điện cực than thủy tinh vật liệu ZIF-67 để xác định dopamine paracetamol 48 2.3.7 Nghiên cứu hoạt tính quang xúc tác phân hủy CGR vật liệu (Zn/Co)ZIFs .50 Chương KẾT QUẢ VÀ THẢO LUẬN .52 3.1 TỔNG HỢP ZIF-67 BẰNG PHƯƠNG PHÁP VI SÓNG VÀ PHƯƠNG PHÁP DUNG MÔI NHIỆT 52 3.1.1 Đặc trưng vật liệu ZIF-67 52 3.1.2 Độ bền vật liệu ZIF-67 60 3.2 NGHIÊN CỨU HẤP PHỤ CONGO RED (CGR) BẰNG ZIF-67 61 3.2.1 Nghiên cứu động học hấp phụ 61 3.2.2 Nghiên cứu cân hấp phụ 68 3.2.3 Nghiên cứu nhiệt động học hấp phụ 72 3.2.4 Ảnh hưởng pH đề xuất chế hấp phụ 76 3.2.5 Tái sử dụng chất hấp phụ ZIF-67 .77 3.3 NGHIÊN CỨU PHÁT TRIỂN PHƯƠNG PHÁP PHÂN TÍCH PRACETAMOL (PRA) VÀ DOPAMINE (DPM) BẰNG PHƯƠNG PHÁP ĐIỆN HÓA SỬ DỤNG ĐIỆN CỰC BIẾN TÍNH ZIF-67 78 3.3.1 Khảo sát ảnh hưởng loại điện cực khác lên đặc tính điện hóa PRA DPM 78 3.3.2 Khảo sát ảnh hưởng dung môi lượng ZIF-67 .80 3.3.3 Khảo sát ảnh hưởng pH .82 3.3.4 Khảo sát ảnh hưởng tốc độ quét (ν) .84 3.3.5 Những ảnh hưởng thông số máy hoạt động 87 3.3.6 Ảnh hưởng số chất cản trở 88 3.3.7 Độ lặp lại giới hạn phát .91 3.3.8 Phân tích mẫu thực 95 3.4 NGHIÊN CỨU TỔNG HỢP (Zn/Co)ZIFs 96 3.5 NGHIÊN CỨU PHÂN HỦY CGR CỦA XÚC TÁC QUANG (Zn/Co)ZIFs 103 3.5.1 Khử màu CGR xúc tác khác 103 3.5.2 Ảnh hưởng pH chất bắt gốc tự 104 3.5.3 Phân hủy quang hóa CGR vật liệu (2Zn/8Co)ZIFs điều kiện ánh sáng khả kiến .106 3.5.4 Khả tái sử dụng (2Zn/8Co)ZIFs 110 KẾT LUẬN 113 DANH MỤC CÁC CƠNG TRÌNH CƠNG BỐ KẾT QUẢ NGHIÊN CỨU CỦA LUẬN ÁN TÀI LIỆU THAM KHẢO PHỤ LỤC DANH MỤC BẢNG BIỂU Bảng 1.1 Mơ tả cấu trúc hình học số SBU điển hình Bảng 1.2 Kích thước hình thái ZIF-67 thu điều kiện phản ứng khác .10 Bảng 1.3 SBET, Vmicro Dmicro tinh thể ZIF-67 thu với tỉ lệ mol Hmin/Co2+ = 20 điều kiện thủy nhiệt 120 °C nhiệt độ phòng 11 Bảng 1.4 So sánh hiệu quang xúc tác MOFs chất hữu khó phân hủy môi trường nước 22 Bảng 1.5 Sự chuyển đổi K0 K 34 Bảng 2.1 Các loại hóa chất sử dụng thực nghiệm 44 Bảng 2.2 Các mẫu ZIF-67 biến tính kẽm theo tỷ lệ khác 46 Bảng 3.1 Đặc tính cấu trúc kích thước hạt/tinh thể ZIF-67 tổng hợp nhiều cách tiếp cận khác .58 Bảng 3.2 Các thông số động học mơ hình biểu kiến bậc mơ hình biểu kiến bậc .63 Bảng 3.3 So sánh hồi quy tuyến tính đa đoạn cho một, hai, ba bốn đoạn sử dụng chuẩn số thông tin AIC 66 Bảng 3.4 Kết phân tích hồi quy tuyến tính ba đoạn theo mơ hình Weber ZIF-67 (giá trị ngoặc đơn hoảng tin cậy 95%) .66 Bảng 3.5 Các thơng số mơ hình khuếch tán màng Boyd hấp phụ CGR vật liệu ZIF-67 .67 Bảng 3.6 Các thơng số mơ hình đẳng nhiệt Langmuir Freundlich nhiệt độ khác 69 Bảng 3.7 Dung lượng hấp phụ chất hấp phụ khác CGR, MB, RhB nhiệt độ môi trường xung quanh 71 Bảng 3.8 Hằng số tốc độ hấp phụ CGR ZIF-67 nhiệt độ khác 72 Bảng 3.9 Các thông số nhiệt động học tính tốn số cân khác .75 Bảng 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TÀI LIỆU 1.1 GIỚI THIỆU CHUNG VẬT LIỆU KHUNG HỮU CƠ KIM LOẠI (MOFs) 1.2 VẬT LIỆU KHUNG HỮU CƠ KIM LOẠI ZIF-67 1.3 PHƯƠNG PHÁP TỔNG HỢP ZIF-67 1.4 CÁC HƯỚNG BIẾN TÍNH VẬT LIỆU... pháp tổng hợp để cải thiện đặc tính cấu trúc vật liệu ZIF-67 đóng vai trị quan trọng ứng dụng chưa đề cập đến nhiều Dựa lý chọn đề tài luận án ? ?Tổng hợp, biến tính ứng dụng vật liệu khung hữu - kim. .. - kim loại ZIF-67? ?? Mục tiêu nghiên cứu: Tổng hợp biến tính vật liệu khung hữu – kim loại ZIF-67 có hoạt tính xúc tác, hấp phụ cảm biến điện hóa Nội dung luận án: - Nghiên cứu tổng hợp ZIF-67 phương