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www.tuhoc.edu.vn – oxit cacbon: CO, CO2 – – 4C3, CaC2, v.v… – – – – VD1: NaHCO3 KCN C3H9N CaC2 C6H5OH Al4C3 HCOONa CaCO3 CO2 (NH4)2CO3 CHCl3 (NH2)2CO – – – – – có xúc tác – htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn VD2: CH4, C2H4, C6H6 VD3: C2H5OH, C3H9N, CHCl3 TOPPER Chú ý A) B) C) D) 4, CHCl3, KHCO3, NH4HCO3, C2H5NH2, HCN, CH3COONa, C12H22O11, (C2H3Cl)n, CO2, (COOH)2 A) B) C) D) A) B) C) D) CH3COOH, CH2=CH–CH2OH, C6H5–CH=CH2, CH4, C6H12O6, (CH3)3N, CH A) B) C) D) A) C2H2, C2H5OH, C2H5NH2, C12H22O11 B) C2H5OH, HCOOCH3, (CH3)3N, CH3Cl C) CH3CHO, C6H6, (COOH)2, CH3COOC2H3 D) C2H3Cl, NaCN, CH3NH2, (C2H3Cl)n htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn H O —C=C—C—O—H X 1,3 – A) 5, 3, C) 3, 5, B) 4, 3, D) 4, 2, Etilen: H—C=C—H H H H H H H H H H H H C C C C C C C=C—H H H (A) (B) htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn – – – —" • • VD4: —C • • VD5: TOPPER Chú ý CH2=CH–CH3 VD6: —C 6H6 H H H C C C C C C C H C C H C C C H C C—C C C C C C htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn TOPPER Chú ý cacbon oxi (2 1); 3); halogen (1) – – VD7: 2H4 H—C=C—H H H VD8: 2H4O2 H H H H—C—C—O—H O H—C—O—C—H H O H O H—C—C—O—H H htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn H –C—H –CH3 H H –O—H –OH –N—H –NH2 VD: CH3–CH2–OH CH3CH2OH O O –C—H –CHO –C—OH –COOH H VD9: O —C—C—O—H H O — 3—C—OH — 3COOH H H H H H H htttp://tuhoc.edu.vn/blog H (A) H—C=C—C—O—H (B) H—C—C—N—C—H H H H H www.tuhoc.edu.vn Các VD10: CH4 C2H6 +CH2 C3H8 +CH2 C4H10 v.v… +CH2 – hóa khác 2H4O2 A TOPPER Chú ý B không không A) CH4, C2H6, C3H8, C4H10 C) C6H6, C7H8, C8H10, C9H12 B) C2H4, C3H6, C4H8, C5H10 D) C4H4, C4H6, C4H8, C4H10 không A) CH3COOH HCOOCH3 B) (CH3)2NH CH3CH2NH2 C) CH3CH2OH CH3OCH3 D) CH2=CH–COOH CH2=CH–CH2OH C A) B) C) D) htttp://tuhoc.edu.vn/blog www.tuhoc.edu.vn 10 B A + C D A VD11: CH3CH2OH + HBr to + D C B CH3CH2Br + HOH H2O + A VD12: CH2=CH2 + H2 A VD13: CH2—CH2 H B Ni to A B CH3CH3 B A H2 SO4 (®Æc) 180 o C + B CH2=CH2 + H2O OH VD14: C3H8 + 5O2 to 3CO2 + 4H2O D A) CH4 + 3O2 B) C4H10 htttp://tuhoc.edu.vn/blog Ni to to CO2 + 2H2O CH4 + C3H6 C) C2H4 + HBr C2H5Br D) CH3COOC2H5 + NaOH CH3COONa + C2H5OH www.tuhoc.edu.vn (B) H H H E (A) H—C—C—C—H H H H H—C—C—C—O—H H O H H H H H (D) H H H (C) H H H—C—N—C—H (E) O H H (F) H H TOPPER Chú ý H H—C—O—C—H H C C C C C H H O C C—O—H H H F A) B) C) D) G (1) CH2=CH2 + H2O CH3CH2OH (2) C2H6 + Cl2 C2H5Cl + HCl (3) CH 2O 2O CH3CH2OH + NaCl (4) CH3CH2Cl + NaOH (5) CH3CHO + H2 CH3CH2OH (6) CH3COOH + C2H5OH HCOONa + CH3OH (7) HCOOCH3 + NaOH HCOONa + H2O (8) CH3NH2 + HCl CH3NH3Cl CH2=CH2 + CH4 (9) CH3CH2CH3 htttp://tuhoc.edu.vn/blog (A) (B) (C) www.tuhoc.edu.vn Câu C Câu A B D B B D B C B B D D A E F B G 67 +2 (a) CH2=CH–CH2OH; (b) CH3CH2NHCH3 E (a) CH3CH2CH2OH (c) CH3NHCH3 (e) HCOOCH3 (b) CH3CHOHCH3 3)2NH (d) CH2=CH (f) 3)2CHOH COOH G htttp://tuhoc.edu.vn/blog 10