1 – oxit cacbon: CO, CO2 – – 4C3, CaC2, v.v… – – – – VD1: NaHCO3 KCN C3H9N CaC2 C6H5OH Al4C3 HCOONa CaCO3 CO2 (NH4)2CO3 CHCl3 (NH2)2CO – – – – – có xúc tác – VD2: CH4, C2H4, C6H6 VD3: C2H5OH, C3H9N, CHCl3 Chú ý A) B) C) D) 4, CHCl3, KHCO3, NH4HCO3, C2H5NH2, HCN, CH3COONa, C12H22O11, (C2H3Cl)n, CO2, (COOH)2 A) B) C) D) A) B) C) D) CH3COOH, CH2=CH–CH2OH, C6H5–CH=CH2, CH4, C6H12O6, (CH3)3N, CH A) B) C) D) A) C2H2, C2H5OH, C2H5NH2, C12H22O11 B) C2H5OH, HCOOCH3, (CH3)3N, CH3Cl C) CH3CHO, C6H6, (COOH)2, CH3COOC2H3 D) C2H3Cl, NaCN, CH3NH2, (C2H3Cl)n H O —C=C—C—O—H X 1,3 – A) 5, 3, C) 3, 5, B) 4, 3, D) 4, 2, Etilen: H—C=C—H H H H H H H H H H H H C C C C C C C=C—H H H (A) (B) – – – —" • • VD4: —C • • VD5: Chú ý CH2=CH–CH3 VD6: —C 6H6 H H H C C C C C C C H C C H C C C H C C—C C C C C C Chú ý cacbon 1); 3); halogen (1) – – VD7: 2H4 H—C=C—H H H VD8: 2H4O2 H H—C—C—O—H H O H O H—C—O—C—H H O H oxi (2 H—C—C—O—H H H –C—H –CH3 H H –O—H –OH –N—H –NH2 VD: CH3–CH2–OH CH3CH2OH O O –C—H –CHO –C—OH –COOH H VD9: O —C—C—O—H H O — 3—C—OH — 3COOH H H H H H H H (A) H—C=C—C—O—H (B) H—C—C—N—C—H H H H H Các VD10: CH4 C2H6 +CH2 C3H8 +CH2 C4H10 v.v… +CH2 – hóa khác 2H4O2 A Chú ý B không không A) CH4, C2H6, C3H8, C4H10 C) C6H6, C7H8, C8H10, C9H12 B) C2H4, C3H6, C4H8, C5H10 D) C4H4, C4H6, C4H8, C4H10 không A) CH3COOH HCOOCH3 B) (CH3)2NH CH3CH2NH2 C) CH3CH2OH CH3OCH3 D) CH2=CH–COOH CH2=CH–CH2OH C A) B) C) D) 10 B A + C D A VD11: CH3CH2OH + HBr to + D C B CH3CH2Br + HOH H2O + A VD12: CH2=CH2 + H2 A VD13: CH2—CH2 H B Ni to A B CH3CH3 B A H2 SO4 (®Æc) 180 o C + B CH2=CH2 + H2O OH VD14: C3H8 + 5O2 to 3CO2 + 4H2O D A) CH4 + 3O2 B) C4H10 Ni to to CO2 + 2H2O CH4 + C3H6 C) C2H4 + HBr C2H5Br D) CH3COOC2H5 + NaOH CH3COONa + C2H5OH (B) H H H E (A) H—C—C—C—H H H H H—C—C—C—O—H H O H H H H H (D) H H H (C) H H H—C—N—C—H (E) O H H (F) H H Chú ý H H—C—O—C—H H C C C C C H H O C C—O—H H H F A) B) C) D) G (1) CH2=CH2 + H2O CH3CH2OH (2) C2H6 + Cl2 C2H5Cl + HCl (3) CH 2O 2O (4) CH3CH2Cl + NaOH CH3CH2OH + NaCl (5) CH3CHO + H2 CH3CH2OH (6) CH3COOH + C2H5OH HCOONa + CH3OH HCOONa + H2O (7) HCOOCH3 + NaOH (8) CH3NH2 + HCl CH3NH3Cl CH2=CH2 + CH4 (9) CH3CH2CH3 (A) (B) (C) Câu C Câu A B D B B D B C B B D D A E F B G 67 +2 (a) CH2=CH–CH2OH; (b) CH3CH2NHCH3 E (a) CH3CH2CH2OH (c) CH3NHCH3 (e) HCOOCH3 (b) CH3CHOHCH3 3)2NH (d) CH2=CH (f) 3)2CHOH COOH G 10