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©2001 CRC Press LLC Figure 3.2.4 Simplified energy level diagram for singly ionized gold showing the number of laser lines in each supermultiplet. The energies of the He and Ne metastables and ground-state ions are also shown with respect to the ground state of the neutral gold atom. ©2001 CRC Press LLC Figure 3.2.5 Simplified energy level diagram for singly ionized zinc showing the majority of observed Zn + laser lines. The energies of the He and Ne metastables and ground-state ions are also shown with respect to the ground state of the neutral zinc atom. (From Bridges, W. B., Methods of Experimental Physics, Vol. 15A, Tang, C. L., Ed., Academic Press, New York, 1979. With permission.) ©2001 CRC Press LLC Figure 3.2.6 Simplified energy level diagram for singly ionized mercury showing the majority of observed Hg + laser lines. The energies of the He and Ne metastables and ground-state ions are also shown with respect to the ground state of the neutral mercury atom. (From Bridges, W. B., Methods of Experimental Physics, Vol. 15A, Tang, C. L., Ed., Academic Press, New York, 1979. With permission.) ©2001 CRC Press LLC Figure 3.2.7 Simplified energy level diagram for singly ionized cadmium showing the majority of observed Cd + laser lines. The energies of the He and Ne metastables and ground-state ions are also shown with respect to the ground state of the neutral cadmium atom. (From Bridges, W. B., Methods of Experimental Physics, Vol. 15A, Tang, C. L., Ed., Academic Press, New York, 1979. With permission.) ©2001 CRC Press LLC Figure 3.2.8 Energy level diagram for singly ionized neon showing the majority of Ne + laser lines. Energy levels are from Moore, C. E., Reference 1757. ©2001 CRC Press LLC Figure 3.2.9 Energy level diagram for singly ionized argon showing the majority of Ar + laser lines. Energy levels are from Moore, C. E., Reference 1757. ©2001 CRC Press LLC Figure 3.2.10 Simplified energy level diagram for Ar + showing the blue-green laser lines in the 4p → 4s supermultiplet. (From Bridges, W. B., Appl. Phys. Lett. 4, 128, 1964. With permission.) ©2001 CRC Press LLC Figure 3.2.11 Energy level diagram for doubly ionized argon showing the majority of Ar 2+ laser lines. Energy levels are from Moore, C. E., Reference 1757, except those shown dashed which are positioned through isoelectronic arguments by McFarlane 997 and Marling 989 . ©2001 CRC Press LLC Figure 3.2.12 Energy level diagram for singly ionized krypton showing the majority of Kr + laser lines. Energy levels are from Moore, C. E., Reference 1757; revisions from Minnhagen et al. 1007 ©2001 CRC Press LLC Figure 3.2.13 Energy level diagram for doubly ionized krypton showing the majority of Kr 2+ laser lines. Energy levels are from Moore, C. E., Reference 1757. [...]... 0 .52 5367 0 .52 5320 ±0.000 050 1 (3 P)5p 4 D 0 1/2 → (3 P)5s 4 P 0 1/2 0 .52 71 15 0 .52 7130 ±0.000 050 1 (1 D)5p 2 D 0 5/ 2 → (1 D)5s 2 D 3/2 0 .52 7127 0 .52 7130 ±0.000 050 1 (3 P)5p 4 D 0 5/ 2 → (3 P)4d 4 F7/2 0 .53 053 9 0 .53 055 0 ±0.000 050 1 (3 P)5p 2 D 0 3/2 → (3 P)5s 2 P 1/2 0 .55 2244 0 .55 2280 ±0.000 050 1 (3 P)5p 4 P 0 5/ 2 → 4s4p 4 2 P 3/2 0 .55 2266 0 .55 2280 ±0.000 050 1 (3 P)5p 4 P 0 3/2 → (3 P)5s 4 P 5/ 2 0 .55 6688... 9 15, 958 ,963, 958 , 1087,1090,1219 1034,1069 1076,1083,1086, 9 15, 943, 958 ,1069 1092 0 .51 759 3 0 .52 2760 ±0.000 050 → 1076,1083,1086 958 ,1069 ±0.000 050 1 5/ 2 3/2 (3 P)5p 4 D 0 7/2 → (3 P)5s 4 P 5/ 2 1076,1083,1086, 9 15, 943, 958 , 1087,1090,1220 0 .52 2749 0 .51 7600 (3 P)5s 4 P 963,1034,1069 1076,1083,1086, 9 15, 943, 958 , 1087,1088,1090, 963,1034,1069 1092,1221 0 .52 5309 0 .52 5260 ±0.000 050 1 (3 P)5p 2 D 0 5/ 2 → (3 P)5s... (3 P)5p 2 D 0 5/ 2 → 4s4p 4 2 P 3/2 0.499279 0.499290 ±0.000 050 1 (3 P)5p 4 P 0 3/2 → (3 P)5s 4 P 3/2 0 .50 68 65 0 .50 6870 ±0.000 050 1 (3 P)5p 4 P 0 5/ 2 → (3 P)5s 4 P 5/ 2 0 .50 9 650 0 .50 9610 ±0.000 050 1 ?( 3 P)5p 4 D 0 7/2 → (3 P)4d 4 F9/2 0 .51 42 15 0 .51 4190 ±0.000 050 1 (3 P)5p 4 D 0 3/2 → (3 P)5s 4 P 1/2 1 (3 P)5p 4 D 0 1076,1083,1086, 9 15, 958 , 1087,1090,1217 1034,1069 1076,1083,1086, 9 15, 958 , 1087,1090,1218... Transition Comments 0 .54 5380 0 .54 5388 ±0.000006 1 (3 P)4p 4 D 0 7/2 → (3 P)4s 4 P 5/ 2 0 .54 7360 0 .54 7374 ±0.000006 1 (3 P)4p 4 D 0 1/2 → (3 P)4s 4 P 1/2 1083,1084,1092, References 857 ,869,1489 1094,12 15 → 869,1489 0 .55 09 65 0 .55 0990 ±0.000006 1 3/2 1084 1489 0 .55 6491 0 .55 651 1 ±0.000006 1 (3 P)4p 4 D 0 5/ 2 → (3 P)4s 4 P 5/ 2 1084 1489 1 (3 P)4p 2 D 0 0 .56 3999 0 .56 4012 ±0.000006 3/2 5/ 2 → (3 P)4s 4 P 1084,1094... 1084,1090,1121 155 ,11 45 1 (1 S)6p 2 P 0 1084,1090,1122 155 ,11 45 1/2 → (1 S)5s 2 S1/2 1118 1073,1083,1087, 9 05, 1064,11 45 9 05, 928,11 45 1119 868,9 05, 1139,11 45 5.08483 5. 086000 © 2001 CRC Press LLC ±0.000100 ±0.000400 3/2 → (1 S)5d 2 D 5/ 2 Cadmium Wavelength ( m) Measured value ( m) Uncertainty Charge Transition Comments References 1 4d 10 5d 2 S1/2 →4d 10 5p 2 P 3/2 6923 852 0. 257 3 1 6923 852 0.2748 1 6923 852 6920... 0.2312 0.3 250 1 0.3 250 29 0.3 250 1 4d 10 6s 2 S1/2 →4d 10 5p 2 P 12 4d 10 6s 2 S1/2 →4d 10 5p 2 P 3/2 5s 2 2 D 3/2 → (1 S)5p 2 P 0 1/2 5s 2 2 D 3/2 → (1 S)5p 2 P 0 1/2 0.44 156 5 0.44 156 0 1 5s 2 2 D 5/ 2 → (1 S)5p 2 P 0 3/2 1074,1083,1086, 1034 1087,1090 ±0.000070 → 0.4416 0.488172 1 0.4882 1 (3 D)5p 4 F0 5/ 2 → (1 S)5d 2 D 3/2 5/ 2 → 10 65, 1083,10 85 6920 3/2 (1 S)5d 2 D 1034,1039,1064, 1088,1090,1123 5s 2 2... 0 .55 6710 ±0.000 050 1 (3 P)5p 4 D 0 3/2 → (3 P)5s 4 P 3/2 1 (3 P)5p 4 P 0 → 1076,1083,1086, 958 ,1034,1069 1087 1076,1083,1086, 958 ,1034,1069 1087 1076,1083,1086, 958 ,1069 1222 1076,1083,1086, 958 ,1069 1223 1076,1083,1086, 9 15, 958 ,1069 1090 0 .55 9160 © 2001 CRC Press LLC ±0.000 050 3/2 1/2 958 ,1069 1076,1083,1086, 9 15, 943, 1087,1090,1224 0 .55 9113 9 15, 943, 1087,1090,12 25 (3 P)5s 2 P 1076,1083,1086, 958 ,1069... 1086,1088, 1090,1116 0. 758 848 0. 758 750 ±0.000160 1 (1 S)5p 2 P 0 3/2 → (1 S)5s 2 S1/2 844 676,9 05, 9 45, 1023 1034,1036,1039, 1064,10 85, 11 45 1076,1083,1084, 676,9 05, 9 45, 953 1087,1090,1117 1034,1036,1039, 1064,10 85, 11 45 → 0.76121 0.761118 ±0.000160 1 0.773 250 0.773 250 ±0.000 050 1 9( 1 S)6s 2 S1/2 (1 S)5p 2 P 0 1/2 (1 S)5p 2 P 0 0.7 757 86 0.7 757 1 (1 S)6s 2 S1/2 → (1 S)5p 2 P 0 3/2 1076,10 85, 1120 1.83083 1.831000... (1 S)5p 2 P 0 1074,1081,1083, 0 .50 254 8 0 .50 259 1 (3 D)5p 4 F0 0 .53 3748 0 .53 37 1 (1 S)4f 2 F0 5/ 2 → (1 S)5d 2 D 3/2 1073,1083 676–678 1027 0 .53 7813 0 .53 38 1 (1 S)4f 2 F0 → (1 S)5d 2 D 1027 1073,1081,1083, 868,871, 953 ,1023 1034,1039,1 057 , 1090,1124 5/ 2 1073,1083,1090 1084,1087,1088, 7/2 1 058 ,1083,10 85 5/2 1073,1081,1083, 868,871, 953 ,1023 1084,1087,1088, 7/2 1034,1039,1 057 , 1090 2 1G → (1 S)4f 2 F0 5/ 2... 3/2 1130 160,9 05 1131 160 1128 1 0.8677 9 05, 951 ,10 35, 1086,1087,1134 0.86220? 1076,1081,1083, 160 (1 S)10s 2 S1/2 → (1 S)8p 2 P 0 3/2 (1 S)8s 2 S1/2 → (1 S)7p 2 P 0 3/2 0.93968 0.9396 1 1. 058 4 1. 058 6 1 1. 254 5 1. 254 5 1 1132 160 1.2981 1.2981 1 1131 160 1 .55 55 1 .55 50 (1 S)7p 2 P 0 1 3/2 → (1 S)6d 2 D 160 160,924 160,1102 5/ 2 3.2.3 .5 Group IIIA Lasers Table 3.2 .5 Boron Wavelength ( m) 0.3 451 29 Measured . ±0.000030 1 ( 2 D 5/ 2 )4f 3 D 0 3 → ( 2 D 5/ 2 )4d 3 D 3 1076,1087 1174 0 .50 5177 0 .50 5210 ±0.000030 1 ( 2 D 5/ 2 )4f 3 G 0 5 → ( 2 D 5/ 2 )4d 3 F 4 1076,1087 1174 0 .50 6062 0 .50 6 050 ±0.000030 1. ( 2 D 5/ 2 )5s 3 D 3 1076,1087 806 0.828317 0.828321 1 ( 2 D 5/ 2 )6s 3 D 3 → ( 2 D 5/ 2 )5p 3 D 0 3 1076,1087 9 35 0. 851 108 0. 851 104 1 ( 2 D 5/ 2 )6s 3 D 2 → ( 2 D 5/ 2 )5p 3 D 0 2 1076,1087 9 35 1.771. 806 1.3 753 8 1.3 759 00 ±0.000200 1 ( 2 D 5/ 2 )6p 3 P 0 1 → ( 2 D 5/ 2 )5d 3 S 1 1076,1087 806 1 .59 759 1 .59 8200 ±0.000200 1 ( 2 D 5/ 2 )6p 3 D 0 3 → ( 2 D 5/ 2 )5d 3 P 2 1076,1087 806 1.6 459 3 1.646400

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