©2001 CRC Press LLC C 2 D 2 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 17.45 573.1 Hot Band ?R(23)? 1755 17.498 571050 (ν 4 +ν 5 )\Σ + u → ν 4 Band R(22) 1747 17.56 569.6 (ν 4 +ν 5 )\Σ + u → ν 4 Band R(21) 1747 17.61 567.8 (ν 4 +ν 5 )\Σ + u → ν 4 Band R(16) 1753 17.610 567.87 (ν 4 +ν 5 )\Σ + u → ν 4 Band R(20) 1747 17.665 566.08 (ν 4 +ν 5 )\Σ + u → ν 4 Band R(19) 1747 17.722 564.28 (ν 4 +ν 5 )Σ + u → ν 4 Band R(18) 1747 17.778 562.48 (ν 4 +ν 5 )Σ + u → ν 4 Band R(17) 1747,1748 17.835 560.68 (ν 4 +ν 5 )Σ + u → ν 4 Band R(16) 1747 18.67 535.7 Hot Band ?Q(24)? 1756 18.79 532.2 (2ν 5 +ν 4 )π g → (ν 5 +ν 4 )Σ u Band Q? 1758 18.79 532.3 (ν 4 +ν 5 )Σ + u → ν 4 Band ? 1747 18.84 530.7 (ν 4 +ν 5 )Σ + u → ν 4 Band ? 1747 18.85 530.6 (ν 4 +ν 5 )Σ + u → ν 4 Band Q(1) 1749 18.960 527.43 (ν 4 +ν 5 )Σ + u → ν 4 Band P(2) 1747,1750 18.97 527.1 (2ν 5 +ν 4 )π u → 2ν 4 Σ g Band Q? 1762 19.03 525.6 (2ν 5 +ν 4 )π g → (ν 5 +ν 4 )∆ u Band Q? 1760 19.03 525.6 (2ν 5 +ν 4 )π g → (ν 5 +ν 4 )Σ u Band P(4) 1759 19.03 525.6 (ν 4 +ν 5 )Σ + u → ν 4 Band P(3) 1747 19.081 524.07 (ν 4 +ν 5 )Σ + u → ν 4 Band P(4) 1747 19.13 522.7 (2ν 5 +ν 4 )π u → 2ν 4 \Σ_g Band P(3) 1763 19.20 520.7 (ν 4 +ν 5 )Σ + u → ν 4 Band P(6) 1751 19.27 518.9 (2ν 5 +ν 4 )π g → (ν 5 +ν 4 )∆ u Band P(4) 1761 19.67 508.4 (ν 4 +ν 5 )∆ u → ν 4 Band P(18) 1754 19.947 501.33 (ν 4 +ν 5 )Σ + u → ν 4 Band P(18) 1747 20.010 499.75 (ν 4 +ν 5 )Σ + u → ν 4 Band P(19) 1747,1752 20.073 498.17 (ν 4 +ν 5 )Σ + u → ν 4 Band P(20) 1747 20.13 496.8 (ν 4 +ν 5 )Σ + u → ν 4 Band P(21) 1747 20.202 495.00 (ν 4 +ν 5 )Σ + u → ν 4 Band P(22) 1747 20.267 493.41 (ν 4 +ν 5 )Σ + u → ν 4 Band P(23) 1747 20.332 491.83 (ν 4 +ν 5 )Σ + u → ν 4 Band P(24) 1747 20.44 489.2 Hot Band ?P(25)? 1757 ©2001 CRC Press LLC 12 C 2 D 2 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 17.893 558.87 (ν 4 +ν -5 )Σ + u → ν 4 Band R(15) 6870 18.84 530.8 (ν 4 +ν -5 )Σ + u → ν 4 Band Q(?) 6870 19.511 512.84 (ν 4 +ν -5 )Σ + u → ν 4 Band P(11) 6870 19.634 509.32 (ν 4 +ν -5 )Σ + u → ν 4 Band P(13) 6870 19.758 506.12 (ν 4 +ν -5 )Σ + u u → ν 4 Band P(15) 6870 19.884 502.93 (ν 4 +ν -5 )Σ + u u → ν 4 Band P(17) 6870 12 C 2 DH Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 17.71 564.8 (2ν 4 )Σ + → ν 4 Band R(23) 6854,6855 18.09 552.8 HotbandsR(?) 6854,6863 18.45 542.1 (2ν 4 )Σ + → ν 4 Band R(12) 6854,6856 18.64 536.5 Hotbands R(10) 6854,6864 19.13 522.7 Hotbands Q(?) 6854,6865 19.18 521.4 2ν 4 (∆ c ) → ν 4 Band Q(22) 6854,6862 19.33 517.4 Hotbands Q(?) 6854,6866 19.37 516.2 Hotbands? 6854,6867 19.4 515.5 (2ν 4 )Σ + → ν 4 Band Q(13) 6854,6858 19.4 515.4 (2ν 4 )Σ + → ν 4 Band Q(9) 6854,6857 19.48 513.4 Hotbands Q(11) 6854,6868 20.15 496.2 (2ν 4 )Σ + → ν 4 Band P(10) 6854,6859 20.38 490.7 Hotbands P(12) 6854,6869 20.47 488.5 (2ν 4 )Σ + → ν 4 Band P(14) 6854,6860 21.38 467.8 (2ν 4 )Σ + → ν 4 Band P(25) 6854,6861 C 2 H 2 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 8.03406 1244.70 ν 2 → ν 1 5 Band Q(5)? 1744,1746 8.03523 1244.52 ν 2 → ν 1 5 Band Q(7)? 1745,1746 8.03561 1244.46 ν 2 → ν 1 5 Band Q? 1744 8.03781 1244.12 ν 2 → ν 1 5 Band ? 1745 8.03800 1244.09 ν 2 → ν 1 5 Band Q? 1744 8.04020 1243.75 ν 2 → ν 1 5 Band Q(11) 1745,1746 8.04091 1243.64 ν 2 → ν 1 5 Band Q? 1744 ©2001 CRC Press LLC C 2 H 2 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 8.04428 1243.12 ν 2 → ν 1 5 BandQ(13) 1744,1746 8.04453 1243.08 ν 2 → ν 1 5 Band Q? 1745 8.197 1220 ν 2 → ν 1 5 Band P(10) 1746 8.299 1205 ν 2 → ν 1 5 Band P(16) 1746 COF 2 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ~10 ~1000 0200 → 0100 Band ? 1764,1765 14 NH 3 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 6.270 1595 ν 4 → 0 Band 6871 6.689 1495 ν 4 → 0 Band 6871 9.346 1070 ν 2 → 0 Band aR(6,K) 1766,1790 9.643 1037 ν 2 → 0 Band aR(4,K) or sR(3,K) 1766,1790 9.737 1027 ν 2 → 0 Band aR(3,1), aR(2,2), aR(2,1), aR(4,4), or aR(4,3) 1766,1790 9.921 1008 ν 2 → 0 Band aR(2,0), sR(1,1), sR(1,0), aR(3,3), or aR(3,2) 1766,1790 10.29016 971.882 ν 2 → 0 Band aR(1,1) 1766,1790 10.3376 967.346 ν 2 → 0 Band sQ(3,3) 6873 10.3423 966.905 ν 2 → 0 Band sQ(4,3) 6873 10.3589 965.354 ν 2 → 0 Band sQ(6,6) 6873 10.3670 964.596 ν 2 → 0 Band sQ(7,6) 6873 10.5067 951.776 ν 2 → 0 Band aR(0,0) 6873 10.5459 948.232 ν 2 → 0 Band sP(1,0) 6873 10.54594 948.232 ν 2 → 0 Band sP(1,0) 1766,1790 10.6 941 ν 2 → 0 Band aQ(9,3), aQ(10,4), aQ(9,2), aQ(10,3), or aQ(9,1) 1766,1790 14 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ©2001 CRC Press LLC 10.7 931 ν 2 → 0 Band aQ(8,6), aQ(9,7), aQ(6,5), aQ(3,3), aQ(5,4), aQ(5,5), Q(7,6), aQ(4,4) or aQ(2,2) 1766,1790 10.7182 932.992 ν 2 → 0 Band aQ(5,3) 6873 10.7322 931.774 ν 2 → 0 Band aQ(4,3) 6873 10.73729 931.334 ν 2 → 0 Band aQ(2,2) 1767,1790 10.74394 930.757 ν 2 → 0 Band aQ(3,3) 1767,1790 10.75387 929.898 ν 2 → 0 Band aQ(4,4) 1767,1790 10.7624 929.162 ν 2 → 0 Band aQ(7,6) 6873 10.76710 928.755 ν 2 → 0 Band aQ(5,5) 1767,1790 10.7837 927.323 ν 2 → 0 Band aQ(6,6) 6873,6874 10.8548 921.255 ν 2 → 0 Band aQ(9,9) 6873 11.01 908 ν 2 → 0 Band sP(3,1 or 2) 1769 11.01080 892.157 ν 2 → 0 Band sP(3,0) 1767,1790 11.0111 908.177 ν 2 → 0 Band sP(3,1) 6873 11.20879 892.157 ν 2 → 0 Band aP(2,0) 1767,1770,1790 11.2123 891.882 ν 2 → 0 Band aP(2,1) 6873 11.2603 888.079 ν 2 → 0 Band sP(4,1) 6873 11.261 887.99 ν 2 → 0 Band sP(4,1-2) 1770,1771,1790 11.2628 887.877 ν 2 → 0 Band sP(4,3) 6873 11.46044 872.567 ν 2 → 0 Band aP(3,1) 1766,1767,1770, 1771,1773,1790 11.47135 871.737 ν 2 → 0 Band aP(3,2) 1770 11.52074 868.000 ν 2 → 0 Band sP(5,0) 1766,1767,1770, 1771,1774,1790 11.5212 868.035 ν 2 → 0 Band sP(5,1) 6873 11.52446 867.719 ν 2 → 0 Band sP(5,3) 1790–1792 11.55466 865.452 2ν 2 → ν 2 Band sP(4,1) 1783 11.71208 853.819 ν 2 → 0 Band aP(4,0) 1767,1770–1,1790 11.71582 853.547 ν 2 → 0 Band aP(4,1) 1766–7,1771,1790 11.72712 852.724 ν 2 → 0 Band aP(4,2) 1767,1770,1790 11.74637 851.327 ν 2 → 0 Band aP(4,3) 1767,1770,1790 11.7942 847.876 ν 2 → 0 Band sP(6,1) 6873 11.796 847.78 ν 2 → 0 Band sP(6,1-2) 1770 11.7983 847.578 ν 2 → 0 Band sP(6,3) 6873,6874 11.80167 847.338 ν 2 → 0 Band sP(6,4) 1770,1774 11.97859 834.823 ν 2 → 0 Band aP(5,1) 1766,1767,1770, 1771,1790 14 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ©2001 CRC Press LLC 11.99025 834.011 ν 2 → 0 Band aP(5,2) 1766,1767,1770, 1771,1790 12.01008 832.634 ν 2 → 0 Band aP(5,3) 1766,1767,1770, 1771,1777,1790 12.03872 830.653 ν 2 → 0 Band aP(5,4) 1767,1770–1,1790 12.07912 827.875 ν 2 → 0 Band sP(7,0) 1766,1767,1770, 1771,1774,1778, 1779,1790,1792 12.0797 827.833 ν 2 → 0 Band s P(7,1) 6873 12.0997 826.470 ν 2 → 0 Band s P(7,6) 6873 12.11418 825.479 2ν 2 → ν 2 Band sP(6,4) 1784 12.15575 822.656 2ν 2 → ν 2 Band sP(6,3) 1785 12.18444 820.719 2ν 2 → ν 2 Band sP(6,2) 1786 12.24521 816.646 ν 2 → 0 Band aP(6,0) 1766–7,1770,1771, 1774,1779,1790 12.24911 816.386 ν 2 → 0 Band aP(6,1) 1766,1767,1770, 1771,1790 12.26105 815.591 ν 2 → 0 Band aP(6,2) 1766,1767,1770, 1771,1790 12.28136 814.242 ν 2 → 0 Band aP(6,3) 1766,1767,1770, 1771,1783,1790 12.31072 812.300 ν 2 → 0 Band aP(6,4) 1766,1767,1770, 1771,1790 12.35002 809.715 ν 2 → 0 Band aP(6,5) 1766,1767,1770, 1771,1790 12.37821 807.871 ν 2 → 0 Band sP(8,1) 1770 12.38425 807.477 ν 2 → 0 Band sP(8,3) 1770 12.39560 806.738 ν 2 → 0 Band sP(8,5) 1770 12.4027 806.274 ν 2 → 0 Band sP(8,6) 6873 12.52781 798.224 ν 2 → 0 Band aP(7,1) 1766,1767,1770, 1771,1790–92 12.53999 797.449 ν 2 → 0 Band aP(7,2) 1766,1767,1770, 1771,1790,1792 12.56068 796.135 ν 2 → 0 Band aP(7,3) 1766,1767,1770, 1771,1790,1792 12.59 794.3 2ν 2 →ν 2 Band aR(7,5) 6875 12.59059 794.244 ν 2 → 0 Band aP(7,4) 1766,1767,1770, 1771,1790,1792 12.63063 791.720 ν 2 → 0 Band aP(7,5) 1766,1767,1770, 1771,1790,1792 14 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ©2001 CRC Press LLC 12.68213 788.511 ν 2 → 0 Band aP(7,6) 1766,1767,1770, 1771,1790 12.69716 787.578 ν 2 → 0 Band sP(9,3) 1770 12.7196 786.191 ν 2 → 0 Band sP(9,6) 6873 12.80959 780,665 2ν 2 → ν 2 Band sP(8,5) 1787 12.81145 780.552 ν 2 → 0 Band aP(8,0) 1766,1767,1770, 1771,1781,1784, 1790,1792 12.81532 780.316 ν 2 → 0 Band aP(8,1) 1766,1767,1770, 1771,1790 12.82765 779.566 ν 2 → 0 Band aP(8,2) 1767,1770,1790, 1792 12.84863 778.293 ν 2 → 0 Band aP(8,3) 1766,1767,1770, 1771,1790,1792 12.87890 776.464 ν 2 → 0 Band aP(8,4) 1766,1767,1770, 1771,1790,1792 12.91946 774.026 ν 2 → 0 Band aP(8,5) 1766,1767,1770, 1771,1790,1792 12.97163 770.913 ν 2 → 0 Band aP(8,6) 1766,1767,1770, 1771,1790,1792 12.98352 770.207 2ν 2 → ν 2 Band aR(6,5) 1787 13.0241 767.809 ν 2 → 0 Band sP(10,3) 6873 13.03715 767.039 ν 2 → 0 Band aP(8,7) 1766–67,1790 13.0505 766.252 ν 2 → 0 Band sP(10,6) 6873 13.11233 762.641 ν 2 → 0 Band aP(9,1) 1766,1790 13.12477 761.918 ν 2 → 0 Band aP(9,2) 1766,1790 13.14593 760.692 ν 2 → 0 Band aP(9,3) 1766–67,1790 13.17643 758.931 ν 2 → 0 Band aP(9,4) 1766,1790 13.21725 756.587 ν 2 → 0 Band aP(9,5) 1766,1790 13.23390 755.635 2ν 2 → ν 2 Band aR(5,3) 1777 13.26978 753.592 ν 2 → 0 Band aP(9,6) 1766–67,1790 13.33580 749.861 ν 2 → 0 Band aP(9,7) 1766,1790 13.411 745.7 ν 2 → 0 Band aP(9,8), aP(10,1), or aP(10,0) 1766,1790 13.4153 745.420 ν 2 → 0 Band aP(10,0) 6873 13.4534 780.665 ν 2 → 0 Band aP(10,3) 6873 13.57749 736.513 ν 2 → 0 Band aP(10,6) 1766,1790 13.65533 732.315 2ν 2 → ν 2 Band aR(4,3) 1777 13.72555 728.568 2ν 2 → ν 2 Band aR(4,4) 1784 13.82608 723.271 ν 2 → 0 Band aP(10,9) 1766,1790 14 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ©2001 CRC Press LLC 14.78 677 2ν 2 → ν 2 Band 1788 15.04 665 2ν 2 → ν 2 Band 1788 15.08 663 2ν 2 → ν 2 Band 1788 15.41 649 2ν 2 → ν 2 Band 1788 15.47 646 2ν 2 → ν 2 Band 1788 15.68 637.8 2ν 2 → ν 2 Band aQ(6,3) 6876 15.70 636.9 2ν 2 → ν 2 Band aQ(8,5) 6875 15.78148 633.654 2ν 2 → ν 2 Band aQ(5,3) 1777 15.81600 632.271 2ν 2 → ν 2 Band aQ(7,5) 1787 15.85726 630.626 2ν 2 → ν 2 Band aQ(4,3) 1777 15.87758 629.819 2ν 2 → ν 2 Band aQ(5,4) 1777 15.91292 628.420 2ν 2 → ν 2 Band aQ(6,5) 1787 15.913 628.40 2ν 2 → ν 2 Band aQ(3,3) 6877 15.94637 627.102 2ν 2 → ν 2 Band aQ(4,4) 1784 16.04 623.4 2ν 2 → ν 2 Band ? 6878 16.936 590.45 2ν 2 → ν 2 Band aP(2,0) 6877 16.95 590.0 2ν 2 → ν 2 Band aP(2,1) 6879 18.046 554.14 2ν 2 → ν 2 Band aP(4,0) 6877 18.203 549.37 2ν 2 → ν 2 Band aP(4,3) 6877 18.21 549 2ν 2 → ν 2 Band 1788 18.798 531.97 2ν 2 → ν 2 Band aP(5,3) 6876,6877 18.92674 528.353 2ν 2 → ν 2 Band aP(5,4) 1784 19.198 520.89 2ν 2 → ν 2 Band aP(6,0) 6952 19.29 518.4 2ν 2 → ν 2 Band aP(6,2) 6880 19.401 515.43 2ν 2 → ν 2 Band aP(6,3) 6876,6877 19.55019 511.504 2ν 2 → ν 2 Band aP(6,4) 1784 20.008 499.80 2ν 2 → ν 2 Band aP(7,3) 6876,6877 20.358 491.20 2ν 2 → ν 2 Band aP(8,0) 6877 20.38798 490.485 2ν 2 → ν 2 Band aP(7,5) 1787 20.48 488.3 2ν 2 → ν 2 Band aP(8,2) 6881 20.604 485.34 2ν 2 → ν 2 Band aP(7,6) 6877 20.622 484.92 2ν 2 → ν 2 Band aP(8,3) 6877 21.05409 474.967 2ν 2 → ν 2 Band aP(8,5) 1787 21.228 471.08 2ν 2 → ν 2 Band aP(9,3) 6952 21.333 468.75 2ν 2 → ν 2 Band aP(8,6) 6877 21.471 465.74 3ν 2 → 2ν 2 Band aP(2,0)? 1789 22.542 443.62 3ν 2 → 2ν 2 Band aP(3,2) 1789 22.563 443.20 3ν 2 → 2ν 2 Band aP(3,1) 1789 22.71 440 3ν 2 → 2ν 2 Band 1788 23.675 422.39 3ν 2 → 2ν 2 Band aP(4, or 1) 1789 14 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments ©2001 CRC Press LLC 23.86 419 3ν 2 → 2ν 2 Band 1788 24.918 401.32 3ν 2 → 2ν 2 Band aP(5,1) 1789 25.12 398 3ν 2 → 2ν 2 Band 1788 26.282 380.49 3ν 2 → 2ν 2 Band aP(6,0) 1789 30.69 326 3ν 2 → 2ν 2 Band 1788 31.47 318 3ν 2 → 2ν 2 Band 1788 31.951 312.98 3ν 2 → 2ν 2 Band 1789 32.13 311 3ν 2 → 2ν 2 Band 1788 15 NH 3 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 10.789 926.8 ν 2 → 0 Band aQ(3,3) 6882 10.829 923.45 ν 2 → 0 Band aQ(6,6) 6953 11.072 903.15 ν 2 → 0 Band sP(3,0) 6953 11.257 888.32 ν 2 → 0 Band aP(2,0) 6882 11.586 863.12 ν 2 → 0 Band sP(5,0) 6882,6883 11.763 850.11 ν 2 → 0 Band aP(4,0) 6882,6883 11.798 847.60 ν 2 → 0 Band aP(4,3) 6882 11.859 843.25 ν 2 → 0 Band sP(6,1) 6883 11.866 842.75 ν 2 → 0 Band aP(6,3) 6882 12.063 828.98 ν 2 → 0 Band aP(5,3) 6882,6883 12.148 823.21 ν 2 → 0 Band sP(7,0) 6882,6883 12.299 813.08 ν 2 → 0 Band aP(6,0) 6882,6883 12.336 810.66 ν 2 → 0 Band aP(6,3) 6882,6883 12.447 803.40 ν 2 → 0 Band sP(8,1) 6883 12.616 792.64 ν 2 → 0 Band aP(7,3) 6882,6883 12.739 785.00 ν 2 → 0 Band aP(7,6) 6882,6883 12.867 777.18 ν 2 → 0 Band aP(8,0) 6882,6883 12.905 774.88 ν 2 → 0 Band aP(8,3) 6882,6883 12.967 771.16 ν 2 → 0 aP(8,0) 6953 12.977 770.60 ν 2 → 0 Band aP(8,5) 6884 13.030 767.47 ν 2 → 0 Band aP(8,6) 6882,6883 13.204 757.37 ν 2 → 0 Band aP(9,3) 6882,6883 13.323 750.60 ν 2 → 0 Band aP(9,6) 6883 13.473 742.20 ν 2 → 0 Band aP(10,0) 6883 13.910 718.92 2ν 2 → ν 2 Band sP(10,1) 6885 14.3 699 1793 ©2001 CRC Press LLC 15 NH 3 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 14.8 676 1793 15.2 658 1793 15.7 637 1793 16.0 625 1793 17.8 562 1793 3.3.2.5 Five-Atom Vibrational Transition Lasers Table 3.3.2.4 Five-Atom Vibrational Transition Lasers 12 CF 4 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 15.306 653.32 ν 2 +ν 4 → ν 2 Band R(41) 1794–95,1804 15.40 649.3 ν 2 +ν 4 → ν 2 Band R(33) 1794,1795 15.46 647.0 ν 2 +ν 4 → ν 2 Band – 1797,1815 15.48 646.0 ν 2 +ν 4 → ν 2 Band R(27) 1794–1799,1807 15.49 645.5 ν 2 +ν 4 → ν 2 Band R(26) 1800,1808 15.547 643.23 ν 2 +ν 4 → ν 2 Band R(22) 1797–1801,1809 15.57 642.4 ν 2 +ν 4 → ν 2 Band R(21) 1794–96,1810 15.58 641.9 ν 2 +ν 4 → ν 2 Band R(20) 1799,1811 15.60 640.9 ν 2 +ν 4 → ν 2 Band R(18) 1799,1812 15.607 640.73 ν 2 +ν 4 → ν 2 Band R(17) 1797–9,1801,1813 15.71 636.7 ν 2 +ν 4 → ν 2 Band 1797,1816 15.71 636.6 ν 2 +ν 4 → ν 2 Band R(9) 1797–99,1814 15.74 635.2 ν 2 +ν 4 → ν 2 Band R(7) 1800,1817 15.83 631.8 ν 2 +ν 4 → ν 2 Band Q(7)? 1799,1818 15.84 631.5 ν 2 +ν 4 → ν 2 Band Q(14) 1795,182 15.84 631.3 ν 2 +ν 4 → ν 2 Band Q(28) 1799,1819 15.844 631.15 ν 2 +ν 4 → ν 2 Band Q(36) 1799,1801,1821 15.845 631.12 ν 2 +ν 4 → ν 2 Band Q(31) 1794,1822 15.847 631.05 ν 2 +ν 4 → ν 2 Band Q(29) 1799,1801,1823 15.85 631.0 ν 2 +ν 4 → ν 2 Band 1795,1826 15.85 630.8 ν 2 +ν 4 → ν 2 Band Q(11) 1800,1824 15.85 630.8 ν 2 +ν 4 → ν 2 Band Q(35) 1795,1825 ©2001 CRC Press LLC 12 CF 4 Laser—continued Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 15.85 630.8 ν 2 +ν 4 → ν 2 Band Q(37) 1799,1827 15.91 628.5 ν 2 +ν 4 → ν 2 Band P(5) 1800,1828 15.92 628.2 ν 2 +ν 4 → ν 2 Band P(6) 1800,1829 15.94 627.3 ν 2 +ν 4 → ν 2 Band P(8) 1800,1830 16.00 624.9 ν 2 +ν 4 → ν 2 Band P(12) 1800,1831 16.02 624.4 ν 2 +ν 4 → ν 2 Band P(14) 1796,1832 16.06 622.8 ν 2 +ν 4 → ν 2 Band P(16) 1800,1833 16.07 622.4 ν 2 +ν 4 → ν 2 Band P(17) 1800,1834 16.07 622.4 ν 2 +ν 4 → ν 2 Band P(18) 1796,1835 16.09 621.4 ν 2 +ν 4 → ν 2 Band P(19) 1800,1836 16.11 620.6 ν 2 +ν 4 → ν 2 Band P(21) 1795,1796,1837 16.178 618.11 ν 2 +ν 4 → ν 2 Band P(25) 1797–9,1801,1838 16.21 617.0 ν 2 +ν 4 → ν 2 Band P(27) 1795,1839 16.24 615.7 ν 2 +ν 4 → ν 2 Band P(30) 1799,1840 16.25 615.4 ν 2 +ν 4 → ν 2 Band P(30)? 1800,1841 16.259 615.06 ν 2 +ν 4 → ν 2 Band P(31) 1797– 99,1801,1802 16.27 614.7 ν 2 +ν 4 → ν 2 Band P(32)? 1799,1842 16.29 613.7 ν 2 +ν 4 → ν 2 Band P(35)? 1799,1843 16.340 611.99 ν 2 +ν 4 → ν 2 Band P(37) 1797–9,1801,1844 16.40 609.6 ν 2 +ν 4 → ν 2 Band P(42) 1795,1845 13 CF 4 Laser Wavelength ( m) vac Frequency (cm -1 ) Transition assignment Comments 15.29 654.2 ν 2 +ν 4 → ν 2 Band R 1846,1852 15.32 652.9 ν 2 +ν 4 → ν 2 Band R 1846,1853 15.42 648.4 ν 2 +ν 4 → ν 2 Band R 1846,1854 15.44 647.8 ν 2 +ν 4 → ν 2 Band R 1846,1855 15.45 647.1 ν 2 +ν 4 → ν 2 Band R 1847,1856 15.47 646.6 ν 2 +ν 4 → ν 2 Band R 1846,1857 15.53 644.0 ν 2 +ν 4 → ν 2 Band R 1848,1858 15.54 643.3 ν 2 +ν 4 → ν 2 Band R 1847,1848,1859 15.59 641.3 ν 2 +ν 4 → ν 2 Band R 1846,1860 15.62 640.4 ν 2 +ν 4 → ν 2 Band R 1846,1861 15.62 640.3 ν 2 +ν 4 → ν 2 Band R 1848,1862 15.74 635.5 ν 2 +ν 4 → ν 2 Band R 1849,1863 15.75 635.0 ν 2 +ν 4 → ν 2 Band R 1850,1864 [...]... Comments 6 971 ,71 74 5483,5484,5485 5480,5481,5482 5 477 ,5 478 ,5 479 6 970 ,71 79 5 474 ,5 475 ,5 476 5 471 ,5 472 ,5 473 5468,5469,5 470 5465,5466,54 67 6 970 ,70 12 6 970 ,70 11 6 971 ,71 77 5459,5460,5461 5462,5463,5464 5456,54 57, 5458 5453,5454,5455 5450,5451,5452 6 971 ,71 77 6 970 ,71 77 6 971 ,70 17 54 47, 5448,5449 5441,5442,5443 5444,5445,5446 6 971 ,71 78 6 970 ,70 09 5438,5439,5440 6 970 ,70 14 5435,5436,54 37 5432,5433,5434 5426,54 27, 5428 5429,5430,5431... 2 37. 71 239.18 239.30 239. 47 239.55 239.99 240.33 245.95 246.01 246.80 246.89 2 47. 22 2 47. 29 2 47. 3 2 47. 5 2 47. 53 2 47. 59 2 47. 71 2 47. 90 254.20 255.69 255 .76 256.09 256.41 256.68 263.51 264.69 264 .76 Uncertainty ( m) ±0.49 ±0.50 ©2001 CRC Press LLC Comments 72 42 72 42 72 42 72 42 72 42 72 41 72 13 72 15 72 41 72 41 72 41 72 41 72 41 72 41 72 41 72 15 72 40 72 40 72 40 72 40 72 40 72 40 72 13 72 14 72 39 72 39 72 39 72 39 2669–2 672 ... 1 671 1 671 1 671 1668 1668 1 671 1 671 1 671 1 671 1 671 1 671 1 671 1 671 1668 1 671 1 671 1 671 1 671 1 671 1 671 1 671 1668 Table 3.4 .7 Dideuterodichloromethane – CD 2 Cl 2 Wavelength ( m) 171 .2 246.1 249 254 2 87. 6 2 87. 9 292.5 310.3 328.2 331.4 340.9 342 348.1 3 67. 5 Uncertainty ( m) ±1.2 ±1.2 ±1 .7 ©2001 CRC Press LLC Comments 6 971 ,70 99 6 971 ,70 96 3815–38 17 3812–3814 6 971 ,70 84 6 971 ,70 97 6 971 ,70 88 6 971 ,70 99 6 971 ,70 89... 2641–2644 72 28 72 08 72 27 72 27 72 27 72 07 7226 72 26 72 06 72 25 72 25 72 25 72 05 72 24 72 04 72 23 72 01 72 03 72 00 72 02 72 02 71 99 72 01 72 00 71 98 71 99 72 51 71 98 71 97 26 37 2640 2633–2636 References 1 472 ,1485 1821 1 472 ,1485 1821 1821 1821 1821 1821 1 472 ,1485 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1 472 ,1485 1 472 ,1485... 2685–2688 72 50 72 39 72 22 72 48 72 47 7221 72 47 72 47 7218 72 20 2681–2684 72 46 2 677 –2680 72 19 2 673 –2 676 72 45 72 45 72 18 72 44 72 16 72 18 72 17 7243 72 43 72 43 72 43 72 43 72 43 72 43 72 16 References 1 472 ,1485 1 472 ,1485 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1 472 ,1485 1821 1 472 ,1485 1821 1 472 ,1485 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 1821 Trideuterofluoromethane – CD 3 F—continued... 272 .93 274 .58 274 .65 275 .03 275 .33 283. 37 284 .74 285.06 285.14 285.23 285.31 285. 47 285 .71 285.80 286.29 296.21 296.38 296. 47 296 .73 308.26 308.54 308 .73 308.83 308.92 309.21 309.31 309.59 322.16 322.26 322. 37 323.3 336.02 336.6 336.69 336.81 3 37. 26 3 37. 38 Uncertainty ( m) ±5.0 ±0.45 ±0.44 ©2001 CRC Press LLC Comments 72 37 72 37 2661–2664 72 37 72 37 72 37 7210 72 36 72 36 72 36 72 36 72 09 72 35 72 35 72 35 72 35 72 35... 554 .7 574 .6 1388 1800 1388 1800 1800 1800 10P12 13 CO laser 2 13 CO laser 2 13 CO laser 2 Table 3.4.16 Deuterooxytrideuteromethanol – CD 3 OD(a) Wavelength ( m) 38.1 43.6 97 45.362 62.2 76 .6 77 .2 79 .2 57 80.1 81.5 571 01 86.4 100.0 Uncertainty ( m) ±4.1e-05 ±0.42 ©2001 CRC Press LLC Comments 6 971 ,70 07 6 970 ,71 83 6 971 ,71 82 6 970 ,71 75 6 971 ,70 13 6 970 ,71 73 6 971 ,71 82 6 971 ,71 73 5561,5562,5563 5558,5559,5560 6 971 ,71 73... 6 971 ,70 95 6 971 ,70 98 3809–3811 6 971 ,70 86 6 971 ,70 93 References 1840 1840 1 478 1 478 1840 1840 1840 1840 1840 1840 1840 1 478 1840 1840 Table 3.4 .7 Dideuterodichloromethane – CD 2 Cl 2 —continued Wavelength ( m) 380.8 396 .7 398.4 410.2 4 17. 6 4 37. 4 451.3 469 504.8 520 559.3 618.3 628.4 631 681.8 72 6.8 77 2.6 829 Uncertainty ( m) ±2.3 ±2.5 ±3.1 ±4.1 Comments 6 971 ,70 93 6 971 ,70 87 6 971 ,70 87 6 971 ,70 92 6 971 ,70 89... 6 971 ,70 87 6 971 ,70 92 6 971 ,70 89 6 971 ,70 97 6 971 ,70 91 3806–3808 6 971 ,70 83 3803–3805 6 971 ,70 94 6 971 ,70 99 6 971 ,70 90 3800–3802 6 971 ,70 98 6 971 ,70 85 6 971 ,70 91 379 7– 379 9 References 1840 1840 1840 1840 1840 1840 1840 1 478 1840 1 478 1840 1840 1840 1 478 1840 1840 1840 1 478 Table 3.4.8 Dideuterodifluoromethane – CD 2 F 2 Wavelength ( m) Uncertainty ( m) 192.0 2 07. 835 218.2 67 303.8 320.5 97 456.2 ©2001 CRC Press LLC CO... LLC Transition assignment Comments 1 970 ,1 971 SiF 4 Laser Wavelength ( m) vac Frequency (cm -1) Transition assignment Comments 24 .78 403.5 1 972 ,1 973 25.31 395.1 1 972 ,1 974 25.36 394.3 1 972 ,1 975 25.40 393 .7 1 972 ,1 976 25. 67 389.5 1 972 ,1 977 25. 67 389.5 1 972 ,1 978 25.68 389.4 1 972 ,1 979 25 .77 388.0 1 972 ,1980 25 .79 3 87. 7 1 972 ,1981 26.01 384.4 1 972 ,1982 26.14 382.5 1 972 ,1983 SiH 4 Laser Wavelength ( m) vac Frequency . aP(8,3) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 12. 878 90 77 6.464 ν 2 → 0 Band aP(8,4) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 12.91946 77 4.026 ν 2 → 0 Band aP(8,5) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 12. 971 63 77 0.913 ν 2 . aP (7, 3) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 12.59 79 4.3 2ν 2 →ν 2 Band aR (7, 5) 6 875 12.59059 79 4.244 ν 2 → 0 Band aP (7, 4) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 12.63063 79 1 .72 0 ν 2 → 0 Band aP (7, 5) 176 6, 176 7, 177 0, 177 1, 179 0, 179 2 14 NH 3 . 176 7, 177 0–1, 179 0 11 .71 582 853.5 47 ν 2 → 0 Band aP(4,1) 176 6 7, 177 1, 179 0 11 .72 712 852 .72 4 ν 2 → 0 Band aP(4,2) 176 7, 177 0, 179 0 11 .74 6 37 851.3 27 ν 2 → 0 Band aP(4,3) 176 7, 177 0, 179 0 11 .79 42 8 47. 876