Materials Science and Engineering Handbook Part 3 doc

Shackelford & Alexander Thermodynamic and Kinetic Data 237 TaSi 2 2670 TaS 4 >1575 TeBr 2 612 TeCl 2 448 TeO 2 1006 ThB 4 >2270 ThBr 4 883 ThC 2898 ThCl 4 1043 ThF 4 1375 ThN 2903 ThO 2 3493 ThS 2 2198 TiB 2 3253 TiBr 4 312 TiC 3433 TiCl 4 250 TiF 3 1475 TiI 2 873 TiN 3200 TiO 2 2113 TiSi 2 1813 UB 2 >1770 UBr 4 789 Table 72. MELTING POINTS OF CERAMICS (SHEET 9 OF 11) Compound (K) Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol. 1, CRC Press, Boca Raton, 1974, 348. 6.3 Thermodynamics Page 237 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 238 UC 2863 UCl 4 843 UF 4 1233 UI 4 779 UN 3123 UO 2 3151 USi 2 1970 US 2 >1375 VB 2 2373 VC 3600 VCl 4 245 VF 3 >1075 FI 2 1048 VN 2593 V 2 O 5 947 VSi 2 2023 V 2 S 3 >875 WB 3133 WC 2900 WCl 6 548 WO 3 1744 WSi 2 2320 WS 2 1523 ZnBr 2 667 ZnCl 2 548 ZnF 2 1145 ZnI 2 719 ZnO 2248 Table 72. MELTING POINTS OF CERAMICS (SHEET 10 OF 11) Compound (K) Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol. 1, CRC Press, Boca Raton, 1974, 348. 6.3 Thermodynamics Page 238 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 239 ZnSO 4 873 ZrB 2 3313 ZrBr 2 >625 ZrC 3533 ZrCl 2 623 ZrF 4 873 ZrI 4 772 ZrN 3250 ZrO 2 3123 Zr(SO 4 ) 2 683 ZrS 2 1823 Table 72. MELTING POINTS OF CERAMICS (SHEET 11 OF 11) Compound (K) Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol. 1, CRC Press, Boca Raton, 1974, 348. 6.3 Thermodynamics Page 239 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 240 Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 1 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole Actinium 227 Ac 1050±50 (11.0) (3400) Aluminum Al 658.5 94.5 2550 Aluminum bromide Al 2 Br 6 87.4 10.1 5420 Aluminum chloride Al 2 Cl 6 192.4 63.6 19600 Aluminum iodide Al 2 I 6 190.9 9.8 7960 Aluminum oxide Al 2 O 3 2045.0 (256.0) (26000) Antimony Sb 630 39.1 4770 Antimony pentachloride SbCl 5 4.0 8.0 2400 Antimony tribromide SbBr 3 96.8 9.7 3510 Antimony trichloride SbCl 3 73.3 13.3 3030 Antimony trioxide Sb 4 O 6 655.0 (46.3) (26990) Antimony trisulfide Sb 4 S 6 546.0 33.0 11200 Argon Ar 190.2 7.25 290 Arsenic As 816.8 (22.0) (6620) Arsenic pentafluoride AsF 5 80.8 16.5 2800 Arsenic tribromide AsBr 3 30.0 8.9 2810 Arsenic trichloride AsCl 3 –16.0 13.3 2420 Arsenic trifluoride AsF 3 –6.0 18.9 2486 Arsenic trioxide As 4 O 6 312.8 22.2 8000 Barium Ba 725 13.3 1830 For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 240 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 241 Barium bromide BaBr 2 846.8 21.9 6000 Barium chloride BaCl 2 959.8 25.9 5370 Barium fluoride BaF 2 1286.8 17.1 3000 Barium iodide BaI 2 710.8 (17.3) (6800) Barium nitrate Ba(NO 3 ) 2 594.8 (22.6) (5900) Barium oxide BaO 1922.8 93.2 13800 Barium phosphate Ba 3 (PO 4 ) 2 1727 30.9 18600 Barium sulfate BaSO 4 1350 41.6 9700 Beryllium Be 1278 260.0 – Beryllium bromide BeBr 2 487.8 (26.6) (4500) Beryllium chloride BeCl2 404.8 (30) (3000) Beryllium oxide BeO 2550.0 679.7 17000 Bismuth Bi 271 12.0 2505 Bismuth trichloride BiCl 3 223.8 8.2 2600 Bismuth trifluoride BiF 3 726.0 (23.3) (6200) Bismuth trioxide Bi 2 O 3 815.8 14.6 6800 Boron B 2300 (490) (5300) Boron tribromide BBr 3 –48.8 (2.9) (700) Boron trichloride BCl 3 –107.8 (4.3) (500) Boron trifluoride BF 3 –128.0 7.0 480 Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 2 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 241 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 242 Boron trioxide B 2 O 3 448.8 78.9 5500 Bromine Br 2 –7.2 16.1 2580 Bromine pentafluoride BrF 5 –61.4 7.07 1355 Cadmium Cd 320.8 12.9 1460 Cadmium bromide CdBr 2 567.8 (18.4) (5000) Cadmium chloride CdCl 2 567.8 28.8 5300 Cadmium fluoride CdF 2 1110 (35.9) (5400) Cadmium iodide CdI 2 386.8 10.0 3660 Cadmium sulfate CdSO 4 1000 22.9 4790 Calcium Ca 851 55.7 2230 Calcium bromide CaBr 2 729.8 20.9 4180 Calcium carbonate CaCO 3 1282 (126) (12700) Calcium chloride CaCl 2 782 55 6100 Calcium fluoride CaF 2 1382 52.5 4100 Calcium metasilicate CaSiO 3 1512 115.4 13400 Calcium nitrate Ca(NO 3 ) 2 560.8 31.2 5120 Calcium oxide CaO 2707 (218.1) (12240) Calcium sulfate CaSO 4 1297 49.2 6700 Carbon dioxide CO 2 –57.6 43.2 1900 Carbon monoxide CO –205 7.13 199.7 Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 3 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 242 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 243 Cyanogen C 2 N 2 –27.2 39.6 2060 Cyanogen chloride CNCl –5.2 36.4 2240 Cerium Ce 775 27.2 2120 Cesium Cs 28.3 3.7 500 Cesium chloride CsCl 38.5 21.4 3600 Cesium nitrate CsNO 3 406.8 16.6 3250 Chlorine Cl 2 –103±5 22.8 1531 Chromium Cr 1890 62.1 3660 Chromium (II) chloride CrCl 2 814 65.9 7700 Chromium (III) sequioxide Cr 2 O 3 2279 27.6 4200 Chromium trioxide CrO 3 197 37.7 3770 Cobalt Co 1490 62.1 3640 Cobalt (II) chloride CoCl 2 727 56.9 7390 Copper Cu 1083 49.0 3110 Copper (II) chloride CuCl 2 430 24.7 4890 Copper (I) chloride CuCl 429 26.4 2620 Copper(l) cyanide Cu 2 (CN) 2 473 (30.1) (5400) Copper (I) iodide CuI 587 (13.6) (2600) Copper (II) oxide CuO 1446 35.4 2820 Copper (I) oxide Cu 2 O 1230 (93.6) (l3400) Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 4 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 243 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 244 Copper (I) sulfide Cu 2 S 1129 62.3 5500 Dysprosium Dy 1407 25.2 4100 Erbium Er 1496 24.5 4100 Europium Eu 826 16.4 2500 Europium trichloride EuCl 3 622 (20.9) (8000) Fluorine F 2 –219.6 6.4 244.0 Gadolinium Gd 1312 23.8 3700 Gallium Ga 29 19.1 1336 Germanium Ge 959 (114.3) (8300) Gold Au 1063 (15.3) 3030 Hafnium Hf 2214 (34.1) (6000) Holmium Ho 1461 24.8 4100 Hydrogen H 2 –259.25 13.8 28 Hydrogen bromide HBr –86.96 7.1 575.1 Hydrogen chloride HCl –114.3 13.0 476.0 Hydrogen fluoride HF 83.11 54.7 1094 Hydrogen iodide HI –50.91 5.4 686.3 Hydrogen nitrate HNO 3 –47.2 9.5 601 Hydrogen oxide (water) H 2 O 0 79.72 1436 Deuterium oxide D 2 O 3.78 75.8 1516 Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 5 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 244 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 245 Hydrogen peroxide H 2 O 2 –0.7 8.58 2920 Hydrogen selenate H 2 SeO 4 57.8 23.8 3450 Hydrogen sulfate H 2 SO 4 10.4 24.0 2360 Hydrogen sulfide H 2 S –85.6 16.8 5683 Hydrogen sulfide, di– H 2 S 2 –89.7 27.3 1805 Hydrogen telluride H 2 Te –49.0 12.9 1670 Indium In 156.3 6.8 781 lodine I 2 112.9 14.3 3650 lodine chloride (α) ICl 17.1 16.4 2660 lodine chloride (β) ICl 13.8 13.3 2270 Iron Fe 1530.0 63.7 3560 Iron carbide Fe 3 C 1226.8 68.6 12330 Iron (III) chloride Fe 2 Cl 6 303.8 63.2 20500 Iron (II) chloride FeCl 2 677 61.5 7800 Iron (II) oxide FeO 1380 (107.2) (7700) Iron oxide Fe 3 O 4 1596 142.5 33000 Iron pentacarbonyl Fe(CO) 5 –21.2 16.5 3250 Iron (II) sulfide FeS 1195 56.9 5000 Lanthanum La 920 17.4 2400 Lead Pb 327.3 5.9 1224 Table 73. HEAT OF FUSION FOR ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 6 OF 16) Compound Formula Melting point ˚C Heat of fusion cal/g cal/g mole For heat of fusion in J/kg, multiply values in cal/g by 4184. For heat of fusion in J/mol, multiply values in cal/g-mol (=cal/mol) by 4.184. For melting point in K, add 273.15 to values in ˚C. Values in parentheses are of uncertain reliability. Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973) 6.3 Thermodynamics Page 245 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC [...]... Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (19 73) ©2001 CRC Press LLC 252 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics Page 2 53 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic Data Table 73 HEAT OF FUSION... (e.u.) La solid liquid 6.17 (7 .3) 1.60 – – – – – 1.911 (–0.15) 21.9 (26.0) Li solid liquid gas 3. 05 7.0 (4.97) 8.60 – – – – – – – – 1.292 1.509 ( 34 .30 ) 12.92 32 .00 (–2.84) Mg solid liquid gas 5 .33 (8.0) (4.97) 2.45 – – – – – –0.1 03 – – 1. 733 0.942 ( 34 .78) 23. 39 36 .967 (–7.60) Mn solid, α solid, β solid, γ solid, δ liquid gas 6.70 8 .33 10.70 11 .30 3. 38 0.66 – – – – – – –0 .37 – – – 1.974 2.672 4.760 5.176... K, add 2 73. 15 to values in ˚C Values in parentheses are of uncertain reliability Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (19 73) ©2001 CRC Press LLC 250 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics... Phosphoric acid OsO4 O2 Pd H3PO4 Heat of fusion Melting point ˚C cal/g cal/g mole 17 795 11.9 (17 .3) 2500 (2500) 1020 – 248.6 11.8 3. 83 1700 77.4 1452 71.5 4200 1 030 790 142 5 25.8 1 18470 5800 2496 (68.9) (6500) 21.1 1511 30 8 91.0 8400 24200 –1 63. 7 18 .3 549.5 –210 6.15 172 .3 – 13. 2 –90.9 60.2 35 .5 5540 15 63 2700 (36 .7) (7000) 41.8 9.2 234 0 55.8 –218.8 15.5 3. 3 4060 106 .3 1555 38 .6 4120 42 .3 25.8 2520 For heat... Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (19 73) ©2001 CRC Press LLC 254 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics Page 255 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic Data Table 73 HEAT OF FUSION FOR ELEMENTS AND INORGANIC COMPOUNDS (SHEET... K, add 2 73. 15 to values in ˚C Values in parentheses are of uncertain reliability Source: data from Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R E and Tuve, G L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (19 73) ©2001 CRC Press LLC 248 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics... – – – – – (1.728) ( 3. 8 23) (17 .3) (28.8) Pb solid liquid gas 5.64 7.75 (4.97) 2 .30 –0. 73 – – – – – – – 1.784 1 .36 2 (–45.25) 17 .33 27.11 (– 13. 6) Pd solid liquid 5.80 (9.0) 1 .38 – – – – – 1.791 (1.215) 24.6 ( 43. 8) Po solid liquid gas (5.2) (9.0) (4.97) (3. 2) – – – – – – – – (1.6 93) (0.847) (–28. 73) (17.6) (35 .2) (– 13. 5) d A Source: data from Weast, R C Ed., Handbook of Chemistry and Physics, 69th ed.,... liquid (5. 13) (7.50) (3. 0) – – – 1.6 63 (–2.5 63) 21.1 31 .3 Se solid liquid 3. 30 7.0 8.80 – – – – – 1 .37 5 0.881 11.28 27 .34 Si solid liquid 5.70 7.4 1.02 – – –1.06 2.100 7.646 28.88 33 .17 Sm solid liquid (6.7) (9.0) (3. 4) – – – – – (2.149) (–2.296) (24.2) (33 .4) Sn solid, α, β liquid gas 4.42 6 .30 – – 1.598 14.8 7 .30 (4.97) – – – – – – 0.559 60.21) 26.2 (–14 .3) solid liquid gas (5.60) (7.7) (4.97) (1 .37 ) –... – 2.212 1.887 (–17 .35 ) 22.5 24.1 (– 13. 6) Cu solid liquid 5.41 7.50 1.50 – – – – – 1.680 0.024 23. 30 34 .05 F2 gas 8.29 0.44 – –0.80 2.760 –0.76 Fe solid, α solid, β solid, γ solid, δ liquid 3. 37 10.40 4.85 10 .30 7.10 – 3. 00 – – – – – 0. 43 – – – 1.176 4.281 0 .39 6 4 .38 2 14.59 55.66 19.76 55.11 10.00 – – – –0.021 50. 73 solid liquid 5. 237 (6.645) 3. 33 – – – – – 1.710 (0.648) 21.01 ( 23. 64) Ga d A Source:... and Kinetic Data Table 73 HEAT OF FUSION FOR ELEMENTS AND INORGANIC COMPOUNDS (SHEET 14 OF 16) Heat of fusion Compound Formula Melting point ˚C Sulfur trioxide (α) SO3 SO3 SO3 16.8 32 .3 62.1 25.8 36 .1 79.0 2060 2890 631 0 Ta 2996 ± 50 34 .6–41.5 (7500) TaCl5 206.8 1877 25.1 108.6 9000 48000 4 53 135 6 25 .3 24.6 32 30 39 00 30 2.4 460 5.0 21.0 1 030 5990 2 73 9.5 4400 427 17.7 4260 Sulfur trioxide (β) Sulfur trioxide . Handbook of Materials Science & Engineering 238 UC 28 63 UCl 4 8 43 UF 4 1 233 UI 4 779 UN 31 23 UO 2 31 51 USi 2 1970 US 2 > 137 5 VB 2 237 3 VC 36 00 VCl 4 245 VF 3 >1075 FI 2 1048 VN 25 93 V 2 O 5 947 VSi 2 20 23 V 2 S 3 >875 WB. Alexander Thermodynamic and Kinetic Data 239 ZnSO 4 8 73 ZrB 2 33 13 ZrBr 2 >625 ZrC 35 33 ZrCl 2 6 23 ZrF 4 8 73 ZrI 4 772 ZrN 32 50 ZrO 2 31 23 Zr(SO 4 ) 2 6 83 ZrS 2 18 23 Table 72. MELTING POINTS. trichloride EuCl 3 622 (20.9) (8000) Fluorine F 2 –219.6 6.4 244.0 Gadolinium Gd 131 2 23. 8 37 00 Gallium Ga 29 19.1 133 6 Germanium Ge 959 (114 .3) ( 830 0) Gold Au 10 63 (15 .3) 30 30 Hafnium Hf 2214 (34 .1) (6000) Holmium