Shackelford & Alexander Thermodynamic and Kinetic Data 367 Mercury selenide (HgSe) Sb 6.3x10 –5 0.85 540–630 Nickel aluminate (NiAl 2 O 4 ) Cr 1.17x10 –3 2.2 Fe 1.33 3.5 Nickel chromate (III) (NiCr 2 O 4 ) Cr 0.74 3.1 Cr 2.03x10 –5 1.9 Fe 1.35x10 –3 2.6 Ni 0.85 3.2 Selenium (Se) (amorphous) Fe 1.1x10 –5 0.38 300–400 Ge 9.4x10 –6 0.39 300–400 In 5.2x10 –6 0.32 300–400 Sb 2.8x10 –8 0.29 300–400 Se 7.6x10 –10 0.14 300–400 Sn 4.8x10 –8 0.39 300–400 Te 5.4x10 –6 0.53 300–400 Tl 1.4x10 –6 0.35 300–400 Zn 3.8x10 –7 0.29 300–400 Silicon (Si) Al 8.0 3.5 1100–1400 Ag 2x10 –3 1.6 1100–1350 As 3.2x10 –1 3.5 1100–1350 Au 1.1x10 –3 1.1 800–1200 Table 86. DIFFUSION IN SEMICONDUCTORS * (SHEET 6 OF 8) Semiconductor Diffusing Element D o (cm 2 • s –1 ) ∆E (eV) Temperature Range of Validity (˚C) Source: from Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, 1973, 251. 6.7 Thermodynamics Page 367 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 368 Silicon (Si) (Con’t) B 1.0x10 +1 3.7 950–1200 Bi 1.04x10 +3 4.6 1100–1350 Cu 4x10 –1 1.0 800–1100 Fe 6.2x10 –3 0.86 1000–1200 Ga 3.6 3.5 1150–1350 Hl 9.4x10 –3 0.47 1000–1200 He 1.1x10 –1 0.86 1000–1200 In 1.65x10 +1 3.9 1100–1350 Li 9.4x10 –3 0.78 100–800 P 1.0x10 +1 3.7 1100–1350 Sb 5.6 3.9 1100–1350 Tl 1.65x10 +1 3.9 1100–1350 Silicon carbide (SiC) Al 2.0x10 –1 4.9 1800–2250 B 1.6x10 +1 5.6 1850–2250 Cr 2.3x10 –1 4.8 1700–1900 Sulfur (S) S 2.8x10 +13 2.0 >100 Tin zinc oxide (SnZn 2 O 4 ) Sn 2x10 +5 4.7 Zn 37 3.3 Zinc aluminate (ZnAl 2 O 4 ) Zn 2.5x10 +2 3.4 Zinc chromate (III) (ZnCr 2 O 4 ) Cr 8.5 3.5 Zn 60 3.7 Table 86. DIFFUSION IN SEMICONDUCTORS * (SHEET 7 OF 8) Semiconductor Diffusing Element D o (cm 2 • s –1 ) ∆E (eV) Temperature Range of Validity (˚C) Source: from Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, 1973, 251. 6.7 Thermodynamics Page 368 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 369 a Values obtained at the low concentration limit. * The diffusion coefficient D at a temperature T(K) is given by the following: D=D o e -∆E/kT For D o in m 2 /s, multiply values in cm 2 /s by 10 –4 . Zinc ferrate (III) (ZnFe 2 O 4 ) Fe 8.5x10 +2 3.5 Zn 8.8x10 +2 3.7 Zinc selenide (ZnSe) Cu 1.7x10 –5 0.56 200–570 Zinc sulfide (ZnS) Zn 1.0x10 +16 6.50 >1030 1.5x10 +4 3.25 940–1030 3.0x10 –4 1.52 <940 Table 86. DIFFUSION IN SEMICONDUCTORS * (SHEET 8 OF 8) Semiconductor Diffusing Element D o (cm 2 • s –1 ) ∆E (eV) Temperature Range of Validity (˚C) Source: from Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, 1973, 251. 6.7 Thermodynamics Page 369 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford, James F. & Alexander, W. “Thermal Propertiesof Materials” Materials Science andEngineeringHandbook Ed. James F. Shackelford and W. Alexander Boca Raton: CRC Press LLC, 2001 List of Tables 371 CHAPTER 5 Thermal Properties of Materials Specific Heat & Heat Capacity Specific Heat of the Elements at 25 ˚C Heat Capacity of Ceramics Specific Heat of Polymers Specific Heat of Fiberglass Reinforced Plastics Thermal Conductivity Thermal Conductivity of Metals (Part 1) Thermal Conductivity of Metals (Part 2) Thermal Conductivity of Metals (Part 3) Thermal Conductivity of Metals (Part 4) Thermal Conductivity of Alloy Cast Irons Thermal Conductivity of Iron and Iron Alloys Thermal Conductivity of Aluminum and aluminum alloys Thermal Conductivity of Copper and Copper Alloys Thermal Conductivity of Magnesium and Magnesium Alloys Thermal Conductivity of Nickel and Nickel Alloys Thermal Conductivity of Lead and Lead Alloys Thermal Conductivity of Tin, Titanium, Zinc and their Alloys Thermal Conductivity of Pure Metals (Continued) 7.00 Thermal Page 371 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander 372 List of Tables (Continued) Thermal Properties Thermal Conductivity of Ceramics Thermal Conductivity of Glasses Thermal Conductivity of Cryogenic Insulation Thermal Conductivity of Cryogenic Supports Thermal Conductivity of Special Concretes Thermal Conductivity of SiC-Whisker-Reinforced Ceramics Thermal Conductivity of Polymers Thermal Conductivity of Fiberglass Reinforced Plastics Thermal Expansion Thermal Expansion of Wrought Stainless Steels Thermal Expansion of Wrought Titanium Alloys Thermal Expansion of Graphite Magnesium Castings Linear Thermal Expansion of Metals and Alloys Thermal Expansion of Ceramics Thermal Expansion of SiC-Whisker-Reinforced Ceramics Thermal Expansion of Glasses Thermal Expansion of Polymers Thermal Expansion Coefficients of Materials for Integrated Circuits Thermal Expansion of Silicon Carbide SCS–2–Al Tempering & Softening ASTM B 601 Temper Designation Codes for Copper and Copper Alloys Temper Designation System for Aluminum Alloys Tool Steel Softening After 100 Hours Thermoplastic Polyester Softening with Temperature Heat-Deflection Temperature of Carbon- and Glass-Reinforced Engineering Thermoplastics 7.00 Thermal Page 372 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermal Properties CRC Handbook of Materials Science & Engineering 374 Hafnium 0.035 Helium 1.24 Hollnium 0.0393 Hydrogen (H 2 ) 3.41 Indium 0.056 lodine (I 2 ) 0.102 Iridium 0.0317 Iron (α) 0.106 Krypton 0.059 Lanthanum 0.047 Lead 0.038 Lithium 0.85 Lutetium 0.037 Magnesium 0.243 Manganese, α 0.114 Manganese, β 1.119 Mercury 0.0331 Molybdenum 0.599 Neodymium 0.049 Neon 0.246 Nickel 0.106 Niobium 0.064 Nitrogen (N 2 ) 0.249 Osmium 0.03127 Oxygen (O 2 ) 0.219 Palladium 0.0584 Phosphorus, white 0.181 Phosphorus, red, triclinic 0.160 Table 87. SPECIFIC HEAT OF THE ELEMENTS AT 25 ˚C (SHEET 2 OF 4) Element C p (cal • g -l • K –1 ) Source: data from Weast, R. C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, 1974, D-144., Kelly, K. K., Bulletin 592, Bureau of Mines, Washington, D. C., 1961.and Hultgren, R., Orr, R L., Anderson, P. D., and Kelly, K. K., Selected Values of Thermodynamic Properties of Metals and Alloys, John Wiley & Sons, New York, (1963). 7.01 Thermal Page 374 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermal Properties 375 Platinum 0.0317 Polonium 0.030 Potassium 0.180 Praseodymium 0.046 Promethium 0.0442 Protactinium 0.029 Radium 0.0288 Radon 0.0224 Rhenium 0.0329 Rhodium 0.0583 Rubidium 0.0861 Ruthenium 0.057 Samarium 0.043 Scandium 0.133 Selenium (Se 2 ) 0.0767 Silicon 0.168 Silver 0.0566 Sodium 0.293 Strontium 0.0719 Sulfur, yellow 0.175 Tantalum 0.0334 Technetium 0.058 Tellurium 0.0481 Terbium 0.0437 Thallium 0.0307 Thorium 0.0271 Thulium 0.0382 Tin (α) 0.0510 Table 87. SPECIFIC HEAT OF THE ELEMENTS AT 25 ˚C (SHEET 3 OF 4) Element C p (cal • g -l • K –1 ) Source: data from Weast, R. C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, 1974, D-144., Kelly, K. K., Bulletin 592, Bureau of Mines, Washington, D. C., 1961.and Hultgren, R., Orr, R L., Anderson, P. D., and Kelly, K. K., Selected Values of Thermodynamic Properties of Metals and Alloys, John Wiley & Sons, New York, (1963). 7.01 Thermal Page 375 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermal Properties CRC Handbook of Materials Science & Engineering 376 Tin (β) 0.0530 Titanium 0.125 Tungsten 0.0317 Uranium 0.0276 Vanadium 0.116 Xenon 0.0378 Ytterbium 0.0346 Yttrium 0.068 Zinc 0.0928 Zirconium 0.0671 Table 87. SPECIFIC HEAT OF THE ELEMENTS AT 25 ˚C (SHEET 4 OF 4) Element C p (cal • g -l • K –1 ) Source: data from Weast, R. C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, 1974, D-144., Kelly, K. K., Bulletin 592, Bureau of Mines, Washington, D. C., 1961.and Hultgren, R., Orr, R L., Anderson, P. D., and Kelly, K. K., Selected Values of Thermodynamic Properties of Metals and Alloys, John Wiley & Sons, New York, (1963). 7.01 Thermal Page 376 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC [...]... 0.339 0.3 24 0.312 2.76 2.56 2 .44 2.35 1 .48 1.38 1. 34 1.32 0 .40 3 0.373 0.350 0.332 200 273 300 40 0 0.733 0.682 0.666 0.622 0. 245 0.2 24 0.219 0.2 04 1.97 1.82 1.78 1.62 1.26 1.22 1.21 1.16 0.252 0.232 0.227 0.216 500 600 700 800 0.596 (0.323) (0. 343 ) (0.3 64) 0.197 0.1 94 0.1 94 0.197 1 .49 1.39 1.33 1.28 1.11 1.05 (0 .49 9) (0.557) 0.210 0.207 0.209 0.216 900 1000 1100 1200 (0.3 84) (0 .40 5) (0 .42 5) (0 .44 6) 0.202... Chromium Copper Gold 70 80 90 100 5.0 4. 0 3 .4 3.0 1.08 1.06 1. 04 1.03 2.08 1.82 1.68 1.58 6.7 5.7 5. 14 4.83 3.58 3.52 3 .48 3 .45 200 273 300 40 0 2.37 2.36 2.37 2 .4 0.993 0.975 0.968 0. 947 1.11 0. 948 0.903 0.873 4. 13 4. 01 3.98 3.92 3.27 3.18 3.15 3.12 500 600 700 800 2.37 2.32 2.26 2.2 0.92 (0 .42 ) (0 .49 ) (0.559) 0. 848 0.805 0.757 0.713 3.88 3.83 3.77 3.71 3.09 3. 04 2.98 2.92 900 1000 1100 1200 2.13 (0.93)... 0.7 34 0.73 0.722 4. 3 4. 28 4. 27 4. 2 0.575 0.5 74 0.575 0.578 500 600 700 800 0.721 0.655 0.653 0.6 74 0.567 0.582 0.598 0.613 0.719 0.72 0.723 0.729 4. 13 4. 05 3.97 3.89 0.582 0.586 0.59 0.5 94 900 1000 1100 1200 0.696 0.718 0.739 0.761 0.629 0. 644 0.659 0.675 0.737 0. 748 0.76 0.775 3.82 3. 74 3.66 3.58 0.598 0.602 0.606 0.610 140 0 1600 1800 2000 0.8 04 0.705 0.735 0.7 64 0.791 0.807 0. 842 0.877 0.913 2200... Charles T Lynch, CRC Handbook of Materials Science, Vol 3, CRC Press, Boca Raton, Florida and Engineered Materials Handbook, Vol.2, Engineering Plastics, ASM International, Metals Park, Ohio, 1988 ©2001 CRC Press LLC 382 CRC Handbook of Materials Science & Engineering 7.01 Thermal Page 385 Wednesday, December 31, 1969 17:00 Thermal Properties Table 91 THERMAL CONDUCTIVITY OF METALS (PART 1) (SHEET 2 OF... Charles T Lynch, CRC Handbook of Materials Science, Vol 3, CRC Press, Boca Raton, Florida and Engineered Materials Handbook, Vol.2, Engineering Plastics, ASM International, Metals Park, Ohio, 1988 ©2001 CRC Press LLC 380 CRC Handbook of Materials Science & Engineering 7.01 Thermal Page 381 Wednesday, December 31, 1969 17:00 Thermal Properties Table 89 SPECIFIC HEAT OF (SHEET 3 OF 4) Polymer Class Phenolics;... ©2001 CRC Press LLC 41 4 CRC Handbook of Materials Science & Engineering 7.01 Thermal Page 41 5 Wednesday, December 31, 1969 17:00 Thermal Properties Table 1 04 THERMAL CONDUCTIVITY OF CERAMICS (SHEET 12 OF 12) Class Ceramic Thermal Conductivity (cal • cm-1 • sec-1 • K-1) Silicides Molybdenum Disilicide (MoSi2) 0.129 at 150oC 0.0 74 at 42 5oC 0.053 at 540 oC 0.057 at 650oC 0. 046 at 875oC 0. 041 at 1100oC Source:... Standard Polypropylene: General purpose High impact Polyphenylene sulfide: Standard Specific heat (Btu/lb/°F) 0.35—0 .40 — 0.30—0.35 0.28—0.32 0.27—0.37 0.33 0.293 0.31 0.25—0.35 0.15—0.27 0.35 0.35 0.35 0.30—0.55 0.25—0.35 0.20—0.25 0. 24 0 .45 0 .45 —0 .48 0.26 Source: data compiled by J.S Park from Charles T Lynch, CRC Handbook of Materials Science, Vol 3, CRC Press, Boca Raton, Florida and Engineered Materials. .. 0.28 0.25 0.25 0. 24 142 (T21, sand) 195 (T4, T62) B195 (T4, T6) 2 14 0 .40 0.33 0.31 0.33 200(T4) 319 355(T51, sand) 356(T51, sand) 0.21 0.26 0 .40 0 .40 360 380 750 40 E 0.35 0.23 0 .44 0.33 Data from ASM Metals Reference Book, Third Edition, Michael Bauccio, Ed., ASM International, Materials Park, OH, p156, (1993) ©2001 CRC Press LLC Shackelford & Alexander 395 7.01 Thermal Page 397 Wednesday, December 31,... (Si3N4) Oxides Cerium Dioxide (CeO2) Silicides Molybdenum Disilicide (MoSi2) Tungsten Disilicide (WSi2) 0.1961 cal/g/˚C ; 0-100˚C 0.2277 cal/g/˚C ; 0 -42 0˚C 0.2399 cal/g/˚C ; 0-598˚C 0.17 cal/g/˚C 14. 24T + 5.62x10-3T 49 1-1 140 K 10- 14 cal/g/˚C; 42 5-1000˚C 8 cal/g/˚C; 42 5- 145 0˚C Source: data compiled by J.S Park from No 1 Materials Index, Peter T.B Shaffer, Plenum Press, New York, (19 64) ; SmithellsBrandes,... (0.078) (0.0 84) (0.098) 1 .43 1.39 1.38 1. 34 500 600 700 800 0.613 0. 547 0 .48 7 0 .43 3 0.325 0.312 (0.1 74) (0.19) 1.51 1 .49 1 .47 1 .46 (0.109) (0.12) (0.127) (0.13) 1.3 1.26 1.22 1.18 900 1000 1100 1200 0.38 0.326 0.297 0.282 (0.203) (0.215) 1 .45 (0. 84) (0.91) (0.98) 140 0 1600 1800 2000 0.309 0.327 2200 2600 Mercury Molybdenum 1.92 1.79 1.15 1.12 1.08 1.05 0.996 0. 946 0.907 0.88 0.858 0.825 Values are in . Alexander Thermal Properties 385 70 5.0 1.08 2.08 6.7 3.58 80 4. 0 1.06 1.82 5.7 3.52 90 3 .4 1. 04 1.68 5. 14 3 .48 100 3.0 1.03 1.58 4. 83 3 .45 200 2.37 0.993 1.11 4. 13 3.27 273 2.36 0.975 0. 948 4. 01. LLC Shackelford, James F. & Alexander, W. “Thermal Propertiesof Materials Materials Science and Engineering Handbook Ed. James F. Shackelford and W. Alexander Boca Raton: CRC Press LLC,. 300 40 0 Se 7.6x10 –10 0. 14 300 40 0 Sn 4. 8x10 –8 0.39 300 40 0 Te 5.4x10 –6 0.53 300 40 0 Tl 1.4x10 –6 0.35 300 40 0 Zn 3.8x10 –7 0.29 300 40 0 Silicon (Si) Al 8.0 3.5 1100– 140 0 Ag 2x10 –3 1.6 1100–1350 As 3.2x10 –1 3.5