Tổng hợp than hoạt tính từ bã đậu nành có khả năng xử lý kháng sinh trong nước

BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC SƯ PHẠM KỸ THUẬT THÀNH PHỐ HỒ CHÍ MINH CƠNG TRÌNH NGHIÊN CỨU KHOA HỌC CỦA SINH VIÊN TỔNG HỢP THAN HOẠT TÍNH TỪ BÃ ĐẬU NÀNH CĨ KHẢ NĂNG XỬ LÝ KHÁNG SINH TRONG NƯỚC MÃ SỐ: SV2022-112 CHỦ NHIỆM ĐỀ TÀI: LỮ THỊ NGỌC TRÂM SKC 0 Tp Hồ Chí Minh, tháng 11/2022 BỘ GIÁO DỤC SVÀ ĐÀO TẠO TRƯỜNG ĐH SƯ PHẠM KỸ THUẬT TPHCM BÁO CÁO TỔNG KẾT ĐỀ TÀI NGHIÊN CỨU KHOA HỌC CỦA SINH VIÊN TỔNG HỢP THAN HOẠT TÍNH TỪ BÃ ĐẬU NÀNH CÓ KHẢ NĂNG XỬ LÝ KHÁNG SINH TRONG NƯỚC SV2022-112 Thuộc nhóm ngành khoa học: Mơi trường SV thực hiện: Lữ Thị Ngọc Trâm Dân tộc: Kinh Lớp, khoa: 19150CL0B, Khoa ĐT.CLC Ngành học: Công nghệ Kỹ thuật Môi trường Nam, Nữ: Nữ Năm thứ: /Số năm đào tạo: Người hướng dẫn: TS Nguyễn Duy Đạt TP Hồ Chí Minh, tháng 11/2022 BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐH SƯ PHẠM KỸ THUẬT TPHCM THÔNG TIN KẾT QUẢ NGHIÊN CỨU CỦA ĐỀ TÀI Thông tin chung: - Tên đề tài: Tổng hợp than hoạt tính từ bã đậu nành có khả xử lý kháng sinh nước - Chủ nhiệm đề tài: Lữ Thị Ngọc Trâm Mã số SV: 19150002 - Lớp: 19150CL0B Khoa: Đào tạo Chất lượng cao - Thành viên đề tài: STT Họ tên MSSV Lớp Khoa Nguyễn Thị Trúc Quyên 19150030 19150CL0B ĐT.CLC Huỳnh Thanh Hải 19150012 19150CL0B ĐT.CLC - Người hướng dẫn: TS Nguyễn Duy Đạt Mục tiêu đề tài: - Xác định điều kiện tối ưu (KOH: tỷ lệ than sinh học nhiệt độ nhiệt phân) để tổng hợp chất hấp phụ từ sữa đông đậu nành để loại bỏ TCH dung dịch nước - Khảo sát điều kiện tối ưu cho trình hấp phụ, bao gồm pH dung dịch, thời gian tiếp xúc, nồng độ nhiệt độ ban đầu chất hấp phụ Tính sáng tạo: - Than hoạt tính (AC) sử dụng rộng rãi chất hấp phụ hiệu xử lý tính đặc biệt bao gồm cấu trúc xốp bên tuyệt vời, độ ổn định hóa học tương đối diện tích bề mặt riêng cao Mặc dù AC vi xốp dường vật liệu tốt để loại bỏ chất vi ô nhiễm, lỗ rỗng nhỏ có kích thước nm chúng dễ dàng bị chặn lại, AC có phần trăm thể tích lớn kích thước lỗ nm hoạt động tốt dẫn đến hiệu loại bỏ cao chất gây nhiễm thích hợp tiếp cận vị trí hấp phụ mà khơng bị phần tử lớn khác chặn lại Theo Fikriyyah, AC tạo từ bã đậu nành có diện tích bề mặt 151.5 m2/g vật liệu cho thấy số điểm tương đồng tính chất với AC thương mại thể tích lỗ, đường kính lỗ trung bình khả hấp phụ Nó cho phép vật liệu không hấp thụ chất gây ô nhiễm mà cịn tối ưu hóa việc tiếp xúc với chất xúc tác để bắt đầu phản ứng ơxy hóa, giúp q trình phân hủy hồn tồn chất gây ô nhiễm Kết nghiên cứu: - Vật liệu than hoạt tính có nguồn gốc từ bã đậu nành có khả xử lý kháng sinh (Tetracycline) nước Đóng góp mặt giáo dục đào tạo, kinh tế - xã hội, an ninh, quốc phòng khả áp dụng đề tài: - Đề tài áp dụng thực tế giúp xử lý nước thải bệnh viện, nhà máy dược, chăn ni… có chứa dư lượng TCH nước thải Công bố khoa học SV từ kết nghiên cứu đề tài (ghi rõ tên tạp chí có) nhận xét, đánh giá sở áp dụng kết nghiên cứu (nếu có): Ngày tháng 11 năm 2022 SV chịu trách nhiệm thực đề tài Nhận xét người hướng dẫn đóng góp khoa học SV thực đề tài (phần người hướng dẫn ghi): Ngày tháng 11 năm 2022 Người hướng dẫn (kí, họ tên) MỤC LỤC TÓM TẮT CHƯƠNG 1: GIỚI THIỆU 1.1 Bối cảnh động lực 1.2 Mục tiêu nghiên cứu CHƯƠNG 2: ĐÁNH GIÁ TÌNH HÌNH 2.1 Chất gây ô nhiễm (EC) - dư lượng dược phẩm 2.1.1 Tổng quan thuốc kháng sinh 2.1.2 Các tác động có hại dư lượng dược phẩm 2.1.3 Tổng quan tetracyclin 2.2 Than hoạt tính có nguồn gốc từ bã đậu nành 10 2.2.1 Cơ chế hấp phụ 10 2.2.2 Tổng quan than hoạt tính 12 2.2.3 Khả hấp phụ than hoạt tính gốc đậu nành 15 CHƯƠNG PHƯƠNG PHÁP 16 3.1 Nguyên liệu 16 3.2 Tổng hợp vật liệu 16 3.3 Đặc tính vật liệu 17 3.4 Thiết lập thí nghiệm hấp phụ giải hấp phụ 18 3.4.1 Nghiên cứu hấp phụ theo mẻ 18 3.4.2 Giải hấp tái sử dụng SAC 20 3.4.3 Đẳng nhiệt mơ hình hấp phụ 21 3.5 Hàm sai số 22 4.1 Tính chất vật liệu 23 4.1.1 Ảnh hưởng tỷ lệ KOH:SB nhiệt độ nung đến SAC cuối 23 4.1.2 Các đặc tính kết cấu hình thái 24 4.1.3 Phân tích phổ hồng ngoại – FTIR 28 4.2 Hiệu suất trình hấp phụ 30 4.2.1 Ảnh hưởng pH dung dịch cường độ ion 30 4.2.2 Đường đẳng nhiệt hấp phụ 34 4.2.3 Nhiệt động lực học hấp phụ 38 4.2.4 Thí nghiệm môi trường nước khác 40 4.2.5 Giải hấp tái sử dụng SAC 41 4.2.6 Cơ chế hấp phụ 42 TÀI LIỆU THAM KHẢO 48 DANH MỤC CÁC TỪ VIẾT TẮT AC Activated Carbon AOPs Advanced Oxidation Processes ARB Antibiotic-Resistance Bacteria ARG Antibiotic Resistance Gene BET Brunauer-Emmett-Teller BIC Bayesian Information Criterion BJH Barrett, Joyner, And Halenda DI water Deionized Water ECs Emerging Contaminants EC50 Half-Maximal Effective Concentration EDS Energy Dispersive FDA U.S Food and Drug Administration FTIR Fourier-Transform Infrared Spectroscopy IUPAC International Union of Pure and Applied Chemistry MPSD Marquardt’s Percent Standard Deviation SAC Soybean curd Activated Carbon SB S oybean curd Biochar SC Dried Soybean Curd SD Standard Deviation SEM Scanning Electron Microscope SNC Soybean curd Non-activated Carbon or Pyrochar TCH Tetracycline TOC Total Organic DANH MỤC BẢNG Bảng 2.1 Tóm tắt kích thước phân loại lỗ rỗng IUPAC từ [50] 12 Bảng 2.2 Thơng số SBET, thể tích chiều rộng lỗ rỗng AC tổng hợp mặt vật lý 14 Bảng 3.1 Tham số thí nghiệm hấp phụ 19 Bảng 4.1 Thông số kết cấu SAC SNC 24 Bảng 4.2 So sánh SBET loại than hoạt tính từ q trình hoạt tính KOH 26 Bảng 4.3 Thông số đẳng nhiệt 25oC việc hấp phụ TCH SAC 35 Bảng 4.4 So sánh hấp phụ tối đa TCH chất hấp phụ 37 Bảng 4.5 Các thông số nhiệt động lực học trình hấp phụ TCH 39 Bảng 4.6 Hiệu suất giải hấp TCH từ SAC đầy cách sử dụng dung dịch khử hấp phụ khác 41 DANH MỤC HÌNH ẢNH Hình 2.1 Dữ liệu phân phối thuốc kháng vi khuẩn Hoa Kỳ năm 2009-2018 điều chỉnh từ [34] Hình 2.2 Doanh số bán chất kháng khuẩn tính theo tỷ lệ phần trăm loài sản xuất thực phẩm 31 quốc gia châu Âu năm 2018 theo [43] Hình 2.3 Mười loại thuốc kê đơn thường xuyên nhất, theo tỷ lệ phần trăm điều chỉnh từ [44] 10 Hình 2.4 Cấu trúc hóa học TCH 10 Hình 2.5 Các chế trình hấp phụ metylen xanh lên than sinh học [47, 49] 11 Hình 3.1 Quy trình tổng hợp vật liệu 16 Hình 4.1 Ảnh hưởng (a) tỷ lệ KOH:SB (b) nhiệt độ nung đến SAC cuối 23 Hình 4.2 Hình ảnh SEM EDS 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