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Biomimetic Based Applications Part 10 pdf

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Yang, P.; Yang, W T.; Chen, J C (2008).The Bio-inspired Approach to Controllable Biomimetic Synthesis of Silver Nanoparticles in Organic Matrix of Chitosan and Silver-binding Peptide (NPSSLFRYLPSD) Mater Sci Eng CBiomimetic Supramol Syst 28, 2, 237-242, ISSN 0928-4931 15 Biomimetic Applications of Metal... solution The size of these nanoparticles ranging from 4-5 nm was in the regime of quantum size of ZnO For single ZnO QD, a 374 Biomimetic Based Applications Fig 33 SEM image and schematic illustration (a) Various (including triangular, hexagonal and cubic lattice) single crystallites formed on PET and not moved away with ddH2O (b) Schematic illustration of (a) (c) Spherical particles deposited on blank... planes in a wurtize-type ZnO This wurtize type was further supported by XRD pattern of BOPP-g-PAA/ZnO film (Figure 36), where three characteristic diffraction 376 Biomimetic Based Applications Fig 37 ZnO particles grew on the surface without PAA biomimetic mediation BOPP-gPAA film was directly placed into the mixed solution of Zn(NO3)2 and HMT (0.1 M) The growth took place at 90°C for 48 h The lower two... (Figure 30) Besides these big particles, AFM scanning on the surface (Figure 31) also revealed the existence of some nanoparticles with the size being around 40 nm on the surface The shapes of these crystals mainly included triangular and square Accordingly, based on our results, it seems difficult to obtain uniform silver particles if only peptides were used in this biomimetic synthesis system For... the size change of the silver nanoparticles Besides silver, we also extended this surface-immobilized IBP -based reaction to other peptide system for other material synthesis For example, the polypeptide sequence MS14 (MHGKTQATSGTIQS) (Brown et al, 1997 and 2001; Braun et al, 2002; Kulp et al, 2004; Tamerler et al, 2006) was used for biomimetic preparation of gold nanoparticles and their aggregates (Wang... characters (““BUCT””) behind two kinds of films Fig 24 Surface roughness evaluation by AFM on BOPP-OH before/after SiOx deposition Reproduced from (Yang et al, 2 010) Copyright from Science in China Chemistry Reproduced with permission 368 Biomimetic Based Applications Fig 25 The optical image after putting a BOPP-OH or BOPP-OH/SiOx film on a paper with ““BUCT”” characters on it The two pictures presented the... region (inset picture) showed around 3:1 signal-to-background ratio could be obtained by this type of protein immobilization Reproduced from (Yang et al, 2 010) Copyright from Science in China Chemistry Reproduced with permission 370 Biomimetic Based Applications potential packaging materials (Figure 28 left) The other one is that silanization monolayer, for example, 3-aminopropyltriethoxysilane (APTES),... mean diameter of no more than 5nm (as revealed by TEM), therefore possible light scattering and diffraction from large particles and aggregates was effectively eliminated This highly optical transparence is very important for advanced opto-electrical devices Another 378 Biomimetic Based Applications important requirement for opto-electrical device is the ability to large scale patterning/array of functional... could be also very easily achieved by simply applying a photomask in this 380 Biomimetic Based Applications photopolymerization process The resulting patternable array of nanocomposite film had good quality and large area Possible next work along this direction may be suggested to explore other kinds of polymer brushes for biomimetic material fabrication, since the field about polymer brush-mediated... Achilias, D S (2007) Chemical recycling of poly(ethylene terephthalate) Macromol Mater Eng 292, 128-146, ISSN 1438-7492 (print), 14392054 (online) 382 Biomimetic Based Applications Kumar, S.; Ito, T.; Yanagihara, Y.; Oaki, Y.; Nishimura, T.; Kato, T (2 010) Crystallization of Unidirectionally Oriented Fibrous Calcium Carbonate on Thermo-Responsive Polymer Brush Matrices CrystEngComm 12, 2021-2024, ISSN . 0<2=?>0,;,4K0<2=?>0?8,4% 0<8=,2% >?;<@"=% 7.=J'4")% +0=?.$0% Biomimetic Based Applications 352 i5!aj%.#2"=%+0"%="$,?#';%4?#+=?;%8<%'%>0?+?@'7C%BN,$.="%^HA%Q0"%="7.;+,#$%L"++'8,;,+<%?=% 7.=J'4"%@?;"4.;'=%+"@>;'+"%>'++"=#7%0':"%8""#%.7"2%+?%J'8=,4'+"%>?;<'#,;,#"%B!g_6H%B&'#$%"+% ';)%1FFRH)%Q,a 1 %'#2%/#a%@,4=?>'++"=#7A% % %. SO 4 SO 4 OH + + % N,$A%RA%M<2=?;<7,7%="'4+,?#%740"@"%?J%$='J+"2%7.;J'+"%$=?.>7%?#%>?;<@"=%7.=J'4"A% Biomimetic Based Applications 354 >;.7%5g%@"'7.="@"#+7%,#2,4'+"2%7+=?#$;<%+0'+%+0"%>?;'=%7.;J'+"%$=?.>7%?#%+0"%5!aD+="'+"2% 7.=J'4"%4?#:"=+"2%+?%0<2=?9<;%$=?.>7%'J+"=%7;?L%0<2=?;<7,7%,#%L'+"=%BN,$.="%RHA%% gJ+"=%7.44"77J.;;<%,#+=?2.4,#$%'#,?#%7.;J'+"%'#2%. '#2% ";"4+=??>+,4';%+"40#,Z."7A%`.40%J,;@7%'="%?J+"#%J'8=,4'+"2%8<%7?;D$";%@"+0?2%L0"="%$";'+,?#% '+%0,$0%+"@>"='+.="%,7%#""2"2%+?%"#7.="%+0"%Z.';,+<%?J%4=<7+';7A%6#%4?#+='7+)%;?LD+"@>"='+.="% 8,?@,@"+,4%#.4;"'+,?#%'#2%$=?L+0%,#%'Z."?.7%7?;.+,?#%8<%7.=J'4"D,@@?8,;,O"2%J.#4+,?#';% Biomimetic Based Applications 356 $=?.>7% 4?.;2% >=?:,2"% '#% ';+"=#'+,:"%

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