Đang tải... (xem toàn văn)
Trong bản kết quả phân tích này có: diện tích bề mặt riêng NiOgamaAl2O3, thể tích lỗ xốp NiOgamaAl2O3, đường kính mao quản hấp phụ và nhả hấp phụ của NiOgamaAl2O3, đường đẳng nhiệt hấp phụ và nhả hấp phụ của NiOgamaAl2O3,..... Các bạn có thể tải xuống và tham khảo. Mình đi phân tích mẫu này ở Viện Hóa Học 18 Hoàng Quốc Việt Cầu Giấy Hà Nội
Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: Comments: Degas 250 C 6h Summary Report Surface Area Single point surface area at p/p° = 0.298949197: 102.7882 m²/g BET Surface Area: 105.4424 m²/g t-Plot Micropore Area: 38.1455 m²/g BJH Adsorption cumulative surface area of pores between 1.7000 nm and 300.0000 nm diameter: 128.921 m²/g BJH Desorption cumulative surface area of pores between 1.7000 nm and 300.0000 nm diameter: 165.8988 m²/g Pore Volume Single point adsorption total pore volume of pores less than 380.0462 nm diameter at p/p° = 0.995000000: 0.215004 cm³/g Single point desorption total pore volume of pores less than 380.0462 nm diameter at p/p° = 0.995000000: 0.219279 cm³/g t-Plot micropore volume: 0.004971 cm³/g BJH Adsorption cumulative volume of pores between 1.7000 nm and 300.0000 nm diameter: 0.237561 cm³/g BJH Desorption cumulative volume of pores between 1.7000 nm and 300.0000 nm diameter: 0.262902 cm³/g Pore Size Adsorption average pore diameter (4V/A by BET): 8.15628 nm Desorption average pore diameter (4V/A by BET): 8.31843 nm BJH Adsorption average pore diameter (4V/A): 7.3707 nm BJH Desorption average pore diameter (4V/A): 6.3388 nm N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h Relative Pressure (p/p°) 0.021580574 0.048545787 0.063790454 0.070835899 0.081190500 0.088973855 0.106368355 0.131606765 0.148577349 0.172254249 0.197151460 0.222212067 0.247524079 0.272770509 0.298817936 0.319231723 0.339516084 0.378552633 0.415503885 0.454015847 0.500909745 0.533623568 0.578723893 0.618390020 0.657389157 0.699338428 0.739203419 0.797806480 0.820434094 0.857210813 0.884842523 0.898265095 0.908384165 0.917958082 0.927738816 0.937346132 0.947018030 Absolute Pressure (mmHg) Isotherm Tabular Report Quantity Elapsed Time Adsorbed (h:min) (cm³/g STP) 16.265392 36.604904 48.099766 53.420536 61.230110 67.100151 80.220879 99.253799 112.054291 129.917984 148.692368 167.614532 186.701004 205.769821 225.399460 240.801590 256.108521 285.606201 313.466919 342.524170 378.003113 402.720306 436.824249 466.994110 496.424469 528.168945 558.245483 602.608887 619.776917 647.607544 668.441711 678.590210 686.207947 693.446960 701.147217 708.178162 715.781128 18.9099 21.3843 22.3757 22.7914 23.3632 23.7764 24.6569 25.8660 26.6494 27.7305 28.8631 30.0115 31.1865 32.3940 33.6795 34.7252 35.8072 38.0395 40.3699 43.1434 47.1863 50.6617 56.7187 63.9641 73.8121 87.0750 98.2361 104.1827 105.4741 107.8890 110.0469 111.3016 112.3885 113.5918 115.0066 116.6027 118.5846 01:58 02:06 02:11 02:15 02:18 02:21 02:25 02:28 02:32 02:36 02:40 02:44 02:48 02:52 02:56 03:00 03:04 03:08 03:14 03:20 03:26 03:36 03:42 03:53 04:05 04:19 04:36 04:48 04:56 05:02 05:08 05:14 05:19 05:24 05:29 05:35 05:41 05:46 Saturation Pressure (mmHg) 753.748047 753.705261 754.028442 754.027649 754.144958 754.153625 754.155823 754.179932 754.169434 754.181519 754.222229 754.203735 754.299866 754.274109 754.369751 754.303650 754.315979 754.333984 754.468933 754.425964 754.432190 754.633179 754.689880 754.805969 755.177307 755.145508 755.240845 755.198730 755.332153 755.425598 755.482239 755.435791 755.445374 755.416016 755.423340 755.759277 755.514038 755.826294 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h Relative Pressure (p/p°) 0.952883220 0.959399835 0.966578786 0.973014838 0.979106421 0.983584733 0.986940560 0.994658617 0.994507366 0.995503194 0.990788180 0.987173356 0.983550952 0.980411301 0.973975674 0.964370292 0.951867973 0.943873985 0.933955172 0.921918971 0.911523810 0.902714934 0.891969230 0.862492685 0.825872780 0.779924099 0.745309293 0.702911480 0.663665321 0.625095593 0.591379635 0.582315144 0.538937711 0.496888104 0.459294395 0.422986725 0.374701715 0.333942088 0.305610534 Isotherm Tabular Report Absolute Quantity Elapsed Time Pressure Adsorbed (h:min) (mmHg) (cm³/g STP) 720.165222 725.081299 730.457642 735.230774 739.846313 743.240845 745.937073 751.757385 751.787537 752.494873 748.941284 746.271545 743.568481 741.231934 736.325134 729.018677 719.541077 713.502136 705.988708 696.777344 688.986877 682.294250 674.143311 651.914917 624.108643 589.401123 563.169922 531.100891 501.448730 472.154114 446.519165 439.610046 406.771362 374.742096 346.333344 318.966095 282.409760 251.718979 230.369217 120.1023 121.9051 124.2143 126.7742 129.5876 132.2437 134.8608 137.0300 138.8604 141.9025 140.5945 139.4116 138.1574 137.1824 135.5462 133.4735 131.5228 130.4764 129.1342 127.5945 126.4773 125.5328 124.4205 121.4798 118.0792 114.3786 111.4683 107.4401 102.6647 94.1446 75.2397 70.9116 55.9970 49.3698 44.4632 41.3064 38.0885 35.7967 34.3174 05:53 05:59 06:06 06:12 06:18 06:25 06:32 06:35 06:40 06:51 06:54 06:58 07:03 07:09 07:15 07:22 07:28 07:33 07:38 07:44 07:49 07:54 07:59 08:06 08:13 08:23 08:31 08:40 08:50 09:05 09:26 09:38 09:57 10:09 10:20 10:26 10:34 10:40 10:45 Saturation Pressure (mmHg) 755.774902 755.765503 755.714539 755.621338 755.634216 755.644958 755.807495 755.794373 755.939636 755.893982 755.904541 755.968079 756.004028 756.041809 755.999512 755.953064 755.925293 755.929443 755.912842 755.790222 755.862732 755.824707 755.792114 755.849792 755.695862 755.716003 755.619080 755.572937 755.574707 755.331055 755.046570 754.934937 754.765076 754.178040 754.055237 754.080627 753.692200 753.780334 753.799988 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h Relative Pressure (p/p°) 0.251394420 0.203784131 0.154451942 0.106547034 Isotherm Tabular Report Absolute Quantity Elapsed Time Pressure Adsorbed (h:min) (mmHg) (cm³/g STP) 189.474136 153.565323 116.364662 80.278580 31.6616 29.4443 27.2034 24.9537 10:50 10:55 11:01 11:06 Saturation Pressure (mmHg) 753.692688 753.568604 753.403687 753.456726 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h Isotherm Linear Plot Ni/y-Al2O3 - Adsorption Ni/y-Al2O3 - Desorption 140 120 Quantity Adsorbed (cm³/g STP) 100 80 60 40 20 0.0 0.1 0.2 0.3 0.4 0.5 0.6 Relative Pressure (p/p°) 0.7 0.8 0.9 1.0 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BET Report BET Surface Area: 105.4424 ± 0.2024 m²/g Slope: 0.040820 ± 0.000078 g/cm³ STP Y-Intercept: 0.000459 ± 0.000014 g/cm³ STP C: 89.971365 Qm: 24.2253 cm³/g STP Correlation Coefficient: 0.9999781 Molecular Cross-Sectional Area: 0.1620 nm² Relative Pressure (p/p°) 0.048545787 0.063790454 0.070835899 0.081190500 0.088973855 0.106368355 0.131606765 0.148577349 0.172254249 0.197151460 0.222212067 0.247524079 0.272770509 0.298817936 Quantity Adsorbed (cm³/g STP) 21.3843 22.3757 22.7914 23.3632 23.7764 24.6569 25.8660 26.6494 27.7305 28.8631 30.0115 31.1865 32.3940 33.6795 1/[Q(p°/p - 1)] 0.002386 0.003045 0.003345 0.003782 0.004108 0.004827 0.005859 0.006548 0.007504 0.008508 0.009520 0.010548 0.011579 0.012653 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BET Surface Area Plot Ni/y-Al2O3 Not Fitted 0.012 0.010 1/[Q(p°/p - 1)] 0.008 0.006 0.004 0.002 0.000 0.00 0.05 0.10 0.15 Relative Pressure (p/p°) 0.20 0.25 0.30 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h t-Plot Report Micropore Volume: 0.004971 cm³/g Micropore Area: 38.1455 m²/g External Surface Area: 67.2969 m²/g Slope: 43.507183 ± 0.575330 cm³/g·nm STP Y-Intercept: 3.213422 ± 0.255624 cm³/g STP Correlation Coefficient: 0.999563 Surface Area Correction Factor: 1.000 Density Conversion Factor: 0.0015468 Total Surface Area (BET): 105.4424 m²/g Thickness Range: 0.30000 nm to 0.50000 nm Thickness Equation: SIO2OH.THK Thickness Curve Relative Statistical Pressure (p/p°) Thickness (nm) 0.000000583 0.000001269 0.000002467 0.000004337 0.000006996 0.000010668 0.000015595 0.000022070 0.000030356 0.000040910 0.000054173 0.000070642 0.000091180 0.000116552 0.000149097 0.000186837 0.000232387 0.000287173 0.000352652 0.000429791 0.000520435 0.000626040 0.000747629 0.000886733 0.001044405 0.001222147 0.00853 0.01680 0.02514 0.03348 0.04186 0.05021 0.05857 0.06691 0.07523 0.08350 0.09173 0.10000 0.10830 0.11650 0.12470 0.13280 0.14080 0.14870 0.15660 0.16430 0.17190 0.17930 0.18660 0.19380 0.20070 0.20750 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: Comments: Degas 250 C 6h Thickness Curve Relative Statistical Pressure (p/p°) Thickness (nm) 0.001419677 0.001638732 0.001878428 0.002139985 0.002421749 0.002724421 0.003091054 0.003484834 0.003905820 0.004353289 0.004826527 0.005324614 0.005846740 0.006391686 0.007190915 0.007729329 0.010195556 0.020774951 0.031331281 0.039274728 0.049951782 0.100992972 0.148564479 0.200503714 0.250851460 0.301335723 0.352025502 0.399919124 0.449976343 0.499857499 0.549879719 0.599864809 0.650021913 0.700192544 0.749851602 0.799966476 0.849790401 0.899069029 0.953855339 0.983679159 0.21400 0.22040 0.22660 0.23250 0.23830 0.24390 0.24990 0.25570 0.26140 0.26680 0.27210 0.27720 0.28210 0.28690 0.29340 0.29760 0.31330 0.35700 0.38530 0.40210 0.42120 0.48540 0.52960 0.57070 0.60760 0.64350 0.67910 0.71340 0.75050 0.78970 0.83170 0.87670 0.92720 0.98330 1.04900 1.12800 1.22700 1.36300 1.62500 3.05600 N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 10 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h t-Plot Report - Data Relative Statistical Quantity Pressure (p/p°) Thickness (nm) Adsorbed (cm³/g STP) 0.021580574 0.048545787 0.063790454 0.070835899 0.081190500 0.088973855 0.106368355 0.131606765 0.148577349 0.172254249 0.197151460 0.222212067 0.247524079 0.272770509 0.298817936 0.319231723 0.339516084 0.378552633 0.415503885 0.454015847 0.500909745 0.533623568 0.578723893 0.618390020 0.657389157 0.699338428 0.739203419 0.35939 0.41899 0.44128 0.45073 0.46368 0.47269 0.49074 0.51493 0.52961 0.54879 0.56820 0.58677 0.60522 0.62324 0.64172 0.65608 0.67030 0.69801 0.72476 0.75356 0.79055 0.81779 0.85720 0.89468 0.93499 0.98229 1.03410 18.9099 21.3843 22.3757 22.7914 23.3632 23.7764 24.6569 25.8660 26.6494 27.7305 28.8631 30.0115 31.1865 32.3940 33.6795 34.7252 35.8072 38.0395 40.3699 43.1434 47.1863 50.6617 56.7187 63.9641 73.8121 87.0750 98.2361 Fitted * * * * * * * Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 12 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption Pore Distribution Report Standard User-Defined Reference Curve:SIO2OH.THK Diameter Range: Adsorbate Property Factor: Density Conversion Factor: Fraction of Pores Open at Both Ends: Pore Diameter Range (nm) 345.9 - 144.8 144.8 - 121.3 121.3 - 95.9 95.9 - 74.8 74.8 - 60.5 60.5 - 49.8 49.8 - 42.7 42.7 - 37.7 37.7 - 32.2 32.2 - 28.1 28.1 - 25.0 25.0 - 22.6 22.6 - 20.5 20.5 - 18.2 18.2 - 14.9 14.9 - 12.0 12.0 - 10.7 10.7 - 8.4 8.4 - 7.3 7.3 - 6.4 6.4 - 5.8 5.8 - 5.2 5.2 - 4.7 4.7 - 4.3 4.3 - 3.9 3.9 - 3.6 3.6 - 3.4 3.4 - 3.1 3.1 - 3.0 3.0 - 2.9 Average Diameter (nm) 174.8 126.5 105.6 82.7 66.2 54.1 45.7 39.9 34.5 29.9 26.4 23.6 21.4 19.2 16.2 13.1 11.2 9.2 7.7 6.8 6.0 5.4 4.9 4.5 4.1 3.8 3.5 3.2 3.0 2.9 Incremental Pore Volume (cm³/g) 0.006173 0.004471 0.004540 0.004828 0.004360 0.003814 0.002832 0.002376 0.003611 0.002990 0.002722 0.002378 0.002199 0.002437 0.004276 0.005034 0.002745 0.014534 0.030343 0.037573 0.027947 0.019933 0.015692 0.008133 0.008451 0.004900 0.003380 0.002562 0.000939 0.000679 1.7000 nm to 300.0000 nm 0.95300 nm 0.0015468 0.00 Cumulative Pore Volume (cm³/g) 0.006173 0.010644 0.015184 0.020012 0.024372 0.028186 0.031018 0.033394 0.037005 0.039995 0.042717 0.045095 0.047294 0.049731 0.054007 0.059041 0.061786 0.076320 0.106663 0.144236 0.172183 0.192116 0.207808 0.215941 0.224392 0.229292 0.232672 0.235234 0.236174 0.236853 Incremental Pore Area (m²/g) 0.141 0.141 0.172 0.234 0.264 0.282 0.248 0.238 0.419 0.400 0.413 0.402 0.411 0.507 1.058 1.542 0.977 6.312 15.669 22.147 18.504 14.650 12.811 7.247 8.239 5.220 3.889 3.184 1.236 0.931 Cumulative Pore Area (m²/g) 0.141 0.283 0.455 0.688 0.952 1.233 1.481 1.720 2.139 2.539 2.952 3.355 3.765 4.273 5.331 6.872 7.849 14.162 29.830 51.977 70.481 85.131 97.942 105.189 113.428 118.648 122.537 125.722 126.957 127.888 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 13 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h Pore Diameter Range (nm) 2.9 - 2.7 2.7 - 2.6 Average Diameter (nm) 2.8 2.6 Incremental Pore Volume (cm³/g) 0.000512 0.000196 Cumulative Pore Volume (cm³/g) 0.237364 0.237561 Incremental Pore Area (m²/g) 0.736 0.297 Cumulative Pore Area (m²/g) 128.624 128.921 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 14 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption Cumulative Pore Volume (Larger) User-Defined : Standard BJH Adsorption Cumulative Pore Volume (Larger) BJH Adsorption dV/dlog(D) Pore Volume 0.6 0.20 0.15 0.4 0.3 0.10 0.2 0.05 0.1 0.00 0.0 10 50 Pore Diameter (nm) 100 dV/dlog(D) Pore Volume (cm³/g) Pore Volume (cm³/g) 0.5 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 15 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption dV/dlog(D) Pore Volume User-Defined : Standard Ni/y-Al2O3 0.6 dV/dlog(D) Pore Volume (cm³/g) 0.5 0.4 0.3 0.2 0.1 0.0 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 16 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption dV/dD Pore Volume User-Defined : Standard Ni/y-Al2O3 0.040 dV/dD Pore Volume (cm³/g·nm) 0.035 0.030 0.025 0.020 0.015 0.010 0.005 0.000 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 17 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption Cumulative Pore Area (Larger) User-Defined : Standard BJH Adsorption Cumulative Pore Area (Larger) BJH Adsorption dA/dlog(D) Pore Area 400 120 350 100 300 Pore Area (m²/g) 200 60 150 40 100 20 50 0 10 50 Pore Diameter (nm) 100 dA/dlog(D) Pore Area (m²/g) 250 80 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 18 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption dA/dD Pore Area User-Defined : Standard Ni/y-Al2O3 25 dA/dD Pore Area (m²/g·nm) 20 15 10 5 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 19 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Adsorption dA/dlog(D) Pore Area User-Defined : Standard 400 Ni/y-Al2O3 350 dA/dlog(D) Pore Area (m²/g) 300 250 200 150 100 50 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 20 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption Pore Distribution Report Standard User-Defined Reference Curve:SIO2OH.THK Diameter Range: Adsorbate Property Factor: Density Conversion Factor: Fraction of Pores Open at Both Ends: Pore Diameter Range (nm) 422.7 - 205.8 205.8 - 147.4 147.4 - 121.0 121.0 - 102.1 102.1 - 77.5 77.5 - 56.8 56.8 - 41.7 41.7 - 35.7 35.7 - 30.6 30.6 - 26.2 26.2 - 23.3 23.3 - 21.4 21.4 - 19.4 19.4 - 15.4 15.4 - 12.3 12.3 - 9.9 9.9 - 8.6 8.6 - 7.4 7.4 - 6.5 6.5 - 5.9 5.9 - 5.4 5.4 - 5.2 5.2 - 4.7 4.7 - 4.3 4.3 - 4.0 4.0 - 3.7 3.7 - 3.3 Average Diameter (nm) 247.3 167.2 127.1 109.9 86.4 64.0 47.1 38.1 32.7 28.0 24.5 22.2 20.3 16.9 13.5 10.8 9.1 7.9 6.9 6.2 5.6 5.3 5.0 4.5 4.1 3.8 3.5 Incremental Pore Volume (cm³/g) 0.002020 0.001825 0.002170 0.001662 0.002813 0.003556 0.003161 0.001722 0.002470 0.002923 0.002187 0.001901 0.002230 0.006031 0.007351 0.008406 0.006936 0.010196 0.012942 0.025149 0.060320 0.013595 0.046693 0.016674 0.011241 0.004609 0.002119 1.7000 nm to 300.0000 nm 0.95300 nm 0.0015468 0.00 Cumulative Pore Volume (cm³/g) 0.002020 0.003845 0.006015 0.007677 0.010490 0.014046 0.017207 0.018929 0.021399 0.024322 0.026509 0.028410 0.030640 0.036671 0.044022 0.052429 0.059364 0.069561 0.082503 0.107651 0.167971 0.181566 0.228258 0.244933 0.256174 0.260783 0.262902 Incremental Pore Area (m²/g) 0.033 0.044 0.068 0.060 0.130 0.222 0.269 0.181 0.302 0.417 0.356 0.342 0.440 1.429 2.182 3.120 3.046 5.183 7.509 16.352 43.195 10.252 37.705 14.860 10.927 4.843 2.434 Cumulative Pore Area (m²/g) 0.033 0.076 0.145 0.205 0.335 0.558 0.826 1.007 1.308 1.726 2.082 2.424 2.865 4.293 6.475 9.596 12.641 17.824 25.333 41.684 84.879 95.131 132.836 147.696 158.622 163.465 165.899 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 21 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption Cumulative Pore Volume (Larger) User-Defined : Standard BJH Desorption Cumulative Pore Volume (Larger) BJH Desorption dV/dlog(D) Pore Volume 1.4 0.25 1.2 0.20 Pore Volume (cm³/g) 0.15 0.8 0.6 0.10 0.4 0.05 0.2 0.00 0.0 10 50 Pore Diameter (nm) 100 dV/dlog(D) Pore Volume (cm³/g) 1.0 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 22 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption dV/dlog(D) Pore Volume User-Defined : Standard Ni/y-Al2O3 1.4 1.2 dV/dlog(D) Pore Volume (cm³/g) 1.0 0.8 0.6 0.4 0.2 0.0 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 23 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption dV/dD Pore Volume User-Defined : Standard Ni/y-Al2O3 0.11 0.10 0.09 dV/dD Pore Volume (cm³/g·nm) 0.08 0.07 0.06 0.05 0.04 0.03 0.02 0.01 0.00 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 24 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption Cumulative Pore Area (Larger) User-Defined : Standard BJH Desorption Cumulative Pore Area (Larger) BJH Desorption dA/dlog(D) Pore Area 1,000 160 900 140 800 120 Pore Area (m²/g) 100 600 500 80 400 60 300 40 200 20 100 0 10 50 Pore Diameter (nm) 100 dA/dlog(D) Pore Area (m²/g) 700 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 25 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption dA/dD Pore Area User-Defined : Standard Ni/y-Al2O3 80 70 dA/dD Pore Area (m²/g·nm) 60 50 40 30 20 10 10 50 Pore Diameter (nm) 100 Viện Hóa học MicroActive for TriStar II Plus 2.03 Sample: Operator: Submitter: File: Started: Completed: Report Time: Sample Mass: Cold Free Space: Low Pressure Dose: Automatic Degas: MicroActive for TriStar II Plus Version 2.03 Serial # 377 Unit Port Page 26 Ni/y-Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y-Al2O3.SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019 4:44:35 PM 0.3368 g 19.3811 cm³ None No Analysis Adsorptive: Analysis Bath Temp.: Thermal Correction: Warm Free Space: Equilibration Interval: Sample Density: N2 77.350 K No 7.1210 cm³ Measured 10 s 1.000 g/cm³ Comments: Degas 250 C 6h BJH Desorption dA/dlog(D) Pore Area User-Defined : Standard Ni-y-Al2O3 : Ni/y-Al2O3 1,000 900 dA/dlog(D) Pore Area (m²/g) 800 700 600 500 400 300 200 100 10 50 Pore Diameter (nm) 100 ... TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y -Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y -Al2O3. SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019... TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y -Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y -Al2O3. SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019... TriStar II Plus Version 2.03 Serial # 377 Unit Port Page Ni/y -Al2O3 Nguyễn Bá Mạnh HHBM C:\MicroActive for TriStar II Plus\d \Ni-y -Al2O3. SMP 4/20/2019 1:26:56 AM 4/20/2019 3:20:01 PM 4/20/2019