Moi quan he cua hydrocacbon hóa

Thầy Lê Ngọc Cát Băng - THPT Gò Vấp Hóa 11 SƠ ĐỒ LIÊN QUAN GIỮA CÁC HIDROCARBON CH3-CHO CaCO3   CaO   CaC2 CH3 - CH3 Al4C3 12 CH3COONa  CH4  CH  CH   23 C3H8 C CH3 - CH2Cl 10 25 30 CH  CH 34 32 CH2 = CH-OCOCH3 (Vinyl Acetat) 33 15 16 21 CH2 = CHCl 19 20 P.E 18 22 24 CH  C - CH = CH2 31 13 17 CH2 = CH2  CH3CH2OH 11  27 P.V.C AgC  CAg 14 CH2 - CH2 OH OH 29 CH2 = CH – CH = CH2  C4H10 26  28 (n-butan) Cao su Buna HOOC – COOH (axit oxalic) 36 37 C6H5Cl  C6H5OH (phenol) 38 39 35 C6H5NO2  C6H5NH2 (Anilin) 40 T.N.B  41 C6H12 ( ciclohexan) 42 C6H6Cl6 P.V.A CH3 43 44 (Toluen) 45 CH=CH2 46 C6H5COOH (Axit benzoic ) T.N.T 47 P.S  (Stiren) o 1000 C CaCO3   CaC2 +2H2O   CH  CH + Ca(OH)2 CH3COONa CaO + CO2 CaO,t  + NaOH  CH4  + Na2CO3 o xt,t   CH4 C + 2H2   HgSO4  CH3CHO (Aldehid acetic) CH  CH + H2O  80o C Pd/PbCO ,t 2000 C CaO + 3C    3CH4  + 4Al(OH)3 Al4C3 + 12H2O  C3H8 1500 C 2CH4   CH  CH + 3H2 làm lạnh nhanh 10 Ni  CH3 – CH3 CH  CH + 2H2  t 12 t CH2 = CH2 + H2 Ni,    CH3 – CH3  CH3CH2 Cl + HCl CH3CH3 + Cl2 askt 11 CH  CH + 13 ,t   CH3 – CH3 xt CH2 = CH2 + H2 14 15  CH3 – CH2 Cl CH2 = CH2 + HCl  16 17 H2 SO4 loãng CH2 = CH2 + H2O  CH3CH2OH to 18 Lưu hành nội H2   CH2 = CH2 o cracking   to CaC2 + CO CH4 + C2H4 o Rượu  CH2 = CH2 + KCl + H2O C2H5Cl + KOHđ  to H2 SO4 đặc  CH2 = CH2 + H2O CH3CH2OH  180 o C Thầy Lê Ngọc Cát Băng - THPT Gò Vấp Hóa 11 19 CH3CH2OH + HCl CH3CH2 Cl + H2O 21 xt ,t n CH2= CH2   P 23 Hg CH  CH + HCl  CH2 = CH - Cl to 25 2CH  CH    CH2 = CH - C  CH to o ( CH2 - CH2 ) n 20.C2H5Cl 22.3 (P.E) 2 27 2C2H5OH   CH2 = 450 o C 26.CH CH - CH = CH2 +H2 Al O CH2 = CH2 + 2KMnO4 + 4H2O  C2H4(OH)4 + MnO2 + KOH xt ,t , p n CH2 = CH - Cl  ( CH2 - CH ) n Cl 24 NH Cl ,CuCl o t C + NaOH   CH3CH2OH + NaCl 28.n Pd/PbCO ,t  C – CH = CH2 + H2   CH2 = CH - CH = CH2 o Na,t CH2 = CH - CH = CH2   P +2H2O 29 ( CH2 - CH = CH - CH2 ) n Ni CH2 = CH - CH = CH2 + H2   tO 30.CH  CH + 2AgNO3 + 2NH3  AgC  CAg  + NH4NO3 32.CH  CH + CH3COOH  CH2 = CH -OCOCH3 CH3 - CH2 - CH2 - CH3 31 33 AgC  Cag + 2HCl  CH  CH + 2AgCl  o xt ,t n CH2 = CH - OCOCH3   P ( CH2 - CH )n OCOCH3 34 CH  CH + KMnO4 + H2O 35 CH  CH   HOOC - COOH + MnO2 + KOH C hoạt tính   600 o C (C6H6 : benzen ) Fe,t  C6H6 + Cl2   C6H5Cl + HCl t , p 37 C6H5Cl + NaOH  C6H5OH + NaCl 36 H2 SO4 đặc C6H6 + HNO3đ   C6H5NO2 + H2O Fe  HCl 39 C6H5NO2 + [H]   C6H5NH2 + 2H2O 38 NO2 40 H2 SO4 đặc   C6H5NO2 + 2HNO3đ + 2H2O NO2 O2N 41 t C6H6 + 3H2 Ni,    C6H12 42 C6H6 + 3Cl2 askt  43 AlCl3  C6H5CH3 + HCl C6H6 + CH3Cl  to 44 đặc C6H5CH3 + 3[O]   C6H5COOH + H2O C6H6Cl6 (6.6.6) KMnO O2N 45 C6H5CH3 + 3HNO3đ CH3 NO2 H2 SO4 đặc   + H2O NO2 46 AlCl3  C6H5 - CH= CH2 + HCl C6H6 + CH2 = CH - Cl  to 47 xt ,t , p n C6H5 - CH= CH2  ( CH - CH2 )n C6H5 Lưu hành nội ( P.S: poli Stiren)