Materials Science and Engineering Handbook [CRC Press 2001] Episode 3 pptx

Shackelford & Alexander Thermodynamic and Kinetic Data 217 Barium nitrate Ba(NO 3 ) 2 594.8 Barium oxide BaO 1922.8 Barium phosphate Ba 3 (PO 4 ) 2 1727 Barium sulfate BaSO 4 1350 Beryllium Be 1278 Beryllium bromide BeBr 2 487.8 Beryllium chloride BeCl 2 404.8 Beryllium oxide BeO 2550.0 Bismuth Bi 271 Bismuth trichloride BiCl 3 223.8 Bismuth trifluoride BiF 3 726.0 Bismuth trioxide Bi 2 O 3 815.8 Boron B 2300 Boron tribromide BBr 3 –48.8 Boron trichloride BCl 3 –107.8 Boron trifluoride BF 3 –128.0 Boron trioxide B 2 O 3 448.8 Bromine Br 2 –7.2 Bromine pentafluoride BrF 5 –61.4 Cadmium Cd 320.8 Cadmium bromide CdBr 2 567.8 Cadmium chloride CdCl 2 567.8 Cadmium fluoride CdF 2 1110 Cadmium iodide CdI 2 386.8 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 2 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 217 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 218 Cadmium sulfate CdSO 4 1000 Calcium Ca 851 Calcium bromide CaBr 2 729.8 Calcium carbonate CaCO 3 1282 Calcium chloride CaCl 2 782 Calcium fluoride CaF 2 1382 Calcium metasilicate CaSiO 3 1512 Calcium nitrate Ca(NO 3 ) 2 560.8 Calcium oxide CaO 2707 Calcium sulfate CaSO 4 1297 Carbon dioxide CO 2 –57.6 Carbon monoxide CO –205 Cyanogen C 2 N 2 –27.2 Cyanogen chloride CNCl –5.2 Cerium Ce 775 Cesium Cs 28.3 Cesium chloride CsCl 38.5 Cesium nitrate CsNO 3 406.8 Chlorine Cl 2 –103±5 Chromium Cr 1890 Chromium (II) chloride CrCl 2 814 Chromium (III) sequioxide Cr 2 O 3 2279 Chromium trioxide CrO 3 197 Cobalt Co 1490 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 3 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 218 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 219 Cobalt (II) chloride CoCl 2 727 Copper Cu 1083 Copper (II) chloride CuCl 2 430 Copper (I) chloride CuCl 429 Copper(l) cyanide Cu 2 (CN) 2 473 Copper (I) iodide CuI 587 Copper (II) oxide CuO 1446 Copper (I) oxide Cu 2 O 1230 Copper (I) sulfide Cu 2 S 1129 Dysprosium Dy 1407 Erbium Er 1496 Europium Eu 826 Europium trichloride EuCl 3 622 Fluorine F 2 –219.6 Gadolinium Gd 1312 Gallium Ga 29 Germanium Ge 959 Gold Au 1063 Hafnium Hf 2214 Holmium Ho 1461 Hydrogen H 2 –259.25 Hydrogen bromide HBr –86.96 Hydrogen chloride HCl –114.3 Hydrogen fluoride HF 83.11 Hydrogen iodide HI –50.91 Hydrogen nitrate HNO 3 –47.2 Hydrogen oxide (water) H 2 O 0 Deuterium oxide D 2 O 3.78 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 4 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 219 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 220 Hydrogen peroxide H 2 O 2 –0.7 Hydrogen selenate H 2 SeO 4 57.8 Hydrogen sulfate H 2 SO 4 10.4 Hydrogen sulfide H 2 S –85.6 Hydrogen sulfide, di– H 2 S 2 –89.7 Hydrogen telluride H 2 Te –49.0 Indium In 156.3 lodine I 2 112.9 lodine chloride ( α) ICl 17.1 lodine chloride ( β) ICl 13.8 Iron Fe 1530.0 Iron carbide Fe 3 C 1226.8 Iron (III) chloride Fe 2 Cl 6 303.8 Iron (II) chloride FeCl 2 677 Iron (II) oxide FeO 1380 Iron oxide Fe 3 O 4 1596 Iron pentacarbonyl Fe(CO) 5 –21.2 Iron (II) sulfide FeS 1195 Lanthanum La 920 Lead Pb 327.3 Leadbromide PbBr 2 487.8 Lead chloride PbCl 2 497.8 Lead fluoride PbF 2 823 Lead iodide PbI 2 412 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 5 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 220 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 221 Lead molybdate PbMoO 4 1065 Lead oxide PbO 890 Lead sulfate PbSO 4 1087 Lead sulfide PbS 1114 Lithium Li 178.8 Lithium bromide LiBr 552 Lithium chloride LiCl 614 Lithium fluoride LiF 896 Lithium hydroxide LiOH 462 Lithium iodide LiI 440 Lithium metasilicate Li 2 SiO 3 1177 Lithium molybdate Li 2 MoO 4 705 Lithium nitrate LiNO 3 250 Lithium orthosilicate Li 4 SiO 4 1249 Lithium sulfate Li 2 SO 4 857 Lithium tungstate Li 2 WO 4 742 Lutetium Lu 1651 Magnesium Mg 650 Magnesium bromide MgBr 2 711 Magnesium chloride MgCl 2 712 Magnesium fluoride MgF 2 1221 Magnesium oxide MgO 2642 Magnesium silicate MgSiO 3 1524 Magnesium sulfate MgSO 4 1327 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 6 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 221 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 222 Manganese Mn 1220 Manganese dichloride MnCl 2 650 Manganese metasilicate MnSiO 3 1274 Manganese (II) oxide MnO 1784 Manganese oxide Mn 3 O 4 1590 Mercury Hg –39 Mercury bromide HgBr 2 241 Mercury chloride HgCl 2 276.8 Mercury iodide HgI 2 250 Mercury sulfate HgSO 4 850 Molybdenum Mo 2622 Molybdenum dichloride MoCl 2 726.8 Molybdenum hexafluoride MoF 6 17 Molybdenum trioxide MoO 3 795 Neodymium Nd 1020 Neon Ne – 248.6 Nickel Ni 1452 Nickel chloride NiCl 2 1030 Nickel subsulfide Ni 3 S 2 790 Niobium Nb 2496 Niobium pentachloride NbCl 5 21 l Niobium pentoxide Nb 2 O 5 1511 Nitric oxide NO –163.7 Nitrogen N 2 –210 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 7 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 222 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 223 Nitrogen tetroxide N 2 O 4 –13.2 Nitrous oxide N 2 O –90.9 Osmium Os 2700 Osmium tetroxide (white) OsO 4 41.8 Osmium tetroxide (yellow) OsO 4 55.8 Oxygen O 2 –218.8 Palladium Pd 1555 Phosphoric acid H 3 PO 4 42.3 Phosphoric acid. hypo– H 4 P 2 O 6 54.8 Phosphorus acid, hypo– H 3 PO 2 17.3 Phosphorus acid, ortho– H 3 PO 3 73.8 Phosphorus oxychloride POCl 3 1.0 Phosphorus pentoxide P 4 O 10 569.0 Phosphorus trioxide P 4 O 6 23.7 Phosphorus, yellow P 4 44.1 Platinum Pt 1770 Potassium K 63.4 Potassium borate, meta– KBO 2 947 Potassium bromide KBr 742 Potassium carbonate K 2 CO 3 897 Potassium chloride KCl 770 Potassium chromate K 2 CrO 4 984 Potassium cyanide KCN 623 Potassium dichromate K 2 Cr 2 O 7 398 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 8 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 223 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Thermodynamic and Kinetic Data CRC Handbook of Materials Science & Engineering 224 Potassium fluoride KF 875 Potassium hydroxide KOH 360 Potassium iodide Kl 682 Potassium nitrate KNO 3 338 Potassium peroxide K 2 O 2 490 Potassium phosphate K 3 PO 4 1340 Potassium pyro– phosphate K 4 P 2 O 7 1092 Potassium sulfate K 2 SO 4 1074 Potassium thiocyanate KSCN 179 Praseodymium Pr 931 Rhenium Re 3167±60 Rhenium heptoxide Re 2 O 7 296 Rhenium hexafluoride ReF 6 19.0 Rubidium Rb 38 .9 Rubidium bromide RbBr 677 Rubidium chloride RbCl 717 Rubidium fluoride RbF 833 Rubidium iodide Rbl 638 Rubidium nitrate RbNO 3 305 Samarium Sm 1072 Scandium Sc 1538 Selenium Se 217 Seleniumoxychloride SeOCl 3 9.8 Silane, hexaHuoro– Si 2 F 6 –28.6 Silicon Si 1427 Silicon dioxide (Cristobalite) SiO 2 1723 Silicon tetrachloride SiCl 4 –67.7 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 9 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 224 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC Shackelford & Alexander Thermodynamic and Kinetic Data 225 Silver Ag 961 Silver bromide AgBr 430 Silver chloride AgCl 455 Silver cyanide AgCN 350 Silver iodide Agl 557 Silver nitrate AgNO 3 209 Silver sulfate Ag 2 SO 4 657 Silver sulfide Ag 2 S 841 Sodium Na 97.8 Sodium borate, meta– NaBO 2 966 Sodium bromide NaBr 747 Sodium carbonate Na 2 CO 3 854 Sodium chlorate NaClO 3 255 Sodium chloride NaCl 800 Sodium cyanide NaCN 562 Sodium fluoride NaF 992 Sodium hydroxide NaOH 322 Sodium iodide Nal 662 Sodium molybdate Na 2 MoO 4 687 Sodium nitrate NaNO 3 310 Sodium peroxide Na 2 O 2 460 Sodium phosphate, meta– NaPO 3 988 Sodium pyrophosphate Na 4 P 2 O 7 970 Sodiumsilicate,aluminum– NaAlSi 3 O 8 1107 Table 71. MELTING POINTS OF ELEMENTS AND I NORGANIC COMPOUNDS (SHEET 10 OF 13) Compound Formula Melting Point ˚C Source: data from: Weast, R C., Ed., Handbook of Chemistry and Physics, 55th ed., CRC Press, Cleveland, (1974); and Bolz, R. E. and Tuve, G. L., Eds., Handbook of Tables for Applied Engineering Science, 2nd ed., CRC Press, Cleveland, (1973), p.479 . 6.3 Thermodynamics Page 225 Wednesday, December 31, 1969 17:00 ©2001 CRC Press LLC [...]... AgCl AgF AgI 7 03 728 708 831 AgNO3 Ag2O 4 83 Ag2SO4 Ag2S 933 1098 AlBr3 Al4C3 2000 AlCl3 AlF3 1564 AlI AlN Al2O3 464 >2475 232 2 5 73 371 465 Al2(SO4 )3 10 43 Al2S3 BBr3 137 3 B4C BCl3 2720 BF3 BN B2O3 146 30 00 7 23 BS4 6 63 227 166 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC Shackelford & Alexander 229 6 .3 Thermodynamics... 29 63 MoF6 MoI4 290 MoO3 MoSi2 1068 MoS2 NaBr NaC2 NaCl 1458 10 23 9 73 10 73 NaF NaI NaNO3 1267 935 5 83 Na2N 5 73 Na2SO4 Na2S 1157 NbB NbC 37 3 25 53 14 53 >2270 37 70 NbN Nb2O5 232 3 1764 NbSi2 NiBr2 22 03 NiCl3 NiF2 1274 12 73 NiI2 1070 2257 NiO 1 236 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC 234 CRC Handbook of Materials. .. CrB2 Cr3C2 CrN Cr2O3 2168 1770 >26 03 CrSi2 CuBr CuCl CuF2 18 43 777 695 1129 CuI Cu3N 878 5 73 Cu2O Cu4Si 1508 Cu2S FeBr2 1400 Fe3C FeCl2 2110 FeF3 Fe2O3 >1275 Fe2(SO4 )3 FeS InBr3 21 23 11 23 955 945 1864 7 53 1468 InCl InF3 709 498 14 43 InI3 4 83 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC 232 CRC Handbook of Materials. .. 135 3 > 635 11 53 2508 SrBr2 SrC2 916 >1970 SrCl2 SrF2 1148 SrI2 Sr(NO3)2 5 93 SrO SrSO4 SrS TaB TaBr5 TaC 1 736 6 43 2 933 1878 >2275 >2270 538 38 13 TaCl5 TaF5 489 Ta2N Ta2O5 33 60 37 0 2100 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC 236 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics Page 237 Wednesday,... Zr(SO4)2 ZrS2 CERAMICS (K) 8 73 331 3 >625 35 33 6 23 8 73 772 32 50 31 23 6 83 18 23 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC Shackelford & Alexander 239 6 .3 Thermodynamics Page 240 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic Data Table 73 HEAT OF FUSION FOR ELEMENTS AND INORGANIC COMPOUNDS (SHEET... CdI2 Cd(NO3)2 10 03 1055 6 23 841 137 3 4 23 CdO CdSO4 834 17 73 12 73 CdS CeB6 20 23 24 63 CeCl3 CeF2 1095 CeI3 CeO2 1025 CeS Ce(SO4)2 1710 >28 73 2400 468 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC Shackelford & Alexander 231 6 .3 Thermodynamics Page 232 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic... cal/g cal/g mole –0.7 57.8 10.4 –85.6 8.58 23. 8 24.0 16.8 2920 34 50 236 0 56 83 –89.7 –49.0 27 .3 12.9 1805 1670 156 .3 6.8 781 112.9 14 .3 3650 ICl ICl 17.1 13. 8 16.4 13. 3 2660 2270 Fe Fe3C 1 530 .0 63. 7 35 60 1226.8 68.6 1 233 0 Fe2Cl6 FeCl2 FeO Fe3O4 30 3.8 677 63. 2 61.5 20500 7800 138 0 (107.2) (7700) 1596 142.5 33 000 Fe(CO)5 FeS La Pb –21.2 16.5 32 50 1195 920 32 7 .3 56.9 17.4 5.9 5000 2400 1224 For heat of... Thermodynamics Page 230 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic Data Table 72 MELTING POINTS OF (SHEET 2 OF 11) Compound CERAMICS (K) BaB4 BaBr2 BaCl2 25 43 BaF2 1627 BaI2 Ba(NO3)2 10 13 BaO BaSO4 11 23 1 235 865 22 83 18 53 BaS BeB2 14 73 >22 43 BeBr2 Be2C 7 93 > 237 5 BeCl2 BeF2 BeI2 7 13 Be3N2 25 13 BeO BeSO4 2725 848 491 BiBr3 BiCl3 8 13 7 83 507 BiF3 BiI3 B2O3 1000 Bi(SO4 )3 678 681 1098 Source:... 947 VSi2 20 23 V2S3 >875 31 33 2900 548 WB WC WCl6 WO3 WSi2 WS2 1744 ZnBr2 667 ZnCl2 ZnF2 ZnI2 ZnO 232 0 15 23 548 1145 719 2248 Source: data from: Lynch, Charles T., Ed., CRC Handbook of Materials Science, Vol 1, CRC Press, Boca Raton, 1974, 34 8 ©2001 CRC Press LLC 238 CRC Handbook of Materials Science & Engineering 6 .3 Thermodynamics Page 239 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic... Materials Science & Engineering 6 .3 Thermodynamics Page 235 Wednesday, December 31 , 1969 17:00 Thermodynamic and Kinetic Data Table 72 MELTING POINTS OF (SHEET 7 OF 11) Compound CERAMICS (K) NiSO4 NiS PbBr2 PbCl2 1121 1070 6 43 PbF2 PbI2 Pb(NO3)2 1095 675 PbO PbSO4 771 7 43 1159 PbS PtBr2 14 43 138 7 5 23 PtCl2 854 PtI2 PtS2 633 508 SbBr3 SbCl3 37 0 SbF3 SbI3 565 4 43 Sb2O3 SbS3 928 SiC SiF4 2970 1 83 Si3N4 SiO2 . 831 AgNO 3 4 83 Ag 2 O 5 73 Ag 2 SO 4 933 Ag 2 S 1098 AlBr 3 371 Al 4 C 3 2000 AlCl 3 465 AlF 3 1564 AlI 464 AlN >2475 Al 2 O 3 232 2 Al 2 (SO 4 ) 3 10 43 Al 2 S 3 137 3 BBr 3 227 B 4 C 2720 BCl 3 166 BF 3 146 BN 30 00 B 2 O 3 7 23 BS 4 6 63 Source:. Alexander Thermodynamic and Kinetic Data 233 In 2 O 3 21 83 In 2 S 3 132 3 KBr 1008 KCl 10 43 KF 1 131 KI 958 KNO 3 610 K 2 O 3 7 03 K 2 SO 4 134 2 K 2 S 11 13 LiBr 8 23 LiCl 8 83 LiF 1119 LiI 722 LiNO 3 527 Li 3 N 1118 Li 2 O >1975 Li 2 SO 4 1 132 Li 2 S 1198 MgBr 2 984 MgCl 2 987 MgF 2 1 535 MgI 2 <910 MgO. 22 83 BaSO 4 18 53 BaS 14 73 BeB 2 >22 43 BeBr 2 7 93 Be 2 C > 237 5 BeCl 2 7 13 BeF 2 8 13 BeI 2 7 83 Be 3 N 2 25 13 BeO 2725 BeSO 4 848 BiBr 3 491 BiCl 3 507 BiF 3 1000 BiI 3 681 B 2 O 3 1098 Bi(SO 4 ) 3 678 Table