GIÁO ÁN 11 NÂNG CAO (HK I)

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iTD}Mw9-9"209 " 2.).:u.),9- 9" QTDDM)H %   α =  QTDD39-9""8 m}-9"!M! ,,:82m QTD`N829-9"!MH9*> 9-2"t",22 3/m QTD+2("88r$%9M.J eA8FeA 8j]/  ^OJaK? / <?Of&7/gh iTD=82"809"1m+09" 1 αim QTD+09"1> d+,G1 d+,\1 IZ QAG|``I+"!9y(,ˆ QTHA>9-,22 I+""# 2 +I Y +ggI Qf")I+"9"1+I Y +ggI IZf,) IZ QfAe2(,,22V Q%‰α≤$ dαi%⇒K), 9"/G3 dαi$⇒K), 9"G32828 Q`N82αG,9:9*>9-2"t"2 QT+I Y +ggI ˆ ˆ† ‡ ˆˆ +I Y +gg Q dI d Y   00 + −     =     i%X%%bYijr$% QY eOV ⇒ [ ] Y  00 vi%%bYQjr$% QY i%%YbeOV IZ QA4),e(V Q}-9"α09"1&$  X X b b X (0  (0 + − → +  e$V  Y X X b Y b e V X Y1 (0 1 (0 + − → +  eXV  X X e V X2 0 2 0 + − → +  eYV 8'995 + - dI7),) QTD2("03H.J982().0)0 QTD+2( ",0 I X Zg b W" X eZg b V Y 6egIV X QTDIa3G,9:>9-2"t",22 .).:6egIV X %XO QTD")3)$&4$%5 $67!885$9 ,$& ^OJa>0/ <?Of&:/gh iTD=82"809"3)m+09" 3) &2282m QTD+09"1> d+,G3)P+,\3)P$()H QTD2("03H.J982().0)0 QTD+2( ",0 I+gggIIhOegIV X QTDIa3G,9:>9-2"t",22 .).:6egIV X %XO QTD") Qh6Vk&OJa dA-.)eZTfV d:$&:$9 d=)E2)34"H)3M.:&; ZQQ"Q4 QTD+2(9" VhE [l&"PQ4m3 Qa<n&OOfOJa/ QTD ;<$9$9$&! ,$&$=>TDTH QI(d [ ] X X e V %X2 2 0 ? + = = d [ ] X X e V %b0 2 0 ? = = IZ QA4),e(V Q}-9"%$ Q 00 00 + + ơ e$V X e V? 0 ?0 0 + + ơ eXV X ?0 ? 0 + + + eYV IZ+I Y +ggI +I Y +gg Q dI d [ ] Y Y Y 00 00 ; 00 + = /Gb =YcQ 1" 60`a382.#93w>09"1 WI6A X ZOegIV X A X +g Y IAg Y I X Zg b fgIf X Zg Y +IhI X Zg b AgIW Y <g b `fgIAgI+egIV X +I Y +ggI. 60#=2.).:>1&() 00 00 + + ơ =,9-82()93(n"89-9"G22.).:"8 W<"2a =48 I+" +Al8 AgI `+ 838X7 607/Dung dũch CH 3 COOH 0,1M coự ủoọ ủieọn li =1%. vaọy dung dũch CH 3 COOH coự pH baống: A. 1 ; B. 2 ; C. 3 D. 4 ; 60: +!-.).:09"3)39L>9-.).: W}-9"8&(9"9)39L 6}-9"8&(9"9)/9L }-9"39L&(9"/9L `}-9"/9L&(9"39L 60; +),M)9'2,)()93 W+w!*02#:9"v2# 6}-9"wJ)-82009" +}-9"09"3)!M&$ -D#09"3)9-9": =4d3 1" +)$=82"8G\)E2)3WQ4QQ)8E2)362Q(4m 8'996   +)X=82"8G\-0)0m"03H.J8 9"m +)YD "G\)8 &(9"m &=>4<?/68Y QQQ2%2QQQ :o;op qir(b    !" & Q=82"8G\E2)3WQ4QQ)8)362Q(4 QO)"8 8(N9") QWGQ\)0 Q6&("G&("\8~B' Q69* 9",G\8) #$%&A&y2(BC() QD.J)3WQ4QQ)8)362Q(49M9*G\ QD9* 9"G\) Q`N82&("G\9MH>9-2I d 82gI Q 2  Q….J-(8!-.)"4K) BC 3 Q`JJHM).•Œ'3  QI!0 AgI I+" AI Y )n8K)•H2c E2""E &045657 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@,C@A= ,0 D =, QTD+2( "GQ \)0e@"21"03$0"8H.JV IZ QA["19:BGQ\R0X QD`e-(0V QD "eYGY\V QA?dWG"2I d 82G d6\"2gI Q 82"21 IZAG| Q+!G"$2I d !G) 2I d  Q+!\"$2gI Q !\ )2gI Q  IZD " e$VdI X +g Y  ˆ ˆ† ‡ ˆˆ  Y 0 − dI d d Y 0 −  ˆ ˆ† ‡ ˆˆ  X Y 0 − dI d eXVdOgIV X  ˆ ˆ† ‡ ˆˆ  e V? 0 + dgI Q d e V? 0 + ˆ ˆ† ‡ ˆˆ  X ? + dgI Q 8'997    vwEE=, +BF, , 7OZ<Ta[x&I / <?Of&7/ QTD=8H G'd)q Xd →12+X782X dŒ$d8 G dŒXd+2 G'82 +2 ( K) (,8 '  ")   Hm QTDf") QTD=E2WQ4QQ) 92G"•H "E2XM)M)G8M)\ QTD;03H.J d X X e V XG 0 G 0 + − → + ¬  fM)\ d X X X e V XG 0 G0  − + → + ¬  fM)G  vw+,92G"•H9)H2 #=G8H\'9)3) )Ayqr(s j]+i./ S & $Q/ <?Of&:gh/ QTD=8H AI Y  dK)•H +2(K)(,8Hme`N820) 128)3WQ4QQ)V iTD/`N82)362Q(49MH   6\ \ QTD=NH2+I Y +ggI QTDD3G\E262Q(4(n"8 QTDIa3,2 Y 0 −  Y  (0 − ( − "8,2"•H QTDf") d Y 0 − Y (0 − ( − HFI>H FI>J ⇒ ,K4 ' L 0FM$FCNO  L 0,K4- '1FMAP '0OzK"PQ 0>Z<i4L/ i TD Ia3! [  )9M  )3 62Q(4m QTD+Q6O !N8 6O=R%IL N8$=8*I- {.b8qr( k&45QTgh <?Of&;gh/ QTDIa3 ",G 3)8M)&("'m Q  TD   +      Y  00 −      [ ] Y  00 "8 IZAG| Q G'd )n→![G)0  X X X e V0 G G 0 − + + → ↓ QŒ$8X9)⇒qegIV X 9), .J9*#G#\e!M(9* V X X X e V X XG 0  G  0 + + + → + X X X X e V X XG 0 0 G0  0 − − + → +   v w #85 ),E $F G ; 4 H+".  I  J+".  I  +".  I  #(+".  I B$+". / I#,+". / I IZAG| Q{)•H)3M(8)>⇒AI Y "8\ Q=E2)3WQ4QQ)/H9* IZ @BE$595FK4, @&;L$5904, @#9$FMG$593N;5<:=>5 33N;5<:=>04,  IZD 2E"E29M  IZ i   0> iZLii0 " | Ov& Y\ M0&  K} [\" i 0>  Z<i.L~& •0R XU  R3M€& K1M0&K} IZ;03H.J8 +I Y +ggI → ¬  +I Y +gg Q dI d  [ ] Y Y    00 ;  00 + −         = 8'998 + -   >9-"'& QTDa02 ';  :S-TU;  V9 I,&$9- ';  W)N8- #k&45VQWXgh <?Of&pgh/ QTDIa3M)&("AI Y QTD  Y       b  +      0 −     "8>9-"' & QTDa02  ';   :S-TU;   V 9I,&$9- ';  W)N8- b S & $Q <?Of&•gh/ QTDIa32)"8 mfM4-8 )uc84)H0!3) )m #.mOJa"PQK05Z<&[\" <?Of&‚/ Q+2( " -( )!4  vw/.6+)8#  @%W-  XY  , W $F $&  E-  [ ] Y Y Y   0  00 ;  00 + −         = IZ;03H.J8   [ ] b Y   0 ;  + −         = IZ QO)"8*02#" 2"21e2c2 b  + V8G QD`AI+g Y W" X eZg b V Y f X +g Y OeI+g Y V X  Q=H0 ŠŠŠŠŠŠŠŠŠŠŠŠŠŠŠŠŠŠŠ QIZD9" AI+g Y → W" X eZg b V Y →  f X +g Y → Gb 60< 82()939*M).•9'  X X Y Y X 0  0 + − → +  6    + − → + ¬  + 0  0 + − → + ¬  ` Y X b   0  0 + − + → +  60#=2.).:>1&() 00  00 + − → + ¬  =,9-82()93(n"89-9"G‹22.).:"8 W<"2a =48 I+" +Al8 AgI `+ 838X7 607<82.#93/"8GQ\ WI+"dfgI→ I X Zg b d6+" X → +I X Zg b d+g→ `IAg Y d+)egIV X 60:<  X X X(   ( − + + → ↑ "8 ) WhEZdXI+"→hE+" X dI X Z 6AIZg b dA X Z→XA X Zg b dI X Z f X ZdXI+"→f+"dI X Z 66ZdI X Zg b →6Zg b dI X Z 60;+2,c0() eSVA X +g Y d6+" X eSSVeAI b V X +g Y d6eAg Y V X eSSSV6eI+g Y V X df X +g Y eSDV6+" X dO+g Y Ac02p 2'"8 WeSV 6eSVeSSV eSVeSSVeSSSV `eSVeSSVeSSSVeSDV 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có tính oxi hóa, vừa có tính khử  HS: Trả lời t 0 , p , xt  → N2 + 3.H2 ¬  2.NH3 + Q (∆H = -92KJ)  - Soxh -3, pư tḥn nghịch và tỏa nhiệt N 2 là chất khư (vì nhường e)  HS: Viết phản ứng và trả lời như trên: 27 GIÁO ÁN 11 NÂNG CAO Sơn 2 Tính khử... CO3 , Zn(OH ) 2 D tất cả đều sai C Al (OH ) 3 , Zn(OH ) 2 + C Br − , NH 4 D Tất cả đều sai D Na + , Br − 14 GIÁO ÁN 11 NÂNG CAO GV: Đặng Kim Sơn Đề dùng cho câu 8-9: Trộn 250 ml dung dòch hỗn hợp gồm HCl và H 2SO4 có pH = 2 với 250 ml dung dòch Ba(OH)2 có pH = 13 thì thu được 0 ,116 5 gam kết tủa Câu 8: Vậy nồng độ mol/l của mỗi axit trong hỗn hợp ban đầu là: A) 0,003M và 0,001M B) 0,0045M và 0,0015M... trong nước khơng làm thay đổi pH của dung dịch: 4: A Na2SO4 D.CH3COOH  Bài sắp học: Làm bài tập trong sách bài tạp chuẩn bị tiết sau ḷn tập LƯU HÀNH NỢI BỢ 16 GIÁO ÁN 11 NÂNG CAO Sơn Ngày soạn: Tiết 11 GV: Đặng Kim Bài 7 / 09 / 200 -o0o - LỤN TẬP PHẢN ỨNG TRAO ĐỔI ION TRONG DUNG DỊCH CÁC CHẤT ĐIỆN LI  I MỤC TIÊU BÀI HỌC 1 Kiến thức  Củng cơ - Kiến thức về phản... các loại phản ứng khác) - Vận dụng giải mợt sớ bài tập cơ bản và nâng cao về: Toán nờng đợ, toán pH của dung dịch, pha loãng dung dịch, hiđroxit lưỡng tính, hằng sớ axit-bazơ II CH̉N BỊ:  GV: - Đề kiểm tra (tự ḷn và lí thút)  Học sinh: - Xem lại nợi dung kiến thức cơ bản và nâng cao của chương I (sách giáo khoa, sách bài tập, vở học, đề cương và sách... đây, cặp chất nào cùng tồn tại trong cùng một dung dòch ? LƯU HÀNH NỢI BỢ 22 GIÁO ÁN 11 NÂNG CAO GV: Đặng Kim Sơn A NaAlO2 và KOH B NaOH và NaHCO3 C NaCl và AgNO3 D AlCl3 và Na2CO3 BÀI TẬP TỰ LUẬN 21 Cho 225 ml dung dòch NaOH a M tác dụng với 340 ml dung dòch AlCl 3 0,5 M Sau khi phản ứng kết thúc ta thu được 11, 7 gam kết tủa keo trắng Hãy xác đònh nồng độ mol/l (a) của dung dòch NaOH đem dùng 22... A thu được dd D có pH = 2 Cho biết (H =1 , N = 14 , O = 16 , S = 32 , Ca = 40 , Ba = 137 , Na = 23 , Cl = 35,5 , C = 12 , K = 39) LƯU HÀNH NỢI BỢ 23 GIÁO ÁN 11 NÂNG CAO Sơn GV: Đặng Kim Đáp án trắc nghiệm 01 - / - - 06 - / - - 11 - - - ~ 16 - - = - 02 ; - - - 07 - - = - 12 ; - - - 17 - / - - 03 - / - - 08 - / - - 13 ; - - - 18 ; - - - 04 - - = - 09 - - - ~ 14 - - = - 19 - - - ~ 05 ; - - -... xác định Ở 250C + − −14 2 2 Thì:  H  OH  = 1, 0.10 ( mol / l )     - GV: Kết ḷn: (3) HS: 1, 0.10−14 1, 0.10−14 H +  = OH −  =   OH −  và   H +      11 LƯU HÀNH NỢI BỢ + - GIÁO ÁN 11 NÂNG CAO GV: Đặng Kim Sơn 2 Ý nghĩa tích sơ ion của nước.(trọng tâm)  HS: 2 lít HCl có hòa tan 0,02 mol HCl  Hoạt đợng 3: ngun chất Tìm nờng đợ mol/l của HCl và các K... của nitơ dự đoán tính chất hóa học của NH 3 (tính khư và tính bazơ ́u) Viết phương trình phản ứng hóa học để minh họa ? LƯU HÀNH NỢI BỢ 28 GIÁO ÁN 11 NÂNG CAO Sơn Ngày soạn / /200 Tiết GV: Đặng Kim Bài 11 AMONIAC VÀ ḾI AMONI  I MỤC TIÊU BÀI HỌC 1 Kiến thức  Biết: - Cấu tạo và tính chất vật lí của amoniac, tính chất vật lí của ḿi amoni - Vai trò quang... MgCO3, Na2SO4 D BaCO3, MgSO4, NaNO3 IV: HƯỚNG DẪN BÀI MỚI: Câu 1: Thảo ḷn về bài thực hành lụn tập: Câu 2: Cho thảo ḷn trước bài thí nghiệm thực hành? LƯU HÀNH NỢI BỢ 18 GIÁO ÁN 11 NÂNG CAO Sơn Ngày soạn: Tiết 12 GV: Đặng Kim Bài 8 / 09 / 200 -o0o - BÀI THỰC HÀNH: TÍNH AXIT-BAZƠ PHẢN ỨNG TRONG DUNG DỊCH CHẤT ĐIỆN LI  I MỤC TIÊU BÀI HỌC 1 Kiến thức - Củng cớ các... Do: HCl → H+ + Cl+ + NH 4 Cl  NH 4 + Cl − → +  → NH 4 + H 2O ¬  NH 3 + H 3O +   Thí nghiệm b: dd CH3COONa, dd NaOH nhỏ vào quỳ tím - Hiện tượng: Quỳ tím sang màu xanh 19 GIÁO ÁN 11 NÂNG CAO Sơn - GV: Quan sát theo dỡi hướng dẫn kịp thời cách tiến hành của học sinh  Hoạt đợng 3:  HS: Tiến hành thí nghiệm 2: - Tiến hành: a Cho 2 ml dd Na2CO3 + dd CaCl2 + quan sát .  8'99 11 + -   #ˆ&. hỗn hợp gồm HCl và H 2 SO 4 có pH = 2 với 250 ml dung dòch Ba(OH) 2 có pH = 13 thì thu được 0 ,116 5 gam kết tủa. 60‚Vậy nồng độ mol/l của mỗi axit trong hỗn hợp ban đầu là: A) 0,003M và 0,001M