(Luận văn) nghiên cứu tổng hợp vật liệu composite ag3vo4 bivo4 ứng dụng làm chất xúc tác quang phân hủy các chất hữu cơ ô nhiễm trong môi trường nước

BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC QUY NHƠN ĐINH THỊ HỒNG VÂN lu an va n to p ie gh tn NGHIÊN CỨU TỔNG HỢP VẬT LIỆU COMPOSITE Ag3VO4/ BiVO4 ỨNG DỤNG LÀM CHẤT XÚC TÁC QUANG PHÂN HỦY CÁC CHẤT HỮU CƠ Ô NHIỄM TRONG MÔI TRƯỜNG NƯỚC oa nl w d ul nf va an lu oi lm at nh LUẬN VĂN THẠC SĨ HÓA HỌC z z gm @ om l.c Lu an Bình Định – Năm 2019 n va ac th si BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC QUY NHƠN ĐINH THỊ HỒNG VÂN lu an va n to p ie gh tn NGHIÊN CỨU TỔNG HỢP VẬT LIỆU COMPOSITE Ag3VO4/ BiVO4 ỨNG DỤNG LÀM CHẤT XÚC TÁC QUANG PHÂN HỦY CÁC CHẤT HỮU CƠ Ô NHIỄM TRONG MÔI TRƯỜNG NƯỚC oa nl w d ul nf va an lu Chun ngành: Hóa vơ Mã số: 8440113 oi lm nh at Người hướng dẫn 1: PGS.TS Nguyễn Thị Diệu Cẩm Người hướng dẫn 2: TS Phạm Thanh Đồng z z gm @ om l.c Lu an n va ac th si LỜI CAM ĐOAN Tôi xin cam đoan cơng trình kết nghiên cứu riêng Các số liệu, kết nêu luận văn trung thực chưa công bố cơng trình nghiên cứu Tác giả luận văn Đinh Thị Hồng Vân lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac th si LỜI CẢM ƠN Em xin bày tỏ lịng biết ơn sâu sắc tới giáo PGS.TS Nguyễn Thị Diệu Cẩm thầy giáo TS Phạm Thanh Đồng tận tình hướng dẫn, giúp đỡ, bảo động viên em hoàn thành tốt luận văn Trong trình thực luận văn, em nhận nhiều quan tâm tạo điều kiện Thầy, Cô Khoa Khoa học Tự nhiên Khu thí nghiệm thực hành A6 – Trường Đại học Quy Nhơn Em xin bày tỏ lòng cảm ơn chân thành tới quý Thầy, Cô lu Em xin chân thành cảm ơn gia đình, bạn bè tập thể lớp Cao học Hóa an va K20 ln động viên, khích lệ tinh thần suốt q trình học tập n to nghiên cứu khoa học gh tn Mặc dù cố gắng thời gian thực luận văn cịn p ie hạn chế kiến thức thời gian, kinh nghiệm nghiên cứu nên khơng tránh khỏi thiếu sót Em mong nhận thông cảm ý nl w kiến đóng góp quý báu từ quý Thầy, Cơ để luận văn hồn thiện oa d Em xin chân thành cảm ơn! va an lu ul nf Tác giả luận văn oi lm at nh Đinh Thị Hồng Vân z z gm @ om l.c Lu an n va ac th si MỤC LỤC LỜI CAM ĐOAN LỜI CẢM ƠN MỤC LỤC DANH MỤC CÁC KÝ TỪ VIẾT TẮT DANH MỤC BẢNG BIỂU 10 DANH MỤC HÌNH ẢNH 11 MỞ ĐẦU lu an Lý chọn đề tài va Mục tiêu đề tài n to Đối tượng phạm vi nghiên cứu tn ie gh Phương pháp nghiên cứu p Nội dung nghiên cứu Cấu trúc luận văn nl w oa Chương TỔNG QUAN LÝ THUYẾT d 1.1 Giới thiệu vật liệu xúc tác quang an lu 1.1.1 Khái niệm xúc tác quang chế phản ứng va ul nf 1.1.2 Tổng quan tình hình nghiên cứu vật liệu xúc tác quang Ag VO oi lm BiVO nh 1.2 Giới thiệu bismuth orthovanadate 11 at 1.2.1 Đặc điểm cấu tạo đặc tính BiVO 11 z z 1.2.2 Các phương pháp tổng hợp BiVO 14 @ gm 1.2.3 Ứng dụng BiVO4 17 om l.c 1.2.4 Cơ chế quang xúc tác vật liệu BiVO 18 1.3 Giới thiệu bạc vanadat (Ag3VO4) 20 Lu an 1.3.1 Cấu tạo Ag3 VO4 20 n va ac th si 1.3.2 Cơ chế quang xúc tác Ag3 VO4 21 1.3.3 Phương pháp tổng hợp Ag3 VO 23 1.3.4 Tiềm ứng dụng Ag3 VO 24 1.4 Giới thiệu rhodamine B 26 1.5 Giới thiệu chất kháng sinh tetracycline hydrochloride 27 Chương THỰC NGHIỆM 29 2.1 Hóa chất dụng cụ 29 2.1.1 Hóa chất 29 lu an 2.1.2 Dụng cụ 29 va 2.2 Tổng hợp vật liệu xúc tác quang 29 n to 2.2.1 Tổng hợp vật liệu BiVO4 phương pháp thủy nhiệt 29 tn gh 2.2.2 Tổng hợp vật liệu Ag3 VO4 30 p ie 2.2.3 Tổng hợp vật liệu composie Ag VO4 /BiVO4 phương pháp nl w khuấy trộn, siêu âm 30 oa 2.3 Các phương pháp đặc trưng vật liệu 31 d 2.3.1 Phương pháp nhiễu xạ Rơnghen 31 an lu va 2.3.2 Phương pháp hiển vi điện tử quét 32 ul nf 2.3.3 Phương pháp phổ hồng ngoại 33 lm 2.3.4 Phương pháp phổ phản xạ khuếch tán tử ngoại khả kiến (UV- oi at nh Visible Diffuse Reflectance Spectroscopy) 34 z 2.3.5 Phương pháp phổ lượng tia X hay EDS (Energy Dispersive z @ X-ray) 37 gm 2.3.6 Phương pháp đẳng nhiệt hấp phụ - khử hấp phụ N2 (BET) 39 om l.c 2.3.7 Phương pháp phổ huỳnh quang (PL – Photoluminescence) 41 2.4 Khảo sát hoạt tính quang xúc tác vật liệu 44 Lu an 2.4.1 Khảo sát thời gian đạt cân hấp phụ 44 n va ac th si 2.4.2 Khảo sát hoạt tính quang xúc tác vật liệu tổng hợp 44 2.4.3 Phân tích định lượng RhB 45 2.4.4 Phân tích định lượng tetracycline hydrochloride 47 Chương KẾT QUẢ VÀ THẢO LUẬN 49 3.1 Đặc trưng vật liệu khảo sát hoạt tính quang xúc tác Ag3VO4 49 3.1.1 Đặc trưng vật liệu Ag3 VO4 49 3.1.2 Khảo sát hoạt tính xúc tác quang vật liệu Ag3 VO4 54 3.2 Đặc trưng vật liệu khảo sát hoạt tính xúc tác vật liệu composite lu an Ag3VO4/BiVO4 56 va 3.2.1 Đặc trưng vật liệu composite Ag VO4 /BiVO4 tỉ lệ khối lượng n to khác 56 tn gh 3.2.2 Khảo sát hoạt tính quang xúc tác vật liệu composite p ie Ag3 VO 4/BiVO tỉ lệ khối lượng Ag3 VO4 /BiVO4 khác 62 nl w 3.3 Đặc trưng vật liệu composite Ag3VO4/BiVO4 (AB-12) 67 oa 3.3.1 Phương pháp nhiễu xạ tia X 67 d 3.3.2 Phương pháp phổ kích thích electron 68 an lu va 3.3.3 Phương pháp hiển vi điện tử quét 69 ul nf 3.3.4 Phương pháp phổ hồng ngoại 70 lm 3.3.5 Phương pháp đẳng nhiệt hấp phụ - khử hấp phụ N2 71 oi at nh 3.3.6 Phương pháp tán xạ lượng 73 z 3.4 Động học phản ứng quang xúc tác vật liệu Ag3VO4/BiVO4 z @ rhodamine B 74 gm 3.5 Cơ chế trình quang xúc tác 77 om l.c 3.6 Đánh giá khả tái sử dụng vật liệu xúc tác quang 81 KÊT LUẬN VÀ KIẾN NGHỊ 84 Lu an DANH MỤC CƠNG TRÌNH ĐÃ CƠNG BỐ 86 n va ac th si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an DANH MỤC TÀI LIỆU THAM KHẢO 87 DANH MỤC PHỤ LỤC 95 lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an DANH MỤC CÁC KÝ TỪ VIẾT TẮT AO : Ammonium oxalate BQ : 1,4-Benzoquione CB : Conduction Band (vùng dẫn) Eg : Band gap energy (Năng lượng vùng cấm) EDX : Energy-Dispersive X-ray spectroscopy (Phổ tán xạ lu lượng tia X) an va n IR : Infrared (hồng ngoại) RhB : Rhodamine B (rhodamine B) to tn : Scanning Electron Microscopy (kính hiển vi điển tử quét) SEM gh : Tetracycline hydrochlolide p ie TC TBA : Tert-Butyl ancohol nl w : Ultraviolet – Visible Diffuse Reflectance Spectroscopy (tử oa UV-Vis-DRS d an lu ngoại khả kiến) : Valance Band (vùng hóa trị) XRD : X-Ray Diffaction (nhiễu xạ tia X) ul nf va VB oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an DANH MỤC BẢNG BIỂU Số hiệu Trang Tên bảng bảng Độ dài liên kết Bi-O V-O với cấu trúc đơn tinh 1.1 11 thể BiVO4 Tính chất vật lý thông số đơn tinh thể 1.2 12 BiVO4 2.1 Danh mục hóa chất 29 lu Sự phụ thuộc mật độ A vào nồng độ RhB C an 2.2 46 va (mg/L) n to Sự phụ thuộc mật độ quang A vào nồng độ 48 TC C (mg/L) 3.1 Thành phần nguyên tố Ag, O, V mẫu Ag3VO4 53 p ie gh tn 2.3 nl w 3.2 Năng lượng vùng cấm vật liệu Ag3VO4, BiVO4 mẫu composite AB-105, AB-11, 60 oa d AB-12, AB-13 an lu So sánh lượng vùng cấm độ chuyển hóa va RhB vật liệu Ag3VO4, BiVO4 mẫu 65 ul nf 3.3 lm composite AB-105, AB-11, AB-12, AB-13 oi Tóm tắt số tốc độ mẫu Ag3VO4 (e), nh BiVO4 (f), composite AB-105 (a), AB-11(b), AB- z z 12 (c), AB-13 (d) @ Kết hiệu suất phân hủy RhB vật liệu AB- 82 12 AB-12 tái sinh gm 3.5 77 at 3.4 om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 86 DANH MỤC CƠNG TRÌNH ĐÃ CƠNG BỐ [1] Mai Hùng Thanh Tùng, Đinh Thị Hồng Vân, Nguyễn Thị Phương Lệ Chi, Phạm Thanh Đồng, Nguyễn Minh Phương, Nguyễn Văn Nội, Trương Thanh Tâm, Cao Văn Hoàng, Nguyễn Thị Thu Phương, Đặng Nguyên Thoại, Nguyễn Thị Diệu Cẩm, “Tổng hợp vật liệu composite Ag3VO4/BiVO4 có hoạt tính quang xúc tác cao vùng ánh sáng khả kiến”, Tạp chí Phân tích Lý, Hóa Sinh học (đã chấp nhận đăng) lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 87 DANH MỤC TÀI LIỆU THAM KHẢO Tiếng Việt [1] Phạm Ngọc Nguyên (2004) Giáo trình kỹ thuật phân tích Vật Lý, NXB Khoa học Kỹ thuật, Hà Nội [2] Nguyễn Văn Nội (2017), Vật liệu xúc tác quang vùng khả kiến ứng dụng xử lý ô nhiễm môi trường, NXB Đại Học Quốc gia Hà Nội [3] Nguyễn Kim Phi Phụng (2005), Phổ IR sử dụng phân tích hữu cơ, lu NXB Đại học Quốc gia thành phố Hồ Chí Minh an va [4] Trần Văn Sung (2005), Các phương pháp phân tích vật lý hóa học, n Tài liệu giảng môn học, Đại học Đà Nẵng to tn Tiếng Anh gh p ie [5] A A Firooz, A R Mahjoub, A A Khodadadi (2008), "Preparation of SnO2 nanoparticles and nanorods by using a hydrothermal method at low nl w temperature", Materials Letters, 62(2-13), pp 1789–1792 oa d [6] A Fujishim, K.Hashimoto, T Watanabe, “TiO2 photocatalysis an lu fundamentals and applications”, CMC, Co., Ltd 1999 va nf [7] A R Lim, S H Choh and M S Jang (1995), “Prominent ferroelastic ul domain walls in BiVO4 crystal”, J Phys: Condens Matter.,7(37), pp oi lm 7309–7323 nh at [8] B Line , M Cusker (1994), "Advances in powder diffraction methods for z z zeolite structure", Studies in Surface Science and Catalysis., 84, pp 341– @ gm 356 [9] C Ren, J Fan, S Liu, W Li, F Wang, H Li, X Liu, “One-step l.c om hydrothermal synthesis of the novel Ag3VO4/Ag4V2O7 composites for Lu enhancing visible-light photocatalytic performance,” RSC Advances, vol an 6, no 97, pp 95156–95164, 2016 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 88 [10] D N Ke, T Y Peng, L Ma, P Cai, K Dai (2009), “Effects of hydrothermal temperature on the microstructures of BiVO and its photocatalytic O2 evolution activity under visible light”, Inorg Chem., 48, pp 4685–4691 [11] F Kiantazh, A Habibi-Yangjeh, “Ag3VO4/ZnO nanocomposites with an n–n heterojunction as novel visible-light-driven photocatalysts with highly enhanced activity”, Mater Sci Semicond Process 39 (2015) 671-679 lu [12] F Chen, Q Yang, Y Wang, J Zhao, D Wang, X Li, Z Guo, H Wang, an va Y Deng, C Niu, G Zeng (2017), “Novel ternary heterojunction n photcocatalyst of Ag nanoparticles and g-C3N4 nanosheets co to degradation of refractory pollutant”, Applied Catalysis B: p ie gh tn modified BiVO4 for wider spectrum visible-light photocatalytic Environmental., 205, pp 133-147 nl w [13] H Dong, G Chen, J Sun, C Li, Y Yu, and D Chen, “A novel high- oa d efficiency visible-light sensitive Ag2CO3 photocatalyst with universal an lu photodegradation performances: Simple synthesis, reaction mechanism ul 46–54, 2013 nf va and first-principles study,” Appl Catal B Environ., vol 134–135, pp lm oi [14] H M Fan, D J Wang, L L Wang, H Y Li, P Wang, T F Jiang, T at nh F Xie (2011), “Hydrothermal synthesis and photoelectric properties z of BiVO4 with different morphologies: an efficient visible-light z gm @ photocatalyst”, Appl Surf Sci., 257(17), pp 7758–7762 [15] J Barzegar, A Habibi-Yangjeh, A Akhundi, S Vadivel “ Novel ternary l.c om g-C3N4/Ag3VO4/AgBr nanocomposites with excellent visible-light- an State Sciences, 2018 Lu driven photocatalytic performance for environmental applications”-Solid n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 89 [16] J H Li, W Zhao, Y Guo, Z B Wei, M S Han, H He, S G Yang, C Sun (2015), “Facile synthesis and high activity of novel BiVO 4/FeVO4 heterojunction photocatalyst for degradation of metronidazole”,Appl Surf Sci., 351, pp 270–279 [17] J J Liu, X L Fu, S F Chen, and Y F Zhu, “Electronic structure and optical properties of Ag3PO4 photocatalyst calculated by hybrid density functional method,” Appl Phys Lett., vol 99, no 19, p 191903, Nov 2011 lu [18] J Lim, H Kim, P J J Alvarez, J Lee and W Choi, (2016), “Visible an va Light Sensitized Production of Hydroxyl Radicals Using Fullerol as an n Electron Transfer Mediator”, Environ Sci Technol, 50(19), pp 10545– to gh tn 10553 p ie [19] J M Hu, W D Cheng, S P Huang, et al (2006), "First-principles modeling of nonlinear optical properties of C 3N4 polymorphs", Applied nl w Physics Letters, 89, pp 261117–261119 oa d [20] J Su, X X Zou, G D Li, X Wei, C Yan, Y N Wang, J Zhao, L J an lu Zhou, and J S Chen (2011), “Macroporous V2O5-BiVO4 Composites: of va Effect Heterojunction on the Behavior of nf ul Photogenerated Charges”, Journal of Physical Chemistry, 115 (16), oi lm pp 8064–8071 nh at [21] J Zhang and Z Ma, “Ag3VO4/AgI composites for photocatalytic z degradation of dyes and tetracycline hydrochloride under visible light,” z gm @ Mater Lett., vol 216, pp 216–219, 2018 [22] J Zhang and Z Ma, “Enhanced visible-light photocatalytic performance l.c om of Ag3VO4/Bi2WO6 heterojunctions in removing aqueous dyes and an 212–218, Sep 2017 Lu tetracycline hydrochloride,” J Taiwan Inst Chem Eng., vol 78, pp n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 90 [23] L Jing, Y Xu, S Huang, M Xie, M He, H Xu, H Li, “Novel magnetic CoFe2O4/Ag/Ag3VO4 composites: highly efficient photocatalytic and antibacterial activity”, visible light Applied Catalysis B: Environmental, 2016.11-22 [24] L Shi, L Liang, J Ma, F Wang and J Sun, (2014), Remarkably enhanced photocatalytic activity of ordered mesoporous carbon/g-C3N4 composite photocatalysts under visible light, Dalton Trans, 43, pp 72367244 [25] L Shi, L Liang, J Ma, Y Meng, S Zhong, F Wang, J Sun, (2014), lu an “Highly efficient visible light-driven Ag/AgBr/ZnO composite va photocatalyst for degrading Rhodamine B”, Ceramic International n to [26] L Sun, R Zhang, Y Wang, and W Chen, “Plasmonic Ag@AgCl tn gh nanotubes fabricated from copper nanowires as high-performance visible p ie light photocatalyst,” ACS Appl Mater Interfaces, vol 6, no 17, pp 14819–14826, 2014 nl w [27] L.V Kristallov, V.L Volkov, L.A Perelyaeva - Zhurnal oa d Neorganichesko “Vibrational spectra of silver vanadates”, 1990, 35, an lu 1810-1814 nf va [28] L.V Xiaomeng, J Wang, Z Yan, D Jiang, J Liu, “Design of 3D h-BN ul architecture as Ag3VO4 enhanced photocatalysis stabilizer and promoter” lm Journal of Molecular Catalysis A: Chemical,2016.146-153 oi at nh [29] L Zhang, Y M He, P Ye, Y Wu, T H Wu,“Visible light photocatalytic activities of ZnFe2O4 loaded by Ag3VO4 heterojunction z z composites”,549 (2013) 105-113 @ gm [30] M Xu, B Chai, J Yan, H Wang, Z Ren and K W Paik, (2016), “Facile Synthesis of Fluorine Doped Graphitic Carbon Nitride with l.c Lu and Reviews, 11(12), 1650137 om Enhanced Visible Light Photocatalytic Activity”, NANO: Brief Reports an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 91 [31] M Yan, Y Wu, Y Yan, X Yan, F Zhu, Y Hua, and W Shi, “Synthesis and Characterization of Novel BiVO4/Ag3VO4 Heterojunction with Enhanced Visible-Light-Driven Photocatalytic Degradation of Dyes,” ACS Sustain Chem Eng., vol 4, no 3, pp 757–766, Mar 2016 [32] N C Castillo, A Heel, T Graule, C Pulgarin (2010), “Flame-assisted synthesis of nanoscale amorphous and crystalline, spherical BiVO with visible-light photocatalytic activity”, Appl Catal B: Environ., 95(3-4), pp 335–347 lu [33] R Chen , C Zhu , J Lu , J Xiao , Y Lei, Z Yu (2017), “BiVO 4/α-Fe2 an va O3 catalytic degradation n characterization and of gaseous photocatalytic benzene: properties”, Preparation, Applied Surface to gh tn Science, 427, pp 141-147 p ie [34] R Huo, X L Yang, Y Q Liu, Y H Xu (2017), “Visible light photocatalytic degradation of glyphosate over BiVO prepared nl w by different co-precipitation methods”, Materials Research oa d Bulletin., 88, pp 56-61 an lu [35] R Konta, H Kato, H Kobayashi, and A Kudo, “Photophysical va properties and photocatalytic activities under visible light irradiation of nf ul silver vanadates,” Phys Chem Chem Phys., vol 5, no 14, p 3061, lm oi 2003 nh at [36] R Sharma, U Ma, S Singh, A Verma, M Khanuja (2016), “Visible induced bactericidal and photocatalytic z light activity of z gm @ hydrothermally synthesized BiVO4 nano-octahedrals”, Journal of Photochemistry & Photobiology B: Biology., 162, pp 266-272 l.c om [37] S G Ghugal, S S Umare and R Sasikala, (2015), “Photocatalytic Lu Minerali zation of anionic dyes using bismuth doped CdS-Ta2O5 an composite”, RSC Advances., vol 5, pp 63393-63400 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 92 [38] S Khanchandani, S Kundu, A Patra, A K Ganguli “Band gap tuning of ZnO/In2S3 core/shell nanorod arrays for enhanced visible-light-driven photocatalysis” - The Journal of Physical, 2013, 117, 5558–5567 [39] S M Wang, Y Guan, L P Wang, W Zhao, H He, J Xiao, S G Yang, C Sun, “Fabrication of a novel bifunctional material of BiOI/Ag3VO4 with high adsorption–photocatalysis for efficient treatment of dye wastewater”, Appl Catal B 168-169 (2015) 448-457 [40] S Singha, R Sharma , B R Mehta (2017), “Enhanced surface area, high Zn interstitial defects and band gap reduction in N-doped ZnO lu an nanosheets coupled with BiVO4 leads to improved photocatalytic va performance”, Applied Surface Science., 411, pp 321–330 n to [41] S Tokunaga, H Kato, A Kudo (2001), “Selective preparation of photocatalytic properties”, Chemistry of Materials., 13(12), pp 4624– p ie gh tn monoclinic and tetragonal BiVO4 with scheelite structure and their 4628 nl w [42] S Wang, D Li, C Sun, S Yang, Y Guan, H He, “Synthesis and oa d characterization of g-C3N4/Ag3VO4 composites with significantly an lu enhanced visible-light photocatalytic activity for triphenylmethane dye nf va degradation”, Applied Catalysis B, 2013.08.008 ul [43] T A Albrecht, C L Stern, and K R Poeppelmeier* “The Ag2O-V2O5- lm HF(aq) System and Crystal Structure of α-Ag3VO4” Department of oi nh Chemistry, Northwestern UniVersity, EVanston, Illinois 60208-3113 at [44] V Macagno V, J W Schultze (1984), “The growth and properties of z z thin oxide layers on tantalum electrodes”, Journal of Electroanalytical @ 170.40(2), pp 3495-3502 gm Chemistry and Interfacial Electrochemistry, 180(1-2), pp 157– l.c om [45] Venkatesan Rajalingam (2014), “Synthesis and Characterization of Lu BiVO4 nanostructured materials: application to photocatalysis”, an Condensed Matter [cond-mat] Université du Maine n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 93 [46] X Hu and C Hu “Preparation and visible-light photocatalytic activity of Ag3VO4 powders” Journal of solid state chemistry, 2007 180(2): p 725-732 [47] W Zhang, L Zhou, J Shi, and H Deng, “Synthesis of Ag3PO4/g-C3N4 Composite with Enhanced Photocatalytic Performance for the Photodegradation of Diclofenac under Visible Light Irradiation,” Catalysts, vol 8, no 2, p 45, Jan 2018 [48] W Zhou, H Liu, J Wang, D Liu, G Du, and J Cui, “Ag2O/TiO2 lu Nanobelts Heterostructure with Enhanced Ultraviolet and Visible an va Photocatalytic Activity,” ACS Appl Mater Interfaces, vol 2, no 8, pp n 2385–2392, 2010 to BiVO4/P25 composites for the photocatalytic degradation of p ie gh tn [49] X Song, Y Li, Z Wei, S Ye, D Dionysiou (2017), “Synthesis of ethylene under visible light”, Chemical Engineering Journal, 314, nl w pp 443–452 oa d [50] X X Hu, C Hu J Chem, “Selective photocatalytic degradation of an lu azodyes in NiO/Ag3VO4 suspension” Technol Biotechnol 85 (2010) nf va 1522-1527 ul [51] X Zou, Y Dong, X Zhang, and Y Cui, “Synthesize and characterize of lm nanorods photocatalysts and its photocatalytic activity oi Ag3VO4/TiO2 nh at under visible light irradiation,” Appl Surf Sci., vol 366, pp 173–180, z Mar 2016 z gm @ [52] Y H Ng, A Iwase, A Kudo, R Amal (2010), “Reducing Graphene Oxide on a Visible-Light BiVO4 Photocatalyst for an Enhanced l.c Lu 2607-2612 om Photoelectrochemical Water Splitting”J Mater Sci Lett., 1(17), pp an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 94 [53] Y Li, H Zhang, Z Guo, J Han, X Zhao, Q Zhao and S Kim (2008), “Highly efficient visible-light-induced photocatalytic activity of nanostructured AgI/TiO2 photocatalyst”, Langmuir, vol 24, no 15, pp 8351–8357 [54] Z Y Bian, Y Q Zhu, J X Zhang, A Z Ding, H Wang (2014), “Visible-light driven degradation of ibuprofen using abundant metalloaded BiVO4 photocatalysts”, Chemosphere., 117, pp 527-531 lu an va n to p ie gh tn oa nl w d ul nf va an lu oi lm at nh z z gm @ om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 95 DANH MỤC PHỤ LỤC Phụ lục 1: Bảng giá trị C/C0 rhodamine B theo thời gian t (phút) mẫu Ag3VO4 Phụ lục 2: Bảng giá trị C/C0 rhodamine B theo thời gian t (phút) mẫu Ag3VO4, BiVO4, AB-105, AB-11, AB-12, AB-13 Phụ lục 3: Bảng giá trị C/C0 tetracycline hydrochloride theo thời gian t (phút) mẫu Ag3VO4, BiVO4, AB-105, AB-11, AB-12, AB-13 lu Phụ lục 4: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t an (phút) mẫu Ag3VO4 va n Phụ lục 5: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t to gh tn (phút) mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB- p ie 12, AB-13 Phụ lục 6: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t nl w (phút) mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB- oa d 12, AB-13 an lu Phụ lục 7: Bảng giá trị ln(Co/C) vào thời gian t (phút) theo mơ hình nf va Langmuir- Hinshelwool mẫu Ag3VO4, BiVO4 composite AB- ul 105, AB-11, AB-12, AB-13 lm oi Phụ lục 8: Bảng giá trị ln(Co/C) vào thời gian t (phút) theo mơ hình nh Langmuir- Hinshelwool mẫu Ag3VO4, BiVO4 composite AB- at z 105, AB-11, AB-12, AB-13 z tắt gốc tự gm @ Phụ lục 9: Bảng giá trị C/Co RhB vật liệu AB-12 có mặt chất dập l.c om Phụ lục 10: Bảng giá trị C/Co RhB vật liệu AB-12 sau hai lần thu hồi Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 96 Phụ lục 1: Bảng giá trị C/C0 rhodamine B theo thời gian t (phút) mẫu Ag3VO4 Ag3VO4 Thời gian (phút) C/Co lu an va n to 15 0,595 30 0,380 45 0,260 60 0,156 75 0,097 90 0,064 105 0,033 p ie gh tn Ag3VO4, BiVO4, AB-105, AB-11, AB-12, AB-13 C/Co d Thời gian oa nl w Phụ lục 2: Bảng giá trị C/C0 rhodamine B theo thời gian t (phút) mẫu Ag3VO4 nf an lu (phút) 15 0,595 0,892 30 0,380 0,785 45 0,260 0,570 0,760 60 0,156 0,506 0,683 75 0,097 0,375 0,604 90 0,064 0,336 0,525 0,186 105 0,033 0,285 0,421 0,138 BiVO4 AB-11 AB-12 AB-13 1 1 0,914 0,656 0,479 0,542 0,431 0,279 0,345 0,363 0,166 0,229 0,279 0,088 0,152 0,227 0,062 0,086 va AB-105 ul oi lm at nh 0,839 z z gm @ 0,0624 Lu om l.c 0,0314 0,050 an 0,029 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 97 Phụ lục 3: Bảng giá trị C/C0 tetracycline hydrochloride theo thời gian t (phút) mẫu Ag3VO4, BiVO4, AB-105, AB-11, AB-12, AB-13 C/Co Thời gian lu an va n to Ag3VO4 BiVO4 AB-105 AB-11 AB-12 AB-13 1 1 1 15 0,505 0,589 0,623 0,617 0,466 0,691 30 0,443 0,415 0,597 0,469 0,380 0,541 45 0,417 0,349 0,582 0,437 0,352 0,537 60 0,408 0,324 0,565 0,420 0,332 0,517 75 0,399 0,307 0,559 0,423 0,325 0,509 90 0,393 0,298 0,533 0,434 0,324 0,497 105 0,396 0,290 0,521 0,437 0,321 0,493 p ie gh tn (phút) nl w Phụ lục 4: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t (phút) oa mẫu Ag3VO4 d Ag3VO4 an lu Thời gian Dung lượng hấp phụ q (mg/g) at nh 0,081 0,135 z z 90 0,032 oi 60 lm 30 ul nf va (phút) @ 0,132 150 0,133 180 0,137 210 0,136 gm 120 om l.c Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 98 Phụ lục 5: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t (phút) mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB-12, AB-13 Dung lượng hấp phụ q (mg/g) Thời gian lu an va n to Ag3VO4 BiVO4 AB-105 AB-11 AB-12 AB-13 0 0 0 30 0,0332 0,071 0,032 0,061 0,039 0,041 60 0,081 0,082 0,080 0,102 0,082 0,092 90 0,135 0,080 0,133 0,123 0,135 0,142 120 0,132 0,081 0,131 0,122 0,132 0,139 150 0,133 0,080 0,130 0,120 0,131 0,137 180 0,137 0,082 0,132 0,117 0,130 0,136 210 0,136 0,078 0,133 0,112 0,131 0,135 p ie gh tn (phút) nl w Phụ lục 6: Bảng giá trị dung lượng hấp phụ q (mg/g) thay đổi theo thời gian t (phút) oa mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB-12, AB-13 Dung lượng hấp phụ q (mg/g) d an lu Thời gian Ag3VO4 0 30 0,020 60 0,040 0,014 90 0,038 0,019 0,003 120 0,037 0,019 0,004 150 0,037 0,018 0,003 180 0,036 0,019 0,004 0,051 210 0,038 0,018 0,004 0,052 BiVO4 AB-11 AB-12 AB-13 0 0 0,005 0,003 0,031 0,001 0,003 0,048 0,003 0,017 0,054 0,006 0,025 0,052 0,005 0,025 0,006 0,024 0,006 0,025 va AB-105 nf (phút) ul oi lm at nh 0,003 z z gm @ 0,053 om l.c 0,005 0,024 Lu an n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an 99 Phụ lục 7: Bảng giá trị ln(Co/C) vào thời gian t (phút) theo mơ hình LangmuirHinshelwool mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB-12, AB13 ln(Co/C) Thời gian lu an va n to Ag3VO4 BiVO4 AB-105 AB-11 AB-12 AB-13 0 0 0 15 0,518 0,114 0,089 0,453 0,735 0,613 30 0,966 0,242 0,176 0,842 1,276 1,064 45 1,347 0,562 0,274 1,014 1,795 1,472 60 1,854 0,681 0,381 1,279 2,422 1,886 75 2,330 0,981 0,504 1,483 2,781 2,458 90 2,748 1,089 0,644 1,682 3,462 2,773 3,403 1,255 0,865 1,981 3,536 3,002 gh tn (phút) p ie 105 nl w Phụ lục 8: Bảng giá trị ln(Co/C) vào thời gian t (phút) theo mơ hình Langmuir- oa Hinshelwool mẫu Ag3VO4, BiVO4 composite AB-105, AB-11, AB-12, AB- d 13 an lu Thời gian ln(Co/C) va (phút) Ag3VO4 0 15 0,682 0,589 30 0,813 0,416 45 0,874 0,350 0,542 60 0,895 0,307 0,570 75 0,917 0,299 0,581 0,859 90 0,932 0,290 0,629 0,835 105 0,928 1,255 0,653 0,827 AB-105 AB-11 AB-12 AB-13 0 0 0,462 0,483 0,735 0,369 0,758 1,276 0,614 0,829 1,795 0,621 2,422 0,659 2,781 0,675 ul nf BiVO4 oi lm nh at 0,515 z z @ gm 0,867 0,698 Lu om l.c 3,462 0,706 an 3,536 n va ac Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn th Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn si C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Stt.010.Mssv.BKD002ac.email.ninhd 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