Biomimetic functional surfaces with tailored wettability for water harvesting and anti icing applications

Ph.D Thesis Biomimetic functional surfaces with tailored wettability for water harvesting and anti-icing applications Nguyen Thanh Binh Nano-Mechatronics UNIVERSITY OF SCIENCE AND TECHNOLOGY February 2019 Biomimetic functional surfaces with tailored wettability for water harvesting and anti-icing applications 2019 Nguyen Thanh Binh Biomimetic functional surfaces with tailored wettability for water harvesting and anti-icing applications Nguyen Thanh Binh A Dissertation Submitted in Partial Fulfillment of Requirements For the Degree of Doctor of Philosophy / Master February 2019 UNIVERSITY OF SCIENCE AND TECHNOLOGY Major of Nano-Mechatronics Supervisor Hyuneui LIM We hereby approve the Ph.D thesis of Nguyen Thanh Binh February 2019 Dr Seungchul PARK Chairman of Thesis Committee Dr Wandoo KIM Thesis Committee Member Dr Changdae PARK Thesis Committee Member Dr Junhee LEE Thesis Committee Member Dr Hyoungsoo KIM Thesis Committee Member Dr Youngdo JUNG Thesis Committee Member Dr Hyuneui LIM Thesis Committee Member / Supervisor UNIVERSITY OF SCIENCE AND TECHNOLOGY ACKNOWLEDGEMENT This study is the result of my PhD thesis carried out at Nature-Inspired Nanoconvergence Systems Department – Nano - Convergence Mechanical Systems Research Division – Korea Institute of Machinery and Materials, Korea with tremendous amount of support First, I would like to express my sincere gratitude to my advisor, Professor Hyuneui Lim, for giving me the opportunity to become her student at Nanomechatronics Department (UST), for giving me all the support, encouragement and advice over past six and half years, and for spending long hours editing this thesis Her insightful guidance will be great inspiration for my future work in my university afterwards I would like to thank Dr Wandoo Kim for his valuable advice and encouragement during my Ph.D’s degree I would like to convey my great gratefulness to the members of my dissertation defense committee, Dr Changdae Park, Dr Junhee Lee, Dr Hyoungsoo Kim, Dr Youngdo Jung for giving me all valuable comments and suggestions Specifically, I would like to thank Dr Seungchul Park for his honest advice, valuable support and i encouragement, who served as Chairman of my thesis committee I am also thankful to Dr Duckgyu Lee for assistance regarding experiment process and theoretical support when I started my PhD’s degree A special thank should be given to all my laboratory members, Dr Sunjong Oh, Dr Cholong Jung, Dr Seonggi Kim, Cheonji Lee, Gyuhyeon Han for their enthusiastic support Finally, I dedicate this thesis to my parents, my wife and my daughter for their sincere love, outstanding support, for always beside and encouragement during my PhD’s degree This would have been impossible without them ii ABSTRACT Biomimetic functional surfaces with tailored wettability for water harvesting and anti-icing applications * Biomimetic or Biomimicry refers to an approach that imitates nature’s time- proved models, elements and strategies to solve sustainability human challenges In this study, we proposed the fabrication and investigation process on several bio- inspired functional surfaces with tunable wettability towards solving specific problems: water harvesting and anti-icing Water condensation is a phenomenon which refers to the changing physical state of a matter from gaseous into liquid phase The simplest process can be imagined is water condensation on objects near earth’s surfaces such as: fog, dew, frost, etc In this work, we will focus on optimizing suitable surface morphology for durable and high efficiency water harvesting performance Several geometries and surface energies will have been conducted on Aluminum (Al) plates in order to maximize harvesting efficiency On the other hand, icing phenomenon refers to a process when liquid transferring its physical state to solid phase Ice accumulation on functional surfaces had illustrated many bizarre effects and disadvantages in aviation, industry and human activities Several passive approaches including water repellency, Slippery Liquid-Infused Porous Surfaces (SLIPS) and unique design structure in order to optimize anti-icing performance will be introduced throughout this study Totally, we propose different physicochemical processes which arm to manipulate surface wettability towards solving specific problems including water condensation and anti-icing The understanding about mechanism and fabrication process is useful for designing water harvesting system and icephobic applications *A thesis submitted to committee of the University of Science and Technology in a partial fulfillment of the requirement for the degree of Doctor of Science conferred in February, 2019 초초 초초초초 초초초 초초초 초초초 초초초 초초초초 초 초초 초초 초초 자자자자 자 자자자자자 자자 자자자 자자자 자자자 자자자 자자자자자자 자 자자자 자자 자자자 자자자 자자자자자 자자자 자 자자자자자자자 자 자자자 자자자 자자자자 자자자 자 자자 자자자자 자자자 자자자 자자 자 자자 자자 자자자자 자자자 자자자자 자 자자자 자자자 자자자자자 자자 자자자자 자자자자 자자자 자자 자자자자 자자 자자자 자자자자 자자자 자자자자 자자 자자, 자자, 자자 자자 자자 자자 자자자자 자자 자자자자 자 자 자자 자자자 자자자 자자자자자 자 자자자자자 자자자자 자 자자자자 자 자자자자 자자 자자 자자 자자자자 자자자 자자자자자 자자자자 자자 자자자 자 자자 자자자 자자 자 자자자 자자자자자자 자자자 자자자자 자자자 자자자 자자자자 자자, 자자자자자 자자 자자 자자자자 자자자자자 자자자자 자자자 자자자자 자자자 자자자 자자자 자자자 자자자 자자 자자, 자자 자 자자자자 자자자 자 자 자자자 자자자자자 자 자자자자자 자자자자 자자, 자자자자 자자자 자자자 자자자 자 자 (SLIPS) 자 자자자 자자 자 자자자 자자자자 자자자자자 자자자 자자자자 자자자, 자 자자자자자 자자자자 자 자자 자자 자자자자 자자자 자자자자 자 자 자자 자자자 자자자 자자자 자자자 자자 자자자 자자자 자자자자자 자자자 자자자자 자 자자자자자 자자 자자자자자 자자자자 자 자자 자자 자자자 자자 자자자 TABLE OF CONTENTS ACKNOWLEDGMENTS……………………………………………… i (42) Bormashenko, E Why Does the Cassie–Baxter Equation Apply? 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This would have been impossible without them ii ABSTRACT Biomimetic functional surfaces with tailored wettability for water harvesting and anti- icing applications * Biomimetic or Biomimicry refers... property), anti- icing (slippery and water repellency), anti- bio fouling (water repellency), water condensation (hybrid wetting) Among them, water harvesting and anti- icing performance have recently attracted