Đề thi thử có giải chi tiết môn hóa 2016

 TRƯỜNG THPT LỤC NGẠN SỐ 3 Đề số 48 ĐỀ THI THỬ ĐẠI HỌC NĂM 2013 – 2014 MÔN HÓA HỌC LẦN THỨ 1 Thời gian làm bài: 90 phút; (50 câu trắc nghiệm) Mã đề thi 210   !"# Cho biết nguyên tử khối của các nguyên tố: H = 1, Be =9, C = 12, N = 14, O = 16, Na = 23, Mg = 24, Al = 27, P = 31, S = 32, Cl = 35,5; K = 39, Ca = 40, Fe = 56, Cu = 64, Zn = 65, Br = 80, Ag = 108, Ba = 137.Si=28 Câu 1:$%# &&' ()*+(,(-.,#/0123*14#1*35(67# &85-9 #:& *;30(<'9(=#/0)35#31#>(#2 ? @# ? 1*35(&# & ABC @>(C &)< A. ?D7E B. EF C. 7F% D. FGE Câu 2:(( H 1IFJ HK&(I7J H H;(I?J H (@L)(IEJ HH )(MN-HB-< *O#/0(P1Q#R H(C (( H*4 A. F7E? B. 7?FE C. EF?7 D. 7F?E Câu 3:SDF&)T 7 @ 7 2 6 (=#/01#>()3U(A)I)J1*35(V*A()< A. %67 B. ??% C. EEW D. $% Câu 4: DF?&)85-9#:& ? 22222 ?  (=#/S *C/0DD$&)  2*14#2H4  ()@ < *;()35# *;<L(=#B/0# 7 2X ? I3J*35(DE&)#&)(C 22@#85-*R1)< A. DDE&) B. DD7&) C. DDF&) D. DD?&) Câu 5:Y'Y ?Z (4[#\-@+@;);(@)<6G@#*4\& #*]P1+ \A^#& #*])<FG_1`;);(@(C Y ?Z )< A. a@b? $ E F  B. a@b? E E 7  C. a@b? ? E 7  D. a@b? $  Câu 6:B-)&; 1accI 7 J $ c2cb  *35(*P1(Bd#-3+#-- A. -.,#@e#5- B. *:#@e##3# C. -.,#@e##3# D. (.@e##3#/<@e#5- Câu 7:DF&)(_9I 7  G 2 %  ? J(=#/01#>((, DE&) 2*14#1*35( 5-(_ &)<&H #_Lf1gh&/<1#>(i^(\1#>(i1*35(&# &(_@NA  #@>*O#(C &j A. FE%# & B. F6W# & C. 7?F# & D. F7$# & Câu 8:S#(_k;k;2k;I2J 7 k;I2J ? k; ? 2 E k; 7 2 ? k;I2 ? J 7 k;I2 ? J ? k;2 E k; 7 I2 E J ?  k;2 ? )R)35-.,#/01#>(2 ? *l(4#/<1#>()-.,#H.L@ 1'()\ -.,#HcAm)< A. G B. W C. FD D. 6 Câu 9:1#4#S#(l-(_@#`A IFJk;ZI@J I7Jk; 7 2 ? Z2IAJ I?J1Z2 7 IAJ IEJ1Z1I2 ? J 7 I@J I$J1ZT2 ? I@J I%J)Z )I@J I6J#Z2 ? (@3n#5-H.L@ -.,#HA&)\)< A. I7JI?JIEJ B. IFJI7JI?JI%J C. IFJI7JIEJI$JI6J D. IFJIEJI$JI6J Câu 10:]-o4#(.L) 7 2 ? /0  (`I]11_*]-oFDDpJ1*35(&A#)V ( /<%67& ? IV*A(J85-A9(4qA/0*@d#F%r_L77E)IV*A(J85-A 9=(/<1#>(30(/^@#I3J1*35(7# &ABC @>(C &)< A. $E B. WF C. FDW D. 6$% Câu 11:1s-o<<%WE# & (( @t+@#&^@3n# H/0]11_WDp1*35( 1#>(9<'1#>(9-.,#B/0)35#31#>(#2 ? @# ? *1 4#1*35(&# &#@>(C &)< A. W%E B. E?7 C. ?E$% D. %GF7 Câu 12:(((_22222 ? 22 7  ? 222 &)&8(_ )<DDF(=#/01#>(#2 ? 3@# ? [#A)35#ABC 1*35()< A. F67W B. F$F7 C. FG77 D. F7G% Câu 13:5-(_*+(,(&\(V*:#-o(C  1(4(e#(^#,(-om E  % 2 7 *P1( =#*35(/01#>( 2)< A. W B. FD C. 6 D. G Câu 14:_<30*oL-.,#/01#>(@&;q)]&)FF1*35(7.-h& A. !@-; B. u); C. 1c7c; D. )1; Câu 15:]-o<<&# &85-T2 ? k;I2 ? J 7 1I2 ? J 7 @#*4&)1I2 ? J 7 d#7)R&)k;I2 ? J 7 @#*P1A]A^#(4HL 1-.,#1*35(v)85-AV *A(v)85-A@/<30(1*35(F7)1#>(i(4-wFI@#i(q(, F(_  1L_JA^#(4A L@ @>(C &)< A. FDG% B. F7F? C. W%? D. FFF7 Câu 16: xL(((_ ocH);@;-@;/L) H;); *; H;( )1; H;); ;t;(_@#xL)<&&_&<130(@&)<V*P1A]3n#)< A. $ B. ? C. E D. % Câu 17:(((_)) 7 2 ? ) 7 I2 E J ? y2I2J 7 yI2J 7  T2 ? T2 E k;I2 ? J 7  I E J 7 2 ? (_*P1-.,#*35(/01#>()1#>( 2)< A. 6 B. G C. FD D. W Câu 18:((1#>( 1 (( @t+-@- cF7c*);L);#)() 1&H H;()1(t *; H;()Lc) 1#>("  1I2J 7 V]*'3n#)< A. E B. % C. $ D. 6 Câu 19:(((_)) 7  2 7 1) ?  2 E  7 2 ? #2 ? (_(=# *35(/01#>(k;I2 ? J 7 )< A. % B. G C. W D. 6 Câu 20:@#(((_ 1 7 2 E ) 7 12 E 2 7  7 k; 7 I2 E J ? 2 ? (_(4U\@  7 2 E d#&'-.,#)< A. 6 B. $ C. W D. % Câu 21:(L<<ED7# &85-9#:& H (@L)(/L) H; /<&;L)&; (@L) @: (<'.-h&(L/<`F*M#1#>( 7 2 E *l(`7*M#1#>( I2J 7 3 _LA)35#`FQ#&# &`7H1_]?$E%# &ABC @>(C &)< A. 7?E B. 76D C. ?7E D. ?%$ Câu 22:9<-"#4 <<7DD# &(_z(4(q Hd#6(R* H# &1#>(  27$p1*35(FWW%# &#)H;@)/<L# &&1 @@>(C H/<L)< A. GWE/<7D%6E B. FD7E/<7D%7G C. FD7E/<7W?DG D. GWE/<7D%7G Câu 23:M(]((#]& 1 I J1##2 ? @N IJ14# )U/0 7 2 E I*l(J I(J"  {@@#1#>() IJ1#>(T2 E /< 2 ?  I;J"  @#1#>( 2 IKJ 7 /<1#>(k;I2 ? J ? #]&@ (_A)< A. % B. E C. $ D. ? Câu 24:2 7 )1^U]Am@#((-.,#/0 A. 2 7 30(@ 7 1#>(TY2 E  B. 1#>(T2 230(@ 7  C. 1#>( 22 7 1#>(TY2 E  D.  7 2 7 30(@ 7  Câu 25:"  7DW# &85-'#:&k;k; 7 d#1#>(2 ? *l(4#31*35( $?6%)2 7 I.-h&Am1L_V*A(J/<1#>(1#>((=#/01#>(  I2J 7 3)()_L<'ABC *;&1#*BA)35#A^#*[`A)35#(_@N1*35( )< A. W$%# & B. W$G# & C. 7FE# & D. F%# & Câu 26:(((_ 2 ? 2)I2J ? k;I2J ? k2 7 @ 7 2 ? ) 7  E )(_(=# *35(/01#>( 2)x#V]*'3n#)< A. E B. 6 C. $ D. % Câu 27:"  F%#85-#:& 2 ? T2 ? @#1#>()3T@ _-=B/< FDD&)1#>(9(,  2F$Y/< I2J 7 D?Y ) 7 DFY| 1-.,#)(1*35(& # &ABC @>&)< A. 6WW# & B. FG6# & C. GW$# & D. $GF# & Câu 28:(L<<&# &k; 7 (, 7Dp\-(_@+d#&')35#2 7 /S *C1*35(A 9_-=B9/<F)1#>(#:& I2J 7 DF$Y/<T2DFY1*35(1#>(i/<7F6 # &ABC i/<1#>( 2_LH1_]&ABC @>(C &)< A. F7% B. 7ED C. 77$ D. 7?7 Câu 29:WDE# &85-+#:& *; H;(/< H;);(=#<</01#>( #2 ? @#&^@3n# ? 1*35($$7# &ABC ABC <L/<1#>()3 1A ABO(-.,#(")\&# &(_@NA^# @>(C &)< A. 7F% B. WD?% C. %F6W D. $$7 Câu 30:&'&}15-A& c (=#/030(31*15(1#>(9/<??%)I*A(J 1#>(9(=#/0FDD&)1#>(85-)FY/<)) ?  D%YT)35#ABC 1 *35()< A. ?F7 B. E%W C. E7G D. ?G Câu 31:85-#:&67# &Y#/<FD7# &) 7 2 ? (=#B/0)35#31#>(2 ?   1A((-.,#H.L@ <<1*35(DEEW)A 7 I*A(J/<1#>(iT)35#&1 A 1*35(A(^(\1#>(i)< A. E7% B. W6 C. GF D. EWE Câu 32:((H 12 7 ! 7 2 $ 2 7 2 7 2 ? @2 ? ) 7 2 6 H HV@)< A. E B. 6 C. $ D. % Câu 33:(LH&) ;9\@ 7H&)2 7 YlA(H&)9(=#/0)35#31# >(\(@ @# & (3\@ EH&)#9(*>9@#(( ; 1 A. I2J 7 B. 2 C.  7 wc2 D.  ? 2 Câu 34:EDD&)1#>( I2J 7 FY/<1#>((, DF&)) 7 I2 E J ? DD$&))/< DD7$&) 7 2 E *BA-.,#<<1*35(&# &ABC @>(C &)< A. F$% B. 6$67$ C. W?$7$ D. 6W Câu 35:?%# &)1(t+)&;/0wWDp&)2 7 1*35((/<1#( I2J 7 3 A)35#ABC 1*35()< A. EW# & B. ?%# & C. ?7# & D. ED# & Câu 36:]]*'(C (*'-.,#)< 1B@d#A*3 ]*'(C -.,#S c$D D )*B$D  `(*'-.,#Q#)FD7E)Rj A. F B. 7 C. ? D. E Câu 37:D?$&)'1/<DD%&)k;I2 ? J ? /<(, D7E&) 7 2 E I)x#J 1A(( -.,#H.L@ <<1*35(v)A2I.-h&Am1L_V*A(J^(\1#>(1 *35(A)35#&1A )< A. E?$% B. ?%EW C. ED7 D. $7$7 Câu 38:4 1#1L4 ((4(_1`;)0-#<(e#)<E F  A. E B. 7 C. ? D. F Câu 39:*:#-o;;*+(,(&\(V,#/0(^#,( $  FD 2 7 )< A. G B. % C. 6 D. W Câu 40:WD# & < B/<7DD&)1#>((, )7Y/< 7 2 E D6$YB1(^(\ 1#>(9 1-.,#`A)35#(_@N1*35()< A. ?7$# & B. ?%%# & C. 7$G$# & D. 77$# & Câu 41:[#*:#-o+&(C  %  %  6  W  W  FD )< A. $ B. 6 C. % D. E Câu 42:2H( _(C &'#1L)<~2 7 5-(_(C 4/0*@^(, F7$p*@^/PA )35##1L*4)< A.  B. ! C.  D.  Câu 43:1#>(9(, D7&)k;I2 ? J ? /<D7E&))1#>(9(4U"  *35(*  1# &1IB-.,#\@ A2)<.-h&Am1L_J A. WG%# & B. FW$%# & C. $6%# & D. F7F%# & Câu 44:T*14#85-(( ()(4(^#,( ? 2/< ?  6 2IHO(( 7 2 E *l(VFED   /<VF6D  J`[#;;/< A;1*35(* )< A. 6 B. % C. $ D. W Câu 45:U•B)1(t+/<K@1(t+ e# A. 1#>(#2 ? X ? B. 1#>(@ 7 C. 1I2J 7 V]*'3n# D. ./<*P1*O# Câu 46:xL#:&(((_< 1*oL*P1(4)3€#j A. ) 2 ?  )2 7 y2;I2J 7  B.  7 2yI2J 7 22c22  7  7 22 2 ?  C. )) ?  7 2 2 ? yI2J 7 y2 D. y) 7 )) ?  )2 7  2 ?  7  7 22 Câu 47:&# &85-i#:& H H;(-;) ();L)((=#/S *C/0 1*35( FG%# &85-&19(L<<91*35(FD%# &&1( ( B1(?DE# & 85-i@(=#/0 3`1*35(v) 7 I*A(J@>(C v)< A. EEW B. $% C. ??% D. %67 Câu 48:-3+#@`k;I2 ? J 7 Z 2 E •k; 7 I2 E J ? Zk;I2 ? J ? Z 7 2 E Z2Z 7 2  1A(od#[#((]#1L#.(C -3+#@`)< A. E7 B. E? C. $D D. $7 Câu 49:(((_l(1#>( 1*oL IFJ1#>()I2 ? J ? Z1#>( 7  I7J1#>()) ? Z1#>( 7 2 ? I*14#J I?J)Z1#>( 2 IEJ1#>()) ? Z1#>( 2 I$J1#>( ? Z1#>()) ?  I%J1#>( E )Z1#>( )2 7 I6J1#>( 7 2 ? Z1#>(k;) 7 -.,#\A)< A. ? B. $ C. 7 D. E Câu 50:F$# &85-(( &#:& )&;L) &*&;L) &*;L)&;L) &(=# /S *C/0$D&)1#>()FYT)35#.-h&1*35((4#@>)< A. F%W7$# & B. 7DFW# & C. F$G7$# & D. 7FF7?# & cccccccccccccccccccccccccccccccPhần đáp án và giải chi tiết Câu 1:B BTKL O ancol ancol 2 4 7,2 5,6 n 0,1 n M 56 CH C CH OH 16 Ag : 0,2 m 41 CAg C COONH : 0,1 − → = = = → = → ≡ −  → =  ≡ −  Câu 2:D (474&22IEJ&\_I)\J (44&O;I?J&\,7 Câu 3:A 6 3 2 BTE e Cl Cr Cr 0,6 (n ) 0,2 n 0,6 n .22,4 6,72 2 + + → → = → = → = = Câu 4:B 3 NaOH 3 Ag CH OH : a a b c 0,13 a 0,07 0,13 HCOOH : b b c n 0, 05 b 0,02 B HCOOCH : c c 0,03 4a 4c n 0,4  + + = =      → + = = → = →       = + = =    Câu 5:D [ ] [ ] 6 2 3 5 26 p p 3 n 79 p 26 Fe : Ar 3d 4s Fe : Ar 3d p p 3 n 19 n 30 + + − + = =   → → →   + − − = =   Câu 6:D accI 7 J $ c2cb  *35(*P1(Bd#-3+#-- J@e##3# [ ] 2 2 5 H N CH COOH − − J@e#5-( -@) ( & Câu 7:C 3 2 3 3 3 2 3 3 3 NaNO : 0,1 CH NH NO X NaOH m 23,1 NaHCO NaOH Na CO : 0,1 NH HCO NaOH : 0,4 0,3 0,1  −  + → = + →   − =  Câu 8:A v02 ? (4k;k;2k;I2J 7 k; ? 2 E k; 7 2 ? k;I2 ? J 7 k;2 E k;2 ? v0)(4k; Câu 9:D 2H4 A&)\#‚ )<H(C A&)\-.Q# IFJk;ZI@J số oxh của Fe tăng I7Jk; 7 2 ? Z2IAJ H(C k;#.& I?J1Z2 7 IAJ H(C 1A^# L*[ IEJ1Z1I2 ? J 7 I@J số oxh của Cu tăng (do có O 2 ) I$J1ZT2 ? I@J số oxh của Cu tăng (do có O 2 ) I%J)Z )I@J H(C TrA^# L*[ I6J#Z2 ? số oxh của Ag tăng Câu 10:D  Hm)ƒ/0)]1%67(@ 4 2 2 2 2 BTNT BTNT.Al O Al Al CO : a CO : 0,18 a b 0,24 0,3 CO : 0,06 (n 3.0,02 0,06) CO : 0,06 28a 44.0,06 32b 32 0,3 O : 0,06 O : b n 0,42 n 0,28 m 7,56 ↓   + =     ¬ = = → → + +    =       → = → = → = Câu 11:D Sac Ag Ag 6,84 n 0,02 n 4.0,02.0,8 0,064 m 6,912 342 = = → = = → = Câu 12:C 2 4 HCHO 0,04 Ag HCOOH 0,02 Ag HCOOCH CH 0,04 Ag 0,02.Ag CH C CHO 0,02.CAg C COONH HCOONa 0, 02Ag =  ≡ − →  ≡ −  • Câu 13:D OƒP<A^#4#`#‚ )<-.(.„@  ( ) ( ) 2 2 3 2 3 3 2 2 3 2 3 2 2 3 CH CH CH COOH (1) CH CH CH COOH (2) CH C COOH CH (1) HCOOCH CH CH (2) HCOOCH CH CH (1) HCOOC CH CH (1) CH COOCH CH (1) CH CH COO CH (1) = − − − = − = − = − − = = = = − − Câu 14:D A. !@-; F.-h& B. u); F.-h& C. 1c7c; F.-h& D. )1; 7.-h&- @ „( Câu 15:B 85-A=(/< 7 2  A^#(4A L@ (,#… 2 2 NO ,O -.,#/S *C 3 3 2 3 2 BTNT BTNT HNO N 3 2 H 3 3 2 2 3 BTNT BTE 3 2 5 3 trong KNO trong KNO 3 Fe(NO ) : a PH 1 H 0,1 n 0,12 n 0,12 n 0,12 m Cu(NO ) : 2a KNO : b Fe(NO ) : 0,02 Fe 1e Fe 6a 0,12 a 0,02 m Cu(NO ) : 0,04 N 2e N KNO : b + + + + + +     = → = → = → = → = →        − =  → = → = → →  + =   3 2 3 2 3 Fe(NO ) : 0,02 m 12,13 Cu(NO ) : 0,04 KNO : 0,01       =    Câu 16:A @; -@; /L) H;); *; H;( H;); Câu 17:B ) ) 7 2 ?  y2 I2J 7  yI2J 7    T2 ?  k;I2 ? J 7  I E J 7 2 ?  Câu 18:B  (( @t+ -@- cF7c*) ;L);#)() 1& H H;( )1(t Câu 19:B ) ) 7   2  7  )  ?   2 E   7 2 ? #2 ?  Câu 20:A ) 7 Z2 7 Z 7 2 12 E *]-o1#>( Z2 ? 2 7  7 (=#/0) 7 Z 7 2 k; 7 I2 E J ? ]-o1#>( 2 ? Z 7 2 Câu 21:A ( ) 2 X n 2n 2 2 2 2 2 n 2n 2 2 X H O m 4,02 C H O O nCO n 1 H O X : C H O 14n 30 n 4,02 0,18 n 3,6 n 0,05 n 0,13 m 2,34 − − =  + → + −   + → = → = → = → = Câu 22:B Chat beo trung hoa trung hoa KOH NaOH phan ung NaOH glixerol BTKL m 200 n n 0,025 chi so iot 7 n 0,025 3n 0,025 3.0,205 0,64 x 102,4 200 0,25.x y 18,86 0,025.18 y 206,29 =   → = =  =   → = + = + = → = → + = + + → = Câu 23:C I J1##2 ? @N @ 2 7 IJ14# )U/0 7 2 E I*l(J@ ) I(J"  {@@#1#>() @ 2 7 IJ1#>(T2 E /< 2 ?  @ 2 7 I;J"  @#1#>( 2@  7  IKJ 7 /<1#>(k;I2 ? J ? @ I(_@NJ Câu 24:A 2 7 )1^U]Am#‚ )<H(C Q#S ZE ) Z% A. 2 7 30(@ 7 1#>(TY2 E  1h B. 1#>(T2 230(@ 7  4T2I)\# LJ C. 1#>( 22 7 1#>(TY2 E  4 2I)\# LJ D.  7 2 7 30(@ 7  4 7 I)\# LJ Câu 25:B BTNT BTKL 2 3 BTE BTNT 4 Fe : 0,2 Fe O : 0,1 Fe : a 56a 32b 20,8 20,8 m 85,9 S : b 3a 6b 2,4 S : 0,3 BaSO : 0,3   → → + =    → → → =    → + = →      Câu 26:C  2 ?  )I2J ?  k ) 7   E ) 2 7 @ 7 2 ? Iq @# 2*l(J Câu 27:A Oƒ 3 3 2 2 3 BTNT CaCO KHCO CO CO 2 2 M M 100 n 0,16 OH : 0,21 n 0,21 0,16 0,05 0,16.CO m 0,04.197 7,88 Ba : 0,04 − − + = = → =  → = − =  + → = =    Câu 28:C i/< 2)\(4ABC (,#…i(4 3 HSO − 2 3 2 2 3 BaSO Ba BTDT BTNT.S FeS Ba K K HSO n n 0,1 n 0, 05 n 0,15 0,1 Y n 0,1 S 0,3 n 0,15 m 22,5 n 0,1 n 0,2 + + + + − ↓   = = =    = > → = → = → = → =     = =    ∑ Câu 29:C 3 BTKL CH CHO : a Ag : 2a 44a 26b 8,04 a 0,1 8,04 55,2 CAg CAg : b 216a 240b 55,2 b 0,14 CH CH : b Ag : 0,2 Ag : 0,2 HCl m 61,78 CAg CAg : 0,14 AgCl : 0,28 + = =     → → →     ≡ + = = ≡       + → =   ≡   Câu 30:A Oƒ )1^(4 2 e H OH n n 2n 0,3 − = = = 2 e H OH 3 n n 2n 0,3 H : 0,1 OH 0,1 0,06.3 (0,06 n ) 0,3 n 0,04 m 3,12 Al : 0,06 − + − ↓ ↓ + = = =   → = + + − = → = → =    ∑ Câu 31:C Oƒv0Y#)y@_ L(4&1 E 2 ? ( ) 3 2 e 4 3 4 3 2 3 3 3 Mg(NO ) : 0,3 0,6 0,02.10 Mg : 0,3 n 0,6 NH NO : 0,05 m 91 NH NO : 0,05 8 Al O : 0,1 Al NO : 0,2  −   → = → =  → =       Câu 32:B _(.*P1(1h Câu 33:A o1<L(*U& Câu 34:C ( ) 3 2 3 Al(OH) 2 4 4 4 3 H : 0,1 Ba : 0,4 Al : 0,2 OH 0,1 0,2.3 (0,2 n ) 0,8 OH : 0,8 SO : 0,3 BaSO : 0,3 BaSO : 0,3 m 83,525 Al OH : 0,1 + + + − − −     + → = + + − =      →    → =    ∑ Câu 35:C o1<L(*U& 2 Glu CO n 0,2 n 0,2.0,8.2 0,32 C = → = = → Câu 36:B ^#,(m=# H & FDD FD FD FD FD FD7E 7 7 − = = = = → = m T T γ γ γ γ Câu 37:A m=# 3 2 4H NO 3e NO H O + − + + → + 3 3 2 NO 3 e Cu e H 2 2 2 4 3 4H NO 3e NO H O n 0,18 n 0,36 0,06(Fe ) 0,42 n 0,21 n 0,48 n 0,36 Fe : 0,06 Cu : 0,21 m 43,56 SO : 0,24 NO : 0,06 − + + − + + + − − + + → + =   → = + = → =  = → =      → =     ∑ Câu 38:C :& [ ] [ ] [ ] 1 5 1 10 1 K Ar 4s Cr Ar 3d 4s Cu Ar 3d 4s Câu 39:A Oƒ ( 7  $ „4F*:#-o ( ?  6 „47*:#-o ( E  G „4E*:#-o 4 9 3 3 7 2 5 2 5 3 7 3 HCOOC H (4) CH COOC H (2) C H COOC H (1) C H COOCH (2) Câu 40:C Oƒ1`) L+(" 7 2 E A^# L+*4(4# L 2 2 4 Cl 4 e Ca 2 SO n 0,4 CaSO : 0,15 n 0,2 n 0,4 m 25,95 n 0,15 CaCl : 0,05 − + − =    = → = → =   =    Câu 41:C  %  % 4F  6  W 4F  W  FD 4E Câu 42:A o1<L(*U& 4 4 RH 0,125 R 28 A 4 R → = → = → + Câu 43:D m=# 3 2 4H NO 3e NO H O + − + + → + 3 3 2 NO 3 e Cu Cu e H 4H NO 3e NO H O n 0,6 n 0, 06.3 0,2(Fe ) 0,38 n 0,19 m 12,16 n 0,24 n 0,18 − + + − + + + → + =   → = + = → = → =  = → =   ∑ Câu 44:A Oƒ~351 ?  6 2(4 (_  ? 2/< ?  6 2I•(FJ ?;;  ? 2/< ?  6 2I•(7J &7;;(4F@3n#5-@e#  ?  6 2I•(FJ/< ?  6 2I•(7J &F A;/<F;; Câu 45:B Câu cho điểm nhưng cũng phải chú ý : Br 2 là cách duy nhất Câu 46:B A. ) 2 ?  )2 7 y2;I2J 7  _L))\# L B.  7 2yI2J 7 22c22  7  7 22 2 ?  (1h C. )) ?  7 2 2 ? yI2J 7 y2 _L)) ? )\# L D. y) 7 )) ?  )2 7  2 ?  7  7 22 _Ly) 7 )\# L Câu 47:A 2 3 2 2 BTNT.Na Na CO Na Y H BTKL Y Y H n 0,1 n 0,2 n n 0,1 m 0,2.23 19,6 0,1.2 m 15,2 m 30,4 n 0,4 n 0,2 = → = = → = → + = + → = → = → = → = Câu 48:B v0†#<(Rd#29Am-,(\- (1LU# L/P\#‡ 7 ? ? 7 ? E ? 7 + + − + + + → + + Fe H NO Fe NO H O I7J o]-e5-@:*P/<IFJ4# L Gk;I2 ? J 7 ZF7 2 E •$k;I2 ? J ? Z7k; 7 I2 E J ? Z% 7 2 E Z?2Z% 7 2IFJ Câu 49:D IFJ1#>()I2 ? J ? Z1#>( 7  4 7  v` ( ) 2 3 2 2 3 Al S H O 2Al OH 3H S + → + I7J1#>()) ? Z1#>( 7 2 ? I*14#J 42 7 I?J)Z1#>( 2 4 7  IEJ1#>()) ? Z1#>( 2 T^#(4A I$J1#>( ? Z1#>()) ?  T^#(4A I%J1#>( E )Z1#>( )2 7 T^#(4A I6J1#>( 7 2 ? Z1#>(k;) 7 42 7 Câu 50:A BTKL m 15 0,05.36,5 16,825 → = + = cccccccccccccccccccccccccccccccccccc cccccccccccˆcccccccccc TRƯỜNG THPT CHUYÊN BIÊN HÒA HÀ NAM ĐỀ SỐ 28 ĐỀ THI THỬ ĐẠI HỌC LẦN 1-2014 (Thời gian làm bài 90 phút) . 34:D 4 10 4 10 2 5 10 2 2 C BTNT.oxi BTKL C H O : a X : C H O 0,23Q CO : 1, 02 1, 02 4a 5b a 0 ,13 C H O : b a b 0,23 b 0 ,1 H O : 1, 15 n 1, 02 n 4a 5b a 2b 2x 1, 02.2 1, 15 x 1, 43 m 200,94 (1, 02.44 1, 15 .18 ). ÁN VÀ GIẢI CHI TIẾT Câu 1: D COOH OH BTKL 2 X(tri) : 2a 2a.2 3a.4 1, 6 a 0 ,1 n 2a.3 3a.5 21a 2 ,1 n Y(penta) : 3a 17 8,5 1. 56 1, 5.40 m 2 ,1. 18 m 256,7 17 8,5 14 9,7 H O : 1, 6 18    → + = → = → =.  E ) 2 7 @ 7 2 ? Iq @# 2*l(J Câu 27:A Oƒ 3 3 2 2 3 BTNT CaCO KHCO CO CO 2 2 M M 10 0 n 0 ,16 OH : 0, 21 n 0, 21 0 ,16 0,05 0 ,16 .CO m 0,04 .19 7 7,88 Ba : 0,04 − − + = = → =  → = − =  + → = =    Câu