!"#$%!&'()*+!$%!& !"#$%&!"' !"($ )*+, -. /./0*+ /1/*2 %&!"($$%&345 !" 6(+7 !" !"8 $9*+#$9:1 9*+ 9*+($(+7 !"8"; / + $<6 =>5 4 0($*+#$9+ ?9+*+7@' 9+*++'AB C 9+*+BD+%E 08D'ABF C 9*+BD+%08D'AB9F ?9+*+7#G' 9+*++'1(+B 9+*+7#G'AF *H:1 )9+*+($! $ +6 =+$/G%E I04 J4 0B./K/L/(+F ?H:1 (+F'MNO,M($09+*+2 ? 5%5' .'+(P.'F FP '1 ,#-!.%/0#1 QR18SD 56 = !" ;18S' $<8S T4 0 $<8S(4 0 O8SB0(6 = 6 T8S T4 0 6 T8S T4 08R18S $<4 0%&5 +E U018S $<4 0/ 4R4 V + !" $ #D"8";VI;W8% O8S*+#$9+ K*+'Q0 4 !"' ↓ → + → + X . ,.2 . . K9+'Q0 4 !"' . Y C L. B C L. . . → + → + ,$1(2 +Z% R9[ \ ]7' L. C 88/( B/ . Y *O8S "#$+1 KK'Q0 4 !"/^%[B_ ` 8%% " +Z8 !"#] L. C 8Z,K.8Z2%[BK X ` 8%%5 " 1 4 . a K → + + 8/8 C L. ,K C 2 L. C b ,K C 2 L. C bK. → + K L. C b .bK X c K.'%6 T8S T d ^/ 18S8S(' e%& . f N eB0(4 0 O8S(+F 80 4 !"5(+*S6)4/(+ 9g(/ 9[99S AK. X (bAK. X hA(ibK. X 6 T8S(4 0' 6 T8S(4 018SB0()j4 0%&5 + !" U08S(4 0/ 4R4 0 + !" $ #D"8";/8S(\/ -8%I4B0( -4 0% +E QS(*+#$9+ H'Q0 4 !"A 8. #$ .#$K ,A2f,. 2f . ,A2f, .2f . *QS( "' K,A2fk K QS(+1' . f,A2N, b b K 2 ?\l' H[ L. C 8Z/ . Y /( B g . H[K././,.2 g. /8E mB0()*`4B0(B^ ). X \ T8. >9[./,.2 /K. gI;WV. #$ . `B0(*` mT($ eB0(. #$ . 9 '+BT. #$+99S,.2 ,92 . b,.2 ,92 → . X ib . 9 'eBT. #$+99S,.2 8B^ )/8F99S8B^ )! ;51;4' . b,.2 h,. X 2 ,2 . b,.2 h. X ib .,2 U0,. X 2 +]6)4B8% ,. X 2 → o t . X b. b . X$<4 0' nf oo A Pnf oo A PnKf oo A K 2.#3!!"#$%!& D 56 =' +*^ I04 =4 0 +6 = !" H' !",O2V//./K 4' !",O2%D 56 =' 1 4 . a K H'Q0 4 !",A2 8. #$ . ; T'H+A4+. #$ . ⇒ ,A25/,% R%+12 4D 56 =)A 1 4 . a D 544D 5 d' +*^ >(I0(4 =)4 0 + !" H'D 56 = 1 4 . a 1'4'af'*' ⇒ D 54, * . 2 ]'% R($//X XD 58"; ' +*^ >( 0; % R% [#]f e%& p0(6 =' QJ*$+ TU 0(,2I0+()E P Uf 0(,2)E R T,2@ 8E#$I 18S fMhUf M +ZUf C/ XAfBq,8+[8JB 8E/ I 2 AfBqhAfBq,^ R Tf `I0+(*r2 L4' Uq q B UA A = C>B0")BTAI+#]BTq,9Asq2 9 Asq f Uq UA hUAf9 Asq Uq YQE7 8E8D8Z4 m 8EID BG +( A +ooo9 D t9g8S( M ∆ fB U P ∆ f I,992N I,92PB($8E7 8EIDBG +( A +ooo 9D 456 !2.#3! ,#7 u d ^' F+D 5' H' !",A24 8. / ./K ?(' Hd8+D 59d#$+I;W. / ./K T S' 0( !",A2($,A2/B0(6 =U 0(*+' 0(9+' P d TB0( "/+1 ⇒ QZ D 56 = 1 4 . a K t9gD 5' A UA K C . va 4 1 ==== I4 - S'1/4/a/ \l'8J+n4 09g' oo UA nK C n. v n 4 n 1 ==== I4'1/4/a/ *F+;5' H' !",O24 8. #$ . ?(' T+(87('+( A/+(. P .P. QZ #$+" `( >( ^ ;54' 1 4 . a b,1b 2 a C 4 − . h1. b 4 . +(A+(. +(. +( . +Z'QZ R T8+[8JB % >(' +(. 1 +(A = +(A +(. 1=⇒ P " d T4/a \l'K^8J*$+ R TBT8+[8JB w T " d+( K^8J*$BD++(. $+U ` Ta,I04 =+129d F+U ^' ?uD 54, * . K 9 2 PI8% `I4D 56 = ?(D 54 e%& X F+D 5' H' !",A24 8. / ./K ?(D 5' Hd8+D 59d#$+I;W. / ./K T S' 0( !",A2($,A2 0(*+' 0(9+' P d TB0( "/+1 ⇒ QZ D 56 = 1 4 . a K t9gD 51'4'a' f C K ' v . ' ' K^1'4'a' f'*''9 ⇒ D 54, * . K 9 2 %D 58";' * . K 9 \l'8J+n4 09g'1'4'a' f C nK ' v n. ' n ' n *F+" `;5'9d#$+;5( >( uD 56 = -D 54' ?-D 54, * . K 9 2 ?`9d#$+' QJ+rI0Ufx %',b*bvbC92fU I4f C92v*, U +++ f C92v*, x +++ K^f α 4D 56 =($' α * α . α K 9 α QJ+UyrI0,H'Uyu2 Ty C92v*, U +++ y C92v*, u +++ QJ+I0(E 4 =)E 4 0 ,H' +6 =%4 =+12 K^>%D 54 H', Y 2 T ∆ P+ ∆ zo,4I0{b2 8 9:. q$'Q0 4+$ +$/k !"A 8/XCC(T . @8B #$/ok . `D 56 = + I' >B0)AI+#]+1($Y/vY *+6 =A%X4 =+1 0(6 =Ayv ;' + >B0UfU. Y/vYfXY/vYfko8# K1_ B%U ;8 F+I 'd ^ R'F+;54' T +( ' A f +(o/o ko /k = P . f +(ov/o /C /XCC = . f +(ov/o k /ok = QZ D 5#$#^ " `4' QZ +(#$+P( >( 1 4 . a ,I;WV. #$ .2 e%& C 1 4 . a b, 2 C 4 1 z −+ . h1. b 4 . o/o+(o/ov+(o/ov+( % >( v1 o/ov 1 o/o =⇒= P 4 o/ov 4 o/o =⇒= 8| `81fvP4fG Sa$8J*$BD+ S)+1 U0 `a 9d#$+U %Ufkof1b4bv/ah,v2b,2bvafko ⇒ afv4D 56 =A($ v . v R'Hd#$+D 5 TB0(4 0' f . f +(ov/o /C /XCC = fo/} f . f +(ov/o k /ok = fo/ . f/kN,o/}bo/2fo/~v QZ D 5 1 4 . a ' t9gD 5' A UA . v 4 1 === 1f v k/ }/oko A UA == 4f k/ /oko A UA == af v vk/ ~v/oko Av UA. == 4'D 56 =($' v . v 'uD 54 TB0(4 0' f . f +(ov/o /C /XCC = fo/} f . f +(ov/o k /ok = fo/ . f/kN,o/}bo/2fo/~v QZ D 5 1 4 . a ' %1'4'af v ~v/o /o o/} v . ' ' === fo/ov'o/'o/ov 1'4'af'' ⇒ D 58";($ . ⇒ D 54($, .2 `9d#$+U/ %Ufko ⇒ ,bbv2fko ⇒ f v Xo ko = 4'D 56 =($' v . v *+*^ I04 =)E 4 0' F+8J*$I04 =))+1($X ;' `D 54 uD 54 TB0(4 0' e%& Y f . f +(ov/o /C /XCC = fo/} f . f +(ov/o k /ok = fo/ . f/kN,o/}bo/2fo/~v QZ D 5 1 4 . a ' %1'4'af v ~v/o /o o/} v . ' ' === fo/ov'o/'o/ov 1'4'af'' ⇒ D 58";($ . ⇒ D 54($, .2 uT('H+ +6 =A%X4 =+1 KfX ⇒ D 56 =($' X v . X +*^ UyrI0 F+8J*$Uyv ;' `D 54 uD 54 TB0(4 0' f . f +(ov/o /C /XCC = fo/} f . f +(ov/o k /ok = fo/ . f/kN,o/}bo/2fo/~v QZ D 5 1 4 . a ' %1'4'af v ~v/o /o o/} v . ' ' === fo/ov'o/'o/ov 1'4'af'' ⇒ D 58";($ . ⇒ D 54($, .2 uT('H+Uyv%',bbv2yv ⇒ Xoyv ⇒ y ovv/ Xo v = % ' 'f ⇒ D 56 =($' . 'f ⇒ D 56 =($' C . q$'Q0 4(T !"O<~/Y(T . / 8v(T . P}(T .#$(T K , BT8+[8JB 8EI 2`D 56 =O ;' K1_ 8J*$+ R T8+[8JB/ 9["' QZ D 5' 1 4 . a K ,`I;W4V. / ./K 2 ^ ;54 QZ R T#$+/( >( ;54' 1 4 . a K b, 2 a C 4 1 −+ . h1. b 4 .b K (T ~/Y(T v(T }(T (T % X1 v 1 =⇒= P }4 } 4 =⇒= P =⇒= P oa ~/Y 2 a C 4 ,1 =⇒ −+ = 4'D 56 =($' X } K e%& v X;*(' 9+*+' 1 4 8B +≤ 4 9+4/41/ x H'9*+,A2%UfXo `D 56 = ;' %1b4fXoI4'1f/4fvD 56 =($ v * 5//.' H' !",O2V//.%Ufvo `D 56 =),O2 ;'QZ 1 4 . a %1b4bvafvo 'afI4'1b4fvoNvfCC 1fXP4fkD 56 =($' X k . 'afI4'1b4fvoNvfk 1fP4fCD 56 =($' C . 4"%#;<! ,#7 !"#$%!& 4^ 7+%& KE9) 4^ 7+%& 4^ 7+%&V!(8RTI' +6 = !"/4 =(B^ #] F+8\% S#$ F+ E 5 d 8S5 d(B^ 8%8&($ 7+%&Ld 48e 5 d(B^ 8%/ 5($ 48e 7+%&/I• 7+ B +6 = !"/*+%% SpK4 =*+BD!% (B^ #]4 =B$G(B^ #] $7*+ T ) g E#$+ $<6 =,*; /I0(4 =2#$ 7+%&, 5 d(B^ 4 =2 H' C ($ BT9€4P( C ($ (•BD4 X . (• 9g#]KP X . X BD 9g#]K * 8V8‚/8V6 QV8‚'K! % $<6 ="B_E 4J% % T %& " d($!8V8‚/\ $9|48V 8‚ QV6'K! B%[D 56 =($! 8V 6 uB^ +6 = !" (+7(B^ +6 = !" uB^ 8"',2(B^ σ uB^ 8D',f2V(B^ σ #$ π uB^ *',ƒ2V(B^ σ #$ π ?\l' uB^ 8",2BD%(B^ π , ∆ fo2 uB^ 8D,f2<%(B^ π , ∆ f2 uB^ *,ƒ2<%(B^ π , ∆ f2 K+$B 7+(B^ π +Z 7+#G4>B, ∆ f2 *T ∆ ',L0(B^ π #$#G2 e„ ' ∆ f 21, ∑ + ]1'% S)4 0 'L04 =)4 0 9+*+' 1 4 +Z 1 4 . a ' ∆ f 41+ Q'1/449"P4{1b 1 4 K +Z 1 4 . a K ' ∆ f 4 1 ++ ] "% SX Q'1/4/a/ 49"P4{1bb P4…B …/4(†B († e%& } X X X X X ?t9g'T ∆ v v v v .X X Y q X C C ~ (. Y X } Kv C } K. (+78V6 7+'D 5 7+*R9€ 5 d(B^ )4 = + 6 = XQV6 7+ #J8V6 7+ K! %[D 56 = 7+%&B&($!8V6 7+ *6(+78V6 7+ K!8V6B#J*; %5&($8V6%5 H' X N.#$ X N.N X K!8V6B#JId67*+&($8V67 *+ H'P K!8V6B#J#S T%5&($8V6%5 H' X NfN X P fN X C*R9€ \BD6 = !" D 50;'D 50;($E (+7D 5( R *UD`6 =*R9€($Dj4D`8Z YQV6( R #J8V6( R QV6( R($!8V6% 7+%&,[D 5 7+2 T B#JId6*0BD)4 = +6 =, 5B #J \BD6 =2 QV6,[D 56 =2 QV6 7+ D 5 7+B T B QV6( R D 5 7+0 \BDB T B pUE I0;5!" ;5 ^' H' X Nb( → I X N(b( ;5E' f b → + 1 / → X N X X;5 [' f → + 1 / , N 2 =(>#6 4"?@ABC.!D!.%/0#1 q$'Q0 4+$ +$o/CC !"5,/2 8v}(. @8B T< mB0(4 0‡ QL'k/kn#$k/kn q$'Q0 4+$ +$X/Y !"A 8Y/v(T . @8B #$C/Y .O 8SnB0(4 0 + A‡ QL'kY/}n#$C/Xn q$X'Q0 4+$ +$o/~ !"A 8/X. #$o/YC .T nB0(4 0 + A‡ QL ' Con/ v/v}n #$ YX/XXn e%& k q$C'.1%+$ +$o/v !"O/ 7+*@X4 0//.I;W 8 9:„*`p5 L. C 8Z#$I8%„*`pp5.8Z 4B0(*`p m o/Xv#$*`pp mo/kk * K%ˆ# G) L. C 8Z#$. + T E % R 4 ^ L. C #$.*r! $+‡ ! O8SnB0(4 0 + O QL'ConPv/v}nPYX/XXn q$Y'Q0 4+$ +$E (9+*+AI;W489:#$+E *`5 ]#D +9K 4%XB^ )#$B0(*`5 m/vkO 8SnB0(4 0 +A QL'~onPon q$v'K 9[8\X/+18R80 4+$ +$ !"A> 8X/X . #$o/~ .Tn4 0 + A QL'~onPon q$}'.1%+$ +$/Cv !" 8/Y~1D8P/v .#$/ov(T . @8B T $<n4 0QL'Y/nP}/XnPk/oYnPX/Cn q$k'Q0 4+$ +$X/~Y !"A 8X/X. P/ok .#$/Y~ K . X UZ BB6 T/v !"A%Z AK. X 8/k}A( TnB0(4 0 + QL'}/Y~nPX/o}nP}/vnP}/nPC/Yn q$~'.1%G +$/ !" 8/CC .T. I+„ /Y(T 99S,.2 o/oU 4%CB^ )/99SG(78F8%(7 4% B^ )!T $<n4 0QL'vonPX/XXnPv/v}n q$o'Q0 4+$ +$E ( !"A,//L2 8Y/vk(T BTI‰" ,8B 2Pv/vBT*+#$/+(]O8Sn4 0 +A QL'Xk/}nP~/}nPY/vnL 4"?@=F8GH5IJK q$'O8SB0(6 =) BT + ' * >B0)BTA80#]49+*r E >B0")80#]BDBT*r/Yk QL'CC8#PCC/X8# q$'O8SB0(6 =)BT + I' * C(BTA@8B Zo/k E %"kBTq 8*r R TX/BT+18+[8JB 8E#$ I ! UE (BT^ R T*r Y R T)[E (BT ",8+[8J B2QL'k8#Pko8#P}o8# q$X'UE jVBTA#$BT49+ +8%A^Yn R T`B0(6 =)Aq^ >B0")j80#]F *ro/Y q$C'`B0(6 =)A#$BTqq^ >B0)A80#]q*r#$jV /vkA#$/q^ R T*r/Yvk(T @8B QL'k8#PYv8# 4"?@LF8GMJK q$'O8SD 56 =+j + I' kY/knPC/nUfYv * Y/XnP~/CnPnKP}/Xn.>B0"80#]BDBT($C/oXC YC/YnP~/nPXv/Cn.Po/kk"^ R TC(@8B QL' C k P Y . KP C k . q$'6 T !"A5//. %B^ „;I' ' ' . f/Y'o/X}Y' uD 54)A * `D 56 =/*^ r($*4"^ R T/ok(T 8+@o + #$ o/Y QL' X v . q$X'Q0 4+$ +$o/~Y AIo/CC. #$o/ .#$YY/k( " @8B >B0)A80#]BDBT/oXuD 56 =AQL' Y .K e%& ~ q$C'Q0 4+$ +$o/+(E 49+*+*r(+1#-8)L;5 8}/~(T jBT@}X + #$X >B0")j80#] *rYXsXO 8SD 56 =) !" QL' C C q$Y'Eoo(" !"A,//.2#]ooo(+1(49V80 L;5 8jBT% R Tvoo(/+"] gjBTG(7% R T *rkoo(#$IB8„99SK.9G(7oo( R TBT8+[8J B 8E/I O8SD 56 =)A QL' X k . q$v'O8SD 56 =) !"A%B0(6 =*rv8#q^ rI;W)Id80 4 8%($BT*+#$] QL' q$}'QF/Xv !"A%5 "86 T*r"HH: ;BTK X I#$+Y(99S L. C ULB;51+/(1 G98 G#-8)o(K./YUT $<n) " +A QL'}nK q$k'Q0 oo X "E !"5//. +~oo X +1R TBT 8I ;5($/X(T I8%+"] gG}oo X BT#$I8%+(E„99S K.9>Goo X BTBT8+[8JB * ^ " `;5 E O8SD 56 =) !" QL' X v . q$~'Q0 4+$ +$o/C !"AV+I;W(<( „*`8d L. C 8Z#$*`($,.2 9/ 4*` mX/v#$*`%XoB^ ) * T $<n4 0 E O8SD 56 =A/*^ o/+(A%B0(o/C QL' X C . C q$o'Q0 4+$ +$ !"A<9[v/}(T . ,8B 2L;W4(< ( „*`8d . Y 4*` mX/vV„*`]#D +9 41 oB^ ) Š * TI0‡ E uD 5 d0I4D 56 =)A/*^ >B0)A80#] "($ QL'/kP C k q$'6 T/Y !"A 8/}v. Po/~ .#$(BT ",o + #$ 2UZ B^%"X A 8o/k~v(T "A,8B 2uD 56 =) A QL' Y . K q$'UE !"A5,//.2QR80 4+$ +$o/+(A<#-8)o/X+( . jBTI% R Tv/kk(T ,}X + #$ 2#$%B0(k/v * ^ " `;54#$ T eI0+()jI;5 E ^ (D 56 =)A QL' X v . X q$X'Q0 4+$ +$C/vE !"A 8X/v]H:BT. I#$+ 99S]#D + `8kB^ )/• ^#$+99S$499SK.9 ` 8 X/YB^ )!`D 54#$D 56 =)A QL' X k . X q$C'.1%+$ +$k !"5,//.2/I;WI(<( 8„X 99S L. C ~kn#$*`8d99Sq,.2 L T99S L. C G(7 ~o/Y~n/@99Sq,.2 7+}k/kB^ )#$99SG(78%8 ~/}B^ )! Tn4 0 * `D 56 =)A/*^ C/YAB%"% R T*r R T)/v+1 8+[8JB QL'ConPv/v}nPYX/XCn.P X v . X q$Y'Q0 4+$ +$X/v !"O 8jBTV. / .#$(H: j$4„*`599SAK. X sK. X @ 8E 4%/k}B^ )#$*` 5 m/}+*^ >% .#$(*S gH:BT + #$+oo(99S q,.2 U 8Y/}vB^ )‹/(&*•‹/(499S8FID(7%B^ )! * TB0(4 0 + E uD 56 =O/*^ B0(6 =)Oyoo QL' v ~ . C ( e%& o [...]... hoàn toàn: CnH2n-2 + O2 nCO2 + (n-1) H2O → 2 nCO2>nH2O nAnkin=nCO2-nH2O → Oxi hóa không hoàn toàn: → 3CH ≡ CH + 8KMnO4 3(COOK)2 +2KOH + 8MnO2 + 2H2O IV Điều chế: 0 2CH4 1500→ CH ≡ CH + 3H2 C H 2O CO CaO + 3C → CaC2 → Ca(OH)2 + C2H2 BÀI TẬP 1: Ankin là hidrocacbon: A Co dạng CnH2n-2, mạch hở B Co dạng CnH2n-1, mạch hở C Mạch hở, co 1 liên kết ba trong phân... 2H2O 3n + 1 CnH2n+2 + O2 → nCO2 + (n+1)H2O 2 nCO2 . ` R TBTG(7($YY( +8%% Co (*S g*@K./<G(7($. 9O8S)O, C o 2 q$}}'ECoo("E !"A,5//.2#](T. ^ L. C #$.*r! $+‡ ! O8SnB0(4 0 + O QL'ConPv/v}nPYX/XXn q$Y'Q0 4+$ +$E (9+*+AI;W489:#$+E. =)A/*^ C/YAB%"% R T*r R T)/v+1 8+[8JB QL'ConPv/v}nPYX/XCn.P X v . X q$Y'Q0 4+$ +$X/v !"O