Smithells Metals Reference Book Part 4 pot

Physical properties of molten salts 9-33 Table 9.5 ELECrRICAL CONDUcnVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MIXED IONIC MELTS- continued CdCI,-CdI, Ref. 43 CdCIz-KCI Ref. 47, 24, 3, 27 CdC1,-LiC1 Ref. 43 CdCl,-NaCI Ref. 24 CdC12-PbC12 Ref. 56, 27, 24 CdCI,-TICI Ref. 44,3 Cd1,-KI Ref. 43 Cd(NQ&-KNO, Ref. 46 C4CcI3 Ref. 95, 96 Ce-CeI, Ref. 86 CsBr-NaC1 Ref. 87 P koo Ksoo K600 K700 P GOO K600 K700 Ksoo P lES50 K650 K7S0 P K550 K60O K?O0 P Ks00 K600 K700 P KSOO K500 K700 P K500 KSOO P K200 K300 K700 K250 K30O P K200 IC25D K300 P KZOO K250 K300 P K200 K250 K150 K3OO P KSSS P Ks20 P Ksoo KESO 0 0.22 0.41 0.66 0.95 40 - - 1.55 1.81 0 6.0 6.4 43.9 - (2.25) (24) 2.7 0 1.44 1.88 228 0 1.35 1.70 1.95 0 - - 1.32 1.52 39.4 - - 0.26 36.9 - - 0.46 15.1 - - 0.31 9.0 - - 0.47 0.60 1.05 1.56 0.55 1.00 8.3 2.40 2.55 14.2 0.35 0.56 0.79 1.05 50 1.10 1.24 1.48 1.73 59.1 4.1 4.5 67.6 1.95 2.15 2.45 20 1.68 1.94 2.35 10 1.30 1.66 1.86 19.7 - - - 1.21 1.45 44.6 0.17 0.25 50.0 - - - 0.44 28.6 0.22 0.34 18.1 0.29 0.31 0.54 1.8 202 1.03 1.92 19.5 1.69 1.79 - - 332 0.18 1.03 1.30 60 1.11 127 1.48 1.66 81.2 2.8 3.2 3.5 82.5 1.9 2.1 24 40 1.97 2.36 25 1.12 1.56 1.76 35.5 - - - - 1.09 129 54.8 0.09 0.16 0.24 60.9 0.14 0.26 0.39 40.8 0.12 021 0.32 27.5 0.14 0.25 0.38 0.50 2.8 2.59 1.43 2.74 52.1 1.40 1.50 59.9 - - 1.32 1.57 70 1.19 1.36 1.60 1.78 92.9 2.3 2.6 3.0 92.6 1.85 2.0 2.3 60 1.97 231 40 1.24 1.52 1.72 64.3 0.30 0.66 1.06 1.26 64.5 0.07 0.15 0.23 70.0 0.12 0.23 0.35 51.7 0.10 0.20 0.31 37.1 0.1 1 0.22 0.34 0.46 3.4 3.26 2.07 4.75 59.2 1.21 1.30 - 100 - - 1.96 209 80 1.33 1.51 1.77 1.94 100 21 23 100 1.8 1.9 2.2 80 1.94 2.26 60 1.41 1.66 1.86 75.3 0.31 0.64 0.99 - - - 73.8 0.12 0.20 17.8 0.08 0.18 0.31 61.6 0.10 0.19 0.29 47.0 0.08 0.17 0.28 0.40 3.9 3.81 2.87 8.88 - 90 1.52 1.71 1.97 2.09 100 1.88 2.20 80 1.81 1.99 89.8 0.57 0.89 - - - - 82.9 - - 0.15 84.4 0.04 0.12 0.23 70.6 0.08 0.16 0.26 57.1 - - 0.23 0.34 4.7 4.45 3.7 15.5 100 1.96 218 2.25 - 100 1.97 2.10 100 0.41 0.95 - - - 78.9 - - 0.20 67.4 - - - 0.26 5.3 5.35 6.1 c. 60 9-34 Table 9.S ELECTRICAL CONDUCTIVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MlXED IONIC MELTS- continued Physical properties of molten salts CsBr-ZnSO, Ref. 62 CsCI-NaBr Ref. 87 CsC1-TiCl, Ref. 88 CuCl-KC1 Ref. 47 Cuo-V,05 Ref. 74 CuZS-FeS Ref. 60 Dy-DyClt Ref. 89 Er-ErCl, Ref, 89 FeO-SO, Ref. 41 FeO-TiO, Ref. 63 Fez 03-Vz0 I Ref. FI GdGdBr, Ref. 89 Gd-GdC13 Ref. 89 HgBr,-NH,Br Ref. 32 HgCIz-HgIp Rei. 19 HgCI,-NH,CI Rei. 32 HgCI,-TINOa lief. 19 P K550 P K8OO K8SO P Kg00 P K505 K450 K500 K550 K600 P K8OO KIOOO P KllOO KlSOO P K.100 P K900 K1300 K820 P K1400 P K1300 Icl3O0 R1400 P K9OO KlOOO K1100 P K8ZO P K650 P K2SO K300 P KIPS K250 K300 P K250 K300 P K225 K250 K215 39.8 0.03 0.05 29.4 2.05 2.15 52.1 0.7 25.8 - - - 2.22 10 0.6 1.4 2.2 0 1.530 1.490 0.0 0.42 0.0 0.50 55.9 0.5 0.8 32.6 48 48 15.0 1.4 2.0 3.6 0.0 0.47 0.0 0.41 61.19 0.4 0.55 0 - - - 0.028 0 71.42 0.7 0.95 0 0.4 1 6 0.476 0.536 63.8 0.09 0.13 52.2 1.61 1.70 62.3 0.7 42.0 2.00 2.07 218 232 30 3.2 5.0 - 25 9.30 9.40 9.50 0.9 0.46 1 .o 0.55 63.3 0.9 1.6 35.7 50 47 19.4 3.8 5.8 10.6 0.4 0.58 0.3 0.43 78.63 0.5 0.7 20 0.029 5 0.028 1 0.025 2 81.82 0.9 1.15 10 0.344 0.397 0.450 79.9 0.20 0.26 71.0 1.50 1.58 72.0 0.8 47.6 208 215 226 240 40 3.8 6.0 - 35 8.20 8.30 8.30 27 0.54 3.0 0.67 68.6 1.4 23 56.5 40 34 30.5 6.8 11.6 - 1.3 0.87 0.6 0.45 84.66 0.6(2) 0.8(2) 40 0.016 0 0.0160 0.0160 83.54 0.7 1.1 20 0.274 0.320 0.368 87.0 1.45 1.55 81.5 0.9 57.5 2.23 232 2.44 2.59 50 5.5 10.0 - 50 4.60 5.20 - 4.9 0.65 3.8 0.69 12.4 2.1 4.0 62.1 38 33 2.3 1.27 1 .o 0.49 89.57 0.6 0.75 50 0.009 4 0.009 7 0.0104 86.12 0.8 1.15 40 0.184 0.226 0.269 90.8 1.2 76.0 2.71 2.82 2.94 3.08 65 3.30 4.60 - 7.8 0.76 75.4 32 5.0 91.9 145 155 2.7 1.46 93.64 0.45 0.6 60 0.005 3 0.005 6 0.006 3 9221 0.55 0.75 50 0.150 0.186 0.222 85.9 2.93 3.06 3.20 3.34 75 220 3.80 - 12.0 0.90 78.7 4.2 7.8 97.2 225 - 100 0 0 80 0.001 1 0.002 0 93.84 0.78 1 .o 60 0.126 0.156 0.188 - 100 3.32 3.43 3.54 3.66 100 0.50 1.30 1.70 16.7 0.98 84.9 9.0 - 100 - - O.Oo0 8 9531 0.4 0.6 75 0.100 0.126 - Physical properties of molten salts 9-35 Table 9.5 ELECTRlCAL CONDUCTIVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MIXED IONIC MELTS- continued HgIZ-KI Ref. 44 HgIZ-NHJ Ref. 32 HgIZ-TINO3 Ref. .I9 Ho-HoC1, Ref. $9 K-KBr Ref. 73 K-KCI Ref. 73 K-KF Ref. 90 K-KI Ref. 90, 91 KBF4-KF Ref. 92 KBr-KNO, Ref. 43 KBr-NaC1 Ref. 93 KBr-RbCl Ref. 94 KBr-TlBr Ref. 97 KBr-ZnSO, Ref. 48 KCI-KI Ref. 57 P Kzw K270 K31O P Kzm K350 P KZld K250 K300 P %DO P K763 KS70 P K816 P K900 P K~OO P K700 P K60D K700 KSOO P IC400 K6O0 K700 K800 P K8OO KS50 P K.900 K170 K850 P a 10% t range 1036 P Kb15 K500 K550 P K700 %DO K900 73.3 0.50 0.56 67.64 0.3 0.6 0 0.476 0.536 0.596 0.0 0.53 1 5.6 6.8 1 3.8 1.35 4.5 0.5 4.5 0.5 3.7 30 - - - 5.0 0 032 1.38 - - 33.7 2.97 3.05 19.7 1.64 1.70 1.80 2.2 0.489, 3.239, 0.835, 537-70 I 35.8 0.10 0.12 0.16 2.8 1.31 1.52 1.66 80.4 0.48 0.56 0.64 75.82 0.4 0.5 20 0.302 0.348 0.395 0.7 0.56 2 11.7 16.3 2 6.2 2.72 6.7 1 .o 8.5 1.2 7.9 40 - - 8.0 17.2 0.79 1.34 - - 57.6 251 260 39.5 1.64 1.70 1.80 5.3 0.441, 2.957, 0.49g1 473-640 40.0 0.15 0.21 7.8 1.38 1.56 1.72 - 86.5 0.64 0.69 0.75 82.47 0.5 0.73 40 0.174 0.210 0.248 3.2 0.69 3 22.4 29.5 4 14.1 4.10 12.0 1.5 13.5 2.6 19.7 50 3.0 10.0 37.0 0.78 1.29 - - - 85.9 2.20 2.29 59.5 1.64 1.70 1.80 9.7 2.008, 3.845, 7.546, 650-762 K,=a+bt 91.6 0.64 0.69 0.75 87.98 0.6 0.77 50 0.154 0.182 0.214 6.3 0.84 4 40.8 51.3 6 31.6 4.80 18.0 2.0 19.0 13.5 500 60 5.3 11.5 54.1 1.30 - - - - 89.0 1.95 2.05 81.3 1.65 1.72 1.82 18.4 23904 8.864, 4.9049 619-717 etz 44.4 50.2 - 0.13 0.14 0.16 0.19 0.23 13.3 26.8 1.41 1.48 1.61 1.70 1.76 1.88 96.1 0.43 0.45 - 92.62 0.55 0.7 60 0.136 0.161 0.187 10.6 1.05 6 104.7 129.0 8 64.6 - - 26.0 1500 70 1 .o 6.8 12.5 70.2 1.31 1.53 1.76 - 30.3 0.475, 3.284, 0.84S0 626-791 60.0 0.21 0.25 0.33 41.2 1.56 1.80 1.97 100 0.03 0.03 - 96.58 100 0.37 0.03 0.4 0.03 80 100 0.142 - 0.156 0.0305 0.171 0.0280 8 229.2 263.0 10 117.5 - - 48.7 64.9 4200 7300 80 90 20 1.5 7.2 6.7 128 12.6 86.9 io0 - - - - 1.53 I 1.76 1.76 53.9 720 0.808, 0.4265 4.267, 5.3320 1.47g0 0.865* 687-796 718-783 64.7 73.0 0.24 0.34 0.29 0.41 0.39 0.55 64.4 1.66 1.96 214 9-36 Table 9.5 continued Physical properties of molten salts ELECTRICAL CONDUCTIVRY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MIXED IONIC MELTS- KCI-LiCI** Ref. 57, 10 KCI-MgClz Ref. 56, 37, 16, 9, 7 KCI-NaBr Ref. 93 KCI-NaCI** Ref. 57, 16, 9, 6, 3 KCI-NaI Ref. 43 KC1-PbCI, Ref. 98, 47, 27,24 KCZ-RbBr Ref. 94 KCI-SnCl, Ref. 99 KCI-TiC13 Ref. 88 KCI-ZnCI, Ref. 66 KCI-2iSO4 Ref. 48 KzCrz07-KN03 Ref. 44 KF-NaCI Ref. 6 P KS00 K600 K700 KSOO P K600 K700 KSOO K900 P KSOO KS50 P KSOO K9OO P K700 %SO0 K700 K800 P 550 Ks00 Ksoo Kss0 K700 P 500 %so 470 K8S0 P K300 IC350 P K800 P KSOO Ksso Ksoo K6S0 P K475 Ksoo Ks10 P K3S0 K400 K415 P Ksso K950 K750 0 - - 6.17 6.62 10 1.10 1.33 1.50 22.0 264 2.76 18.7 3.23 3.50 0 2.41 2.68 2.8 1.414 1.645 1.868 2086 - - - - - 9.9 1.42 1.50 1.59 0.0 1.115 1.388 326 1 .o 0 0.09 0.16 0.26 0.37 19.0 0.09 0.14 0 0.56 0.72 0.95 33.20 2.6 3.4 4.2 - 28.2 3.51 4.10 4.56 20 1.17 1.37 1.54 32.0 2.40 253 321 298 3.24 8.0 1.88 2.20 2.51 4.5 1.176 1.401 1.609 1.807 2018 - - - - 22.7 1.58 1.65 1.73 4.1 1.079 1.331 42.0 1.05 10.5 0.40 0.51 0.63 0.76 24.0 0.09 0.12 0.16 24.4 0.52 0.66 0.88 49.85 2.9 3.6 4.3 426 23 1 287 3.42 3.82 30 0.97 1.21 1.39 1.56 51.4 2.29 2.39 40.6 252 285 3.11 19.8 1.68 2.04 2.37 6.1 1.142 1.345 1.558 1.723 1.913 - 39.8 1.70 1.77 1.89 8.7 0.995 1.215 53.0 1.3 17.8 0.64 0.77 0.90 1.02 29.3 0.13 0.17 0.24 421 0.42 0.64 0.74 66.54 32 3.7 (4.4) 55.8 1.87 240 288 3.24 50 0.98 1.24 1.44 1.62 74.0 2.21 232 54.8 235 264 2.88 33.0 1.54 1.86 2.16 14.8 1.034 1.205 1.364 1.515 1.684 - 63.9 1.88 1.98 209 14.1 0.865 1.M 65.9 1.5 26.3 0.70 0.82 0.95 1.06 33.7 0.16 0.21 0.27 55.5 0.35 0.48 0.67 100 4.1 4.5 - 72.2 1.90 2.35 2.72 60 0.97 1.27 1.48 1.67 - 64.8 221 253 276 49.7 1.51 1.84 2.44 20.7 0.937 1.106 1.273 1.417 1.572 1.716 20.3 0.688 0.871 81.4 1.8 35.9 0.76 0.89 1.01 1.14 39.8 0.21 0.25 0.32 74.4 0.22 0.34 0.52 87.6 - - 204 2.36 70 0.98 1.34 1.56 1.75 829 234 256 73.6 1.87 217 37.9 1.038 1.174 1.306 1.467 1.624 - - - 27.8 0.472 0.645 526 0.78 0.92 1.05 1.19 50.0 0.30 0.35 0.44 87.1 0.17 0.26 0.41 100 - - - 2.24 80 1.48 1.76 1.87 - 100 - - 2.22 51.2 - (1.110) 1.230 1.350 1.519 1.670 31.9 0.702 - 58.7 0.79 0.95 1.09 1.24 56.8 0.36 0.41 0.51 100 0.20 0.35 - Physical properties of molten salts 9-37 T&e 9.5 ELECTRICAL CONDUCTIVITY OF MOLTEN BINARY SALT SYSlZMS AND OTHER MIXED IONIC MELTS- conrimred KI-NaCl Ref. 43 KI-ZnSO, Ref. 4% KNOZ-NaNO, Ref. 82 KN03-LiN03 Ref. 101 KNOS-NaNO3** Ref. 19, 101,79, 1 KNOa-RbNO3 Ref. 45 K2S04-ZnS0, Ref. 62 KzTaF,-Ta,05 Ref. 102 KzT3F,-TiOz Ref. 102 KzW04-WO3 Ref. 103 La-LaBr3 Ref. 89 La-LaC13 Ref. 85 La-La13 Ref. 86 P K600 K700 K800 P K440 K460 K480 P a l@b 10% t range P K300 K340 K380 K4Z0 K460 n 33.6 - - 3.06 47.4 0.09 0.12 17.5 - 3.660 6 0.942 8 - 5.010 1 760-869 - 55.0 224 258 50.9 0.08 0.10 27.5 0.336 5 614-804 - - -3.3120 - 1.058 9 74.1 86.9 1.56 1.35 1.87 1.64 2.20 1.91 54.8 60.4 0.11 0.13 0.13 0.16 0.15 0.18 43.0 52.2 -1.9820 -1.2083 0.534 5 0.333 3 -2.4426 -1.2061 654-783 642-794 Kf =a+ bt +et2 120 23.6 32.7 1.262 1.176 1.108 1.472 1.380 1.308 - 1.586 1.510 - - - - - - 66.0 ;,= -0.3788+3.4O x at 160-240 K,= -0.4037+3.47x 10-3r at 240-400 P KID0 K400 KlM) P K3OO K4co P KSOO K3S0 K450 K550 P K8OO K900 P K870 K920 P a 10Zb 10% t range P K8ZO P K9lO P 0 20 - 0.820 1.364 1.160 1.720 1.496 7.1 18.6 - 0.40 0.51 0.52 0.63 0.65 31.6 41.8 0.04 0.06 0.06 0.08 0.07 0.12 78.0 83.4 0.71 0.80 0.85 0.94 81.9 87.5 1.18 1.22 1.29 1.33 37.4 50.5 2.8156 2.8809 0.5601 0.6150 2.0875 2.501 1 891-1010 759-912 40 0.706 1.024 1.351 31.4 0.42 0.55 0.68 52.0 0.05 0.08 0.12 89.0 0.87 1.00 92.3 1.28 1.37 58.3 2.311 1 0.549 2 2.4324 754-770 45.1 1.244 1.434 1.625 1.052 - M 0.652 0.966 1284 40.7 0.57 0.70 - 94.5 1.04 94.5 1.30 1.39 67.4 2.3562 0.565 0 2.392 3 674-819 0.91 Kf = -a + bt -cr2 0.0 0.4 1.2 2.5 0.70 0.94 1.55 3.15 0.3 1.1 2.0 3.0 1.51 1.84 2.46 3.21 0.5 1.4 2.4 3.5 0.87 2.39 5.54 122 94.2 b47 1.73 62.9 0.15 0.18 0.20 60.0 0.8329 583-705 - -27280 -5.3073 55.3 0.998 1.185 1.366 1.548 - 60 0.625 0.931 1.234 56.0 0.59 0.73 - 100.0 0.92 1.05 96.6 1.31 1.40 76.6 5.493 6 1.250 1 5.882 2 773-955 4.1 7.35 4.6 5.02 4.4 20.9 100 1.32 1.52 67.3 0.21 0.24 0.28 79.4 91.0 6.0644 4.2506 8.173 1 5.507 5 - -1.2999 -0.8537 882-934 74.2 1.040 1204 1.365 1.525 - 80 0.572 0.874 1.178 73.3 0.63 0.77 - 98.3 1.39 1.48 85.0 7.543 6 1.640 2 877-995 83.3 - - 1.130 1.287 1.442 100 0.818 1.107 86.0 0.64 0.79 - - 100 1.40 1.49 922 38.80 7.964 6 7.5248 39.636 842-1 016 885-1 029 5.5 6.5 15.8 25.9 6.2 7.21 9-38 Physical properties of molten salts Table 95 mtinued ELECTRICAL CONDUCTIVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MIXED IONIC MELTS- Li3AlFs-Na3AIF, Ref. 80, 65 L~,MoO~-MOO~ Ref. 100 LiN0,-RbN03 Ref. 52 LizW04-W03 Ref. 103 MgC1,-NaCI Ref. 37, 56, 16, 9 MgFz-Na3AlF6 Ref. 72 MnO-Si02 Ref. 81 MoO,-Na,MoO, Ref. 54 Na-NaBr Ref. 73 Na-NaCI Ref. 73 Na-NaI Ref. 90 Na3AIFs-NaF$ Ref. 65,39,34, 12 NaBF4-NaF Ref. 92 P Kiooo 103~ P 10’b 10% t range a P K200 KZSO K300 P 1026 10% t range a P KSOO K~OO P bso Kgn P a K700 io-% P Ksoo K9OO P KE03 Ks94 P K848 Ks93 P K~OO Ksoo K7OO K9OD P KtOOO KlOSO Kiioo P %OD %OD 600 Ksoo 20 30 50 80 3.05 3.38 3.80 4.33 4.8 4.8 4.8 4.8 K,=K~OO~ +a(c - t OOO) at 762-936 19.5 10.470 8 2.498 1 13.536 778-917 10.5 - - 0.43 54.6 6.015 2 1.333 6 5.594 8 805-952 23.2 2.80 2.96 3.12 5 2.5 40 2.32 4.8 - 21.4 1.06 1.45 - 0.25 4.0 4.8 0.25 4.3 4.4 0.4 3.7 4.5 5.0 0 5.4 5.1 5.9 40 - - - 6.5 33.9 7.490 5 1.8153 9.358 9 800-907 16.7 0.20 0.33 0.47 59.7 2.149 1 0.455 8 0.392 3 769-924 39.1 2.31 249 2.67 10 2.2 - 50 2.26 4.1 log K,= 26.4 1.07 1.41 - 0.5 6.3 7.7 0.5 4.9 5.0 0.6 3.5 6.5 20 4.9 5.1 5.4 50 3.0 5.0 120 - - 51.5 60.5 4.031 1 4.6127 1.0289 1.1832 4.489 7 5.21 1 7 768-917 799-945 K,= -a+bt-ctz 23.8 31.9 0.24 - 0.36 0.41 0.51 0.56 69.0 77.5 7.4648 0.6063 1.7642 0.1086 7.6694 -1.9898 757-938 735-890 K,= -a+bt-ct2 57.2 69.0 1.97 1.78 2.16 1.98 2.35 218 55 60 1.85 2.25 3.1 3.4 a-b/(t+273) at 1600- 51.2 62.2 0.86 0.80 1.17 1.11 - - 0.75 1.0 1.4 8.2 9.7 11.5 0.75 1.0 5.3 5.7 5.5 5.9 1 .o 1.3 6.5 - 8.0 10.0 40 60 4.4 3.9 4.6 4.0 4.8 4.2 60 70 1.5 3.0 5.0 6.0 8.0 10.0 14.0 15.0 - - 71.3 2.795 8 0.753 9 2.887 845-956 52.3 0.53 0.72 85.2 5.259 7 1.277 3 4.823 7 - 716-897 81.5 1.63 1.82 2.01 65 2.94 4.6 1 800 71.2 0.75 1.08 - 1.5 14.7 1.5 6.4 6.7 1.6 - - - 122 80 3.3 3.5 3.6 80 3.5 6.5 10.5 15.5 85.2 21.3359 5.368 6 30.734 764-872 65.2 0.61 0.82 923 5.723 7 1.404 8 5.7978 734-907 - 90.3 1.39 1.57 1.75 70 221 2.5 83.1 0.63 0.75 - 2.0 17.5 - 20 - - 15.0 90 3.1 3.2 3.3 90 4.0 7.0 10.5 15.0 91.0 13.2305 3.225 9 16.322 809-908 80.8 - - 0.96 80 2.00 1.7 863 0.91 1.16 - 100 28 2.9 3.1 Physical properties of molten salts 9-39 Table 93 ELECTRICAL CONDUCTIVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MIXED IONIC MELTS- continued NaBr-NaOH Ref. 70 NaCI-Na,C03 Ref. 6 NaC1-NbC1, Ref. 20 NaCI-PbCl, Ref. 17 NaCl-TiCl, Ref. 88 NaCL-ZQ Ref. 20, 104 NaF-SrF, Ref. I1 NaI-NaOH Ref. 70 NaN0,-NaNO, Ref. 43 Na20-Ti0, Ref. 64 Na,WO,-WO, Ref. 103 Nd-NdBr3 Ref. 89 Nd-NdCls Ref. 85 Nd-NdI, Ref. 86 PbBr,-PbC1, Ref. 59, 3 P K300 K400 P KTOO %SO KlOOO P Ksoo KS50 P K500 K600 P Ksoo P KSOO K82S K35O KS50 P t K P K300 K400 P K300 K350 K400 K450 P KlOOO Ki 100 KlZOO P a 102b 10% r range P K730 P Ks55 P K820 P K450 K500 Ksso 17.7 1.18 2.00 0 2.4 2.8 43.8 1.32 1.83 0 1.445 1.91 27.5 1.75 11.5 0.46 - - - - - 900 4.441 21.5 1.14 1.90 0 1.16 1.36 1.55 28.3 0.32 0.74 45.9 4.450 9 0.962 5 4.036 4 - - 780-923 0.4 0.53 1.7 1.20 0.3 0.476 0 1.43 1.69 - 25.0 1.14 1.96 52.45 2.2 3.1 3.1 60.4 2.20 2.60 255 1.51 1.95 36.2 1.75 34.9 1.45 - - - - 950 4.798 35.0 0.87 1.53 21.3 1.02 1.27 1.51 1.73 41.7 0.32 0.45 1.03 50.9 7.001 3 1.547 6 7.0320 750-888 1.5 0.61 24 1.24 0.9 0.585 23.7 1.34 1.56 I 30.4 1.03 1.83 68.81 2.3 3.0 3.4 60.7 2.19 2.59 9.01 1.58 2.005 47.0 1.9 59.7 1.74 1.83 1.97 33.3 loo0 4.961 44.8 0.72 1.32 44.8 1.11 1.34 1.58 1.79 44.6 0.38 0.56 1.16 55.7 4.563 4 1.032 6 4.455 5 - 39.8 0.95 1.75 71.8 298 20.05 1.645 2.07 60.3 23 75.1 2.41 2.83 3.01 - - - 1050 5.407 52.8 0.63 1.23 65.4 1.19 1.44 1.69 1.92 51.7 0.47 0.80 1.55 65.1 7.2754 1.720 1 8.5600 767-905 741-881 K,= -a+bt-crz 3.6 7.5 0.79 0.94 3.8 7.3 1.32 1.54 2.1 5.2 0.759 1.033 45.3 66.6 1.02 0.97 1.25 1.17 1.45 1.36 48.4 0.83 1.63 73.6 294 - 77.4 2.7 88.1 2.88 3.08 3.34 - - 1100 5.642 82.1 1.25 1.51 1.78 2.02 60.0 0.56 0.90 1.76 74.2 3.1368 0.7399 2.4220 689-850 11.4 1.01 11.0 1.67 8.1 1.102 83.8 0.91 1.10 1.26 523 0.79 1.59 100 3.34 3.60 88.7 2.68 3.36 - - 100 1.34 1.62 1.89 2.10 65.5 71.6 0.70 0.86 0.94 1.15 2.10 2.54 83.0 91.6 6.0743 2.7481 1.5506 0.671 8 7.194 3 2.495 8 653-803 701-869 13.9 15.4 0.96 0.92 14.6 18.6 1.77 1.84 11.1 11.5 0.980 0.930 100 0.84 1.03 1.19 9-40 TaMe 9.5 ELFflRICAL CONDUCI’IVITY OF MOLTEN BINARY SALT SYSTEMS AND OTHER MXED IONIC MELTS- continued Physical properties of molten salts PbO-SiOa Ref. 105 Pr-PrBr3 Ref. 89 Pr-PrI, Ref. 86 RbCI-TiCl, Ref. 88 VCI, in KCI-NaCI (equi-molar: 56.1% KCI) Ref. 106 61.4 -1.9 0.5 0.66 0.3 0.61 43.9 0.95 9.6 0.22 3.68 (810) -2.9 71.2 78.8 -2.0 -1.2 -1.2 -0.6 1.1 25 0.80 1.10 1.3 2.6 1.28 248 54.0 64.6 0.95 1.0 12.8 17.9 0.48 2.34 (610) 3.77 (790) 3.94 (790) 84.8 -0.7 -0.2 4.1 1.47 4.2 4.24 75.8 1.2 22.4 1.30 3.94 89.7 -0.3 0.0 5.8 1.90 6.3 8.25 87.6 1.4 29.7 3.85 1.18 (605) 93.7 97.1 0.0 0.2 0.2 0.6 8.6 8.7 2.38 2.67 8.1 8.9 14.8 21.0 39.7 52.0 1.46 0.050 3.68 (795) 293 (805) ~~~ *See also Na,AlF6-NaF. ** See ulso ‘Physical Propties Data Compilations Relevant to Energy Storage I1 Mohcn Salts: Data on Single and Multi- Component Salt Systems’, I. Janz et al., NSRDS-NBS 61, Part 11. t Melts may contain up to l%MgO. t See ulso AIF,-Na,AIF,. REFERENCES TO TABLE 9.5 1. H. M. Goodwin and R. D. Mailey, Phys. Reo., 1908, 26, 28. 2. V. A. Izbekov and V. A. Plotnikov, J. Russ. Phys-Chem Soc., 1911, 43, 18. 3. C. Sandonnini, Gazz. Chim. Id., 1920, SO, 289. 4. K. Arndt and W. Kalass, Z. Elektrochem, 1924, 30, 12. 5. V. A. Plotnikov and P. T. Kalita, J. Russ. Phys Chem. Soc, 1930, 62, 2195. 6. E. Ryschkewitsch, Z. Elektrochem., 1933,39, 531. 7. S. V. Karpachev, A. G. Stromberg and 0. Poltoratzkaya, 3. phys. Chem (USSR), 1934,5, 793. 8. V. P. Barzakovskii, Proc. 1st All-Union Cod. on Non-Aqueous Solutions, 1935, 153. 9. K. P. Batashev, Metallurg. (USSR), 1935, 10, 100. 10. S. V. Karpachev, A. G. Strombexg and V. N. Podchainova, J. Got. Chen (USSR), 1935, 5, 1517. 11. M. de Kay Thompson and A. L. Kaye, Trans. Electrochem Soc., 1935,67, 169. 12. K. P. Batashev, Legkie Metal., 1936, 10, 48, quoted by V. P. 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[...]... conrinurd P 91650 91750 tlleoo 20.0 4. 6~106 263000 33100 16600 30.8 24x105 50100 7 940 49 00 36.9 40 .9 3.2~105 1 8 ~ 1 0 5 26900 15100 42 70 2 340 2570 1350 28 .4 63.1 5.53 4. 03 3. 14 80.2 5. 24 3. 94 3.05 57.8 1380 780 580 62.9 42 20 2 240 1660 - - 4. 56 3. 54 4 .45 3.38 36 .4 47 42 .0 360 210 180 130 - ~ 100 4. 83 3.73 2.97 4 60 ~~ 620 370 300 45 .2 50.0 - - 40 70 690 390 890 160 100 69.7 5820 43 00 * See also ‘Physical Properties... 84 92 101 100 74 85.8 94. 4 83 91 99 99.1 77 81 89 65.6 - 160 149 87.1 - 98.5 75 80 88 - - 197 - 0 15.9 162 163 163 33.6 160 144 - - 92 - 61.6 1 94 178 166 70.0 137 123 122 89.0 80 87 95 35 .4 235 232 238 41 .4 1 84 179 185 50.0 80 88 - 90.0 78 86 95 100 80 86 94 47 .4 106 103 59.0 110 106 67.2 1 14 112 - 132 135 35 .4 49.6 - - 303 292 247 237 20.5 29 .4 98 94 P - 822 146 147 149 0 93 89 O9SO 73.3 176 150 140 ... 119 94. 5 121 972 122 100 127 17.8 315 317 317 23.9 328 328 328 27.8 338 33.5 - - 43 .1 - 3 34 332 352 349 369 3 64 381 3 74 49.1 31.8 58.3 129.6 125.0 0.0 74 0.059 0 0 liquidus-c 40 0 a1100 Li,SO,-NaCl* Ref 7, 6 0 109 1 04 95 38.8 131 125 116 65.5 148 143 1 34 81.6 168 1 64 157 94. 5 198 1 94 187 98.7 208 2 04 196 100 2 24 220 211 P 0 38.0 105 97 92 57.9 126 120 1 14 68.1 140 1 34 - 78.6 155 149 145 89.2 179 1 74 168... 7350 745 0 Yl5-.I Y 140 0 5 84. 0 YlOOO Ref 30 YlZSO FeO Ref 28 1 34. 8 0.015 595 GaCI, Ref 24 600-660 a b t0 66 56 45 GaCI, Ref 17 Yso YllO Y 140 BiCIJ Ref 6 Y275 732s Y375 67 59 53 GeO, Ref 21 Y1ooo YlZOO Y 140 0 BrF, Ref 18 92.5 0.069 41 4 42 1-597 1 14. 25 98. 84 83.75 Cs2SO4 r BiBr, Ref 6 73 .47 64. 77 53.17 56.6 0.18 170 166-170 27 24 21 241 253 265 727 37 36 34 HgBrz Ref 8 Y 241 Y45 7276 64 60 BrF, Ref 18 79 24 22... ‘I 140 0 - - - 23.9 32 800 2 240 372 46 8 OM) 107OM) 24 OOO - 38.7 7 940 661 81 ‘I1600 - 29.9 15 100 1350 200 - - 120 21.8 12000 2 190 1120 710 25.9 44 70 loo0 580 40 0 - 28.9 - 33.2 - 42 700 17 800 8 320 16.1 50 100 8 320 3 890 2 040 510 300 200 220 140 100 72 52 41 34. 8 610 360 280 35.5 46 0 270 210 36.2 350 200 180 40 .1 250 150 120 41 .4 190 120 110 85 4. 8 90 5.9 95 6 .4 97.5 6.7 2.8 3.27 2.67 2.21 1.91 4. 2... Principal references are in bold type + AgBr-AgCI Ref 12 P 0 - %+ a 1.98 1.68 ij520 tlsao AgBr-KBr Ref 12 57.1 P - k00 boa qioa ~ tl?oa 0 0 2 .46 1.86 283 227 88.9 2.12 1.62 1.28 100 208 1.66 1 .40 44 .5 67.6 2 .47 1. 84 1.65 61.1 1.61 1. 24 80 .4 210 1.56 1. 24 9.8 4. 13 2.59 1.99 24. 1 3 .47 230 1. 84 4.56 2-75 1.87 100 240 1.78 1. 74 0 p 100 3.38 269 2.28 - 1.63 1.28 q6oa 86.0 84. 0 3.12 2 .46 2.09 3.55 54. 3 q500... 87 90 84 90.7 94 0700 CdCIZ-NaCI Ref 16 1 6 21 93 87 88 84 100 82 81 81 78 - 0.900 CdCI,-PbClz Ref 16 0700 1 14 4 40 108 101 6 16 98 92 8 25 90 85 9 26 85 8 1 0 126 116 1 41 116 108 3 18 107 11 0 49 .7 98 93 90 87 0 585 31 588 0 2 24 220 21 1 16 205 201 1 94 32 193 188 181 48 189 185 177 1 52 163 160 1 54 1 24 116 2 74 - 3 86 97 94 - - 4 9 -0 93 91 90 64. 7 103 94 92 P P 0600 c700 Cr,O,-FeO Ref 4 P CSCI-LipsO4... 47 .9 13.6 8.6 6.5 5.5 67 .4 19.6 12.6 8.7 7.0 13.8 2.3 - 19.9 - 2.3 7 .4 2 .4 52.8 - 27.2 7.0 2.2 35.9 19.5 5.6 1.9 46 .6 13.8 4. 2 1.8 71.6 19.1 9.6 6.0 4. 3 79.7 18.1 9.2 6 .4 4.6 - - 5.8 7 .4 5.1 6 .4 4.8 62.7 18.2 8.9 5.6 4. 1 2.5 6.5 5 6.3 10 5.7 562 9.6 3.2 1 .4 83.5 15 4. 8 - I - 41 .9 - AlF3-Na3AlF6 Ref 7 A1203-Na3AiF6 Ref 7 p 11000 2.5 6.9 5 6.9 10 7.1 P 44 .5 49 .2 30 900 6 170 1900 54. 9 35 so0 8 710 3 160... references are in bold type AgBr-AgC1 6 Ref 1 P os00 0600 AgBT-AgI Ref 16 P 160 6 64 158 155 84. 0 155 152 100 152 148 1 67 122 118 3 48 127 123 5 45 133 130 7 62 11 4 138 100 152 148 2 83 96 92 5 13 99 96 7 03 11 0 8 63 113 110 100 146 146 326 112 105 5 63 117 110 72.6 13 2 117 8 86 136 19 2 100 171 166 0 137 127 1 14 139 129 2 56 144 1 34 43.7 10 5 142 67 .4 100 160 152 16 1 171 2 25 161 2 005 7 0 4. .. 100 175 172 0 107 100 28 .4 65.7 126 120 78.1 133 126 93 .4 160 1 54 - 103 47 .1 117 111 0 1 14 100 17 .4 115 100 44 .8 121 108 65.5 126 116 88.3 137 125 100 25 149 5 150 10 152 15 155 0 585 5.5 555 15 .4 543 22.3 573 0 83 81 20.9 78 76 41 .3 74 72 61.7 71 80.9 68 66 100 67 109 68 148 140 92.8 144 141 100 171 Physical properties of molten saks 9 -47 Table 9.1 SURFACE TENSION OF MOLTEN BINARY SALT SYSTEMS AND . 66. 54 32 3.7 (4. 4) 55.8 1.87 240 288 3. 24 50 0.98 1. 24 1 .44 1.62 74. 0 2.21 232 54. 8 235 2 64 2.88 33.0 1. 54 1.86 2.16 14. 8 1.0 34 1.205 1.3 64 1.515 1.6 84 - 63.9 1.88. 1. 64 1.70 1.80 5.3 0 .44 1, 2.957, 0 .49 g1 47 3- 640 40 .0 0.15 0.21 7.8 1.38 1.56 1.72 - 86.5 0. 64 0.69 0.75 82 .47 0.5 0.73 40 0.1 74 0.210 0. 248 3.2 0.69 3 22 .4 29.5 4. 2.5 142 5.6 598 2.5 143 24. 7 46 .7 169 1 64 1 64 160 16.7 34. 8 122 127 118 123 28.3 51.3 96 99 92 96 326 56.3 112 117 105 110 11 .4 25.6 139 144 129 1 34 46 .5 72 .4 130.3 140 .1