I. pIIAN {]ItrtJNG CIIO'r'A'f' CA 'l'fti Stltl: (40 cliu, tit'cfiu I tlin ciiu 40) Ciu l: Cho clr-urg clich circ mu0i sau: NallSor; Nal{Cor; (NI.l'r):So'r: NaNO;: Nar(lol:'/n('h: ('LrSor Cl-lrCOONa. 56 dLrng clicli c6 gi6 tri pFI > 7 ld L.2. I]. 3 C,4 t).5. C'iu 2: X la ho.p ch6t hlLl co mach ho (chita C, I-1, O) c6 pli6n tir tihOi bang 90 clvC. (lho X iltc cltntl,-i vrii Na c1-r thLr clLla-c so mol I12 bapg sd mol X phan ilng. Miit lihac X co lchzi udng phhn iLng vtir Nall('Or. Sir cOng lhfrc cAu 1ao co th6 c6 cira X lzi h.4. l]. 3. c. -5. I). 2 . Ciiu 3: l-lodr tal ltet 7 ,2 gam hSn hgp X gorn Al v2l K vdo [00m] dr-urg dich l l('l 1 M thLr cluo-c 3.3(r lit I I' (clktc). fhdnh phl'no/o khOi lLrgng Al c6 trong X ld t\.79.69'2o. B. 15,0%. (:. 18,75%. l)' 35'0(%' Cffu 4: Mqt h6n hop g6m hai axit cacboxylic uo, clon clr[rc. mach ho ke tiep nhaLr troug cirr.rg clay cl0ng cling. I-Ay m garr h6n hop r6i therr vdo clo 75 ml clung clich NaOII 0,2M. D0 trurtrg hoii lLxrng NaOil con dr-r cAl th€rn vdo 25rnl clLng dich FICI 0,2M. C0 car.r dung dich sau ltl.ri trung hoit thu cltLo-c 1.0425 garn chat ran khan. Cong thiic phdn tircira hai axit lAn h'ro-t ld TRU'ONG DrrSP rrA NQI 'I'ITUONG'TIIP'I' CII UYEN Md tti: 251 I)E 1'III 1'IIU'l)AI IIQC LAN 1'lliJ'V NAM 2(il I MON IIOA IIOC Thi'i ginn ldm hdi: 90 Phtit B. CI{rCOOl'l va Crl.lsCOOI I D. CrlITCOOI I vd C,rlle(lool I ll. chr-r ki 4. nh6m Vlll/\. D. chr-r ki 4, nh6m llA. l]. (l?l'l5cl iO vzi f l(ll lO. D. ICrong co nghiOrr \-s (( { \ aa It + 3 .]3 , Ciiu 5: I-loh tan hodl todn h6n ho.p X (g6ni x mol Fe, y mol Cu, z mol FerOi vz\ t mol lrcrOr) trong clrtng cllch l-lCl kh6ng thAy co khi bay ra khdi binh, dung dich thu duoc chi chfLa ? uiuOi. MOi cltran tie giira sir mol cdc chAt trong h6n h-op X ld A.x ry-:27.12t. B.xr y 221 31. C.x ly=.\ztt. l).x ty '/.t t. {liiu 6: Ion M2'c6 tong s6 hat proton, notron, electron ldr 80 trong do sd hqt mang diOn nhi0tr lion sd lral khong rrang cli6n ld 20. 'l'rong birng tLrAn l.roiur cAc nguy€n io hoa iroc. rlguye n t0 M thudc A. I"lCOOIl vd CI-I:COOLI. C. Czl IiCOOH vd Crl'lzCOOI I. A. chu lii 4. nh6m VIIIB. C. chr-r hi 3, nhom VlllB. A. CIhCIIO vd llCllO. C. CrllrCI-lO va I-lCl IO Cf,u 7: 'l'r6n 3.36 gam ancleirit don chirc X v6'i rn6t ancleiiit ilon chitc Y (Mr > Mv) 16i thCm lilLtic v;iti tlc cluo-c 0,1 lit clung cych Z v<i'i t01g ndng dd cdc anciehil id 0,8M. 'l'h€rl tLt' iiL citrng clich AgN0;/N1 { r ilrt t'iio clur-rg clich Z r6i ti€p hdrnfu cl16 n6ng dOr-r phAn frLrg hoi\n todn thu dtLcrc 21.(r gam Ag. Oong t]riLc ciitt tilr cira X vai Y lAn h-Lo1 lir c6u 8: Cho tirng chat: Fe, Fe(OFI)2, Fe(Oi-l)r, Ire3o4, Irezo.i, rc(No;)2. lre(NO:):, |eSOa, l;c:(SO.r)r. IreCO: lAn itrot phAn iutg voiilzSOl cldc, n6ng. S0 phAn irng thuQc loai phAn itng oxi hoil lthLl lA n.5 r]. 8. c.6 D.7. glixclol v2l h6n ho1-r ba axii bco: arit pitrttL:itru. Ciiu 9: 'l-huy phdn hoAr-r todn m6t triglixcLit (X) thr-t cluo-c zrxit stcalic vzi axir olcic. SO ctdng phAn cAtr tao cLra X lt'r A.5 r)1 l), _) c.4. t). ? (jfiu 1{): 'l'rciug pfiopg tfif nghiCm lthi CO: cil-roc cli0r-r che tiL (]aCOr vit ciung clich ll('l thirorrg tri liri lilri liiclrg clolra vA lioi utitic. I)e thu clr-ro-c L'Oi gAn nhr-r tinli l<hi6t. rrgur.ii ta dfrn h5n hop l<hi lAn lll'ot ilLra hai binh clr-tng cdc clung dich ndo tt'ong ciic dr-rng clich cluoi dAy '/ A. NaOll. I l:SO,r cl4c ti. NailCOr. I'lzSOr clitc. {1. Na:COr. Na(ll. tr)" I l:SO r rlirc. Nzr3('O r. NIlr. I ral ttl tittrg clilt tittit Irilr ' i Cliu 11: Ciro circ c[At: CI'lrNIfi, Cr,llsNIIz. (CI-lr):NII. (('{,lls):NiI r'zi (thco chieu tLr trhi cluar phiii)cLra 5 chat tren lir l]. ((l(,1 i'):l\l l. Cct-l;Nl lz. NI'lr. (ll l:N1 1?, (Cllr)2NFl' {1. ((lr,i'l:):Nll, NFI:, Col{sNl'iz, Ci-l:Ntiz ' (ClFi3)zNH' t). Clr,llsNl.lz, (Cal-I;)zNtr'I, NII;, CII:NFIz' (CFlr)2NH" {liiu trZ: Cho cAn biurg (rrong binh kin) salr: CO (k) -r IlzO (k) 4 2 COt (k)) 'I'rong chc y6u 16: (1) tdng nhiet ciQ; (2) th€ni mot h-rgng_ co; (3) th6mrnot cfturrg cua he ; (5) dirlg.*t *u. tdc. SO y6'-r td ldnr thay ddi c6n bang cira hQ ld r') tL.L, Hz&) AI{<0 li-rong FIu; (a) gidm hP suAt R1 t-e" J. D6 pliAn bi6t dung dicl-r cua ba hgp chAt trCn' tt" 4. ,{1 {lAu tr3: q<i 3 chAt htru co.: glvxin. l'ictylaruii1, axit'glutamic ct) thc dung thLr0c thLi lA rt" Na0l{. B" Na. Cfiu 14: Llho phAn tit c6c chAt sau: l1 r1t12n CllC la x' ' '-'- - A"5 H\.7 L.0. C" HCI I). quj'tim Am. FIIJr, COz, Cl{+, NH:, Br2, C2Ha, Clz, CzHz' HCl" Sd chAt md phdn tir 1\A {lf;u tr5: Ngtroi ta ct} th6 diAu ch6 metanol tireo c6c chch sau: (i) cll,r -4'? )co-;{ > cl'l3ol-l (2)2CLI,| r Oz xrlie+ 2CI'I301-I (3) crr ,',\"') rctjci r;er+cFirct (4) cHicoocH3 r'NaoItr-ril+cHrcooFl t cFl3ol{ 'l'rong c0ng nghicp. metanoi aittcrc siin xr-rAt theo cAch n. (1). (2) i,A (i). i}. (2), (3) vri (4) t:"(2j vd (3). E]" (1) vd(Z)' ciiu 16; r)c tru'g hoir ln garn ri6n rrqip x g6m rrai axit no, don chirc. mach hd, k6 ti5p nhaLr troirg ciln-o' rliiy clfinu cllng cAn i 00ml dr-rng clicli NaOH 0"3M. Mar khac dern d6t ch6y rn gam h5n hqp X rdi cho tr.rd' b6 sdrn pham cr-ray lan ruot di qua binh (r) dq'g pzor. bi'nh (2) dpng dr,urg dich Koll duthay kh6i h-rong binh(1)'a*gagan].binh(2) rang(3,64+a)gam.Thanh ph|,n%vakrroirr-rqngctraaxirc6s6rig'rye'tii cacbon nho hon irong X li A' 30.14%. A1"'33,33oA' C" 6g'86yo' ffi" 66"6'/%' {.iu 17: r,)6r c}i6y hodn toirn 1 7,6 gamFes vd 12 ganFes2, sr-rc toin b0 khi thr-r d'uroc vlio v ml dung dich r.ia()r.r ?-5ltt {L} . t ,iul;el,,,t). Gia iri t6i rlii;u cua y can clung de hap thu' het hhi in A. 100 !3'2AA' c' 50' t)" 150' '\"''- '';""- ''l'4r ''ii" x' li il'li:{;" i-ilio 5'5 gam Xtitc dtrng v6'i ch'rng dicli NaOil clr-ro-c '{ tin-{ g.$: { OilQ tflLlli (-lL,{t titdll rllrc{r LLl(r r" a-) !2 o "" 7 1{, r!1,, x l)hAir fri,khoi cLia Y lrin hrvn cua XId44 SO clong pirAn l l ,;a.tn nrLroi Y i:it sii ngr-ri,,en iiL ('batl1-t uuu /\' i {i.ltr llc s ,,iii.,, ti.,t, c ria X li., ^ I lJ^l. {:"3' E}"4' ci*; 1$: liiin ilrr-r hoiiir loiri.r v lii. {.jor (cr clkrc) vz\o bi'ir clr*rg 200 ml du*g clictrr x (Naoll trhd v} l"lar(lo: ir.51\,4) i"ci li.1 drrng rlicl-l ii*r'Jttoc sar-r 'otira. tnlg {chi iarn bal'hoi nuoc) thi thr-r ei*o'c 19'9 garn ch5t rail khan. (jia tri V ja A. 1^12 13' 3"36. {:"2'24 s" 5'6' {r6u zi}: Lsre x ki-rorrg uo, l,acr} iro, c6 ti ktri0i hoi so v6i oxi bbrqz,GT75. Khi X tharr gia pha. it^g xh phong 5oa tao i-a m0t aiidehi'i ,zh m0l i-*uOi rila axit hfru co 56 doi1g phin cAutao cira '>i li A" 4 83" 3. c"7' I)" 5' cftu 2n: Tr0* durg riictrr x t:lu-,:a 13ar*; Otr-{-: 0,17 (rnol); }"la'.0,02 (mol) vcri dung drch Y chira Iliic,; co] : 0,03 (nlcl); tria': 0,1 (rnol) il'rn clr-loc rn ga-'i\ kat tiia, Gi6 tri cira m li !\. l1:, 1 1) . !] < crl f1 '7 <tO q ,/.{)(_). $. 13.79. lr,L.:. irg ni'Lo itr-rug X la I 5.73'/o' Xa phong ho:r riliry :.il-ii.1c1.,it V i,lhil Y ihrrc lrien 6:'hal.r r'tc;i Cfiu 23: I)hAn ilng niro clLrcii clAy dirng cl0 giai thich su'hinh tlidnh thach nhr-r tiong l.rang clong'/ A. CO2 r Cla(OIl). ,-r CaCOr I l-12O. C.Ca(IIC().),-l>(]aC():r(]():ltl?O.I).Ca(]()rr(]():rII:()**_> Ciu 24: Cho ciic chAt sar-r : C2ll3Cl, Czll,1, C:l-lo, C2llrCOOII. C{,ll1NO (czrplolactanr). vinyl ilxolal. phcnyl axctat. Sd circ chAt trong cl6y co khd nang thar"ii gia phhn img triuig hcrp llr A.6. I]. 4 c.5 Ciiu 25: Cho a gam le (du) vdo Vr lit dLrng drch Cu(NO:): 1M seu: l<hi ket gam chAt rf,n. Cho a gam Fe (clLr) vAo V2 lit clung dich AgNOr 1M. sar-r khi cluo'c m gam chAt rin. QLran he cr-ra V r vd Vr li\ A' V1 ' V:. I]. Vr 2V: C. VI l0V2 ChuT(t: 'l't.ong so cAc polimc sau: (l) to tlni. (2) stri bong. (3) lcn, (4) to 6,6, (7) to axetal. Loai t<t c6 ngLrOn goc xenh-rlozo Ia: A.(1), (2),(6). I).3. thirc phan [r'ng tlrLr tlrt<rc rrr l<Ot thLrc phtin Ln-rg cirng thLr I). lOv r v: cnang. (5) lo visco. ((i) nilon D. (2). (s). (7). B. (2), (3), (7). c. (2), (3), (5) Ciu27: LISn hop X gOm SOz vd 02 c6 ti khOi so voi I-12 bing 28.I.Ay 4.48 lit h6n hop X (clktc) cho cli clLra binh dr-urg V2O5 nung n6ng. I.I6n hcrrr thu cltr<rc cho lOi qr:a clung dich Ua(OII): ciLl thAy cri 33.19 gani k6t tLra. I-li6r-r sLrAt phAn img oxi hod SO: thi\nh SO.r lirr h.2504. 1r.40%. c.60%. l\.15% Ciiu 2fi:'l'run-e liod 5.4 gam l.ron hop X 96m CII-rCOOll. CIlr,,.CI'ICOOIl. (.'61[5Oll (phcnol) r'ii C6I-I5COOH (axit benzoic) cAn dirng V rnl dung dich NaOII 0,1M. (16 can clr,urg clich sar-r phAn irrrg. tiir-r ducvc 6,94 gam h6n hgp ch6t rin khan. Gi61ri cira V ld A. 700. 8.669,6. c.3s0 t). 900 Cfiu29: Cho c6c phAn irng: (1) O: I dlrng dich I(l ) (3) i(Cllor (r) r lICl ddc + (5) Clz (du) t durng ciich llzS + t0 (7) NaNOz (bdo hod) -r- NFI4CI ftao hod) Sfi phAn intg cri th6 tao ra clon ch6t ki: A.5. C'f,u 30: '|rong citc chAt: zurctchit act'ylic. axctot'r. (2) l,t,I ll:O "' o (a) SO: t clurng dich I I:S (6) NI-13 (du) r Cl2 + t]. 6. {:.7. lt. + xicloplolran, xiclohcxau. benzcn. stiren. axil arctic. axit iiclt'lic. anclchit a.r.clic. ctyl axctat. viuyl axctat. c{irnct1,l ctc. S0 cliit ct'r lihli rrirng larrr rriat uriru rruric t},.7 . t). 4 !1. 30,0. bt'onr lir: A.5. Ciu 31: Cho m garlr pharr irng xay l'a hoAu rn ldr A. 31 .6. c.6 (liiu 32: Chi clirng thr-r0c thLr Cu(Ol-i)z/OI'l rlirng cliclr licng bict sau: A. glucozo. urantoz(y. glixcr-ol. anclchit axclic c.21,2. 1J.24.4. tlong cli€r-r hi0n thich ho'p cri tlrC phan [ri"^t cltrtrc tlit czi ciie li. long tring 1rung. glLrcozrr. liLrctozo'. glircrol. (1. setccarozo. glixerol. zurctchit axetic, ancol etylrc. I). glLrcozcr. lr)ng trirng trinrg. glixcrtil, ancol clr lic. (liiu 33: I{ozl tan hoan tozur 34,8 gzrm h6n hop X (g0nr l;co, llc-rOr. l;czO.r) cihi iOr thicu V nrl clurr-r, cliclr llrSOr 2il^5o1, (D 1.2 g/nrl). saur phan furg tliu drroc h6n liop l.rai nrLrOi cri sO rlol biin-u rrliau. (iiir tri cuii V lz\ A. zl00 h6n ho-p X gdnr (Fe, FeO, ItcaOa, |c2O3) vdo 400 ml clung dich Il{ll 2lvi. saii i,hi toArr tlru duoc2"24lit khi LIz (clktc). dLrng dich Y vit2.8 garn I;e l<lrong tan. (iiA tri rl. 250. c" r0i) r). 100 {lAu 3.{: i}hcnolpirtalci' (X) lir chAt chi thi r'2'-r thudng cluoc clirng tlot.ig chr-rAn dd axit -bazo' Tro'g )i' tr telt]roilr-ltrngcAclrguy6nt6ldm.':m|l:t-I]o=60:3,5:16.Bi€tlrlrOiir-ro''rrgplrAi-rtirciraXrrirr-itrorlg lilroang liL 300 clOn 320 clvC' So ngr-ry6u tt cacbon co trong X la A. 10 a4' 12' c' 5' x)" 20' CAu 35: Ciro cAc clung dich sar-r: NaOI.l, Nal-ICO;' BaClz' NazCO:' NallSO'r' N€u tr6n cAc clr'ing dich vo'i *hau rhco tirng d6i 'iQt thi t6ng s0 citp co th6 x6y ra phh'r irng l'roi hqc ld A" 4. i3' s' c' 6' Ll-' 7 ' CAu 36: I(hi clLrng c1Lrj,'ti'i vA clr-rng clicir bro''r. khdng ft6 phdl biQt drro-c clfry chAt n" cHrcl{o, czl lscooll. cltrz="cLicooH' !3. CI IrCIIO. CI{rCOOIl, CII2="CIICIIO' C. Crl IiOI l, Cl-lz-' CI I-CI'IzOI I, CI{3COOFI' CFIz"=CFICOOF{' q). C?l I;OI l. CI'{rC1'1(). CI{IC0OH' CFIi:CHCOOFI' cfru37:DiQnphan(.ro'idiqncl]ctrO)mOiilutigdichgomlJaci.''acuso'r(tiiQs6moltuc-ngirngld3: 1 ). t10* krri o caioi xr-rat liicn bqt khi tiri dh-rg cri6n ph6n. Trong cdr clua tri'h diqn phan tr6*, sa* irharn thLr clurJc tr anc)i la A" khi cl: va or. iB" klii LIz vA Cz. c' clii c6 khi cl2' D" kLri clz vd {iu {.fru 3g: ciro so <16 chLiye' rro6 sar:: a rcrr(()rt),rorr' ,dung dlch xanh iam-J-+ket tua db gach .l.rorrg c6c cliat : Glucozo;l,ructozo ;mantozo; saccarozo;tinh bOi; andehit axetic ;glixerol (X; thoi urdir so c16 ti:€rl ld n " 2. !*' 5' c" 3' x)" 4' {rfiar 39: Nlri.L prrin iroa' ro2r' r' gam ir6n hqp X (gor' KNos va Fc(No:)z)' I'l6n hqp khi ii'tt-t clLt'oc clcitr rian vao Lrinir ciriLa 2 iir F-izo r.iri khong riray khi tiro6r ra ichoi binh. i}-rng cich titi cir-rcvc c(r gi6 iri pii i r.a chr chiia 'r0r chAt tan ciLry .hAt. Coi the tich clung dich thay ci6i kh.ng d6'g k6' Gi' tri m la A" 28.1 . 13" 46.1' {" 38',2' D "23',A5' {-fiu 4{}: ChAt hu.r-r so X- eri c6ng tkruc phAn tu CrHs. Cho X tdc dung voi,AgNO3'{\H3 clu thu drro-c k6t tta y. l,lrAn rLl liiroi cua Y lo'n hon ctia X Iir214"56 dong ptran eAu tao co thA co cua X l2r i* I {:" 4' D" 5' /\" /. !x" t,ai^N !.tn[iN{; [10 e ftul A".l.hcoctal:'tt'ngtniretrCgtuAn{l{}crttl,{|t,citlt4irf6ncfru5{}} 1 t. . /, ,t.:,.^.j,., i ,r,,\,. <,i:r ,rl,iii'rizr cjinir sr-i cir-rng c10ng c<i ilic;:cn de p'l.ril clterr nIrr'rng lihOng i:.ru.il'|'l]llirilti.l'lCll!Ll{,tlt'-{1.,L.1.ct'J'! ' ,r' ' ,.,.' ,-!,.rn,, l. i'r ui :i-r, i llll r'(1r |Jlj.'. r r.; rltrr{!i l/ir\r':- t A tiCLl thr-r rlhiiu lihi ()r' sitth ra l<hi (lO' dOc' 11" iiCr-r {lirr niri6u khi [)'- sinh ra i<hi (l(}' Jl:S' S{}i d6c' ci-" riiriC,-r itidrocaciron l<litirg chay h0t la nhfLng [<1ii iiOc' i.]" sr,,li La hlrr .'j()2. iizS' . , j ' r: (liu z$2: Arrtlchir X co ii klLdi hoi so voi H2 bArrg 36' Sd ':ong tl-rirc c6u iao co thi co eua X ta A"-j &3'4' c'i' ri.i)," .,Ai 1!A,. !.on X gom r::ar: cttiL.aricoi metylic, ancol etylic, ancol propylic'ra nrr6'c' Cho in garn X tAc \,i[i-d 'iJ" 1 (\,t! (rt,L/ rji_irrgviiriiatriclr-Lrhir,c 15,6glitxi2(o.dr<,rc).Mati<rr6ccidichltyhoa'toanr1lg^rnXthr-rcir-rc-cviiico2{ii tlkic) viL 46"8 gatn t-tr20. Gi6 tri cr-ta m vir V iin iircrt ia h. 4?- ttaT{.t.,l1 i}" 42 vit 47 '5()' {'" \?'6 oU ':'U.* " , . W" 61'2'ia26'88' tl6u ,$4: I)6 phan bier glucozo va lRictozo ngr-toi ta co thCI dilng thnrc i:hll la ^ { ,/(\1" ! \ /r'ii t !3. Na- ./.:. { '-l\\ /! r t,/ .rr I ,{ . Llurig ciir:ii il'',, i-}' clLlng di':il Agirli);/l\i}-[; ttril , ' : ,. .r1,,) l'". ,,,'r; ,1,.'; i'iri, L!lr' I i'.;' \ i 1-l 'i'1lrr tlrA; 'i'Lt ;i' "" r'i l'l.' , :'.' : ' .::l i thi s0 chf,t Cjiu 46: (lho circ cirir kint krai nguycn chat ti0p xuc tr"LLc tiCp vtii rthittr: lrc vi l'b: l;c vlt /.t1. liq ia Srr: Ic vz) Ni; Iie vd Cu. I(hi nhirng circ cdp l<inr loai tlcn vAo clLrng clich axi1. so cirp l<itn loai trorig d6 lic tri piril huy tlLlcrc lA A.3. l].4 c. 1. D.2. C6,v 47: ChAt hlLu ccr X (chiLa C, I{, O), plidn tir chi chira mot loai nhom chirc. I)dt chdy X thi thLr cltt<rc s0 mol FI20 thu cluo-c gAp i,5 lAn s6 mol CO2. (lho 0,1,5 mol X tirc clung v6'i Na (r,rla clir). sarr-t plian ftng lhtr cluoc rn gam cl'rdt rZrn vA 3,36lit I-12 (o'clktc). (iia tri cua tr lzi A. r5,9. t]. 10.2 c. 15.6 r). rtJ.O Ciiu 4tt: I')0 trLrng hoa 8,6 garn nrOt axit cacboxylic (X) Cl<,rn chfic, rlacli hci cdn l00mI dr-rng ciich NaOll i M. So clong phan cau 1ao cua X lA h.4. Il. 3. c. -5. I). 2 Ciiu 49: DOt chay hodl rohr.r 9,984 gant kirn loai M (co hoir tri hai ltliong clOi trong ht2p chdt; trong h5n hop khi Clz vir Oz. Sau phin ring thr: dr-ro-c 20,73 gan't chat rin vA th0 tictr lr6n hcrp khi clZr phan ung li\ 3.4212lit (o'dktc). I(irn loai M ld A. Cu. ^ll.Zn. (l.Mg, l)- Ca. t s-^ a t Ciu 50: DLmg cricrr x,"lti-cft ,,414", *;, :$ ",1' \1iA43:rqi*$riS/a 0,i mor ('r ('rro V rit clLrng clich NaOI I I M vdo dLr-ng dich-X cffi"lrrorrg kct tLra tltLr clrtcrc lA lo'rr nlAt thi giri tr i ctra V lii I]. 'I'hco chu'o'ng trinh Nf,ng cao (10 c6u, tir cfiu 5I ct€tr cfiu 6Q Ciiu 51: Dfit ch6y hohn todrn m6t ancol X thi sd raol COzthu clttoc bing75% so mol IIzO 1ao {.hz\nh: tong sd mol COz vd I-lzO bine 4 tan tone s6 nol X v2r Oz di phan iurg. Cho 6.9 gan-r X thc clLrng vtii Na ciLL iiri "9 thu clrroc V lft I-12 (ctktc;. Gia tri ctra V ld n. 1,2ti8. l\.2,52. c. i,12. I). 1,68. Ciiu 52: Cho luong dLl Cl: vi NaOII vAo dung clich m5u thtr ctri cliira 1 cation ltinr loai. I)r-rng clich tlrtr dr-roc sau phin irng c6 rndu vduig. Dung dich m6ri thir chila ion kim lo4i ld A. n l3''. l]. C13*. C. Fe2*. I). A13'. Cflu 53: Cho sr-rAt cliOn clOng chuAn cira c6c pin cli0n ho6: Mg-C n ld2.7 i V. CLr-Ag la 0.46V. Ilict thc' clicll cLrc chu6n E.lr,,.in,, '= 10,8V. tne Aien cr"rc chr-rAn lll,,,, , ,,, vi\ Iif.,,, ,,,,cti gilt tri lAn ltrot le\: A. -2,37V vd r'0,34V. ll. +2^07V vz\ I 0.64V. C. -231V vd *0,34V. I)' -2.07V vi\ I 0.64V. (liiu 54: IIoA tan hoeut todn 60.48 geul l<in.r loai M irong [{3SO1clirc. utirrg. clLL.'l'o:in b0 lihi X thohl ra cluoc hfip thu h0t vao 2 lit clr-rng clich cirua lla(Ol"{)2 0,0tjM vzi ltoll 0.055M. thtr c'lr-ioc tlting ciicii \" r a 32,55 garl ket tua. [)un nong dung clich Y lai rhAy xr-rdt hien th0nr ket tua. Kim loai M lA A.Mg I]. Cu l). Ag. Cflu 55: 'frong s0 cdrc ci6ng phAn c6u tao, Lnach irii Lmg i,ci'i c6ng thilc phAn tLt'C,rlloo: c<i bao tthicLr cslc i:ir thO cltrcc <Ii6u che tryrc tiOp tir axit vd ancol tuolg irrig? 4.2 I]. 3 r Ll . t). l. C'ffu 5(r: Cho 3.56 garr-r ziiaurin t6c clLrng hOt vii-i ilN0l ri nhi.^t ciO thAp. tliu tlliuc chat X, (lho X ttic clLtrrg vrit liini loai I( chL. thr-r cliroc nr garu muoi vdr V liL I12 (ti ctlilc). (liit tri cua ttr vz\ V lan lutrt li\ A. (r.64 vA 8,96. l]. 5. I I vA 0.448. (1. 6.64 va 0.44f] l). 6.96 r'i\ 0.896 {liiu 57: I)e xirc clinir n6ng clo clLtng dich NaOI'I. ngu'di ta ciitng clung clich c16 chr-ran clO 2-5.00rntclLrrrg clich ll2Cro.r 0.05M (clLrng plicnolphtalcin ldnr chi tiri). l<hi chLran clO phiii clLrng het.{6.5Onr1 citrng clicir NaOll. N0r;11c1o niolii cr-ra clung clich NaOI'{ c16 ld A. 0.017M. t]. 0.0-s4N4. {1. 0.025M l}. 0.027M. {lriu 5fi: Cho 2-,16 garu bOr AI vi\o clirng rlicl'r chita hin irop gonr ('Lr('l' {).1] nrol t,i\ lrc('lr 0.0(r rrtol. SirLr lihi phlin irng.r:iy t'a lro:\n iot\n lhu clLroc nr gzrrn cliit lin X. (jih rri cttit nr l:\ C. Fc. l)' l'' {lf,u 59: Oho pll-rong trinh ho6 hoc :N:2ft) + 3l-12ft) f-+ ZNllr(k) N6u d 1ra.g tii6i cA. bdng, no'g cl6 cr-ra NFIr lA 0,30 'rol//, cira Nz lA 0,05 mol// vd cira LIz lei 0'10 rnol// thi hirng s0 "a" Uang ctra pl-rirn iurg iA A. lti. t|.60. c' 1800' D" 3600' ciu 6{}: cho *r gar, h51 hqp X gdm tinh bOr vd glucozo tdc c|,urg ooi l.tgttg du dung dich AgNo3 trong .Nl'13 dun n6ng thu c{uo-c 21,6 gan-r Ag. Mat khdc dun n6ng m gam X v6i dung dich HCI lodng' dr-r dd phdn irng xAy ra hod' toa'. thu cluo.'c dung dich y. Dprig tlich Y larn mAt iniu vira hot dti'g dich chira 32 gam llrz. Gi6 tri cira nr ld A. 17.1. B. 50.4. c" 33,3. D.34,2. HET S**6;: Y'ffa.*,. Tffix rF{{I tr&r F{QC LAN TE{uI v nap am nry<lN F{OA HQC Ngity ttei: {}8/5/2{} f 1 Cau ec-l z.3E 4Eet E EA & s-teF \-d[a aEl 9q9 253 254 ,, L l3 A C D 31 (- t3 A l) cB {- t> L,b A ID '1 -j L. l; g, 3 ? *, l] l) t) C 9q JJ A D C 4 IF C E\ L' A qfr A" A A IR q l.p A l) t.b C 35 t- I-b t3 !) [] 6 x) f,- 13 A l,L 36 p ,4 g\ L-p E} tt A A C 37 A l1' t- t, {} (3 A A I} A3 A {1 ?.fr C C ii A q x3 tb A {} 3S C C E} C , tf [- [_ C E} {, 4fi ffi E} {} A g) 11 ,A B t3 D 41 tr) t_ A E} E,) ,g ct T{ .x3 [3 X} A 42 D {l C X} 13 B t- ffi t) 43 {- d- fl3 ,d 4^fr da+ E} E9 fI C A 44 A q i) A 15 ,{ n (- l\ $ 4.5 {- T3 E} li 4fi. It g3 C 4ffi A E} d-' C t) "t/ B} q E} A 47 TF H3 {: B 4{} ll \tj d- E} {} {- d7t6 F5 {- (l B:! flq r\ LL] {} H-b H} fit) C g) { {_ 2& I3 A { {1 \- E: fn i9u t_ E) E, {1 P" Gr4 d-u ,\ -ro E} {- s\ 6E 51 L3 ,4 E} ) 22 tr3 H} A EI R*t J,L C [] {B .{- 4 ':! q., A {} { 8= -4 -3.J A q9 E-B rL zd* C il1 ,4. g] g3 5,4 A ua. rL Hi, d) R- dU [3 ,A n ,t n i,"3 E} tr) A t- nt: g) [3 A-E H9 5S E} 1tr0 q-, /\ n5 27 A $ F3 {} 5V {} ,l\ U"D iil nri E,tl) X} H} d) {, 58 .A A tr) { ' 9di ,L* A H} A 1a 59 l\ t\ i] ( 3fi B B} A A [}["/ R! [-t _q_ { . thi nh SO.r lirr h. 250 4. 1r.40%. c.60%. l. 15% Ciiu 2fi:'l'run-e liod 5. 4 gam l.ron hop X 96m CII-rCOOll. CIlr,,.CI'ICOOIl. (.'61[5Oll (phcnol) r'ii C6I-I5COOH. 0. 055 M. thtr c'lr-ioc tlting ciicii " r a 32 ,55 garl ket tua. [)un nong dung clich Y lai rhAy xr-rdt hien th0nr ket tua. Kim loai M lA A.Mg I]. Cu l). Ag. Cflu 55 :. R- dU [3 ,A n ,t n i,"3 E} tr) A t- nt: g) [3 A-E H9 5S E} 1tr0 q-, / n5 27 A $ F3 {} 5V {} ,l U"D iil nri E,tl) X} H} d) {, 58 .A A tr) { ' 9di ,L* A H} A 1a 59 l t i] ( 3fi B B} A A [}["/ R! [-t _q_ {