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Đề thi môn hoá chính thức hệ Cambridge IGCSE™ Chemistry, đề thi bao gồm đề trắc nghiệm (multiple choice) và đề tự luận (Theory). Ngoài ra còn chia hai hệ cơ bản (core) và hệ nâng cao (extended) giúp các bạn học sinh có thể lựa chọn đề phù hợp nhất.
Cambridge IGCSE™ *9534637521* CHEMISTRY0620/43 May/June 2023 Paper Theory (Extended) hour 15 minutes You must answer on the question paper No additional materials are needed INSTRUCTIONS ● Answer all questions ● Use a black or dark blue pen You may use an HB pencil for any diagrams or graphs ● Write your name, centre number and candidate number in the boxes at the top of the page ● Write your answer to each question in the space provided ● Do not use an erasable pen or correction fluid ● Do not write on any bar codes ● You may use a calculator ● You should show all your working and use appropriate units INFORMATION ● The total mark for this paper is 80 ● The number of marks for each question or part question is shown in brackets [ ] ● The Periodic Table is printed in the question paper This document has 16 pages IB23 06_0620_43/2RP © UCLES 2023 [Turn over 1 Some symbol equations and word equations, A to J, are shown A H+ + OH– → H2O B Cr3+ + 3OH– → Cr(OH)3 C methane + chlorine → chloromethane + hydrogen chloride D propene + bromine → 1,2-dibromopropane E C10H22 → C8H18 + C2H4 F G methane + oxygen → carbon monoxide + water H C2H5COOH + CH3OH → C2H5COOCH3 + H2O I J 6CO2 + 6H2O → C6H12O6 + 6O2 chlorine + aqueous potassium bromide → bromine + aqueous potassium chloride hydrogen + oxygen → water Use the equations to answer the questions that follow Each equation may be used once, more than once, or not at all Give the letter, A to J, for the equation which represents: (a) photosynthesis ��������������������������������������������������������������������������������������������������������������������� [1] (b) an addition reaction ������������������������������������������������������������������������������������������������������������� [1] (c) a precipitation reaction �������������������������������������������������������������������������������������������������������� [1] (d) incomplete combustion �������������������������������������������������������������������������������������������������������� [1] (e) a displacement reaction ������������������������������������������������������������������������������������������������������� [1] (f) a substitution reaction ��������������������������������������������������������������������������������������������������������� [1] [Total: 6] © UCLES 2023 0620/43/M/J/23 Question starts on the next page © UCLES 2023 0620/43/M/J/23 [Turn over (a) The symbols of the elements in Period 3 of the Periodic Table are shown Na Mg Al Si P S Cl Ar Use the symbols of the elements in Period 3 to answer the questions that follow Each symbol may be used once, more than once, or not at all Give the symbol of the element that: (i) is present in purified bauxite ����������������������������������������������������������������������������������������� [1] (ii) contains atoms with a full outer shell of electrons �������������������������������������������������������� [1] (iii) is used to kill microbes in water treatment �������������������������������������������������������������������� [1] (iv) forms an amphoteric oxide ������������������������������������������������������������������������������������������� [1] (v) forms an oxide which causes acid rain ������������������������������������������������������������������������� [1] (vi) has an oxidation number of –1 when it forms a compound with hydrogen [1] (b) The relative atomic masses of elements can be calculated from the relative masses of isotopes and their percentage abundances (i) Identify the isotope to which all relative masses are compared [1] (ii) Table 2.1 shows the relative masses and the percentage abundances of the two isotopes in a sample of magnesium Table 2.1 relative mass of isotope percentage abundance of isotope 24 85 26 15 Calculate the relative atomic mass of magnesium to one decimal place © UCLES 2023 relative atomic mass = [2] 0620/43/M/J/23 (c) An ion contains 10 electrons, 13 protons and 14 neutrons (i) State the nucleon number of the ion [1] (ii) Identify the element that forms this ion [1] [Total: 11] © UCLES 2023 0620/43/M/J/23 [Turn over 3 Magnesium forms ionic compounds (a) M agnesium reacts with fluorine to form the ionic compound magnesium fluoride The electronic configurations of an atom of magnesium and an atom of fluorine are shown in Fig. 3.1 magnesium atom fluorine atom Mg F Fig 3.1 (i) Ions are formed by the transfer of electrons from magnesium atoms to fluorine atoms Complete the dot-and-cross diagrams in Fig. 3.2 to show the electronic configurations of one magnesium ion and one fluoride ion Show the charges on the ions magnesium ion fluoride ion Mg F Fig 3.2 [3] (ii) Deduce the formula of magnesium fluoride [1] (iii) W hen solid magnesium fluoride is dissolved in water it forms a solution that conducts electricity State one other change that can be made to solid magnesium fluoride to allow it to conduct electricity [1] © UCLES 2023 0620/43/M/J/23 (b) Silicon tetrachloride, SiCl 4, and silicon(IV) oxide, SiO2, are covalent compounds Complete the dot-and-cross diagram in Fig. 3.3 to show the electronic configuration in a molecule of silicon tetrachloride Show outer shell electrons only Cl Cl Si Cl Cl Fig 3.3 [2] (c) The melting points of silicon tetrachloride and silicon(IV) oxide are shown in Table 3.1 Table 3.1 melting point / °C silicon tetrachloride –69 silicon(IV) oxide 1710 (i) Silicon tetrachloride has a low melting point because it has weak forces of attraction between particles Name the type of particles that are held together by these weak forces of attraction [1] (ii) Explain, in terms of structure and bonding, why silicon(IV) oxide has a high melting point [2] [Total: 10] © UCLES 2023 0620/43/M/J/23 [Turn over 4 Hydrogen is produced by the reaction between zinc and dilute sulfuric acid, H2SO4 Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g) (a) A student carries out an experiment using excess zinc and dilute sulfuric acid The student measures the volume of hydrogen produced at regular time intervals using the apparatus shown in Fig. 4.1 Lumps of zinc are used gas syringe lumps of zinc dilute sulfuric acid Fig 4.1 The rate of reaction decreases as the reaction progresses The rate eventually becomes zero (i) Explain why the rate of reaction decreases as the reaction progresses [1] (ii) Explain why the rate of reaction eventually becomes zero [1] (b) The experiment is repeated using powdered zinc instead of lumps of zinc All other conditions remain the same Explain, in terms of collision theory, why the rate of reaction increases if powdered zinc is used [2] © UCLES 2023 0620/43/M/J/23 (c) The equation for the reaction is shown Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g) 25.0 cm3 of 2.00 mol / dm3 H2SO4(aq) is added to excess zinc Calculate the volume of H2 formed at room temperature and pressure (r.t.p.) The volume of one mole of any gas is 24 dm3 at r.t.p Use the following steps ● Calculate the number of moles of H2SO4 used mol ● Deduce the number of moles of H2 produced mol ● Calculate the volume of H2 formed at r.t.p dm3 [3] (d) Hydrogen can also be produced by the reaction of zinc with dilute hydrochloric acid (i) Write a symbol equation for this reaction [2] (ii) State the test for hydrogen gas test positive result [1] © UCLES 2023 [Total: 10] 0620/43/M/J/23 [Turn over 10 5 This question is about electricity and chemical reactions (a) Aqueous copper(II) sulfate is an electrolyte The electrolysis of aqueous copper(II) sulfate using inert electrodes forms: ● copper at the cathode ● oxygen at the anode (i) State what is meant by the term electrolyte [2] (ii) State the term given to the Roman numeral, (II), in the name copper(II) sulfate [1] (iii) State what happens to the colour of the aqueous copper(II) sulfate as this electrolysis progresses [1] (iv) Write an ionic half-equation for the formation of copper at the cathode [2] (v) Give the formula of the ion that forms oxygen at the anode [1] (b) The electrolysis of aqueous copper(II) sulfate is repeated using copper electrodes State what happens to the anode [1] (c) Spoons can be electroplated with silver (i) Name the substances used as: the anode (positive electrode) the cathode (negative electrode) the electrolyte [3] (ii) State two reasons why spoons are electroplated 1 [2] © UCLES 2023 0620/43/M/J/23 13 (ii) In the second stage, nitrogen monoxide reacts with water and oxygen to produce nitric acid Balance the symbol equation for the reaction .NO + .O2 + .H2O → .HNO3[1] (c) A student makes aqueous copper(II) nitrate by adding an excess of solid copper(II) carbonate to dilute nitric acid (i) Write the symbol equation for this reaction [2] (ii) State two observations that indicate the copper(II) carbonate is in excess 1 [2] (iii) Name one compound, other than copper(II) carbonate, that can be added to dilute nitric acid to produce aqueous copper(II) nitrate [1] [Total: 15] © UCLES 2023 0620/43/M/J/23 [Turn over 14 7 This question is about organic compounds (a) Propane and chlorine react at room temperature An equation for the reaction is shown C3H8 + Cl 2 → C3H7Cl + HCl (i) State the condition required for this reaction [1] (ii) Draw the displayed formulae of two structural isomers with the formula C3H7Cl [2] (b) Alkenes are a homologous series of hydrocarbons (i) State two characteristics that all members of the same homologous series have in common 1 [2] (ii) Addition polymers are made from alkenes Complete Fig. 7.1 to show one repeat unit of the addition polymer formed from but-2-ene C C Fig 7.1 [2] © UCLES 2023 0620/43/M/J/23 15 (c) A repeat unit of a condensation polymer is shown in Fig. 7.2 The polymer is made from two monomers O C O CH2 C O CH2CH2 O Fig 7.2 (i) Draw the structures of the monomers used to produce the polymer in Fig. 7.2 [2] (ii) Name the type of condensation polymer in Fig. 7.2 [1] (iii) Name the two homologous series to which the monomers in (i) belong 1 [2] [Total: 12] Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the publisher will be pleased to make amends at the earliest possible opportunity To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge Assessment International Education Copyright Acknowledgements Booklet This is produced for each series of examinations and is freely available to download at www.cambridgeinternational.org after the live examination series Cambridge Assessment International Education is part of Cambridge Assessment Cambridge Assessment is the brand name of the University of Cambridge Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge © UCLES 2023 0620/43/M/J/23 © UCLES 2023 12 V Cr Mn Co 27 Ni 28 Cu 29 Zn 30 Fe 57–71 56 55 0620/43/M/J/23 – 90 89 232 thorium actinium – Th Ac 140 cerium 139 lanthanum 59 231 protactinium Pa 91 141 praseodymium Pr – 58 Ce – Db dubnium Rf rutherfordium La 57 actinoids 105 181 Ta tantalum 73 93 niobium Nb 41 51 vanadium 238 uranium U 92 144 neodymium 60 Nd – Sg seaborgium 106 184 W tungsten 74 96 molybdenum Mo 42 52 chromium – neptunium Np 93 – promethium 61 Pm – Bh bohrium 107 186 Re rhenium 75 – technetium Tc 43 55 manganese – plutonium Pu 94 150 samarium 62 Sm – Hs hassium 108 190 Os osmium 76 101 ruthenium Ru 44 56 iron – americium Am 95 152 europium 63 Eu – Mt meitnerium 109 192 Ir iridium 77 103 rhodium Rh 45 59 cobalt – curium Cm 96 157 gadolinium 64 Gd – Ds darmstadtium 110 195 Pt platinum 78 106 palladium Pd 46 59 nickel The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.) actinoids lanthanoids – Ra radium Fr francium 89–103 178 104 137 88 133 87 Hf hafnium Ba barium lanthanoids Cs 72 91 zirconium Zr 40 48 titanium caesium 89 yttrium 88 strontium 85 rubidium Y 39 45 Sr 38 40 Ca Rb 37 39 K scandium – berkelium Bk 97 159 terbium 65 Tb – Rg roentgenium 111 197 gold Au 79 108 silver Ag 47 64 copper – californium Cf 98 163 dysprosium 66 Dy – Cn copernicium 112 201 Hg mercury 80 112 cadmium Cd 48 65 zinc calcium Ti 26 potassium Sc 25 31 24 – einsteinium Es 99 165 holmium 67 Ho – Nh nihonium 113 204 Tl thallium 81 115 indium In 49 70 gallium Ga 27 20 24 19 23 aluminium Al 13 11 boron magnesium 23 sodium 22 B C N O VI F VII VIII – fermium Fm 100 167 erbium 68 Er – Fl flerovium 114 207 lead Pb 82 tin 119 Sn 50 73 germanium Ge 32 28 silicon Si 14 12 carbon – mendelevium Md 101 169 thulium 69 Tm – Mc moscovium 115 209 Bi bismuth 83 122 antimony Sb 51 75 arsenic As 33 31 phosphorus P 15 14 nitrogen – nobelium No 102 173 ytterbium 70 Yb – Lv livermorium 116 – Po polonium 84 128 tellurium Te 52 79 selenium Se 34 32 sulfur S 16 16 oxygen – Lr lawrencium 103 175 lutetium 71 Lu – Ts tennessine 117 – At astatine 85 127 iodine I 53 80 bromine Br 35 35.5 chlorine Cl 17 19 fluorine – Og oganesson 118 – Rn radon 86 131 xenon 54 Xe 84 krypton 36 Kr 40 argon 18 Ar 20 neon Ne 10 helium V hydrogen IV He Mg 21 relative atomic mass name atomic symbol atomic number Key III H Group Na 11 Be beryllium Li lithium II I The Periodic Table of Elements 16 Cambridge IGCSE™ CHEMISTRY 0620/43 Paper Theory (Extended) May/June 2023 MARK SCHEME Maximum Mark: 80 Published This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the examination It shows the basis on which Examiners were instructed to award marks It does not indicate the details of the discussions that took place at an Examiners’ meeting before marking began, which would have considered the acceptability of alternative answers Mark schemes should be read in conjunction with the question paper and the Principal Examiner Report for Teachers Cambridge International will not enter into discussions about these mark schemes Cambridge International is publishing the mark schemes for the May/June 2023 series for most Cambridge IGCSE, Cambridge International A and AS Level and Cambridge Pre-U components, and some Cambridge O Level components This document consists of 11 printed pages © UCLES 2023 [Turn over 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Generic Marking Principles May/June 2023 These general marking principles must be applied by all examiners when marking candidate answers They should be applied alongside the specific content of the mark scheme or generic level descriptors for a question Each question paper and mark scheme will also comply with these marking principles GENERIC MARKING PRINCIPLE 1: Marks must be awarded in line with: the specific content of the mark scheme or the generic level descriptors for the question the specific skills defined in the mark scheme or in the generic level descriptors for the question the standard of response required by a candidate as exemplified by the standardisation scripts GENERIC MARKING PRINCIPLE 2: Marks awarded are always whole marks (not half marks, or other fractions) GENERIC MARKING PRINCIPLE 3: Marks must be awarded positively: marks are awarded for correct/valid answers, as defined in the mark scheme However, credit is given for valid answers which go beyond the scope of the syllabus and mark scheme, referring to your Team Leader as appropriate marks are awarded when candidates clearly demonstrate what they know and can marks are not deducted for errors marks are not deducted for omissions answers should only be judged on the quality of spelling, punctuation and grammar when these features are specifically assessed by the question as indicated by the mark scheme The meaning, however, should be unambiguous GENERIC MARKING PRINCIPLE 4: Rules must be applied consistently, e.g in situations where candidates have not followed instructions or in the application of generic level descriptors © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED May/June 2023 GENERIC MARKING PRINCIPLE 5: Marks should be awarded using the full range of marks defined in the mark scheme for the question (however; the use of the full mark range may be limited according to the quality of the candidate responses seen) GENERIC MARKING PRINCIPLE 6: Marks awarded are based solely on the requirements as defined in the mark scheme Marks should not be awarded with grade thresholds or grade descriptors in mind © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED May/June 2023 Science-Specific Marking Principles Examiners should consider the context and scientific use of any keywords when awarding marks Although keywords may be present, marks should not be awarded if the keywords are used incorrectly The examiner should not choose between contradictory statements given in the same question part, and credit should not be awarded for any correct statement that is contradicted within the same question part Wrong science that is irrelevant to the question should be ignored Although spellings not have to be correct, spellings of syllabus terms must allow for clear and unambiguous separation from other syllabus terms with which they may be confused (e.g ethane / ethene, glucagon / glycogen, refraction / reflection) The error carried forward (ecf) principle should be applied, where appropriate If an incorrect answer is subsequently used in a scientifically correct way, the candidate should be awarded these subsequent marking points Further guidance will be included in the mark scheme where necessary and any exceptions to this general principle will be noted ‘List rule’ guidance For questions that require n responses (e.g State two reasons …): The response should be read as continuous prose, even when numbered answer spaces are provided Any response marked ignore in the mark scheme should not count towards n Incorrect responses should not be awarded credit but will still count towards n Read the entire response to check for any responses that contradict those that would otherwise be credited Credit should not be awarded for any responses that are contradicted within the rest of the response Where two responses contradict one another, this should be treated as a single incorrect response Non-contradictory responses after the first n responses may be ignored even if they include incorrect science © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED May/June 2023 Calculation specific guidance Correct answers to calculations should be given full credit even if there is no working or incorrect working, unless the question states ‘show your working’ For questions in which the number of significant figures required is not stated, credit should be awarded for correct answers when rounded by the examiner to the number of significant figures given in the mark scheme This may not apply to measured values For answers given in standard form (e.g a 10n) in which the convention of restricting the value of the coefficient (a) to a value between and 10 is not followed, credit may still be awarded if the answer can be converted to the answer given in the mark scheme Unless a separate mark is given for a unit, a missing or incorrect unit will normally mean that the final calculation mark is not awarded Exceptions to this general principle will be noted in the mark scheme Guidance for chemical equations Multiples / fractions of coefficients used in chemical equations are acceptable unless stated otherwise in the mark scheme State symbols given in an equation should be ignored unless asked for in the question or stated otherwise in the mark scheme © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question Answer May/June 2023 Marks 1(a) J 1(b) D 1(c) B 1(d) G 1(e) F 1(f) C Question Answer Marks 2(a)(i) Al 2(a)(ii) Ar 2(a)(iii) Cl 2(a)(iv) Al 2(a)(v) S 2(a)(vi) Cl 2(b)(i) 12C 2(b)(ii) M1 24 85(%) + 26 15(%) M2 2430 / 100 = 24.3 2(c)(i) 27 2(c)(ii) Aluminium / Al © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question 3(a)(i) Answer M1 eight crosses in second shell of Mg May/June 2023 Marks M2 dots and cross in second shell of F M3 ‘2+’ charge on Mg ion on correct answer line and ‘–‘ charge on F ion on correct answer line 3(a)(ii) MgF2 3(a)(iii) melting M1 dot and cross single bonds 3(b) M2 pairs of non-bonding e on each Cl and no non-bonding e on Si 3(c)(i) molecule(s) 3(c)(ii) M1 covalent bonds M2 strong bonds and giant (covalent) structure Question 4(a)(i) Answer Marks concentration (of sulfuric acid particles) decreases OR frequency of collisions between particles decreases 4(a)(ii) © UCLES 2023 all the (sulfuric) acid has reacted Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question 4(b) Answer M1 greater surface area (of zinc) May/June 2023 Marks M2 frequency of collisions between (zinc and acid) particles increases 4(c) M1 mol H2SO4 = 2.00 x 25.0/1000 = 0.05(00) M2 mol H2 = M1 = 0.05(00) M3 vol H2 = M2 24 = 1.2(0) 4(d)(i) Zn + 2HCl → ZnCl2 + H2 M1 ZnCl2 M2 equation correct 4(d)(ii) lighted splint and (squeaky) pop Question 5(a)(i) Answer M1 ionic compound Marks M2 molten and / or aqueous 5(a)(ii) oxidation number (of copper) 5(a)(iii) fades / (becomes) colourless 5(a)(iv) Cu2+ + 2e → Cu M1 Cu2+ and (any number of) e on left hand side M2 equation correct 5(a)(v) 5(b) © UCLES 2023 OH– anode dissolves Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question 5(c)(i) Answer M1 silver May/June 2023 Marks M2 spoon M3 (aqueous or solution) of silver nitrate 5(c)(ii) M1 prevent corrosion M2 improve appearance 5(d)(i) M1 carbon dioxide: (increased) global warming M2 carbon monoxide: toxic 5(d)(ii) needs high pressure to store hydrogen Question Answer Marks 6(a)(i) air 6(a)(ii) methane 6(a)(iii) M1 450 (°C) M2 200 (atm) 6(a)(iv) iron 6(a)(v) M1 (a substance which) increases the rate of a reaction M2 remains unchanged at the end of the reaction © UCLES 2023 Page of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question 6(b)(i) Answer temperature change: M1 low(er) rate (of reaction) May/June 2023 Marks pressure change: M2 (position of) equilibrium shifts to the left hand side/ towards reactants 6(b)(ii) 4NO + 3O2 + 2H2O →.4HNO3 6(c)(i) CuCO3 + 2HNO3 → Cu(NO3)2 + CO2 + H2O M1 Cu(NO3)2 M2 correct equation 6(c)(ii) M1 undissolved solid M2 effervescence stops on addition of more copper(II) carbonate 6(d)(iii) copper(II) oxide or copper(II) hydroxide Question Answer Marks 7(a)(i) ultraviolet (light) 7(a)(ii) M1 displayed formula of 1–chloropropane M2 displayed formula of 2–chloropropane 7(b)(i) any from: (same) general formula (same / similar) chemical properties or reactions (contain the same) functional group © UCLES 2023 Page 10 of 11 0620/43 Cambridge IGCSE – Mark Scheme PUBLISHED Question 7(b)(ii) Answer M1 single bond between the two C atoms (and nothing on continuation bonds) May/June 2023 Marks M2 CH3 group and H on first carbon and CH3 group and H on second carbon and whole structure correct 7(c)(i) M1 structural formula of propan-1,3-dioic acid M2 structural formula of ethan-1,2-diol 7(c)(ii) polyester 7(c)(iii) M1 carboxylic acids M2 alcohols © UCLES 2023 Page 11 of 11