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Oligozinc Enzymes J Am Chem Soc., 118 , 9288-9294 Ruggiero, C.E., Carrier, S.M., Antholine, W.E., Whittaker, J.W., Cramer, C.J & Tolman, W.B (1993) Synthesis and structural and spectroscopic characterization of mononuclear copper nitrosyl complexes: models for nitric oxide adducts of copper proteins and copper-exchanged zeolites J Am Chem Soc., 115 , 112 85 -112 98 424 Biomimetic Based Applications Santini, C.,... 3, 117 1 -118 4 422 Biomimetic Based Applications Pate, J.E., Thamann, T.J & Solomon, E.I (1986) Resonance raman studies of the coupled binuclear copper active site in met azide hemocyanin Spectroc Acta Pt A-Molec Biomolec Spectr., 42A, 313-318 Pellei, M., Gioia Lobbia, G., Papini, G & Santini, C (2010) Synthesis and Properties of Poly(pyrazolyl)borate and Related Boron-Centered Scorpionate Ligands Part. .. (M = Mo, W) Inorg Chem., 36, 356-361 416 Biomimetic Based Applications Hulse, C.L., Tiedje, J.M & Averill, B.A (1989) Evidence for a copper-nitrosyl intermediate in denitrification by the copper-containing nitrite reductase of Achromobacter cycloclastes J Am Chem Soc., 111 , 2322-2323 Ibrahim, M.M., He, G., Seebacher, J., Benkmil, B & Vahrenkamp, H (2005) Biomimetic thiolate alkylation with zinc pyrazolylbis(thioimidazolyl)borate... Creation of type-1 and type-2 copper sites by addition of exogenous ligands to the Pseudomonas aeruginosa azurin His117Gly mutant J Am Chem Soc., 115 , 112 1 -112 9 Den Blaauwen, T., Hoitink, C.W., Canters, G.W., Han, J., Loehr, T.M & Sanders-Loehr, J (1993) Resonance Raman spectroscopy of the azurin His117Gly mutant Interconversion of type 1 and type 2 copper sites through exogenous ligands Biochemistry, 32,... 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Proteins J Am Chem Soc., 119 , 4182-4196 Lee, S.C & Holm, R.H (2003) Speculative synthetic chemistry and the nitrogenase problem Proc Natl Acad Sci U S A., 100, 3595-3600 Biomimetic Applications of Metal Systems Supported by Scorpionates 419 Lee, S.C & Holm, R.H (2004) The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters Chem Rev., 104, 113 5 -115 7 Lehnert, N., Cornelissen,... molecular topological analogues of the PN cluster of nitrogenase 406 Biomimetic Based Applications High-nuclearity metal-sulfur clusters may function as precursors to other clusters related in structure to the P-cluster (Fe8S9) and FeMo-cofactor cluster (MoFe7S9) of nitrogenase (Zhou et al., 2002; Berlinguette et al., 2006) In particular, the double cubane [HB(pz)3]2Mo2Fe6S8(PEt3)4 system has been... complexes as manganese superoxide dismutase mimics Inorg Chem., 32, 1879-1880 418 Biomimetic Based Applications Kitajima, N., Osawa, M., Tanaka, M & Morooka, Y (1991) A novel dioxygenase type oxygen insertion Carbon-hydrogen bond oxidation of isopropyl groups in a dimanganese complex with molecular oxygen J Am Chem Soc., 113 , 8952-8953 Kitajima, N & Tolman, W.B (1995) Coordination chemistry with sterically... enzymes have become excellent targets within biomimetic chemistry Modelling of hydrogenase enzymes requires the efficient synthesis of half-sandwich complexes of the form [HB(timR)3]NiX or [H2B(timR)2]NiX The chemistry of nikel is driven by the formation of bis-ligand complexes such as [HB(timR)3]2Ni (Garner et al., 2003; Senda et al., 2006) and 408 Biomimetic Based Applications [H2B(timR)2]2Ni (Alvarez et... 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