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BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC BÁCH KHOA HÀ NỘI - NGUYỄN VĂN QUANG NGHIÊN CỨU CHẾ BIẾN PHẾ THẢI PHOTPHOGIP LÀM PHÂN BÓN VÀ PHỤ GIA XI MĂNG LUẬN ÁN TIẾN SĨ KỸ THUẬT HÓA HỌC Hà Nội- 2016 BỘ GIÁO DỤC VÀ ĐÀO TẠO TRƯỜNG ĐẠI HỌC BÁCH KHOA HÀ NỘI - NGUYỄN VĂN QUANG NGHIÊN CỨU CHẾ BIẾN PHẾ THẢI PHOTPHOGIP LÀM PHÂN BÓN VÀ PHỤ GIA XI MĂNG Chuyên ngành: Kỹ thuật Hóa học Mã số: 62520301 LUẬN ÁN TIẾN SĨ KỸ THUẬT HÓA HỌC NGƯỜI HƯỚNG DẪN KHOA HỌC 1.GS.TSKH La Văn Bình PGS.TS La Thế Vinh Hà Nội – 2016 LỜI CAM ĐOAN T i xin cam oan c c kết qu nghiên c u luận n c a t i ới s h ớng n GS.TSKH La Văn Bình PGS.TS La Thế Vinh C c số li u kết qu ày luận n hoàn toàn trung th c, kh ng ch p, tr ng l p với C c kết qu nghiên c u c ng ch a có c ng ố t kì kh c t k c ng trình nghiên c u kh c Hà Nội, th ng Thay m t tập thể h ớng n năm 2016 T c gi GS.TSKH La Văn Bình Nguy n Văn Quang i c trình LỜI CẢM N Đ u tiên t i xin g i lời c m n ch n thành s u s c tới GS TSKH La Văn Bình ã gi p t i nh h ớng tên tuổi t c h ớng tài, c ng chi tiết, Th y ã kh ng qu n ng i n t i kiến th c, kĩ quan trọng từ ngày u ỡ ngỡ Tôi xin g i lời tri n s u s c nh t tới PGS.TS La Thế Vinh, Th y ã tận tình h ớng n, a nh h ớng, t o i u ki n thuận l i nh t gi p t i hoàn thành luận n T i xin ch n thành c m n c c th y, c Bộ m n C ng ngh c c ch t v c ã t o i u ki n thuận l i v c sở vật ch t chuyên m n gi p t i hoàn thành luận n T i xin ch n thành c m n Khoa Hóa học, Tr ờng ĐHSP Hà Nội ã t o i u ki n v thời gian ể t i hoàn thành luận n Cuối c ng t i xin ch n thành c m ng ời th n n s ộng viên kh ch l c a c i t gia ình ã t o ni m tin gi p t i ph n n u học tập hoàn thành luận n T c gi Nguy n Văn Quang ii , MỤC LỤC DANH MỤC CÁC CHỮ VIẾT TẮT v DANH MỤC CÁC BẢNG .vi DANH MỤC CÁC HÌNH viii MỞ ĐẦU CHƯ NG TỔNG QUAN 1.1 Thành phần hóa học photphogip T nh h nh ph t sinh s d ng photphogip 1.2.1 Tình hình ph t sinh s ụng photphogip giới .8 1.2.2 Tình hình s n xu t tiêu thụ photphogip Vi t Nam 22 Nhận xét 24 Ứng d ng c c sản phẩm sau x lý 25 1.4.1 Ứng ụng c a ammonium sulfate thu c 25 1.4.2 Ứng ụng c a Canxi flouri e .25 1.4.3 Ứng ụng c a Canxi oxi e 26 1.4.4 Ứng ụng Canxi sulfi e 26 1.4.5 Ứng ụng c a l u hu nh ioxi e 27 Kết luận 27 CHƯ NG PHƯ NG PHÁP NGHIÊN CỨU VÀ THỰC NGHIỆM 28 2.1 Ph ng ph p nghi n cứu .28 2.1.1 Ph ng ph p hóa học ớt ph n t ch thành ph n nguyên li u s n ph m [1,2,27,32,86] 28 2.1.2 Ph ng ph p hóa l ph n t ch nguyên li u s n ph m 33 Ph ng ph p nghi n cứu thực nghiệm 37 2.2.1 D ng ph n ng trao ổi ion ể chuyển hóa gốc sulfate c a ã th i photphogip thành muối sulfate hòa tan 37 2.2.2 Ph n ng ng pha r n 38 2.2.3 X l số li u 40 CHƯ NG KẾT QUẢ VÀ THẢO LUẬN .41 3.1 Phân tích thành phần photphogip ban đầu 41 3.1.1 Thành ph n hóa học học c a photphogip 41 3.1.2 Hàm l ng c c nguyên tố kh c m u photphogip 41 3.1.3 Thành ph n pha 43 3.2 Nghi n cứu phản ứng chu n hóa g c sulfate P dung d ch 44 3.2.1 Kh o s t c c yếu tố nh h ởng ến hi u su t ph n ng .44 3.2.2 Ph n t ch thành ph n s n ph m 56 3.2.3 Nhận x t 60 3.2.4 S i u chế ammonium sulfate từ photphogip 61 3.3 Nghi n cứu qu tr nh kh photphogip phản ứng pha rắn 63 3.3.1 Nhi t ộng học qu trình ph n h y photphogip 63 3.3.2 Ảnh h ởng c c yếu tố ến hi u su t kh canxi sulfate ằng l u hu nh 71 3.3.3 Ảnh h ởng c c yếu tố ến hi u su t kh PG ằng than ho t t nh 78 3.3.4 Ảnh h ởng c c yếu tố ến hi u su t kh PG ằng than gỗ 91 3.3.5 Ảnh h ởng c c yếu tố ến hi u su t kh PG ằng than 96 3.3.6 Nhận x t 103 Nhận xét chung 103 iii KẾT LUẬN 105 TÀI LIỆU THAM KHẢO 106 DANH MỤC CÁC CƠNG TRÌNH ĐÃ CƠNG BỐ CỦA LUẬN ÁN 115 PHỤ LỤC 116 iv DANH MỤC CÁC CHỮ VIẾT TẮT Chữ viết t t FDG Tên Flue-gas esulfurization gypsum ( th ch cao nhà m y kh l u hu nh) DTA Ph n t ch nhi t vi sai ( ifferential thermal analyis) DSC Ph p o nhi t l ng qu t vi sai ( ifferential scanning calorimetry) ICP-MS Ph ng ph p khối phổ plasma ICP-MS (inductively coupled plasma mass spectrometry) IR Phổ h ng ngo i PG Photphogip XRD Phổ nhi u x tia X DH Dihydrat HH Hemihydrat HDH Hemidihydrat KCN Khu c ng nghi p C2 S 2CaO.SiO C3 S 3CaO.SiO SA Ammonium sulfate v DANH MỤC CÁC BẢNG Nội ung Trang B ng 1.1 H p ch t hóa học iển hình PG c a số v ng Mỹ B ng 1.2 N ng ộ c a nguyên tố vi l ng PG B ng 1.3 N ng ộ ch t phóng x qu ng PG B ng 1.4 Kết qu ph n t ch m u PG iển hình theo c ng ngh DH, HH, HDH B ng 3.1 Thành ph n hóa học ã th i photphogip 41 B ng 3.2 Hàm l ng hóa học c c nguyên tố kh c ã th i photphogip 42 B ng 3.3 Ảnh h ởng tốc ộ khu y ến hi u su t ph n ng 45 B ng 3.4 Ảnh h ởng thời gian ến hi u su t ph n ng 47 B ng 3.5 Ảnh h ởng t l PG/H2 O ến hi u su t ph n ng 48 B ng 3.6 Ảnh h ởng khối l ng NH4 F ến hi u su t ph n ng 50 B ng 3.7 Ảnh h ởng c a nhi t ộ ến hi u su t ph n ng 51 B ng 3.8 Ảnh h ởng c a n ng ộ thể t ch NH3 ến hi u su t ph n ng 52 B ng 3.9 Ảnh h ởng c a n ng ộ thể t ch ure ến hi u su t ph n ng 54 B ng 3.10 Ảnh h ởng NH3 ure ến hi u su t ph n ng 55 B ng 3.11 Thành ph n hóa học c a m u ammonium sulfate thu c B ng 3.12 Thành ph n c c nguyên tố kh c ammonium sulfate thu 57 60 c sau ph n ng B ng 3.13 Một số ữ ki n th ng số c a CaSO , CaO, SO , O2 64 B ng 3.14 Tỷ l c c 68 ng l u hu nh c c nhi t ộ kh c B ng 3.15 C c th ng số nhi t ộng c a C CO 70 B ng 3.16 Ảnh h ởng nhi t ộ ến hi u su t ph n ng PG ằng l u hu nh 72 B ng 3.17 Ảnh h ởng c a k ch th ớc h t ến hi u su t qu trình ph n h y 73 PG ằng l u hu nh thời gian 60 ph t B ng 3.18 Ảnh h ởng c a thời gian ến hi u su t qu trình ph n h y PG 74 ằng l u hu nh B ng 3.19 Ảnh h ởng c a t p ch t ến hi u su t ph n h y photphogip 76 B ng 3.20 Kh o s t hi u su t ph n ng ph n h y PG ằng l u hu nh 78 nhi t ộ 600o C B ng 3.21 Ảnh h ởng thời gian nung khối l ng than ho t t nh ến hi u su t ph n ng nung m u nhi t ộ 700 o C vi 80 C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an B ng 3.22 Ảnh h ởng thời gian nung khối l ng than ho t t nh ến 82 B ng 3.23 Ảnh h ởng thời gian nung khối l ng than ho t t nh ến 84 hi u su t ph n ng nung m u nhi t ộ 900 o C hi u su t ph n ng nung m u nhi t ộ 1000 o C B ng 3.24 Khối l ng CaSO kh hi u su t ph n ng 89 B ng 3.25 Ảnh h ởng thời gian nung khối l ng than gỗ ến hi u su t 92 ph n ng nung m u nhi t ộ 900 o C B ng 3.26 Ảnh h ởng thời gian nung khối l ng than gỗ ến hi u su t 94 ph n ng nung m u nhi t ộ 1000 o C B ng 3.27 Ảnh h ởng thời gian nung khối l ng than ến hi u su t 97 ến hi u su t 99 ến hi u su t 101 ph n ng nung m u nhi t ộ 700 o C B ng 3.28 Ảnh h ởng thời gian nung khối l ng than ph n ng nung m u nhi t ộ 900 o C B ng 3.29 Ảnh h ởng thời gian nung khối l ng than ph n ng nung m u nhi t ộ 1000 o C vii Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an DANH MỤC CÁC HÌNH Nội ung Trang Hình 1.1 PG c a giới Hình 1.2 Quy trình chuyển ổi ng c ịng c a FGD 17 Hình 1.3 Ammonium sulfate từ PG với NH3 CO 18 Hình 1.4 S n xu t ammonium sulfate từ th ch cao FGD NH3 , CO 19 Hình 1.5 H thống t ch h p l ng ph n h y PG thành CaO SO 21 Hình 1.6 Photphogip c a nhà m y DAP Đình V - H i Phịng 23 Hình 2.1 Ch ng c t làm giàu F - 32 Hình 3.1 Gi n XRD m u ã th i PG an u 43 Hình 3.2 Ảnh h ởng tốc khu y ến hi u su t ph n ng 46 Hình 3.3 Ảnh h ởng c a thời gian ến hi u su t ph n ng 47 Hình 3.4 Ảnh h ởng t l PG H2 O ến hi u su t ph n ng 49 Hình 3.5 Ảnh h ởng c a khối l ng NH4 F ến hi u su t ph n ng 50 Hình 3.6 Ảnh h ởng c a nhi t ộ ến hi u su t ph n ng 51 Hình 3.7 Ảnh h ởng c a n ng ộ thể t ch NH3 ến hi u su t ph n ng 53 Hình 3.8 Ảnh h ởng c a n ng ộ thể t ch ure ến hi u su t ph n ng 54 Hình 3.9 Ảnh h ởng c a NH3 ure 56 ến hi u su t ph n ng Hình 3.10 S n ph m Ammonium sulfate thu c 56 Hình 3.11 Gi n XRD c a Ammonium sulfate thu Hình 3.12 Gi n XRD c a canxi flouride thu Hình 3.13 Phổ IR c a Ammonium sulfate thu Hình 3.14 Phổ IR c a canxi flouride thu Hình 3.15 Quy trình c ng ngh c sau ph n ng c sau ph n ng c sau ph n ng c sau ph n ng i u chế Ammonium sulfate từ photphogip 57 58 58 59 62 Hình 3.16 S phụ thuộc c a ∆GT (cp) vào nhi t ộ T c a ph n ng 3-1 66 Hình 3.17 C n ằng c c c u t l u hu nh với nhi t ộ t 67 ng ng Hình 3.18 S phụ thuộc c a ∆GT ph n ng 3-18 vào nhi t ộ 69 Hình 3.19 S phụ thuộc ∆GT c a ph n ng (3-22) theo nhi t ộ 71 Hình 3.20 Ảnh h ởng c a nhi t ộ ến qu trình ph n ng kh PG ằng l u 72 hu nh Hình 3.21 Ảnh h ởng c a k ch th ớc h t ến hi u su t ph n ng kh PG viii Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn 73 C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an [74] Myung gyu Lee, Young Nam Jang , Kyung won Ryu, Wonbeak Kim, JunHwan Bang, (2012), Mineral carbonation of flue gas desulfur ization gypsum for CO2 sequestration, Energy 47 370-377 [75] N A Yahay, H Ahmad, (2011), Numerical Investigation of Indoor Air Temperature with the Application of PCM Gypsum 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an [86] Shaocong Zheng, Ping Ning, et al, (2012), Reductive decomposition of photphogypsum with high-sulfua-concentration coal to SO2 in an inert atmosphere Elsevier Science, 57, 12-08-2012 [87] Singh M (2005), Role of phosphogypsum impurities on strength and microstructure of selenite plaster Constr Build 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77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an [97] Valenti, G., (1987) High-temperature synthesis of calcium sulphoaluminate from phosphogypsum Thermochimica Acta 113, 269-275 [98] XiaohongLiu, JialiLiu, FeipengZhao (2012), Application of Gypsum Composite Concrete in the Antique Building Bracket Set, Applied Mechanics and Materials Vols 174-177 pp 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sun x, liu x, han w and wang l (2013), Reaction mechanism of reductive decomposition of FGD gypsum with anthracite Thermochim Acta 559 23–31 [106] Zheng SC, Ning P, Ma LP, et al (2011), Reductive decomposition of phosphogypsum with high-sulfur-concentration coal to SO2 in an inert atmosphere ChemEng Res Des 2011;89:2736–41 [107] Zheng SC, Ning P, Ma LP, et al (2010), Reaction properties of thermal decomposition of phosphogypsum in different atmospheres J Wuhan UnivTechnol – Mater Sci 2010; 34(3):580–3 [in Chinese] [108] Zhou, L., Chen, D., Luo, W., Wang, Y., Yu, Y., Liu, F., (2007), Transparent glass ceramic containing Er3ỵ:CaF nano-crystals prepared by solgel method, Mater Lett, 61, 3988 114 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an DANH MỤC CÁC CƠNG TRÌNH ĐÃ CƠNG BỐ CỦA LUẬN ÁN Nguy n Văn Quang, La Văn Bình, La Thế Vinh iều chế ammonium sulfatee từ gypsum ammonium flouride T p ch Hóa học, 52 (5A),143-146 (2014) Nguy n Văn Quang, La Văn Bình, La Thế Vinh Qu tr nh kh g psum carbon hoạt tính kết hợp với silic dioxide nhiệt độ cao T p ch Hóa học, 53 (3e122015),143-146 (2015) Nguy n Văn Quang, La Văn Bình, La Thế Vinh, Nguy n Quang B c Nghi n cứu trình kh g psum l u huỳnh nhiệt độ cao T p ch Hóa học, 53 (5e-2015), 107-110 (2015) Nguy n Văn Quang, La Văn Bình, La Thế Vinh Nghi n cứu qu tr nh kh photphogip than hoạt tính nhiệt độ cao T p ch Hóa học, 53(6e453-2015), 333336 (2015) 115 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an PHỤ LỤC Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample d=2.840 500 400 d=2.010 Lin (Cps) 300 d=1.371 d=1.422 d=1.815 d=2.125 d=2.228 d=3.273 d=4.237 100 d=1.642 d=3.336 200 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 1.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 13 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-078-1922 (C) - Oldhamite, syn - CaS - Y: 70.73 % - d x by: - WL: 1.5406 - Cubic - a 5.68900 - b 5.68900 - c 5.68900 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 14.49 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - Phụ ục XRD mẫu sản phẩm g P , 5g C hoạt tính nung o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample d=2.847 500 400 d=2.013 Lin (Cps) 300 d=1.425 d=1.420 d=1.542 d=1.574 d=1.706 d=1.644 d=3.342 d=1.867 d=1.844 d=1.818 d=4.253 d=4.694 100 d=3.494 200 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 2.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 11 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-078-1922 (C) - Oldhamite, syn - CaS - Y: 57.39 % - d x by: - WL: 1.5406 - Cubic - a 5.68900 - b 5.68900 - c 5.68900 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 12.91 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 18.00 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - Phụ ục XRD mẫu sản phẩm g P , 5g C hoạt tính nung 116 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn o C gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 500 d=2.841 400 d=2.010 Lin (Cps) 300 d=1.540 d=1.816 d=2.276 d=2.452 d=4.238 100 d=1.422 d=1.642 d=3.334 200 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 3.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 13 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-078-1922 (C) - Oldhamite, syn - CaS - Y: 50.14 % - d x by: - WL: 1.5406 - Cubic - a 5.68900 - b 5.68900 - c 5.68900 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 24.87 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - Phụ ục XRD mẫu sản phẩm g P , 5g C hoạt tính nung o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 800 d=3.483 700 600 400 d=3.327 Lin (Cps) 500 300 d=1.374 d=1.452 d=1.487 d=1.560 d=1.540 d=1.522 d=1.670 d=1.646 d=1.746 d=1.864 d=1.814 d=2.124 d=2.081 d=2.202 d=2.177 d=2.322 d=2.276 d=2.467 d=2.839 d=3.105 d=4.232 100 d=3.852 200 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 4.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 12 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 24.19 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 33.34 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - Phụ ục XRD mẫu sản phẩm g P , g C hoạt tính , g SiO nung 65 o C gi 117 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample d=3.485 600 500 300 d=1.381 d=1.374 d=1.540 d=1.563 d=1.646 d=1.746 d=1.865 d=1.848 d=1.816 d=1.978 d=1.934 d=2.081 d=2.204 d=2.180 d=3.862 d=4.242 100 d=2.321 d=2.842 d=2.792 200 d=2.462 d=3.337 Lin (Cps) 400 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 5.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 14 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 33.43 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 24.96 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - Phụ ục XRD mẫu sản phẩm g P , 5g C hoạt tính , g SiO nung 65 o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 1200 d=3.498 1100 1000 900 800 Lin (Cps) 700 600 500 d=1.397 d=1.382 d=1.492 d=1.565 d=1.543 d=1.537 d=1.526 d=1.648 d=1.592 d=1.750 d=1.819 d=1.869 d=1.939 d=1.994 d=2.128 d=2.086 d=2.329 d=2.280 d=2.236 d=2.209 d=2.184 d=2.475 d=3.117 d=3.875 100 d=8.717 200 d=4.258 300 d=2.853 d=2.802 d=3.343 400 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 6.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 14 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 31.93 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 22.92 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - P ụ lục XRD mẫu sản phẩm g P ,2g C hoạt tính 0,2g SiO2 nung 65 o C 118 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample d=3.341 d=3.493 400 d=1.382 d=1.488 d=1.561 d=1.541 d=1.593 d=1.702 d=1.673 d=1.648 d=1.817 d=1.749 d=1.868 d=1.937 d=1.979 d=2.127 d=2.081 d=2.209 d=2.185 d=2.328 d=2.278 d=2.456 d=2.627 d=2.852 d=2.774 d=3.115 d=3.874 100 d=4.050 d=2.403 200 d=4.249 Lin (Cps) 300 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 7.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 13 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 56.39 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 73.66 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - 00-039-1425 (*) - Cristobalite, syn - SiO2 - Y: 10.50 % - d x by: - WL: 1.5406 - Tetragonal - a 4.97320 - b 4.97320 - c 6.92360 - alpha 90.000 - beta 90.000 - gamma 90.000 - Primitive - P41212 (92) - - 17 01-070-4068 (C) - Calcium Oxide - CaO - Y: 15.94 % - d x by: - WL: 1.5406 - Cubic - a 4.80700 - b 4.80700 - c 4.80700 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - P ụ lục XRD mẫu sản phẩm g P o ,1g C hoạt tính , g SiO2 nung 950 C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 800 d=3.346 700 d=3.499 600 Lin (Cps) 500 400 300 d=1.397 d=1.383 d=1.373 d=1.490 d=1.563 d=1.541 d=1.525 d=1.672 d=1.648 d=1.700 d=1.749 d=1.818 d=1.869 d=1.994 d=2.127 d=2.084 d=2.329 d=2.283 d=2.235 d=2.210 d=2.185 d=2.475 d=2.457 d=2.404 d=2.850 d=2.779 d=2.721 d=3.115 d=4.063 100 d=3.875 d=4.255 200 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 8.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 14 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 39.82 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 26.51 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - 00-039-1425 (*) - Cristobalite, syn - SiO2 - Y: 3.49 % - d x by: - WL: 1.5406 - Tetragonal - a 4.97320 - b 4.97320 - c 6.92360 - alpha 90.000 - beta 90.000 - gamma 90.000 - Primitive - P41212 (92) - - 171 01-070-4068 (C) - Calcium Oxide - CaO - Y: 3.75 % - d x by: - WL: 1.5406 - Cubic - a 4.80700 - b 4.80700 - c 4.80700 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 11 P ụ lục XRD mẫu sản phẩm g P , 5g C hoạt tính 119 o , g SiO nung 95 C Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 800 d=3.500 700 600 400 d=1.375 d=1.397 d=1.491 d=1.454 d=1.542 d=1.526 d=1.649 d=1.594 d=1.749 d=1.869 d=1.818 d=1.937 d=2.086 d=1.995 d=1.980 d=2.799 d=3.124 d=4.254 d=3.875 100 d=4.059 200 d=2.329 d=2.282 d=2.237 d=2.210 d=2.184 d=2.850 d=3.344 300 d=2.473 d=2.457 d=2.404 Lin (Cps) 500 10 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 9.raw - Type: 2Th/Th locked - Start: 10.000 ° - End: 70.000 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 13 s - 2-Theta: 10.000 ° - Theta: 5.000 ° - Chi: 0.00 ° 01-080-0787 (D) - Calcium Sulfate - Ca(SO4) - Y: 54.06 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.99200 - b 6.99900 - c 6.24000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bmmb 03-065-0466 (C) - Quartz low, syn - SiO2 - Y: 33.22 % - d x by: - WL: 1.5406 - Hexagonal - a 4.91410 - b 4.91410 - c 5.40600 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3221 (154) - - 00-039-1425 (*) - Cristobalite, syn - SiO2 - Y: 4.74 % - d x by: - WL: 1.5406 - Tetragonal - a 4.97320 - b 4.97320 - c 6.92360 - alpha 90.000 - beta 90.000 - gamma 90.000 - Primitive - P41212 (92) - - 171 01-070-4068 (C) - Calcium Oxide - CaO - Y: 3.18 % - d x by: - WL: 1.5406 - Cubic - a 4.80700 - b 4.80700 - c 4.80700 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 11 P ụ lục XRD mẫu sản phẩm g P o , g C hoạt tính , g SiO nung 95 C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 1-700C-1h 3100 3000 2900 2800 d=3.490 2700 2600 2500 2400 2300 2200 2100 2000 1900 1700 1600 1500 1400 1300 1200 1100 1000 900 800 d=1.396 d=1.372 d=1.425 d=1.490 d=1.564 d=1.541 d=1.524 d=1.594 d=1.647 d=1.748 d=1.815 100 d=1.867 d=1.851 d=1.935 d=1.992 d=2.083 d=2.206 d=2.180 d=2.324 d=2.278 d=2.469 200 d=2.793 300 d=3.112 400 d=3.864 500 d=3.336 600 d=2.845 700 d=4.240 Lin (Cps) 1800 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 1-700C-1h.raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: 0.8 s - Temp.: 25 °C (Room) - Time Started: 12 s - 2-Theta: 20.000 ° - Theta: 10.000 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 29.59 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-003-0444 (D) - Quartz - SiO2 - Y: 1.39 % - d x by: - WL: 1.5406 - Hexagonal - a 4.90300 - b 4.90300 - c 5.39300 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3121 (152) - - 112.275 - P ụ lục XRD mẫu sản phẩm g P , g than gỗ nung 120 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn o C gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 2-800C-1h 2100 2000 1900 d=3.486 1800 1700 1600 1500 1400 Lin (Cps) 1300 1200 1100 1000 900 800 700 d=1.365 d=1.424 d=1.397 d=1.489 d=1.563 d=1.540 d=1.591 d=1.645 d=1.669 d=1.746 d=1.865 d=1.849 d=1.814 d=1.990 d=1.934 100 d=2.081 d=2.204 d=2.178 d=2.323 d=2.467 200 d=3.112 d=4.248 d=3.863 300 d=2.788 400 d=2.843 d=3.333 500 d=2.122 600 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 2-800C-1h.raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: 0.8 s - Temp.: 25 °C (Room) - Time Started: 12 s - 2-Theta: 20.000 ° - Theta: 10.000 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 44.02 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-003-0444 (D) - Quartz - SiO2 - Y: 2.58 % - d x by: - WL: 1.5406 - Hexagonal - a 4.90300 - b 4.90300 - c 5.39300 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3121 (152) - - 112.275 - P ụ lục XRD mẫu sản phẩm g P , g than gỗ nung o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 3-900C-1h 1200 d=3.488 1100 1000 900 800 600 500 d=1.396 d=1.425 d=1.490 d=1.462 d=1.541 d=1.524 d=1.562 d=1.593 d=1.646 d=1.747 d=1.697 d=1.867 d=1.849 d=1.814 d=1.992 d=1.936 d=2.082 d=2.206 d=2.180 d=2.325 d=2.278 d=2.467 d=2.399 d=2.610 d=2.788 d=3.114 100 d=3.858 200 d=4.041 300 d=3.337 d=2.844 400 d=4.242 Lin (Cps) 700 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 3-900C-1h.raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: 0.8 s - Temp.: 25 °C (Room) - Time Started: 10 s - 2-Theta: 20.000 ° - Theta: 10.000 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 69.53 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-003-0444 (D) - Quartz - SiO2 - Y: 4.48 % - d x by: - WL: 1.5406 - Hexagonal - a 4.90300 - b 4.90300 - c 5.39300 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3121 (152) - - 112.275 01-082-1691 (C) - Lime - CaO - Y: 6.46 % - d x by: - WL: 1.5406 - Cubic - a 4.79670 - b 4.79670 - c 4.79670 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 110.364 - I/I P ụ lục XRD mẫu sản phẩm g P , g than gỗ nung 121 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn o C gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 4-1000C-1h 1200 1100 d=3.483 1000 900 800 Lin (Cps) 700 600 d=1.424 d=1.396 d=1.488 d=1.562 d=1.522 d=1.645 d=1.698 d=1.865 d=1.815 d=1.848 d=1.990 d=1.935 d=2.081 d=2.178 d=2.466 d=2.399 d=2.788 d=3.331 d=3.110 100 d=3.857 d=4.227 200 d=4.039 300 d=2.203 d=2.323 400 d=1.746 d=2.841 500 20 30 40 50 60 70 2-Theta - Scale File: Quang SP mau 4-1000C-1h.raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: 0.8 s - Temp.: 25 °C (Room) - Time Started: 11 s - 2-Theta: 20.000 ° - Theta: 10.000 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 73.95 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-003-0444 (D) - Quartz - SiO2 - Y: 4.32 % - d x by: - WL: 1.5406 - Hexagonal - a 4.90300 - b 4.90300 - c 5.39300 - alpha 90.000 - beta 90.000 - gamma 120.000 - Primitive - P3121 (152) - - 112.275 01-082-1691 (C) - Lime - CaO - Y: 4.82 % - d x by: - WL: 1.5406 - Cubic - a 4.79670 - b 4.79670 - c 4.79670 - alpha 90.000 - beta 90.000 - gamma 90.000 - Face-centered - Fm-3m (225) - - 110.364 - I/I P ụ lục XRD mẫu sản phẩm g P , g than gỗ nung 1000 o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 3000 2900 2800 2700 2600 2500 2400 d=3.485 2300 2200 2100 2000 1900 1700 1600 1500 1400 1300 1200 1100 1000 900 d=1.563 d=1.645 d=1.669 d=1.747 d=1.815 d=1.866 d=1.849 d=1.989 d=1.540 d=1.523 d=1.515 100 d=1.935 d=1.909 d=2.082 d=2.204 d=2.178 d=2.124 200 d=2.843 d=2.792 300 d=3.108 400 d=3.861 500 d=2.323 600 d=2.277 700 d=2.466 d=3.332 800 d=4.237 Lin (Cps) 1800 20 30 40 50 60 70 2-Theta - Scale File: Quang mau 1(2).raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 11 s - 2-Theta: 20.000 ° - Theta: 10.000 ° - Chi: 0.00 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 26.73 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-028-0775 (Q) - Calcium Oxide - CaO - Y: 3.32 % - d x by: - WL: 1.5406 - P ụ lục XRD mẫu sản phẩm g P , g than đ nung 122 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn o C gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 3000 2900 2800 2700 2600 2500 2400 d=3.482 2300 2200 2100 2000 1900 Lin (Cps) 1800 1700 1600 1500 1400 1300 1200 1100 1000 900 800 700 d=1.423 d=1.395 d=1.485 d=1.562 d=1.522 d=1.645 d=1.746 d=1.865 d=1.989 d=1.934 d=2.080 d=1.591 100 d=2.203 d=2.177 d=2.321 200 d=2.270 300 d=2.466 d=3.853 400 d=3.327 500 d=2.840 d=2.786 600 20 30 40 50 60 70 2-Theta - Scale File: Quang mau 2(2).raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 10 s - 2-Theta: 20.000 ° - Theta: 10.000 ° - Chi: 0.00 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 29.98 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-028-0775 (Q) - Calcium Oxide - CaO - Y: 3.36 % - d x by: - WL: 1.5406 - P ụ lục XRD mẫu sản phẩm g P , g than đ nung o C gi Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample 2300 2200 2100 2000 1900 d=3.488 1800 1700 1600 1500 1300 1200 1100 1000 900 800 700 d=1.396 d=1.425 d=1.490 d=1.541 d=1.524 d=1.564 d=1.592 d=1.647 d=1.748 d=1.697 d=1.817 d=1.991 d=1.937 d=2.083 d=2.207 d=2.181 d=2.325 d=2.469 d=1.867 d=1.851 100 d=2.402 d=2.793 200 d=3.116 300 d=3.866 400 d=3.338 500 d=2.845 600 d=4.248 Lin (Cps) 1400 20 30 40 50 60 70 2-Theta - Scale File: Quang mau 3(2).raw - Type: 2Th/Th locked - Start: 20.000 ° - End: 70.010 ° - Step: 0.030 ° - Step time: s - Temp.: 25 °C (Room) - Time Started: 11 s - 2-Theta: 20.000 ° - Theta: 10.000 ° - Chi: 0.00 ° 01-074-1782 (D) - Calcium Sulfate - CaSO4 - Y: 45.46 % - d x by: - WL: 1.5406 - Orthorhombic - a 6.23000 - b 6.98000 - c 6.97000 - alpha 90.000 - beta 90.000 - gamma 90.000 - Base-centered - Bbmm ( 00-028-0775 (Q) - Calcium Oxide - CaO - Y: 4.02 % - d x by: - WL: 1.5406 - P ụ lục XRD mẫu sản phẩm g P , g than đ nung 900 o C 123 Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn gi C.33.44.55.54.78.65.5.43.22.2.4 22.Tai lieu Luan 66.55.77.99 van Luan an.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.C.33.44.55.54.78.655.43.22.2.4.55.22 Do an.Tai lieu Luan van Luan an Do an.Tai lieu Luan van Luan an Do an Stt.010.Mssv.BKD002ac.email.ninhd 77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77.77.99.44.45.67.22.55.77.C.37.99.44.45.67.22.55.77t@edu.gmail.com.vn.bkc19134.hmu.edu.vn.Stt.010.Mssv.BKD002ac.email.ninhddtt@edu.gmail.com.vn.bkc19134.hmu.edu.vn