Api dr 53 1996 scan (american petroleum institute)

~ S T D - A P I I P E T R O PUBL DR53-ENGL L99b ~TNAmerican 0732290 b 9LiO -* Petroleum Institute Characterization of Exploration and Production Associated Waste Health and Environmental Sciences Department Publication Number DR53 November 1996 `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale STD.API/PETRO ~~ PUBL DR53-ENGL L79b 0732270 05b403b 887 ~ = ~ `,,-`-`,,`,,`,`,,` - One of ithie mmsi significant long-term trends affecting the future vitality of the petroleum industry is the public’s about the environment Recognizingthis trend, API member companies have developed a positiva, ỵmwmkboking strategy called STEP: Strategies for Today’s Environmental Partnership This ,programaims a0 address public concerns by improving our industry’s environmental, health and safety perfomantx%documenting performance improvements; and communicating them to the public The faindatbn d STEP W the API Environmental Mission and Guiding Environmental Principles .W#¡RONMENTAL MISSION AND GUIDING ENVIRONMENTAL PRINCIPLES The mmlms af the American Petroleum Institute are dedicated to continuous efforts to improve the compatiMQ d ou operations with the environment while economically developing energy resources and supplying tqjh quality products and services to consumers The members recognize the importance of efficientiy mmhg society’s needs and our responsibility to work with the public, the government, and others Eo $emlap and to use natural resources in an environmentally sound manner while protecting the health and sabty of our employees and the public To meet these responsibilities, API members pledge to manage our v e s according to these principles: To rem@w and to respond to community concerns about our raw materials, products and - + To operate our plants and facilities, and to handle our raw materials and products in a manner that pmtects the environment, and the safety and health of our employees and the public + To make safety, health and environmental considerations a priority in our planning, and our d&qmnt + C of new products and processes To advise promptly, appropriate officials, employees, customers and the public of information on signiíkant industry-related safety, health and environmental hazards, and to recommend protecaie measures To cwnsel customers, transporters and others in the safe use, transportation and disposal of our TBW materials, products and waste materials To ecc)wmically develop and produce natural resources and to conserve those resources by using energy efficiently To extend knowledge by conducting or supporting research on the safety, health and environmental effects of our raw materials, products, processes and waste materials To commit to reduce overall emission and waste generation To work with others to resolve problems created by handling and disposal of hazardous substancec from our operations To participate with government and others in creating responsible laws, regulations and stanâards to safeguard the community, workplace and environment To promote these principles and practices by sharing experiences and offering assistance to others who produce, handle, use, transport or dispose of similar raw materials, petroleum products and wastes Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale S T D A P I / P E T R O PUBL D R - E N G L 9 b O732290 05b11037 713 Characterization of Exploration and Production Associated Wastes Health and Environmental Sciences Department API PUBLICATION NUMBER DR53 PREPARED BY: INSTITUTE AMERICAN PETROLEUM PRODUCTION WASTE ISSUE GROUP NOVEMBER 1996 American Petroleum Institute `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale ~ S T D - A P I i P E T R O PUBL D R - E N G L L 9 b 2 0 b b5T = FOREWORD API PUBLICATIONS NECESSARILY ADDRESS PROBLEMS OF A GENERAL NATURE WITH RESPECT TO PARTICULAR CIRCUMSTANCES, LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS SHOULD BE REVIEWED API IS NOT UNDERTAKING TO MEET THE DUTIES OF EMPLOYERS, MANUFACTURERS, OR SUPPLIERS TO WARN AND PROPERLY TRAIN AND EQUIP THEIR EMPLOYEES, AND OTHERS EXPOSED, CONCERNING HEALTH AND SAFETY RISKS AND PRECAUTIONS, NOR UNDERTAKING THEIR OBLIGATIONS UNDER LOCAL, STATE, OR FEDERAL LAWS NOTHING CONTAINED IN ANY API PUBLICATION IS TO BE CONSTRUED AS GRANTING ANY RIGHT, BY IMPLICATION OR OTHERWISE, FOR THE MANUFACTURE, SALE, OR USE OF ANY METHOD, APPARATUS, OR PRODUCT COVERED BY LETTERS PATENT NEITHER SHOULD ANYTHING CONTAINED IN THE PUBLICATION BE CONSTRUED AS INSURING ANYONE AGAINST LIABILITY FOR INFRINGEMENT OF LETïERS PAENT iii Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale `,,-`-`,,`,,`,`,,` - Copyright O 1996 American Petroleum Institute ~~~ ~~~ S T D - A P I I P E T R O P U B L D R - E N G L L77b m 0732270 05b4037 57b ACKNOWLEDGMENTS THE FOLLOWING PEOPLE ARE RECOGNIZED FOR THEIR CONTRIBUTIONS OF TIME AND EXPERTISE DURING THIS STUDY AND IN THE PREPARATION OF THIS REPORT API STAFF CONTACTS Harley H.Hopkins, Health and Environmental Sciences Department Tim Sampson, Exploration and Production Department Mark Rubin, Exploration and Production Department MEMBERS OF THE PRODUCTION WASTE ISSUE GROUP IN PARTICULAR, MEMBERS OF THE ASSOCIATED WASTE PROJECT WORK GROUP Rebecca Carovillano, Exxon Production Research Jim Collins, ARCO George Deeley, Shell Development Company Robert Huddleston, Conoco Cheri Koch, Chevron Research and Technology Company Janet Peargin, Chevron Research and Technology Company Jeffrey Ralston, Exxon Company, USA Danny Rycroft, Phillips Petroleum Company Nina Springer, Exxon Production Research Neal Thurber, Amoco Corporation John Wiggin, Exxon Company, USA R H Youngs, British Petroleum Gary Walters, Quanterra Environmental Services, is acknowledged for his role in the sample analysis phase of the project API also acknowledges Ashok Katyal and Jack Parker, Environmental Systems and Technologies, Inc., for performing the VADSAT model simulations API would like to thank Jim Evans, Gas Research Institute, for his participation in the project, including his review of this manuscript iv `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale ~ S T D - A P I / P E T R O PUBL DR53-ENGL 199b ~ 0732290 RSbLiOLiO m TABLE OF CONTENTS Section Page SAMPLING AND ANALYSIS FATE AND TRANSPORT MODELING SUMMARY OF RESULTS AND FINDINGS RECOMMENDATIONS BACKGROUND METHODS e5-1 Sample Collection Sampling Procedures General Sampling Techniques General Sampling Considerations 2-1 EXECUTIVE SUMMARY SAMPLING INFORMATION ANALYTICAL RESULTS CRUDE OIL IMPACTED SOILS Sampling and Analysis Results Discussion TANKBOTTOMS Sampling and Analysis Results Discussion WORKOVER FLUIDS Sampling and Analysis ANALYTICAL METHODS e5-2 e54 e5-4 e5-6 1-1 2-1 2-1 2-2 2-3 2-4 2-6 3-1 3-1 3-1 3-2 3-4 3-5 3-6 3-6 `,,-`-`,,`,,`,`,,` - 3-9 3-9 3-10 Discussion 3-11 3-12 3-12 3-12 3-14 Sampling and Analysis 3-14 Results PRODUCED SAND Sampling and Analysis Results Discussion USEDOIL Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale 3-11 3-15 S T D - A P I I P E T R O PUBL DR53-ENGL L97b 0732290 05b1104L 1'44 = TABLE OF CONTENTS (Continued) Section Paqe ANALYTICAL RESULTS USED OIL (Continued) `,,-`-`,,`,,`,`,,` - Results Discussion 3-15 3-18 DEHYDRATION AND SWEETENING MATERIALS GLYCOL WASTE 3-18 3-18 Sampling and Analysis 3-20 Results Discussion 3-20 3-22 Sampling and Analysis Results Discussion SPENT MOLECULAR SIEVE Sampling and Analysis Results DEHYDRATION CONDENSATE WATER 3-22 3-23 3-23 3-24 3-24 3-24 SPENT IRON SPONGE 3-25 3-26 3-26 3-26 3-27 3-27 Discussion Sampling and Analysis Results USED AMINE Sampling and Analysis Results Discussion PIT AND SUMP SAMPLES Discussion Sampling and Analysis Discussion RIG WASH Sampling and Analysis Results Discussion Results Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale 3-28 3-29 3-29 3-30 3-31 3-31 3-31 3-34 3-34 3-34 3-34 3-35 S T D * A P I / P E T R O PUBL DR53-ENGL L 9 b W 0732290 05b11042 TABLE OF CONTENTS (Continued) Section Pane ANALYTICAL RESULTS (Continued) 3-35 3-36 3-36 3-39 3-39 3-39 3-39 3-40 3-41 Volatile Organic Compounds 3-41 OVERALL DATA DISCUSSION Semi-Volatile Organic Compounds 3-42 Metals 3-43 Laboratory and Project Quality Assurance/Quality Control (QAiQC) Summary 3-44 3-44 Laboratory Contaminants 3-45 COMPARISON OF GRI AND API ANALYTICAL RESULTS 3-46 3-46 Sampling and Analysis 3-46 Results 3-46 Discussion Matrix Interferences FATE AND TRANSPORT OF ASSOCIATED WASTE CONSTITUENTS INTRODUCTION 4-1 4-1 4-1 INPUT DATA USED IN ASSOCIATED WASTE MODELING 4-3 4-12 MODELING RESULTS AND DISCUSSION REFERENCES R-1 OVERVIEW OF THE VADSAT MODEL LIST OF APPENDICES Appendix A: Appendix B: Appendix C: Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS A-2 ANALYTICAL METHODS AND QUALITY CONTROL 6-1 C-1 ANALYTICAL RESULTS SUMMARY OF SAMPLES COLLECTED Not for Resale `,,-`-`,,`,,`,`,,` - Sampling and Analysis Results Discussion PIGGING MATERIALS Sampling and Analysis Results Discussion OIL BASED MUD CUTTINGS STD.API/PETRO PUBL D R - E N G L 177b 0732290 b 4 T L ï M LIST OF FIGURES Firiure 3-1 Paae Glycol Dehydrator 3-19 LIST OF TABLES Table Paae `,,-`-`,,`,,`,`,,` - 2-2 Representative Sampling 2-2 2-3 3-1 Total Appendix IX Volatile Components Detected in Crude Oil Impacted Soil 3-2 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Crude Oil Impacted Soil 3-3 2-1 Summary of Associated Waste Samples Collected 3-2 3-4 3-5 3-3 3-4 Total Appendix IX Metals Detected in Crude Oil Impacted Soil 3-5 Total Appendix IX Volatile Components Detected in Tank Bottoms 3-6 Petroleum Refinery List Semi-Volatile Organic Compounds Detected inTankBottoms 3-7 3-8 3-9 3-1O Background Soil Concentrations for Metals Total Appendix IX Metals Detected in Tank Bottoms 3-7 Total Appendix IX Volatile Components Detected in Workover Fluids Total Appendix IX Volatile Components Detected in Produced Sand 3-7 3-8 3-11 3-13 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Produced Sand 3-13 3-11 Total Appendix IX Metals Detected in Produced Sand 3-14 3-12 Total Appendix IX Volatile Components Detected in Used Oil 3-16 3-13 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Used Oil 3-16 3-17 Total Appendix IX Volatile Components Detected in Glycol Waste 3-20 3-14 Total Appendix IX Metals Detected in Used Oil 3-15 3-16 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Glycol Waste 3-21 3-21 Total Appendix IX Volatile Components Detected in Dehydration Condensate Water 3-23 3-17 Total Appendix IX Metals Detected in Glycol Waste 3-18 3-25 3-20 Total Appendix IX Volatile Components Detected in Spent Iron Sponge 3-27 3-21 Total Appendix IX Volatile Components Detected in Used Amine 3-29 3-19 Total Appendix IX Volatile Components Detected in Mol Sieve Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale ~ ~~ S T D - A P I / P E T R O PUBL DR53-ENGL L99b ~~ 2 0 b 4 753 LIST OF FIGURES Figure 3-1 Paqe Glycol Dehydrator 3-19 LIST OF TABLES Table Pape 2-2 2-3 2-1 Summary of Associated Waste Samples Collected 2-2 Representative Sampling 3-1 Total Appendix IX Volatile Components Detected in Crude Oil Impacted Soil 3-2 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Crude Oil Impacted Soil 3-3 3-2 3-4 3-3 Total Appendix IX Metals Detected in Crude Oil Impacted Soil 3-4 Background Soil Concentrations for Metals 3-5 Total Appendix IX Volatile Components Detected in Tank Bottoms 3-6 Petroleum Refinery List Semi-Volatile Organic Compounds Detected inTankBottoms 3-8 3-9 `,,-`-`,,`,,`,`,,` - 3-7 3-1O 3-5 3-7 3-7 3-8 Total Appendix IX Volatile Components Detected in Workover Fluids 3-11 Total Appendix IX Metals Detected in Tank Bottoms Total Appendix IX Volatile Components Detected in Produced Sand 3-13 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Produced Sand 3-13 3-14 3-11 Total Appendix IX Metals Detected in Produced Sand 3-12 Total Appendix IX Volatile Components Detected in Used Oil 3-13 3-16 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Used Oil 3-16 3-14 Total Appendix IX Metals Detected in Used Oil 3-15 3-16 3-17 Total Appendix IX Volatile Components Detected in Glycol Waste 3-20 Petroleum Refinery List Semi-Volatile Organic Compounds Detected in Glycol Waste 3-17 Total Appendix IX Metals Detected in Glycol Waste 3-18 Total Appendix IX Volatile Components Detected in Dehydration Condensate Water 3-19 3-20 3-21 3-21 3-21 3-23 3-25 Total Appendix IX Volatile Components Detected in Spent Iron Sponge 3-27 Total Appendix IX Volatile Components Detected in Used Amine 3-29 Total Appendix IX Volatile Components Detected in Mol Sieve Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale ~ STD.API/PETRO P U B L D R - E N G L L99b 0732290 05b4L77 280 APPENDIX C ANALYTICAL RESULTS `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale `,,-`-`,,`,,`,`,,` - c-2 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS S T D - A P I / P E T R O PUBL DR53-ENGL L 9 b I07322911 05bqL78 117 m Not for Resale `,,-`-`,,`,,`,`,,` - c-3 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS STD*API/PETRO P U B L DR53-ENGL L99b ~~ ~~ ~ 0732290 05bliL79 053 Not for Resale - ~ = ~~~ 2 05bllLBO `,,-`-`,,`,,`,`,,` - S T D o A P I / P E T R O P U B L D R - E N G L L77b _ c-4 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale STD.API/PETRO PUBL D R - E N G L `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS 1776 D 2 05blll81 701 D c-5 Not for Resale `,,-`-`,,`,,`,`,,` - C-6 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale S T D - A P I / P E T R O P U B L D R - E N G L L99b = 0732290 05b4182 b48 STD.API/PETRO PUBL D R - E N G L b m `,,-`-`,,`,,`,`,,` - 0732270 b L 584 c-7 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale C-8 `,,-`-`,,`,,`,`,,` - Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS STD.API/PETRO PUBL DR53-ENGL L 7Notbfor Resale m 2 05bLiLBLi Lillo m `,,-`-`,,`,,`,`,,` - c-9 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS S T D * A P I / P E T R O PUBL DR53-ENGL 177b = Not for Resale 2 0 b 357 ~ ~ 0732290 05bllLôb 273 `,,-`-`,,`,,`,`,,` - STD.API/PETRO PUBL DR53-ENGL L 7 b c-1o Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale S T D A P I / P E T R O PUBL D R - E N G L 277b `,,-`-`,,`,,`,`,,` - c-11 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale 2 û 05bllLô7 LZT ~ ~ S T D A P I / P E T R O P U B L D R - E N G L L 7 b H 0732290 05bqLBB 0bb `,,-`-`,,`,,`,`,,` - c-12 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale 073227Cl 05bliL87 T T W `,,-`-`,,`,,`,`,,` - STD-API/PETRO P U B L DR53-ENGL L97b C-13 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale `,,-`-`,,`,,`,`,,` - 11961.5Cl P Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale ~~ STD.API/PETRO i’ ~ P U B L D R - E N G L L77b M 0732270 05bLIL71 b H ~ ~ - Petroleum Institute 1220 L Street, Northwest Washington, D.C.20005 202-682-8000 httpiiwww.api.org `,,-`-`,,`,,`,`,,` - American Order No I00053 Copyright American Petroleum Institute Provided by IHS under license with API No reproduction or networking permitted without license from IHS Not for Resale