umes hazardous waste management manual(1)

University of Maryland Eastern Shore Environmental Health and Safety Hazardous And Regulated Waste Management Manual 2009 University of Maryland Eastern Shore, Backbone Road, Princess Anne, MD 21853 (410) 651-6652 Fax (410) 651-7918 TABLE OF CONTENTS EMERGENCY TELEPHONE NUMBERS PART I GENERAL INFORMATION Introduction I-1 Purpose I-1 Regulatory Requirements I-1 Responsibility and Liability .I-3 Requirements for Laboratory Personnel Leaving the University I-4 PART II HAZARDOUS CHEMICAL WASTE MANAGEMENT Purpose I-1 Regulatory Authority I-1 Definitions I-1 Procedure for Hazardous Chemical Waste Disposal II-2 Procedure for Hazardous Chemical Waste Removal II-3 Materials With Special Requirements II-4 Unknown Wastes .II-6 PART III BIOLOGICAL, PATHOLOGICAL, OR MEDICAL WASTE (BPMW) MANAGEMENT, INCLUDING SHARPS AND CONTAMINATED GLASSWARE Purpose III-1 Regulatory Authority III-1 Definitions .III-1 Biological Waste Disposal Procedures III-3 PART IV LOW-LEVEL RADIOACTIVE WASTE MANAGEMENT Purpose IV-1 Regulatory Authority .IV-1 Low-Level Radioactive Waste Disposal Procedure IV-1 PART V EMERGENCY SPILL RESPONSE PROCEDURES Purpose V-1 Regulatory Authority V-1 Procedures and Equipment V-1 PART VI CHEMICAL STORAGE FACILITY Chemical Storage Facility .VI-1 Hazardous and Regulated Waste Management Manual PART VII EPA HAZARDOUS WASTE CODES Criteria and Characteristics of Hazardous Waste VII-1 Maximum Concentration of Contaminants for the Toxicity Characteristic .VII-2 Hazardous Waste from non-specific sources VII-3 Acute Hazardous Waste VII-7 TOXIC (NON-ACUTE) HAZARDOUS WASTE VII-14 HAZARDOUS WASTE REMOVAL REQUEST FORM Appendix A Hazardous and Regulated Waste Management Manual EMERGENCY TELEPHONE NUMBERS CALL IMMEDIATELY FOR ANY EMERGENCY INCLUDING INJURED OR SICK PERSON, CHEMICAL SPILL OR FIRE Emergency (FIRE - POLICE - RESCUE) - 24 hour # UMES Campus Police Department Maryland Poison Control Center 911 3300 1-800-222-1222 Environmental Health and Safety Preston Cottman, Manager Danna Maloney, Assistant Manager (410) 651-6652 (410) 621-3040 Human Resources Lisa Johnson (410) 651-7848 Physical Plant Operations and Maintenance Work Control Office (410) 651-7752 Hazardous and Regulated Waste Management Manual PART I GENERAL INFORMATION INTRODUCTION The U.S Environmental Protection Agency (EPA) has established the definition of what constitutes a hazardous waste This agency also strictly regulates and enforces the storage, handling, and disposal of these materials Under these regulations, generators of hazardous waste are perpetually responsible for any and all damages to human health, personal property, or the environment In many instances, activities (e.g maintenance and operations, teaching and research, and health services) of the university produce hazardous waste, and the University Of Maryland Eastern Shore (UMES) is therefore classified as a generator of hazardous waste PURPOSE The purpose of this manual is provide the University of Maryland Eastern Shore community with information to guide department chairs/directors, faculty, and staff in compliance with federal, State, local and University requirements for managing hazardous and other regulated wastes (controlled waste), and to provide for the effective and efficient safe handling, storage, and disposal of controlled waste generated by UMES This manual provides procedures to assist campus waste generators in the handling and disposal of controlled wastes in accordance with existing regulations REGULATORY REQUIREMENTS The following is a list of the regulatory authorities, and a brief description of their regulations, acts, and programs that may have a direct impact on hazardous waste generators Environmental Protection Agency EPA regulates controlled waste through six major regulatory programs: RCRA, CERCLA, TSCA, FIFRA, CWA, and CAA RCRA (1976) Resource Conservation and Recovery Act Defined and regulated solid and hazardous wastes (Regulations directly impact the hazardous waste generator.) HSWA (1984) Hazardous and Solid Waste Amendments Made RCRA more stringent (Regulations directly impact the hazardous waste generator.) CERCLA (1980) Comprehensive Environmental Response, Compensation and Liability Act (Superfund) Provides mechanisms to assign liability Hazardous and Regulated Waste Management Manual I-1 to corporations and individuals (May impact the hazardous waste generator) SARA (1988) Superfund Amendments and Reauthorization Act Created Community Right-To-Know for hazardous and toxic chemical reporting TSCA (1976) Toxic Substances Control Act Regulates chemical usage, including PCB usage, storage, and disposal FIFRA (1988) Federal Insecticide, Fungicide, and Rodenticide Act Controls the manufacture and use of pesticides intended to kill, repel, or control living organisms CAA (1963) Clean Air Act Regulates discharges to air (Regulations directly impact the hazardous waste generator.) CAAA (1990) Clean Air Act Amendments CWA (1977) Clean Water Act Regulates discharges to water (Regulations directly impact the hazardous waste generator.) Department of Transportation The Department of Transportation (DOT) regulates the transportation of Hazardous Materials and Hazardous Substances HMTA (1991) Hazardous Materials Transportation Act Regulates packaging and transport of hazardous materials Occupational Safety and Health Administration The Occupational Safety and Health Administration (OSHA) develops and enforces safety standards for response to hazardous chemical emergencies, employee awareness and right-to-know chemical information, as well as laboratory safety standards These standards have been adopted and are enforced by Maryland Occupational Safety and Health (MOSH) HAZWOPER (1989) Hazardous Waste Operations and Emergency Response Sets standards for employee safety At UMES, only Emergency Response Teams must train beyond the awareness level HAZCOM (1983) Hazard Communication (Right-To-Know) Employers must inform employees of chemical hazards (Regulations directly impact the hazardous waste generator.) Hazardous and Regulated Waste Management Manual I-2 LSS (1991) Laboratory Safety Standard (Occupational Exposure to Hazardous Chemicals in Laboratories) Laboratories must develop Chemical Hygiene Plans, etc (Regulations directly impact the hazardous waste generator.) Maryland Department of the Environment Under EPA authority, the State of Maryland Department of the Environment (MDE) regulates the management of controlled wastes within the State of Maryland MDE dictates what can be discharged into the atmosphere, water, and land MDE is the prime regulator of the University’s hazardous, radioactive, biological, pathological, and medical wastes RESPONSIBILITY AND LIABILITY A Environmental Health and Safety (EHS) is the University's liaison to the regulatory agencies Its mission, in part, is to assist University departments with compliance in regulations B All University personnel generating or disposing of controlled wastes are responsible for compliance with federal, State, and local laws and regulations, as well as with University policies and procedures Each department, individual, laboratory, research center, maintenance facility, etc., that generates or disposes of materials regulated as controlled waste is considered a generator Each generator is required to comply with applicable regulatory standards and may be liable for civil or criminal penalties for regulatory infractions C Department chairs/directors, faculty, managers, supervisors, and staff have the following responsibilities regarding safe waste management: Become familiar with chemical selection and usage by peers and subordinates; Identify, segregate, collect, and properly store controlled wastes; Develop and implement an active waste minimization program by investigating material substitution, scale reduction, chemical exchange, and purchase control within each department; Encourage personnel to seek waste handling guidance from EHS; Accurately identify and properly label all waste material; Ensure that no chemicals are abandoned in place due to personnel retirement, termination of employment, graduation, etc.; and, Provide staff and student training and information as required by regulation and University policy Hazardous and Regulated Waste Management Manual I-3 REQUIREMENTS FOR LABORATORY PERSONNEL LEAVING THE UNIVERSITY Abandoning regulated wastes without proper disposal or identification is a regulatory violation and also creates both a dangerous storage situation and an expensive disposal problem University policy requires that all hazardous materials (biological, chemical, radiological) are removed from laboratory spaces that are vacated temporarily (e.g for renovation or reconstruction) or permanently These spaces must also be decontaminated and cleaned All researchers planning to leave campus must properly identify all waste material and arrange for their disposal before departing the University The laboratory custodian must provide EHS with a completed “Certification of Vacancy” form before outside personnel can enter the laboratory Hazardous and Regulated Waste Management Manual I-4 PART II HAZARDOUS CHEMICAL WASTE MANAGEMENT PURPOSE EHS maintains a Hazardous Waste Management System for the proper handling, storage, recycling, and disposal of toxic or hazardous materials subject to regulations as hazardous waste This system complies with the RCRA Act of 1976, Hazardous Solid Waste Amendments of 1984, U.S EPA regulations, and regulations established by MDE UMES faculty, staff, and students generate hazardous waste through teaching, research, and support activities EHS operates a chemical storage facility (CSF) that allows for the consolidation of hazardous wastes prior to off-site shipment These procedures are to be used by University personnel in the identification, short-term storage, and removal of hazardous waste REGULATORY AUTHORITY COMAR 26.13.01-.10, Hazardous Waste 40 CFR PARTS 260-273, Hazardous Waste DEFINITIONS A Hazardous Waste - Any solid or liquid waste that is specifically listed by EPA or MDE as a hazardous waste, or meets one or more of the hazardous waste characteristics, or is a regulated mixture of hazardous and non-hazardous waste B Acute Hazardous Waste - Hazardous wastes that are considered exceptionally toxic as listed under 40 CFR Part 261.33 (listed wastes having codes beginning with "P") C Corrosivity - An aqueous waste having a pH less than or equal to 2, or greater than or equal to 12.5; or a liquid that corrodes steel as described under 40 CFR Part 261.22 D Flammability - A liquid (other than an aqueous solution containing less than 24 percent alcohol by volume) with a flashpoint of less than 60oC (140o F) as determined by a Pensky-Martens closed cup tester using ASTM method D-93-70 or D-93-80; or it is not a liquid and is capable under standard temperature and pressure of causing a fire; or it is an ignitable compressed gas; or is an oxidizer E Reactivity - A waste that is normally unstable and readily undergoes violent change without detonating; or reacts violently with water; or forms potentially explosive mixtures with water; or when mixed with water generates toxic gases, vapors, or fumes; or a cyanide or sulfide bearing waste that generates toxic gases, Hazardous and Regulated Waste Management Manual II-1 vapors, or fumes when exposed to pH conditions between and 12.5; or is capable of detonation or explosive reaction F Toxicity - A waste whose extract under the test procedure specified under 40 CFR Part 261.24 contains one or more constituents at concentrations greater than those specified in Table I of the above referenced part G Hazardous Waste Label - A specified label that must be attached to each container of chemical waste The label has the words "Hazardous Waste" displayed and requires the name of the waste components in standard English nomenclature H Satellite Accumulation Area (SAA)- An area where a generator may accumulate up to 55 gallons of non-acutely hazardous waste or one quart of acutely hazardous waste in containers at or near any point of generation where wastes initially accumulate that is under the control of the generator PROCEDURE FOR HAZARDOUS CHEMICAL WASTE DISPOSAL All generators of hazardous waste whether they are a SAA or not, must properly manage containers and segregate waste based on chemical compatibility The following practices must be used at all times: A Management of Waste Steams Waste streams must be separated as follows: a b c d e Organic-, Non-Halogenated-, non-Metal-Waste Organic-, Halogenated-, non-Metal Waste Organic-, Halogenated, Metal Waste Organic-, Non-Halogenated, Metal Waste Metal Salts Waste Do not mix solid and liquid waste Liquids should be strained of all solids Heavy metal solutions must not be mixed with any organic solvent or solution Halogenated and non-halogenated organic solvents should be segregated into separate containers Store incompatible chemical waste away from each other and use secondary containment in case of spillage Hazardous and Regulated Waste Management Manual II-2 U059 Daunomycin U366 Dazomet U060 DDD U061 DDT U062 Diallate U063 Dibenz[a,h]anthracene U064 Dibenzo[a,i]pyrene U066 1,2-Dibromo-3-chloropropane U069 Dibutyl phthalate U070 o-Dichlorobenzene U071 m-Dichlorobenzene U072 p-Dichlorobenzene U073 3,3'-Dichlorobenzidine U074 1,4-Dichloro-2-butene U075 Dichlorodifluoromethane U078 1,1-Dichloroethylene U079 1,2-Dichloroethylene U025 Dichloroethyl ether U027 Dichloroisopropyl ether U024 Dichloromethoxy ethane U081 2,4-Dichlorophenol U082 2,6-Dichlorophenol U084 1,3-Dichloropropene U085 1,2:3,4-Diepoxybutane U108 1,4-Diethyleneoxide U028 Diethylhexyl phthalate U395 Diethylene glycol, dicarbamate U086 N,N'-Diethylhydrazine U087 O,O-Diethyl S-methyl dithiophosphate U088 Diethyl phthalate U089 Diethylstilbesterol U090 Dihydrosafrole U091 3,3'-Dimethoxybenzidine U092 Dimethylamine U093 p-Dimethylaminoazobenzene Hazardous and Regulated Waste Management Manual VII-20 U094 7,12-Dimethylbenz[a]anthracene U095 3,3'-Dimethylbenzidine U096 alpha,alpha-Dimethylbenzylhydroperoxide U097 Dimethylcarbamoyl chloride U098 1,1-Dimethylhydrazine U099 1,2-Dimethylhydrazine U101 2,4-Dimethylphenol U102 Dimethyl phthalate U103 Dimethyl sulfate U105 2,4-Dinitrotoluene U106 2,6-Dinitrotoluene U107 Di-n-octyl phthalate U108 1,4-Dioxane U109 1,2-Diphenylhydrazine U110 Dipropylamine U111 Di-n-propylnitrosamine U403 Disulfiram U390 EPTC U041 Epichlorohydrin U001 Ethanal U404 Ethanamine, N,N-diethyl- U174 Ethanamine, N-ethyl-N-nitroso- U155 1,2-Ethanediamine, N,N-dimethyl-N'-2-pyridinyl-N'-(2-thienylmethyl)- U067 Ethane, 1,2-dibromo- U076 Ethane, 1,1-dichloro- U077 Ethane, 1,2-dichloro- U131 Ethane, hexachloro- U024 Ethane, 1,1'-[methylenebis (oxy)]bis[2-chloro- U117 Ethane, 1,1'-oxybis-(I) U025 Ethane, 1,1'-oxybis[2-chloro- U184 Ethane, pentachloro- U208 Ethane, 1,1,1,2-tetrachloro- U209 Ethane, 1,1,2,2-tetrachloro- U218 Ethanethioamide U226 Ethane, 1,1,1-trichloro- Hazardous and Regulated Waste Management Manual VII-21 U227 Ethane, 1,1,2-trichloro- U410 Ethanimidothioic acid, N,N'-[thiobis[(methylimino)carbonyloxy]] bis-, dimethyl ester U394 Ethanimidothioic acid, 2-(dimethylamino)-N-hydroxy-2-1 oxo-, methyl ester U359 Ethanol, 2-ethoxy- U173 Ethanol, 2,2'-(nitrosoimino)bis- U395 Ethanol, 2,2'-oxybis-, dicarbamate U004 Ethanone, 1-phenyl- U043 Ethene, chloro- U042 Ethene, (2-chloroethoxy)- U078 Ethene, 1,1-dichloro- U079 Ethene, 1,2-dichloro- U210 Ethene, tetrachloro- U228 Ethene, trichloro- U112 Ethyl acetate U113 Ethyl acrylate U238 Ethyl carbamate (urethane) U117 Ethyl ether U114 Ethylenebisdithiocarbamic acid, salts & esters U067 Ethylene dibromide U077 Ethylene dichloride U359 Ethylene glycol monoethyl ether U115 Ethylene oxide U116 Ethylenethiourea U076 Ethylidene dichloride U118 Ethyl methacrylate U119 Ethyl methanesulfonate U407 Ethyl Ziram U396 Ferbam U126 Fluoranthene U122 Formaldehyde U123 Formic acid U124 Furan U125 Furancarboxaldehyde U147 2,5-Furandione Hazardous and Regulated Waste Management Manual VII-22 U213 Furan, tetrahydro- U125 Furfural U124 Furfuran U206 Glucopyranose, 2-deoxy-2-(3-methyl-3-nitrosoureido)-, U206 D-Glucose, 2-deoxy-2-[[(methylnitrosoamino)-4 carbonyl]amino]- U126 Glycidylaldehyde U163 Guanidine, N-methyl-N'-nitro-N-nitroso- U127 Hexachlorobenzene U128 Hexachlorobutadiene U130 Hexachlorocyclopentadiene U131 Hexachloroethane U132 Hexachlorophene U243 Hexachloropropene U133 Hydrazine U086 Hydrazine, 1,2-diethyl- U098 Hydrazine, 1,1-dimethyl- U099 Hydrazine, 1,2-dimethyl- U109 Hydrazine, 1,2-diphenyl- U134 Hydrofluoric acid U134 Hydrogen fluoride U135 Hydrogen sulfide U135 Hydrogen sulfide H2S U096 Hydroperoxide, 1-methyl-1-phenylethyl- U116 2-Imidazolidinethione U137 Indeno[1,2,3-cd]pyrene U375 3-Iodo-2-propynyl n-butylcarbamate U396 Iron, tris(dimethylcarbamodithioato-S,S')-, U190 1,3-Isobenzofurandione U140 Isobutyl alcohol U141 Isosafrole U142 Kepone U143 Lasiocarpine U144 Lead acetate U146 Lead, bis(acetato-O)tetrahydroxytri- U145 Lead phosphate Hazardous and Regulated Waste Management Manual VII-23 U146 Lead subacetate U129 Lindane U163 MNNG U147 Maleic anhydride U148 Maleic hydrazide U149 Malononitrile U150 Melphalan U151 Mercury U384 Metam Sodium U152 Methacrylonitril U092 Methanamine, N-methyl- U029 Methane, bromo- U045 Methane, chloro- U046 Methane, chloromethoxy- U068 Methane, dibromo- U080 Methane, dichloro- U075 Methane, dichlorodifluoro- U138 Methane, iodo- U119 Methanesulfonic acid, ethyl ester U211 Methane, tetrachloro- U153 Methanethiol U225 Methane, tribromo- U044 Methane, trichloro- U121 Methane, trichlorofluoro- U036 4,7-Methano-1H-indene, 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7ahexahydro- U154 Methanol U155 Methapyrilene U142 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one,1,1a,3,3a,4,5,5,5a, 5b,6decachlorooctah ydro- U247 Methoxychlor U154 Methyl alcohol U029 Methyl bromide U186 1-Methylbutadiene U045 Methyl chloride Hazardous and Regulated Waste Management Manual VII-24 U156 Methyl chlorocarbonate U226 Methyl chloroform U157 3-Methylcholanthrene U158 4,4'-Methylenebis(2-chloroaniline) U068 Methylene bromide U080 Methylene chloride U159 Methyl ethyl ketone (MEK) U160 Methyl ethyl ketone peroxide U138 Methyl iodide U161 Methyl isobutyl ketone U162 Methyl methacrylate U161 4-Methyl-2-pentanone U164 Methylthiouracil U010 Mitomycin C U365 Molinate U059 5,12-Naphthacenedione, 8-acetyl-10-[(3-amino-2,3,6-3 trideoxy)-alpha-Llyxo-hexopyranosyl)oxy]-7,8,9,10-tetrahydro-6,8,11-trihydroxy-1-methoxy-, (8S-cis)- U167 1-Naphthalenamine U168 2-Naphthalenamine U026 Naphthalenamine, N,N'-bis(2-chloroethyl)- U165 Naphthalene U047 Naphthalene, 2-chloro- U166 1,4-Naphthalenedione U236 2,7-Naphthalenedisulfonic acid, 3,3'-[(3,3'-dimethyl[1,1'-biphenyl]-4,4'diyl)bis(azo)bis [5-amino-4-hydroxy]-, tetrasodium salt U279 1-Naphthalenol, methylcarbamate U166 1,4-Naphthoquinone U167 alpha-Naphthylamine U168 beta-Naphthylamine U217 Nitric acid, thallium(1+) salt U169 Nitrobenzene U170 p-Nitrophenol U171 2-Nitropropane U172 N-Nitrosodi-n-butylamine Hazardous and Regulated Waste Management Manual VII-25 U173 N-Nitrosodiethanolamine U174 N-Nitrosodiethylamine U176 N-Nitroso-N-ethylurea U177 N-Nitroso-N-methylurea U178 N-Nitroso-N-methylurethane U179 N-Nitrosopiperidine U180 N-Nitrosopyrrolidine U181 Nitro-o-toluidine U193 1,2-Oxathiolane, 2,2-dioxide U058 2H-1,3,2-Oxazaphosphorin-2-amine, N,N-bis(2-chloroethyl) tetrahydro-, 2oxide U115 Oxirane U126 Oxiranecarboxyaldehyde U041 Oxirane, (chloromethyl)- U182 Paraldehyde U391 Pebulate U183 Pentachlorobenzene U184 Pentachloroethane U185 Pentachloronitrobenzene (PCNB) See F027 Pentachlorophenol U161 Pentanol, 4-methyl- U186 1,3-Pentadiene U187 Phenacetin U188 Phenol U048 Phenol, 2-chloro- U039 Phenol, 4-chloro-3-methyl- U081 Phenol, 2,4-dichloro- U082 Phenol, 2,6-dichloro- U089 Phenol, 4,4'-(1,2-diethyl-1,2-ethenediyl)bis- U101 Phenol, 2,4-dimethyl- U052 Phenol, methyl- U132 Phenol, 2,2'-methylenebis[3,4,6-trichloro- U411 Phenol, 2-(1-methylethoxy)-, methylcarbamate U170 Phenol, 4-nitro See F027 Phenol, pentachloro Hazardous and Regulated Waste Management Manual VII-26 See F027 Phenol, 2,3,4,6-tetrachloro See F027 Phenol, 2,4,5-trichloro See F027 Phenol, 2,4,6-trichloro U150 L-Phenylalanine, 4-[bis(2-chloroethyl)amino]- U145 Phosphoric acid, lead(2+) salt (2:3) U087 Phosphorodithioic acid, O,O-diethyl S-methyl ester U189 Phosphorus sulfide U190 Phthalic anhydride U191 2-Picoline U179 Piperidine, 1-nitroso- U400 Piperidine, 1,1'-(tetrathiodicarbonothioyl)-bis- U383 Potassium dimethyldithiocarbamate U378 Potassium n-hydroxymethyl- n-methyldi-thiocarbamate U377 Potassium n-methyldithiocarbamate U192 Pronamide U194 1-Propanamine U111 1-Propanamine, N-nitroso-N-propyl- U110 1-Propanamine, N-propyl- U066 Propane, 1,2-dibromo-3-chloro- U083 Propane, 1,2-dichloro- U149 Propanedinitrile U171 Propane, 2-nitro- U027 Propane, 2,2'-oxybis[2-chloro- U193 1,3-Propane sultone See F027 Propanoic acid, 2-(2,4,5-trichlorophenoxy)- U235 1-Propanol, 2,3-dibromo-, phosphate (3:1) U140 1-Propanol, 2-methyl- U002 2-Propanone U007 2-Propenamide U084 1-Propene, 1,3-dichloro- U243 1-Propene, 1,1,2,3,3,3-hexachloro- U009 2-Propenenitrile U152 2-Propenenitrile, 2-methyl- U008 2-Propenoic acid U113 2-Propenoic acid, ethyl ester Hazardous and Regulated Waste Management Manual VII-27 U118 2-Propenoic acid, 2-methyl-, ethyl ester U162 2-Propenoic acid, 2-methyl-, methyl ester U373 Propham U411 Propoxur U387 Prosulfocarb U194 n-Propylamine U083 Propylene dichloride U148 3,6-Pyridazinedione, 1,2-dihydro- U196 Pyridine U191 Pyridine, 2-methyl- U237 2,4-(1H,3H)-Pyrimidinedione, 5-[bis(2-chloroethyl)amino]- U164 4(1H)-Pyrimidinone, 2,3-dihydro-6-methyl-2-thioxo- U180 Pyrrolidine, 1-nitroso- U200 Reserpine U201 Resorcinol U202 Saccharin, & salts U203 Safrole U204 Selenious acid U204 Selenium dioxide U205 Selenium sulfide U205 Selenium sulfide SeS2 U376 Selenium, tetrakis(dimethyldithiocarbamate) U015 L-Serine, diazoacetate (ester) See F027 Silvex (2,4,5-TP) U379 Sodium dibutyldithiocarbamate U381 Sodium diethyldithiocarbamate U382 Sodium dimethyldithiocarbamate U206 Streptozotocin U103 Sulfuric acid, dimethyl ester U277 Sulfallate U189 Sulfur phosphide See F027 2,4,5-T U402 Tetrabutylthiuram disulfide U207 1,2,4,5-Tetrachlorobenzene U208 1,1,1,2-Tetrachloroethane Hazardous and Regulated Waste Management Manual VII-28 U209 1,1,2,2-Tetrachloroethane U210 Tetrachloroethylene See F027 2,3,4,6-Tetrachlorophenol U213 Tetrahydrofuran U401 Tetramethylthiuram monosulfide U214 Thallium(I) acetate U215 Thallium(I) carbonate U216 Thallium(I) chloride U216 Thallium chloride Tlcl U217 Thallium(I) nitrate U366 2H-1,3,5-Thiadiazine- 2-thione, tetrahydro-3,5- dimethyl- U218 Thioacetamide U410 Thiodicarb U153 Thiomethanol U244 Thioperoxydicarbonic diamide [(H2N)C(S)]2S2, tetramethyl- U402 Thioperoxydicarbonic diamide, tetrabutyl U403 Thioperoxydicarbonic diamide, tetraethyl U409 Thiophanate-methyl U219 Thiourea U244 Thiram U220 Toluene U221 Toluenediamine U223 Toluene diisocyanate U328 o-Toluidine U353 p-Toluidine U222 o-Toluidine hydrochloride U389 Triallate U011 1H-1,2,4-Triazol-3-amine U227 1,1,2-Trichloroethane U228 Trichloroethylene U121 Trichloromonofluoromethane See F027 2,4,5-Trichlorophenol See F027 2,4,5-Trichlorophenol U404 Triethylamine U234 1,3,5-Trinitrobenzene Hazardous and Regulated Waste Management Manual VII-29 U182 1,3,5-Trioxane, 2,4,6-trimethyl- U235 Tris(2,3-dibromopropyl) phosphate U236 Trypan blue U237 Uracil mustard U176 Urea, N-ethyl-N-nitroso- U177 Urea, N-methyl-N-nitroso- U385 Vernolate U043 Vinyl chloride U248 Warfarin, & salts, when present at concentrations of 0.3% or less U239 Xylene U200 Yohimban-16-carboxylic acid, 11,17-dimethoxy-18-[(3,4,5trimethoxybenzoyl)oxy]-, methyl ester, (3beta,16beta,17alpha,18beta,20alpha)- U407 Zinc, bis(diethylcarbamodithioato-S,S')- U249 Zinc phosphide Zn3P2, when present at concentrations of 10% or less Hazardous and Regulated Waste Management Manual VII-30 APPENDIX A HAZARDOUS WASTE REMOVAL REQUEST FORM Hazardous and Regulated Waste Management Manual UNIVERSITY OF MARYLAND EASTERN SHORE HAZARDOUS WASTE REMOVAL REQUEST FORM Container No                                                                                                                                                                   Researcher/PI:       Department:       Building/Rm #:       Telephone:       Contact Person/Title:       Waste Charge #:       CONTAINER SIZE / TYPE WASTE DESCRIPTION                                                                                                                                                                                                                                                                                                                                     WASTE VOLUME / WEIGHT (KG)                                                                                                                                                                   COMPONENT PERCENTAGE                                                                                                                                                                                                                                                                                                                                     Principal Investigator Signature: EHS USE ONLY: Date of waste removal:       Waste removed by: EHS USE ONLY EPA NO       UNIVERSITY OF MARYLAND EASTERN SHORE HAZARDOUS WASTE REMOVAL REQUEST FORM INSTRUCTIONS Complete the form in its entirety and submit the form to EHS to request the removal of identified hazardous chemical, biological (pathological and infectious), or radioactive wastes A separate form is required for each waste category (i.e chemical, radioactive, infectious or other medical wastes) Submit requests via fax to Ext 7918 or by mailing this form through campus mail Please adhere to the following detailed instructions in filling out the form: Hazardous Chemical Waste: The information is required by Federal (EPA) and State (Maryland Department of the Environment (MDE)) regulations in order to provide an operating record showing complete and accurate waste identification and a record of waste origin and destination The waste description must include the chemical name (s) Chemical mixtures must be identified by listing the solute, each chemical component, and the respective percentages The total waste volume / weight (mL, L, g, or kg) represents the actual volume / weight of the waste in the container Fractions should be rounded The container type is “B” for bottle, “C” for can, and “O” for other container Example Container No Waste Description Phenol Methylene chloride Chemical Mixture: Sodium hydroxide Methylene chloride Water Container Size / Type Waste Volume / Weight (kg) Component Percentage 500 mL, B L, B 100% 100% 150 mL, B 15% 29% 56% EHS USE ONLY EPA NO Biological, Pathological, and Medical Waste (BPMW): BMPW consists of the following types of materials: Vaccines, cultures, blood products, body fluids, infectious agents, bloodborne pathogens and materials so contaminated, pathological waste and pathology specimens, sharps (including hypodermic syringes, needles, scalpel blades, razor blades, blood vials, vacutainer tubes with needles attached or containing blood), suture needles, needles with attached tubing, culture dishes from medical facilities or contaminated with HBV/HIV, animal wastes (consisting only of contaminated animal carcasses, body parts, and bedding of animals known to have been exposed to infectious agents), and isolation wastes (materials contaminated with blood, excretions, exudates, or secretion of humans or animals who are isolated to protect others from disease, or isolated animals infected with communicable disease agents If BPMW is contaminated with a hazardous chemical or a radioactive isotope, include the relevant information on the chemical or the isotope in the waste description Low-Level Radioactive Waste (LLRW): This information is required by Federal (NRC) and State (Maryland Radiation Management Administration) regulations in order to provide an operating record showing complete and accurate waste identification and a record of waste origin and destination The waste description must include the isotope(s) present in the container, and the activity for each isotope in microcuries or millicuries The waste type must also be identified as Dry Solid (paper, plastic, glass, UNIVERSITY OF MARYLAND EASTERN SHORE HAZARDOUS WASTE REMOVAL REQUEST FORM etc.), Aqueous (water based only, does not contain hazardous chemicals), Mixed (liquid based, contains hazardous chemicals), Animal Parts, Source, Sharps, Vials, or Medical Waste If LLRW contains hazardous chemical, indicate the complete chemical composition of the waste ... following EPA Hazardous Wastes and no other Hazardous Wastes retains its EPA Hazardous Waste Number(s): F020, F021, F022, F026, F027, and/or F028.) Acute Hazardous Waste EPA Hazardous Substance Waste. .. 26.13.01-.10, Hazardous Waste 40 CFR PARTS 260-273, Hazardous Waste DEFINITIONS A Hazardous Waste - Any solid or liquid waste that is specifically listed by EPA or MDE as a hazardous waste, or meets... waste, or meets one or more of the hazardous waste characteristics, or is a regulated mixture of hazardous and non -hazardous waste B Acute Hazardous Waste - Hazardous wastes that are considered exceptionally