... disaccharides in ILs containing [Cl]- [40] However, ILs containing [Cl]- cannot be used to carry out enzyme reactions due to the inactivation of most enzymes [41] Only ILs containing the dicyanamide ... enhancing lipase activity in the synthesis of sugar ester using ionicliquids was investigated In the lipase-catalyzed esterifications of glucose with vinyl laurate or lauric acid in [Bmim][TfO], 2.4 ... chain in the cation and/or shape or symmetry [ 18, 19] Some typical cation/anion combinations comprising the main families of ILs are illustrated in Figure Figure Some typical cation/anion combinations...
... ranging from to 60 The fructosyl units are linked by (21) IonicLiquidsin Catalytic Biomass Transformation 19 linkages with the glucose as the terminating unit of the polymer chain [ 38] Inulins ... (Vidinha, Lourenco, Nunes, Duarte, and Barreiros) Similarly, ionicliquids are finding increasing use in the popular area of nanomaterials Much of this effort is directed toward using ionicliquids ... of 5-HMF using inulin inionicliquids under mild conditions Combining [BMIM][Cl] and a strong acidic cation exchange resin gave a 5-HMF yield of 55% in 20 Subsequently, a two-step in one pot...
... with running buffer and the sample is introduced by dipping one end into the sample and applying an electric field (electrokinetic injection) or by applying gas pressure (hydrodynamic injection) ... synthesized in 1951 [1], an alkylpyridinium based salt (N-ethylpyridinium bromidealuminium chloride) However, it was not until the discovery of the 1,3dialkylimidazolium based ionicliquidsin 1 982 that ... solved by coupling CE with MS The main difficulty of coupling CE with MS lies in the fact that the MS system operating under high vacuum and interfacing to CE can reduce hydrodynamic flow in the capillary...
... close Windows Explorer Module 8: Implementing Security in a Windows 2000 Network 39 ?? set up auditing of a printer To Click the Start button, point to Settings , and then click Printers In the ... security in a Windows 2000 network 2 Module 8: Implementing Security in a Windows 2000 Network Introduction to Securing a Windows 2000 Network Slide Objective ? To identify the purpose of securing ... returning it to the user, such as an e-mail attachment using a secure messaging system Module 8: Implementing Security in a Windows 2000 Network 25 Lab A: Implementing Security in a Windows...
... up to a yield of 98 % in M chloride solutions (Scheme 8. 2) [13] With olefins other than ethene two isomeric chlorohydrins can be obtained, one of them being chiral When pyridine was replaced by ... by monodentate chiral amines in the enantioselectivities were low (8- 12%) (Scheme 8. 3) [14] The mononuclear complexes performed better providing the chiral chlorohydrin in 46-76% e.e Even better ... atmospheric air or 1-3 bar In an ethanol/water mixture 88 % yield of 2-hexanone and 92 % yield of 2-hexadecanone was obtained in and h, respectively, with a Catalytic oxidations in aqueous media - recent...
... protecting allyl groups under exceedingly mild conditions In an interesting reaction, reshuffling of functional groups can be achieved in the rearrangement of homoallylic alcohols (Scheme 9.2) [8, 9] ... Korzinski, 209th Meeting of the Am Chem Soc., Anaheim, CA, 1995, INOR 2 68 59 H Borwieck, O Walter, E Dinjus, J Rebizant, J Organometal Chem 19 98, 570, 121 60 M Poliakoff, Chemistry in Britain, ... 1992, 75, 161 27 M Tokunaga, Y Wakatsuki, Angew Chem Int Ed 19 98, 37, 286 7 28 G Villain, P Kalck, A Gaset, Tetrahedron Lett 1 980 , 21, 2901 29 C S Chin, S Y Kim, K.-S Joo, G Won, D Chong, Bull Korean...
... up-to-date link status 691 Routing Group Master Routing Group Master Lead -in Knowing when a link is DOWN and addressing that status is critical to maintaining an effective routing system Routing Routing ... Native Mode Routing Group Routing Group Routing Group Routing Group Administrative Group Routing Group Routing Group Routing Group Routing Group Routing Group Routing Group Administrative Group ... Define message routing and routing groups, create routing groups, explain how message transfer works between servers running Exchange 2000 installed in the same routing group and installed in...
... chí minh TRà V INH u Bn ph LONG AN DồN G THáP AN GIANG SóC TRăNG BạC LIêU Cà MaU " ụ Thủ đô Thành phố Trung tâm DITAGIS thực GIS i cng vi phn mm Arcview Yu t xut bn TRUNG TM CễNG NGH THễNG TIN ... CễNG NGH THễNG TIN A Lí - DITAGIS To cỏc thnh phn bn Cỏc cụng c to: Bn Chỳ gii T l Mi tờn ch hng Biu Bng thuc tớnh Hỡnh nh GIS i cng vi phn mm Arcview TRUNG TM CễNG NGH THễNG TIN A Lí - DITAGIS ... vi phn mm Arcview TRUNG TM CễNG NGH THễNG TIN A Lí - DITAGIS Xut d liu Xut bng d liu thuc tớnh GIS i cng vi phn mm Arcview TRUNG TM CễNG NGH THễNG TIN A Lí - DITAGIS Xut d liu (tt) Xut d liu...
... Interface Science 110 (2004) 19 48 Table The summary of the pHPZC of aluminas and hydrated aluminas Material pHPZC Experimental method Refs a-Al2O3 8. 4 9.2 9.1 9.2 8. 68. 8 9.4 9.1 6.7 7.9 8. 5 8. 0 ... importance of alumina in the natural aquatic environment and its growing application in drinking and wastewater purification, the knowledge of aluminas structure and possible interactions in water are ... outer-sphere complexation reactions for Mmq and Lly ions can be given by the reactions w37 ,88 ,89 x: B Kasprzyk-Hordern / Advances in Colloid and Interface Science 110 (2004) 19 48 28 AlOH q Mmq~AlOyyMmqqHq...
... · 10 in NaCl/Tris, mounted in glycerol containing 25% NaCl/Tris and 0.1% p-phenylenediamine and examined using a laser scanning microscope (TCS NT) equipped with a Leica (DMIRBE, Inc.) inverted ... penaeidin localization at the site of injection Injection of microorganisms resulted in a dramatic decrease in numbers of both circulating and tissue in ltrating haemocytes within h of injection ... H) Regarding phagocytosis reactions, internalized bacteria were observed after 20 incubation mainly into hyaline haemocytes (Fig 10I) Intracellular phagocytosed bacteria observed in hyaline cells...
... used in some ionicliquids 3.4.1 Chloroaluminate Systems In case of chloroaluminate ionic liquids, the potential of an aluminum electrode immersed in the acidic ionicliquids that contain AlCl3 ... electrodes in nonchloroaluminate ionicliquids especially for the N(CF3SO2 )− ionicliquids Platinum wire is used for the electrode and immersed in an ionic liquid that contains iodine and an ... LIQUIDS Hiroyuki Ohno 1.1 IONICLIQUIDSIonicliquids are salts with a very low melting temperature Ionicliquids have been of great interest recently because of their unusual properties as liquids...
... explain the dynamical properties on ILs based on MD simulation results taking into consideration mainly following points: how can cross-correlated ionic motions in ILs be modified by interionic ... effects of [XF6]- inionicliquids Theoretical study J Phys Chem B, 113, 984 0- 985 1 [15] Refer to the sec.4 in ref.1 and references therein The Dynamical Properties on Ionic Liquids: Insights from ... scattering in molecular fluids J Chem Phys., 72, 280 1- 281 8 [37] Geiger, L C., & Ladanyi, B M (1 987 ) Higher order interaction-induced effects on Rayleigh light scattering by molecular liquids...
... Shishkina 18 ω = W0/Wing – Wing/W0 = fk7[InH]/(Wik6)0.5 = king[InH]/(Wik6)0.5, where W0 is the oxidation rate of methyl oleate without additivies InH, Wi – the initiation rate Since Wing is determined ... described in Ref 15 The interval from the beginning of the experience to the point of intersection of two straight lines for which tg α1 = tg α2 was taken as τ in the presence of InH The first line ... saturated fatty-acid chains of phospholipids [ 38, 39] It is known that a lot of proteins participating in signal transduction in the cell are capable of being localized in rafts including PKC as well...
... Concerning the Commercial Use of IonicLiquids 681 How Pure are Ionic Liquids? 681 Is the Color of IonicLiquids a Problem? 682 How Stable are Ionic Liquids? 682 Are IonicLiquids Toxic? 683 Are Ionic ... 8. 1 8. 2 8. 3 8. 3.1 8. 3.2 8. 4 8. 5 8. 6 9.1 9.2 9.3 9.3.1 The Scanning Tunneling Microscope 587 Results 589 Summary 604 IonicLiquidsin Material Synthesis: Functional Nanoparticles and Other Inorganic ... Enzymes inIonicLiquids 655 Special Techniques for Biocatalysis with IonicLiquids 657 Conclusions and Outlook 6 58 Industrial Applications of IonicLiquids 663 Matthias Maase IonicLiquidsin Industrial...