Synthesis spectroscopic analysis and electrochemical performance of modified b nickel hydroxide electrode with cuo

6 8 0
Synthesis  spectroscopic analysis and electrochemical performance of modified b nickel hydroxide electrode with cuo

Đang tải... (xem toàn văn)

Thông tin tài liệu

Journal of Science: Advanced Materials and Devices (2017) 93e98 Contents lists available at ScienceDirect Journal of Science: Advanced Materials and Devices journal homepage: www.elsevier.com/locate/jsamd Original Article Synthesis, spectroscopic analysis and electrochemical performance of modified b-nickel hydroxide electrode with CuO B Shruthi a, B.J Madhu b, *, V Bheema Raju c, S Vynatheya d, B.Veena Devi a, G.V Jayashree a, C.R Ravikumar e a Department of Chemistry, Dr Ambedkar Institute of Technology, Bangalore, 560 056, India Post Graduate Department of Physics, Government Science College, Chitradurga, 577 501, India Department of Chemistry, R.N.S Institute of Technology, Bangalore, 560 098, India d Materials Technology Division, Central Power Research Institute, Bangalore, 560 080, India e Department of Chemistry, East West Institute of Technology, Bangalore, 560 091, India b c a r t i c l e i n f o a b s t r a c t Article history: Received 16 July 2016 Received in revised form 15 December 2016 Accepted 18 December 2016 Available online 23 December 2016 In the present work, a modified b-nickel hydroxide (b-Ni(OH)2) electrode material with CuO has been prepared using a co-precipitation method The structure and property of the modified b-Ni(OH)2 with CuO were characterized by X-ray diffraction (XRD), Fourier Transform infra-red (FT-IR), Raman and thermal gravimetric-differential thermal analysis (TG-DTA) techniques The results of the FT-IR spectroscopy and TG-DTA indicate that the modified b-Ni(OH)2 electrode materials contain intercalated water molecules and anions A pastedetype electrode was prepared using nickel hydroxide powder as the main active material on a nickel sheet as a current collector Cyclic voltammetry (CV) and Electrochemical impedance spectroscopy (EIS) studies were undertaken to assess the electrochemical behavior of pure bNi(OH)2 and modified b-Ni(OH)2 electrode with CuO in a M KOH electrolyte The addition of CuO into bnickel hydroxide was found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current The modified nickel hydroxide with CuO was also found to exhibit a higher proton diffusion coefficient and a lower charge transfer resistance These findings suggest that the modified b-Ni(OH)2 with CuO possesses an enhanced electrochemical response and thus can be recognized as a promising candidate for battery electrode applications © 2016 The Authors Publishing services by Elsevier B.V on behalf of Vietnam National University, Hanoi This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/) Keywords: Nickel hydroxide Spectroscopic analysis Thermal analysis Electrochemical properties Impedance spectroscopy Introduction In the recent decades, much interest has concentrated on the development of novel electrode materials for advanced energy conversion and storage devices [1e4] Due to growing demand for telecommunication devices, substantial attention is concentrated on improvement of alkaline battery devices with greater specific energies Among them, batteries based on Nickel/Metal hydride (Ni-MH) materials are treated as one of the favorable candidates due to their superiority in terms of output power, capacity, reliability, life and cost Nickel hydroxide is extensively used in rechargeable nickel-based batteries as a positive electrode material due to its remarkable chemical and thermal stability [5] The * Corresponding author E-mail address: bjmadhu@gmail.com (B.J Madhu) Peer review under responsibility of Vietnam National University, Hanoi positive nickel electrode strongly influences the performance of the alkaline batteries In these batteries, the capacity of the negative electrode is greater than that of the positive electrode and hence the cell capacity is limited by the positive electrode For Nickel/ metal hydride (NieMH) cells, the performance of the nickel electrode is to be sufficiently improved to match the superior properties of the metal hydride negative electrode Thus, the preparation of a high performance nickel electrode becomes significant and essential These objectives could be attained by selecting the proper conditions for the synthesis of high performance active material by using suitable additives that could provide the conductive network to enhance the utilization of the nickel hydroxide The reversibility of the Ni(II)/Ni(III) electrochemical reaction could be increased by the incorporation of additives Further, it could inhibit aging effects involving unstable nickel hydroxide species and increase the polarization of the oxygen evolution reaction [6e8] http://dx.doi.org/10.1016/j.jsamd.2016.12.002 2468-2179/© 2016 The Authors Publishing services by Elsevier B.V on behalf of Vietnam National University, Hanoi This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/) 94 B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 It is well known that the nickel hydroxide (Ni(OH)2) exists in two polymorphic forms, namely a-Ni(OH)2 and b-Ni(OH)2, which are transformed into g-NiOOH and b-NiOOH, respectively during charging [5,9] The b-phase exhibits superior stability compared to the a-Ni(OH)2 Many studies have revealed that incorporation of compounds containing transition metal atom, such as cobalt compounds, into the nickel electrode is an effective approach to improve active material utilization and cycle life [10,11] The cobalt compound reduces both the oxidizing and reducing potentials of the nickel electrode and increases the oxygen evolution potential, thus the utilization of the active material is improved [12] In addition, adding cadmium, zinc, manganese, barium, magnesium, calcium and copper compounds into the nickel electrode are reported to have beneficial effects such as inhibiting the swelling of the nickel electrode during charging and thus prolong the cycleelife of rechargeable batteries [13,14] In the present study, the influence of Cupric oxide (CuO) on the structure and electrochemical performance of the nickel hydroxide electrodes is investigated and the results are reported Experimental 2.1 Preparation of cupric oxide Cupric oxide (CuO) was prepared by solution combustion method using stoichiometric composition of Copper nitrate as oxidizer and urea as a fuel The aqueous solution containing redox mixture was taken in a pyrex dish and heated in a muffle furnace maintained at 500 ± 10  C The mixture finally yields porous powder 2.2 Synthesis of modified b-nickel hydroxide electrodes with CuO Modified b-nickel hydroxide electrode material with 3% CuO was synthesized using co-precipitation method The chemical synthesis of b-nickel hydroxide in the presence of CuO additive was achieved in three steps viz (i) addition of the reagents, (ii) digestion of the precipitate and (iii) drying and grinding of the precipitate Analar grade potassium hydroxide (KOH) and nickel sulphate (NiSO4) were used as reagents A solution of M KOH was added to M NiSO4 solution by dripping at a flow rate of 10 ml minÀ1 with constant stirring The addition of the reagent was terminated when the pH of the suspension reaches 13 Additive added was 3% CuO The mixture was left for 24 h for digestion of the precipitate The separation of the precipitate from the excess reagent was done by centrifugation at 1500 rpm for h The precipitate was washed carefully with triple distilled water Barium chloride (BaCl2 (1 M)) in excess was added to wash water, causing precipitation of barium sulphate (BaSO4) Washing of the precipitate was concluded when the white precipitate of BaSO4 was no more found in the wash water The sample was then dried in an air oven at about 60  C for 48 h modified nickel hydroxide electrode with CuO material was carried out by Perkin Elmer STA 6000 thermal analyzer 2.4 Fabrication of electrodes and electrochemical testing Following two compositions of the electrode materials were achieved viz (i) pure b-Ni(OH)2 electrode with no additives having the composition: 85% b-Ni(OH)2 powder ỵ 10% graphite powder ỵ 5% polytetrauoroethylene (PTFE) as binder and (ii) Modified b-Ni(OH)2 electrode having the composition: 85% of modified b-Ni(OH)2 with 3% CuO ỵ 10% graphite powder ỵ 5% PTFE as binder Electrodes were fabricated by mixing electrode material with graphite and PTFE solution to form slurry Obtained slurry was pasted onto a Ni sheet Electrode was dried at around 80  C temperature for h Electrode dimension was kept cm  cm covering the rest with insulating teflon tape Cyclic voltammetry experiments were undertaken using CHI604D electrochemical workstation For cyclic voltammetric studies, the test electrode prepared as described above was used as a working electrode A platinum foil as counter electrode, Hg/HgO electrode as reference electrode and M KOH solution as electrolyte were used Prior to cyclic voltammetry measurements, the electrodes were activated in M KOH solution After resting for 30 min, CV measurements were recorded All CV studies were undertaken at room temperature EIS measurements were undertaken using a CHI604D electrochemical workstation The test electrode prepared as described above was used as a working electrode A platinum foil as counter electrode, Hg/HgO electrode as reference electrode and M KOH solution as electrolyte were used Impedance spectra were recorded at room temperature The impedance spectra were recorded at the biasing voltage of 0.1 V and amplitude of 0.025 V Results and discussion Structure of modified b-nickel hydroxide with CuO was examined using XRD analysis, with a CuKa source Fig displays XRD pattern of representative modified b-nickel hydroxide with CuO Diffraction peaks can be indexed completely to a crystal phase of bNi(OH)2, with lattice parameters, a ¼ 3.130 Å and c ¼ 4.630 Å, which are well-matched with the standard values in literature [8] In addition, the XRD pattern revealed the occurrence of monoclinic system of copper oxide with end centered lattice (JCPDS 041-0254) 2.3 Characterization of modified b-nickel hydroxide electrodes with CuO Crystal structure of the modified nickel hydroxide with CuO was studied by XRD analysis using Bruker AXS D8 Advance diffractometer with a Cu Ka source (l ¼ 1.54 Å) The FTIR (Infra-red) spectrum (400-4000 cmÀ1) of the modified nickel hydroxide with CuO was recorded on a Bruker Alpha spectrophotometer in KBr pellets Raman spectroscopic studies of the synthesized samples were carried out using BRUKER RFS 27 FT-Raman spectrometer Thermal gravimetric-differential thermal analysis (TG-DTA) of the Fig XRD pattern of modified b-Ni(OH)2 with CuO 95 3584 3662 993 1098 280 300 330 444 486 604 622 and cubic system of nickel oxide with face centered lattice (JCPDS 047-1049) within the electrode material Weight fractions of different phases present in the sample was estimated from the XRD spectra The 16.18 wt.% of b-Ni(OH)2, 72.80 wt.% of CuO and 11.02 wt.% of NiO are present within the sample Modified b-nickel hydroxide with CuO was studied by FT-IR spectroscopic technique in the range of 400e4000 cmÀ1 Fig shows the FT-IR spectrum of representative modified b-nickel hydroxide with CuO The infra-red spectrum confirms that synthesized nickel hydroxide can be regarded as b-form, due to presence of (i) strong and a narrow band around 3655 cmÀ1 relating to y(OH) stretching vibration, which reveals the presence of hydroxyl groups in free alignment, (ii) band around 512 cmÀ1 is related to lattice vibration of d(OH) and (iii) a weak band at 484 cmÀ1 appearing from lattice vibration of Nie-O, y(Nie-O) [15,16] Broad and strong band placed around 3430 cmÀ1 is allocated to Oe-H stretching vibration of the H2O molecules and of H-bound OH group Furthermore, peak noticed around 1637 cmÀ1 is ascribed to bending vibration of H2O molecules [17] The peaks situated between 800 and 1800 cmÀ1 could be attributed to existence of anions, which have not possibly been entirely removed during washing The bands at 1046 cmÀ1 and 1388 cmÀ1 are related to stretching vibrations of carbonate anion [8] The bands at 1041 cmÀ1 and 1137 cmÀ1 are related to vibrations of SO2À anion [18] Detected peak around 1469 cmÀ1 is ascribed to different vibrational modes of carbonate groups appeared due to adsorption of atmospheric carbon dioxide [19] Two weak bands observed in the IR spectra at high frequencies (2853 and 2924 cmÀ1), can be allocated to stretching mode of (e-CH2) and (e-CH3) groups of residual organic surfactant, while their bending modes (d(e-CH2), d(CH3)) appear in the range 1700e1400 cmÀ1 [20,21] Observed bands around 425, 529, and 603 cmÀ1 corresponds to typical stretching vibrations of Cue-O bond in monoclinic CuO [22] Further, absence of absorption peak around 610 cmÀ1 related to infrared active mode of Cu2O confirms the presence of pure CuO within the sample [23] Modified b-nickel hydroxide with CuO was studied by Raman spectroscopy Fig shows Raman spectrum of representative modified b-nickel hydroxide with CuO Well-crystallized b-nickel hydroxide is associated with three Raman peaks around 3584 cmÀ1, 444 cmÀ1, and 300 cmÀ1, which are attributed to symmetric Raman Intensity (a.u.) B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 500 1000 1500 2000 2500 3000 3500 4000 -1 Wave number (cm ) Fig Raman spectrum of modified b-Ni(OH)2 with CuO stretching of OHÀ groups, stretching of NieeO, and E-type vibration of NieeOH lattice, respectively [24,25] As compared to wellordered b-nickel hydroxide, synthesized Ni(OH)2 shows additional Raman peaks (3662 cmÀ1, 3584 cmÀ1, 1098 cmÀ1, 993 cmÀ1, 622 cmÀ1 and 486 cmÀ1) as shown in Fig The wave number (486 cmÀ1) corresponding to stretching vibration of NieeO for the prepared Ni(OH)2 is greater than that for well-ordered b-nickel hydroxide Analogous results have also been noticed for the extremely disordered Ni(OH)2 [26,27] The bands observed at 622 cmÀ1, 993 cmÀ1, and 1098 cmÀ1 suggest the existence of adsorbed sulfate ions [26,28] Band noticed around 3584 cmÀ1 is allocated to the symmetric stretch of bulk OHÀ group [26,28] As compared to wellcrystallized b-nickel hydroxide, additional wide band around 3662 cmÀ1 reveals microstructural disorders of Ni(OH)2, which can be ascribed to stretching of surface OHÀ group [26,27] Raman peak round 280 cmÀ1 is assigned to Raman active optical-phonon Ag mode of monoclinic CuO, and the weaker peaks at 330 and 604 cmÀ1corresponds to B1g and B2g modes, respectively [29] Thermal analysis of the modified b-nickel hydroxide electrode material bonded with PTFE was studied by TG-DTA Fig shows representative TG-DTA curves of modified b-nickel hydroxide -50 1046 6.5 Weight (mg) 2853 2924 1041 1637 1469 3430 1388 603 3655 7.0 1137 425 529 50 6.0 100 5.5 150 5.0 200 4.5 512 4000 3500 3000 2500 2000 1500 1000 -1 Wave number (cm ) Fig FTIR spectrum of modified b-Ni(OH)2 with CuO 484 500 4.0 100 200 300 400 500 600 700 Heat flow Endo down (mW) Transmittance (%) 7.5 250 o Temperature ( C) Fig TG-DTA curves of modified b-nickel hydroxide electrode with CuO 96 B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 electrode with CuO bonded with PTFE Three endothermic peaks were observed in the DTA curve The first endothermic peak is at around 119  C due to the elimination of adsorbed water molecules, which is supported by the weight loss of 1.97% The second endothermic peak observed at 320  C is related to the endothermic nature of CuO added b-nickel hydroxide during the decomposition of Ni(OH)2 into the NiO with the corresponding weight loss of 18.15% The third endothermic peak at around 402  C is attributed to the decomposition of CuO and intercalated anions with a corresponding weight loss of 9.06% Weight loss observed in the region between 450  C and 650  C can be attributed to the loss of intercalated anions and thermal decomposition of PTFE used as a binder for the preparation of electrode [30] Thus, TG studies shows that modified b-Ni(OH)2 electrode with CuO bonded with PTFE material has considerable amount of adsorbed-intercalated H2O molecules These H2O molecules play substantial role in enhancement of electrochemical behavior of electrodes since they offer way for diffusion of proton along molecular chain among layers Fig displays the CV curves of pure b-nickel hydroxide and modified b-nickel hydroxide with CuO electrodes in M KOH electrolyte at a scanning rate of 0.025 V sÀ1 at potential window of 0e0.7 V vs Hg/HgO Observed pair of strong redox peaks in CV curve is owed to Faradaic reactions of b-nickel hydroxide It is well known that the surface faradic reactions will proceed according to the following reaction [16], charge b NiOHị2 ! b NiOOH ỵ Hỵ ỵ eÀ (1) discharge The anodic peak is due to the oxidation of the b-Ni(OH)2 in to bNiOOH and the cathodic peak is due to the reverse process Near the strong oxidation peak (observed at 500 mV) belonging to the bNiOOH, another typical weak oxidation peak around 452 mV occurs in Fig corresponding to the pure b-Ni(OH)2 electrode Observed additional weak oxidation peak may be due to the presence of easily oxidized grains probably contained with excess alkali incompletely removed during synthesis [31] The excess alkali is responsible for decrease in the local electrochemical potential required for the oxidation reaction [31] But for the electrodes with CuO, no typical peak contributed by the presence of excess alkali is found in Fig Epc 0.004 Generally, the peak potential difference (DEa,c) between the anodic (Epa) and cathodic (Epc) peak potentials is considered as a measure of the reversibility of the redox reaction [32e37] Smaller DEa,c means more reversible electrode reaction Variation in anodic peak potentials, cathodic peak potentials and oxygen evolution reactions with the addition of CuO by co-precipitation method is shown in the Fig In order to compare the characteristics of the electrodes, CV data in Fig consisting of anodic nickel hydroxide oxidation peak and cathodic oxyhydroxide reduction peak potentials is tabulated in Table As compared to pure b-Ni(OH)2, the DEac values of modified b-nickel hydroxide with CuO are reduced, which shows that the inclusion of CuO is found to improve the reversibility of the electrode reaction In the CuO added b-Ni(OH)2 electrode material, protons can also freely intercalate into the cupric oxide lattice on reduction and out of the lattice on oxidation, allowing facile interconversion of the O2 4OHÀ [35] From Fig it can be seen that the polarized current is low before the appearance of electrochemical reaction because there are not any free electrons in the electrolyte The presence of polarized current indicates the occurrence of redox reaction As shown in the Fig 5, the strong terminal peak deals with the oxidation peaks of water When nickel hydroxide electrode is being charged, oxygen evolution reaction (OER) is a parasitic side reaction, which has negative effects on the charge efficiency and the structure of the electrode Oxygen evolution reaction may contribute significantly to the electrode degradation by generating the internal tensile stress within the pores of the porous pasted nickel electrode and accordingly affect the cyclic performance of the electrodes and batteries In the present studies, as compared to pure b-Ni(OH)2, the (EOEeEpa) values of the modified b-nickel hydroxide with CuO are increased, which indicates that the insertion of CuO is found to increase the separation of the anodic peak from the oxygen evolution current Large (EOEeEpa) value facilitates the electrode to be charged fully before oxygen evolution Among the studied compositions, the modified nickel hydroxide electrode with CuO is found to possess larger (EOEeEpa), indicating an increased separation of the anodic peak from the oxygen evolution current Therefore, modified nickel hydroxide electrode with CuO can efficiently restrain the oxygen evolution reaction and improve the charge efficiency It is well established that the electrochemical reaction process of a nickel hydroxide electrode is limited by proton diffusion through the lattice [20,30,37] Therefore, it is of much importance to study the nickel hydroxide electrode's proton diffusion coefficient According to the Randles e Sevcik equation [36], at 25  C the peak current, ip, in the cyclic voltammogram can be expressed as, 0.002 1 ip ¼ 2:69  105  n2  A  D2  Co  y2 Current (A) 0.000 -0.002 -0.004 EOE Epa Pure β - Ni(OH)2 -0.006 Modified β - Ni(OH)2 with CuO -0.008 -0.010 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Potential (V) Fig CV curves of pure and modified b-Ni(OH)2 electrodes with CuO at a scanning rate of 0.025 V sÀ1 (2) where n is the electron number of the reaction (~1 for b-Ni(OH)2), A is the surface area of the electrode (1 cm2), D is the diffusion coefficient, y is the scanning rate, and Co is the initial concentration of the reactant For an Ni(OH)2 electrode, Co ¼ r/M, where r and M are the density and the molar mass of Ni(OH)2 respectively Fig displays the relation between the ip and y½ for pure bnickel hydroxide and modified b-Ni(OH)2 electrodes with CuO A good linear relationship between ip and y½ revealed that electrode Table CV characteristics for pure and modified b-Ni(OH)2 electrodes Electrode Epa(V) Epc (V) EOE (V) D Eac(V) EOEÀEpa(V) 0.500 Pure b-Ni(OH)2 Modified b-Ni(OH)2 with CuO 0.424 0.331 0.284 0.550 0.543 0.169 0.140 0.050 0.119 B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 0.0028 0.0024 Q1 Pure β-Ni(OH)2 Modified β - Ni(OH)2 with CuO R1 0.0020 0.0016 ip(A) 97 R2 0.0012 Fig Proposed equivalent circuit for nickel hydroxide electrodes 0.0008 Table Equivalent circuit parameters for pure and modified b-Ni(OH)2 electrodes 0.0004 0.0000 0.02 0.04 0.06 0.08 1/2 υ 0.10 -1 0.12 0.14 0.16 Electrode R1/U R2/U Y1 n1 Pure b-Ni(OH)2 Modified b-Ni(OH)2 with CuO 1.1646 1.1876 3894 1285 0.0001470 0.0001194 0.82000 0.70464 1/2 (Vs ) Fig Relationship between ip and y½ for pure and modified b-nickel hydroxide electrodes reaction of b-Ni(OH)2 is regulated by diffusion of protons Using the slope of fitted line in Fig in Randles e Sevcik equation [36], the proton diffusion coefficients for modified b-nickel hydroxide with CuO is found to be 4.0666  10À12 cm2 sÀ1, which is comparatively greater than that of pure b-nickel hydroxide with 1.44  10À12 cm2sÀ1 Thus, the proton diffusion coefficient was found to increase with an insertion of CuO in to b-nickel hydroxide electrode material by co-precipitation method Observed proton diffusion coefficient values are comparable with the values in literature Han et al obtained the proton diffusion coefficient values of 1.93  10À11 cm2 sÀ1 and 5.50  10À13 cm2 sÀ1 for nanometer Ni(OH)2 and spherical Ni(OH)2 respectively [38] Li et al obtained the proton diffusion coefficient values of 3.54  10À11 cm2 sÀ1 and 9.34  10À12 cm2 sÀ1 2À for NOÀ intercalated Al-substituted nickel hydroxide and SO4 intercalated Al-substituted nickel hydroxide respectively [39] Fig shows the Nyquist plots of pure b-Ni(OH)2 and modified bNi(OH)2 electrode with CuO at the biasing voltage of 0.1 V and an amplitude of 0.025 V Experimental data was analyzed by fitting equivalent circuit shown in Fig Parameters R1, R2 and Q1 are ohmic resistance, charge-transfer resistance and constant phase element (CPE) respectively It displays that R1 is in series with parallel connection of Q1 and R2 The impedance of constant phase element (ZCPE) is given by ZCPE ¼ 1/Y (ju)n, where u is angular frequency in rad sÀ1, Y and n are variable factors of CPE [30] Equivalent circuit parameters for pure b-nickel hydroxide electrode and modified b-nickel hydroxide electrodes with CuO are tabulated in the Table From the Table 2, it can be seen that, the charge transfer resistance R2 is reduced after CuO is incorporated The presence of CuO grains enhance the effectiveness of the current collection process and further improves the charge transfer process on the electrode and electrolyte interface This implies that the electrochemical reaction within the modified beNi(OH)2 electrode with CuO proceeds more easily than that within the pure beNi(OH)2 electrode Conclusion A modified b-nickel hydroxide electrode material with CuO has been prepared using co-precipitation method The results of the FTIR spectroscopy and TG-DTA studies indicate that the modified bNi(OH)2 with CuO contains water molecules and anions Addition of CuO into nickel hydroxide by co-precipitation method is found to enhance the reversibility of the electrode reaction and also increase the separation of the oxidation current peak of the active material from the oxygen evolution current Further, modified nickel hydroxide with CuO is also found to exhibit higher proton diffusion coefficient and lower charge transfer resistance These findings suggest that the modified b-Ni(OH)2 electrode with CuO synthesized by co-precipitation method possess improved electrochemical properties and thus can be recognized as a promising candidate for the battery electrode applications Acknowledgements Authors wish to acknowledge the Sophisticated Test and Instrumentation Centre (STIC), CUSAT, Cochin for TG-DTA analysis and SAIF, IIT, Madras for Raman analysis References Fig Electrochemical impedance plots of pure and modified b-nickel hydroxide electrodes [1] Lin Li, Zhong Wu, Shuang Yuan, Xin-Bo Zhang, Advances and challenges for flexible energy storage and conversion devices and systems, Energy Environ Sci (2014) 2101e2122 [2] Zhong Wu, Xiao-Lei Huang, Zhong-Li Wang, Ji-Jing Xu, Heng-Guo Wang, XinBo Zhang, Electrostatic induced stretch growth of homogeneous b-Ni(OH)2 on 98 [3] [4] [5] [6] [7] [8] [9] [10] [11] [12] [13] [14] [15] [16] [17] [18] [19] [20] B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 graphene with enhanced high-rate cycling for supercapacitors, Sci Rep (2014) 3669 (8pp) Zhong-Li Wang, Dan Xu, Ji-Jing Xu, Xin-Bo Zhang, Oxygen electrocatalysts in metaleair batteries: from aqueous to nonaqueous electrolytes, Chem Soc Rev 43 (2014) 7746e7786 Xiao-lei Huang, Jia Chai, Tao Jiang, Ying-Jin Wei, Gang Chen, Wan-qiang Liu, Dongxue Han, Li Niu, Limin Wang, Xin-bo Zhang, Self-assembled large-area Co(OH)2 nanosheets/ionic liquid modified graphene heterostructures toward enhanced energy storage, J Mater Chem 22 (2012) 3404e3410 H Bode, K Dehmelt, J Witte, Zur kenntnis der nickelhydroxidelektrodedI.Über das nickel (II)-hydroxidhydrat, Electrochim Acta 11 (1966) 1079e1087 H.S Lim, S.A Verzwyvelt, Effects of electrode thickness on power capability of a sintered-type nickel electrode, J Power Sources 62 (1) (1996) 41e44 D.E Reisner, A.J Salkind, P.R Strutt, T.D Xiao, Nickel hydroxide and other nanophase cathode materials for rechargeable batteries, J Power Sources 65 (1e2) (1997) 231e233 S Nathira Begum, V.S Muralidharan, C Ahmed Basha, The influences of some additives on electrochemical behaviour of nickel electrodes, Int J Hydrogen Energy 34 (2009) 1548e1555 T Pan, J.M Wang, Y.L Zhao, H Chen, H.M Xiao, J.Q Zhang, Al-stabilized anickel hydroxide prepared by electrochemical impregnation, Mater Chem Phys 78 (2003) 711e718 R.D Armstrong, G.W.D Briggs, E.A Charles, Some effects of the addition of cobalt to the nickel hydroxide electrode, J Appl Electrochem 18 (1988) 215e219 K Watanabe, M Koseki, N Kumagai, Effect of cobalt addition to nickel hydroxide as a positive material for rechargeable alkaline batteries, J Power Sources 58 (1996) 23e28 C Chakkaravarthy, P Periasamy, S Jegannathan, K.I Vasu, The nickel/iron battery, J Power Sources 35 (1991) 21e35 D.M Constantin, E.M Rus, L Oniciu, L Ghergari, The influence of some additives on the electrochemical behaviour of sintered nickel electrodes in alkaline electrolyte, J Power Sources 74 (1998) 188e197 Li Jun, Li Rong, Wu Jianming, Su Hang, Effect of cupric oxide addition on the performance of nickel electrode, J Power Sources 79 (1999) 86e90 P.V Kamath, G.N Subbanna, Electroless nickel hydroxide: synthesis and characterization, J Appl Electrochem 22 (1992) 478e482 P Baraldi, G Davolio, An electrochemical and spectral study of the nickel oxide electrode, Mater Chem Phys 21 (1989) 143e154 Mustafa Aghazadeh, Ahmad Nozad Golikand, Mehdi Ghaemi, Synthesis, characterization, and electrochemical properties of ultrafine b-Ni(OH)2 nanoparticles, Int J Hydrogen Energy 36 (2011) 8674e8679 N.V Kosova, E.T Devyatkina, V.V Kaichev, Mixed layered NieMneCo hydroxides: crystal structure, electronic state of ions, and thermal decomposition, J Power Sources 174 (2007) 735e740 P Jeevanandam, Y Koltypin, A Gedanken, Synthesis of nanosized a-nickel hydroxide by a sonochemical method, Nano Lett (2001) 263e266 Enbo Shangguan, Zhaorong Chang, Hongwei Tang, Xiao-Zi Yuan, Haijiang Wang, Synthesis and characterization of high-density non-spherical [21] [22] [23] [24] [25] [26] [27] [28] [29] [30] [31] [32] [33] [34] [35] [36] [37] [38] [39] Ni(OH)2 cathode material for NieMH batteries, Int J Hydrogen Energy 35 (2010) 9716e9724 A.C Chapman, L.E Thirlwell, Spectra of phosphorus compoundsdI the infrared spectra of orthophosphates, Spectrochim Acta 20 (1964) 937e947 I.Y Erdogan, O Gullu, Optical and structural properties of CuO nanofilm: its diode application, J Alloys Compd 492 (2010) 378e383 R Ranjbar-Karimi, A Bazmandegan-Shamili, A Aslani, K Kaviani, Sonochemical synthesis, characterization and thermal and optical analysis of CuO nanoparticles, Phys B Condens Matter 405 (2010) 3096e3100 F.P Kober, Infrared spectroscopic investigation of charged nickel hydroxide electrodes, J Electrochem Soc Electrochem Sci 114 (1967) 215e218 C Johnston, P.R Graves, In situ raman spectroscopy study of the nickel oxyhydroxide electrode (NOE) system, Appl Spectrosc 44 (1990) 105e115 S Deabate, F Fourgeot, F Henn, X-ray diffraction and micro-Raman spectroscopy analysis of new nickel hydroxide obtained by electrodialysis, J Power Sources 87 (2000) 125e136 Changjiu Liu, Yanwei Li, Synthesis and characterization of amorphous a-nickel hydroxide, J Alloys Compd 478 (2009) 415e418 R.L Frost, M.L Weier, J.T Kloprogge, Raman spectroscopy of some natural hydrotalcites with sulphate and carbonate in the interlayer, J Raman Spectrosc 34 (10) (2003) 760e768 K Mageshwari, R Sathyamoorthy, Flower-shaped CuO nanostructures: synthesis, characterization and antimicrobial activity, J Mater Sci Technol 29 (10) (2013) 909e914 B Shruthi, B.J Madhu, V Bheema Raju, Influence of TiO2 on the electrochemical performance of pasted type b-nickel hydroxide electrode in alkaline electrolyte, J Energy Chem 25 (2016) 41e48 Donald Tuomi, The forming process in nickel positive electrodes, J Electrochem Soc 112 (1) (1965) 1e12 Steven L Petersen, Dennis E Tallman, Gold and platinum poly(chlorotrifluoroethylene) composite electrodes, Anal Chem 62 (1990) 459e465 W.G Zhang, W.Q Jiang, L.M Yu, Z.Z Fu, W Xia, M.L Yang, Effect of nickel hydroxide composition on the electrochemical performance of spherical Ni(OH)2 positive materials for NieMH batteries, Int J Hydrogen Energy 34 (2009) 473e480 B Liu, H Yuan, Y Zhang, Z Zhou, D Song, Cyclic voltammetric studies of stabilized a-nickel hydroxide electrode, J Power Sources 79 (1999) 277e280 Guoping Wang, Lei Zhang, Jiujun Zhang, A review of electrode materials for electrochemical supercapacitors, Chem Soc Rev 41 (2012) 797e828 A.H Zimmerman, P.K Effa, Discharge kinetics of the nickel electrode, J Electrochem Soc 131 (1984) 709e713 B Shruthi, V Bheema Raju, B.J Madhu, Synthesis, spectroscopic and electrochemical performance of pasted b-nickel hydroxide electrode in alkaline electrolyte, Spectrochim Acta Part A 135 (2015) 683e689 X.J Han, P Xu, C.Q Xu, L Zhao, Z.B Mo, T Liu, Study of the effects of nanometer b-Ni(OH)2 in nickel hydroxide electrodes, Electrochim Acta 50 (2005) 2763e2769 Y.W Li, J.H Yao, C.J Liu, W.M Zhao, W.X Deng, S.K Zhong, Effect of interlayer anions on the electrochemical performance of Al-substituted a-type nickel hydroxide electrodes, Int J Hydrogen Energy 35 (2010) 2539e2545 ... Characterization of modified b- nickel hydroxide electrodes with CuO Crystal structure of the modified nickel hydroxide with CuO was studied by XRD analysis using Bruker AXS D8 Advance diffractometer with a... kinetics of the nickel electrode, J Electrochem Soc 131 (1984) 709e713 B Shruthi, V Bheema Raju, B. J Madhu, Synthesis, spectroscopic and electrochemical performance of pasted b- nickel hydroxide electrode. .. b- nickel hydroxide electrode with CuO 96 B Shruthi et al / Journal of Science: Advanced Materials and Devices (2017) 93e98 electrode with CuO bonded with PTFE Three endothermic peaks were observed

Ngày đăng: 17/03/2021, 20:24

Mục lục

    Synthesis, spectroscopic analysis and electrochemical performance of modified β-nickel hydroxide electrode with CuO

    2.1. Preparation of cupric oxide

    2.2. Synthesis of modified β-nickel hydroxide electrodes with CuO

    2.3. Characterization of modified β-nickel hydroxide electrodes with CuO

    2.4. Fabrication of electrodes and electrochemical testing

Tài liệu cùng người dùng

  • Đang cập nhật ...

Tài liệu liên quan