ReagentGuide 8th Synthestic Organic Chemistry Materials Chemistry

Reagent Guide 8th Edition Synthetic Organic Chemistry & Materials Chemistry www.TCIchemicals.com Cyclooctyl group [2+3] cycloaddition with azides High reaction rate constant H H O O N H O NH2 BCN-amine [B4062] H N N O H N O Amino group Easy to modify NH2 O O ADIBO-amine [A2607] A2607 B4062 9,15-Diaza-18-DBCO-3,6-dioxa-10,14,18-trioxooctadecylamine (ADIBO-amine) N-(1R,8S,9s)-Bicyclo[6.1.0]non-4-yn-9-ylmethyloxycarbonyl1,8-diamino-3,6-dioxaoctane (BCN-amine) 25mg 25mg 100mg 2001 2004 2011 2010 2010 O Cl H O2 S O work as CO surrogate N O N-Formylsaccharin T3121 F0854 Cl Cl + O Cl T3121 R R1 X Pd(OAc)2 [A1424] Xantphos [B2709] NR3, solvent O O R1 Cl Cl Nucleophiles Br O N + DMF, 75-85 oC Br F0854 Hydrogenation of hydride species from Ei3SiH T3121 F0854 2,4,6-Trichlorophenyl Formate N-Formylsaccharin H O H N S O H 1g 5g 2012 2014 2013 2 O Pd(OAc)2 [A1424] DPPB [B1246] Et3SiH [T0662] Na2CO3 H SR2 NR2 R1 R O2 S O R1 O Cl R1 : aryl, alkenyl X : I, Br, OTf OR2 R1 O Br N S CO H Cl 2,4,6-Trichlorophenyl Formate O H Cl 5g 25g B2134 B1375 B1123 O Se OH Bu O CH3O Se Bu OCH3 Bu C1944 L0021 H3C CH3 H3C CH3 N NO N Ru O C(CH3)3 (CH3)3C O Cl C(CH3)3 (CH3)3C P1742 O0414 O CH3 C O Pb P0930 KMnO4 N B2134 B1375 B1123 C1944 C O Bu O CH3 O O Os OH O OH CH3 Cr2O72 2 P1910 12MoO3 H3PO4 OsO4 P1088 N H xH2O Q0058 N H FCrO3 N H Cr2O722 T1559 Bu Ag2 H N O Si C18H37 O OCH ClCrO3 T1803 O O OCH3 O Si P0931 N H S0815 Fe 3O4 O0308 Cr2O7 N Bu N Bu Bu Pr ReO4 Pr N Pr RuO4 Pr Benzeneseleninic Acid Bis(4-methoxyphenyl) Selenoxide Bis(tetrabutylammonium) Dichromate Chloronitrosyl[N,N -bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediaminato]ruthenium(IV) 1g 5g 5g 10g 100mg L0021 O0414 O0308 P1910 P1742 P0930 P0931 P1088 Q0058 S0815 T1803 T1559 Lead Tetraacetate (contains Acetic Acid) Osmium Catalyst supported on Magnetite (0.07-0.09mmol/g) Osmium Tetroxide (4% in Water) Phosphomolybdic Acid Hydrate Potassium Permanganate Pyridinium Chlorochromate Pyridinium Dichromate Pyridinium Fluorochromate Quinolinium Dichromate Silver(II) Pyridine-2-carboxylate Tetrabutylammonium Perrhenate Tetrapropylammonium Perruthenate B2897 25g 500g 1g 10mL 100g 300g 500g 500g 5g 25g 5g 5g 5g 25g 25g 25g 100g 100g 10g 1g 1g 1g D3428 D3429 CH3 CH3 CH3 N N ClO4 CH3 M1774 M2072 M1775 T0836 CH3 ClO4 T0839 CH3 CH3 ClO4 CH3 N ClO4 CH3 CH3 CH3 CH3 N CH3 CH3 ClO4 CH2CH3 Bu CH3 Bu CH3 CH3CH2 N CH2CH3 ClO4 ClO4 CH2CH3 Bu N N CH3 N Bu ClO4 CH3 T0841 CH3 CH3 N CH3 ClO4 CH3 B2897 D3428 D3429 M1774 M2072 M1775 T0836 T0839 T0841 9-(2-Biphenylyl)-10-methylacridinium Perchlorate 9-(2,5-Dimethylphenyl)-10-methylacridinium Perchlorate 9-(2,6-Dimethylphenyl)-10-methylacridinium Perchlorate 9-Mesityl-10-methylacridinium Perchlorate 9-Mesityl-2,7,10-trimethylacridinium Perchlorate 10-Methyl-9-phenylacridinium Perchlorate Tetrabutylammonium Perchlorate Tetraethylammonium Perchlorate Tetramethylammonium Perchlorate B3152 1g 1g 1g 1g 25g B3497 O B3153 CH3 O C O O C CH3 Si CH3 1g 100g 5g 5g 5g 5g 1g 5g 500g 25g 25g CH3 CH3 O O Si CH3 CH3 CH3 C OOH CH3 C0357 C2223 D3411 M0927 O O CH3 CH3 C OOH CH3 C O Mg2+ CH3 C O O C CH3 C OOH CH3 CH3 CH3 Cl B3152 B3497 B3153 C0357 C2223 D3411 M0927 6H2O C OOH O Benzoyl Peroxide (wetted with ca 25% Water) Bis(trimethylsilyl) Peroxide (contains Hexamethyldisiloxane) (ca 30% in Hexane) tert-Butyl Hydroperoxide (70% in Water) 3-Chloroperoxybenzoic Acid (contains ca 30% Water) Cumene Hydroperoxide (contains ca 20% Aromatic Hydrocarbon) Di-tert-butyl Peroxide Monoperoxyphthalic Acid Magnesium Salt Hexahydrate A2678 25g 5g 100g 25g 250g 100g 100mL 25g 500g B2539 B1175 O CH3 C O I O O O CF3 N O I C O I O C CF3 I O C CH3 BF4 N Br B1616 B2121 O O CF3 C O I O C CF3 F F F I0330 D4477 D2045 CH3 CH3 C OO I O AcO OAc AcO I O O CH3 O I0479 O O CH3 C O I O C CH3 O CH3 C O CH3 CH3 O F CH3 F I0072 I0073 I O n I0791 HO I P1015 P1415 O O HO O I O O O HO I O S O O O C CH3 CH3 P I O C CH3 O A2678 B2539 B1175 B1616 B2121 D4477 D2045 I0330 I0479 I0072 I0073 I0791 P1015 P1415 1-Acetoxy-5-bromo-1,2-benziodoxol-3(1H)-one (ABBX) Barluenga s Reagent [Bis(trifluoroacetoxy)iodo]benzene (PIFA) [Bis(trifluoroacetoxy)iodo]pentafluorobenzene 1-(tert-Butylperoxy)-1,2-benziodoxol-3(1H)-one Dess-Martin Periodinane (8-12% in Dichloromethane) Dess-Martin Periodinane Iodobenzene Diacetate (PIDA) Iodomesitylene Diacetate Iodosobenzene 2-Iodosobenzoic Acid 2-Iodoxybenzoic Acid (IBX) (stabilized with Benzoic Acid + Isophthalic Acid) Koser Reagent Poly[4-(diacetoxyiodo)styrene] (PSDIB) 5g 1g 1g 10g 25mL 5g 25g 5g 5g 5g 1g 1g 1g 25g 5g 1g 250mL 25g 250g 25g 5g 10g 25g 25g 5g D3219 D3220 L0069 N(CH3)2 Cl N Cl N O P0557 M0981 M2192 CH3 xH2O CH3 O O T1362 T0466 CH3 O CH3 N CH3 N O N CH3 O O 2,6-Dichloropyridine N-Oxide 4-(Dimethylamino)pyridine N-Oxide Hydrate 2,6-Lutidine N-Oxide 4-Methylmorpholine N-Oxide (50% in Water, ca 4.8mol/L) 4-Methylmorpholine N-Oxide Pyridine N-Oxide Trimethylamine N-Oxide Anhydrous Trimethylamine N-Oxide Dihydrate D3219 D3220 L0069 M0981 M2192 P0557 T1362 T0466 N A1348 1g 25mL 5g 25g 1g 25g H0878 I0908 O O CH3 CH3 N O O O O CH3 CH3 CH3 CH3 O M1197 O O C HN C CH3 5g 5g 25g 500mL 25g 500g 5g 500g CH3 N CH3 CH3 CH3 N CH3 O CH3 I O T1560 OCH3 CH3 CH3 CH3 N O A1348 H0878 I0908 M1197 T1560 CH3 CH3 CH3 CH3 N CH3 O 4-Acetamido-TEMPO Free Radical 4-Benzoyloxy-TEMPO Free Radical 4-[2-[2-(4-Iodophenoxy)ethoxy]carbonyl]benzoyloxy-2,2,6,6-tetramethylpiperidin-1-oxyl 4-Methoxy-TEMPO Free Radical TEMPO Free Radical T1837 T2507 Bi 25g 5g 100mg 1g 5g 5g 25g T1956 CH3 Cl Cl 5g 1g CH3O Cl BF4 Bi CH3 Bi Cl OCH3 OCH3 T2038 T1957 CF3 CH3 Cl Cl CF3 Bi CH3 Bi Cl Cl CH3 CF3 T1837 T2507 T1956 T2038 T1957 Triphenylbismuth Dichloride Triphenyl-2,6-xylylbismuthonium Tetrafluoroborate Tris(2-methoxyphenyl)bismuth Dichloride Tris(4-trifluoromethylphenyl)bismuth Dichloride Tri-o-tolylbismuth Dichloride 5g 1g 5g 1g 5g 100mg 1g 1g A2065 C1806 B2151 O NH C CH3 CH3 N B0656 Bu B2188 O Br N Br CH3 NH C CH3 S Cl H3C S N C CH3 CH3 O H0362 CH3 Br S2O8 N Bu BF4 B2240 O Br Bu CH3 O T0617 Bu (NH4)2Ce(NO3)6 CH3 CH3 H3C C O Cl CH3 H3C Br O C1326 CH3 C1327 CH3 CH3 S O O D0318 T0061 T0970 Cl CH3 O SO2NNa Cl O Cl Cl Cl Cl O N N O C0076 O S O O H1404 Cl 3H2O CH3 I0074 O Cl Cl M2274 M2321 Cl N OH N O I N CH3 CH3 O0310 P0998 2KHSO5 KHSO4 K2SO4 S N O A2065 C1806 B2151 T0617 B0656 B2240 SO3 O SO2NCl CH3 N CH3 SO3 (CH2)6SCH3 N CH3 CH3 T1559 SO3 N Pr Pr N Pr RuO4 Pr 4-Acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium Tetrafluoroborate Ammonium Cerium(IV) Nitrate Bis(tetrabutylammonium) Peroxydisulfate Bromanil N-Bromosuccinimide N-tert-Butylbenzenesulfenamide 25g 1g 50g 5g 5g 100g 5g 5g 500g 25g 25g 500g 25g B2188 H0362 C1326 C1327 C0076 T0061 T0970 D0318 H1404 I0074 M2274 M2321 O0310 P0998 T1559 N-tert-Butylbenzenesulfinimidoyl Chloride tert-Butyl Hypochlorite (2R,8aS)-(+)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent] (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent] Chloramine T Trihydrate Chloranil o-Chloranil Dichloramine T 2-Hydroxy-2-azaadamantane N-Iodosuccinimide 1-Methyl-3-[6-(methylsulfinyl)hexyl]imidazolium p-Toluenesulfonate 1-Methyl-3-[6-(methylthio)hexyl]imidazolium p-Toluenesulfonate Potassium Peroxymonosulfate [>45%(T) as KHSO5] Pyridine - Sulfur Trioxide Complex Tetrapropylammonium Perruthenate 200mg 5g 25g 1946 1991 1968 1975 1979 1983 1993 2002 1987 1994 1960 1996 1g 25g 1g 1g 25g 25g 5g 25g 1g 25g 1g 1g 25g 100g 1g 5g 500g 5g 5g 500g 500g 25g 500g 5g 100g 5g 5g 500g 500g 5g 1 OCH(CF3)2 H B OCH(CF3)2 Na OCH(CF3)2 [S0810] O OTBS CH3 O / THF (3 eq.) CHO Hexafluoroisopropanol, 25 °C, 1.5 h OTBS OH CH3 Y 94% T2346 S0396 S0480 S0394 L0186 L0170, L0203 D1843 D2581 D2972 D2971 L0203 L0170 LiAlH4 [(CH3)2CHCH2]2AlH L0159 S0467 OC(CH3)3 Li H Al OC(CH3)3 NaAl(OCH2CH2OCH3)2H2 OC(CH3)3 D2972 D2971 L0203 L0170 L0159 S0467 Diisobutylaluminum Hydride (17% in Toluene, ca 1.0mol/L) Diisobutylaluminum Hydride (19% in Hexane, ca 1.0mol/L) Lithium Aluminum Hydride (Powder) Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca 2.5mol/L) Lithium Tri-tert-butoxyaluminum Hydride (ca 30% in Tetrahydrofuran, ca 1.0mol/L) Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca 3.6mol/L) 100mL 500mL 100mL 500mL 25g 100g 100mL 100mL 25g 100g 500g T1473 (CH2)3CH3 CH3(CH2)3 Sn H (CH2)3CH3 T1473 Tributyltin Hydride (stabilized with BHT) S0481 10 250g 100g 5g 500g 25g Z0010 NaH S0481 Z0010 25g H Zr Sodium Hydride (60%, dispersion in Paraffin Liquid) Zirconocene Chloride Hydride Cl 1g B1139 L0186 Ph3P Ph3P P1719 P1681 Cu L0164 CH(CH3)CH2CH3 BH4 LiBH4 Li H B CH(CH3)CH2CH3 CH(CH3)CH2CH3 P1380 S0480 S0396 CH3 CH2 N CH3 P CH3 KBH4 CH3 CH3CH2CH BH NaBH4 K NaBH3CN BH3CN S0394 S0810 OCH(CF3)2 OAc Na T0917 Na OCH(CF3)2 OAc Bu N Bu T1553 CH3 CH3 Bu H B OCH(CF3)2 AcO B H T0852 CH3 N CH3 BH4 BH4 CH3 CH3 Bu B1139 L0186 L0164 P1719 Bis(triphenylphosphine)copper Tetrahydroborate Lithium Borohydride (ca 3mol/L in Tetrahydrofuran) Lithium Tri-sec-butylborohydride (ca 21% in Tetrahydrofuran, ca 1.0mol/L) (Polystyrylmethyl)trimethylammonium Cyanoborohydride cross-linked with 10% DVB (30-50mesh) P1681 P1380 S0480 S0396 S0394 S0810 T0917 T0852 T1553 Potassium Borohydride Potassium Tri-sec-butylborohydride (ca 1.0mol/L in Tetrahydrofuran) Sodium Borohydride Sodium Cyanoborohydride Sodium Triacetoxyborohydride Sodium Tris(1,1,1,3,3,3-hexafluoroisopropoxy)borohydride Tetrabutylammonium Borohydride Tetramethylammonium Borohydride Tetramethylammonium Triacetoxyborohydride OAc 5g 100mL 100mL 5g 25g 25g 100g Price on request 25g 100g 500g 5g 25g 250g 25g 100g 5g 5g 25g 5g 25g 5g 25g (2.6-3.0mmol/g) B1827 T2346 CH3 CH3 CH3 C S(CH2)2S CH3 D2581 OAc CH3 N CH3 AcO B H 2BH3 C CH3 CH3 BH3 O D1843 CH2CH3 N BH3 CH3SCH3 BH3 CH2CH3 B1827 T2346 D2581 D1843 1,2-Bis(tert-butylthio)ethane Borane Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca 0.9mol/L) (stabilized with Sodium Borohydride) N,N-Diethylaniline Borane Dimethyl Sulfide Borane 1g 100mL 500mL 25g 100g 25mL 100mL 11 B1264 B4084 CH3 CH3 C NH2 BH3 B3018 CH3CH2 B1569 D1842 BH3 N B1264 B4084 B3018 M0898 B1569 D1842 T1180 T1181 CH3 H N BH3 CH3 BH3 CH3CH2 N CH3 N 25g 100g 25mL 100mL 5g 25g 5g 25g 25mL 25g 500g 25g 25g I0796 CH3 CH3 B Cl CH3 CH3 I0797 CH3 B Cl CH3 H2 B CH3 CH3 N N CH3 CH3 CH3 CH3 B H2 CH3 CH3 CH3 CH3 CH3 H2 B CH3 CH3 N N CH3 CH3 CH3 D2403 CH(CH3)2 Si H CH3 SiH2 Si H Si CH3 CH3 Si H OCH2CH3 CH3 P1291 H CH3 OCH2CH3 CH3 Cl CH(CH3)2 D1825 CH3 100mL 100mL 100mL 5g 5g C0778 H Si Cl D2406 D2820 CH3 CH3 (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca 1.6mol/L) (-)-B-Chlorodiisopinocampheylborane (55-65% in Heptane, ca 1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca 1.7mol/L) (+)-Isopinocampheylborane TMEDA Complex (-)-Isopinocampheylborane TMEDA Complex D2196 B H2 C1492 12 BH3 CH3 CH2CH3 C2023 C1615 CH3 BH3 O Borane - tert-Butylamine Complex Borane - 5-Ethyl-2-methylpyridine Complex Borane - 2-Methylpyridine Complex Borane - Morpholine Complex Borane - Pyridine Complex Dimethylamine Borane Triethylamine Borane Trimethylamine Borane C1614 C1614 C2023 C1615 I0796 I0797 CH3 T1181 CH2CH3 CH3 N CH3 T1180 H N BH3 BH3 N CH3 M0898 T1437 SiH3 CH3 CH3 CH3 Si O Si H H CH3 T1896 T0398 T0662 T1334 CH2CH3 Cl H Si Si Si H H Cl CH3CH2 Si H T0661 i (CH2)5CH3 iPr CH3(CH2)5 Si H CH2CH3 Cl T1533 (CH2)5CH3 Pr Si H iPr T1463 Si(CH3)3 Si H (CH3)3Si Si H Si(CH3)3 C1492 C0778 D2403 D2196 D2406 D2820 D1825 P1291 T1437 T1896 T0398 T0662 T1334 T1533 T0661 T1463 Chlorodiisopropylsilane Chlorodimethylsilane Diethoxymethylsilane [Hydrosilylating Reagent] Dimethylphenylsilane Diphenylsilane Diphenylsilane Methyldiphenylsilane Phenylsilane 1,1,3,3-Tetramethyldisiloxane 1,1,2,2-Tetraphenyldisilane Trichlorosilane Triethylsilane Trihexylsilane Triisopropylsilane Triphenylsilane Tris(trimethylsilyl)silane (stabilized with TBBP) 5g 5mL C2648 H0697 H0204 H0172 O 5mL 25mL 25mL 250mL 25mL 25mL 5g 25g 5g 25g 25mL 5mL 25mL 25mL 250mL 1g 5g 25g 500g 25mL 250mL 10g 25mL 100mL 25g 5mL 25mL H0169 C NHNH2 H2NNH2 H2NNH2 2HBr xH2O Cl H0170 H0173 H0174 I0777 SO2NH N C H2NNH2 C2648 H0697 H0204 H0172 H0169 H0170 2HCl H2NNH2 HBr 3-Chlorobenzohydrazide Hydrazine Anhydrous Hydrazine Monohydrate (79%) Hydrazine Monohydrate Hydrazine Dihydrobromide Hydrate Hydrazine Dihydrochloride H2NNH2 HCl NO2 CH3 CH3 5g 25g 10g 100g 25g 500g 25mL 500mL 25g 500g 25g 500g 13 H0173 H0174 I0777 Hydrazine Monohydrobromide Hydrazine Monohydrochloride N -Isopropylidene-2-nitrobenzenesulfonohydrazide 25g 25g D4311 D3775 O CH3 S0494 T0430 OC(CH3)3 N H H1221 O O O (CH3)3CO CH3CH2O C CH3 CH3 T0488 500g 500g 5g C OCH2CH3 N H HI CH3 T0519 T1819 CH3 SmI2 OCH3 O CH3 O P O CH3 CH3O P OCH3 P D4311 D3775 H1221 S0494 T0430 T0488 T0519 T1819 Di-tert-butyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Hydriodic Acid (57%) Samarium(II) Iodide (ca 0.1mol/L in Tetrahydrofuran) Triethyl Phosphite Trimethyl Phosphite Triphenylphosphine Triphenylphosphine Selenide P1785 P1491 P1701 P1702 P1703 P1490 P1528 P1786 P1720 P1944 R0075 R0076 S0487 Palladium 10% on Carbon (wetted with ca 55% Water) Palladium 10% on Carbon (wetted with ca 55% Water) Palladium 5% on Barium Carbonate Palladium 5% on Barium Sulfate Palladium 5% on Calcium Carbonate (poisoned with Lead) Palladium 5% on Carbon (wetted with ca 55% Water) Palladium Hydroxide 20% on Carbon (wetted with ca 50% Water) Palladium on SH Silica Gel (0.1mmol/g) Platinum(IV) Oxide Poly(methylphenyl)silane supported Palladium/Alumina Hybrid Catalyst [=Pd / (PSi-Al2O3)] Rhodium 5% on Carbon (wetted with ca 55% Water) Ruthenium 5% on Carbon (wetted with ca 50% Water) Skeletal Nickel Catalyst slurry in Water P 1g Se 1g 5g 5g 25g 300mL 25mL 25mL 500mL 25mL 25g 500g 5g 5g 5g 5g 5g 5g 10g 5g 25g 25g 10g 25g 25g 25g 50g 1g 200mg 1g 1g 25g 50g R0129 O O O O Ar2 Cl H2 P N Ru N P Ar2 Cl H2 Me Me OMe Me OMe Ar= Me 14 R0128 O R0131 Me Ar2 Cl H2 P N Ru N P Ar2 Cl H2 O O O R0130 O Me O OMe O Ar2 Cl H2 P N Ru N P Ar2 Cl H2 O O O O O Me Me OMe Ar= Ar= R0133 Me R0135 Me R0134 Ar2 Cl H2 P N Ru N P Ar2 Cl H2 Me Me Ar= Me OMe Ar2 Cl H2 P N Ru H2 N P Ar2 Me OMe H Me Me MeO Ar= Me Me Ar= Me Me RuCl2[(R)-dm-segphos ][(R)-daipen] RuCl2[(S)-dm-segphos ][(S)-daipen] RuCl2[(R)-dm-segphos ][(R,R)-dpen] RuCl2[(S)-dm-segphos ][(S,S)-dpen] RuCl2[(R)-xylbinap][(R)-daipen] RuCl2[(S)-xylbinap][(S)-daipen] RuCl2[(R)-xylbinap][(R,R)-dpen] RuCl2[(S)-xylbinap][(S,S)-dpen] (R)-RUCY -XylBINAP (S)-RUCY -XylBINAP R0129 R0128 R0131 R0130 R0133 R0132 R0135 R0134 R0139 R0138 OMe Ar= Me Me MeO Me OMe R0138 Ar2 Cl H2 H P N Ru H2 N P Ar2 Ar= Me Me OMe Me R0139 Ar2 Cl H2 P N Ru N P Ar2 Cl H2 OMe Ar= Me Me Ar2 Cl H2 P N Ru N P Ar2 Cl H2 Me Me Ar= Me R0132 Me Ar2 Cl H2 P N Ru N P Ar2 Cl H2 Ar2 Cl H2 P N Ru N P Ar2 Cl H2 200mg 200mg 200mg 200mg 200mg 200mg 200mg 200mg 200mg 200mg R0146 R0147 Me Ru P Ar2 R0156 Me Ar2 P Cl Cl Me O Ar2 P O Ru Cl P Ar2 Me 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g Cl Me Me O O Me Ar2 P Ru Cl P Ar2 Me Me Cl Me Ar= Ar= Ar= Me R0157 R0158 Me Ar2 P Ru Cl P Ar2 Me O O O O O Me O Cl O Me O R0159 Me Ar2 P Ru Cl P Ar2 Me O Me O Cl O Ar= Ar= Ru P Ar2 Cl Me Cl Ar= Ru P Ar2 Me O tBu Cl Me Cl Me Cl Ru P Ar2 Cl [RuCl(p-cymene)((R)-binap)]Cl [RuCl(p-cymene)((S)-binap)]Cl [RuCl(p-cymene)((R)-dm-segphos )]Cl [RuCl(p-cymene)((S)-dm-segphos )]Cl [RuCl(p-cymene)((R)-dtbm-segphos )]Cl [RuCl(p-cymene)((S)-dtbm-segphos )]Cl Cl Me O O Me O Me Ar2 P Ru P Ar2 Ar= Me Ar2 P Ru Cl P Ar2 Me Me Me Ar= Cl Me Cl Me Ar= Me Cl Me Ar= Me R0146 R0147 R0156 R0157 R0158 R0159 O Ar2 P R0151 Me Ar2 P Ru Cl P Ar2 Me Me Ar= O R0155 Me OMe R0150 Ar2 P Me O Cl tBu Me Ar2 P Me tBu R0149 Me O Ar= OMe Me R0148 O tBu R0154 Me Ar2 P Ru Cl P Ar2 Me Me 200mg 200mg 200mg 200mg 200mg 200mg 1g 1g 1g 1g 1g 1g 15 [RuCl(p-cymene)((R)-segphos )]Cl [RuCl(p-cymene)((S)-segphos )]Cl [RuCl(p-cymene)((R)-tolbinap)]Cl [RuCl(p-cymene)((S)-tolbinap)]Cl [RuCl(p-cymene)((R)-xylbinap)]Cl [RuCl(p-cymene)((S)-xylbinap)]Cl R0154 R0155 R0148 R0149 R0150 R0151 200mg 200mg 200mg 200mg 200mg 200mg R0123 R0122 F F CH3 F O S O N Ru N H2 R0124 R0127 CH3 Cl CH3 F F F CH3 F O S O N Ru CH3 CH3 R0126 CH3 R0125 F F F N H2 N H2 R0123 R0122 R0125 R0124 R0127 R0126 T3078 T3077 CH3 Cl CH3 N H2 CH3 O S O N Ru CH3 Cl CH3 N H2 N H2 CH3 O CH3 CH3 O N Ru N H Cl CH3 Cl H Ru N O O S N O CH3 Cl CH3 RuCl[(R,R)-Fsdpen](p-cymene) RuCl[(S,S)-Fsdpen](p-cymene) RuCl[(R,R)-Tsdpen](p-cymene) RuCl[(S,S)-Tsdpen](p-cymene) RuCl[(R,R)-Tsdpen](mesitylene) RuCl[(S,S)-Tsdpen](mesitylene) (R,R)-Ts-DENEB (S,S)-Ts-DENEB 200mg 200mg 200mg 200mg 200mg 200mg 200mg 200mg 1911 1991 2008 CH3 Cl T3077 S 1972 1912 1988 1998 16 CH3 Cl T3078 O CH3 O S O N Ru CH3 O S O N Ru CH3 CH3 CH3 CH3 O S O N Ru 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1 NO2 O NO2 R O 1a) Br HN Y 88% N N O Br NHBr Y 90-99% N OH O Br DBI (1) 1b) NO2 3b) [D3753] Y 68% O R Br Br N N NH2 3a) Y 69% 2 2 I O N CH3 CH3 N O I DIH (2) [D3657] OMe NO2 OMe (0.5 eq.) EtOH-conc.H2SO4, 20 °C, 10 Y 97% I NO2 (1 eq.) 90% H2SO4, °C, 60 Y 75% I COOH F COOH (1 eq.) 90% H2SO4, °C, 90 Y 75% F I 17 B2440 B3664 D1868 SF3 CH3OCH2CH2 CH3OCH2CH2 CH3 F N S CH3 F Et F N S F Et CH3 C CH3 F F CH3 D3812 F0335 F0358 F0344 F0225 SO3 N N F F O O S N S O F O N N 2BF4 Cl N CH2Cl 2BF4 F0343 F F0327 Cl BF4 N F0346 F0328 CH3 F CH3 F CH3 H0598 CH3 Et BF4 N N CH3 F F M1573 BF4 CF3SO3 N CH3 CF3SO3 CH3 N P1888 P0999 T1592 Ph Si F Ph T1635 F F Ph Bu4N Bu4N Ph Bu N O T1909 Bu (HF)x KHF2 KF Ph Sn F Ph N Bu H2F3 Bu HF2 T2027 Bu Bu N Bu Bu T1037 T1339 T1125 T1338 Bu Bu F T1295 SF3 N CF3 F F F P1758 Et CH3 F N N Bu F xH2O (CH3CH2)4NF 4HF Bu T2026 T2754 T2023 T2022 CH3 (CH3CH2)4NF B2440 B3664 D1868 D3812 F0335 F0358 F0344 F0225 F0343 F0327 F0346 F0328 H0598 M1573 18 3HF CH3 N CH3 CH3 F 4H2O (CH3CH2)3N 5HF (CH3CH2)3N 3HF Bis(2-methoxyethyl)aminosulfur Trifluoride 4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride (FLUOLEADTM) (Diethylamino)sulfur Trifluoride (DAST) 1,1 -Difluoro-2,2 -bipyridinium Bis(tetrafluoroborate) N-Fluorobenzenesulfonimide (NFSI) N-Fluoro-N -(chloromethyl)triethylenediamine Bis(tetrafluoroborate) (F-TEDA-BF4) 1-Fluoro-2,6-dichloropyridinium Tetrafluoroborate 2-Fluoro-1-methylpyridinium p-Toluenesulfonate 1-Fluoropyridinium Tetrafluoroborate 1-Fluoropyridinium Trifluoromethanesulfonate 1-Fluoro-2,4,6-trimethylpyridinium Tetrafluoroborate 1-Fluoro-2,4,6-trimethylpyridinium Trifluoromethanesulfonate Ishikawa s Reagent Morpholinosulfur Trifluoride (Morph-DAST) 5g 5g 5g 25g 25g 5g 25g 5g 5g 5g 5g 5g 100g 1g 25g 5g 100g 1g 25g 100g 25g 25g 25g 25g 5g 25g 500g 5g P1758 P1888 P0999 T1295 T1909 T1592 T1635 T1037 T1339 T1125 T1338 T2027 T2026 T2754 T2023 T2022 Potassium Fluoride Potassium Hydrogenfluoride Pyridinium Poly(hydrogenfluoride) Tetrabutylammonium Bifluoride Tetrabutylammonium Difluorotriphenylsilicate Tetrabutylammonium Difluorotriphenylstannate Tetrabutylammonium Dihydrogen Trifluoride Tetrabutylammonium Fluoride Hydrate Tetrabutylammonium Fluoride (70-75% in Water) Tetrabutylammonium Fluoride (ca 1mol/L in Tetrahydrofuran) Tetrabutylammonium Fluoride (ca 1mol/L in Tetrahydrofuran) Tetraethylammonium Fluoride Tetrahydrofluoride Tetraethylammonium Fluoride Trihydrofluoride Tetramethylammonium Fluoride Tetrahydrate Triethylamine Pentahydrofluoride Triethylamine Trihydrofluoride B1543 25g 5g 5g 1g 5g 25g 25g 25mL 25mL 100mL 5g H0362 C0075 CH3 CH2 N CH3 CH3 C0076 C1374 C0202 Cl SO2NCl H3C H3C C O Cl xH2O C0802 C0291 O O SO2NNa ClCH2OCH3 CH3 C0460 N Cl N Cl 3H2O CH3 Na H3C ICl4 Cl SO2NNa 300g 500g 100g 25g 25g 5g 25g 100g 500g 100mL 500mL 10g 10g 25g 10g 10g O O D0318 D1645 M0094 M0970 Cl SO2NCl Cl N Cl N O Cl N Cl CH3 OCH3 O S Cl CH3OCH2 O Cl C Cl CH3 O0082 D1003 O O Cl Cl Cl O O N T0620 T2048 T2040 O O Cl Cl B1543 H0362 C0075 C0076 C1374 C0202 Cl O NNa N T0611 Benzyltrimethylammonium Tetrachloroiodate tert-Butyl Hypochlorite Chloramine B Hydrate Chloramine T Trihydrate o-Chloramine T Chloromethyl Methyl Ether S Cl O N N N O Cl CCl3 S Cl O O Cl 25g 25g 25g 25g 100g 5g 500g 500g 500g 25g 500g 19 N-Chlorophthalimide N-Chlorosuccinimide Cyanuric Chloride Dichloramine T Dichloromethyl Methyl Ether Methanesulfonyl Chloride Methoxyacetyl Chloride Oxalyl Chloride Sodium Dichloroisocyanurate Thionyl Chloride (ca 1mol/L in Dichloromethane) Thionyl Chloride Trichloroisocyanuric Acid Trichloromethanesulfonyl Chloride C0802 C0291 C0460 D0318 D1645 M0094 M0970 O0082 D1003 T2048 T2040 T0620 T0611 B2358 B2553 CH3 CH2 CH3 B2152 N H Br S O Br N CH3 D3976 N Br O HN Br O N P1743 Br D1987 O O Br Br O O D1787 Cl CH3 C C Cl Br3 Cl Cl N H O P0825 T1235 T1284 Br Br xH2O O P0928 CH3 CH3 N CH3 Br3 20 N(CH3)2 Br Br CH3 O N N H HBr3 N (CH2)3CH3 O NaN N Br3 O N Br B2148 CH3 N D1710 Br N Br Br CH3 O O O N S CH3 Cl D3753 O Br B3596 Cl Br O CH3 N CH3 Br B B1697 Cl D1265 Br CH3 CH3 O O CH3 NC N Br CH3 PF6 B3311 B0662 O Br N Br N O B0656 N CH3 Br3 B1016 O Br2 CH3 CH3 N CH3 CH3 B0530 500g 500g 500g 500g 250g 500g 500g 500g 500g 500mL 500mL 25g 500g 5g 25g 25g T1382 B2414 25g 100g 25g 25g 25g 25g 25g 100g 25g 25g PBr3 N H Bu Br Bu Br3 N Bu Br3 Bu Br Br T1382 B2358 B2553 B2414 B0530 B1016 B3311 B1697 B2152 B0656 B0662 B3596 D3976 D1265 D3753 D1710 D1987 D1787 B2148 P1743 P0825 T1235 T1284 P0928 Benzyltrimethylammonium Tribromide Bis(2,4,6-trimethylpyridine)bromonium Hexafluorophosphate Boron Tribromide (17% in Dichloromethane, ca 1mol/L) Bromine N-Bromoacetamide 2-Bromo-2-cyano-N,N-dimethylacetamide Bromodimethylsulfonium Bromide N-Bromophthalimide N-Bromosaccharin N-Bromosuccinimide Bromotrichloromethane 1-Butyl-3-methylimidazolium Tribromide 1,8-Diazabicyclo[5.4.0]-7-undecene Hydrogen Tribromide 1,3-Dibromo-5,5-dimethylhydantoin Dibromoisocyanuric Acid 5,5-Dibromomeldrum s Acid (=5,5-Dibromo-2,2-dimethyl-4,6-dioxy-1,3-dioxane) 1,2-Dibromo-1,1,2,2-tetrachloroethane 4-Dimethylaminopyridinium Bromide Perbromide Monosodium Bromoisocyanurate Hydrate Phosphorus Tribromide Pyridinium Bromide Perbromide 2,4,4,6-Tetrabromo-2,5-cyclohexadienone Tetrabutylammonium Tribromide Trimethylphenylammonium Tribromide B1604 5g 1g 90g 5g 25g 25g 5g 5g 5g 25g B2539 CH3 N CH3 ICl2 N I N BF4 CH3 CH3 C1190 D3657 O N ICH2CH2Cl CH3 N H1221 I O I0074 O O B1604 B2539 B2359 C1190 D3657 D4340 S N O I I N CH3 PF6 CH3 I0604 T2717 O ICl I N I2 HI CH3 P2086 N CH3 I CH3 CH3SCH N I I0784 N CH3 D4340 CH3 25g 5g 100g 25g B2359 CH3 CH2 5g 5g 5g 100g 25g 25g 5g 100mL 500g 25g 5g 25g 25g 25g 500g 500g 5g 5g 500g 25g 25g 25g 25g 25g 300g 500g 25g 500g 500g I0308 CH3 CH3 N CH3 ICl2 CH3 CH3 CH3 Si I CH3 O Benzyltrimethylammonium Dichloroiodate Bis(pyridine)iodonium Tetrafluoroborate Bis(2,4,6-trimethylpyridine)iodonium Hexafluorophosphate 1-Chloro-2-iodoethane (stabilized with Copper chip) 1,3-Diiodo-5,5-dimethylhydantoin N,N-Dimethyl-N-(methylsulfanylmethylene)ammonium Iodide 5g 1g 1g 5g 5g 25g 1g 5g 5g 25g 25g 21 H1221 I0604 I0784 I0074 P2086 T2717 I0308 Hydriodic Acid (57%) Iodine N-Iodosaccharin N-Iodosuccinimide Pyridine Iodine Monochloride Tetramethylammonium Dichloroiodate Trimethylsilyl Iodide (stabilized with Aluminum) 300mL 500g 5g 25g 100g 1g 5g 5g 5g 25g 25g 5g 1968 2002 2001 2000 1991 1965 2007 22 O R1 R2 OH cat F F3C SiMe3 + R1 [T1570] CuI (10 mol%) phen (10 mol%) I F3C SiEt3 + X KF, NMP/DMF [T2764] R2 CF3 CF3 X CF3 O S N O [T2624] [T3014] O0367 O F S CF2 C OCH3 S N O CF3 T2764 CH3 CH3 T3014 CH2CH3 CH3CH2 Si CF3 CH2CH3 CF3 O P2172 O O I O BF4 [O0367] F0311 CF3 I CF3 N BF4 Cu N CF3 O O CF3SO2Na Zn(SO2CF3)2 Langlois reagent Baran reagent [T2033] [Z0028] T1336 T2033 O CF3 PPh3 T2624 I CF3 T1570 I O CH3 CH3 CF3SO2Na ONa T2883 CH3 CH3 Si CF3 P Cu CF3 CH3 23 Z0028 O CF3 S O Zn2 2H2O F0311 O0367 P2172 T1336 T2033 T2764 T3014 T2624 T1570 T2883 Z0028 Methyl Difluoro(fluorosulfonyl)acetate [(Oxido)phenyl(trifluoromethyl)- 4-sulfanylidene]dimethylammonium Tetrafluoroborate (1,10-Phenanthroline)(trifluoromethyl)(triphenylphosphine)copper(I) Sodium Trifluoroacetate Sodium Trifluoromethanesulfinate Triethyl(trifluoromethyl)silane 1-Trifluoromethyl-1,2-benziodoxol-3(1H)-one (contains 60% Diatomaceous earth) 1-Trifluoromethyl-3,3-dimethyl-1,2-benziodoxole (Trifluoromethyl)trimethylsilane (Trifluoromethyl)tris(triphenylphosphine)copper(I) Zinc(II) Bis(trifluoromethanesulfinate) Dihydrate 1984 1989 2009 2008 2006 2007 2008 2008 2011 1991 2011 2012 2012 24 5g 200mg 1g 25g 100g 5g 1g 1g 1g 5g 1g 1g 25g 1g 5g 500g 25g 5g 5g 5g 25g 5g 5g 3 O O CH3 Ph N N SCF3 SCF3 P2143 CF3 M2595 I SCF3 T3143 O CH3 S C C O Nu CuCl, base dioxane, r.t [T3143] C1159 O IPh [P2143] NuH O [M2595] SO2CF3 Ph N O SCF3 N SCF3 CF3SCu O P2143 C1159 M2595 T3143 Benzoyl(phenyliodonio)(trifluoromethanesulfonyl)methanide Copper(I) Trifluoromethanethiolate N-Methyl-N-(trifluoromethylthio)aniline N-(Trifluoromethylthio)phthalimide 1g 1g 200mg 1g 5g 5g 1g 5g 2012 2012 2012 2009 2013 2013 2014 25 Vilsmeier-Haack Reaction Formylating Reagent R CHO H Duff Reaction N R Cl Rieche Reaction N CH3 Cl N CH3 [C1545] (also applicable to some electron-rich alkenes) N Cl N Cl OMe [H0093] [D1645] (under acidic condition) (with Lewis acid) Formylating Reagents H (1) formylating reagent R M R CHO N H3C N CHO (2) H2O EtO OHC H3C M = Li, Mg etc O CF3 TFEF [D0722] [T2586] [E0495] formylating reagents R OH R1 NH R2 formylating reagent (base) R OCHO O R1 NCHO R2 S O N CHO O [F0854] N NC O CHO CHO [F0356] formylating reagents 26 N N [B3920] B3920 C1545 F0356 D1645 D2344 N N N H C H CH3 C N Cl CH3 Cl O Cl O H CN Cl CH3CH2 OCH3 CH3CH2 O O N C N CH OCH3 O O0187 D0722 F0053 O OCH2CH3 CH3 H C OPh OCH2CH3 F0513 D4143 N O2N H CH3 F0157 Cl N E0495 O NO2 F0234 O H F0854 G0393 O O C H O N N H OH S C H O O O H0093 M0552 N CH OCH2CH3 CH3 M1187 N O P0018 CH3 O C H CH3 N CH3 N N Cl CH3 O0066 O N N N O CH3 N C H N N N C H CH3 T2586 O0068 OCH2CH3 (CH2O)n H C OCH2CH3 OCH2CH3 T3141 N OCH3 O H B3920 C1545 F0356 D1645 D2344 O0187 D0722 D4143 F0053 E0495 F0513 F0157 F0234 F0854 G0393 H0093 M0552 M1187 P0018 O0066 T2586 O0068 T3141 O CF3 H C OCH3 N N N OCH3 1H-Benzotriazole-1-carboxaldehyde (Chloromethylene)dimethyliminium Chloride Cyanomethyl Formate Dichloromethyl Methyl Ether N-(Diethylcarbamoyl)-N-methoxyformamide Diethyl Phenyl Orthoformate N,N-Dimethylformamide 1-(2,4-Dinitrophenyl)pyridinium Chloride Ethyl Formate Ethyl N-Phenylformimidate Formic Acid 4-Formylmorpholine 1-Formylpiperidine N-Formylsaccharin Gold s Reagent Hexamethylenetetramine N-Methylformanilide N-Methyl-N-(2-pyridyl)formamide Paraformaldehyde Triethyl Orthoformate 2,2,2-Trifluoroethyl Formate Trimethyl Orthoformate Tris(1H-benzotriazol-1-yl)methane N N N N N 1g 25g 5g 25g 5g 25mL 100mL 25mL 5g 25g 25mL 100mL 5g 5g 25g 25g 1g 25g 25mL 25mL 200mg 5g 250g 25g 250g 1g 25g 500mL 1g 500mL 25g 300mL 500g 500mL 25g 25g 500g 500g 5g 500g 500mL 5g 500mL 1g 27 1973 1958 1997 1981 1996 2003 2001 2012 1932 1934 1941 1945 1960 1941 1941 1999 2011 1993 2011 1999 2012 1992 1978 O 2N N H SiMe3 Cl NO2 N Zincke's salt (1) [D4143] N SiMe3 1M NaOH aq N H N H CHO Y 67% N SiMe3 H N H KOt-Bu THF, 80 °C N H H NH CHO Y 84% Norfluorocurarine 1905 2012 2009 28 CHO Pd-catalyzed Cross-coupling Cyanation Using Boronic Acids CH2SCN R B(OH)2 + 1) Pd(PPh3)4 (cat.) CuTC R CN Dioxane [T0198] CuTC = CO2Cu S Pd-catalyzed Cyanation of Aryl Halides X R 2) O + H3C Pd(OAc)2 (cat.) CN O CN DPPE, TMEDA, DMF R [C0441] X = Cl, Br, I Pd-catalyzed C-H Cyanation CH3 Ar H + H3C NC 3) Pd(OAc)2 (cat.) Cu(TFA)2 Ar CN CH3 [B1274] H Ar H : R1 R3 N R N R2 H Pd-catalyzed Cyanation of Alkenyl Halides 4) R2 X R1 R3 X = Cl, Br, I CH3 + HO CN CH3 [M0361] Pd2(dba)3 (cat.) DPPP, Na2CO3 Et2O/DMA R2 CN R1 R3 29 M0361 T0198 B1274 CH2SCN CH3 C0441 O P1613 T1046 NC T0990 CH3 O O NC P OCH2CH3 O CH3 KCN CH3 S CH2NC O Acetone Cyanohydrin Benzyl Thiocyanate tert-Butyl Isocyanide 2-Chlorobenzyl Thiocyanate Copper(I) Cyanide Diethyl Cyanophosphonate Ethyl Cyanoacetate Potassium Cyanide p-Toluenesulfonylmethyl Isocyanide Trimethylsilyl Cyanide CH3 Si CN CH3 25mL 500mL 25g 500g 5mL 25mL 1g 5g 25g 300g 5g 25g 25g 500g 25g 5g 25g 25mL 100mL 500mL 2006 2012 2012 2014 30 CuCN CH3 C1242 M0361 T0198 B1274 C3003 C1952 C1242 C0441 P1613 T1046 T0990 Cl CH3 C NC CH3 C1952 CH2SCN CH3 HO C CN OCH2CH3 C3003 2 1 O O t-BuO C NaOH aq / MeOH NH , KOH MeO C O [I0510] R CH2Br R CH2N O R CH2N CF3CO2H R CH2N H C OMe 6 8 RS - R1 SO2NHY a) NO2 SO2NHR1 NO2 NO2 c) R2X, K2CO3, DMF or R2OH, DEAD, PPh3 b) When 5a Pd(PPh3)4, pyrrolidine 5b TFA 5c BCl3 9 Me R MgBr Me O Me S O N C Me O Me [A1441] , MgCl2 (cat.) A1632 O CH3 R N C A1137 SO2NH C OCH2CH NO2 R1NHR2 Y = Alloc 5a [A1632] a) R1X, K CO , DMF Boc 5b [B2303] or Cbz 5c [C1757] R OH, DEAD, PPh3 O CH3 i) c) ii) RS - S O N C R1NH2 N Y O2S b) R1NHY b) CH3 5 CH3 C OMe O CH3 O H C Ot-Bu O A1441 C Ot-Bu CH2 Hydrolysis Me Me A2457 N R NH2 A1341 N N N N NH2 CH3 CH3 N3 S CH2N3 PF6 31 B3380 B2303 B1648 Br O SO2NH CH3 C C NH2 B2857 I0510 O O SO2NH C OtBu C OtBu O CH3 H P O N C O C CH3 O O NO2 CH3O CH3 CH3 O CH3O C NH C OtBu CH3 C1757 I0497 B1734 D2361 D1899 O SO2NH C OCH2 NO2 tBuO D1672 O O O C NH C OtBu M1182 P O O H0258 OCH2CH3 N CH3 N H2N OH N P1235 M0886 M0343 O CH3ONH2 N H OCH3 HCl HCl H2N OH O H2SO4 O O N H D2479 H C N N HCl H0196 P0403 O O H2N O S OH CH3 OCH2CH3 OCH2CH3 CH3 H0530 H2N P OCH2CH3 N O S O N C CH3 N3 BuO C NH P OCH2CH3 H0093 CH3 O O O O t NK NNa H C O O T1184 CH3 CH3 Si CH2N3 CH3 A1441 A1632 A1137 A2457 A1341 B3380 B2303 B1648 B2857 I0510 C1757 I0497 B1734 D2361 D1899 D1672 M1182 H0093 H0258 H0196 H0530 M0886 M0343 P1235 32 Acetoxime O-(2,4,6-Trimethylphenylsulfonate) N-Allyloxycarbonyl-2-nitrobenzenesulfonamide 4-Amino-1,2,4-triazole 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate Azidomethyl Phenyl Sulfide 2-Bromoisobutyramide N-(tert-Butoxycarbonyl)-2-nitrobenzenesulfonamide N-(tert-Butoxycarbonyl)-p-toluenesulfonamide tert-Butyl [Bis(4-methoxyphenyl)phosphinyloxy]carbamate tert-Butyl Methyl Iminodicarboxylate N-Carbobenzoxy-2-nitrobenzenesulfonamide Di-tert-butyl Iminodicarboxylate Diethyl N-(tert-Butoxycarbonyl)phosphoramidate Diethyl Phosphoramidate N,O-Dimethylhydroxylamine Hydrochloride Diphenylphosphoryl Azide Ethyl O-Mesitylsulfonylacetohydroxamate Hexamethylenetetramine Hydroxylamine Hydrochloride Hydroxylamine Sulfate Hydroxylamine-O-sulfonic Acid O-Methylhydroxylamine Hydrochloride (ca 40% in Water, ca 5.4mol/L) O-Methylhydroxylamine Hydrochloride Phthalimide DBU Salt 5g 25g 1g 5g 5g 10g 1g 5g 5g 25g 5g 1g 25g 25g 100g 25g 5g 25g 25g 25g 100g 25mL 100g 25g 5g 250g 5g 5g 25g 25g 25g 5g 5g 25g 25g 5g 25g 500g 250g 25g 500g 500g 500g 500g 500mL 500g 25g P0403 D2479 T1184 Phthalimide Potassium Salt Sodium Diformylamide Trimethylsilylmethyl Azide 25g 1g 1887 500g 25g 5g 1968 1991 1977 1978 1993 1999 2002 1989 33 O O H EtO C N O EtO C N N C OEt OH R1 R3 HO + O H N C OEt R2 O R2 R3 O R1 O O PPh3 PPh3 O R R R O O N H O O R1 R2 EWG R1 R2 OH O EWG O R1 R EWG EWG OH R1 R2 HO CN R1 CN OH R1 R1 R O R R R2 R Ns N R1 X S R1 R2 Ns SH O R2 N H O N3 DPPA R2 N R2 R1 O R2 R2 O N C N N C N O O ADDP [A1051] EtO C N N C OEt DEAD [A0705] O Easy to remove because of high-polarity molecule O N C N N C N TMAD [A1458] 34 Ph P Ph triphenylphosphine [T0519] Ph Ph P N Ph P N Ph [D2471] Ph Separable by extraction Ph [P1843] Separable by filtration O CN O P Ph [D2766] [D2478] Bu3P Ph P O EtO [C1500] OEt NC SO2Ph pKa = 12.0 pKa = 13.3 A1458 A1332 A0776 O O Cl3CH2CO C N N C OCH2CCl3 O O B3364 NMe2 O N C N N C N A0705 O t SO2Tol pKa = 23.4 O O C N N C D3544 BnO C N N C OBn MeS A1051 O Me2N Applicable to tertiary alcohols O BuO C N N C OtBu O O CH3OCH2CH2O C N N C OCH2CH2OCH3 A1246 O O EtO C N N C OEt O iPrO O C N N C OiPr A0882 O O MeO C N N C OMe 35 1,1 -Azobis(N,N-dimethylformamide) 1,1 -(Azodicarbonyl)dipiperidine Bis(2-methoxyethyl) Azodicarboxylate Bis(2,2,2-trichloroethyl) Azodicarboxylate Dibenzyl Azodicarboxylate (40% in Dichloromethane, ca 1.7mol/L) Di-tert-butyl Azodicarboxylate (20% in Toluene) Diethyl Azodicarboxylate (40% in Toluene, ca 2.2mol/L) Diisopropyl Azodicarboxylate (40% in Toluene, ca 1.9mol/L) Dimethyl Azodicarboxylate (40% in Toluene, ca 2.7mol/L) A1458 A1051 B3364 A1332 A0776 D3544 A0705 A1246 A0882 D2411 1g 5g 25g 25g D1019 5g 25g 5g 5g 25g 25g 250g 250g 25g 100g 100g D2478 Et (CH3)2N P P P Et D2766 D2471 CH2 P I0583 P P CH3 T1165 Bu T1005 CH3(CH2)5 P Bu D2411 D1019 D2478 D2766 D2471 I0583 P1843 T1912 T0361 T1165 T1005 T0503 T0519 (CH2)5CH3 t Bu P T0519 (CH2)7CH3 CH3(CH2)7 P P (CH2)7CH3 Dicyclohexylphenylphosphine 1g 5g Diethylphenylphosphine 1mL 5mL 4-(Dimethylamino)phenyldiphenylphosphine 1g 5g 4-Diphenylphosphinomethyl Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (0.5-1.0mmol/g) 5g Diphenyl-2-pyridylphosphine 1g 5g Isopropyldiphenylphosphine 1g 5g Phenoxydiphenylphosphine 5g 25g 5g Tri-tert-butylphosphine Tributylphosphine 25mL 100mL 500mL 25mL Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca 18% in Toluene, ca 0.60mol/L) Trihexylphosphine 25mL Tri-n-octylphosphine 25mL 100mL 500mL Triphenylphosphine 25g 500g C1500 Bu Bu P CH CN Bu 36 O P T0503 (CH2)5CH3 P P P tBu Bu Bu T1912 t CH CH3 N T0361 P1843 C1500 Cyanomethylenetributylphosphorane 1g 5g 25g 1981 1999 1993 1994 1994 1995 1989 1998 1983 2010 1995 2000 2006 2013 37 NO2 O O NO2 O Me Me O R1 OH + (1.0 eq.) NO2 O O [M1439] (1.1 eq.) R2OH R1 Et3N (1.1 eq.), DMAP (0.1 eq.), rt OR2 + OR2 Me (1.1 eq.) Ester A R1COOH Ester B R2OH PhCH2 THPO(CH2)5 CH2=CHCH2 C9H19C(CH3)2 Ph(CH2)2 Ph(CH2)2 Ph(CH2)2 Ph(CH2)2 Y % Ester A / Ester B 95 98 92 94 >200 >200 >200 >200 1 A1797 A1861 B3816 B1774 N N N N N N O C N(CH3)2 PF6 N N O C N(CH3)2 B1657 BF4 N N N N N(CH3)2 PF6 N N O C N O N N(CH3)2 B2771 N N(CH3)2 N O C N N(CH3)2 B1658 O C 38 N N B1651 N PF6 PF6 N N N OP[N(CH3)2]3 B1213 N(CH3)2 N(CH3)2 BF4 CH3 O O O CH2 N C N CH2 O CH3 O B3604 F N P N CH3 O PF6 N O CH3 N P N Cl O O F F F F F O F O C O F F F B3817 B3927 O N N C O N B0832 CH3 O Cl C1988 N C1131 N N N Cl O O O N(CH3)2 C0903 O N N Cl N Cl N CH3 O C0906 N N C N O CH3 N CH2O C O N BF4 O CH3 C1651 O N(CH3)2 N N C C1639 C1408 Cl O C N(CH3)2 C0905 O O N O N PF6 C0119 N O CH3 N N(CH3)2 CH2O C O N O C O C CH3 C1926 O C CH3 O CH3 Cl N C1362 O O PF6 N P Br BF4 Br CH2CH3 O Cl C CH3 ClO4 N N C1124 CH3 CH3 Cl O CH2O C O N CH3 CH3 C1574 N B2680 O N CH3 CH3 O B1036 Br B(OH)2 CH3 CH3 CH3 CH3 N PF6 C1298 CH3 PF6 Cl CH3 C1379 C1375 SO3 CH2CH3 N BF4 O Cl N I N CH3 C1957 CH3 N Cl CH3 CH3 N N PF6 CH3CH2O C N P Cl NC PF6 C N O C D0436 N C N O N N D1393 Bu N C1242 O Bu N(CH3)2 O P Bu D0254 N CH3 OH N N N D3293 C N SO3 O O OCH2CH3 N CH2CH2N D3263 NC P OCH2CH3 OCH2CH3 N O D2039 O OCH2CH3 CH3 P CH CN PF6 D3262 BF4 C0793 O N Cl N Cl C1500 O CH3 C CH3 C2733 N N PF6 Cl CH3 C2551 N C Cl N D2919 O C N N(CH3)2 N(CH3)2 BF4 D4029 OCH3 CH3 N O N C N CH3 N SO3 CH3 CH3 F NH2 CH3 CH3 CH3 F N F F CH3O N N N CH3 CH3CH2 N C N (CH2)3N Cl F CH3 CH3 O D1601 CH3CH2 N C N D1450 (CH2)3N CH3 D2898 N CH3 HCl D2899 SO3 CH3 CH3 N N N D1771 CH3 CH3 N C N CH2OH H CH2 N CH3 CH3 N C CH2OH H CH2 CH3 N H CH3 CH3 39 D3683 D2038 D1720 D1672 D2201 O O O NH2 CF3SO3 N C N P O O O O O N3 S S O OCH3 C1407 D1114 O P O D2477 T1906 O D1662 O O O O N N O C O N N S S S S S N N N O C O N O C O N N O D2222 E0916 O2 N NO2 N S S E0363 E0847 C N O C N(CH3)2 N N(CH3)2 NC OCH2CH3 C OCH2CH3 BF4 F0726 N CH3 F H0468 CH3 CH3 N N CH3 PF6 O O OH N O OH M1439 NOH N OH O M0071 M0670 SO2Cl CH3 CH3 SO2Cl CH3 N CH3 O CH3 N CH3 CH3 SO2Cl M1116 O O M1186 SO3Na N H2O OH H1304 O H0395 O N N CH2O C O N CH3 O N CH3 B0249 H0623 O H0528 F CH3 O NOH O SO3 O O NC F0225 F0239 O CH3CH2O C N O T0681 N0477 N0634 O NO2 O O NO2 O C CF3 CH3 O N O Me Me N H N O NO2 N N O CH3 N CH3 N O C N CH3 BF4 CH3 NO2 O0200 O0390 T0648 P1626 P2231 O N O O BF4 N O N C C N N O C O C CCl3 Cl Cl Cl Cl F O CH3SO3 P O OSO2CH3 40 P1768 P1320 P1319 SO2CH3 n O CH2CH2CH3 P O CH3CH2CH2 O P P O CH2CH2CH3 O F P0939 O O O2N N Q0016 SO2Cl N F F F S O N N F O N C O C O F O F Cl P1042 F CF3SO3 N(CH3)2 N(CH3)2 NH3 F S0836 T1562 T2908 SO2Cl SO3Na F CH3 F T2929 B(OH)2 CH3 CH3 CH3 N F CH3 F CH3 OH T1017 T1985 O O N O C CH3 CH3 SO2Cl T2224 N(CH3)2 N(CH3)2 N O C T1413 N N N H N N SO2 N H CH3 Cl N Cl Cl Cl Cl Cl T1593 T0459 CH3 O CF3 CH3 O C O C T1122 SO2Cl CH CH CH3 SO3 CH3 CH3 CF3 CH CH3 CH3 CH3 N H CH3 CH3 A1797 A1861 B3816 B1774 B1651 B1657 B1658 B2771 B1213 B3604 B3817 B3927 O-(7-Azabenzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Hexafluorophosphate O-(7-Azabenzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Tetrafluoroborate O-(Benzotriazol-1-yl)-N,N,N ,N -bis(pentamethylene)uronium Hexafluorophosphate 1H-Benzotriazol-1-yloxytripyrrolidinophosphonium Hexafluorophosphate 1H-Benzotriazol-1-yloxytris(dimethylamino)-phosphonium Hexafluorophosphate 5g O-(Benzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Hexafluorophosphate 5g O-(Benzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Tetrafluoroborate 1,3-Bis(2,2-dimethyl-1,3-dioxolan-4-ylmethyl)carbodiimide (This product is only available in Japan.) Bis(2-oxo-3-oxazolidinyl)phosphinic Chloride Bis(pentafluorophenyl) Carbonate N,N,N ,N -Bis(tetramethylene)-O-(N-succinimidyl)uronium Hexafluorophosphate 2,6-Bis[(2,2,6,6-tetramethyl-1-piperidinyl)methyl]phenylboronic Acid (contains varying amounts of C1298 B1036 B2680 B0832 C1574 C1124 C1362 C0119 C1988 C1926 C1131 C1639 C1408 C1651 C0905 C0903 C0906 C1379 C1375 C1957 C2551 C2733 N-(2-Bromobenzyloxycarbonyloxy)succinimide 2-Bromo-1-ethylpyridinium Tetrafluoroborate Bromotripyrrolidinophosphonium Hexafluorophosphate N-tert-Butyl-5-methylisoxazolium Perchlorate tert-Butyl 2,4,5-Trichlorophenyl Carbonate N-Carbobenzoxyoxysuccinimide 2,2 -Carbonylbis(3,5-dioxo-4-methyl-1,2,4-oxadiazolidine) 1,1 -Carbonyldiimidazole O-(6-Chlorobenzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Hexafluorophosphate O-(6-Chlorobenzotriazol-1-yl)-N,N,N ,N -tetramethyluronium Tetrafluoroborate N-(2-Chlorobenzyloxycarbonyloxy)succinimide 2-Chloro-1,3-dimethylimidazolinium Chloride (ca 25% in Dichloromethane) 2-Chloro-1,3-dimethylimidazolinium Chloride 2-Chloro-1,3-dimethylimidazolinium Hexafluorophosphate 2-Chloro-3-ethylbenzoxazolium Tetrafluoroborate 2-Chloro-1-methylpyridinium Iodide 2-Chloro-1-methylpyridinium p-Toluenesulfonate 1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium Hexafluorophosphate 1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium Tetrafluoroborate Chloro-N,N,N ,N -tetramethylformamidinium Hexafluorophosphate Chlorotripyrrolidinophosphonium Hexafluorophosphate (1-Cyano-2-ethoxy-2-oxoethylidenaminooxy)dimethylaminomorpholinocarbenium Hexafluorophosphate (This product is only available in Japan.) Cyanomethylenetributylphosphorane 1-Cyclohexyl-3-(2-morpholinoethyl)carbodiimide Metho-p-toluenesulfonate N,N -Dicyclohexylcarbodiimide 3-(Diethoxyphosphoryloxy)-1,2,3-benzotriazin-4(3H)-one Diethyl Cyanophosphonate 3,4-Dihydro-3-hydroxy-4-oxo-1,2,3-benzotriazine C1500 C0793 D0436 D3262 C1242 D2039 BF4 OH C Cl N N(CH3)2 T0389 O N N(CH3)2 O O T0340 PF6 Anhydride) 5g 1g 1g 5g 25g 25g 5g 5g 1g 200mg 5g 5g 1g 25g 25g 1g 5g 5g 5g 5g 5g 1g 5g 1g 5g 5g 25g 5g 10g 25g 5g 5g 25g 100g 100g 25g 1g 25g 5g 5g 1g 10g 25g 25g 5g 5g 250g 5g 250g 5g 25g 10g 25g 25g 25g 25g 25g 25g 25g 5g 5g 25g 5g 25g 25g 400g 5g 25g 25g 41 D3263 D1393 D0254 D3293 D2919 D4029 D1601 D1450 D2898 D2899 D1771 D3683 D2038 D1720 D1672 D2201 C1407 D1114 D2477 T1906 D1662 D2222 E0916 E0363 E0847 F0239 F0225 F0726 H0468 H0528 H0395 B0249 H0623 H1304 M1186 M0071 M0670 M1439 M1116 T0681 N0477 N0634 O0200 O0390 T0648 P1626 P2231 P1042 P1320 P1319 P1768 P0939 Q0016 S0836 T1562 T2908 T2929 T2224 T1017 T1985 T0340 T1413 T0389 T1593 T0459 T1122 42 O-(3,4-Dihydro-4-oxo-1,2,3-benzotriazin-3-yl)-N,N,N ,N -tetramethyluronium Tetrafluoroborate 5g 25g 5g 25g 3,4-Dihydro-2H-pyrido[1,2-a]pyrimidin-2-one N,N -Diisopropylcarbodiimide 25g 250g Dimesitylammonium Pentafluorobenzenesulfonate 1g 5g 4-(4,6-Dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium Chloride 5g 25g 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide 5g 25g 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide Hydrochloride 5g 25g 250g 4-Dimethylaminopyridine 25g 100g 500g 100mg (4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine (4S,5S)-1,3-Dimethyl-4,5-diphenyl-2-[(R)-1-benzyl-2-hydroxyethylimino]imidazolidine 100mg 2,6-Dimethylpyridinium p-Toluenesulfonate 25g Diphenylammonium Trifluoromethanesulfonate 1g 5g 25g Diphenyl (2,3-Dihydro-2-thioxo-3-benzoxazolyl)phosphonate 5g 25g N,N-Diphenyl-4-methoxybenzamide 5g Diphenylphosphoryl Azide 5g 25g 250g 4,6-Diphenylthieno[3,4-d]-1,3-dioxol-2-one 5,5-Dioxide 5g Di-2-pyridyl Carbonate 5g 2,2 -Dipyridyl Disulfide 5g 25g 250g 4,4 -Dipyridyl Disulfide 5g 25g O,O -Di-2-pyridyl Thiocarbonate 1g 5g 25g Di(N-succinimidyl) Carbonate 2,2 -Dithiobis(5-nitropyridine) 5g O-[(Ethoxycarbonyl)cyanomethyleneamino]-N,N,N ,N -tetramethyluronium Tetrafluoroborate 1g 5g 1-Ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline 25g Ethyl Cyano(hydroxyimino)acetate 25g N-[(9H-Fluoren-9-ylmethoxy)carbonyloxy]succinimide 5g 25g 5g 25g 2-Fluoro-1-methylpyridinium p-Toluenesulfonate 1g 5g Fluoro-N,N,N ,N -tetramethylformamidinium Hexafluorophosphate 25g 200g 500g 1-Hydroxybenzotriazole Monohydrate N-Hydroxy-5-norbornene-2,3-dicarboximide 25g 250g N-Hydroxyphthalimide 25g 100g 500g N-Hydroxysuccinimide 25g N-Hydroxysuccinimide 25g 100g 500g N-Hydroxysulfosuccinimide Sodium Salt 200mg 1g 2,4-Mesitylenedisulfonyl Dichloride 5g 25g 2-Mesitylenesulfonyl Chloride 25g 500g 9-Methyl-3,4-dihydro-2H-pyrido[1,2-a]pyrimidin-2-one 25g 2-Methyl-6-nitrobenzoic Anhydride 1g 5g 25g 5g 6-Methyl-2H-pyrido[1,2-a]pyrimidin-2-one 4-Nitrophenyl Trifluoroacetate 5g 25g 3-Nitro-1,2,4-triazole 5g 2-(5-Norbornene-2,3-dicarboximido)-1,1,3,3-tetramethyluronium Tetrafluoroborate 5g 25g 1,1 -Oxalyldiimidazole 1g 5g O-[2-Oxo-1(2H)-pyridyl]-N,N,N ,N -tetramethyluronium Tetrafluoroborate 1g 5g Pentachlorophenyl Trichloroacetate 25g Pentafluoroanilinium Trifluoromethanesulfonate 1g 5g 25g Pentafluorophenyl 4-Nitrobenzenesulfonate 1g 5g Phosphorus Pentoxide - Methanesulfonic Acid 25g 500g 25g Propylphosphonic Acid Anhydride (Cyclic Trimer) (48% in N,N-Dimethylformamide, ca 1.6mol/L) 25g 100g Propylphosphonic Acid Anhydride (Cyclic Trimer) (50% in Ethyl Acetate, ca 1.7mol/L) 3-Pyridinecarboxylic Anhydride 1g 5g 4-Pyrrolidinopyridine 5g 25g Quinoline-8-sulfonyl Chloride 5g 25g Sodium 2,3,5,6-Tetrafluoro-4-hydroxybenzenesulfonate 1g 5g 2,4,5,6-Tetramethylbenzenedisulfonyl Dichloride 5g 1g 2-[(2,2,6,6-Tetramethyl-1-piperidyl)methyl]phenylboronic Acid (contains varying amounts of Anhydride) N,N,N ,N -Tetramethyl-O-(N-succinimidyl)uronium Hexafluorophosphate 5g 25g N,N,N ,N -Tetramethyl-O-(N-succinimidyl)uronium Tetrafluoroborate 1g 5g 1H-Tetrazole 5g 25g 1-(p-Toluenesulfonyl)imidazole 5g 25g 1,2,4-Triazole 25g 100g 500g 2,4,6-Trichlorobenzoyl Chloride 5g 25g 2,4,5-Trichlorophenol 25g 500g 4-Trifluoromethylbenzoic Anhydride 10g 2,4,6-Triisopropylbenzenesulfonyl Chloride 25g 500g 25g 2,4,6-Trimethylpyridinium p-Toluenesulfonate 2002 2002 2003 2004 2004 2007 2003 43 O R1 R3 Olefinating Reagent R1 R2 Aldehyde, Ketone Wittig Reaction Horner-Emmons Reaction R3 R4 Peterson Reaction R3 R4 PR3 R4 R2 Julia Reaction R3 R4 POR2 R3 SiR3 R4 / (Na/Hg) SO2Ar Reagents for carbonyl olefination Tebbe Reagent / Petasis Reagent O R1 R1 Cp2Ti=CH2 R2 R2 Aldehyde, Ketone Ester, Lactone, Thiolester, Amide Tebbe Reagent : Ti CH2 Cl Al CH3 CH3 Petasis Reagent : [C1411] CH3 Ti CH3 [D4100] Titanium-mediated Methylenating Reagents A1305 A1439 A1007 O O P CH2 C CH3 Cl 44 P CH C CH3 P CH2CH CH2 Br A1012 A0862 P CH2CH CH2 B2025 P B0824 (CH2)4CH3 Cl P CH2 B1206 B3928 B0970 O P CH2CH2CH2Br C1061 P P (CH2)3CH3 (CH2)4 C OH C1739 CH2 P Br Br Br C1286 Cl O P CH2 C O C CH3 Br C1759 CH3 CH3 C1009 Br Cl Br B1208 P CH2Br P CH2 Br Cl C1378 D2907 Cl P CH2Cl Cl P CH2CH P CH CH2CN P Cl P CH2 Br Cl Br D4072 Cl D1654 D1655 D2056 OCH3 P CH2 P CH2CH2N OCH3 Br O O CH3 P CH2CH2 P CH2CH2 CH3 E0382 E0549 T1944 O P CH2 Br C1641 O P CH2CH3 P CH2 C OCH2CH3 OCH2CH3 Br O Br Br E0407 O P CH2 O O Br E0421 D2164 P CH2CH3 I Br P CH C OCH2CH3 Br F0331 H0545 H0540 H1240 HO O O P C C OCH2CH3 P CH2 P C H CH3 (CH2)6CH3 Br P (CH2)5CH3 Br P CH2 Cl I0552 Br M1326 M0828 M0779 M0253 O P CH(CH3)2 I P CH2 C OCH3 P CH2OCH3 Br T1363 P CH3 N0700 N0701 P1182 C OCH3 O P CH2 I T2718 O P CH P CH3 Br Cl Cl P CH2 NO2 Br P CH2 O C O (CH2)3CH3 CH2 P (CH2)3CH3 Br (CH2)3CH3 Br 45 T1458 T1510 T1498 CH3 CH3 CH3 C H P CHCN CH3 CH3 T2565 O P CH P CH2C C Si CH3 Br I T2002 T1958 CH3 P CH2CH2 Si CH3 P CH2OCH2CH2 Si CH3 Cl T2001 P1438 P1200 T1506 O P CH P C C O C P CH2 C CH P CH2CH2CH3 Br P (CH2)13CH3 Br Br T1644 P CH CH2 Br A1305 A1439 A1007 A1012 A0862 B2025 B0824 B1206 B1208 B3928 B0970 C1061 C1759 C1009 C1286 C1739 C1378 D2907 D4072 D1654 D1655 D2056 D2164 E0421 E0407 E0382 E0549 T1944 C1641 F0331 H0545 H0540 H1240 I0552 M1326 M0828 M0779 M0253 T1363 N0700 46 Acetonyltriphenylphosphonium Chloride (Acetylmethylene)triphenylphosphorane Allyltriphenylphosphonium Bromide Allyltriphenylphosphonium Chloride Amyltriphenylphosphonium Bromide Benzyltriphenylphosphonium Bromide Benzyltriphenylphosphonium Chloride (Bromomethyl)triphenylphosphonium Bromide 3-Bromopropyltriphenylphosphonium Bromide (tert-Butoxycarbonylmethyl)triphenylphosphonium Bromide Butyltriphenylphosphonium Bromide 4-(Carboxybutyl)triphenylphosphonium Bromide (2-Chlorobenzyl)triphenylphosphonium Chloride (Chloromethyl)triphenylphosphonium Chloride Cinnamyltriphenylphosphonium Bromide (Cyanomethyl)triphenylphosphonium Chloride Cyclopropyltriphenylphosphonium Bromide (2,4-Dichlorobenzyl)triphenylphosphonium Chloride (3,4-Dimethoxybenzyl)triphenylphosphonium Bromide 2-Dimethylaminoethyltriphenylphosphonium Bromide 2-(1,3-Dioxan-2-yl)ethyltriphenylphosphonium Bromide 2-(1,3-Dioxolan-2-yl)ethyltriphenylphosphonium Bromide (1,3-Dioxolan-2-yl)methyltriphenylphosphonium Bromide 4-Ethoxybenzyltriphenylphosphonium Bromide Ethoxycarbonylmethyl(triphenyl)phosphonium Bromide Ethyltriphenylphosphonium Bromide Ethyltriphenylphosphonium Iodide Ethyl (Triphenylphosphoranylidene)acetate Ethyl 2-(Triphenylphosphoranylidene)propionate (Formylmethyl)triphenylphosphonium Chloride Heptyltriphenylphosphonium Bromide Hexyltriphenylphosphonium Bromide (2-Hydroxybenzyl)triphenylphosphonium Bromide Isopropyltriphenylphosphonium Iodide Methoxycarbonylmethyl(triphenyl)phosphonium Bromide (Methoxymethyl)triphenylphosphonium Chloride Methyltriphenylphosphonium Bromide Methyltriphenylphosphonium Iodide Methyl (Triphenylphosphoranylidene)acetate (1-Naphthylmethyl)triphenylphosphonium Chloride 25g 25g 5g 25g 25g 5g 25g 5g 5g 5g 5g 25g 25g 25g 25g 25g 25g 5g 5g 25g 25g 25g 100g 100g 100g 25g 5g 25g 25g 25g 25g 25g 250g 500g 25g 25g 25g 250g 250g 25g 25g 25g 100g 5g 25g 5g 25g 25g 25g 25g 5g 250g 500g 250g 250g 5g 25g 500g 500g 25g 25g 25g 500g 500g 500g 100g 25g N0701 P1182 T2718 T1458 T1510 T1498 T2001 T1958 T2002 T2565 P1438 P1200 T1506 T1644 (4-Nitrobenzyl)triphenylphosphonium Bromide Phenacyltriphenylphosphonium Bromide Tributyl(1,3-dioxolan-2-ylmethyl)phosphonium Bromide 2-(Trimethylsilyl)ethoxymethyltriphenylphosphonium Chloride (2-Trimethylsilylethyl)triphenylphosphonium Iodide (3-Trimethylsilyl-2-propynyl)triphenylphosphonium Bromide (Triphenylphosphoranylidene)acetaldehyde (Triphenylphosphoranylidene)acetonitrile 2-(Triphenylphosphoranylidene)acetophenone (Triphenylphosphoranylidene)ketene Triphenylpropargylphosphonium Bromide Triphenylpropylphosphonium Bromide Triphenyl(tetradecyl)phosphonium Bromide Triphenylvinylphosphonium Bromide B2815 5g 1g 5g 5g 1g 5g 25g B2801 B1714 O OCH2CH3 CH2 P CH3O CH3O OCH2CH3 O O OCH2CH3 O CH3CH2O P CH2 CH2 CH3CH2O O CH3O P OCH2CH3 CH3O OCH2CH3 D3069 B1795 B2814 O OCH3 HN CH2 CHCH2 P OCH2CH3 OCH2CH3 O CH3 P CH2 C O C CH3 CH3O CH3O O O P CH3 B1781 CH2 P O CH3CH2O O OCH3 HN Boc D3688 O O CH3CH2O C OCH3 CF3CH2O C2440 O P O OCH2CH3 O B4011 O CF3CH2O P CH2 P CH2 C OCH2 CH2 P B1923 25g 25g 5g 25g 5g 5g 25g 25g 5g 5g 25g 500g 25g 5g Cbz D4434 OCH2CH3 O OCH2CH3 O CH3CH2O P CH2CH2Br CH3CH2O P CH2 CH3CH2O Br(CH2)3 CH3CH2O P OCH2CH3 OCH2CH3 Br C1595 D3335 D4588 O CH2 P Cl O CH2 P D3323 C1430 OCH2CH3 O OCH2CH3 ClCH2 OCH2CH3 OCH2CH3 O P OCH2CH3 NC CH2 P OCH2CH3 O OCH2CH3 OCH2CH3 CH3CH2O P CH2CN CH3CH2O Cl D2423 D4074 E0483 D3324 D3689 O O OCH2CH3 CH3CH2O P CH2 CH3CH2O S OCH2CH3 S CH2 P O O P OCH2CH3 OCH2CH3 CH3CH2O P CH2CH3 O F CH2 P CH3CH2O OCH2CH3 OCH2CH3 OCH2CH3 OCH2CH3 I D3325 D3326 D4000 O CH3 CH3 O CH CH2 P CH2 P OCH2CH3 D3708 O OCH2CH3 CH2 P OCH2CH3 OCH2CH3 OCH3 OCH2CH3 OCH2CH3 D3873 O CH3 N OCH3 O P OCH2CH3 OCH2CH3 O CH3OCH2 P OCH2CH3 OCH2CH3 OCH3 47 D3327 D3328 O OCH2CH3 CH2 P D3336 O CH2 P OCH2CH3 CH3 OCH2CH3 CH2 P OCH2CH3 O C CH2 P OCH2CH3 P1193 CH3 C CH2 O S N CH2 S OCH3 D3824 CH3CH2O P CH2SCH3 OCH2CH3 CH3CH2O N OCH2CH3 CH2 P OCH2CH3 O0208 OCH3 Cl3C P OCH2CH3 OCH2CH3 D3875 O O O CH3O P CH2 CH3O P CH3 C CH3 Cl Br O CH P O CH3O CH3O D3709 O O OCH2CH3 OCH2CH3 O P OCH3 P OCH3 P M0943 S O O OCH2CH3 D4607 O D3981 S P P1258 P OCH2CH3 OCH2CH3 D3992 O O O O OCH2CH3 OCH2CH3 CH3 D3174 O M1208 OCH2CH3 CH3 CH3 D3339 D3827 O D2547 D2548 M1210 O Cl O O CH3 CH P O D2873 O O P O N O P CH2 OCH3 T1582 CH3 O C OCH2CH3 O O O P CH2 CH3OCH2 P C OCH2CH3 M1319 F0340 D1523 O CH2 O CH3CH2O P CH2 O P OCH2CH3 OCH2CH3 (CH3)2CHO C OCH3 (CH3)2CHO O CH3CH2O CH2 O O P CH2 P OCH(CH3)2 OCH(CH3)2 CH3CH2O CH3CH2O P OCH2CH3 O O P O OCH2CH3 F O CH3CH2O P CH2 C OCH2CH3 CH3CH2O OCH2CH3 T2135 CH3CH2O CH3CH2O D1524 O CH3 O O P CH C OCH2CH3 CH3CH2O P B2815 B2801 B1923 B1714 B4011 B2814 C2440 D3069 B1795 D3688 B1781 D4434 C1595 D3335 48 P1265 CH3CH2O O (CH2)2 C OCH2CH3 O CH3O P CH2 O C OCH3 CH3O Benzyl Dimethylphosphonoacetate 9,10-Bis(diethylphosphonomethyl)anthracene 4,4 -Bis(diethylphosphonomethyl)biphenyl Bis(2,2,2-trifluoroethyl) (Methoxycarbonylmethyl)-phosphonate N-(tert-Butoxycarbonyl)-2-phosphonoglycine Trimethyl Ester tert-Butyl Diethylphosphonoacetate N-Carbobenzoxy-2-phosphonoglycine Trimethyl Ester Diethyl Allylphosphonate Diethyl Benzylphosphonate Diethyl (4-Bromobenzyl)phosphonate Diethyl 2-Bromoethylphosphonate Diethyl (3-Bromopropyl)phosphonate Diethyl (3-Chlorobenzyl)phosphonate Diethyl (4-Chlorobenzyl)phosphonate 1g 1g 1g 1g 5g 1g 1g 1g 1g 5g 5g 1g 1g 5g 5g 5g 5g 25g 5g 5g 5g 5g 25g 25g 25g 5g 5g 25g D4588 D3323 C1430 D2423 D4074 E0483 D3324 D3689 D3325 D3326 D4000 D3708 D3873 D3327 D3328 D3336 D3827 M1208 D3339 D3174 P1193 P1258 D4607 D3992 D3981 M0943 O0208 D3875 D3824 D3709 D2547 D2548 M1210 D2873 T1582 M1319 F0340 D1523 T2135 D1524 P1265 Diethyl (Chloromethyl)phosphonate Diethyl (4-Cyanobenzyl)phosphonate Diethyl Cyanomethylphosphonate Diethyl 2,2-Diethoxyethylphosphonate Diethyl (1,3-Dithian-2-yl)phosphonate Diethyl Ethylphosphonate Diethyl (4-Fluorobenzyl)phosphonate Diethyl (4-Iodobenzyl)phosphonate Diethyl (4-Isopropylbenzyl)phosphonate Diethyl (3-Methoxybenzyl)phosphonate Diethyl (4-Methoxybenzyl)phosphonate Diethyl (N-Methoxy-N-methylcarbamoylmethyl)phosphonate Diethyl (Methoxymethyl)phosphonate Diethyl (2-Methylbenzyl)phosphonate Diethyl (3-Methylbenzyl)phosphonate Diethyl (4-Methylbenzyl)phosphonate Diethyl Methylphosphonate Diethyl (Methylthiomethyl)phosphonate Diethyl (2-Oxo-2-phenylethyl)phosphonate Diethyl (2-Oxopropyl)phosphonate Diethyl (Phthalimidomethyl)phosphonate Diethyl 1-Pyrrolidinemethylphosphonate Diethyl (Trichloromethyl)phosphonate Dimethyl 1,3-Benzodithiol-2-ylphosphonate Dimethyl 2-(1,3-Dithiole)phosphonate Dimethyl Methylphosphonate Dimethyl (2-Oxopropyl)phosphonate Diphenyl 4-Bromo- -chlorobenzylphosphonate Diphenyl -Chlorobenzylphosphonate Diphenyl (N-Methoxy-N-methylcarbamoylmethyl)phosphonate Ethyl Diphenylphosphonoacetate Ethyl Di-o-tolylphosphonoacetate Methoxymethyl(diphenyl)phosphine Oxide Methyl Diethylphosphonoacetate Tetraethyl p-Xylylenediphosphonate Tetraisopropyl Methylenediphosphonate Triethyl 2-Fluoro-2-phosphonoacetate Triethyl Phosphonoacetate Triethyl 2-Phosphonopropionate Triethyl 3-Phosphonopropionate Trimethyl Phosphonoacetate D4100 CH3 Ti 1g 5g 5g 5g 5g 5g 5g 5g 1g 5g 5g 5g 5g 5g 5g 1g 5g 5g 5g 1g 25g 5g 5g 1g 1g 1g 25g 1g 100g 25g 25g C1411 CH3 5g 5g 5g 25g 5g 25g 25g 25g 5g 25g 25g 25g 5g 25g 25g 5g 25g 25g 25g 25g 25g 25g 5g 25g 25g 5g 25g 1g 5g 500g 25g 25g 5g 5g 5g 1g 25g 25g 100g 25g 5g 500g 25g 250g 250g T2052 Ti Cl Al CH3 CH3 TiCl4 T0616 Cl D4100 C1411 T2052 T0616 Ti Cl Dimethyltitanocene (5% in Tetrahydrofuran/Toluene) Tebbe Reagent (ca 0.5mol/L in Toluene) Titanium(IV) Chloride (14% in Dichloromethane, ca 1.0mol/L) Titanocene Dichloride 100g 25mL 100mL 500mL 5g 25g 49 B0041 B1444 B0527 SH SCH2S B0396 D0184 D0192 D1106 D0610 CH3 Cl 50 CH3 Cl CH3 C CH3 Cl CH3 N N CH3 CH3 B0041 B1444 B0527 B0396 D0184 D0192 D1106 D0400 D0610 T0147 T0430 O T0430 CH3 CH3 CH3 D0400 CH3CH2 C CH3 CH2Br2 Br T0147 CH2I2 Cl Br Li CH3 BF3 O CH3 O Benzenethiol Bis(phenylthio)methane Boron Trifluoride - Ethyl Ether Complex Butyllithium (ca 15% in Hexane, ca 1.6mol/L) 1,1-Dibromoethane (stabilized with Copper chip) Dibromomethane 2,2-Dichlorobutane 2,2-Dichloropropane Diiodomethane (stabilized with Copper chip) N,N,N ,N -Tetramethylethylenediamine Triethyl Phosphite P O CH3 25mL 500mL 5g 25g 25mL 100mL 500mL 100mL 500mL 5g 25g 500g 10mL 10mL 25g 100g 500g 25mL 500mL 25mL 500mL ArO ArO R CHO Reagent D2547 D2548 O P CH2CO2Et , Triton ® B D2547 or D2548 R CO2Et o THF, -78 C Ar D2547 Ph D2548 o-Tolyl R Yield (%) Ph 98 93:7 C7H15 100 90:10 Ph 100 96:4 C7H15 97 94:6 n n Ethyl Diphenylphosphonoacetate Ethyl Di-o-tolylphosphonoacetate (Z :E) 1g 5g 1g 1995 1997 2000 51 R X + catalyst M R' or HYR'n R R' or (-M+X- or HX) R R'-M R-MII-R' +X-) (-M Transmetalation R + Reductive elimination Catalyst regeneration Kosugi-Migita-Stille cross-coupling Miyaura-Ishiyama cross-coupling Suzuki-Miyaura cross-coupling M= Pd, Ni L= PR3 etc R-MII-X M(0)Ln R R' Kumada-Tamao-Corriu cross-coupling Hiyama cross-coupling Sonogashira-Hagiwara cross-coupling Negishi cross-coupling X Oxidative addition M(0)Ln YR'n catalyst = Pd, Ni, Cu, Fe etc R = Ar, alkenyl, Het X = I, Br, OTf, Cl etc M = Mg, Zn, Sn, B, Si etc Y = N, O, P, S etc M(0)Ln RnY-H + Ar-MII-Nu R Nu Base (-HX) Reductive elimination Nucleophilic substitution Buchwald-Hartwig cross-coupling Y= N, O, P, S etc Catalyst regeneration Tsuji-Trost allylation H H R' R' R Insertion MIIX β-Hydride elimination R' R O Insertion 52 R R'-M or Nu-H II M X H-MII-X Reductive elimination Mizoroki-Heck reaction CO + O R R' Transmetalation Nucleophilic substitution & Carbonylation Reductive elimination + (-HX) M(0)Ln Catalyst regeneration High reactivity but low stability ≈ Reactive without phosphine ligands at room temperature Inexpensive and easy to remove In many cases heating is required for the reactions to proceed Chemically stable and easy to handle Formation of cationic complexes is unfavorable for metal exchange reactions Little by-product Effective to add some salts like LiCl for the reactions to proceed Expensive and hard to remove Only in a special case will the reactions proceed Use of highly active catalysts Use of heteroaromatic chlorides (R = heteroaromatic rings) The order of the reactivity as follows: Electron-withdrawing group > electron-donating group Improves oxidative addition Electron-withdrawing group is effective for oxidative addition Improves reductive elimination Hiyama cross-coupling Kumada-Tamao-Corriu cross-coupling R X + R' Ni(0) cat MgX R R' X + R' X + R' Pd(0) cat ZnX Ar X Kosugi-Migita-Stille cross-coupling X + R' Pd(0) cat SnR''3 R R' X + R' B(OR'')2 Base X + H YR'n Base Y= N, O X + X Pd(0) cat Base Ar B(OR)2 Ar YR'n Ar B(OH)2 + H YR'n Y= N, O, S Cu(OAc)2 Ar Base, O2 YR'n Carbonylation via CO insertion Pd(0) cat R' + Chan-Lam-Evans cross-coupling Mizoroki-Heck reaction R R' R R' Buchwald-Hartwig cross-coupling Ar Ar Base (RO)2B B(OR)2 Pd(0) cat Pd(0) cat R' + Pd(0) cat Cu(I) cat Miyaura-Ishiyama Borylation Ar Suzuki-Miyaura cross-coupling R R R' Sonogashira-Hagiwara cross-coupling R R' (R'–AlR2 and R'–ZrCp2Cl can be also used.) R Pd(0) cat SiR''3 (SiR''3=Si(OR)3, SiR3-nFn, etc.) (SiR''3=Si(OH)Me2: Hiyama-Denmark coupling) Negishi cross-coupling R R Base R R' Nu H R X + R' or or H M O Pd(0) cat CO R Nu or R' or H 53 Liebeskind-Srogl cross-coupling Fukuyama cross-coupling O R + R' ZnX O Pd(0) cat R SEt O R' R SEt + R' B(OH)2 Pd(0) cat CuTc O R R' Kochi-Furstner cross-coupling R X + R' MgX Fe(acac)3 THF-NMP R R' Palladium-phosphine complexes: Pd(0): Pd(PPh3)4, Pd[P(t-Bu)3]2 etc Pd(II): PdCl2(PPh3)2, PdCl2[(o-tolyl)3P]2, PdCl2(dppf), PdCl2(dppe), PdCl2(dppp), etc Precurcors of palladium catalysts: Pd(0): Pd2(dba)3·CHCl3, Pd(dba)2 etc Pd(II): Pd(OAc)2, PdCl2(CH3CN)2, PdCl2(PhCN)2, [PdCl(allyl)]2, Na2PdCl4, PdCl2 etc Me CN Cl MeO OMe CN Me 2% Pd[P(t-Bu)3]2 [B3161] + ClZn THF/NMP, 100 °C Me MeO Me OMe 76% 54 Cl Cl base D PdII L X reductive elimination HO N Cl Pd Pd Cl L Pd0 active Pd species palladacycle (stable complex) NH Pd C(CH3)3 Cl P C(CH3)3 N OH C(CH3)3 Cl D Cl Najera catalyst I [C2734] [D3806] A1479 B2029 CH2 HC Cl Pd Cl CH2 B1668 B3224 CN Pd CN Ph Cl Cl Fe Fe Pd Ph B2055 Ph Ph P Cl Pd P Cl Ph Ph PdCl2 P C(CH ) 3 C(CH3)3 B2161 B2018 CH3 Ph Ph P Cl Pd Cl P CH2Cl2 (CH3CN)2PdCl2 CH2 C(CH3)3 P C(CH3)3 B2192 Ph P Ph PdCl2 P Ph Cl B2031 Ph B3161 Pd B3160 CH CH C CH CH P Ph B2064 Ph Ph P Pd P Ph Ph CH2 Ph3P O Pd Cl B2016 CH B1374 Ph Ph P Cl Ph3P CH2 Pd B1676 CH3Ph2P Pd CH3Ph2P O Cl Pd Cl O CH3 Ph B2042 B1667 B2026 CH3 t-Bu3P O P Pd t-Bu3P Cl Ph3P Cl Ph3P Pd P Pd O C CH3 Ph3P O C CH3 Ph3P Pd P Cl CH3 Cl O Pd Cl Cl P C2734 D2604 D3806 Cl Cl NH2 Pd C(CH3)3 Cl P C(CH3)3 Pd HO N Cl Pd Cl N OH C(CH3)3 Cl Pd Cl P1785 P1491 P1490 A1424 O Pd CH3 C O Pd2 Cl Cl 55 P2106 P1489 P2017 PdCl2 [Pd(CH3COO)2]3 P1425 P1944 P1528 CH2 HC Pd Cl C2372 NH O P PdCl2 20 n i-Pr CH3O S0540 i-Pr CH3O N i-Pr i-Pr Pd CH3O N Cl N i-Pr CH3 CH3 Cl O HN N T1350 Pd2 i-Pr N Pd Cl CH3 CH3 C2407 i-Pr i-Pr N i-Pr Pd C O C2387 i-Pr N i-Pr Pd / (PSi-Al2O3) CF3 C2406 i-Pr N CH3 Pd(OH)2 CH CH2 i-Pr CH3 O CH Cl Pd CH P1870 CH3 T2184 i-Pr N N i-Pr i-Pr Pd HN Cl O Na2PdCl4 P Pd Pd2 CH CH C CH CH O CH3 56 A1479 B2029 B1676 B1668 B3224 B1374 B3160 B2031 B2016 B2064 B2192 B2161 B2018 B3161 B2055 B2042 B1667 B2026 C2734 D2604 D3806 P1785 P1491 P1490 A1424 P2106 P1430 Allylpalladium(II) Chloride Dimer Benzylbis(triphenylphosphine)palladium(II) Chloride Bis(acetonitrile)palladium(II) Dichloride Bis(benzonitrile)palladium(II) Dichloride Bis[1,2-bis(diphenylphosphino)ethane]palladium(0) Bis(dibenzylideneacetone)palladium(0) [1,1 -Bis(di-tert-butylphosphino)ferrocene]palladium(II) Dichloride [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride [1,2-Bis(diphenylphosphino)ethane]palladium(II) Dichloride [1,1 -Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct [1,3-Bis(diphenylphosphino)propane]palladium(II) Dichloride Bis(methyldiphenylphosphine)palladium(II) Dichloride Bis(2,4-pentanedionato)palladium(II) Bis(tri-tert-butylphosphine)palladium(0) Bis(tricyclohexylphosphine)palladium(II) Dichloride Bis(triphenylphosphine)palladium(II) Diacetate Bis(triphenylphosphine)palladium(II) Dichloride Bis(tri-o-tolylphosphine)palladium(II) Dichloride Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) Dichloro(1,5-cyclooctadiene)palladium(II) Najera Catalyst I Palladium 10% on Carbon (wetted with ca 55% Water) [Useful catalyst for coupling reaction, etc.] Palladium 10% on Carbon (wetted with ca 55% Water) Palladium 5% on Carbon (wetted with ca 55% Water) Palladium(II) Acetate Palladium(II) Acetate Trimer Palladium Catalyst Set (includes useful Palladium catalysts) P1489 P2017 P1528 P1870 P1425 Palladium(II) Chloride Palladium(II)( -cinnamyl) Chloride Dimer Palladium Hydroxide 20% on Carbon (wetted with ca 50% Water) Palladium(II) Trifluoroacetate Poly[N-isopropylacrylamide-co-4-(diphenylphosphino)styrene] Palladium(II) Dichloride P1944 C2372 C2406 C2387 C2407 C0540 Poly(methylphenyl)silane supported Palladium/Alumina Hybrid Catalyst [=Pd / (PSi-Al2O3)] SingaCycleTM-A1 (This product is unavailable in the U.S.) SingaCycleTM-A2 (This product is unavailable in the U.S.) SingaCycleTM-A3 (This product is unavailable in the U.S.) SingaCycleTM-A4 (This product is unavailable in the U.S.) Sodium Tetrachloropalladate(II) 500mg 100mg 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g 250mg 1g 1g 1g 5g 1g 1g 250mg 5g 5g 5g 1g 1g 1g 1g 5g 5g 5g 5g 5g 5g 5g 25g 5g 5g 5g 1g 5g 5g 25g 5g 1g 5g 1g 25g 25g 25g 5g 5g Palladium(II) Acetate / Allylpalladium(II) Chloride Dimer / Bis(benzonitrile)palladium(II) Dichloride / Bis(dibenzylideneacetone)palladium(0) / [1,1 -Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct / Bis(triphenylphosphine)palladium(II) Dichloride / Tetrakis(triphenylphosphine)palladium(0) 1set 5g 200mg 10g 50g 1g 5g 1g (ratio, acrylamide:phosphine=20:2) 200mg 200mg 200mg 200mg 100mg 1g 1g 1g 1g 1g 1g T1350 T2184 Tetrakis(triphenylphosphine)palladium(0) Tris(dibenzylideneacetone)dipalladium(0) B(OH)2 + 1g 5g 1g 25g 5g cat NiCl2(dppf), BuLi [B2226] Cl K3PO4, dioxane, 80 °C OMe OMe Y 94 % [when Pd(PPh3)4 Y < 1%] H3C Ph O O H3C Ni(acac)2 [N0096] Ni source Ni xH2O Ni P Ph Ph Ph P Ph [B2225] Cl Ni Cl P Ph Ph Ph P Cl Cl Ni Fe P Ph [B1313] Ph P Ph [B2226] Ni-phosphine complexes Ph i-Pr Cl Cl i-Pr N N i-Pr i-Pr Cl Ni Cl PPh3 [B3235] Ni-NHC complex 57 Cross coupling of primary alkyl halides n-alkyl X + R MX Cross coupling of secondary alkyl halides cat Ni(acac)2 or NiX2 additive X + R' R X= I, Br R= n-alkyl, s-alkyl, benzyl, aryl M= Zn O R1 (base or additive) R2 Me etc R' X= I, Br, MY= ZnX, B(OH)2, BBN, SiF3, Si(OMe)3 etc R'= alkyl, aryl, alkenyl Ligand: Ph Ph Ar O O N M= Mg F MY R2 THF/NMP additive: cat NiX2 cat Ligand R1 n-alkyl etc N N R R' ZnX B3235 N Ar Ar R B2225 N Me B(OH)2 SiF3 Ar etc NH HN Me R' BBN R' Si(OMe)3 B2226 (CH3)2CH Ph N (CH3)2CH B1313 N0096 Ph Ph Cl B3235 B2225 B2226 B1313 N0096 B3534 B1571 S0487 Ph Ni Ni P P O Cl O CH3 Fe Cl Ph Ph S0487 Ph3P Cl Ph3P Ni Cl Cl Ni [1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene]triphenylphosphine Nickel(II) Dichloride 200mg [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride 1g 5g [1,1 -Bis(diphenylphosphino)ferrocene]nickel(II) Dichloride 1g [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride 5g 25g Bis(2,4-pentanedionato)nickel(II) Hydrate Bis(tricyclohexylphosphine)nickel(II) Dichloride 1g Bis(triphenylphosphine)nickel(II) Dichloride 10g Skeletal Nickel Catalyst slurry in Water [Active catalyst for Hydrogenation] 1972 1995 1996 1997 1997 2000 2004 2008 2009 58 Ph Cl Ni P Ni P Cl B1571 CH3 Ph P B3534 Ph P Ph NiCl2 P Ph Ph P CH(CH3)2 N Ni Cl PPh3 Cl CH(CH3)2 1g 25g 5g 25g 500g 5g 100g 50g (CH2)5CH3 MgBr + Br Fe(acac)3 (5 mol%) [I0079] Et2O, reflux, 0.5 h (CH2)5CH3 Y 73% Br MgBr + Fe(OAc)2 [I0765] (3 mol%) Xantphos [B2709] O PPh2 (6 mol%) PPh2 Et2O, rt, 15 Cl i Pr N i Cl Pr iPr N + i Pr SIPr HCl (15 mol%) [B3157] FeF3 3H2O (5 mol%) + BrMg Y 64% THF, 60 °C, 24 h Y 98% D2571 I0765 T1686 Ph N N Fe O O O CH3 C O O Fe2 Fe O Ph H0555 I0079 T0750 CH3 CF3 O CF3 O O Fe Fe Fe O CF3 O O 3 CH3 CH3 59 D2571 I0765 T1686 H0555 I0079 T0750 N,N -Bis(salicylidene)ethylenediamine Iron(II) Iron(II) Acetate Tris(dibenzoylmethanato) Iron Tris(hexafluoroacetylacetonato)iron(III) Tris(2,4-pentanedionato)iron(III) Tris(trifluoro-2,4-pentanedionato)iron(III) 5g 5g 5g 25g 100g 1998 2004 2007 2007 Ullmann-type Coupling Cu(I) source, Ligand Ar X Nu + Ar Nu base, Δ under Ar or N2 X= I, Br Nu: Nu: Ligand O R O CO2H N H R' HO OH R' R 60 NH2 H2N H2N N O etc CO2H CO2H NHR HO R N N etc N CO2H etc R=H or Me MeO R HN HO Ar etc O RHN Ligand O HN HN Cu(I) source: CuI, Cu2O, CuBr, (CuOTf)2-C6H6, CuCl etc Cu(I) complex: CuTC, Cu(MeCN)4PF6 etc solvent: DMSO, DMF, NMP, dioxane, MeCN, toluene etc base: K2CO3, K3PO4, Cs2CO3, DIPEA, Et3N etc OMe Salen N MeHN NHMe N N etc HS R HO OH etc NaI (X= Br) MeHN NHMe 25g 25g 25g 1g 500g 5g Liebeskind-Srogl Cross-coupling Reaction O Pd cat CuTc O R SEt + R' B(OH)2 S O Cu R R' O CuTC [C2312] Chan-Lam-Evans Coupling Ar B(OH)2 + Cu(OAc)2, O2 Et3N or Pyr HYRn Y= N, O, S YRn Ar CH2Cl2, MS 4A r.t.~ C0384 B1513 B3834 B1677 CH3 H N O Cu Cu N H O CH3 C2422 C2304 A1540 CH3 (CH3)2CH (CH3)2CH CH(CH3)2 Cu Cl CH(CH3)2 N CH3 Cl O Cu N O C2346 C1952 CH3 N N N N Cl O CH3 Cu Cl CH3 CH3 O OCu CH3 C O Cu2 CuCN H2O CH3 C2410 C2312 Cu(BF4)2 T1292 Cu D2542 H3C CH3 N Cu N H3C CH3 O S H3C CH3 N Cu O N H H3C CH3 H O C0384 B1513 B3834 B1677 C2304 C2422 Cu2 S O O D3891 O O CF3 O D4395 T1442 CF3 O T2665 N S OCu Cu N Cl Cl T2666 2Cl Li2CuCl4 (CH3CN)4Cu PF6 Bis(2,4-pentanedionato)copper(II) Bis(1,3-propanediamine) Copper(II) Dichloride Bis(8-quinolinolato)copper(II) (purified by sublimation) Bis(8-quinolinolato)copper(II) Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) Chloro(1,3-dimesitylimidazol-2-ylidene)copper(I) (CH3CN)4Cu BF4 25g 1g 200mg 200mg 250g 10g 1g 25g 1g 1g 61 A1540 C2346 C1952 C2410 C2312 T1292 T1442 D3891 D2542 D4395 T2665 T2666 Copper(I) Acetate Copper(II) Acetate Monohydrate Copper(I) Cyanide Copper(II) Tetrafluoroborate (ca 45% in Water) Copper(I) 2-Thiophenecarboxylate Copper(II) Trifluoromethanesulfonate Copper(I) Trifluoromethanesulfonate Benzene Complex Dichloro(1,10-phenanthroline)copper(II) Di- -hydroxo-bis[(N,N,N ,N -tetramethylethylenediamine)copper(II)] Chloride Dilithium Tetrachlorocopper(II) (ca 2.5% in Tetrahydrofuran, ca 0.1mol/L) Tetrakis(acetonitrile)copper(I) Hexafluorophosphate Tetrakis(acetonitrile)copper(I) Tetrafluoroborate 5g 25g 25g 1g 5g 1g 1g 5g 100mL 1g 25g 500g 300g 500g 5g 25g 5g 5g 25g 500mL 5g 5g 2003 2008 2013 R R Wider R P(o-tol)3 P(t-Bu)3 P PCy3 θ PPh3 θ M P(O(o-tol))3 P(n-Bu)3 Cone angle of P(OPh)3 P(OMe)3 monodentate phosphines Narrower (θ) 62 R R P R ω Wider P M Bite angle of bidentate phosphines (ω) R ω Xantphos DPEphos DPPF DPPB BINAP DPPP DPPE Narrower Wider DIOP PPFA BINAP Norphos DIPAMP Chiraphos Narrower Advantages of vBRIDP® High electron density at C2-carbon Advantages of cBRIDP® Increasing bulkiness Ar Ar R' Ar Ar Ar P R Ar Controlling electron density R' P R R R Bulky alkyl groups Aryl groups located desired positions PPh2 PPh2 H3C Bulky alkyl groups Me OCH3 Ph2P CH3 (S,S)-Chiraphos [B2704] O O PPh2 PPh2 (R,R)-Norphos [B3449] NMe2 PPh2 PCH2CH2P PPh2 PPh2 Fe H3CO PPh2 (S)-BINAP [B1405] (R,R)-DIOP (R,R)-DIPAMP (R)-(S)-PPFA [B3035] [D2535] etc [B1113] B2711 B2710 P Fe P B3450 B1406 PPh2 PPh2 B2709 C(CH3)3 C(CH3)3 C(CH3)3 Fe P CH(CH3)2 PPh2 PPh2 PPh2 PPh2 CH(CH3)2 CH(CH3)2 PPh2 CH(CH3)2 B1246 PPh2 B2704 CH3 P (CH2)4 P P P CH3 B2027 B1959 B1113 CH3 PPh2 P CH2CH2 P O PPh2 P C(CH3)3 B1405 B1137 CH3 B3449 PPh2 Fe PPh2 P (CH2)6 P CH3 O CH3 O H H CH2 P CH2 P 63 B1112 B1982 CH3 O CH2 P CH3 O CH2 P B1960 P CH2 P B2867 P B1138 (C6H5)2P (CH2)5 P P(C6H5)2 P CH2CH2CH2 O B3035 B3036 C2979 OCH3 OCH3 PCH2CH2P PCH2CH2P CH3O CH3O C2980 C2981 Me D3940 Me P Me Me Me Me Me D3387 C(CH3)3 D2411 (CH3)3C P P Me Me P P D3388 D3389 P C(CH3)3 P P P C(CH3)3 (CH3)2N D2535 D2536 D2775 N(CH3)2 PPh2 (CH3)2N Ph2P Fe T0361 T2584 E0519 Bu P T0519 P CH2CH3 P T1165 (CH3)3C P H P Bu tBu CH2 P T1643 O C(CH3)3 Bu tBu Bu OCH3 P(C6H5)2 Fe T1912 t D2766 CH3 CH3 BF4 P O C(CH3)3 T1614 P O T0861 T1024 T1025 OCH3 CH3 OCH3 CH3 CH3 P P P P OCH3 CH3 P CH3O OCH3 CH3 CH3 T0862 CH3 P CH3 B2711 B2710 B3449 B3450 B1406 B1405 64 CH3 1,1 -Bis(di-tert-butylphosphino)ferrocene 1,1 -Bis(diisopropylphosphino)ferrocene (2R,3R)-(-)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene ((2R,3R)-(-)-Norphos) (2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene ((2S,3S)-(+)-Norphos) (R)-(+)-2,2 -Bis(diphenylphosphino)-1,1 -binaphthyl ((R)-(+)-BINAP) (S)-(-)-2,2 -Bis(diphenylphosphino)-1,1 -binaphthyl ((S)-(-)-BINAP) 100mg 100mg 1g 1g 100mg 100mg 1g 5g 1g 5g B1246 B2704 B2709 B1137 B2027 B1959 B1113 B1112 B1982 B1960 B2867 B1138 B3035 B3036 C2979 C2980 C2981 D3940 D3387 D2411 D3388 D3389 D2535 D2536 D2775 D2766 E0519 T1912 T0361 T2584 T1165 T1643 T0519 T1614 T0861 T1024 T1025 T0862 1,4-Bis(diphenylphosphino)butane 5g 100mg (2S,3S)-(-)-Bis(diphenylphosphino)butane ((S,S)-Chiraphos) 4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene (Xantphos) 1g 1,2-Bis(diphenylphosphino)ethane 10g 1,1 -Bis(diphenylphosphino)ferrocene 1g 5g 1,6-Bis(diphenylphosphino)hexane 1g (2R,3R)-(-)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol ((-)-DIOP) (2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol ((+)-DIOP) Bis(diphenylphosphino)methane 5g 1,5-Bis(diphenylphosphino)pentane Bis[2-(diphenylphosphino)phenyl] Ether 5g 1,3-Bis(diphenylphosphino)propane 5g (R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane ((R,R)-DIPAMP) (S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane ((S,S)-DIPAMP) 100mg cBRIDP 200mg 200mg Cy-cBRIDP 200mg Cy-vBRIDP Di-tert-butylphenylphosphine 2-(Di-tert-butylphosphino)biphenyl Dicyclohexylphenylphosphine 1g 2-(Dicyclohexylphosphino)biphenyl 1g 2-(Dicyclohexylphosphino)-2 -(dimethylamino)biphenyl 1g (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine ((R)-(S)-PPFA) (S)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine ((S)-(R)-PPFA) 100mg (S)-(-)-2-Diphenylphosphino-2 -methoxy-1,1 -binaphthyl 4-Diphenylphosphinomethyl Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (0.5-1.0mmol/g) Ethyldiphenylphosphine Tri-tert-butylphosphine Tributylphosphine 25mL 100mL Tri-tert-butylphosphonium Tetrafluoroborate 1g Tricyclohexylphosphine (contains Tricyclohexylphosphine Oxide) (ca 18% in Toluene, ca 0.60mol/L) Tri(2-furyl)phosphine 1g Triphenylphosphine 25g Tris(2,6-dimethoxyphenyl)phosphine Tris(4-methoxyphenyl)phosphine 5g 5g Tri(o-tolyl)phosphine Tri(m-tolyl)phosphine 5g Tri(p-tolyl)phosphine 5g 25g 1g 5g 25g 25g 5g 1g 1g 25g 1g 25g 25g 100mg 1g 1g 1g 1g 5g 1g 5g 5g 5g 100mg 100mg 1g 5g 5g 5g 500mL 5g 25mL 5g 500g 25g 25g 25g 25g 25g 2009 2008 2008 2011 65 R N N base R R N N R H N-Heterocyclic Carbene (NHC) R: Bulky substituent N N N IPr N N IMes N SIPr B3506 CH CH3 N B3158 N CH3 CH CH3 N N CH3 CH3 66 N (CH3)2CH CH(CH3)2 CH(CH3)2 CH(CH3)2 N Cl (CH3)2CH CH(CH3)2 D3882 C CH3 CH3 C CH3 CH3 N CH3 N Cl N N N CH3 CH3 CH3 (CH3)2CH D3472 CH3 N CH3 CH CH3 CH3 CH CH3 CH3 CH3 CH3 CH CH3 D3711 CH3 CH3 CH CH3 D3611 (CH3)2CH CH N CH3 CH CH3 N SIMes B3157 CH3 B3465 N BF4 (CH3)3C N N C(CH3)3 N Cl Cl D3446 D3870 CH3 CH3 N CH3 CH3 CH3 CH3 N N N Cl CH3 CH3 CH3 CH3 CH3 CH3 B3506 B3157 D3611 B3465 B3158 D3711 D3472 D3882 D3446 D3870 1,3-Bis(2,6-diisopropylphenyl)imidazolidin-2-ylidene 1,3-Bis(2,6-diisopropylphenyl)imidazolinium Chloride (SIPrHCl) 500mg 1,3-Bis(2,6-diisopropylphenyl)imidazolium Chloride (IPrHCl) 500mg 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) 1,3-Bis(2,4,6-trimethylphenyl)imidazolinium Chloride (SIMesHCl) 1,3-Di-tert-butylimidazolium Tetrafluoroborate (It BuHBF 4) 1,3-Di-tert-butylimidazol-2-ylidene (It Bu) 1,3-Dicyclohexylimidazolium Chloride (IcHexHCl) (This product is only available in Japan.) 1,3-Dimesitylimidazolium Chloride (IMesHCl) 1,3-Dimesitylimidazol-2-ylidene (IMes) 1g 5g 25g 5g 5g 5g 5g 5g 5g 5g 1g 5g 1g 1g 1g 1g 1g 1g 1g 2006 2009 B0468 B2695 D0905 B1018 CH3 CH3 N N N B0709 C2430 CH3 CH3 N H OCs CsO CsF OCs CH3 M0508 L0204 L0222 CH3 N CH3 N CH3 LiCl S0560 S0485 O HCl H2O KO H2O CH3 P1758 N N N N CH3 P1748 N P0221 CH3 CH3 P0081 N C(CH3)3 C(CH3)3 O D1599 CH3 D3134 N D0925 CH3 N C2204 O NH2 N CH3 N C2160 CH3 CH3 CH3 O OK KF NaO ONa CH3ONa 67 T0054 T0057 (CH2)3CH3 CH3(CH2)3 N B2695 D0905 B0468 B1018 B0709 C2430 C2160 C2204 D3134 D0925 D1599 L0204 L0222 M0508 P0221 P0081 P1748 P1758 S0560 S0485 T0054 T0057 Z0015 68 (CH2)3CH3 (CH2)3CH3 Br (CH2)3CH3 Z0015 CH3(CH2)3 N (CH2)3CH3 (CH2)3CH3 I Zn Bathophenanthroline (purified by sublimation) Bathophenanthroline 2,2 -Bipyridyl 1,8-Bis(dimethylamino)naphthalene [for Dehydrohalogenation] tert-Butylamine Cesium Acetate Cesium Carbonate Cesium Fluoride 4,4 -Di-tert-butyl-2,2 -bipyridyl Diisopropylamine N,N-Diisopropylethylamine Lithium Chloride Anhydrous Lithium Chloride (2.3% in Tetrahydrofuran, ca 0.5mol/L) 1-Methylimidazole 1,10-Phenanthroline Monohydrate 1,10-Phenanthroline Hydrochloride Monohydrate Potassium Carbonate Potassium Fluoride Sodium Carbonate Sodium Methoxide Tetrabutylammonium Bromide Tetrabutylammonium Iodide Zinc (Powder) 25g 1g 25mL 25mL 25mL 25g 25g 25g 1g 1g 5g 100g 500g 5g 25g 100mL 500mL 25g 100g 25g 100g 25g 100g 1g 5g 100mL 500mL 100mL 500mL 25g 300g 100mL 100g 500g 1g 25g 25g 300g 300g 300g 100g 500g 100g 500g 100g 500g 300g R X + H R' or R H + M R' catalyst R catalyst R' X H + or M R H + H R' H + H cf Cross-coupling reactions R X catalyst + R' M X O H + Si(OEt)3 + R R' M RuH2(CO)(PPh3)3 (2 mol%) [C2251] toluene, reflux, h O Si(OEt)3 69 B1676 B1374 B2018 CH3 (CH3CN)2PdCl2 O O CH CH C CH CH Pd Pd O CH3 B3292 B2055 D4333 A1424 CH3 O O S Pd P O C CH3 O C CH3 S O P O Cl Cl Cl B1676 B1374 B2018 B3292 B2055 D4333 A1424 P1870 O PPh2 P1870 CH3 O Pd PPh2 Pd2 CH3 C O O CF3 C O Pd2 Pd Cl Bis(acetonitrile)palladium(II) Dichloride Bis(dibenzylideneacetone)palladium(0) Bis(2,4-pentanedionato)palladium(II) 1,2-Bis(phenylsulfinyl)ethane Palladium(II) Diacetate Bis(tricyclohexylphosphine)palladium(II) Dichloride Dichloro[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene]palladium(II) Palladium(II) Acetate Palladium(II) Trifluoroacetate B1902 1g 1g 1g 200mg 1g 200mg 1g 1g C2251 5g 5g 5g 1g 5g 1g 5g 5g D2751 (CH3)2CH Cl Cl H Ru Cl P Ru Cl Ru CH3 Cl CO Cl Ru H Ru Cl Cl CH(CH3)2 CH3 H1010 R0074 Cl Cl Ru Ru Cl Cl T2181 RuCl3 D1997 Ru(CO)4 (CO)4Ru Ru(CO)4 P Ru Cl Cl B1902 C2251 D2751 H1010 R0074 T2181 D1997 70 Benzeneruthenium(II) Chloride Dimer Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II) Dichloro(p-cymene)ruthenium(II) Dimer (Hexamethylbenzene)ruthenium(II) Dichloride Dimer Ruthenium(III) Chloride Triruthenium Dodecacarbonyl Tris(triphenylphosphine)ruthenium(II) Dichloride 1g 250mg 1g 1g 100mg 1g 5g 1g 5g 1g 5g 1g 5g B3961 B2091 C2253 BF4 BF4 Rh Rh Cl Rh Cl Rh C2461 B1045 N0453 P1788 R0069 CH3 CH3 CH2 CH2 CH2 Cl Rh CH2 CH3 Cl CH2 Rh Cl CH2 CH2 Cl Rh CH2 Rh Rh Cl CH3 CH3 Rh O CH3 Cl Rh Cl O Cl Rh Cl CH3 CH3 Cl CH3 CH3 CH3 T2054 O O CH3(CH2)6 O O O Rh Rh O O O (CH2)6CH3 R O Rh H R CH3 O R O H H O OO Rh Rh O O O R O H R O O Cl CH3 O O Cl Cl C OCH2CH3 R O O O R H O O N R= O H O CH3 R O C OCH2CH3 OO R O R O R= CH3 O Cl N O H Cl O O Cl Cl C OCH2CH3 O O O H Rh Rh O R H R' R O O CH3 R H H OO O R R= O CH3 O F O O O F F C OCH2CH3 O O O R H CH2 O C OCH2CH3 R Ph Ph O R H OO Rh Rh N O H F R'= N R= T1544 R Rh Rh R OO O O O H R' H R' O T2661 H H Rh Rh N R= O H Cl R T2660 R H Rh R C OCH2CH3 T2659 OO Rh O O O N R= H O O O H T2658 H Rh O O O R O OO R R' H H H O T1551 R H (CH2)6CH3 R T2055 R (CH2)6CH3 CH3 O O Rh CH3 CH3 R0161 O Rh O O O R R= O CH3 F N O H F O O F F C OCH2CH3 Rh O O O Ph Ph Ph Ph Ph Ph Ph O O Ph Rh O O Ph Ph CH2Cl2 T0931 P B3961 B2091 C2253 C2461 B1045 N0453 P1788 R0069 R0161 T2054 T2055 T1551 T2658 T2659 T2660 T2661 T1544 T0931 Rh Cl Bis(1,5-cyclooctadiene)rhodium(I) Tetrafluoroborate Bis[ -(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate Chlorobis(cyclooctene)rhodium(I) Dimer Chlorobis(ethylene)rhodium(I) Dimer Chloro(1,5-cyclooctadiene)rhodium(I) Dimer Norbornadiene Rhodium(I) Chloride Dimer (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer Rhodium(II) Acetate Dimer Rhodium(II) Octanoate Dimer Tetrakis[N-phthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis[N-phthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis[N-phthaloyl-(S)-phenylalaninato]dirhodium Ethyl Acetate Adduct Tetrakis[N-tetrachlorophthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis[N-tetrachlorophthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis[N-tetrafluorophthaloyl-(R)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis[N-tetrafluorophthaloyl-(S)-tert-leucinato]dirhodium Bis(ethyl Acetate) Adduct Tetrakis(triphenylacetato)dirhodium(II) Dichloromethane Adduct Tris(triphenylphosphine)rhodium(I) Chloride 100mg 1g 100mg 1g 100mg 500mg 200mg 100mg 1g 100mg 200mg 1g 100mg 1g 200mg 1g 100mg 100mg 100mg 50mg 100mg 50mg 100mg 100mg 1g 5g 71 C2252 C3040 P Ir C2985 CO P Cl Ir C1807 C2662 Ir Ir Ir Cl O I0616 IrCl3 N O xH2O Ir O PF6 CH3 C2252 C3040 C2985 C1807 C2662 C2824 I0616 T2557 CH3 Carbonylchlorobis(triphenylphosphine)iridium(I) Carbonylhydridotris(triphenylphosphine)iridium(I) Chlorobis(cyclooctene)iridium(I) Dimer Chloro(1,5-cyclooctadiene)iridium(I) Dimer (1,5-Cyclooctadiene)(methoxy)iridium(I) Dimer (1,5-Cyclooctadiene)(pyridine)(tricyclohexylphosphine)iridium(I) Hexafluorophosphate Iridium(III) Chloride Hydrate Tris(2,4-pentanedionato)iridium(III) B2225 B2226 Ph Ni P Ph N0096 B3534 P O Ni O P Ph3P Cl Ph3P Ni 200mg 200mg 1g 1g 200mg 250mg 1g 200mg 1g 100mg 1g 5g 1g Ph P Ph NiCl2 P Ph Ph Cl Cl Ph P Cl Ni Cl P Ph Ph B0034 Cl Ni Fe Ph B1571 CH3 CH3 Cl Cl B1313 Ph P Ir CH3 Ir Ir Cl T2557 P O Cl Ir H C2824 CH3 Cl CO Ph N0850 O Ni S O O 6H2O NiCl2 T0276 N0861 O CH3 Ni2 SO3 B2225 B2226 B1313 N0096 B3534 B1571 72 6H2O CF3 Ni2 S O O [1,2-Bis(diphenylphosphino)ethane]nickel(II) Dichloride [1,1 -Bis(diphenylphosphino)ferrocene]nickel(II) Dichloride [1,3-Bis(diphenylphosphino)propane]nickel(II) Dichloride Bis(2,4-pentanedionato)nickel(II) Hydrate Bis(tricyclohexylphosphine)nickel(II) Dichloride Bis(triphenylphosphine)nickel(II) Dichloride 1g 5g 1g 5g 25g 1g 10g 25g 5g 25g 500g 5g 100g B0034 N0850 T0276 N0861 Nickel(II) Benzenesulfonate Hexahydrate Nickel(II) Chloride Anhydrous Nickel(II) p-Toluenesulfonate Hexahydrate Nickel(II) Trifluoromethanesulfonate 1g 25g 500g 25g 5g 200mg 1g 25g T2994 P T2994 Au Cl (Triphenylphosphine)gold(I) Chloride C0384 C2304 C2346 (CH3)2CH CH3 N O Cu O CH3 N (CH3)2CH CH(CH3)2 Cu Cl CH(CH3)2 O CH3 C O Cu2 H2O T1292 O CF3 C0384 C2304 C2346 T1292 Cu2 S O O Bis(2,4-pentanedionato)copper(II) Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]copper(I) Copper(II) Acetate Monohydrate Copper(II) Trifluoromethanesulfonate 25g 200mg 25g 5g 250g 1g 500g 25g 73 (I) Oxidative addition Hydrides remain on the metals Low-valent metals Ru(0), Rh(I), Pd(0), Ni(0) etc are used Effective to assist intramolecular chelation from the directing group ‡ (I) H H Mn Mn+2 (II) Electrophilic aromatic substitution (SEAr) Hydrogen atom is pulled out as a proton Reactive to electron-rich aromatic rings and five-membered heterocycles Generally, not rate-limiting step and low KIE(kH/kD=1.2~2.0) ‡ (II) M H M X H O (III) R -HX ‡ (III) Concerted metalation-deprotonation (CMD) Hydrogen atom is pulled out as a proton Reactive to fluorine or nitrogen substituted electron-poor aromatic rings If C-H bond cleavage is rate-limiting step, showed high KIE(kH/kD=3.5~7.0) M O H M - RCO2H ‡ (IV) M R H (IV) σ-Bond metathesis Hydrogen atom is pulled out as a hydrocarbon Early transition metal complexes with unsaturated coordination state Activation of sp3 C-H bonds -RH M DG DG H M H DG:Directing Group R O DG: Z R N R' N R NMe2 R OMe O Z= O, NR, S R= Me, H, OR, NR2 H N R= Me, NMe2 CN F O F N H CF3 F F N O N H Si N i-Pr Auxiliary groups aimed at C-H bond activations 74 i-Pr etc I Ar-H/Ar-X Coupling (Pd, Ni, Cu, Fe etc.) (X= I, Br etc.) Ar II Ar-H/Ar-M Coupling (Ru, Rh, Pd, Ni etc.) (M= B etc.) Ar H + X R or H + M catalyst R or III Ar-H/Ar-H Coupling (Pd(II), Rh(III) etc.) cross-dehydrogenative coupling (CDC) Ar H + H Ar R R= aryl, alkenyl R Oxidative addition Electrophilic aromatic substitution (SEAr) by low-valent metal species by high-valent metal species R cat M + R or R' H R R R + Y R DG R R DG Y' cat M Y' or Y' H Y Y Low-valent metal catalyst: RuH2(CO)(PPh3)3, Ru3(CO)12, RhCl(PPh3)3 etc High-valent metal catalyst: Pd(OAc)2, (Cp*RhCl2)2 etc R DG OH R R DG CO + cat M H O DG O conditions Pd(II) cat., acid, oxidant, CO (1 atm) or Ru(0), Rh(I) cat CO (high pressure), alkene R R DG R O R H Y + Y H H R Y R + cat M or E Y cat M R E M= Ir, Rh, Ru, Pt etc Y= SiR3, B(OR)2 M= Pd(II) etc E: OR, OCOR NRR', NCOR SR, SO2R I, Br, Cl, F 75 A0963 A1554 B1883 B3976 CH2MgBr CH2 B1884 B1933 B0726 C1504 MgBr CH3 C MgCl MgBr CH3 MgCl CH3 C2039 MgBr MgCl CH3 CH3 CH3 C1505 MgBr B1148 B1147 CH2MgCl CH2 D3551 E0778 E0135 E0497 E0134 MgBr MgBr CH3 CH3 MgBr CH3 MgCl CH3 H0822 F0673 H0821 I0517 I0518 MgBr CH3 CH3 MgBr CH3 MgBr CH3 MgBr CH3 CH3 MgBr F I0654 I0543 I0542 CH3 CH3 CH3 MgCl P1251 CH3 M0364 M0362 M0785 MgCl LiCl P1177 CH3MgBr P2025 CH3MgI P1381 CH3(CH2)14MgBr P0880 T1698 MgBr T1699 P0191 T1700 MgBr MgBr MgI T1451 T2609 CH3 CH3 CH3 CH3 76 MgBr MgBr MgBr CH3 CH3 MgCl MgBr CH3 O0240 Si CH3 CH3 CH2MgCl V0053 CH2 CHMgBr A0963 A1554 B1883 B3976 B1933 B1884 B1148 B1147 B0726 C1504 C1505 C2039 D3551 E0497 E0134 E0778 E0135 F0673 H0822 H0821 I0517 I0518 I0543 I0542 I0654 M0362 M0785 M0364 O0240 P1251 P1177 P2025 P1381 P0191 P0880 T1698 T1699 T1700 T1451 T2609 V0053 Allylmagnesium Bromide (ca 13% in Ethyl Ether, ca 0.7mol/L) Allylmagnesium Chloride (ca 11% in Tetrahydrofuran, ca 1.0mol/L) Benzylmagnesium Bromide (ca 12% in Tetrahydrofuran, ca 0.6mol/L) Benzylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 0.9mol/L) Benzylmagnesium Chloride (ca 16% in Tetrahydrofuran, ca 1mol/L) sec-Butylmagnesium Bromide (ca 16% in Tetrahydrofuran, ca 1mol/L) tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca 2mol/L) tert-Butylmagnesium Chloride (26% in Ethyl Ether, ca 2mol/L) Butylmagnesium Chloride (23% in Tetrahydrofuran, ca 2mol/L) Cyclohexylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 1mol/L) Cyclopentylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 1mol/L) Cyclopropylmagnesium Bromide (ca 10% in Tetrahydrofuran, ca 0.7mol/L) (2,5-Dimethylphenyl)magnesium Bromide (20% in Tetrahydrofuran, ca 1mol/L) Ethylmagnesium Bromide (13% in Tetrahydrofuran, ca 1mol/L) Ethylmagnesium Bromide (39% in Ethyl Ether, ca 3mol/L) Ethylmagnesium Chloride (ca 1.0mol/L in Tetrahydrofuran) activated with Zinc Chloride (ca 10mol%) Ethylmagnesium Chloride (ca 18% in Tetrahydrofuran, ca 2mol/L) 4-Fluorophenylmagnesium Bromide (ca 19% in Tetrahydrofuran, ca 1.0mol/L) Heptylmagnesium Bromide (21% in Tetrahydrofuran, ca 1mol/L) Hexylmagnesium Bromide (20% in Tetrahydrofuran, ca 1mol/L) Isobutylmagnesium Bromide (17% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Chloride (ca 11% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Chloride (ca 13% in Ethyl Ether, ca 1mol/L) Isopropylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca 1mol/L) Methylmagnesium Bromide (12% in Tetrahydrofuran, ca 1mol/L) Methylmagnesium Bromide (35% in Ethyl Ether, ca 3mol/L) Methylmagnesium Iodide (33% in Ethyl Ether, ca 2mol/L) n-Octylmagnesium Bromide (ca 22% in Tetrahydrofuran, ca 1mol/L) Pentadecylmagnesium Bromide (ca 15% in Tetrahydrofuran, ca 0.4mol/L) Pentylmagnesium Bromide (18% in Tetrahydrofuran, ca 1mol/L) Phenylmagnesium Bromide (16% in Tetrahydrofuran, ca 1mol/L) Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca 2mol/L) Phenylmagnesium Iodide (ca 42% in Ethyl Ether, ca 2mol/L) Propylmagnesium Bromide (ca 27% in Tetrahydrofuran, ca 2mol/L) o-Tolylmagnesium Bromide (ca 17% in Tetrahydrofuran, ca 0.9mol/L) m-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca 1mol/L) p-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca 1mol/L) Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca 1mol/L) Trimethylsilylmethylmagnesium Chloride (ca 18% in Tetrahydrofuran, ca 1mol/L) Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca 1mol/L) A1222 B1974 (CH2)3CH3 CH3(CH2)3 Sn CH2CH (CH2)3CH3 CH3(CH2)3 B1975 (CH2)3CH3 CH2 CH3(CH2)3 Sn C C Sn (CH2)3CH3 CH3(CH2)3 100mL 100g Price on request 100g 250g 100g 250g 250g 250g 100g 100g 100g 100g 250g 250g 250g 250g 250g 250g 250g 250g 250g 250g 250g 100mL 250g 250g 100g 250g 250g 250g 250g 250g 250g 250g 100g 100g 100g 100mL 100mL 100g (CH2)3CH3 (CH2)3CH3 CH3(CH2)3 CH3(CH2)3 Sn Sn (CH2)3CH3 (CH2)3CH3 CH3(CH2)3 77 B1832 B4209 B0396 Sn CH3 (CH2)3CH3 Cl Li C CH3(CH2)3 (CH2)3CH3 D1340 Al Li CH3 D1338 D1373 CH3 Sn CH3 Cl H0842 M1655 M0589 P1429 T1750 C CH CH3 T1866 Si CH2 CH3 (CH2)3CH3 Sn (CH2)3CH3 (CH2)3CH3 (CH2)3CH3 CH3(CH2)3 Sn CH CH2 (CH2)3CH3 (CH2)3CH3 CH3(CH2)3 Sn H (CH2)3CH3 (CH2)3CH3 T0784 Al CH3 CH3 CH3 (CH2)3CH3 Si C C Sn CH3 (CH2)3CH3 (CH2)3CH3 CH3 CH3 Al CH3 CH3 CH3 T0782 T1575 CH3 CH3 Sn CH3 CH3 T1865 (CH2)3CH3 T0783 T0925 CH3 CH3 (CH2)3CH3 T1473 CH3(CH2)3 Sn F OH T0919 CH3(CH2)3 Sn (CH2)3CH3 CH2CH CH2 (CH2)3CH3 T1794 CH3 Cl Sn (CH2)3CH3 CH2CH CH2 CH2 CHCH2 Sn CH2CH CH2 (CH2)3CH3 Cl CH3 T0058 T0678 CH3(CH2)3 Sn (CH2)3CH3 CH3 CH3 T0363 (CH2)3CH3 CH3CH2 Al O Li Cl CH3 M0744 CH3HgI T2009 Al Sn Cl O CH3(CH2)7 Sn (CH2)7CH3 CH3HgCl C1411 Ti O CH3 E0648 M0258 CH3Li Li (CH2)3CH3 Cl Zn(CH2CH3)2 Cl CH3(CH2)3 Sn Sn Cl CH3 CH3 CH3(CH2)3 CH3 D3902 D3214 CH3 D0305 CH3 CH3(CH2)3 (CH2)3CH3 CH3(CH2)3 Sn D0223 CH3 CH3 Al CH3 CH3 T0958 CH3 CH3 Sn Cl CH3 A1222 B1974 B1975 B1832 B4209 B0396 78 Allyltributyltin Bis(tributylstannyl)acetylene trans-1,2-Bis(tributylstannyl)ethylene Bis(tributyltin) tert-Butyllithium (ca 18% in Pentane, ca 1.9mol/L) Butyllithium (ca 15% in Hexane, ca 1.6mol/L) 5g 1g 1g 5g 25g 5g 5g 25g 100mL 100mL 500mL D0223 D0305 D1340 D3902 D3214 D1338 D1373 E0648 H0842 M1655 M0589 M0258 M0744 P1429 C1411 T2009 T0058 T0919 T1750 T0363 T0678 T1473 T1865 T1866 T1794 T0783 T0925 T0784 T0782 T1575 T0958 Dibutyltin Dichloride Dibutyltin Oxide Diethylaluminum Chloride (ca 15% in Hexane, ca 0.87mol/L) Diethylzinc (ca 15% in Toluene, ca 1mol/L) Diethylzinc (ca 17% in Hexane, ca 1mol/L) Dimethyltin Dichloride Di-n-octyltin Oxide Ethylaluminum Dichloride (17% in Hexane, ca 1mol/L) Hexyllithium (30% in Hexane, ca 2.3mol/L) Methyllithium (ca 3-5% in Ethyl Ether, ca 1-2mol/L) Methylmercuric Chloride Methylmercuric Iodide Monobutyltin Oxide Phenyllithium (ca 16% in Butyl Ether, ca 1.6mol/L) Tebbe Reagent (ca 0.5mol/L in Toluene) Tetraallyltin Tetrabutyltin Tetramethyltin Tributylethynyltin Tributyltin Chloride Tributyltin Fluoride Tributyltin Hydride (stabilized with BHT) [Reducing Reagent] Tributyl(trimethylsilylethynyl)tin Tributyl(trimethylsilylmethyl)tin Tributylvinyltin Triethylaluminum (15% in Hexane, ca 1.0mol/L) Triethylaluminum (15% in Toluene, ca 1.1mol/L) Triisobutylaluminum (15% in Hexane, ca 0.50mol/L) Trimethylaluminum (15% in Hexane, ca 1.4mol/L) Trimethylaluminum (15% in Toluene, ca 1.8mol/L) Trimethyltin Chloride 25g 100g 25g 25g 100mL 100g 25g 25g 1g 25g 5g 1g 100g 25g 25g 5g 1g 5g 5g A0775 A1601 O NH2 C CH3 Fe Fe B0886 B2711 B4272 O P C Fe Fe P B2027 PPh2 B3501 Fe O B O O CH3 CH3 CH3 CH3 Ph P Ph NiCl2 P Ph B2227 Fe PPh2 Fe CH(CH3)2 Ph P Ph PdCl2 P Ph R CH2Cl2 Fe R N Fe R= CH CH3 CH3 O Ph B2063 B0885 CH3 (CH2)3CH3 C CH3 NH C OC(CH3)3 Fe CH(CH3)2 CH(CH3)2 B3197 O Br Fe Fe Ph CH3 CH3 O P Ph2P CH(CH3)2 B2064 Fe Ph B3476 B Fe PCl2 Ph P Ph CoCl2 P Ph Fe P Fe B2226 PPh2 B3196 PCl2 C(CH3)3 B3374 Fe B2710 C(CH3)3 C(CH3)3 C(CH3)3 500g 500g 100mL 100mL 500mL 500g 500g 100mL 100mL 100mL 5g 25g 500g 100mL 25mL 5g 500g 25g 5g 500g 25g 250g 25g 5g 25g 100mL 100mL 100mL 100mL 100mL 25g Fe CH3 Fe CH3 CH3 79 F0312 F0313 B0913 B0915 D2829 O O C CH3 Fe Fe D1272 D2951 C CH3 C O O D1271 D2537 CH2N C CH2CH2CH3 Fe D2538 CH3 Fe D2536 D1273 N(CH3)2 PPh2 D2529 Fe Fe CH D0444 F0406 F0280 O CH3 CH2CH3 CH3 CH2 Fe Fe PPh2 O F0165 N(CH3)2 Fe CH3 E0394 N CH3 N(CH3)2 Fe Fe D3822 CH3 CH3 (CH3)2N Ph2P Fe Ph2P D2528 CH3 CH3 (CH3)2N Ph2P PPh2 O D2535 CH3 N(CH3)2 PPh2 CH3 C CH2CH2CH3 (CH2)3CH3 Br CH3 Fe Fe Fe Fe O (CH2)3CH3 Br C Fe Fe F0664 F0320 O Fe Fe F0286 O C OH B(OH)2 C OH Fe Fe B0914 O C Fe O CH3 CH2CH2 C OH CH2 N (CH2)11CH3 CH3 Fe Fe B(OH)2 B(OH)2 C OH Br C OH O F0166 F0167 H0941 CH3 CH2 Fe Br I0749 A0775 A1601 B0886 B2711 B4272 B2710 80 CH2 N CH3 CH3 Fe O CH CH3 Fe CH2OH Fe Fe T2546 S C O N Fe CHCH3 O O CH3 OH C NHNH2 T2545 O H0464 O Fe I S0820 N Fe CH3 N CH3 CH3 H0463 V0064 O CH3 S Fe CH CH3 CH2 Fe O Acetylferrocene Aminoferrocene Benzoylferrocene 1,1 -Bis(di-tert-butylphosphino)ferrocene 1,1 -Bis(dichlorophosphino)ferrocene 1,1 -Bis(diisopropylphosphino)ferrocene 10g 100mg 5g 100mg 200mg 100mg 25g 1g 25g 1g 1g 1g B3196 B2027 B3374 B2226 B2064 B3197 B3501 B3476 B2227 B2063 B0885 F0312 F0313 B0913 B0915 D2829 D1272 D2951 D1271 D2537 D2538 D2535 D2536 D1273 D2528 D2529 D3822 E0394 D0444 F0406 F0280 F0165 F0664 B0914 F0320 F0286 F0166 F0167 H0941 H0463 H0464 I0749 S0820 T2545 T2546 V0064 (R,R )-2,2 -Bis(diphenylphosphino)-1,1 -biferrocene 1,1 -Bis(diphenylphosphino)ferrocene 1g [1,1 -Bis(diphenylphosphino)ferrocene]cobalt(II) Dichloride [1,1 -Bis(diphenylphosphino)ferrocene]nickel(II) Dichloride 1g [1,1 -Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct (S,S )-2,2 -Bis[(S)-4-isopropyloxazolin-2-yl]-1,1 -biferrocene 1,1 -Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ferrocene Bromoferrocene N-(tert-Butoxycarbonyl)aminoferrocene tert-Butylferrocene Butylferrocene Cyclohexenylferrocene Cyclopentenylferrocene 1,1 -Diacetylferrocene 1,1 -Dibenzoylferrocene 1,1 -Dibromoferrocene 1,1 -Dibutylferrocene 1,1 -Dibutyrylferrocene N,N-Dimethylaminomethylferrocene (R)-N,N-Dimethyl-1-[(S)-1 ,2-bis(diphenylphosphino)ferrocenyl]ethylamine (S)-N,N-Dimethyl-1-[(R)-1 ,2-bis(diphenylphosphino)ferrocenyl]ethylamine (R)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine (S)-N,N-Dimethyl-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine 1,1 -Dimethylferrocene (R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine (S)-(-)-N,N-Dimethyl-1-ferrocenylethylamine (S)-1-(Diphenylphosphino)-2-[(S)-4-isopropyloxazolin-2-yl]ferrocene Ethylferrocene Ferrocene 25g Ferroceneacetic Acid Ferroceneboronic Acid (contains varying amounts of Anhydride) [Cyclic boronating reagent for GC/MS] Ferrocenecarboxylic Acid 1g 1,1 -Ferrocenediboronic Acid (contains varying amounts of Anhydride) 1,1 -Ferrocenedicarboxylic Acid 3-Ferrocenoylpropionic Acid (Ferrocenylmethyl)dodecyldimethylammonium Bromide (Ferrocenylmethyl)trimethylammonium Bromide (Ferrocenylmethyl)trimethylammonium Iodide (Hydrazinocarbonyl)ferrocene [for HPLC Labeling] 1-Hydroxyethylferrocene Hydroxymethylferrocene (S)-(4-Isopropyloxazolin-2-yl)ferrocene N-Succinimidyl Ferrocenecarboxylate (R)-(p-Toluenesulfinyl)ferrocene (S)-(p-Toluenesulfinyl)ferrocene Vinylferrocene B1951 C1589 D3307 100mg 500mg 5g 25g 1g 5g 1g 5g 5g 25g 100mg 500mg 1g 5g 1g 5g 1g 1g 5g 10g 25g 25g 25g 5g 5g 25g 1g 5g 1g 5g 5g 25g 5g 25g 100mg 100mg 100mg 100mg 5g 25g 200mg 1g 200mg 1g 200mg 1g 5g 100g 500g 1g 5g 100mg 1g 5g 25g 1g 1g 5g 25g 5g 1g 5g 5g 1g 1g 5g 1g 5g 1g 200mg 1g 1g 5g 1g 1g D3321 CH3 CH3 CH3 Fe Co PF6 PF6 CH3 CH3 Cl Zr Cl CH3 CH3 CH3 CH3 (CH2)3CH3 Cl Zr Cl (CH2)3CH3 CH3 D4100 D3286 H0914 I0645 CH2CH2CH3 CH3 Ti CH3 Cl Hf Cl Cl CH2CH2CH3 Hf Cl CH3 CH3 D1574 C Zr Cl Cl Ni 81 R0078 C1411 Ru Ti Z0009 CF3SO3 T1658 Cl Al CH3 CH3 Z0010 Zr SO3CF3 T0616 O V0090 O F3C S O Ti Cl O S CF3 O Ti Cl Cl V Cl O Z0007 H Zr Cl Cl Zr Cl O B1951 C1589 D3307 D3321 D4100 D3286 H0914 I0645 D1574 R0078 C1411 T1658 T0616 V0090 Z0009 Z0010 Z0007 -Benzene( -cyclopentadienyl)iron(II) Hexafluorophosphate Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate Decamethylzirconocene Dichloride 1,1 -Dibutylzirconocene Dichloride Dimethyltitanocene (5% in Tetrahydrofuran/Toluene) 1,1 -Dipropylhafnocene Dichloride Hafnocene Dichloride 1,1 -Isopropylidenezirconocene Dichloride Nickelocene Ruthenocene Tebbe Reagent (ca 0.5mol/L in Toluene) Titanocene Bis(trifluoromethanesulfonate) Titanocene Dichloride Vanadinocene Dichloride Zirconocene Bis(trifluoromethanesulfonate) Tetrahydrofuran Adduct Zirconocene Chloride Hydride Zirconocene Dichloride C2201 C1994 Ph3P Ru PPh3 Cl 1g 1g 1g 1g 100mg 5g Ti Cl Cl 1g 5g 5g 1g C1995 Cl 5g 5g 1g 1g 5g 100g 1g 25g 100mg 5g 1g 25mL 1g 25g 1g 5g 25g 25g I0646 Cl Zr Cl Cl Cl Ti Cl Cl P1651 CH3 CH3 CH3 CH3 Cl C2201 C1994 C1995 I0646 P1651 82 Ti Cl CH3 Cl Cyclopentadienylbis(triphenylphosphine)ruthenium(II) Chloride Cyclopentadienyltitanium(IV) Trichloride Cyclopentadienylzirconium(IV) Trichloride (Indenyl)titanium(IV) Trichloride (Pentamethylcyclopentadienyl)titanium(IV) Trichloride 1g 1g 1g 5g 5g 5g 1g 1g B4209 B0396 B4697 P1049 D4395 H0842 L0060 L0191 A1478 L0203 L0170 L0267 B2542 H0915 L0186 L0210 L0253 L0224 L0204 L0222 L0171 F0171 L0146 H1057 L0225 H0580 L0144 P0659 S0237 L0133 L0158 L0159 L0164 L0190 T1548 L0240 M1655 L0080 P1429 tert-Butyllithium (ca 18% in Pentane, ca 1.9mol/L) Butyllithium (ca 15% in Hexane, ca 1.6mol/L) Butyllithium (ca 20% in Cyclohexane, ca 2.3mol/L) Dilithium Phthalocyanine Dilithium Tetrachlorocopper(II) (ca 2.5% in Tetrahydrofuran, ca 0.1mol/L) Hexyllithium (30% in Hexane, ca 2.3mol/L) Lithioncarmine (powder) Lithium Acetate Lithium Acetoacetate Lithium Aluminum Hydride (Powder) Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca 2.5mol/L) Lithium Bis(pentafluoroethanesulfonyl)imide Lithium Bis(trifluoromethanesulfonyl)imide Lithium Bis(trimethylsilyl)amide (ca 26% in Tetrahydrofuran, ca 1.3mol/L) Lithium Borohydride (ca 3mol/L in Tetrahydrofuran) Lithium Bromide Lithium tert-Butoxide (ca 10% in Tetrahydrofuran, ca 1mol/L) Lithium Carbonate Lithium Chloride Anhydrous Lithium Chloride (2.3% in Tetrahydrofuran, ca 0.5mol/L) Lithium Diisopropylamide (ca 20% in Tetrahydrofuran/Ethylbenzene/Heptane, ca 1.5mol/L) Lithium Formate Monohydrate Lithium Hexafluorophosphate Lithium 1,1,2,2,3,3-Hexafluoropropane-1,3-disulfonimide Lithium Hydroxide Anhydrous Lithium DL-2-Hydroxybutyrate Lithium L-Lactate Lithium Pyruvate Monohydrate [Guaranteed for Standard to GOT, GPT] Lithium Stearate Lithium Tetrafluoroborate Lithium Tetrakis(pentafluorophenyl)borate - Ethyl Ether Complex Lithium Tri-tert-butoxyaluminum Hydride (ca 30% in Tetrahydrofuran, ca 1.0mol/L) Lithium Tri-sec-butylborohydride (ca 21% in Tetrahydrofuran, ca 1.0mol/L) Lithium Triethylborohydride (ca 12% in Tetrahydrofuran, ca 1.0mol/L) Lithium Trifluoromethanesulfonate Lithium Trifluoro(trifluoromethyl)borate - Dimethyl Carbonate Complex Methyllithium (ca 3-5% in Ethyl Ether, ca 1-2mol/L) (2,4-Pentanedionato)lithium Phenyllithium (ca 16% in Butyl Ether, ca 1.6mol/L) C0075 C0076 C1374 D1331 D0923 D1930 P0973 M0632 M0096 S0489 H0894 S0480 S0396 D1003 D2479 D0716 S0548 S0547 E0195 S0392 S0481 M0057 Chloramine B Hydrate 25g 500g Chloramine T Trihydrate 25g 500g o-Chloramine T 25g 5,5-Diphenylhydantoin Sodium Salt 25g 500g 1g Dipicrylamine Sodium Salt (contains 10% Water) Disodium Dimercaptomaleonitrile 1g 5g Disodium Phthalocyanine 1g 5g 2-Mercaptopyridine N-Oxide Sodium Salt (40% in Water, ca 3.3mol/L) 25g 500g Methyl Mercaptan Sodium Salt (ca 15% in Water) 25g 500g Sodium Azide 100g 100mL 500mL Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca 1.9mol/L) Sodium Borohydride 25g 100g 500g 5g 25g 250g Sodium Cyanoborohydride [Reducing Agent] Sodium Dichloroisocyanurate 25g 500g Sodium Diformylamide 25g 25g 500g Sodium Dimethyldithiocarbamate Dihydrate Sodium Ethoxide (ca 20% in Ethanol) 500mL Sodium Ethoxide 100g Sodium Ethylxanthate 25g 500g Sodium Hexafluorophosphate 25g 100g 500g Sodium Hydride (60%, dispersion in Paraffin Liquid) Sodium 2-Mercaptobenzothiazole 25g 500g 100mL 100mL 500mL 100mL 500mL 1g 100mL 500mL 100mL 1g 25g 500g 1g 5g 25g 100g 100mL 1g 25g 250g 100mL 500mL 100mL 25g 100g 500g 100mL 25g 500g 25g 300g 100mL 100mL 500mL 25g 500g 25g 100g 1g 5g 25g 100g 500g 5g 25g 25g 25g 25g 500g 25g 1g 5g 100mL 100mL 100mL 500mL 25g 1g 5g 100mL 25g 500g 100mL 83 84 S0486 S0485 S0540 A5131 Sodium Methoxide (ca 5mol/L in Methanol) Sodium Methoxide Sodium Tetrachloropalladate(II) Sodium Tetrakis(4-fluorophenyl)borate Hydrate [Precipitation reagent for Cs and titrimetric reagent for A5130 T0193 S0394 B0131 Sodium Tetraphenylborate [Precipitation reagent for K] Sodium 2-Thiobarbiturate Sodium Triacetoxyborohydride o-Sulfobenzimide Sodium Salt Dihydrate A1490 B1124 B4377 C0714 I0223 I0019 I0220 N0428 P0097 P0179 P0403 P1480 H0893 P1681 P1807 P1008 P2155 B0747 P1613 E0194 G0160 H0817 H1058 H0652 P0309 I0023 P1808 I0177 P2153 T1083 N0006 O0056 O0164 P0534 R0058 S0057 S0164 P2168 A5132 P1380 P2114 P1692 P0475 P1479 P0988 P0989 S0156 S0903 A5107 Acesulfame K Bismuthiol II Hydrate Bismuth Tripotassium Dicitrate Carbazole Potassium Salt Indigodisulfonic Acid Dipotassium Salt Indigotetrasulfonic Acid Tetrapotassium Salt Hydrate Indigotrisulfonic Acid Potassium Salt 4-Nitrocatechol Sulfate Dipotassium Salt Hydrate [Substrate for Sulfatase] Phenolphthalein Disulfate Potassium Salt Hydrate N-Phenylglycine Potassium Salt Phthalimide Potassium Salt Potassium Allyltrifluoroborate Potassium Bis(trimethylsilyl)amide (11% in Toluene, ca 0.5mol/L) Potassium Borohydride Potassium (Bromomethyl)trifluoroborate Potassium tert-Butoxide Potassium [[(tert-Butoxycarbonyl)amino]methyl]trifluoroborate Potassium Butylxanthate Potassium Cyanide Potassium Ethylxanthate Potassium Guaiacolsulfonate Hemihydrate Potassium Hexafluoroarsenate Potassium 1,1,2,2,3,3-Hexafluoropropane-1,3-disulfonimide Potassium Hyaluronate from Cockscomb Potassium Hydrogen Phthalate Potassium 3-Indoleacetate Potassium (Iodomethyl)trifluoroborate Potassium Isopropylxanthate Potassium (Methoxymethyl)trifluoroborate Potassium Monomethyl Terephthalate Potassium 1-Naphthaleneacetate Potassium Oleate Potassium Oxonate Potassium Propylxanthate Potassium Rhodizonate Potassium Sorbate Potassium Sulfamate Potassium Tetracyanoborate Potassium Tetrakis(4-chlorophenyl)borate [Anion for the neutral carrier type ion electrode] Potassium Tri-sec-butylborohydride (ca 1.0mol/L in Tetrahydrofuran) Potassium Trifluoroacetate Potassium Trifluoro(trifluoromethyl)borate Potassium Trihydrogen Dioxalate Dihydrate [for Determination of pH] Potassium Vinyltrifluoroborate Pyridoxylidene-L-glutamic Acid Dipotassium Salt Pyridoxylidene-L-isoleucine Potassium Salt Sinigrin Hydrate Sinigrin TBPE (=Tetrabromophenolphthalein Ethyl Ester Potassium Salt) T0036 F0027 Tetrabromofluorescein Potassium Salt Uranine K nonionic surfactants] [Sensitive spectrophotometric reagent for amines, quaternary ammonium salts and other cations] 25g 100mL 500mL 100g 500g 1g 1g 1g 25g 25g 25g 5g 10g 500g 100g 500g 100g 5g 1g 500g 25g 5g 25g 1g 1g 1g 5g 1g 1g 5g 25g 500g 25g 500g 1g 5g 100mL 500mL 25g 100g 1g 5g 25g 100g 500g 1g 5g 25g 25g 25g 100g 500g 25g 10g 1g 5g 1g 25g 500g 1g 25g 1g 5g 25g 1g 25g 500g 25g 25g 500g 5g 25g 25g 1g 25g 500g 100g 200mg 1g 5g Price on request 25g 1g 5g 25g 25g 500g 1g 5g 1g 1g 100mg 100mg 1g 25g 25g F0172 Formic Acid Rubidium Salt C2430 C2202 C2160 C2203 C2204 C2205 Cesium Acetate Cesium Bromide Cesium Carbonate Cesium Chloride Cesium Fluoride Cesium Iodide B0454 B4720 Bis(2,4-pentanedionato)beryllium(II) Bis[2-(2-pyridinyl)phenolato]beryllium(II) A0963 A1554 A0484 A5353 B1883 B3976 B1933 H0556 M0001 T0749 B1884 B1148 B1147 B0726 B4643 C0780 C1504 C1505 D4683 D3551 E0094 E0497 E0134 E0778 E0135 F0673 H0822 H0821 I0517 I0518 I0543 I0542 I0654 E0396 G0276 M0938 P0108 P1018 M2209 S0238 T1304 M0362 M0785 M0364 M0927 O0240 Allylmagnesium Bromide (ca 13% in Ethyl Ether, ca 0.7mol/L) Allylmagnesium Chloride (ca 11% in Tetrahydrofuran, ca 1.0mol/L) 8-Anilino-1-naphthalenesulfonic Acid Magnesium(II) Salt Hydrate ANS-Mg (=Magnesium 8-Anilino-1-naphthalenesulfonate) [Hydrophobic fluorescent probe] Benzylmagnesium Bromide (ca 12% in Tetrahydrofuran, ca 0.6mol/L) Benzylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 0.9mol/L) Benzylmagnesium Chloride (ca 16% in Tetrahydrofuran, ca 1mol/L) Bis(hexafluoroacetylacetonato)magnesium(II) Hydrate Bis(2,4-pentanedionato)magnesium(II) Bis(trifluoro-2,4-pentanedionato)magnesium(II) Hydrate sec-Butylmagnesium Bromide (ca 16% in Tetrahydrofuran, ca 1mol/L) tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca 2mol/L) tert-Butylmagnesium Chloride (26% in Ethyl Ether, ca 2mol/L) Butylmagnesium Chloride (23% in Tetrahydrofuran, ca 2mol/L) sec-Butylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca 1.2mol/L) Chlorophyll (Total Chlorophyll: ca 6.0%) Cyclohexylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 1mol/L) Cyclopentylmagnesium Bromide (ca 18% in Tetrahydrofuran, ca 1mol/L) Di-sec-butylmagnesium - Lithium Chloride (13% in Tetrahydrofuran, ca 0.8mol/L) (2,5-Dimethylphenyl)magnesium Bromide (20% in Tetrahydrofuran, ca 1mol/L) Ethylenediaminetetraacetic Acid Magnesium Disodium Salt Hydrate Ethylmagnesium Bromide (13% in Tetrahydrofuran, ca 1mol/L) Ethylmagnesium Bromide (39% in Ethyl Ether, ca 3mol/L) Ethylmagnesium Chloride (ca 1.0mol/L in Tetrahydrofuran) activated with Zinc Chloride (ca 10mol%) Ethylmagnesium Chloride (ca 18% in Tetrahydrofuran, ca 2mol/L) 4-Fluorophenylmagnesium Bromide (ca 19% in Tetrahydrofuran, ca 1.0mol/L) Heptylmagnesium Bromide (21% in Tetrahydrofuran, ca 1mol/L) Hexylmagnesium Bromide (20% in Tetrahydrofuran, ca 1mol/L) Isobutylmagnesium Bromide (17% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Bromide (15% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Chloride (ca 11% in Tetrahydrofuran, ca 1mol/L) Isopropylmagnesium Chloride (ca 13% in Ethyl Ether, ca 1mol/L) Isopropylmagnesium Chloride - Lithium Chloride (15% in Tetrahydrofuran, ca 1mol/L) Magnesium(II) 2-Ethylbutyrate Magnesium(II) Gluconate Hydrate Magnesium 4-Nitrobenzyl Malonate Hydrate Magnesium Phenoxyacetate Dihydrate Magnesium(II) Phthalocyanine Magnesium Porphyrin Magnesium(II) Stearate Magnesium Trifluoromethanesulfonate Methylmagnesium Bromide (12% in Tetrahydrofuran, ca 1mol/L) Methylmagnesium Bromide (35% in Ethyl Ether, ca 3mol/L) Methylmagnesium Iodide (33% in Ethyl Ether, ca 2mol/L) Monoperoxyphthalic Acid Magnesium Salt Hexahydrate n-Octylmagnesium Bromide (ca 22% in Tetrahydrofuran, ca 1mol/L) 5g 25g 25g 25g 25g 100g 25g 100g 100g 100g 25g 5g 200mg 100mL 100g 25g 1g Price on request 100g 250g 1g 25g 5g 100g 250g 250g 250g 100mL 25g 100g 100g 100mL 100g 25g 250g 250g 250g 250g 250g 250g 250g 250g 250g 250g 250g 100mL 25g 25g 500g 25g 25g 1g 100mg 25g 250g 5g 25g 250g 250g 100g 25g 500g 250g 85 86 P1251 P1177 P2025 P1381 P0191 P0880 T1698 T1699 T1700 T2966 T1451 T2609 V0053 Pentadecylmagnesium Bromide (ca 15% in Tetrahydrofuran, ca 0.4mol/L) Pentylmagnesium Bromide (18% in Tetrahydrofuran, ca 1mol/L) Phenylmagnesium Bromide (16% in Tetrahydrofuran, ca 1mol/L) Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca 2mol/L) Phenylmagnesium Iodide (ca 42% in Ethyl Ether, ca 2mol/L) Propylmagnesium Bromide (ca 27% in Tetrahydrofuran, ca 2mol/L) o-Tolylmagnesium Bromide (ca 17% in Tetrahydrofuran, ca 0.9mol/L) m-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca 1mol/L) p-Tolylmagnesium Bromide (19% in Tetrahydrofuran, ca 1mol/L) Trimagnesium Dicitrate Nonahydrate Trimethylsilylmethylmagnesium Chloride (20% in Ethyl Ether, ca 1mol/L) Trimethylsilylmethylmagnesium Chloride (ca 18% in Tetrahydrofuran, ca 1mol/L) Vinylmagnesium Bromide (14% in Tetrahydrofuran, ca 1mol/L) 250g 250g 250g 250g 250g 250g 100g 100g 100g 25g 500g 100mL 100mL 100g A0422 A2476 C0930 A0738 C2789 G0037 G0232 G0095 G0200 H0917 H0651 L0006 L0043 O0076 M0548 M0549 K0021 K0022 K0023 P0012 C2003 P0503 S0054 S0236 T0002 T0004 T0902 T1799 C0849 D1869 E0088 F0372 L0075 P0274 P0410 4-Aminosalicylic Acid Calcium Salt Heptahydrate Atorvastatin Calcium Salt Trihydrate Bis(2,4-pentanedionato)calcium(II) Calcium Alginate Calcium Dobesilate Hydrate Calcium Gluconate Monohydrate Calcium DL-Glycerate Hydrate Calcium Glycerophosphate Hydrate Calcium Glycolate Calcium 3-Hydroxy-3-methylbutyrate Hydrate Calcium 2-Hydroxy-4-(methylthio)butyrate Calcium Lactobionate Hydrate Calcium Levulinate Dihydrate Calcium Mesoxalate Trihydrate Calcium Methacrylate Hydrate Calcium Methanesulfonate Calcium 3-Methyl-2-oxobutyrate Hydrate Calcium 3-Methyl-2-oxovalerate Hydrate Calcium 4-Methyl-2-oxovalerate Hydrate Calcium D-Pantothenate Calcium Phthalate Hydrate Calcium Propionate Calcium Sorbate Calcium Stearate Calcium DL-Tartrate Tetrahydrate Calcium meso-Tartrate Trihydrate Calcium Thioglycolate Trihydrate Calcium L-Threonate 4-Chlorobenzoyl-L-tryptophan Calcium Salt Diethylenetriaminepentaacetic Acid Calcium Trisodium Salt Hydrate Ethylenediaminetetraacetic Acid Calcium Disodium Salt Hydrate Fenoprofen Calcium Salt Dihydrate Lithol Rubin BCA Phosphocholine Chloride Calcium Salt Tetrahydrate Phytin 25g 1g A0760 C0078 C0978 D0876 E0085 S0235 G0052 I0039 L0074 M0046 P0257 P0258 R0026 Barium Acrylate Monomer Barium Chloranilate Trihydrate Barium 2-Cyanoethylphosphate Hydrate [Phosphorylating Agent] Barium Diphenylamine-4-sulfonate Barium Disodium Ethylenediaminetetraacetate Hydrate Barium Stearate D-Glucose 6-Phosphate Barium Salt Heptahydrate Inosine -Monophosphate Barium Salt Hydrate Lake Red CBA Mannose-6-phosphate Barium Salt Hydrate 6-Phosphogluconate Barium Salt Hydrate 3-Phospho-D-glyceric Acid Barium Salt Dihydrate Ribose-5-phosphate Barium Salt Hydrate 25g 25g 25g 25g 5g 5g 25g 5g 25g 25g 1g 25g 25g 25g 25g 500g 5g 25g 500g 1g 500g 10g 500g 25g 25g 25g 25g 25g 5g 25g 500g 5g 25g 25g 500g 25g 500g 25g 500g 25g 25g 500g 25g 25g 25g 500g 25g 25g 250g 500g 25g 25g 5g 25g 1g 5g 25g 25g 25g 500g 100mg 1g 100mg 25g 100mg Price on request 1g 100mg 1g A0244 A0804 A1831 A0245 A1200 A0246 B1895 D1340 D2972 D2971 E0648 L0203 L0170 L0159 M1211 M0468 M0469 C1167 P2280 P1944 S0467 C1411 T0783 T0925 T0784 T0782 T1575 A0241 T2238 T1527 A1267 Aluminum sec-Butoxide 25g 500g 5g Aluminum tert-Butoxide Aluminum(III) Chloride 100g 500g Aluminum Ethoxide 25g 250g Aluminum Glycinate 25g 500g Aluminum Isopropoxide 100g 500g Bis(2-ethylhexanoato)hydroxyaluminum 25g 250g 100mL Diethylaluminum Chloride (ca 15% in Hexane, ca 0.87mol/L) Diisobutylaluminum Hydride (17% in Toluene, ca 1.0mol/L) 100mL 500mL 100mL 500mL Diisobutylaluminum Hydride (19% in Hexane, ca 1.0mol/L) Ethylaluminum Dichloride (17% in Hexane, ca 1mol/L) 100mL 25g 100g Lithium Aluminum Hydride (Powder) Lithium Aluminum Hydride (10% in Tetrahydrofuran, ca 2.5mol/L) 100mL Lithium Tri-tert-butoxyaluminum Hydride (ca 30% in Tetrahydrofuran, ca 1.0mol/L) 100mL 50mL Methylaluminum Bis(2,6-di-tert-butyl-4-methylphenoxide) (0.4mol/L in Toluene) Mucicarmine 25g Mucicarmine Solution acc to Mayer 500mL Phthalocyanine Chloroaluminum 1g 1g 5g Polydimethylsilane supported Palladium/Alumina Hybrid Catalyst [=Pd / (PMPSi-Al2O3)] 1g Poly(methylphenyl)silane supported Palladium/Alumina Hybrid Catalyst [=Pd / (PSi-Al2O3)] 25g 100g 500g Sodium Bis(2-methoxyethoxy)aluminum Dihydride (70% in Toluene, ca 3.6mol/L) Tebbe Reagent (ca 0.5mol/L in Toluene) 25mL 100mL Triethylaluminum (15% in Hexane, ca 1.0mol/L) 100mL Triethylaluminum (15% in Toluene, ca 1.1mol/L) Triisobutylaluminum (15% in Hexane, ca 0.50mol/L) 100mL 100mL Trimethylaluminum (15% in Hexane, ca 1.4mol/L) 100mL Trimethylaluminum (15% in Toluene, ca 1.8mol/L) Tris(2,4-pentanedionato)aluminum(III) 25g 100g 500g 5g Tris(8-quinolinolato)aluminum (purified by sublimation) Tris(8-quinolinolato)aluminum 25g 250g Tris(trifluoro-2,4-pentanedionato)aluminum(III) 5g 25g G0359 Gallium(III) Chloride Anhydrous 5g 25g I0778 I0020 Indium(III) Chloride Anhydrous Tris(2,4-pentanedionato)indium(III) 5g 25g 10g C0954 T1351 Cyclopentadienyl Thallium Thallium(III) Trifluoroacetate A2170 A1222 A1491 B4685 B4437 B4378 T0650 B1974 B1975 B0907 B1832 B4536 B4453 D2466 Allenyltributyltin Allyltributyltin Allyltriphenyltin 4,8-Bis(2-butyl-n-octyloxy)-2,6-bis(trimethylstannyl)benzo[1,2-b:4,5-b ]dithiophene 4,8-Bis[5-(2-ethylhexyl)thiophen-2-yl]-2,6-bis(trimethylstannyl)benzo[1,2-b:4,5-b ]dithiophene 4,8-Bis(n-octyloxy)-2,6-bis(trimethylstannyl)benzo[1,2-b:4,5-b ]dithiophene Bis(2,4-pentanedionato)tin(IV) Dichloride Bis(tributylstannyl)acetylene trans-1,2-Bis(tributylstannyl)ethylene Bis(tributylstannyl) Sulfide Bis(tributyltin) 2,5-Bis(trimethylstannyl)thieno[3,2-b]thiophene 4,7-Bis(5-trimethylstannyl-2-thienyl)-2,1,3-benzothiadiazole Dibutyltin Bis(trifluoromethanesulfonate) 5g 10g 5g 5g 1g 1g 1g 5g 200mg 1g 25g 25g 200mg 200mg 200mg 25g 5g 5g 5g 25g 1g 200mg 5g 87 88 D0302 D0223 D0303 D0304 D0305 D1338 D4649 D1373 D2358 H1312 M1494 M0744 P1282 S0909 T2009 T1592 T0058 T0919 T0165 T2053 T3149 T2940 P1024 P0997 T1194 T3191 T1750 T1797 T2995 T3046 T1736 T1798 T0677 T0363 T0678 T1473 T1865 T1866 T1794 T1742 T1928 T0958 T0447 Dibutyltin Diacetate Dibutyltin Dichloride Dibutyltin Dilaurate Dibutyltin Maleate (so called) [for PVC stabilizer] Dibutyltin Oxide Dimethyltin Dichloride Dimethyltin Oxide Di-n-octyltin Oxide Diphenyltin Sulfide [Activator for O-Glycoside Synthesis] Hexamethylditin Methyl Tributylstannyl Sulfide Monobutyltin Oxide Phenyltin Trichloride SnAP-TM Reagent Tetraallyltin Tetrabutylammonium Difluorotriphenylstannate Tetrabutyltin Tetramethyltin Tetraphenyltin Tin(IV) Chloride (ca 1.0mol/L in Dichloromethane) Tin(II) 2-Ethylhexanoate Tin(IV) 2,3-Naphthalocyanine Dichloride Tin(II) Phthalocyanine Tin(IV) Phthalocyanine Dichloride Tin(II) Trifluoromethanesulfonate Tributyl(1-ethoxyvinyl)tin Tributylethynyltin Tributyl(2-furyl)tin Tributyl(4-methoxy-2-pyridyl)tin Tributyl(1-phenyl-5-pyrazolyl)tin Tributyl(2-pyridyl)tin Tributyl(2-thienyl)tin Tributyltin Acetate Tributyltin Chloride Tributyltin Fluoride Tributyltin Hydride (stabilized with BHT) [Reducing Reagent] Tributyl(trimethylsilylethynyl)tin Tributyl(trimethylsilylmethyl)tin Tributylvinyltin Trimethyl(2-pyridyl)tin Trimethyl(4-pyridyl)tin Trimethyltin Chloride Triphenyltin Chloride E0093 L0279 N0339 L0230 P0766 L0021 T0164 Ethylenediaminetetraacetic Acid Lead(II) Disodium Salt Hydrate Lead(II) Iodide [for Perovskite precursor] Lead Naphthenate Lead(II) Phthalocyanine (purified by sublimation) Lead(II) Phthalocyanine Lead Tetraacetate (contains Acetic Acid) Tetraphenyl Lead 25g 25g 25g 100g 25g 100g 25g 100g 25g 25g 25g 1g 25g 25g 5g 200mg 1g 1g 25g 5g 100g 200mg 1g 1g 1g 25g 5g 1g 1g 1g 1g 5g 5g 100g 25g 5g 1g 5g 1g 1g 5g 25g 1g 200mg 1g 25g 500g 500g 500g 500g 500g 500g 100g 500g 1g 5g 100g 500g 25g 1g 5g 5g 500g 25g 25g 100mL 500g 1g 5g 1g 25g 5g 5g 5g 5g 5g 25g 25g 25g 500g 25g 250g 25g 5g 25g 5g 5g 25g 5g 500g 5g 25g 1g 25g 500g 5g OTMS + Ph HCHO aq Yb(OTf)3 (20 mol%) [T1610] H2O – THF 1) O Ph OH Y 1st run 2nd run 3rd run 94% 91% 93% 2) Yb(OTf)3 (20 mol%) [T1610] CHO + CHO CH2Cl2, °C Y 1st run 2nd run T1918 T1292 O CF3 CF3 CF3 T1921 T1920 CF3 S OAg O La3 S O O CF3 T1610 O O Sc3 S O CF3 InCl3 O Tm3 S O O CF3 Yb3 S O O xH2O T1294 O CF3 O T1331 O O Hf4 S O O Nd3 S O O CF3 T1663 O T1293 O Cu2 S O O T1919 CF3 I0778 O Ce3 S O O T1708 77% (exo : endo = 93 : 7) 75% (exo : endo = 92 : 8) O Y3 S O O CF3 Zn2 S O O 89 T1918 T1292 T1708 I0778 T1293 T1919 T1663 T1331 T1920 T1610 T1921 T1294 Cerium(III) Trifluoromethanesulfonate Copper(II) Trifluoromethanesulfonate Hafnium(IV) Trifluoromethanesulfonate Indium(III) Chloride Anhydrous Lanthanum(III) Trifluoromethanesulfonate Neodymium(III) Trifluoromethanesulfonate Scandium(III) Trifluoromethanesulfonate Silver Trifluoromethanesulfonate Thulium(III) Trifluoromethanesulfonate Ytterbium(III) Trifluoromethanesulfonate Hydrate Yttrium(III) Trifluoromethanesulfonate Zinc(II) Trifluoromethanesulfonate 5g 5g 1g 5g 5g 5g 1g 10g 5g 5g 1991 25g 25g 5g 25g 25g 25g 5g 25g 5g 25g 25g 25g 1992 1992 1994 1995 1998 2000 2001 2007 90 A0005 B2283 B2281 O CH2CH2 F C0572 C0513 F C0468 C0503 C0505 C1689 D0443 H0084 H0087 I0016 I0354 CH3 CH3 CH2 CH2 CH3 CH3 CH3 CH3 CH3 CH3 M1425 M1411 CH3 CH3 N0346 N0166 P1292 CH3 CH3 CH3 CH3 CH3 CH3 CH3 P1633 T1333 T0470 CH3 CH3 A0005 B2283 B2281 C0572 C0468 C0503 C0505 C1689 C0513 D0443 H0084 H0087 I0016 I0354 CH3 Acenaphthylene trans,trans-1,5-Bis(4-fluorophenyl)-1,4-pentadien-3-one 1,2-Bis(3-indenyl)ethane 1,3,5-Cycloheptatriene 1,4-Cyclohexadiene (stabilized with BHT) 1,5-Cyclooctadiene [stabilized with Octadecyl 3-(3 ,5 -Di-tert-butyl-4 -hydroxyphenyl)propionate] 1,3,5,7-Cyclooctatetraene (stabilized with HQ) 1H-Cyclopenta[l]phenanthrene p-Cymene Dicyclopentadiene (stabilized with BHT) [precursor to Cyclopentadiene] 1,5-Hexadiene Hexamethylbenzene Indene Indene 5g 1g 10mL 25mL 100mL 1mL 100mg 25mL 25mL 25mL 25mL 100mL 25g 25g 5g 25mL 25mL 500mL 5mL 1g 500mL 500mL 500mL 5g 500mL 25mL 91 2-Methylbenzo[e]indene (mixture of 1H- and 3H-form) 2-Methylcyclopenta[l]phenanthrene 2,5-Norbornadiene (stabilized with BHT) 2-Norbornene 1,2,3,4,5-Pentamethylcyclopentadiene 1,2,3,4,5-Pentaphenyl-1,3-cyclopentadiene 1,2,3,4-Tetraphenyl-1,3-cyclopentadiene 1,3,5-Trimethylbenzene M1425 M1411 N0346 N0166 P1292 P1633 T1333 T0470 100mg 1g 100mg 1g 25mL 100mL 500mL 25g 400g 5mL 25mL 100mg 1g 1g 5g 25mL 500mL P0052 A0881 A0869 O O CH3 B1733 B1457 O O O O C CH2 C O B3382 C1277 D0039 CH3 CH3 O D1729 O O CH3 E0405 O CH3 C CH2 C C CH3 O Cl CH3 D1678 O CH3 O CH3 C CH2 C CH3 CH3 F0083 H1395 O O CH3 O CH3 CH3 CH3 H0476 C CH2 C N O CH3 O O O O C CH2 C CF3 O O CH3 CH3 CH3 N O M1272 O CH3 O D2512 O O O C CH3 C CH3 O O CH3 CH C CH3 CH3 D0910 CH3 CH3 CH3O CH3 D2413 CF3(CF2)2 C CH2 C C CH3 O O O OCH3 C CH3 CH3 O CH3O O C CH3 O C CH2 C CH3 O CH3 CH3 CF3 CF3 CH3 M0597 M1132 P0160 P1297 T2037 O CH3 O O O CH3 CH3 T0434 92 CH3 O CH3 CH3 O CH3 CH2 CH3 C (CF2)6CF3 C (CF2)6CF3 O T0437 O O O CH3 C CH2 C CH3 T1583 O CF3 O O T0438 O O CF3 F3C T2997 O O O S O C CH2 C CF3 O CF3 CH3 P0052 A0881 A0869 B1733 B1457 B3382 C1277 D0039 D1729 D2413 D0910 D1678 D2512 E0405 F0083 H1395 H0476 M1272 M0597 M1132 P0160 P1297 T2037 T0434 T1583 T0437 T0438 T2997 Acetylacetone 2-Acetylcyclohexanone 2-Acetylcyclopentanone 1,3-Bis(4-methoxyphenyl)-1,3-propanedione 3-Butyl-2,4-pentanedione 1-(4-tert-Butylphenyl)-3-(4-methoxyphenyl)-1,3-propanedione 3-Chloroacetylacetone Dehydroacetic Acid 2,2-Dimethyl-6,6,7,7,8,8,8-heptafluoro-3,5-octanedione 2,6-Dimethyl-3,5-heptanedione 1,3-Diphenyl-1,3-propanedione Dipivaloylmethane 1,3-Di(2-pyridyl)-1,3-propanedione 3-Ethyl-2,4-pentanedione 2-Furoyltrifluoroacetone 3,5-Heptanedione Hexafluoroacetylacetone 1-(2-Mesitylene)-1,3-butanedione 6-Methyl-2,4-heptanedione 3-Methyl-2,4-pentanedione 1-Phenyl-1,3-butanedione 3-Phenyl-2,4-pentanedione 9H,9H-Triacontafluoro-8,10-heptadecanedione Trifluoroacetylacetone 4,4,4-Trifluoro-1-(2-naphthyl)-1,3-butanedione 4,4,4-Trifluoro-1-phenyl-1,3-butanedione 4,4,4-Trifluoro-1-(2-thienyl)-1,3-butanedione 4,4,4-Trifluoro-1-(p-tolyl)-1,3-butanedione B2652 25g 5g B2653 N OH (CH3)3C C(CH3)3 (CH3)3C OH C(CH3)3 (CH3)3C B2619 B3015 H3C CH3 H3C CH3 N N (CH3)3C (CH3)3C C(CH3)3 HO CH N OH HO OH OH N N C(CH3)3 D2572 NCH2CH2N CH HO CH3 CH3 C CH3 OH CH3 HO C CH3 C CH3 CH3 C CH3 CH3 CH3 CH3 D1307 CH N OH N CH3 HO C(CH3)3 (CH3)3C H0199 N OH HO B4418 N N HO 25mL 500mL 10mL 25mL 25mL 5g 25g 5mL 25g 100g 25g 25g 500g 5g 5g 25g 25g 500g 5g 25g 1g 5g 5mL 5g 25g 5g 25g 5g 25g 5g 25g 5mL 5mL 25mL 100g 500g 1g 5g 100mg 25g 100g 10g 25g 25g 25g 500g 5g 25g OH N CH HO HO CH3 CH N CH2 CH N CH C(CH3)3 D1422 OH HO CH N B2652 B2653 B4418 B2619 B3015 H0199 (CH2)3 N CH (1R,2R,4R,5R)-2,5-Bis(3,5-di-tert-butyl-2-hydroxybenzylideneamino)bicyclo[2.2.1]heptane (1S,2S,4S,5S)-2,5-Bis(3,5-di-tert-butyl-2-hydroxybenzylideneamino)bicyclo[2.2.1]heptane (R,R)-(-)-N,N -Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine N,N -Bis(3,5-di-tert-butylsalicylidene)-1,1,2,2-tetramethylethylenediamine N,N -Bis(5-hydroxysalicylidene)ethylenediamine N,N -Bis(salicylidene)ethylenediamine 5g 1g 1g 25g 100mg 100mg 25g 5g 5g 500g 93 N,N -Bis(salicylidene)-1,2-phenylenediamine N,N -Bis(salicylidene)-1,2-propanediamine N,N -Bis(salicylidene)-1,3-propanediamine D2572 D1307 D1422 5g A1548 A1699 NH SO2 D2521 B2316 F3CO2SHN NHSO2CF3 D3716 CH3 NH2 CH3 CH3 NH2 CH3 CH3 D2395 N C CH(C6H5)2 N C CH2C(C6H5)3 N C CH2C(C6H5)3 OH O OH O OH O D2176 N(CH3)2 (CH3)2N N(CH3)2 OCH3 OCH3 D2175 E0077 NH2 NH2 NH2 H2N H1215 NH2 H0093 M2476 M2090 H N NH NH HN NH HN N H N 6HCl N NH N O CH3(CH2)7 N O CH3 O N N N (CH2)7CH3 (CH2)7CH3 (CH2)7CH3 CH3 O N HO OH N H Q0062 S0884 S0461 N N H T1426 H 4HCl O CH3CH2O C CH2 T1874 H N T2540 HN OCH3 OCH3 (CH3)2N NHCH2CH2NH CH3 NH2 N H D2396 NH2 HN H2N N N C CH2C(C6H5)3 HN NHSO2CF3 D0493 CH3 OH O HN CH3 N NH2 N C CH2C(C6H5)3 H N NH SO2 CH3 OH O H N NH CH3 CH3 NH2 N C CH(C6H5)2 N H NH CH3 D3720 D0887 F3CO2SHN D0134 OH O H1070 94 CH3 D3719 D0720 CH3 CH3 B2317 CH3 D2520 NH2 NH2 25g 25g 25g N NH N NH H T1289 O CH2 C OCH2CH3 N N O N CH2 C OCH2CH3 N O CH2 C OCH2CH3 N CH3 HN O HO C CH2 N CH3 N CH3 N N O CH2 C OH N CH2 C OH O T0548 CH3 CH3 O CH2 C OH N HN T0537 CH3 CH3 T1875 N CH3 CH3 CH3 CH3 N N CH3 T0147 T1877 CH3 CH3 CH3 N N CH3 T1876 N N CH3 N T2541 T2642 O CH3 CH2 C OC(CH3)3 HN HN NH CH3 NH N O HO C CH2 H N H N N CH3 T1878 O N N CH2 C OC(CH3)3 N CH2 C OC(CH3)3 O T0429 B4304 T1879 T1243 O CH2 C OC(CH3)3 N HN O N CH2 C OC(CH3)3 N H2N N H H N NH2 CH3 H N N CH3 H N CH3 CH3 N N CH3 N H2N H2N N NH2 CH3 CH2 C OC(CH3)3 O T2898 CH3 CH3 N CH3 A1548 A1699 D2520 D2521 B2316 B2317 D0134 D0493 D3716 D3719 D3720 D2395 D2396 D0720 D0887 D2176 D2175 E0077 H1070 H1215 H0093 M2476 M2090 Q0062 S0884 S0461 T1874 T1875 T1426 T2540 T1289 T0537 T0548 T0147 T1877 T1876 T1878 T2642 T2541 T0429 N N CH3 N CH3 CH3 (R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide (S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide (R,R)-N,N -Bis(trifluoromethanesulfonyl)-1,2-diphenylethylenediamine (S,S)-N,N -Bis(trifluoromethanesulfonyl)-1,2-diphenylethylenediamine (1R,2R)-1,2-Bis(2,4,6-trimethylphenyl)ethylenediamine (1S,2S)-1,2-Bis(2,4,6-trimethylphenyl)ethylenediamine 1,4-Diazabicyclo[2.2.2]octane Diethylenetriamine (1S,2S)-N,N -Dihydroxy-N,N -bis(diphenylacetyl)cyclohexane-1,2-diamine (1R,2R)-N,N -Dihydroxy-N,N -bis(3,3,3-triphenylpropionyl)cyclohexane-1,2-diamine (1S,2S)-N,N -Dihydroxy-N,N -bis(3,3,3-triphenylpropionyl)cyclohexane-1,2-diamine (R,R)-(-)-2,3-Dimethoxy-1,4-bis(dimethylamino)butane (S,S)-(+)-2,3-Dimethoxy-1,4-bis(dimethylamino)butane N,N -Dimethylethylenediamine N,N -Diphenylethylenediamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1S,2S)-(-)-1,2-Diphenylethylenediamine Ethylenediamine Anhydrous 1,4,7,10,13,16-Hexaazacyclooctadecane 1,4,7,10,13,16-Hexaazacyclooctadecane Hexahydrochloride Hexamethylenetetramine 2,2 -(Methylimino)bis(N,N-di-n-octylacetamide) N-Methyliminodiacetic Acid Quinuclidine (+)-Sparteine (-)-Sparteine 1,4,7,10-Tetraazacyclododecane 1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetraacetic Acid 1,4,7,10-Tetraazacyclododecane Tetrahydrochloride Tetraethyl 1,4,8,11-Tetraazacyclotetradecane-1,4,8,11-tetraacetate N,N,N ,N -Tetramethyl-1,4-diaminobutane N,N,N ,N -Tetramethyl-1,6-diaminohexane N,N,N ,N -Tetramethyl-1,3-diaminopropane N,N,N ,N -Tetramethylethylenediamine 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane 1,5,9-Triazacyclododecane 1,4,7-Triazacyclononane Tri-tert-butyl 1,4,7,10-Tetraazacyclododecane-1,4,7,10-tetraacetate Tri-tert-butyl 1,4,7,10-Tetraazacyclododecane-1,4,7-triacetate Triethylenetetramine 100mg 100mg 25g 100g 25mL 1g 1g 5mL 1g 1g 25mL 25g 1mL 5g 200mg 1g 200mg 1g 25mL 25mL 25mL 200mg 200mg 1g 100mg 25mL 1g 1g 1g 1g 500mg 500mg 500g 500mL 100mg 100mg 100mg 5g 5g 25mL 25g 5g 5g 500mL 100mg 100mg 500g 5mL 25g 1g 1g 1g 5g 1g 5g 200mg 25mL 500mL 500mL 500mL 1g 100mg 5g 1g 200mg 500mL 95 N,N ,N -Trimethyldiethylenetriamine 1,4,7-Trimethyl-1,4,7-triazacyclononane (stabilized with NaHCO3) Tris(2-aminoethyl)amine Tris[2-(dimethylamino)ethyl]amine B4304 T1879 T1243 T2898 A0261 5mL 1g 5g 25mL 100mL 1g 5g B3197 B4196 CH3 CH3 R H2N NH2 CH N CH2CH2 N CH R Fe CH N R= Fe CH3 CH3 O O N O CH3 D4273 D4168 D4652 D3822 CH3 N N H2N S O N S NH2 S N O Br N CH3 CH3 H0291 I0001 N OH D2823 N O C N O O C F N F N NH FF HN F CH3CH2 FF F CH2CH3 A5019 CH2 C(CH3)3 F CH2CH3 NH N N F F T1495 T1438 T1815 HO Cl NH N Cl NH OR N HN HO N N T1497 CH3O NH HO Cl Cl N HN CH3O N N HN OH CH3O NH N N HN OCH3 F OCH3 F F F OH OCH3 N N HN F F CH3 F CH3 H3C F NH F F OCH3 CH3O 96 NH OH T1729 F F HO OH Cl T1730 OCH3 OCH3 N OH N HO T1360 OH NH N HN HN Cl OR OCH3 OH Cl Cl RO R = CH2CO2H CH3O N HN N CH N T1832 HO CH N N OH CH N N OH N N FF F O N S0328 O N O N P1795 P0355 F FF O N OR HS C(CH3)3 S O FF S0267 OH N M1402 N CH3CH2 F F N HN FF CH2CH3 C(CH3)3 O N F NH N F CH3CH2 F F F CH2CH3 CH3CH2 O N M1401 P1947 CH2CH3 CH3 C O N C(CH3)3 O N O0319 CH3CH2 F CH3 S O0234 CH3 O N N H N N CH N CH3 C O M1390 CH3 CH3 OH I0567 CH3 OH I0582 CH3 CH3 CH3 CH3 I0795 O S CH3 CH3 Br N CH N Fe PPh2 O CH3 H0973 CH3 F0893 CH3 N N OH N F F F F F F F F CH3 H3C CH3 CH3 CH3 NH N N HN CH3 CH3 CH3 CH3 T1358 T1359 T2222 T0830 T2993 N N NH N N NH N HN N NH N HN N N N N HN N N N N H N N N N N N N S N N,N -Bis(2-aminobenzal)ethylenediamine 1g 100mg 500mg (S,S )-2,2 -Bis[(S)-4-isopropyloxazolin-2-yl]-1,1 -biferrocene 20mg (S,S)-4,6-Bis(4-isopropyl-2-oxazolin-2-yl)-m-xylene 2,2 -Diamino-4,4 -bithiazole 200mg 1g 2,4-Dibromo-6-[[[[(4S,5S)-4,5-dihydro-4,5-diphenyl-1-tosyl-1H-imidazol-2-yl]methyl]50mg [(S)-1-phenylethyl]amino]methyl]phenol trans-2,6-Diisopropyl-N-(2-pyridylmethylene)aniline 200mg 1g (S)-1-(Diphenylphosphino)-2-[(S)-4-isopropyloxazolin-2-yl]ferrocene 200mg 1g 1g 5g 4-Fluoro-N-salicylideneaniline 2-(2-Hydroxyphenyl)benzothiazole 5g 25g 2-(2-Hydroxyphenyl)benzoxazole 1g 25g Imidazole 25g 100g 500g 100mg (R,R)-(+)-2,2 -Isopropylidenebis(4-tert-butyl-2-oxazoline) 100mg 1g (S,S)-(-)-2,2 -Isopropylidenebis(4-tert-butyl-2-oxazoline) 250mg 1g 5g (R,R)-2,2 -Isopropylidenebis(4-phenyl-2-oxazoline) 250mg 1g (S,S)-2,2 -Isopropylidenebis(4-phenyl-2-oxazoline) 2,2 -Methylenebisbenzothiazole 5g 25g (+)-2,2 -Methylenebis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole] 100mg 500mg (-)-2,2 -Methylenebis[(3aS,8aR)-3a,8a-dihydro-8H-indeno[1,2-d]oxazole] 100mg 500mg 2,3,7,8,12,13,17,18-Octaethylporphyrin 100mg 1g 2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin 100mg 200mg 1g (4S,4 S)-2,2 -(Pentane-3,3 -diyl)bis(4-benzyl-4,5-dihydrooxazole) 1g Phthalocyanine (purified by sublimation) Phthalocyanine 25g 2-Salicylideneaminophenol 5g 25g Salicylideneamino-2-thiophenol 1g 5g N-Salicylideneaniline 25g 5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin 100mg 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin 100mg 5,10,15,20-Tetrakis(3,5-dihydroxyphenyl)porphyrin 100mg 1g 5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin 100mg 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin 100mg 5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrin 100mg 1g 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin 100mg 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)porphyrin 100mg 1g meso-Tetraphenylchlorin 100mg Tetraphenylporphyrin (Chlorin free) 1g 5,10,15,20-Tetra(4-pyridyl)porphyrin 1g 2-(4-Thiazolyl)benzimidazole 25g 250g 1g 5g Tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine A0261 B3197 B4196 D4273 D4168 D4652 D3822 F0893 H0973 H0291 I0001 I0795 I0567 D2823 I0582 M1390 M1401 M1402 O0234 O0319 P1947 P1795 P0355 S0328 A5019 S0267 T1495 T1438 T1815 T1832 T1497 T1360 T1730 T1729 T1358 T1359 T2222 T0830 T2993 B3510 B3934 N N H B2217 B2218 O O N N N N O CH3 CH3 CH3 CH3 CH3 O N HN O N NH O N N N B2220 O O N CH3 N NH B2219 CH3 CH3 N N H B4227 O N N N B4228 O N N N O O N N N HN CH3 CH3 97 B4104 D4652 D2037 CH3 N O CH3 N N N D3640 N CH3 CH3 L0085 L0065 CH3 N H N N L0067 N N CH3 CH3 T1487 N N N N CH2 N N N N N N CH2 N H N CH2 N N CH2 2,6-Bis(2-benzimidazolyl)pyridine 2,6-Bis[(2R,4S,5S)-1-benzyl-4,5-diphenylimidazolidin-2-yl]pyridine 2,6-Bis[(2S,5S)-4,4-diphenyl-1-aza-3-oxabicyclo[3.3.0]octan-2-yl]pyridine (R,R)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine (S,S)-2,6-Bis(4-isopropyl-2-oxazolin-2-yl)pyridine 2,6-Bis[(2S,4S)-4-methyl-5,5-diphenyloxazolidin-2-yl]pyridine (R,R)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine (S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine (S)-4-tert-Butyl-2-(2-pyridyl)oxazoline trans-2,6-Diisopropyl-N-(2-pyridylmethylene)aniline 3,5-Di(2-pyridyl)pyrazole 3,6-Di(2-pyridyl)-1,2,4,5-tetrazine 2,3-Lutidine 2,4-Lutidine 2,5-Lutidine 2,6-Lutidine 3,4-Lutidine 3,5-Lutidine 2-(2-Pyridyl)benzoxazole N,N,N ,N -Tetrakis(2-pyridylmethyl)ethylenediamine 2-(1H-1,2,4-Triazol-3-yl)pyridine Tris(2-pyridylmethyl)amine B1077 KO B4297 1g 250mg 5mL C C OK xH2O O NaO C N N xH2O B4557 C ONa CH3 CH3 N N N B3622 B1876 O O O N N N N N N N N HO C C OH N N O HO C C OH CN N 98 25mL 25mL 25mL 25mL 25mL 1g 1g 200mg 1g 5g 50mg 50mg 5g 5g 50mg 1g 1g 5g 1g 5g 5g 25mL 500mL 500mL 500mL 500mL 500mL 5g 5g 1g 5g B0841 O O 1g 500mg 250mg 250mg 1g 200mg 1g 1g B4509 O N B1423 CH3 CH3 T2671 CH2 N CH2CH2 N CH2 B3510 B3934 B4228 B2217 B2218 B4227 B2219 B2220 B4104 D4652 D2037 D3640 L0063 L0085 L0065 L0067 L0066 L0068 P2098 T1487 P2100 T2671 CH3 P2100 CH2 N O N CH3 L0068 CH3 N N N CH3 CH3 P2098 N L0066 CH3 N CH3 N N N CH3 C CH3 L0063 CH3 N N N B3502 B3533 O B0468 B3859 B2496 O HO C C OH N O O N HO C N B0470 N C OH B3572 N N B4645 CH2Cl N N O O B4420 CH2Cl CH3(CH2)5 N ClCH2 N N B3973 N (CH2)5CH3 CH2Cl B4114 N N B3732 N CH2OH CH2OH N N B3218 Br O N N N S N B3297 CH3 N B3511 S N N CH3 CH3 N N N N H N N CH3 N N Br N Br N B3219 D2892 Br N N N D3988 D2913 NH2 NH2 N N H2N D3134 D3919 N N NH2 D4541 N N Br D4635 N Br Br N N O O CH3O C C OCH3 N N H1347 CH2OH N N B1077 B4509 B0841 B1423 B4297 B4557 CH3 CH3 N N OCH2CH3 N N B0842 CH3 N P2202 N N (CH2)8CH3 (CH2)8CH3 CH3 N N CH3 T0024 N N T2959 O C OCH3 N OCH3 N O N OCH3 D3917 CH3 N N OCH2CH3 CN B2138 M2464 CH3 N N B0852 N D3886 P N Br Br D4511 O NC N N D4358 C(CH3)3 C(CH3)3 Br N O O C OCH3 C OCH3 C OCH3 N N N N 2,2 -Bicinchoninic Acid Dipotassium Salt Hydrate Bicinchoninic Acid Disodium Salt Hydrate 2,2 -Bi-4-lepidine 2,2 -Bi(1,8-naphthyridine) 2,2 -Bipyrazine 2,2 -Bipyridine-6-carbonitrile N N N N N N 1g 1g 5g 5g 100mg 100mg 100mg 200mg 1g 99 B3622 B1876 B3502 B3533 B0468 B3859 B2496 B0470 B3572 B4645 B4420 B3511 B3973 B3297 B4114 B3732 B3218 B3219 D2892 D2913 D3919 D4358 D3988 D3134 D4541 D4511 D3886 D4635 B0852 B2138 B0842 D3917 H1347 M2464 P2202 T0024 T2959 2,2 -Bipyridine-3,3 -dicarboxylic Acid 2,2 -Bipyridine-4,4 -dicarboxylic Acid 2,2 -Bipyridine-5,5 -dicarboxylic Acid 2,2 -Bipyridine-6,6 -dicarboxylic Acid 2,2 -Bipyridyl 2,2 -Bipyridyl 1,1 -Dioxide 2,2 -Bipyrimidyl 2,2 -Biquinoline 4,4 -Bis(chloromethyl)-2,2 -bipyridyl 6,6 -Bis(chloromethyl)-2,2 -bipyridyl 4,4 -Bis(5-hexyl-2-thienyl)-2,2 -bipyridyl 4,4 -Bis(hydroxymethyl)-2,2 -bipyridine 1,2-Bis(4 -methyl-2,2 -bipyridin-4-yl)ethane 2,6-Bis(2-pyridyl)-4(1H)-pyridone 6-Bromo-2,2 -bipyridyl 6-Bromo-4,4 -dimethyl-2,2 -bipyridyl -(4-Bromophenyl)-2,2 :6 ,2 -terpyridine -Bromo-2,2 :6 ,2 -terpyridine 4,4 -Diamino-2,2 -bipyridyl 6,6 -Diamino-2,2 -bipyridyl 4,4 -Dibromo-2,2 -bipyridyl 5,5 -Dibromo-2,2 -bipyridyl 6,6 -Dibromo-2,2 -bipyridyl 4,4 -Di-tert-butyl-2,2 -bipyridyl 6,6 -Dicyano-2,2 -bipyridyl Diethyl 2,2 :6 ,2 -Terpyridine-4 -phosphonate 4,4 -Dimethoxy-2,2 -bipyridyl Dimethyl 2,2 -Bipyridine-4,4 -dicarboxylate 4,4 -Dimethyl-2,2 -bipyridyl 5,5 -Dimethyl-2,2 -bipyridyl 6,6 -Dimethyl-2,2 -bipyridyl 4,4 -Dinonyl-2,2 -bipyridyl 4-Hydroxymethyl-4 -methyl-2,2 -bipyridyl Methyl 2,2 :6 ,2 -Terpyridine-4 -carboxylate -(4-Pyridyl)-2,2 :6 ,2 -terpyridine 2,2 :6 ,2 -Terpyridine Trimethyl 2,2 :6 ,2 -Terpyridine-4,4 ,4 -tricarboxylate 1g 100mg 1g 100g 25g 200mg 1g 200mg 1g 200mg 1g 1g 1g 1g 200mg 1g 1g 1g 1g 1g 1g 5g 1g 5g 100mg 1g 1g 200mg 100mg B2695 D0905 B2694 D0711 5g 1g 1g 5g 500g 5g 1g 5g 1g 1g 200mg 5g 1g 1g 5g 5g 5g 5g 1g 250mg 5g 1g 5g 5g 1g 200mg 5g 5g 25g 25g 5g 5g 1g 100mg 200mg 1g 200mg B0989 NaO3S SO3Na xH2O N N N B0429 C1560 Cl D4421 (CH2)3CH3 D3869 Cl N Cl 100 OH xH2O N Cl N N Br D0772 HO Cl Br N N D4186 N N N N N CH3(CH2)3 N N H2O N D3209 Cl N D2565 C0786 Br Br N N N CH3 CH3 B2632 N N N N N CH3 CH3 D1559 D3849 B0985 CH3 CH3 M2512 NaO3S N N N0423 CH3 N N CH3 N HCl H2O N 1/2H2O T3133 N N N NO2 CH3 xH2O P1973 P0221 P0879 CH3 N CH3 CH3 N0214 CH3 N N N CH3 D0771 N N N N N M0300 SO3Na O O N N H2O T0847 Br N Br N Br Br N B2694 D0711 B2695 D0905 B0989 B2632 B0429 C1560 C0786 D3209 D2565 D4186 D4421 D3869 D0772 D1559 D3849 B0985 M2512 M0300 D0771 N0423 N0214 P0221 P0879 P1973 T3133 T0847 N CH3 CH3 CH3 CH3 Bathocuproine (purified by sublimation) Bathocuproine Bathophenanthroline (purified by sublimation) Bathophenanthroline Bathophenanthrolinedisulfonic Acid Disodium Salt Hydrate 3-Bromo-1,10-phenanthroline 5-Bromo-1,10-phenanthroline Monohydrate 2-Chloro-1,10-phenanthroline 5-Chloro-1,10-phenanthroline 3,8-Dibromo-1,10-phenanthroline 2,9-Dibutyl-1,10-phenanthroline 2,9-Dichloro-1,10-phenanthroline 4,7-Dichloro-1,10-phenanthroline Hydrate 4,7-Dihydroxy-1,10-phenanthroline 4,7-Dimethyl-1,10-phenanthroline 5,6-Dimethyl-1,10-phenanthroline 2,9-Diphenyl-1,10-phenanthroline Disodium Bathocuproinedisulfonate 2-Methyl-1,10-phenanthroline 5-Methyl-1,10-phenanthroline Hydrate Neocuproine Hemihydrate Neocuproine Hydrochloride Monohydrate 5-Nitro-1,10-phenanthroline 1,10-Phenanthroline Monohydrate 1,10-Phenanthroline Monohydrate 1,10-Phenanthroline-5,6-dione 3,5,6,8-Tetrabromo-1,10-phenanthroline 3,4,7,8-Tetramethyl-1,10-phenanthroline 1g 1g 1g 200mg 100mg 100mg 200mg 100mg 200mg 200mg 100mg 100mg 100mg 1g 1g 5g 1g 1g 5g 5g 1g 5g 1g 200mg 1g 1g 1g 1g 1g 1g 1g 1g 100mg 1g 1g 1g 1g 1g 25g 25g 1g 25g 25g 5g 100mg 1g 101 O Br N H O Br N H Br C NH S S O O CF3CO2H (0.5 mol%) HO O Br Acetone, H2O N H O O Y 70%, 92% e.e A1301 A0945 A1043 O N CH2NH2 CH2CH3 B3440 D3803 H3C D3804 N H H3C C Si O N H NH D3185 D3186 N H N H O H3C N H D2365 D2735 F0818 OH C N H H1407 H0784 OH F C N H H0768 N H C OH OH N H OH CH2NH I0589 OH H N N H OH C CH3 O O CH3 I0395 N CH3 M1169 M1161 OH N CH3 102 C N H OH O N H OH O N H CH2OCH3 N H CH2OCH3 M1097 N M1183 CH2NH M2077 N CH3 CH2 N N H CH3 P1830 P1404 O C OH P1241 N H P1784 A1301 A0945 A1043 B3440 D3803 D3804 D3185 D3186 D2365 D2735 F0818 H1407 H0784 H0768 I0589 I0395 M1169 M1161 M1097 M1183 M2077 M1995 O0370 P1830 P1404 P0994 P0481 P1925 P1241 P1784 T3080 T0219 CH2 N O OH N N H N H N C OH OH O N H CH2 N T0219 O N H N H H CH3 P1925 N H O O N 2HCl T3080 N N H H N P0481 N H C OH O0370 CH3 OH P0994 O N H M1995 O O C NH S O HO C NH S S (S)-(-)-2-Aminomethyl-1-ethylpyrrolidine (S)-(+)-2-(Anilinomethyl)pyrrolidine L-Azetidine-2-carboxylic Acid trans-4-(tert-Butyldiphenylsilyloxy)-L-proline (R)-(+)-2-(Diphenylmethyl)pyrrolidine (S)-(-)-2-(Diphenylmethyl)pyrrolidine (2R,5R)-2,5-Diphenylpyrrolidine (2S,5S)-2,5-Diphenylpyrrolidine (R)-(+)- , -Diphenyl-2-pyrrolidinemethanol (S)-(-)- , -Diphenyl-2-pyrrolidinemethanol trans-4-Fluoro-L-proline (2S)-N-[(1S)-1-(Hydroxydiphenylmethyl)-3-methylbutyl]-2-pyrrolidinecarboxamide (R)-(-)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine (S)-(+)-2-[Hydroxy(diphenyl)methyl]-1-methylpyrrolidine (R)-(+)-Indoline-2-carboxylic Acid (S)-(-)-Indoline-2-carboxylic Acid (R)-2-(Methoxymethyl)pyrrolidine (S)-2-(Methoxymethyl)pyrrolidine (S)-(-)-1-Methyl-2-(1-naphthylaminomethyl)pyrrolidine (S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine -Methyl-L-proline (S)-2-[(1-Methyl-2-pyrrolidinyl)methyl]isoindoline Dihydrochloride (2S,3aS,7aS)-Octahydro-1H-indole-2-carboxylic Acid D-Pipecolic Acid L-Pipecolic Acid D-Proline L-Proline (R)-(-)-1-(2-Pyrrolidinylmethyl)pyrrolidine (S)-(+)-1-(2-Pyrrolidinylmethyl)pyrrolidine (S)-5-(Pyrrolidin-2-yl)-1H-tetrazole N-(2-Thiophenesulfonyl)-L-prolinamide L-Thioproline 1g 1g 100mg 1g 1g 1g 200mg 1g 100mg 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 5g 25g 1g 100mg 25g 5g 5g 1g 5g 1g 1g 100mg 100mg 5g 5g 50mg 1g 5g 5g 1g 5g 5g 5g 1g 5g 5g 5g 5g 25g 5g 25g 250g 1g 5g 500mg 100mg 500g 103 A0177 A0179 B3398 O O CH3 M0099 P0135 O CH3S OH T0228 CH3 OH A0177 A0179 B3398 M0102 M0099 P0135 P0134 T2937 T0228 T0230 T0539 T0541 NH (CH3)3CO OH OH CH H Cl HO H CH2 B1684 HO CH2 H Cl HO H CH2 H CH3O N N CH2 CH H CH N CH2 C0349 H CH2 Cl N N C0348 CH2 CH 25g 250g 5g 25g 500g 25g 250g 100mg 25g 500g 100g 500g 5g 25g 25g H CH N C0347 5g 25g 1g 5g 100g 5g 25g 25g B1689 CH2 H PPh2 NH2 N H 1g 25g B1683 CH C0350 CH2 CH H CH2 CH H Cl H HO N HO N H N N C0351 CH H N HCl xH2O N H N O N H I0728 CH3CH2 N HO N H0752 CH2 N N N N D4305 CH2 N HO H 2H2SO4 2H2O N D4306 H HO 2HCl N 104 HO CH2 CH3O CH2 H CH3 CH3 CH3 OH NH2 N H O-tert-Butyl-L-threonine D-Methionine L-Methionine D-Phenylalanine L-Phenylalanine O-TBDPS-D-Thr-N-Boc-L-tert-Leu-Diphenylphosphine D-(+)-Threonine L-(-)-Threonine D-Tryptophan L-Tryptophan CH2 Ph O D-Alanine L-Alanine B1685 Ph N H CH3 Si O O NH2 NH2 OH O T0541 O OH CH3 CH3 O CH3 NH2 T0539 O CH3 O NH2 T0230 OH T2937 OH NH2 OH NH2 O OH NH2 CH3 P0134 O CH3S OH NH2 NH2 M0102 O (CH3)3CO CH3 OH CH3CH2 H N H N N N HO O CH3O N O H HCl N H HO N Q0076 Q0074 CH2 CH HOCH2 Q0006 Q0010 CH2 CH CH2 CH H Q0028 CH2 CH N N N HO CH2OH N HO H CH3O CH2 CH H HO H CH3O N N H2SO4 2H2O H H N CH3O N Q0030 CH2 HO H CH H N HCl 2H2O CH3O N B1683 B1689 B1684 B1685 C0347 C0348 C0349 C0350 C0351 D4306 D4305 H0752 I0728 Q0076 Q0074 Q0006 Q0010 Q0028 Q0030 N-Benzylcinchonidinium Chloride N-Benzylcinchoninium Chloride N-Benzylquinidinium Chloride N-Benzylquininium Chloride Cinchonidine Cinchonidine Dihydrochloride Cinchonidine Sulfate Dihydrate Cinchonine Cinchonine Hydrochloride Hydrate N-(9-Deoxy-epi-cinchonidin-9-yl)picolinamide N-(9-Deoxy-epi-cinchonin-9-yl)picolinamide Hydroquinidine Hydrochloride -Isocupreidine Quincoridine Quincorine Quinidine Quinidine Sulfate Dihydrate Quinine Quinine Hydrochloride Dihydrate 25g 25g 25g 100mg 100mg 5g 5g 25g B1143 B1144 O O B1143 B1144 10g 5g 5g 5g 250g 25g 25g 200g 25g 100mg 100mg 250g 1g 1g 1g 25g 25g 100g 25g O O P OH O O P OH (R)-(-)-1,1 -Binaphthyl-2,2 -diyl Hydrogen Phosphate (S)-(+)-1,1 -Binaphthyl-2,2 -diyl Hydrogen Phosphate 100mg B1142 B1100 1g 100mg 5g 1g B2048 OH OH OH OH OH HO O O H3C CH3 105 B1614 B1615 OH HO O O OH HO O O H3C H3C CH3 (R)-(+)-1,1 -Bi-2-naphthol (S)-(-)-1,1 -Bi-2-naphthol (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane B1142 B1100 B2048 B1614 B1615 B3296 5g 5g 1g 1g B3549 25g 25g 5g 5g 1g B3592 N N BF4 S N S N N N CF3 CH3 CH3 N B3593 C0015 C0972 D3983 D3984 CH3 CH3 BF4 O N N CH3 HO3SCH2 CH3 CH2SO3H CH3 H O N N CF3 N H E0974 I0807 L0272 CH2CH3 CH3CH2 CH3 O N CH3 O O N CH3 H CH3 I CH3 O O N CH3 H N O Cl H2O H HN N N O CH3 N Cl H2O L0137 CH3 OH CH3 O H CH3 H OCH3 H HBr OH OCH3 OH OH CH3 CH3 O N L0236 OCH3 H N CH3 NH2 CH3 OH CH3 NH2 CH3 O T1215 N N S HCl B3296 B3549 B3592 B3593 106 (+)-Benzotetramisole 200mg 1g (-)-Benzotetramisole (R)-Benzyl-2-[4-(trifluoromethyl)phenyl]-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazolium Tetrafluoroborate 200mg (S)-Benzyl-2-[4-(trifluoromethyl)phenyl]-6,7-dihydro-5H-pyrrolo[2,1-c][1,2,4]triazolium Tetrafluoroborate 200mg 5g 1g 1g 1g C0015 C0972 D3983 D3984 E0974 I0807 L0272 L0236 L0137 T1215 (+)-10-Camphorsulfonic Acid (-)-10-Camphorsulfonic Acid (+)-(5aR,10bS)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate (-)-(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium Chloride Monohydrate (1R,3S,5R,7R,8aS)-7-Ethylhexahydro-1-(6-hydroxy-4-quinolinyl)-3,7-methano1H-pyrrolo[2,1-c][1,4]oxazine (R,R)-2-Iodo-1,3-bis[1-(mesitylcarbamoyl)ethoxy]benzene Lappaconitine Hydrobromide D-(-)-Leucinol L-(+)-Leucinol Levamisole Hydrochloride 1971 25g 100g 25g 500g 500g 100mg 100mg 200mg 1g 5mL 10g 100mg 200mg 1g 5g 25mL 25g 1974 2000 2004 2007 2005 2008 107 B1786 B1754 CH2 B2166 I0761 N CH3 CH NH O O O CH3 O P1307 CH3 CH3 NH O O O O (R)-4-Benzyl-2-oxazolidinone (S)-4-Benzyl-2-oxazolidinone (R)-(-)-4-Benzyl-3-propionyl-2-oxazolidinone (S)-(+)-4-Benzyl-3-propionyl-2-oxazolidinone (4R)-(+)-4-Isopropyl-5,5-diphenyl-2-oxazolidinone (4S)-(-)-4-Isopropyl-5,5-diphenyl-2-oxazolidinone (R)-4-Isopropyl-2-oxazolidinone (S)-4-Isopropyl-2-oxazolidinone (R)-(-)-4-Isopropyl-3-propionyl-2-oxazolidinone (S)-(+)-4-Isopropyl-3-propionyl-2-oxazolidinone (R)-(-)-4-Phenyl-2-oxazolidinone (S)-(+)-4-Phenyl-2-oxazolidinone 1g 1g CH3 Ph N O CH3 Ph CH3 CH3 SO2 O CH3 Ph SO2 CH3 N Bn B2048 CH3 CH3 CH3 Ph OH CH3 SO2 CH3 N Bn CH3 Ph O CH3 O SO2 CH3 CH3 SO2 CH3 N Bn CH3 B1614 OH HO O O OH HO O O Ph N Bn CH3 Ph O P1372 CH3 CH3 CH3 CH3 N O P1371 25g 25g 25g 5g 5g 5g 25g 25g 5g 5g 25g 25g B2103 CH3 CH3 SO2 5g 5g 5g 1g 1g 1g 5g 5g 1g 1g 5g 5g 1g A1535 CH3 CH3 O NH O A1534 O CH3 O H3C CH3 108 O O P1308 CH3 N O B2104 NH O CH3 O B1786 B1754 B2165 B2166 I0761 I0762 I0572 I0451 I0594 I0573 P1307 P1308 CH3 CH3 NH O O N CH3 CH3 NH O I0573 CH3 O I0451 O I0594 O O I0572 C CH2CH3 O CH3 O C CH2CH3 N CH3 CH3 CH O CH2 CH2 NH O I0762 CH3 O CH2 NH O B2165 H3C CH3 Ph OH B1615 B2907 OH HO O O B2908 C1324 O (CH3)3C S NH2 (CH3)3C S NH2 D2898 C2023 C1615 CH3 NH S S O O D2899 CH3 B Cl CH3 T2578 N CH3 N CH3 CH3 N C N CH2OH H CH2 O I0575 CH3 B Cl CH3 HN O C1614 CH3 CH3 O H3C CH3 C1325 CH3 N CH3 CH3 CH3 N C CH2OH CH3 NH H CH2 S S T2579 CH3 CH3 CH3 S CH3 CH3 S CH3 A1534 Acetic Acid (1R,2S)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenylpropyl Ester A1535 Acetic Acid (1S,2R)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenylpropyl Ester B2103 B2104 P1371 (1R,2S)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenyl-1-propanol (1S,2R)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenyl-1-propanol (1R,2S)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenylpropyl Propionate P1372 (1S,2R)-2-[N-Benzyl-N-(mesitylenesulfonyl)amino]-1-phenylpropyl Propionate B2048 B1614 B1615 B2907 B2908 C1324 C1325 C1614 C2023 C1615 D2898 D2899 I0575 T2578 T2579 (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (-)-4,5-Bis[hydroxy(diphenyl)methyl]-2,2-dimethyl-1,3-dioxolane (+)-4,5-Bis[hydroxy(diphenyl)methyl]-2-methyl-2-phenyl-1,3-dioxolane (R)-(+)-tert-Butylsulfinamide (S)-(-)-tert-Butylsulfinamide (+)-10,2-Camphorsultam (-)-10,2-Camphorsultam (+)-B-Chlorodiisopinocampheylborane (58% in Hexane, ca 1.6mol/L) (-)-B-Chlorodiisopinocampheylborane (55-65% in Heptane, ca 1.7mol/L) (-)-B-Chlorodiisopinocampheylborane (60% in Hexane, ca 1.7mol/L) (4R,5R)-1,3-Dimethyl-4,5-diphenyl-2-[(S)-1-benzyl-2-hydroxyethylimino]imidazolidine (4S,5S)-1,3-Dimethyl-4,5-diphenyl-2-[(R)-1-benzyl-2-hydroxyethylimino]imidazolidine (S)-4-Isopropylthiazolidine-2-thione (1R,4R,5R)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane (1S,4S,5S)-4,7,7-Trimethyl-6-thiabicyclo[3.2.1]octane 1g [Reagent for double aldol reaction] [Reagent for double aldol reaction] 1g 1g 1g 5g 5g 1g [Reagent for anti-selective asymmetric aldol reaction] [Reagent for anti-selective asymmetric aldol reaction] 1g 1g 1g 1g 1g 1g 1g 1g 1g 5g 5g 1g 5g 5g 5g 5g 100mL 100mL 100mL 100mg 100mg 1g 5g 5g 109 Alkylation CH3OCH2CHCH3 OH TBAB + BuCl OBu 50% NaOH aq Y 97% TBAB : Tetrabutylammonium Bromide C8H17Cl Bu3P + Na2S C16H33 1) CH3OCH2CHCH3 2) Br (C8H17)2S H 2O Y 91% Cyanation 3) Cl(CH2)3Cl 18-Crown-6 + KCN NC(CH2)3CN CH3CN Y 97% Oxidation CH3(CH2)7CH CH2 + KMnO4 4) (C8H17)3N CH3 Cl CH3(CH2)7CO2H Benzene – H2O Y 91% CH2 OH N Cl N O Ph2C N Ot-Bu + BnBr [B1689] (10 mol%) CH2Cl2 50% NaOH aq 20 ºC, h O Ph2C N 5) Ot-Bu Bn Y 75% 66% e.e (R) 110 O Ph N CO2Bn O (S,S)-TaDiAS-2nd* (cat.) [D3476] (10 mol%) O + O Cs2CO3, PhCl -40 ºC, 66 h C6H13 Ph BnO2C O tandem cyclization Ph N Ph O N BnO2C C6H13 Y 84% 82% e.e 6) N C6H13 B1683 B1689 CH2 CH H CH2 Cl HO (+)-cylindricine C total steps C6H13 HO H B1684 CH H N N HO CH2 N CH2 Cl CH H Cl N CH2 HO H CH2 H CH3O N N B1685 CH2 CH H Cl HO H N CH2 CH3O N B1683 B1689 B1684 B1685 N-Benzylcinchonidinium Chloride N-Benzylcinchoninium Chloride N-Benzylquinidinium Chloride N-Benzylquininium Chloride 10g 5g 5g 5g D3475 CH3 CH2Ph CH2 N CH2 O O CH2 N CH2 CH2Ph CH3 D3475 D3476 D3476 CH3 CH3 2BF4 2 CH3 CH2Ph CH2 N CH2 O O CH2 N CH2 CH2Ph CH3 CH3 CH3 2 2BF4 6,10-Dibenzyl-N,N -dimethyl-N,N,N ,N -tetrakis(4-methylbenzyl)-1,4-dioxaspiro[4.5]decane(2R,3R)-diylbis(methylammonium) Tetrafluoroborate [=(R,R)-TaDiAS-2nd] 6,10-Dibenzyl-N,N -dimethyl-N,N,N ,N -tetrakis(4-methylbenzyl)-1,4-dioxaspiro[4.5]decane(2S,3S)-diylbis(methylammonium) Tetrafluoroborate [=(S,S)-TaDiAS-2nd] 200mg 1g 200mg 1g 111 1975 1974 1974 1971 1989 2006 2007 2000 1978 1977 1976 1976 1973 2003 112 2003 O PhCH2 C Cl O PhCH2 NHTs [T1444] i) C O NHTs ii) recrystallization OH Y.64% ( >99% d.e.) 40% KOH aq OH H3C N OTBDPS HN N SO2 i-Pr O O C N OH syn, racemic i-Pr [T2223] (5 mol%) i-Pr (i-PrCO)2O (0.5 eq.) i-Pr2NEt (0.5 eq.) nonpolar solvent (49% conv.) O O O C N O C N + O C 94% e.e O i-Pr OH 90% e.e 113 O O O O OH R1 CH3O + R2CO2H [M1973] R2 O OCH3 R1 OH R1 + (+)-BTM (cat.), iPr2NEt, CH2Cl2, rt [B3296] O OH O [M1973] + R3OH (+)-BTM (cat.), iPr2NEt, CH2Cl2, rt [B3296] CH3 O + OR3 OH CH3 CH3 BTM=(+)-Benzotetramisole A1230 A1231 A1017 OH NH2 NH2 OH OH OH A1029 A0526 NH H2N O N H NH OH H2N O B1118 CH3O N H C0349 CH2 CH HO H H N C0350 CH2 CH HO H 2HCl N 114 H H CH CH2 CH H CH3O N H O O HO HO H N H N H H O HCl H2O CH2 H N N C0791 CH H CH2 CH N N N 2H2SO4 2H2O N CH2 CH3O C0351 H N C0347 H O C0348 S H N CH3O NHCH2 N N B0671 H NHCH2 S HCl NH2 H CH2OH N OH B0946 B0670 CH2OH B3549 O N H NH2 O2N B3296 NH OH H2N N H NH2 B1119 A0528 NH2 HO H N H N HO HCl xH2O H2SO4 2H2O H N D1588 H0752 L0129 CH3 CH3 CH3 H CH3O H H2N O OH O H2N H2N OH M0826 M0545 N0543 CH3 N0482 CH3 CH3 NH2 CH3 O H2N OH OH HCl NH2 CH3 N0481 CH3 CH3 CH3 NO2 CH3 P1028 P0794 Q0006 Q0010 H Q0028 CH2 CH NH2 N HO H CH3O N O O H O HCl xH2O N HO O H H N HCl 2H2O N N T1380 CH3 N NH2 H N H H H CH3O N N CH CH2 CH3O H H H H H S0094 H H H H2SO4 2H2O S0093 N N H N S0257 H HO H CH3O N S0249 NH2 Q0030 CH2 CH H N HO CH3 NH2 NH2 CH2 CH NH2 OH OH CH3 P0793 CH3 NH2 P1118 NH2 HCl OH P1289 O HCl NH2 N L0071 N OH 2HCl NH2 NH2 HCl NH2 L0128 O N HO CH3 L0131 H CH3CH2 O HNO3 O H H H O CH3 H2SO4 5H2O T1381 CH3 NH2 CH3 A1230 A1231 A1017 A1029 A0526 A0528 B3296 B3549 B1119 B1118 B0946 B0670 B0671 C0347 (1R,2S)-(-)-2-Amino-1,2-diphenylethanol (1S,2R)-(+)-2-Amino-1,2-diphenylethanol D-(-)-threo-2-Amino-1-(4-nitrophenyl)-1,3-propanediol D-(-)-Arginine L-(+)-Arginine L-(+)-Arginine Hydrochloride (+)-Benzotetramisole (-)-Benzotetramisole (+)-cis-2-Benzylaminocyclohexanemethanol (-)-cis-2-Benzylaminocyclohexanemethanol Brucine Anhydrous Brucine Hydrate Brucine Hydrochloride Monohydrate Cinchonidine 25g 200mg 1g 1g 25g 1g 100g 25g 1g 1g 1g 25g 5g 5g 500g 5g 500g 500g 5g 1g 5g 5g 25g 25g 5g 250g 115 C0348 C0349 C0350 C0351 C0791 D1588 H0752 L0129 L0131 L0128 L0071 M0826 M0545 N0543 N0482 N0481 P1289 P1028 P0794 P0793 P1118 Q0006 Q0010 Q0028 Q0030 S0249 S0257 S0093 S0094 T1380 T1381 Cinchonidine Dihydrochloride Cinchonidine Sulfate Dihydrate Cinchonine Cinchonine Hydrochloride Hydrate Cinchonine Sulfate Dihydrate (+)-Dehydroabietylamine Hydroquinidine Hydrochloride L-(+)-Lysine L-(+)-Lysine Dihydrochloride D-(-)-Lysine Monohydrochloride L-(+)-Lysine Monohydrochloride (+)-Menthol (-)-Menthol (S)- -Methyl-4-nitrobenzylamine Hydrochloride (R)-(+)-1-(1-Naphthyl)ethylamine (S)-(-)-1-(1-Naphthyl)ethylamine D-Phenylalaninol L-Phenylalaninol (R)-(+)-1-Phenylethylamine (S)-(-)-1-Phenylethylamine (S)-1-Phenyl-2-(p-tolyl)ethylamine Quinidine Quinidine Sulfate Dihydrate Quinine Quinine Hydrochloride Dihydrate Strychnine Strychnine Hydrochloride Hydrate Strychnine Nitrate Strychnine Sulfate Pentahydrate (R)-(+)-1-(p-Tolyl)ethylamine (S)-(-)-1-(p-Tolyl)ethylamine 25g 5g 25g 5g 25g 5g 25g 25g 100g 1g 1g 5g 5g 25mL 100mL 25mL 100mL 5g 5g 5g 25g 1mL A1454 A1453 O O CH3 C O A0545 O C OH 25g 25g 200g 25g 25g 25g 250g 25g 25g 25g 500g 500g 500g 1g 5g 5g 25g 25g 500mL 500mL 25g 25g 25g 100g 25g 25g 25g 25g 25g 1mL 5mL O CH3 C O O C OH HO OH O A0546 B1121 OH O C OH C OH O O NH NH C NH2 C0012 C0015 CH3 H CH3 CH3 COOH COOH C1417 CH3 O B1143 O O C C0972 CH3 CH2SO3H C1418 O CH3 HO3SCH2 CH3 O D2636 H O O H O O H O CH3 CH3 CH3 CH2SO2Cl O HO OH O CH3 O P OH CH3 ClSO2CH2 CH3 O D1911 CH3 O O O C1308 O O O P OH D1386 O 116 O C0998 O H B1144 O O O HO B1120 NH2 O O CH3 C O O HO O OH O O CH3 O O CH3 C O O O D2645 O D1398 D3826 D1354 D3492 O O O CH3 C O O CH3 C O Ph O HO O O O HO O O O O HO O OH O p-Tol O Ph O2N O G0057 HN OH H2O Ph O p-Tol OH O O D1387 D1417 O Ph OH H2O O O O D1853 G0059 O NO2 M0021 M0022 O p-Tol O O O HO OH O O HO OH O HO O OH NH2 p-Tol O O HO OH O NH2 O HO OH OH O OH O M0662 M0661 M1221 HO HO C OH M0990 CH3 O O CH3 C OH CH3 I0334 I0335 CH3 O O O C Cl O C Cl CH3 CH3 M1622 CH3 NCO M1021 CH3 NCO I0336 O OH H N O I0398 P1354 CH3O CH3 M0824 O OH O CH3 NCO OH H N CH3 O P0573 CH3 Q0009 T0026 O CH3 NCO HO C OH O N H OH O O OH N H O OH O HO HO OH O OH OH OH T0025 T1702 T1163 NO2 OH O HO OH H N OH OH O OH O NO2 O O2N NO2 N OH O OH CH3 O A1454 A1453 A0545 A0546 B1121 B1120 B1143 B1144 C0012 C0015 C0972 C0998 C1308 C1417 (+)-O-Acetyl-L-mandelic Acid (-)-O-Acetyl-D-mandelic Acid D-Aspartic Acid L-Aspartic Acid (+)-cis-2-Benzamidocyclohexanecarboxylic Acid (-)-cis-2-Benzamidocyclohexanecarboxylic Acid (R)-(-)-1,1 -Binaphthyl-2,2 -diyl Hydrogen Phosphate (S)-(+)-1,1 -Binaphthyl-2,2 -diyl Hydrogen Phosphate (+)-Camphoric Acid (+)-10-Camphorsulfonic Acid (-)-10-Camphorsulfonic Acid (+)-10-Camphorsulfonyl Chloride (-)-10-Camphorsulfonyl Chloride (+)-trans-1,2-Cyclohexanedicarboxylic Anhydride 5g 5g 25g 100mg 1g 100mg 25g 25g 100g 25g 10g 5g 100mg 25g 25g 25g 500g 5g 5g 5g 1g 100g 500g 500g 25g 25g 1g 117 (-)-trans-1,2-Cyclohexanedicarboxylic Anhydride (+)-Diacetyl-D-tartaric Acid (-)-Diacetyl-L-tartaric Acid (+)-Diacetyl-L-tartaric Anhydride (-)-Diacetyl-D-tartaric Anhydride (+)-Dibenzoyl-D-tartaric Acid Monohydrate (+)-Dibenzoyl-D-tartaric Acid (-)-Dibenzoyl-L-tartaric Acid Monohydrate (-)-Dibenzoyl-L-tartaric Acid (R)-(-)-N-(3,5-Dinitrobenzoyl)- -phenylglycine (+)-Di-p-toluoyl-D-tartaric Acid (-)-Di-p-toluoyl-L-tartaric Acid D-Glutamic Acid L-Glutamic Acid D-(+)-Malic Acid L-(-)-Malic Acid D-(-)-Mandelic Acid L-(+)-Mandelic Acid (+)-Menthyl Chloroformate (-)-Menthyl Chloroformate (S)-(+)-2-(6-Methoxy-2-naphthyl)propionic Acid (R)-(+)- -Methylbenzyl Isocyanate (S)-(-)- -Methylbenzyl Isocyanate (R)-(+)-N-( -Methylbenzyl)phthalamic Acid (S)-(-)-N-( -Methylbenzyl)phthalamic Acid (R)-(-)-1-(1-Naphthyl)ethyl Isocyanate (S)-(+)-1-(1-Naphthyl)ethyl Isocyanate D-Pyroglutamic Acid L-Pyroglutamic Acid D-(-)-Quinic Acid D-(-)-Tartaric Acid L-(+)-Tartaric Acid (2R,3R)-Tartranilic Acid (+)- -(2,4,5,7-Tetranitro-9-fluorenylideneaminoxy)propionic Acid C1418 D2636 D1386 D1911 D2645 D1398 D3826 D1354 D3492 D1853 D1417 D1387 G0057 G0059 M0021 M0022 M0662 M0661 M1221 M0990 M1021 I0334 I0335 M1622 M0824 I0336 I0398 P1354 P0573 Q0009 T0026 T0025 T1702 T1163 A1454 100mg 25g 25g 1g O O A2128 O C OH 5g 25g 25g 25g 25g 1g 25g 25g 25g 25g 5g 100g 100g 25g 5mL 5mL 25g 5g 1g 1g 1g 1g 5g 25g 5g 25g 25g 1g A1453 CH3 C O 1g 5g 25g 25g 25g 500g 250g 500g 250g 5g 250g 250g 250g 500g 25g 500g 500g 250g 25mL 25mL 500g 25g 5g 5g 1g 5g 5g 25g 500g 25g 500g 500g 5g 1g O CH3 C O O C OH CH2 CH CH2 A1984 B3296 B3549 B1219 N O S CH3 N N S CH3 CH3 COCl O CH3 118 CH3 C0998 O CH3 O C1308 CH3 CH2SO2Cl CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 N CH2 CH CH2 C1022 B1220 CH3 CH3 ClSO2CH2 O O C1417 CH3 O O O O C1418 H O H O O O H O O H O CH3 M0573 M0571 M1221 CH3 I0335 CH3 CH3 O C Cl CH3 I0336 NCO O O C Cl CH3 N0581 CH3 O OCH2 C Cl OCH2 C OH CH3 I0334 CH3 O O CH3 M0990 CH3 CH3 CH3 CH3 I0398 N0582 O CH3 NCO CH3 Cl HN T1444 NCO CH3 NCO O Cl SO2 HN SO2 NO2 T2223 SO2 O HN N Cl HN Ph CH3 N O CH3 Si tBu Ph SO2 iPr iPr iPr A1454 A1453 A2128 A1984 B3296 B3549 B1219 B1220 C1022 C0998 C1308 C1417 C1418 M0573 M0571 M1221 M0990 I0334 I0335 N0581 I0336 I0398 N0582 T1444 T2223 (+)-O-Acetyl-L-mandelic Acid 5g 25g 5g 25g (-)-O-Acetyl-D-mandelic Acid 1g 5g (R)-5-Allyl-2-oxabicyclo[3.3.0]oct-8-ene (S)-5-Allyl-2-oxabicyclo[3.3.0]oct-8-ene 1g (+)-Benzotetramisole 200mg 1g 5g (-)-Benzotetramisole 1g 100mg Bis[(2R,3aS,4R,7aS)-octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl] Ether 100mg Bis[(2S,3aR,4S,7aR)-octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl] Ether (-)-Camphanic Chloride 1g 5g 25g (+)-10-Camphorsulfonyl Chloride 10g 25g (-)-10-Camphorsulfonyl Chloride 5g 25g 100mg 1g (+)-trans-1,2-Cyclohexanedicarboxylic Anhydride (-)-trans-1,2-Cyclohexanedicarboxylic Anhydride 100mg 1g (-)-Menthoxyacetic Acid 5g 25g (-)-Menthoxyacetyl Chloride 10g (+)-Menthyl Chloroformate 5mL 25mL (-)-Menthyl Chloroformate 5mL 25mL 1g 5g 25g (R)-(+)- -Methylbenzyl Isocyanate (S)-(-)- -Methylbenzyl Isocyanate 1g 5g N-(1-Naphthalenesulfonyl)-L-phenylalanyl Chloride 5g 1g 5g (R)-(-)-1-(1-Naphthyl)ethyl Isocyanate 1g 5g (S)-(+)-1-(1-Naphthyl)ethyl Isocyanate N-(4-Nitrophenylsulfonyl)-L-phenylalanyl Chloride 5g N-(p-Toluenesulfonyl)-L-phenylalanyl Chloride 5g N -(2,4,6-Triisopropylbenzenesulfonyl)-O-(tert-butyldiphenylsilyl)- -methyl-L-histidinol 100mg 1991 1992 2004 2006 2007 2008 119 A2298 A2299 A0729 B2334 B1906 tBu Si CH3 C CH3 CH2CH3 CH3 CH3 CH2CH CH2 CH3CH2 Si CH2CH CH2 CH3 CH2CH CH2 CH2 CH3 CH2CH3 CH3 CH3 Si CH3 Si CH3 CH3 Si Cl CH3 N CH3 CH3 C O Si tBu CH3 B1688 B1773 CH3 Cl Si CH3 CH2CH2 CH3 Si CH3 CH3 Cl CH3 N CH3 B1436 SiH(CH3)2 CH3 CH3 Si CH2CH2 Si CH3 B3565 B1699 N CH3 CH3 CH3 H3C H3C C O Si CH3 B1043 B0995 SiH(CH3)2 B2697 Cl CH3 Si Cl CH3 CH3 H3C T1525 B1223 CH3 CH3 CH3 CH3 C Si H CH3 tBu CH3 CH3 B3566 Si N CH3 CH3 O Si C(CH3)3 N CH3 CH3 CH3 CH3 CH3 C N B2898 B1663 O Si O S CF3 H3C H3C C Si D2262 Cl H3C O T2116 Br CH3 H3C H3C C Si H H3C 120 H 3C H3C C Si H3C O O S CF3 O CH3O Si C CH3 CH3 CH3 CH3 CH2CH3 CH Si Cl CH2CH3 CH3 CH3 CH3 CH3 CH C Si CH3 CH3 Cl T0589 C0306 C2411 CH3 CH2CH3 CH3CH2 Si CH3 Cl Cl Cl (CH3)2HC OCH3 D1594 O CF3 O CH3 C N Si CH3 CH3 T0585 CH3 CH3 CH3 CH3 CH3 Si CH3 Si CH3 CH3 O CH3 CH2 C O Si CH3 CH3 iPr O Si O S CF3 iPr iPr O T1573 CH3 CH3 N O O O S CF3 C(CH3)3 iPr Cl T1535 Si O iPr CH3 CH3 N CH3 Si Cl iPr S CF3 C(CH3)3 S O Si T1588 CH2CH3 O N O O CH3 CH2CH3 O O O CF3 I0324 T1078 T1277 O (CH3)3SiCH2CH2O C O N CH2CH3 CH3CH2 Si CH3 T2591 CH T1689 O CH3 CH3 Si O C CHCH3 CH2CH3 S O Si CH3 M0536 CH3 CH3 CH3 CH(CH3)2 M1199 CH3 Si O Si Cl CH3 H3C Cl CH3 Si(CH3)3 T1468 CH3 CH(CH3)2 Si O Si Cl H3C C Si C Si Cl CH3 D2334 (CH3)2HC (CH3)3Si D3135 H3C Cl CH3 Si(CH3)3 Si Cl CH2CH3 D1608 D2469 N O Si CH3 CH3 (CH3)3SiO O CH3 C CH C CH3 O T0871 O CF3 CH3 S O Si CH3 O A2298 A2299 A0729 B2334 B1906 B1688 B1773 B1699 B1436 B0995 B3565 B1043 B2697 T1525 B1223 B3566 B2898 B1663 D2262 T2116 T0589 C0306 C2411 D2469 CH3 Allyl(tert-butyl)dimethylsilane Allyltriethylsilane Allyltrimethylsilane Benzylchlorodimethylsilane N,O-Bis(tert-butyldimethylsilyl)acetamide 1,2-Bis(chlorodimethylsilyl)ethane 1,2-Bis[(dimethylamino)dimethylsilyl]ethane 1,2-Bis(dimethylsilyl)benzene tert-Butoxydiphenylchlorosilane (stabilized with CaCO3) tert-Butyldimethylchlorosilane tert-Butyldimethylsilane 1-(tert-Butyldimethylsilyl)imidazole tert-Butyldimethylsilyl N-Phenylbenzimidate tert-Butyldimethylsilyl Trifluoromethanesulfonate tert-Butyldiphenylchlorosilane tert-Butyldiphenylsilane tert-Butyldiphenylsilyl Trifluoromethanesulfonate tert-Butylmethoxyphenylsilyl Bromide Chlorodiethylisopropylsilane Chloro(dimethyl)thexylsilane Chlorotriethylsilane Chlorotrimethylsilane Chlorotris(trimethylsilyl)silane Di-tert-butyldichlorosilane 25mL 5g 5g 5mL 25g 1g 5mL 5g 25mL 1g 1g 5g 5g 25g 25mL 100mL 5g 5g 250mL 5g 5g 25g 5g 5mL 25mL 100g 5g 5g 5g 25g 100mL 5g 5g 1g 5g 25g 100g 500mL 5g 5g 121 Di-tert-butylsilyl Bis(trifluoromethanesulfonate) 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 1,3-Dichloro-1,1,3,3-tetramethyldisiloxane Diethylisopropylsilyl Trifluoromethanesulfonate Dimethylisopropylchlorosilane Isopropenyloxytrimethylsilane 1-Methoxy-1-trimethylsilyloxypropene N-Methyl-N-trimethylsilylacetamide Triethylsilyl Trifluoromethanesulfonate Triisopropylsilyl Chloride Triisopropylsilyl Trifluoromethanesulfonate N-[2-(Trimethylsilyl)ethoxycarbonyloxy]succinimide N-Trimethylsilylimidazole N-(Trimethylsilyl)morpholine 3-Trimethylsilyl-2-oxazolidinone 4-Trimethylsilyloxy-3-penten-2-one Trimethylsilyl Trifluoromethanesulfonate D3135 D1608 D2334 T1468 D1594 I0324 M1199 M0536 T1689 T1078 T1588 T2591 T0585 T1277 T1535 T1573 T0871 A2301 B0105 B3571 N S N S S M2594 P1894 F F F F A2301 B0105 B3571 B3567 T0872 M2594 P1894 P0677 T0670 122 F CF3 C O F F O C O S CF3 O O CF3 C SCH2CH3 S T0670 F O CH3O C O 25g 5g 25g 25g 5g 25mL 5mL 5g 25g 25g 250mL 25g 5g 100g 25mL 5g 25mL 250g T0872 O C P0677 F O 5g O C Cl C CH3 1g 10g 5g 25mL 5g 1g 25g 5mL 5mL B3567 O O 1g 5g 5g 1g 5mL O (CH3)3C C Cl O CF3 N C N F 3-Acetylthiazolidine-2-thione Benzoyl Chloride 3-Benzoylthiazolidine-2-thione Benzoyl Trifluoromethanesulfonate S-Ethyl Trifluorothioacetate Methyl Pentafluorophenyl Carbonate Pentafluorophenyl Trifluoroacetate Pivaloyl Chloride 1-(Trifluoroacetyl)imidazole 5g 25mL 500mL 1g 5g 5g 5mL 1g 5g 25g 25mL 500mL 5g 25g A0480 A1247 B2379 B1151 B1257 OCH3 CHO CH O OCH3 H S CH3 BF4 CH2 C O CH2 S OCH3 OCH3 B3563 B3577 D0555 D0626 D4208 O C H CH3CH3 (CH3)3SiO OSi(CH3)3 CH3 C Si O CH CH3CH3 OCH3 OCH3 OCH3 O O S S CH3 O CH3 OCH3 E0478 E0479 CH3 CH3 CH3 Si O(CH2)2O Si CH3 CH3 P1378 E0471 CH3 CH3 CH3 CH3 Si CH3 S(CH2)2S Si CH3 CH3 CH3 P0763 Si CH3 A0480 A1247 B2379 B1151 B1257 B3563 B3577 D0555 D0626 D4208 E0478 E0479 E0471 E0105 S HS O O S S CH2CH2 S S O O CH3 I0303 HO OH CH2 CH3 C OCH3 D2390 CH3 CH3 E0105 SH CH3 O O S S(CH2)3S S O CH3 O p-Anisaldehyde p-Anisaldehyde Dimethyl Acetal Benzaldehyde 1,3-Benzodithiolylium Tetrafluoroborate Benzyl Isopropenyl Ether 1,3-Bis(trimethylsilyloxy)propane tert-Butyl[4-(dimethoxymethyl)phenoxy]dimethylsilane 3,4-Dihydro-2H-pyran 2,4-Dimethoxybenzaldehyde 3-(1,3-Dithian-2-ylidene)-2,4-pentanedione Ethylenedioxybis(trimethylsilane) Ethylenedithiobis(trimethylsilane) Ethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] Ethylene Glycol 25mL 500mL 25mL 500mL 500g 5g 1mL 5mL 5g 25g 5g 25mL 100mL 500mL 25g 500g 1g 5g 25g 5g 5g 25g 25g 500g 123 I0303 P1378 P0763 D2390 2-Methoxypropene (Phenylthio)trimethylsilane 1,3-Propanedithiol Trimethylene Di(thiotosylate) [Protecting Reagent for Active Methylene] B0643 C0274 A1268 25mL 500mL 5g 25g 25mL 100mL 5g 25g A2302 A2303 O CH2 Br O O CH2 Cl CH2 CHCH2O C Cl O CH2 CHCH2O C O N CH2 CHCH2O C O O B0411 B0412 C1591 C0176 B3021 CH2Br CH2Cl O B3234 C1124 Cl3C C OCH2 C1600 P1281 CH2O C O O C OCH2 P1277 O Cl O O CH2O C O N CH2O C O N O O CF3 CH2O C N O2N C1131 O NH O O CH2O C Cl B1483 B3574 M0676 O CH2 M2016 O O CH2O 124 CH2 CH2Br Cl3C C OCH2 OCH2 OCH3 OCH3 B0643 C0274 A1268 A2302 A2303 B0411 B0412 C0176 B3021 C1591 B3574 B1483 B3234 C1124 O NH O C O C O O N0181 CH2Cl CH2O C OCH2 O Allyl Bromide Allyl Chloride Allyl Chloroformate N-(Allyloxycarbonyloxy)succinimide Allyl Phenyl Carbonate Benzyl Bromide (stabilized with Propylene Oxide) Benzyl Chloride (stabilized with -Caprolactam) Benzyl Chloroformate (30-35% in Toluene) Benzyl Chloroformate Benzyl 4-Nitrophenyl Carbonate Benzyl Phenyl Carbonate Benzyl 2,2,2-Trichloroacetimidate Benzyl 2,2,2-Trifluoro-N-phenylacetimidate N-Carbobenzoxyoxysuccinimide NO2 25g 25g 500g 25mL 500mL 25g 500g 5g 25g 5g 25g 100g 500g 25g 500g 25mL 500mL 25g 250g 5g 5g 25g 25g 1g 5g 25g 250g N-(2-Chlorobenzyloxycarbonyloxy)succinimide Diallyl Dicarbonate Dibenzyl Carbonate Dibenzyl Dicarbonate 4-Methoxybenzyl Chloride (stabilized with Amylene) 4-Methoxybenzyl 2,2,2-Trichloroacetimidate 4-Nitrobenzyl Bromide C1131 P1277 C1600 P1281 M0676 M2016 N0181 T2713 25g 10g 5g 5g 25g 25mL 5g 500g 25g 5g 250g 1g 1g 5g C0795 N O O O O C OCH2CCl3 CCl3CH2O C Cl O T2713 C0795 N-(2,2,2-Trichloroethoxycarbonyloxy)succinimide 2,2,2-Trichloroethyl Chloroformate C1339 C0202 C2412 M0680 M0681 CH3 CH3 Si CH2CH3 CH2CH2OCH2Cl ClCH2OCH3 Cl O CCl3 CH3O(CH2)2OCH2Cl CH3O(CH2)2OCH2 N CH2CH3 CH2CH3 CH3 C1339 C0202 C2412 M0680 M0681 2-(Chloromethoxy)ethyltrimethylsilane (stabilized with Diisopropylethylamine) Chloromethyl Methyl Ether Chloromethyl 2,2,2-Trichloroethyl Ether 2-Methoxyethoxymethyl Chloride (2-Methoxyethoxymethyl)triethylammonium Chloride 25g Cl 5mL 100g 25mL 500g 5g 25mL 500mL 5g 125 B0916 B0988 C1573 CH3 CH3 CH3 O O C N N CH3 O O O C O N C CH3 CH3 CH3 CH3 C0933 B3590 CH3 CH3 F0239 F0197 O O CH2O C O N O 126 CH3 O C O C CH3 CH3 Cl CH3 N CH3 O C S N O O C N CH3 CH3 N N D3878 D3879 D3880 D1547 CH3 O O CH3 CH3 C O C O C O C CH3 CH3 N-tert-Butoxycarbonylimidazole 2-(tert-Butoxycarbonyloxyimino)-2-phenylacetonitrile N-(tert-Butoxycarbonyloxy)phthalimide 2-(tert-Butoxycarbonylthio)-4,6-dimethylpyrimidine 1-tert-Butoxycarbonyl-1,2,4-triazole tert-Butyl Carbazate tert-Butyl Phenyl Carbonate tert-Butyl 2,4,5-Trichlorophenyl Carbonate Di-tert-butyl Dicarbonate (ca 30% in Dioxane) Di-tert-butyl Dicarbonate (ca 30% in Tetrahydrofuran) Di-tert-butyl Dicarbonate (ca 30% in Toluene) Di-tert-butyl Dicarbonate B0916 B0988 C1573 B1089 B1969 C0933 B3590 C1574 D3878 D3879 D3880 D1547 F0239 F0197 F0936 O Cl CH3 O CH3 O Cl CH3 O C O C CH3 CH3 CH3 C1574 O O O C NHNH2 B1969 CH3 O O C O N CH3 CH3 B1089 CN CH3 100g 100mL 100g 25g 100g 10g 25g 5g 25g 25g 250g 25g 5g 500g 500mL 500g 500g 5g 25g 1g 25g 100g 5g 5g 5g 5g 25g 5g F0936 O CH2O C Cl F F F F O F CH2O C O N-[(9H-Fluoren-9-ylmethoxy)carbonyloxy]succinimide 9-Fluorenylmethyl Chloroformate 9-Fluorenylmethyl Pentafluorophenyl Carbonate 5g B1702 D2504 D1612 CH3O C Cl Br D2915 C Cl OCH3 T1071 T1526 T0512 N N C CH3O C Cl Cl C0308 O O Cl C O B1702 D2504 D1612 D2915 M0790 T1071 T1526 T0512 C0308 C Br CBr N CBr C Cl Cl O 9-Bromo-9-phenylfluorene 2-Chlorotrityl Chloride 4,4 -Dimethoxytrityl Chloride 4-(Dimethylamino)-1-(triphenylmethyl)pyridinium Chloride 4-Methoxytrityl Chloride 4,4 ,4 -Tris(benzoyloxy)trityl Bromide 4,4 ,4 -Tris(4,5-dichlorophthalimido)trityl Bromide Trityl Bromide Trityl Chloride A2555 C N N O 5g 5g 25g 5g 25g B1655 SO2Cl O N CH3 CH3 (CH2)3CH3 (CH2)3CH3 D0835 CH3 D1463 CH3 C1415 SCl NO2 NO2 S O P P Cl Cl Cl NO2 NO2 I0060 M0071 M0802 SO2Cl O CH3 O O CH3 NH Cl3C C O F CH3CH2O C N B1496 SO2NCO SO2Cl D2159 C0683 25g 100g 25g 25g 25g 5g 250g 25g 1g 100g 500g SO2Cl CH3 CH3 D2461 B1128 B1122 B0994 O O CH3 CH3 CH3 Cl M0790 M1004 SO2Cl CH3 O C CH2Br CH3I CH3 OCH3 OCH3 127 M0441 N0142 OH N0507 C1400 SO2Cl O2N SCH3 P1782 P1614 P1902 O F O O O F S O T1485 NH2 C CH2Br N H O F F T0272 T0998 T1606 CH3 T3177 O CH2CH3 S NCO O O T2872 CH3CH2 O A2555 B1122 B0994 B1128 B1655 B1496 D2461 D2159 D0835 D1463 C1415 C0683 I0060 M0071 M0802 M1004 M0441 N0142 N0507 C1400 N0363 P2188 P1782 P1614 P1902 T1485 T0272 T0998 T1606 T3177 T1146 T2590 128 CH3 O T1146 CH2CH3 O2N CH3 Si CHN2 CH3 SO2CF3 T1467 NO2 CH3 O C OCH2CH2 Si CH3 CH3 CH3 T1237 N O O C OCH2CH2Si(CH3)3 S O S O N BF4 T2544 N N O O CH3 N CH3 T2590 N O SO2Cl N NO2 O C Cl NO2 P2188 CF3 SCl O NO2 F N0363 SO2F N N O C S Cl Cl3CO C OCH2CH2Si(CH3)3 OCCl3 O 5-Acetyl-1,3-dimethylbarbituric Acid Bansyl Chloride (10% in Hexane) Bansyl Chloride 1,2-Benzenedisulfonyl Dichloride Benzenesulfonyl Isocyanate tert-Butyl 2,2,2-Trichloroacetimidate Dibenzosuberyl Chloride Dimethylthiophosphinoyl Chloride 2,4-Dinitrofluorobenzene 2,4-Dinitrophenylsulfenyl Chloride Diphenylphosphinic Chloride N-Ethoxycarbonylphthalimide Iodomethane (stabilized with Copper chip) 2-Mesitylenesulfonyl Chloride 4-Methoxybenzenesulfonyl Chloride -Methoxyphenacyl Bromide 4-(Methylthio)phenol 2-Nitrobenzenesulfonyl Chloride 4-Nitrobenzenesulfonyl Fluoride 4-Nitrophenyl Chloroformate 2-Nitrophenylsulfenyl Chloride Pentafluorophenyl Trifluoromethanesulfonate Phenacyl Bromide Phthalic Anhydride 2-(1H-Pyrazol-5-yl)aniline p-Toluenesulfonic Anhydride p-Toluenesulfonyl Chloride p-Toluenesulfonyl Isocyanate Triethyloxonium Tetrafluoroborate (15% in Dichloromethane, ca 1mol/L) [Ethylating Reagent] 1-(Trifluoromethanesulfonyl)imidazole Trimethylsilyldiazomethane (ca 10% in Hexane, ca 0.6mol/L) 1-[2-(Trimethylsilyl)ethoxycarbonyloxy]benzotriazole 1g 10mL 25g 25g 10mL 5g 5mL 5g 25g 5g 5mL 25mL 5g 25g 1g 5g 25g 500g 5g 10g 25g 25g 500g 100mL 300mL 25g 500g 100g 500g 5g 25g 25g 250g 100g 500g Price on request 25g 250g 25g 100g 200mg 1g 25g 500g 500g 1g 5g 25g 25g 500g 25g 500g 100mL 1g 5g 25mL 100mL 1g 5g 1mL 1g 5g T2872 T2544 T1237 T1467 4-[2-(Trimethylsilyl)ethoxycarbonyloxy]nitrobenzene 2-(Trimethylsilyl)ethyl 3-Nitro-1H-1,2,4-triazole-1-carboxylate Triphenylmethanesulfenyl Chloride Triphosgene 1g 25g 5g 5g 10g 250g 1971 1975 1999 129 Cationic Parts N R Anionic Parts R Cl Br R N R N N R R CH3COO CF3COO R R TfO R P R N R R Tf2N R N B2195 PF6 CH3 CH3 Cl N CH3 E0556 130 N CH2CH3 N I CH3 CH3O N CH3O CH3 N CH2CH3 CH3SO3 N O P O E0494 CH3 N N E0490 CH3 E0755 CH3 Br B3028 D3240 N CH2CH3 Lipase Enzymatic Catalyst D3341 N BR4 CH3(CH2)15O(CH2CH2O)nSO3 Solvent N PF6 (CH2)3CH3 C4H9 E0543 BF4 CH3 N CH3 N N R N R Water Solubility I CH3 Cl N CH2CH3 E0836 N CH3 N CH2CH3 CF3SO3 N CH3 N CH2CH3 CF3BF3 E0650 E0754 CH3 N CH2CH3 CH3CH2OSO3 N N CH3 I N (CH2)3CH3 N N PF6 N (CH2)3CH3 H1099 N N Br CH3 N N N Cl N B2473 D4289 N N N N CH2CH2CH3 N (CH2)3CH3 CH3 N CH3 CH3 CH3 (CH2)3CH3 N I CH3 N CH2CH2CH3 B2474 N BF4 CH3 CH3 CH3 (CH2)3CH3 N CF3SO3 N CH3 PF6 CH3 (CH2)3CH3 H1286 B3159 N N Cl CH3 D3903 B4182 CH3 (CF3SO2)2N Br N (CF3SO2)2N N CH3 (CH2)7CH3 CH2CH3 B2475 CH3 CH3 (CF3SO2)2N N N PF6 N N (CH2)9CH3 (CH2)7CH3 CH3 (CH2)5CH3 CH3 Cl N (CH2)5CH3 E0753 N PF6 CH3 M1904 N (CF3SO2)2N N CH3 N (CH2)7CH3 N CH3 D4351 CH3 N SCN (CH2)3CH3 (CH2)5CH3 M2063 CH3 H1098 N BF4 (CH2)5CH3 (CH2)5CH3 M2062 FeCl4 N BF4 N (CH2)3CH3 H1097 N H1423 CH3 N (CH2)3CH3 (CH2)3CH3 CH3 N CF3BF3 N CH3 N (CF3SO2)2N N CH3 B4091 CH3 (CH2)3CH3 H1227 N CF3SO3 N Br N (CH2)3CH3 B2195 CH3 B2672 CH3 Cl N CH3 N (CH2)3CH3 (CH2)3CH3 B2477 CH3 B3542 N Br3 N (CH2)3CH3 B2320 I CH2CH2CH3 CH3 N CH2CH3 B2193 N B2337 PF6 N CH2CH3 N CH2CH3 N CH3 N (CF3SO2)2N N FeCl4 CH3 N BF4 N CH3 N B3596 CH3 B2194 CH3 N CH2CH3 B2708 (NC)2N N M1440 (CF3SO2)2N N N CH2CH3 E0706 CH3 E0493 CH3 N CH2CH3 E0599 N E0496 CH3 N HSO4 N E0680 CH3 (CH2)3CH3 N CH3 CH3 I (CH2)5CH3 131 D3341 D3240 E0490 E0543 E0556 E0755 E0494 E0836 E0754 E0650 E0680 E0496 E0493 E0599 E0706 M1440 B2194 B2193 B2708 B3596 B2337 B3542 B2195 B2320 B2477 B2672 B4091 H1097 H1227 H1099 H1423 H1098 M1904 M2062 M2063 D4351 E0753 D3903 D4289 B2473 B2475 B4182 B2474 B3159 H1286 1,3-Dimethylimidazolium Chloride 1,3-Dimethylimidazolium Dimethyl Phosphate 1-Ethyl-3-methylimidazolium Chloride 1-Ethyl-3-methylimidazolium Bromide 1-Ethyl-3-methylimidazolium Iodide 1-Ethyl-3-methylimidazolium Methanesulfonate 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate 1-Ethyl-3-methylimidazolium Trifluoro(trifluoromethyl)borate 1-Ethyl-3-methylimidazolium Hydrogen Sulfate 1-Ethyl-3-methylimidazolium Ethyl Sulfate 1-Ethyl-3-methylimidazolium Dicyanamide 1-Ethyl-3-methylimidazolium Tetrafluoroborate 1-Ethyl-3-methylimidazolium Hexafluorophosphate 1-Ethyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Ethyl-3-methylimidazolium Tetrachloroferrate 1-Methyl-3-propylimidazolium Iodide 1-Butyl-3-methylimidazolium Chloride 1-Butyl-3-methylimidazolium Bromide 1-Butyl-3-methylimidazolium Iodide 1-Butyl-3-methylimidazolium Tribromide 1-Butyl-3-methylimidazolium Trifluoromethanesulfonate 1-Butyl-3-methylimidazolium Trifluoro(trifluoromethyl)borate 1-Butyl-3-methylimidazolium Tetrafluoroborate 1-Butyl-3-methylimidazolium Hexafluorophosphate 1-Butyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Butyl-3-methylimidazolium Tetrachloroferrate 1-Butyl-3-methylimidazolium Thiocyanate 1-Hexyl-3-methylimidazolium Chloride 1-Hexyl-3-methylimidazolium Bromide 1-Hexyl-3-methylimidazolium Tetrafluoroborate 1-Hexyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Hexyl-3-methylimidazolium Hexafluorophosphate 1-Methyl-3-n-octylimidazolium Bromide 1-Methyl-3-n-octylimidazolium Chloride 1-Methyl-3-n-octylimidazolium Hexafluorophosphate 1-Decyl-3-methylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Ethyl-2,3-dimethylimidazolium Bis(trifluoromethanesulfonyl)imide 1,2-Dimethyl-3-propylimidazolium Iodide 2,3-Dimethyl-1-propylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Butyl-2,3-dimethylimidazolium Chloride 1-Butyl-2,3-dimethylimidazolium Tetrafluoroborate 1-Butyl-2,3-dimethylimidazolium Trifluoromethanesulfonate 1-Butyl-2,3-dimethylimidazolium Hexafluorophosphate 1-Butyl-2,3-dimethylimidazolium Bis(trifluoromethanesulfonyl)imide 1-Hexyl-2,3-dimethylimidazolium Iodide N Cl B3232 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g B1329 Br N CH2CH3 B2196 25g 25g 250g 25g 25g 25g 25g 5g 25g 25g 5g 25g 25g 25g 5g 25g 100g 5g 25g 5g 25g 5g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 5g 5g 5g 1g 5g 5g 5g N CH2CH3 B1743 5g E0171 E0544 5g 5g 25g 5g 5g 5g 5g P1393 Cl (CH2)3CH3 B3425 CH3 N Br (CH2)3CH3 132 N (CH2)3CH3 BF4 N (CH2)3CH3 PF6 N Cl CH2CH2CH3 N Cl (CH2)3CH3 E0681 B3104 B3426 CH3 CH3 N E0682 Br N CH2OH CH3CH2OSO3 CH3CH2OSO3 N CH2CH3 (CH2)3CH3 B2700 CH3 CH3 Br Cl N CH2CH3 N (CH2)3CH3 (CH2)3CH3 B2701 CH3 PF6 N (CH2)3CH3 E0544 E0171 B1329 B1743 B3232 B2196 P1393 B3425 B3104 E0681 E0682 B3426 B2700 B2701 1-Ethylpyridinium Chloride 1-Ethylpyridinium Bromide 1-Butylpyridinium Chloride 1-Butylpyridinium Bromide 1-Butylpyridinium Tetrafluoroborate 1-Butylpyridinium Hexafluorophosphate 1-Propylpyridinium Chloride 1-Butyl-3-methylpyridinium Chloride 1-Butyl-3-methylpyridinium Bromide 1-Ethyl-3-methylpyridinium Ethyl Sulfate 1-Ethyl-3-(hydroxymethyl)pyridinium Ethyl Sulfate 1-Butyl-4-methylpyridinium Chloride 1-Butyl-4-methylpyridinium Bromide 1-Butyl-4-methylpyridinium Hexafluorophosphate 5g 5g 5g 5g 25g 25g 25g 25g 25g 25g 5g 5g 25g 25g 5g 25g 25g 25g 5g 25g 10g 5g 5g 5g 1g 5g 5g B3424 Br CH3 B3424 N (CH2)3CH3 1-Butyl-1-methylpiperidinium Bromide A2274 T2761 N CH2CH2CH3 CH3(CH2)4 N CH2CH3 T0054 (CH2)3CH3 CH3(CH2)3 N (CH2)3CH3 Cl (CH2)3CH3 M1660 (CH2)3CH3 CH3(CH2)3 N (CH2)3CH3 Br (CH2)3CH3 (CF3SO2)2N C1966 (CH2)7CH3 CH3 N (CH2)7CH3 CH3 N (CH2)3CH3 (CH2)3CH3 CH2CH3 CH3 (CF3SO2)2N T0055 (CH2)3CH3 CH2CH3 CH3 CH3 T2679 (CF3SO2)2N T1124 CH3 N CH3 (CH2)7CH3 CH3 (CF3SO2)2N (CF3SO2)2N (CH2)3CH3 CH3(CH2)3 P (CH2)3CH3 Br (CH2)3CH3 133 T2564 T2680 (CH2)3CH3 CH3 P (CH2)3CH3 (CH2)3CH3 CH3OCH2CH2 P (CH2)3CH3 (CH2)3CH3 (CH2)3CH3 T2314 (CH2)3CH3 CH3(CH2)3 P CH3CH2 S (CF3SO2)2N CH2CH3 Trimethylpropylammonium Bis(trifluoromethanesulfonyl)imide Amyltriethylammonium Bis(trifluoromethanesulfonyl)imide Tributylmethylammonium Bis(trifluoromethanesulfonyl)imide Tetrabutylammonium Chloride Tetrabutylammonium Bromide Methyltri-n-octylammonium Bis(trifluoromethanesulfonyl)imide Cyclohexyltrimethylammonium Bis(trifluoromethanesulfonyl)imide Tetrabutylphosphonium Bromide Tributylmethylphosphonium Bis(trifluoromethanesulfonyl)imide Tributyl(2-methoxyethyl)phosphonium Bis(trifluoromethanesulfonyl)imide Tributylhexadecylphosphonium Bromide Triethylsulfonium Bis(trifluoromethanesulfonyl)imide CH3 5g M2098 E0977 N 25g 100g B3358 CH3 N CH2CH2CH3 Cl CH3 N (CH2)3CH3 (CF3SO2)2N Br N E0977 M2098 B3358 B3427 B2851 (CH2)3CH3 CH3 N (CH2)3CH3 1-Ethyl-1-methylpyrrolidinium Tetrafluoroborate 1-Methyl-1-propylpyrrolidinium Bis(trifluoromethanesulfonyl)imide 1-Butyl-1-methylpyrrolidinium Chloride 1-Butyl-1-methylpyrrolidinium Bromide 1-Butyl-1-methylpyrrolidinium Bis(trifluoromethanesulfonyl)imide 5g 5g 5g 5g 5g 2009 2003 134 5g 25g 100g (CF3SO2)2N BF4 CH2CH3 5g 25g 25g 5g 25g 100g 500g 5g 5g 500g 5g 5g 25g 5g B2851 B3427 CH3 CH2CH3 (CH2)15CH3 Br (CH2)3CH3 (CF3SO2)2N (CF3SO2)2N T2761 A2274 T2679 T0055 T0054 M1660 C1966 T1124 T2680 T2564 H1047 T2314 H1047 25g 25g 25g 25g 25g (CF2)nCF3 P1384 (n=1), b.p 135 °C CF3(CF2)nCF3 P0839 (n=4), b.p 60 °C CF3(CF2)n P0851 (n=5), b.p 82 °C N P1051 (n=4) O0268 (n=6), b.p 104 °C (CF2)nCF3 E0485 (n=7), b.p 125 °C F F F F F F H0085 b.p 81 °C F F CF3 CF3 F F F F F F F F F F F F F Br D2669 DMF/THF E0485 P1420 P0851 F F F CF3 F F F O2N 85% Fluorous Phase (C6F13CH2CH2)3SnCl 99% (CF2)3CF3 CF3(CF2)3 N H0085 F P1755 CF3(CF2)7Br (CF2)3CF3 CF3(CF2)10CF3 P0837 F F F H0946 CF3 F F F F F F F F CF3(CF2)5CF3 F F Inorganic salt and water soluble waste CH2Cl2 Phase P0074 CF3(CF2)7CF3 CF3CHFCHFCF2CF3 F F P0837 b.p 142 °C Water Phase O2N F F P0856 b.p 104 °C FBS F F F CH2Cl2 CF3(CF2)4CF3 H2O F F F F F P0846 b.p 76 °C (C6F13CH2CH2)3SnPh PdCl2(PPh3)2 LiCl + F F F F O0268 F F F F F F F F F F F F F F F F CF3(CF2)6CF3 F 135 O0292 P0856 F F F F F F F F F CF3 F P1348 F F F F T1012 F F F F F D2669 E0485 P0074 H0946 P1755 P1420 P0851 H0085 P0837 O0268 O0292 P0856 P1348 P0867 P1051 P0839 P0846 T1012 T2921 F F P0839 CF2CF3 CF3CF2 N CF2CF3 C5F11 C5F11 N C5F11 CF3CF2CF2CF T2921 O CF3 CF3 CF3 CH3 F 2H,3H-Decafluoropentane 25g Eicosafluorononane 25g Heptacosafluorotributylamine [for Mass spectrometry] Heptadecafluoro-n-octyl Bromide 5g Hexacosafluorododecane Hexadecafluoro(1,3-dimethylcyclohexane) 10g Hexadecafluoroheptane (mixture of isomers) Hexafluorobenzene 25g Octadecafluorodecahydronaphthalene Octadecafluorooctane Octafluorocyclopentene Octafluorotoluene 5g Pentadecafluorotriethylamine 5g Perfluoro(2-butyltetrahydrofuran) (so called) Perfluorotriamylamine (so called) Tetradecafluorohexane 10g 25g Tetradecafluoromethylcyclohexane 25g Tetradecafluoro-2-methylpentane 1,1,1-Trifluoroacetone (in cylinder without valve) [To use this product charged in cylinder, a valve is required which is sold separately (Product Code:V0030)] 2009 1997 136 CF3(CF2)4CF3 F P0846 F P1051 CF3 500g 10g 100g 25g 1g 25g 25g 250g 25g 10g 50g 25g 25g 25g 25g 250g 100g 25mL 100g H2 Pd / (PSi-Al2O3) [P1944] neat, rt, 0.2 mL min-1 I + 14.5 g 1.5 h TON 2200 B(OH)2 recycle average yield 95% in 10 times HN O PdCl2 20 [P1425] recovery n 5.0 x 10-5 mol eq A2006 B2372 B2370 B2371 B2292 F F CH2NHCH2CH2NH P P CH2O C NH(CH2)4NHO2S O 2N P CH2O C NH(CH2)2NHO2S O 2N P CH2O C NH(CH2)3NHO2S CH P O 2N F SO2CF3 SO2CF3 F 137 C2141 D3525 M1452 M1857 O CH3 CH2N C N P P P1415 CH2 N (CH2)3N C NCH2CH3 CH3 O C CH3 O O PEG O C (CH2)2 C O P P P1425 O CH CH3 Cl Cl N CH3 CH3 NH O P 20 C O NH NH CH CH3 PdCl2 C O CH3 (CH2)3 CH3 N CH3 C12H25 n n PW12O403 P1719 CH3 CH2 N O P P1698 O P1944 N (CH2 CH)12 (CH2 CH)1 P O C CH3 CH2 P1697 CH3 Ru I CH2 P Cl P1427 O P D2766 (CH2 CH)x (CH2 CH)y (CH2 CH)z C O C O C O NH NH CH CH3 N (CH2)3 CH3 CH3 N CH3 n C12H25 RuO4 n n/3 S0545 CH3 Pd / (PSi-Al2O3) P SO2Cl CH2 N CH3 CH3 P BH3CN A2006 N-(2-Aminoethyl)aminomethyl Polystyrene Resin cross-linked with 1% DVB (50-100mesh) B2372 N-(4-Benzyloxytrityl)-N -(2-nitrobenzenesulfonyl)-1,4-diaminobutane Resin B2370 N-(4-Benzyloxytrityl)-N -(2-nitrobenzenesulfonyl)-1,2-diaminoethane Resin B2371 N-(4-Benzyloxytrityl)-N -(2-nitrobenzenesulfonyl)-1,3-diaminopropane Resin B2292 Bis(trifluoromethanesulfonyl)methyltetrafluorophenyl Polystyrene Resin C2141 D3525 D2766 M1452 M1857 P1415 P1427 P1425 P1697 P1698 P1944 P1719 S0545 (3.1-3.5mmol/g) 5g 1g cross-linked with 1% DVB (200-400mesh) (0.9-1.1mmol/g) 1g cross-linked with 1% DVB (200-400mesh) (0.9-1.1mmol/g) 1g cross-linked with 1% DVB (200-400mesh) (0.9-1.1mmol/g) 100mg N-Cyclohexylcarbodiimidomethyl Polystyrene Resin cross-linked with 1% DVB (50-100mesh) (1.4-1.6mmol/g) 5g 5g 1-(3-Dimethylaminopropyl)-3-ethylcarbodiimide Resin cross-linked with 1% DVB (50-100mesh) (1.0-1.3mmol/g) 4-Diphenylphosphinomethyl Polystyrene Resin cross-linked with 2% DVB (200-400mesh) (0.5-1.0mmol/g) 5g 1g 3-Methyl-2-oxoimidazolidin-1-ylmethyl Polystyrene Resin cross-linked with 1% DVB 5g Morpholinomethyl Polystyrene Resin cross-linked with 1% DVB (50-100mesh) (2.9-3.5mmol/g) Poly[4-(diacetoxyiodo)styrene] 1g 5g Polyethylene Glycol-bound Ruthenium Carbene Complex 100mg Poly[N-isopropylacrylamide-co-4-(diphenylphosphino)styrene] Palladium(II) Dichloride 100mg (ratio, acrylamide:phosphine=20:2) Poly[[N-isopropylacrylamide-co-[N-[3-(dodecyldimethylammonio)-propyl]acrylamide]]phosphotungstate] 200mg 1g Poly[[N-isopropylacrylamide-co-[N-[3-(dodecyldimethylammonio)-propyl]acrylamide]co-(1,3,5-triacryloylhexahydro-1,3,5-triazine)]perruthenate] 200mg 1g Poly(methylphenyl)silane supported Palladium/Alumina Hybrid Catalyst [=Pd / (PSi-Al2O3)] 1g (Polystyrylmethyl)trimethylammonium Cyanoborohydride 5g 25g cross-linked with 10% DVB (30-50mesh) (2.6-3.0mmol/g) Sulfonyl Chloride Polystyrene Resin cross-linked with 1% DVB (50-100mesh) (4.5-5.3mmol/g) 5g 25g cross-linked with 2% DVB (200-400mesh) (0.9-1.2mmol/g) 2013 2006 2003 2002 2004 2005 138 25g B0529 C2188 C2893 B(OH)2 CH3 B(OH)2 B(OH)2 C2442 E0913 F0280 F0664 H0913 B(OH)2 B(OH)2 Fe CH3CH2B(OH)2 Fe I0597 I0787 CH3 B(OH)2 CH3 P1942 M1553 CH3 CH3 CHB(OH)2 B(OH)2 B O O O0452 CH3B(OH)2 CH3 P2267 B(OH)2 CH3 B(OH)2 B B CH CH2 O CH CH2 B0529 C2188 C2893 C2442 E0913 F0280 F0664 H0913 I0597 I0787 M1553 O0452 P2267 P1942 T2498 B(OH)2 T2498 CH2 CH CH3 CH3 B(OH)2 B(OH)2 N Butylboronic Acid (contains varying amounts of Anhydride) Cyclohexylboronic Acid (contains varying amounts of Anhydride) 1-Cyclopentenylboronic Acid (contains varying amounts of Anhydride) Cyclopentylboronic Acid (contains varying amounts of Anhydride) Ethylboronic Acid (contains varying amounts of Anhydride) Ferroceneboronic Acid (contains varying amounts of Anhydride) 1,1 -Ferrocenediboronic Acid (contains varying amounts of Anhydride) Hexylboronic Acid (contains varying amounts of Anhydride) Isobutylboronic Acid (contains varying amounts of Anhydride) Isopropylboronic Acid (contains varying amounts of Anhydride) Methylboronic Acid (contains varying amounts of Anhydride) n-Octylboronic Acid (contains varying amounts of Anhydride) Pentylboronic Acid (contains varying amounts of Anhydride) Propylboronic Acid (contains varying amounts of Anhydride) 2,4,6-Trivinylboroxin - Pyridine Complex 1g 1g 5g 1g 1g 1g 1g 100mg 1g 5g 5g 1g 1g 5g 5g 1g 25g 5g 5g 5g 5g 1g 1g 5g 25g 25g 5g 5g 25g 25g 5g 139 A2453 A2818 A1942 B(OH)2 B(OH)2 B(OH)2 O O NH C CH3 C CH3 O C CH3 O A1907 A2745 A1281 B(OH)2 B(OH)2 A1774 B(OH)2 A1843 A2328 NH2 B4725 B(OH)2 B4590 F B2145 B2488 B(OH)2 B(OH)2 B(OH)2 OCH2 CH2O F B(OH)2 OCH2 B2489 B2294 B2490 B3927 B(OH)2 B1886 B2860 (HO)2B B(OH)2 B3600 N CH3 CH3 CH2Br B1858 B4279 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 O B4772 CH3 NH C O C CH3 Br CH3 Br B4700 B4640 B(OH)2 CH3 CH3 CH3 B(OH)2 B(OH)2 O(CH2)3CH3 CH3 C O C CH3 O NH C O C CH3 B4727 B(OH)2 B(OH)2 Br B4335 Br 140 B(OH)2 B(OH)2 CH2Br B(OH)2 B2890 B4726 CF3 B4463 CF3 B2889 CF3 N B3814 B(OH)2 Br B(OH)2 B(OH)2 CH3 CH3 CH3 CH3 B(OH)2 CF3 B3022 CH3 CH3 B(OH)2 O OCH2 F B3056 B(OH)2 B(OH)2 OCH2 C OCH2 CH2O B3683 B(OH)2 O B4639 (CH2)4CH3 B3779 B(OH)2 B(OH)2 1/2H2SO4 NH2 CH3 O B(OH)2 B(OH)2 H2O NH2 C CH3 A2336 CH3 C O C CH3 O CH3 O(CH2)3CH3 O(CH2)3CH3 B3726 B3739 B2251 B2589 C2992 B(OH)2 B(OH)2 B(OH)2 B(OH)2 CH3 CH3 CH3 CH3 O Si C CH3 CH3 C Si O B(OH)2 O CH3 CH3 CH3 C CH3 CH3 CH3 C2570 C2967 C2926 C NH2 (CH2)3CH3 CH3 C2523 C2385 B(OH)2 B(OH)2 B(OH)2 N N O Cl C NH2 O2N C OH B(OH)2 O C2501 C2028 C1353 C2664 C2772 B(OH)2 B(OH)2 B(OH)2 B(OH)2 C OH O B(OH)2 B(OH)2 Cl C OH O O C OH Cl C OH OCH2CH3 O C2666 C2946 C1760 Cl Cl F C2969 F F C2386 C2292 B(OH)2 Cl C2525 C2577 B(OH)2 B(OH)2 OCH3 OCH3 OH C2665 B(OH)2 CH3 CH3 C2591 B(OH)2 B(OH)2 C2601 C2571 B(OH)2 B(OH)2 CF3 CF3 Cl C2456 Cl C2416 B(OH)2 B(OH)2 CF3 Cl Cl Cl Cl Cl C1473 B(OH)2 CH3 Cl CH3 Cl C1705 B(OH)2 Cl B(OH)2 B(OH)2 OCH3 Cl Cl C2676 Cl Cl F C1613 F Cl C3056 B(OH)2 B(OH)2 B(OH)2 C3049 B(OH)2 B(OH)2 F Cl C2645 C2749 B(OH)2 B(OH)2 B(OH)2 C2914 F Cl C2031 B(OH)2 C1778 B(OH)2 B(OH)2 CN CN F F CN CN CN 141 D4670 D4263 B(OH)2 Br D3434 Cl D3783 Cl Cl Cl D2909 D4681 D3523 B(OH)2 B(OH)2 B(OH)2 B(OH)2 Cl Cl O(CH2)3CH3 D3357 D3044 B(OH)2 B(OH)2 O(CH2)3CH3 Br Cl D2494 B(OH)2 B(OH)2 B(OH)2 F Cl Cl Cl D3391 Cl Cl D3087 F D3521 OCH3 F D3522 D3861 B(OH)2 OCH3 D4428 OCH3 D4194 B(OH)2 CH3 N CH3 D3514 D3974 O CH3 C N CH3 CH3 CH3 CH3 CH3 CH3 B(OH)2 CH3 CH3 CH3 D3396 B(OH)2 B(OH)2 CH3 CH3 E0877 B(OH)2 CH3 CH3 D3537 D3516 D3110 B(OH)2 CH3 E0848 E0868 B(OH)2 CH3 CH3 E1124 B(OH)2 B(OH)2 B(OH)2 B(OH)2 OCH3 B(OH)2 D3633 B(OH)2 CH3O B(OH)2 HCl D3517 CH3 B(OH)2 OCH3 OCH3 D4013 B(OH)2 N B(OH)2 CH3O D3513 B(OH)2 CH3O OCH3 OCH3 F D3512 B(OH)2 OCH3 B(OH)2 B(OH)2 F F F D3853 B(OH)2 F F CH2CH3 D3081 B(OH)2 F C N O D3436 B(OH)2 CH2CH3 C OCH2CH3 O O N C OCH2CH3 F C OCH2CH3 OCH2CH3 O E1107 E0723 B(OH)2 CH3CH2O 142 E0724 B(OH)2 E0725 B(OH)2 E0818 B(OH)2 B(OH)2 CH2CH3 OCH2CH3 OCH2CH3 OCH2CH3 E0720 F0785 F0954 F0977 B(OH)2 F0951 B(OH)2 B(OH)2 B(OH)2 F OH O B(OH)2 CH2CH3 F0941 F0876 F0919 B(OH)2 B(OH)2 C OCH3 F F HO F F0775 F0683 B(OH)2 F OCH3 OCH3 F0915 F0666 B(OH)2 B(OH)2 F F F0712 CH3 F0697 F0976 B(OH)2 B(OH)2 B(OH)2 CH3 F CH3 F CH3 CH3 CH3 F0407 F F0404 F0942 F1006 B(OH)2 B(OH)2 F F CH3CH2CH2 F B(OH)2 F0834 B1873 B(OH)2 B(OH)2 F CF3 F F0446 H1357 CHO O H C H1489 H1345 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 OCH3 CF3 F0445 CF3 F0830 B(OH)2 F F B(OH)2 F F0788 CF3 F F F0361 B(OH)2 B(OH)2 F0816 F OCH3 F CH3O B(OH)2 B(OH)2 B(OH)2 CH2OH CHO H1244 O(CH2)5CH3 CHO H1204 H1495 B(OH)2 B(OH)2 (CH2)5CH3 H1402 H1184 B(OH)2 CH3 CH2OH H1228 B(OH)2 OH OH HO CH2OH H1185 B(OH)2 B(OH)2 OH I0830 B(OH)2 OH I0806 B(OH)2 I I0887 B(OH)2 OCH CH3 CH3 B(OH)2 CH3 CH3 143 I0620 I0950 M2417 M2418 M2676 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 O CH CH3 CH3 M1905 CH3 SCH SH CH3 M1906 SH M1907 M2244 B(OH)2 B(OH)2 CH3 C OCH3 B(OH)2 CH3 O O C OCH3 CH3 C OCH3 OCH3 O M2677 M2311 M2255 B(OH)2 M2256 CH2OCH3 M1322 B(OH)2 B(OH)2 OCH3 CH3O CH3 OCH3 M1252 M2457 M1127 M1313 B(OH)2 B(OH)2 B(OH)2 B(OH)2 M1261 CH3 OCH3 CH3 OCH3 B(OH)2 B(OH)2 CH3 M2685 B(OH)2 B(OH)2 CH2 N H B(OH)2 CH3 NO2 OCH3 M1314 CH3 CH3 OCH3 M1126 M2678 B(OH)2 B(OH)2 M1972 M1570 B(OH)2 B(OH)2 B(OH)2 SCH3 SO2CH3 CH3 M1793 CH3 SO2CH3 M1458 N0630 B(OH)2 B(OH)2 N0649 N0929 B(OH)2 B(OH)2 B(OH)2 SCH3 N1009 SCH3 N0798 N0946 N0811 N0563 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 NO2 NO2 N0812 P1904 P1093 B(OH)2 P1974 P1984 B(OH)2 B(OH)2 F F F F O NO2 144 F B(OH)2 B(OH)2 P2158 B0857 P1358 P2290 P1968 B(OH)2 N B(OH)2 B(OH)2 N (HO)2B B(OH)2 B(OH)2 OCH2CH2CH3 P2162 P1625 P2105 S0831 T2412 B(OH)2 CH3CH2CH2 B(OH)2 B(OH)2 N B(OH)2 C B(OH)2 O T2792 T2908 B(OH)2 T2413 B(OH)2 CH3 CH3 T2362 T1773 OCF3 N CH3 CH3 T1800 OCF3 T1793 T1788 T2874 B(OH)2 CF3 T2654 B(OH)2 CH3 F CH3 T2664 OCH3 T2430 B(OH)2 B O O B Cl F O B O B Cl F Cl F O B B O O B O F F B B O F O B F O B F B(OH)2 F B O O B F F F F A2453 A2818 A1942 A1907 B O F V0075 F O O B Cl T1929 O B F F Cl Si(CH3)3 B T1814 Cl B Si(CH3)3 CH3 D3435 O B(OH)2 CH3 OCH3 CH3 T2640 T1887 B(OH)2 CH3 CH3O F T2663 B(OH)2 CH3 CH3 CH F T1960 CH3 CH F F T2837 B(OH)2 CH F F CF3 F B(OH)2 F CF3 T2804 OCF3 T2574 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 B(OH)2 F CH CH2 3-Acetamidophenylboronic Acid (contains varying amounts of Anhydride) 4-Acetoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Acetylphenylboronic Acid (contains varying amounts of Anhydride) 4-Acetylphenylboronic Acid (contains varying amounts of Anhydride) 1g 200mg 5g 1g 5g 1g 25g 5g 145 146 A2745 A1281 A1774 A2336 A1843 A2328 B4725 B3779 B3683 B4639 B4590 B3056 B2145 B2488 B2489 B2294 B2490 B3927 3-Amino-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 3-Aminophenylboronic Acid Monohydrate (contains varying amounts of Anhydride) 3-Aminophenylboronic Acid Hemisulfate 4-Amylphenylboronic Acid (contains varying amounts of Anhydride) 2-Anthraceneboronic Acid (contains varying amounts of Anhydride) 9-Anthraceneboronic Acid (contains varying amounts of Anhydride) 4-(Benzyloxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Benzyloxy-4-fluorophenylboronic Acid (contains varying amounts of Anhydride) 2-Benzyloxy-5-fluorophenylboronic Acid (contains varying amounts of Anhydride) 4-Benzyloxy-3-fluorophenylboronic Acid (contains varying amounts of Anhydride) 2-Benzyloxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Benzyloxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Benzyloxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Biphenylboronic Acid (contains varying amounts of Anhydride) 3-Biphenylboronic Acid (contains varying amounts of Anhydride) 4-Biphenylboronic Acid (contains varying amounts of Anhydride) 4,4 -Biphenyldiboronic Acid 2,6-Bis[(2,2,6,6-tetramethyl-1-piperidinyl)methyl]phenylboronic Acid B3022 B1886 B2860 B3600 B3814 B4463 B2889 B2890 B1858 B4279 B4335 B4726 B4772 B4700 B4640 B4727 B3726 B3739 B2251 B2589 C2992 C2570 C2967 C2926 C2523 C2385 C2501 C2028 C1353 C2664 C2772 C2666 C2946 C1760 C2914 C2749 C2645 C2969 C2386 C3056 C2292 C3049 C2525 C2577 C2665 C1705 C1613 C1473 C2591 C2601 2,4-Bis(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 3,5-Bis(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) -Bromo-4-biphenylboronic Acid (contains varying amounts of Anhydride) 2-(Bromomethyl)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Bromomethyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Bromo-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) 2-Bromophenylboronic Acid (contains varying amounts of Anhydride) 3-Bromophenylboronic Acid (contains varying amounts of Anhydride) 4-Bromophenylboronic Acid (contains varying amounts of Anhydride) 3-[(tert-Butoxycarbonyl)amino]phenylboronic Acid (contains varying amounts of Anhydride) 4-[(tert-Butoxycarbonyl)amino]phenylboronic Acid (contains varying amounts of Anhydride) 3-(tert-Butoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(tert-Butoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Butoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Butoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Butoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-(tert-Butyldimethylsilyloxy)phenylboronic Acid (contains varying amounts of Anhydride) 4-(tert-Butyldimethylsilyloxy)phenylboronic Acid (contains varying amounts of Anhydride) 4-tert-Butylphenylboronic Acid (contains varying amounts of Anhydride) 4-Butylphenylboronic Acid (contains varying amounts of Anhydride) 3-Carbamoylphenylboronic Acid (contains varying amounts of Anhydride) 4-Carbamoylphenylboronic Acid (contains varying amounts of Anhydride) 3-(9H-Carbazol-9-yl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(9H-Carbazol-9-yl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Carboxy-3-chlorophenylboronic Acid (contains varying amounts of Anhydride) 3-Carboxy-5-nitrophenylboronic Acid (contains varying amounts of Anhydride) 2-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-4-ethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Chloro-4-fluorophenylboronic Acid (contains varying amounts of Anhydride) 2-Chloro-5-fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-2-fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-4-fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-5-fluorophenylboronic Acid (contains varying amounts of Anhydride) 4-Chloro-3-fluorophenylboronic Acid (contains varying amounts of Anhydride) 5-Chloro-2-fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-4-hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Chloro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 5-Chloro-2-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Chloro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 3-Chloro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 4-Chloro-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 5-Chloro-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 2-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 3-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride) 2-Chloro-5-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Chloro-2-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) (contains varying amounts of Anhydride) 1g 1g 1g 5g 5g 250mg 1g 1g 1g 1g 1g 1g 5g 1g 5g 5g 5g 200mg 1g 1g 5g 1g 1g 1g 5g 5g 1g 1g 1g 200mg 1g 1g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g 1g 1g 5g 5g 1g 1g 5g 25g 25g 5g 1g 5g 5g 5g 5g 5g 5g 25g 5g 25g 25g 25g 1g 1g 5g 25g 1g 1g 5g 1g 5g 25g 25g 5g 5g 5g 1g 1g 5g 5g 5g 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 25g 5g 5g 5g 5g 5g 25g 25g 5g 5g C2571 C2676 C2456 C2416 C2031 C1778 D4670 D4263 D3434 D2494 D3044 D3357 D3783 D2909 D4681 D3523 D3391 D3436 D3087 D3081 D3853 D3521 D3522 D3861 D3512 D3513 D4428 D4013 D4194 D3974 D3516 D3514 D3517 D3633 D3110 D3396 D3537 E0877 E0848 E0868 E1124 E1107 E0723 E0724 E0725 E0818 E0720 F0785 F0954 F0977 F0951 F0941 F0876 F0919 F0775 F0683 F0915 F0712 F0666 F0697 F0976 F0407 F0404 F0361 F0942 F1006 F0816 F0788 4-Chloro-3-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 3-Cyano-4-fluorophenylboronic Acid (contains varying amounts of Anhydride) 4-Cyano-3-fluorophenylboronic Acid (contains varying amounts of Anhydride) 2-Cyanophenylboronic Acid (contains varying amounts of Anhydride) 3-Cyanophenylboronic Acid (contains varying amounts of Anhydride) 4-Cyanophenylboronic Acid (contains varying amounts of Anhydride) 3,5-Dibromophenylboronic Acid (contains varying amounts of Anhydride) 2,4-Dibutoxyphenylboronic Acid (contains varying amounts of Anhydride) 2,3-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 2,4-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 2,5-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 2,6-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 3,4-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 3,5-Dichlorophenylboronic Acid (contains varying amounts of Anhydride) 4-(Diethylcarbamoyl)phenylboronic Acid (contains varying amounts of Anhydride) 2,3-Difluorophenylboronic Acid (contains varying amounts of Anhydride) 2,4-Difluorophenylboronic Acid (contains varying amounts of Anhydride) 2,5-Difluorophenylboronic Acid (contains varying amounts of Anhydride) 2,6-Difluorophenylboronic Acid (contains varying amounts of Anhydride) 3,5-Difluorophenylboronic Acid (contains varying amounts of Anhydride) 2,3-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2,4-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2,5-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2,6-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 3,4-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 3,5-Dimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-(Dimethylamino)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Dimethylamino)phenylboronic Acid Hydrochloride (contains varying amounts of Anhydride) 3-(Dimethylcarbamoyl)phenylboronic Acid (contains varying amounts of Anhydride) 9,9-Dimethylfluoren-2-boronic Acid (contains varying amounts of Anhydride) 2,3-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 2,4-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 2,5-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 2,6-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 3,4-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 3,5-Dimethylphenylboronic Acid (contains varying amounts of Anhydride) 4-(Diphenylamino)phenylboronic Acid (contains varying amounts of Anhydride) 2-(Ethoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Ethoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Ethoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Ethoxy-3-fluorophenylboronic Acid (contains varying amounts of Anhydride) 6-Ethoxy-2-naphthaleneboronic Acid (contains varying amounts of Anhydride) 2-Ethoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Ethoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Ethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Ethylphenylboronic Acid (contains varying amounts of Anhydride) 4-Ethylphenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-4-biphenylboronic Acid (contains varying amounts of Anhydride) 3-Fluoro-5-hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 5-Fluoro-2-hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Fluoro-3-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-6-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Fluoro-4-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Fluoro-3-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 5-Fluoro-2-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-5-methylphenylboronic Acid (contains varying amounts of Anhydride) 3-Fluoro-4-methylphenylboronic Acid (contains varying amounts of Anhydride) 4-Fluoro-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 4-Fluoro-3-methylphenylboronic Acid (contains varying amounts of Anhydride) 5-Fluoro-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 2-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 4-Fluorophenylboronic Acid (contains varying amounts of Anhydride) 3-Fluoro-4 -propyl-4-biphenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-3-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-4-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Fluoro-5-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 1g 1g 1g 1g 1g 5g 5g 5g 1g 5g 5g 5g 5g 1g 5g 5g 5g 1g 5g 1g 1g 1g 1g 5g 5g 5g 1g 1g 1g 1g 1g 5g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g 1g 5g 1g 5g 5g 5g 1g 1g 1g 1g 5g 1g 5g 5g 25g 25g 25g 5g 25g 25g 25g 5g 25g 5g 5g 25g 25g 25g 5g 25g 5g 5g 5g 25g 25g 25g 5g 5g 5g 5g 5g 5g 25g 5g 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 25g 5g 1g 5g 5g 5g 5g 5g 25g 5g 5g 5g 5g 25g 5g 25g 25g 25g 5g 5g 5g 5g 147 F0830 F0834 B1873 F0445 F0446 H1357 H1489 H1345 H1244 H1204 H1495 H1402 H1184 H1185 H1228 I0830 I0806 I0887 I0620 I0950 M2417 M2418 M2676 M1905 M1906 M1907 M2244 M2685 M2677 M2311 M2255 M2256 M1261 M1322 M1252 M2457 M1127 M1313 M1314 M1126 M2678 M1972 M1570 M1793 M1458 N0630 N0649 N0929 N1009 N0798 N0946 N0811 N0563 N0812 P1904 P1093 P1974 P1984 P2158 B0857 P1358 P2290 P1968 P2162 P1625 P2105 S0831 T2412 148 4-Fluoro-3-(trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 5-Formyl-2-methoxyphenylboronic Acid (contains varying amounts of Anhydride) 2-Formylphenylboronic Acid (contains varying amounts of Anhydride) 3-Formylphenylboronic Acid (contains varying amounts of Anhydride) 4-Formylphenylboronic Acid (contains varying amounts of Anhydride) 4-Hexyloxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Hexylphenylboronic Acid (contains varying amounts of Anhydride) 2-(Hydroxymethyl)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Hydroxymethyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Hydroxymethyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Hydroxy-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 6-Hydroxy-2-naphthaleneboronic Acid (contains varying amounts of Anhydride) 2-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Iodophenylboronic Acid (contains varying amounts of Anhydride) 4-Isopropoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Isopropylphenylboronic Acid (contains varying amounts of Anhydride) 4-Isopropylphenylboronic Acid (contains varying amounts of Anhydride) 4-(Isopropylthio)phenylboronic Acid (contains varying amounts of Anhydride) 3-Mercaptophenylboronic Acid (contains varying amounts of Anhydride) 4-Mercaptophenylboronic Acid (contains varying amounts of Anhydride) 3-Methacrylamidophenylboronic Acid (contains varying amounts of Anhydride) 2-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-Methoxy-2,6-dimethylphenylboronic Acid (contains varying amounts of Anhydride) 4-Methoxy-3,5-dimethylphenylboronic Acid (contains varying amounts of Anhydride) 4-(Methoxymethyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Methoxy-5-methylphenylboronic Acid (contains varying amounts of Anhydride) 4-Methoxy-2-methylphenylboronic Acid (contains varying amounts of Anhydride) 6-Methoxy-2-naphthaleneboronic Acid (contains varying amounts of Anhydride) 2-Methoxyphenylboronic Acid (contains varying amounts of Anhydride) 3-Methoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Methoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-Methyl-1-naphthaleneboronic Acid (contains varying amounts of Anhydride) 4-Methyl-3-nitrophenylboronic Acid (contains varying amounts of Anhydride) 2-Methylphenylboronic Acid (contains varying amounts of Anhydride) 3-Methylphenylboronic Acid (contains varying amounts of Anhydride) 4-Methylphenylboronic Acid (contains varying amounts of Anhydride) 2-(Methylsulfonyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Methylsulfonyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride) 1-Naphthaleneboronic Acid (contains varying amounts of Anhydride) 2-Naphthaleneboronic Acid (contains varying amounts of Anhydride) 10-(2-Naphthyl)anthracene-9-boronic Acid (contains varying amounts of Anhydride) 3-(2-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(1-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(2-Naphthyl)phenylboronic Acid (contains varying amounts of Anhydride) 2-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 3-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 4-Nitrophenylboronic Acid (contains varying amounts of Anhydride) Pentafluorophenylboronic Acid (contains varying amounts of Anhydride) 9-Phenanthreneboronic Acid (contains varying amounts of Anhydride) 4-Phenoxyphenylboronic Acid (contains varying amounts of Anhydride) 10-Phenyl-9-anthraceneboronic Acid (contains varying amounts of Anhydride) 4-(1-Phenyl-1H-benzimidazol-2-yl)phenylboronic Acid (contains varying amounts of Anhydride) Phenylboronic Acid (contains varying amounts of Anhydride) 1,4-Phenylenediboronic Acid (contains varying amounts of Anhydride) 4-Phenylnaphthalene-1-boronic Acid (contains varying amounts of Anhydride) 4-Propoxyphenylboronic Acid (contains varying amounts of Anhydride) 4-(trans-4-Propylcyclohexyl)phenylboronic Acid (contains varying amounts of Anhydride) 1-Pyreneboronic Acid (contains varying amounts of Anhydride) 4-[(1-Pyrrolidinyl)carbonyl]phenylboronic Acid (contains varying amounts of Anhydride) 9,9 -Spirobi[9H-fluorene]-2-boronic Acid 2-p-Terphenylboronic Acid (contains varying amounts of Anhydride) 1g 1g 1g 1g 1g 5g 1g 1g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 5g 5g 1g 1g 1g 5g 1g 5g 5g 5g 1g 1g 5g 5g 5g 1g 1g 1g 1g 5g 5g 1g 1g 200mg 1g 5g 1g 1g 1g 5g 5g 1g 1g 1g 25g 5g 1g 5g 1g 5g 1g 1g 5g 5g 5g 25g 5g 5g 5g 5g 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 25g 25g 5g 5g 5g 25g 5g 5g 25g 25g 25g 5g 5g 25g 25g 25g 5g 5g 5g 5g 5g 25g 25g 1g 5g 5g 1g 5g 25g 5g 5g 5g 25g 1g 5g 250g 25g 5g 25g 5g 25g 5g 5g 1g -m-Terphenylboronic Acid (contains varying amounts of Anhydride) 2-[(2,2,6,6-Tetramethyl-1-piperidyl)methyl]phenylboronic Acid (contains varying amounts of Anhydride) 2-(Trifluoromethoxy)phenylboronic Acid (contains varying amounts of Anhydride) 3-(Trifluoromethoxy)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Trifluoromethoxy)phenylboronic Acid (contains varying amounts of Anhydride) 2-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 1g 3-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Trifluoromethyl)phenylboronic Acid (contains varying amounts of Anhydride) 2,3,4-Trifluorophenylboronic Acid (contains varying amounts of Anhydride) 2,3,5-Trifluorophenylboronic Acid (contains varying amounts of Anhydride) 2,4,6-Trifluorophenylboronic Acid (contains varying amounts of Anhydride) 2,4,6-Triisopropylphenylboronic Acid (contains varying amounts of Anhydride) 3,4,5-Trimethoxyphenylboronic Acid (contains varying amounts of Anhydride) 2,4,6-Trimethylphenylboronic Acid 3-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride) 4-(Trimethylsilyl)phenylboronic Acid (contains varying amounts of Anhydride) 2,4,6-Triphenylboroxin 2,4,6-Tris(3,4-dichlorophenyl)boroxin 2,4,6-Tris(3,4-difluorophenyl)boroxin 2,4,6-Tris(4-fluorophenyl)boroxin 2,4,6-Tris(m-terphenyl-5 -yl)boroxin 2,4,6-Tris(3,4,5-trifluorophenyl)boroxin 4-Vinylphenylboronic Acid (contains varying amounts of Anhydride) T2792 T2908 T2413 T2362 T1773 T1800 T1793 T1788 T2574 T2874 T2804 T2654 T2837 T1960 T2663 T2664 T2640 D3435 T2430 T1814 T1887 T1929 V0075 A2364 B2978 1g 5g 5g 1g 1g 1g 1g 1g 1g 5g 5g 5g 1g 1g B4522 B(OH)2 O CH3 C B4774 B2893 S Cl N N Cl B(OH)2 E1115 F N S B(OH)2 B(OH)2 C OC(CH3)3 O D4567 OCH2CH3 Cl S B(OH)2 (HO)2B O CH3O N OCH3 F0935 CH3 F B(OH)2 D4690 F0739 N O B(OH)2 F (HO)2B N Br D4711 F0984 (HO)2B B(OH)2 Cl D4006 S S Br B(OH)2 S S B4063 C2066 B(OH)2 S O (HO)2B D4057 D3823 B(OH)2 N N C2288 B(OH)2 B(OH)2 D4373 O B2862 B(OH)2 C2589 N B(OH)2 (HO)2B S C2560 S B3307 B(OH)2 1g 1g 5g 5g 25g 25g 5g 5g 5g 5g 5g 5g 1g 5g 5g 5g 25g 25g 25g 10g 100mg 5g 5g B(OH)2 N F B(OH)2 N F 149 F0770 F0859 F0548 F (HO)2B N B(OH)2 F0394 F0438 F0549 O O H C N F F0611 S S B(OH)2 I0803 O H C O M2159 B(OH)2 B(OH)2 M2335 N H (HO)2B O M2035 M1850 H C S B(OH)2 M2029 B(OH)2 O B(OH)2 N (HO)2B N OCH3 P2169 OCH3 P2001 B(OH)2 (HO)2B (HO)2B N N P1673 O P1594 N CH3 S Q0080 (HO)2B T2621 T1772 B(OH)2 N A2364 B2978 B4522 B4774 B2893 B3307 B2862 B4063 C2560 C2589 C2288 C2066 D4567 D4373 D4057 D4006 D4711 D4690 D3823 E1115 F0984 F0739 F0935 F0770 150 N T1975 T3188 B(OH)2 S B(OH)2 S B(OH)2 B(OH)2 B(OH)2 N S N N Q0087 N N Q0086 B(OH)2 B(OH)2 P1759 B(OH)2 B(OH)2 N O OCH3 (HO)2B N S 5-Acetyl-2-thiopheneboronic Acid (contains varying amounts of Anhydride) Benzofuran-2-boronic Acid (contains varying amounts of Anhydride) Benzofuran-3-boronic Acid (contains varying amounts of Anhydride) Benzo[b]thiophene-3-boronic Acid (contains varying amounts of Anhydride) Benzo[b]thiophene-2-ylboronic Acid (contains varying amounts of Anhydride) 2-Bromopyridine-5-boronic Acid (contains varying amounts of Anhydride) 5-Bromo-2-thiopheneboronic Acid (contains varying amounts of Anhydride) 1-(tert-Butoxycarbonyl)-2-pyrroleboronic Acid (contains varying amounts of Anhydride) 2-Chloropyridine-3-boronic Acid (contains varying amounts of Anhydride) 2-Chloropyridine-4-boronic Acid (contains varying amounts of Anhydride) 2-Chloropyridine-5-boronic Acid (contains varying amounts of Anhydride) 5-Chloro-2-thiopheneboronic Acid (contains varying amounts of Anhydride) Dibenzofuran-4-boronic Acid (contains varying amounts of Anhydride) Dibenzothiophene-2-boronic Acid (contains varying amounts of Anhydride) Dibenzothiophene-4-boronic Acid (contains varying amounts of Anhydride) 2,6-Difluoro-3-pyridineboronic Acid (contains varying amounts of Anhydride) 2,3-Dihydrobenzofuran-5-boronic Acid (contains varying amounts of Anhydride) 2,6-Dimethoxypyridine-3-boronic Acid (contains varying amounts of Anhydride) Dithieno[3,2-b:2 ,3 -d]thiophene-2-boronic Acid (contains varying amounts of Anhydride) 2-Ethoxypyridine-5-boronic Acid (contains varying amounts of Anhydride) 2-Fluoro-3-methylpyridine-5-boronic Acid (contains varying amounts of Anhydride) 2-Fluoropyridine-3-boronic Acid (contains varying amounts of Anhydride) 2-Fluoropyridine-4-boronic Acid (contains varying amounts of Anhydride) 2-Fluoropyridine-5-boronic Acid (contains varying amounts of Anhydride) 5g 1g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 200mg 1g 5g 1g 1g CF3 25g 1g 5g 5g 25g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 200mg 5g 1g 5g 1g 25g 5g 5g F0859 F0548 F0611 F0549 F0394 F0438 I0803 M2159 M2029 M2335 M2035 M1850 P2169 P2001 P1673 P1594 P1759 Q0080 Q0087 Q0086 T2621 T1772 T1975 T3188 5-Fluoropyridine-3-boronic Acid (contains varying amounts of Anhydride) -Formyl-2,2 -bithiophene-5-boronic Acid (contains varying amounts of Anhydride) 5-Formyl-2-furanboronic Acid (contains varying amounts of Anhydride) 5-Formyl-2-thiopheneboronic Acid (contains varying amounts of Anhydride) 2-Furylboronic Acid (contains varying amounts of Anhydride) 3-Furylboronic Acid (contains varying amounts of Anhydride) 6-Indoleboronic Acid (contains varying amounts of Anhydride) 2-Methoxypyridine-3-boronic Acid (contains varying amounts of Anhydride) 2-Methoxypyridine-5-boronic Acid (contains varying amounts of Anhydride) 2-Methoxy-5-pyrimidylboronic Acid (contains varying amounts of Anhydride) 3,4-(Methylenedioxy)phenylboronic Acid (contains varying amounts of Anhydride) 5-Methyl-2-thiopheneboronic Acid (contains varying amounts of Anhydride) 9-Phenylcarbazole-2-boronic Acid (contains varying amounts of Anhydride) 9-Phenylcarbazole-3-boronic Acid (contains varying amounts of Anhydride) 3-Pyridylboronic Acid (contains varying amounts of Anhydride) 4-Pyridylboronic Acid (contains varying amounts of Anhydride) 5-Pyrimidylboronic Acid (contains varying amounts of Anhydride) Quinoline-3-boronic Acid (contains varying amounts of Anhydride) Quinoline-5-boronic Acid (contains varying amounts of Anhydride) Quinoline-8-boronic Acid (contains varying amounts of Anhydride) Thieno[3,2-b]thiophene-2-boronic Acid (contains varying amounts of Anhydride) 2-Thiopheneboronic Acid (contains varying amounts of Anhydride) 3-Thiopheneboronic Acid (contains varying amounts of Anhydride) 2-(Trifluoromethyl)pyridine-5-boronic Acid (contains varying amounts of Anhydride) A2086 A2574 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 200mg 5g 1g 5g 1g 100mg 1g 200mg 1g A2157 CH3 CH3 CH3 O B CH C CH2 CH3 O CH3 CH3 O B4103 CH3 CH3 CH3 B CH2 CH3 CH3 O O CH3 O C2707 CH3 O O CH3 CH3 C2276 CH3 CH3 D3596 CH3 O B CH2CH CH2 C3101 CH3 CH3 CH3 CH3 CH3 O O CH3 CH3 O CH3 O CH3 O B B B CH2Br B CH2 B O O CH3 B3199 CH3 O CH3 B CH2CH CH2 CH3 B3448 5g 1g O CH3 CH3 CH3 D3738 D3649 E1116 CH3 CH3 CH3 O CH2 CH B B CH3 O O(CH2)3CH3 O(CH2)3CH3 CH2 CHCH2 B OCH(CH3)2 OCH(CH3)2 BrCH2 B E1074 M2071 CH3 B C CH O CH3 A2086 A2574 A2157 B3448 B4103 B3199 CH3 O OCH(CH3)2 CH3 O B CH2CH3 T2297 CH3 CH3 O CH3 OCH(CH3)2 CH3 CH3 CH3 5g 1g 5g 5g 5g 5g 1g 5g 5g 5g 25g 5g 1g 25g 25g 5g 1g 5g 200mg 1g 1g 25g 5g 1g CH3 O CH3 O B CH2 CH3 CH3 O CH3 O B CH CH2 OCH3 CH3 2-Allenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Allyl-5,5-dimethyl-1,3,2-dioxaborinane (stabilized with Phenothiazine) 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 2-Benzyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Bis[(pinacolato)boryl]methane 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1g 1g 1g 1g 1g 1g 5g 5g 5g 5g 5g 5g 151 C2707 C3101 C2276 D3596 D3738 D3649 E1116 E1074 M2071 T2297 2-(1-Cyclohexenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Dibutyl Vinylboronate (stabilized with Phenothiazine) Diisopropyl Allylboronate Diisopropyl (Bromomethyl)boronate 2-Ethyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-(4-Methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-vinyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) B4633 CH3 O CH3 O CH3 CH3 B4588 CH3 O B O CH3 O B O CH3 CH3 CH3 CH3 B3501 CH3 CH3 CH3 O O CH3 CH3 O CH3 CH3 O B (CH2)9CH3O CH3 CH3 B3956 Fe CH3 CH3 O B O O CH3 CH3 CH3 CH3 O O B B O O CH3 CH3 B CH3 D3601 O CH3 B N CH2CH3 CH3 CH2CH3 CH3 CH3 O CH3 CH3 CH3 O CH3 O CH3 O CH3 B O CH3 O CH3 O CH3 CH3 O CH3 O Cl OH Cl CH3 CH3 CH3 CH3 O CH3 O N CH3 CH3 CH3 CH3 O CH3 O CH3 OH B CH3 CH3 M2665 O CH3 CH3 O CH3 O O OH Cl D2853 I0653 B CH3 B B B CH3 CH3 CH3 O CH3 Cl CH3 O (CH2)7CH3 O O CH3 B F CH3 O CH3(CH2)7 CH3 CH3 CH3 NC H1280 O CH3 B D4201 B B F0531 CH3CH2O C O CH3 B CH3 O O D3832 O O B CH3 CH3 E0667 Br D4575 CH3 CH3 CH3 O Cl B D3533 O CH3 CH3 CH3 O B CH3 CH3 C2004 CH3 CH3 O CH3 CH3 CH3 Br O CH3 CH3 O O CH3(CH2)5 CH3 B B O D4195 CH3 CH3 O B (CH2)5CH3 O B B4771 C2621 NC O CH3 O CH3 NC O O CH3 CH3 C2823 CH3 CH3 CH3 CH3 B3582 CH3 CH3 CH3 B2828 CH3 CH3 C2993 (CH2)11CH3 O O CH3(CH2)11 CH3 CH3 CH3 CH3 B B O O B CH3 CH3 O O CH3 CH3 B4029 CH3 CH3 CH3 CH3 O B 152 CH3 CH3 O B O CH3 B B B4624 CH3 O B OCH (CH ) CH3 B3151 O CH3 5g CH3 CH3 B B4166 1g B3019 CH3 1g 5g 5g 5g 5g 5g 5g 1g 5g 25g 1g 1g 1g 1g 1g 1g 200mg I C OCH3 B CH3 B O O CH3 CH3 CH3 CH3 N0824 P1855 CH3 CH3 NO2 CH3 O O B CH3 T3196 CH3 CH3 B O B C H O B CH3 O O CH3 CH3 B CH3 CH3 O CH3 O CF3 OH CH3 CH3 O CH3 B O CH3 CH3 O T2888 CH3 CH3 O CH3 O CH3 O B CH3 O C CH3 CH3 CH3 CH3 O O O CH3 O T3219 O2N CH2Br B CH3 O O CH3 B CH3 CH3 T2428 B B B CH3 O CH3 O T3089 CH3 CH3 O T3224 B CH3 T3261 CH3 CH3 OH O CH3 T3103 O CH3 T1954 B CH3 CH3 C OH O B O CH3 CH3 CH3 O O CH3 CH3 CH3 N1006 CH3 NH2 T2945 CH3 CH3 CH3 O CH3 T3218 O CH3 B B B CH3 CH3 C OH O HO O OH O CH3 B O T2841 T1953 CH3 CH3 O O CH3 CH3 T1952 CH3 CH3 B C CH3 CH3 CH3 CH3 CH3 CH3 T3031 NH CH3 NH2 O O O CH3 CH3 CH3 O CH3 O T3162 OCH3 O CH3 CH3 CH3 O CH3 O CH3 T2923 CH3 CH3 CH3 T1951 CH3 B O CH3 T3028 CH3 O NH2 B CH3 T1950 CH3 O O CH3 CH3 CH3 CH3 CH3 CH3 CH3 O CH3 O CF3 B CH3 B4633 B3019 B3151 B4166 B4588 B4624 B4029 B3582 B3501 B3956 B2828 B4771 C2004 C2993 C2823 C2621 1,4-Benzenediboronic Acid Bis(pinacol) Ester 2-(4-Biphenylyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 4,4 -Bis(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)biphenyl 4,4 -Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-didecylfluorene 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-didodecylfluorene 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-dihexylfluorene 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-di-n-octylfluorene 1,1 -Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ferrocene 2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrene 2-(2-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-(4-Bromophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2-(2-Chlorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane 2-Cyanophenylboronic Acid 1,3-Propanediol Ester 2-(2-Cyanophenyl)-5,5-dimethyl-1,3,2-dioxaborinane (This product is only available in Japan.) 2-(2-Cyanophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane D4575 D4201 D3601 D4195 D3533 D3832 2-(3,5-Dichlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 2,6-Dichloro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol N,N-Diethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 5,5-Dimethyl-2-phenyl-1,3,2-dioxaborinane 2-(3,5-Dimethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane N,N-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline (This product is only available in Japan.) 5g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 5g 1g 25g 5g 1g 5g 1g 1g 1g 1g 5g 5g 5g 5g 1g 5g 5g 5g 5g 5g 5g 25g 5g 5g 153 D2853 E0667 F0531 H1280 I0653 M2665 N0824 P1855 T1950 T3028 T1951 T3196 T2923 T3162 T2841 T2945 T3031 T1952 T1953 T1954 T3224 T3218 N1006 T3089 T3219 T2888 T3103 2,6-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenol Ethyl 2-(5,5-Dimethyl-1,3,2-dioxaborinan-2-yl)benzoate 2-(2-Fluorophenyl)-5,5-dimethyl-1,3,2-dioxaborinane 2-(Hydroxymethyl)phenylboronic Acid Cyclic Monoester 2-(2-Iodophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Methyl 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate 2-Nitro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 2-Phenyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane -(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)acetanilide 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)aniline 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)anisole 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzaldehyde 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzoic Acid 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl Bromide -(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl-4-ol 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenol 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl Acetate 4,4,5,5-Tetramethyl-2-(1-naphthyl)-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-(2-nitrophenyl)-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-(3-perylenyl)-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-(m-tolyl)-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-(p-tolyl)-1,3,2-dioxaborolane 4,4,5,5-Tetramethyl-2-[4-(trifluoromethyl)phenyl]-1,3,2-dioxaborolane 1g T3261 T2428 4,4,5,5-Tetramethyl-2-[3-(triphenylen-2-yl)phenyl]-1,3,2-dioxaborolane 2-[2-(Trifluoromethyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 1g 1g 5g 1g 1g 5g 1g 1g 1g 1g 1g 1g 1g 1g 1g 1g 200mg 1g 1g 1g 200mg (This product is only available in Japan.) B4364 B4158 CH3 O CH3 O CH3 N CH3 N S S O B O CH3 CH3 N CH3 CH3 B3200 CH3 CH3 CH3 O CH3 O B S O CH3 O CH3 CH3 CH3 D4290 CH3 O B B S CH3 S O S Br CH3 CH3 O CH3 CH3 S CH3 M2650 CH3 O CH3 O S O CH3 OCH3 N CH3 CH3 CH3 O CH3 N O O (CH2)7CH3 CH3 O B (CH2)5CH3 O B CH3 S O CH3 CH3 O0439 O0410 CH3(CH2)7 CH3 O O CH3 CH3 CH3 S O CH3 M2681 O O H1294 CH3 CH3 N CH3 CH3 CH3 CH3 CH3 O B CH3 O B N C O C CH3 CH3 B CH3 B CH3 N N CH3 154 O CH3 CH3 O CH3 CH3(CH2)7 CH3 B Br CH3 CH3 O H1298 B M2339 CH3 CH3 N O CH3 CH3 CH3 CH3 CH3 (CH2)11CH3 O CH3 B B O CH3 CH3 CH3 D3772 CH3(CH2)5 B O CH3 O0428 CH3 B O CH3 D4291 CH3(CH2)11 B4051 CH3 CH3 CH3 CH3 B3749 N S O CH2 B3363 CH3 CH3 CH3 O B O CH3 O B O CH3 CH3 B 5g 1g 5g B3573 CH3 CH3 5g 1g 1g 5g 1g 5g 1g 25g 1g 5g 5g 25g 5g 5g 1g 5g 5g 5g 5g 5g 5g 5g 5g 1g 5g 5g CH3 O N B N O CH3 CH3 CH3 CH3 O CH3 O CH3 B CH3 N (CH2)7CH3 O CH3 O CH3 B CH3 CH3 CH3 CH3 O B O CH3 S O0411 P2277 T3215 CH3 CH3 O CH3 O (CH2)7CH3 B S CH3 O CH3 CH3 T2518 T3117 CH3 CH3 O B O B CH3 CH3 N N N CH3 CH3 CH3 O O B O CH3 N O CH3 CH3 S O CH3 B S O N H CH3 CH3 CH3 CH2CH2CH3 T3236 I0590 I0739 S O B CH3 CH3 CH3 CH3 O CH3 O B B O N H N T2345 CH3 CH3 CH3 O CH3 CH3 CH3 T2349 CH3 CH3 O CH3 O T2756 CH3 CH3 CH3 O CH3 O CH3 O B B N H N N CH3 T2924 CH3 CH3 O CH3 B O CH3 CH3 B4364 B4158 B3573 B3363 B3200 B3749 B4051 D3772 D4290 D4291 O0428 H1298 H1294 M2650 M2339 M2681 O0439 O0410 O0411 P2277 T3215 T2518 T3117 T3236 I0590 I0739 T2756 T2345 T2349 T2924 CH3 O CH3 O B N S CH3 1-Benzyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g 1g 2,6-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzo[1,2-b:4,5-b ]dithiophene 4,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,1,3-benzothiadiazole 1g 5,5 -Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2 -bithiophene 5g 5-Bromo-5 -(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2 -bithiophene 1g 2-Bromo-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g 1g 1-(tert-Butoxycarbonyl)-1,2,3,6-tetrahydro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 3,5-Dimethyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)isoxazole 1g 5g 3-Dodecyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 4-Dodecyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 9-(9-Heptadecanyl)-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-carbazole 200mg 1g 3-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 25g 4-Hexyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 5g 2-Methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g 1-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g 1-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g 200mg 9-n-Octyl-2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole 3-n-Octyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 1g 5g 4-n-Octyl-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1-Propyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g 1-(Tetrahydropyran-2-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-pyrazole 1g 5g 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,2 -bithiophene 1g 5g 25g 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)carbazole 1g 5g 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)dibenzothiophene 1g 5g 1g 5g 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)isoquinoline 1g 5g 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyrazole 1g 5g 3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g 25g 4-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1g 5g 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)thiophene 1g 5g 155 A1299 A1334 O O CH3 O A2153 HCl NH2 A0826 HO A1688 O A1043 O OH HBr B1756 O C OH NH2 NH2 A1438 O C OH H2N CH3 O C OH NH CH3 B3177 F N O C OH N O C OH C OC(CH3)3 O O B4083 C1584 B4141 HO O Boc O N Boc C OCH2 O O Boc O O C1377 O OH NH2 C OH C OC(CH3)3 C2109 Cl N OH N O O B3700 O C OH N O OH N Boc NH C OC(CH3)3 B1635 OH N O C1612 OH F F O C OH C OC(CH3)3 B4202 C OH NH C OC(CH3)3 F O OH Br B3539 OH B3178 CH3 O O Br Br CH3 O OH C B3538 O B4005 HO O O OH NH2 O C OH O OH OH B4142 O B1757 OH NH2 O C OH NH C HCl CH3 NH2 A2286 B1120 OH NH 156 Br NH2 O B1121 OH NH2 OH NH2 CH2 O O OH A1689 O CH3 HO NH2 OH A1377 O OH O S A1450 O OH O O CH3 CH3 A1457 O CH2 O OH CH3 O A1648 A1647 HCl CH3 O OH Cl CH3 OH Cl C1663 C2738 C1365 O CH3 O OH Cl Cl C1655 Cl D2636 CH3 O C OH C OH C OH C OH O O O CH3 O O O HCl NH2 O H2N OH 2HCl NH2 CH3 H2N D3491 D1354 D3492 D1398 D3826 O O HOOC O C OCH3 HOOC O C OCH3 HOOC O C OCH3 HOOC O C OCH3 O Ph O O O HO O Ph OH H2O O Ph O O O HO OH H2O O D4375 D3677 O D2702 D2686 O O O CH3 C OH CH3 CH3O OH NH2 NH CH3O (CH3)3C O O O (CH3)3C HO C OH HCl D1387 O p-Tol E0993 O E0994 O O p-Tol O HO OH O OH O O N O N O N O N O O O OH H0937 HO O NH2 H0933 I0589 O O OH NH2 O OH CH3 OH L0026 O OH OH O OH I0395 O N O HO NH HO H1339 OH NH2 OH O O HO O HO N H OH O HN H0758 F NH OH H1224 O C Cl O NH O G0265 H C O CH2CH3 O p-Tol O O F0721 F0818 CH2CH3 O HO p-Tol O O C(CH3)3 O O D1417 O OH O C(CH3)3 O O HO OH O O Ph O O D2539 HCl OH NH2 O O OH O OH O D3490 H2N D1573 O HO O O OH NH2 D0083 CH3 O OH O D1377 O O HO O C2569 O D1386 O OH OH Cl CH3 OH Cl D3825 CH3 Cl C1954 O CH3 O O OH Cl C1953 O OH CH3 CH3 OH OH C1373 CH3 C1371 O CH3 OH OH N H C1372 N H OH O N H OH O CH3 OH CH3 OH 157 L0144 M0021 M0022 M0662 M0661 O O O O CH3 HO OLi M1366 HO OH O OH OH O M1021 M0829 M1228 O CH3 C OH OH M1229 M1226 O C OH OH HO N0327 HO OH O0281 O0276 N H H H2N P1288 OH C OH O O O O P1219 O CH3 C OH P1830 HO OH O O N H OH N0678 Q0009 O O C OH C OH N H N H T1740 T0026 OH OH O OH OH O HO O HO OH OH O OH OH T1515 O O C OH N H T0025 HO C OH T0219 O C OH O C OH O HO T1741 O P1404 O OH N0654 OH NH2 P0936 O OH OH OH C OH HCl NH2 O P1168 158 H2N P1981 NH2 O 2HCl NH2 O O O OH C OH P0820 O O OH NH2 O O NH2 CH3 O0064 H OH NH2 OH NH2 O0089 O CH3 O CH3 CH3 O0370 O OH O OH O CH3 N0686 O N0303 O OH O CH3 N0673 O C OH CH3 O HO CH3O HO M1227 O CH3 CH3O O O CH3O C OH OH M0830 CH3O HO C OH OH O CH3 HO O C OH C OH NH T1900 O O HO C NH S CF3 HO CH3 OH T1901 O CF3 OH HO CH3 A1299 A1334 A1647 A1648 A2153 A1457 A1450 A1377 A0826 A1688 A1689 A2286 A1438 A1043 B1121 B1120 B4142 B4005 B1756 B1757 B3538 B3539 B4202 B3177 B3178 B1635 B4141 B3700 B4083 C1584 C1612 C2109 C1377 C1663 C2738 C1365 C1372 C1371 C1655 C1373 C1953 C1954 C2569 D3825 D2636 D1386 D0083 D1573 D1377 D3490 D3491 D1398 D3826 D1354 D3492 D2539 D4375 D3677 (S)-(-)-2-Acetoxypropionic Acid 5g 25g 5mL 25mL (S)-(-)-3-(Acetylthio)-2-methylpropionic Acid 200mg 1g D-2-Allylglycine Hydrochloride 200mg 1g 5g L-2-Allylglycine Hydrochloride 1g 5g D-2-Aminoadipic Acid 1g 5g L-2-Aminoadipic Acid (S)-(+)-2-Amino-4-bromobutyric Acid Hydrobromide 1g 5g 1g 5g (R)-(-)-2-Aminobutyric Acid 1g 5g (S)-(+)-2-Aminobutyric Acid (1R,2R)-2-Aminocyclohexanecarboxylic Acid 100mg 100mg (1S,2S)-2-Aminocyclohexanecarboxylic Acid 200mg (1S,3R)-3-Aminocyclohexanecarboxylic Acid (S)-(-)-4-Amino-2-hydroxybutyric Acid 5g 25g 100mg 1g L-Azetidine-2-carboxylic Acid (+)-cis-2-Benzamidocyclohexanecarboxylic Acid 5g 5g (-)-cis-2-Benzamidocyclohexanecarboxylic Acid (S)-Benzylsuccinic Acid 5g 25g 5g (R)-2-Bromo-3-methylbutyric Acid 5g 25g (R)-(+)-2-Bromopropionic Acid (S)-(-)-2-Bromopropionic Acid 5g 25g 1g (1R,3S)-3-(tert-Butoxycarbonylamino)cyclohexanecarboxylic Acid (1S,3R)-3-(tert-Butoxycarbonylamino)cyclohexanecarboxylic Acid 1g 200mg 1g (S)-1-(tert-Butoxycarbonyl)-4,4-difluoro-2-pyrrolidinecarboxylic Acid (2S,4R)-1-(tert-Butoxycarbonyl)-4-fluoro-2-pyrrolidinecarboxylic Acid 200mg 1g 200mg 1g (2S,4S)-1-(tert-Butoxycarbonyl)-4-fluoro-2-pyrrolidinecarboxylic Acid trans-N-(tert-Butoxycarbonyl)-4-hydroxy-L-proline 5g N-(tert-Butoxycarbonyl)-4-oxo-L-proline 1g 5g 1g 5g (S)-1-(tert-Butoxycarbonyl)-2-piperidinecarboxylic Acid N-(tert-Butoxycarbonyl)-L-pyroglutamic Acid 5g 25g (3S)-2-Carbobenzoxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylic Acid 5g 1g 5g 3-Chloro-L-alanine Hydrochloride (R)-2-Chlorobutyric Acid 1g 5g 1g 5g (S)-2-Chlorobutyric Acid 1g 5g 2-Chloro-D-mandelic Acid 5g 25g 2-Chloro-L-mandelic Acid (S)-2-Chloro-3-methylbutyric Acid 1g 5g (2S,3S)-2-Chloro-3-methylvaleric Acid 1g 5g 1g 5g (S)-2-Chloro-4-methylvaleric Acid (R)-(+)-2-Chloropropionic Acid 1g 5g 25g (S)-(-)-2-Chloropropionic Acid 1g 5g 25g (1R,2R)-1,2-Cyclohexanedicarboxylic Acid 1g 5g (1S,2S)-1,2-Cyclohexanedicarboxylic Acid 1g 5g 1g 5g L-2-Cyclohexylglycine 100mg 1g 3,4-Dehydro-L-proline (+)-Diacetyl-D-tartaric Acid 5g 25g (-)-Diacetyl-L-tartaric Acid (S)-(+)-2,4-Diaminobutyric Acid Dihydrochloride 1g 100mg 1g (R)-(-)-2,3-Diaminopropionic Acid Hydrochloride 100mg 1g (S)-(+)-2,3-Diaminopropionic Acid Hydrochloride (+)-Di-p-anisoyl-D-tartaric Acid 25g (-)-Di-p-anisoyl-L-tartaric Acid 25g (+)-Dibenzoyl-D-tartaric Acid Monohydrate 25g 500g 25g 250g (+)-Dibenzoyl-D-tartaric Acid (-)-Dibenzoyl-L-tartaric Acid Monohydrate 25g 500g (-)-Dibenzoyl-L-tartaric Acid 25g 250g 5g 25g D-(-)-2-(2,5-Dihydrophenyl)glycine (S)-(-)-6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoline-3-carboxylic Acid Hydrochloride 1g 5g 1g 5g (S)-(+)-2,2-Dimethylcyclopropanecarboxylic Acid 159 D2702 D2686 D1417 D1387 E0993 E0994 F0818 F0721 G0265 H1224 H0937 H1339 H0758 H0933 I0589 I0395 L0026 L0144 M0021 M0022 M0662 M0661 M1366 M1021 M0830 M0829 M1228 M1229 M1226 M1227 N0327 N0303 N0673 N0686 O0370 O0089 O0064 O0281 O0276 P0820 P1288 P1981 P1168 P1219 P0936 P1830 P1404 N0654 N0678 Q0009 T0026 T0025 T1740 T1741 T1515 T0219 T1900 T1901 (+)-Dipivaloyl-D-tartaric Acid (-)-Dipivaloyl-L-tartaric Acid (+)-Di-p-toluoyl-D-tartaric Acid (-)-Di-p-toluoyl-L-tartaric Acid (R)-(-)- -[[(4-Ethyl-2,3-dioxo-1-piperazinyl)carbonyl]amino]benzeneacetic Acid (R)-(-)- -[[(4-Ethyl-2,3-dioxo-1-piperazinyl)carbonyl]amino]-4-hydroxybenzeneacetic Acid trans-4-Fluoro-L-proline O-Formyl-D-mandeloyl Chloride (S)-(-)-2-Guanidinoglutaric Acid D-Homoserine (R)-(+)-2-(4-Hydroxyphenoxy)propionic Acid (S)-2-Hydroxy-4-phenylbutyric Acid 4-Hydroxy-D-(-)-2-phenylglycine (S)-(+)-2-Hydroxy-4-phthalimidobutyric Acid (R)-(+)-Indoline-2-carboxylic Acid (S)-(-)-Indoline-2-carboxylic Acid 1g L-Leucic Acid Lithium L-Lactate D-(+)-Malic Acid 25g L-(-)-Malic Acid 25g D-(-)-Mandelic Acid L-(+)-Mandelic Acid (R)-(-)-2-Methoxy-2-(1-naphthyl)propionic Acid (S)-(+)-2-(6-Methoxy-2-naphthyl)propionic Acid 100mg (R)-(-)- -Methoxyphenylacetic Acid (S)-(+)- -Methoxyphenylacetic Acid (R)-(-)-2-Methylglutaric Acid (S)-(+)-2-Methylglutaric Acid (R)-(+)-Methylsuccinic Acid (S)-(-)-Methylsuccinic Acid D-Norleucine 100mg L-Norleucine 1g D-Norvaline L-Norvaline (2S,3aS,7aS)-Octahydro-1H-indole-2-carboxylic Acid L-Ornithine Dihydrochloride L-Ornithine Monohydrochloride (R)-(-)-5-Oxotetrahydrofuran-2-carboxylic Acid (S)-(+)-5-Oxotetrahydrofuran-2-carboxylic Acid D-2-Phenylglycine L-2-Phenylglycine D-(+)-3-Phenyllactic Acid L-(-)-3-Phenyllactic Acid (R)-(-)-2-Phenylpropionic Acid (S)-(+)-Phenylsuccinic Acid D-Pipecolic Acid L-Pipecolic Acid (R)-(-)-3-Piperidinecarboxylic Acid (S)-(+)-3-Piperidinecarboxylic Acid D-(-)-Quinic Acid D-(-)-Tartaric Acid L-(+)-Tartaric Acid (R)-(+)-Tetrahydrofuran-2-carboxylic Acid (S)-(-)-Tetrahydrofuran-2-carboxylic Acid 1g (S)-(-)-1,2,3,4-Tetrahydroisoquinoline-3-carboxylic Acid L-Thioproline (R)-3,3,3-Trifluoro-2-hydroxy-2-methylpropionic Acid (S)-3,3,3-Trifluoro-2-hydroxy-2-methylpropionic Acid A2124 A1101 O 160 O O O C CH3 O O 1g 1g 25g 1g 5g 5g 100g 100g 25g 25g 1g 1g 5g 1g 1g 5g 1g 1g 1g 25g 1g 1g 25g 25g 1g 1g 1g 5g 1g 1g 1g 5g 25g 25g 5g 5g 5g 25g L0161 O O 1g 5g 25g 25g 1g 1g O O C CH3 O CH3 O OH 5g 25g 250g 250g 5g 5g 50mg 25g 100mg 5g 5g 5g 500g 5g 1g 5g 25g 25g 25g 500g 500g 250g 100mg 500g 5g 5g 5g 5g 25g 5g 10g 5g 25g 5g 5g 5g 250g 5g 5g 500g 100g 5g 5g 5g 1g 25g 5g 5g 5g 25g 500g 500g 25g 25g 25g 500g 1g 1g M1354 M1355 B3987 O O B4083 Boc B4026 N O Boc N H O O T0005 OC(CH3)3 OH O OH O OH T1387 CH3 O O O OH T0621 CH3 O O O CH3 O CH3 OH CH3 CH3 O O CH3 O M1230 O O O O C OCH3 O O CH3 CH3 CH3 O CH3O OCH3 O M1232 OH P1189 O O O CH3O OCH3 O O CH3O OCH3 OH CH3 T1659 OCH3 O T0006 CH3O CH3 E0948 C OCH3 O OCH3 O O CH3O C O O CH3O CH3 OH M1347 O M1231 CH3 O C OCH3 CH3O C CH3 M1343 CH3 OH O O CH3O C OH OH O I0447 OH CH3 O OH O O O O I0474 CH3 CH3 OC(CH3)3 O T0003 OH O OH CH3 CH3 O (CH3)3CO OH OH O CH3 CH3 OH O T1195 O O CH3 CH3 C O C CH3 CH3 O O O O O O(CH2)3CH3 N O O O M1348 O CH3O C D3898 H HO H O CH3(CH2)3O Boc T1671 O M1351 OCH3 N O H1418 HOH2C OH O OCH3 N OH OH B1755 HO HO O O B3843 O CH3 CH3 E0940 E0469 O OH O CH3O OH OCH3 O OCH3 O OH C OCH2CH3 O CH3O N OH E0450 H0904 O CH3CH2 O N0655 N H CH3 CH3 M1273 N0679 O O CH3 O C OCH2CH3 C OCH2CH3 CH3 H0958 SO3 O CH3 CH3 HOCH2 CH3 L0115 O CH3 O OH OH T1241 O O O OH OH N H M1344 O O OCH2CH3 N CH3CH2 O O CH3 L0162 OCH2CH3 N Boc C O C CH3 O OCH2CH3 N O CH3 O O O O CH3 CH3 O O 161 A1383 B2139 O CH3 B2140 O S Br CH3 CH3 CH3 O M1349 O HO OCH3 CH3 HO M1350 O CH3 OCH3 OCH3 O OCH3 OH M2198 OCH3 CH3 OH P0011 O O OCH3 N H OCH3 CH3 OH CH3 O O (+)-O-Acetyl-D-malic Anhydride (-)-O-Acetyl-L-malic Anhydride Benzyl (S)-(-)-Lactate Benzyl D-(-)-Mandelate Benzyl L-(+)-Mandelate N-(tert-Butoxycarbonyl)-cis-4-hydroxy-L-proline Methyl Ester N-(tert-Butoxycarbonyl)-trans-4-hydroxy-L-proline Methyl Ester (S)-(-)-3-tert-Butoxycarbonyl-4-methoxycarbonyl-2,2-dimethyl-1,3-oxazolidine N-(tert-Butoxycarbonyl)-L-pyroglutamic Acid tert-Butyl L-Pyroglutamate (-)-Corey Lactone Dibenzyl L-Tartrate Di-tert-butyl L-(+)-Tartrate Dibutyl L-(+)-Tartrate Diethyl D-(+)-Malate Diethyl L-(-)-Malate Diethyl D-(-)-Tartrate Diethyl L-(+)-Tartrate Diisopropyl D-(-)-Tartrate Diisopropyl L-(+)-Tartrate Dimethyl (+)-2,3-O-Isopropylidene-D-tartrate Dimethyl (-)-2,3-O-Isopropylidene-L-tartrate Dimethyl D-(+)-Malate Dimethyl L-(-)-Malate Dimethyl (S)-(+)-2-Methylglutarate Dimethyl (R)-(+)-Methylsuccinate Dimethyl (S)-(-)-Methylsuccinate Dimethyl (2R,3R)-2,3-O-(1-Phenylethylidene)-L-tartrate Dimethyl D-(-)-Tartrate Dimethyl L-(+)-Tartrate Ethyl (R)-1-(tert-Butoxycarbonyl)-3-piperidinecarboxylate Ethyl N-(tert-Butoxycarbonyl)-D-pyroglutamate 1g 5g 5g 5g 5g 1g 1g 1g 5g 5g 1g 200mg OH OH R0063 OH O T2902 H HO O O N OH A2124 A1101 L0161 M1354 M1355 B3987 B3843 B1755 B4083 B4026 H1418 T1671 D3898 T0005 M1351 M1348 T1195 T0003 T1387 T0621 I0474 I0447 M1347 M1343 M1230 M1231 M1232 P1189 T1659 T0006 E0948 E0940 162 O M2350 O L0163 CH3 OCH3 OCH3 Cl L0136 O O O OCH3 CH3 Cl H0956 O CH3O C CH3 OCH3 CH3 H0703 O O Br OCH3 CH3 D2562 C1634 O O OCH3 C1633 OH O O CCl3 25g 5g 5g 25g 25g 25g 25g 5g 5g 5g 5g 1g 5g 25g 25g 25g 25g 5g 5g 25g 25g 5g 1g 25g 1g 500g 25g 25g 250g 500g 250g 500g 5g 25g 25g 25g 5g 5g 5g 5g 25g 25g 5g 5g Ethyl (R)-(+)-1-Ethyl-2-pyrrolidinecarboxylate Ethyl (S)-(-)-1-Ethyl-2-pyrrolidinecarboxylate Ethyl (R)-2-Hydroxy-4-phenylbutyrate Ethyl L-(-)-Lactate Ethyl D-(-)-Mandelate Ethyl L-(+)-Mandelate Ethyl (R)-(-)-3-Piperidinecarboxylate Ethyl (S)-(+)-3-Piperidinecarboxylate Ethyl L-(-)-O-Tosyllactate (S)-(+)- -Hydroxymethyl- -butyrolactone L-(-)-Lactide Methyl (R)-(+)-3-(Acetylthio)-2-methylpropionate Methyl (R)-(+)-3-Bromoisobutyrate Methyl (S)-(-)-3-Bromoisobutyrate Methyl (R)-(+)-2-Chloropropionate Methyl (S)-(-)-2-Chloropropionate Methyl (R)-(+)-2,2-Dimethyl-1,3-dioxolane-4-carboxylate Methyl (R)-(-)-3-Hydroxyisobutyrate Methyl (R)-(+)-2-(4-Hydroxyphenoxy)propionate Methyl D-(+)-Lactate Methyl L-(-)-Lactate Methyl D-(-)-Mandelate Methyl L-(+)-Mandelate Methyl D-3-Phenyllactate Methyl L-Pyroglutamate D-(-)-Pantolactone D-(+)-Ribono-1,4-lactone (2R,5S)-2-Trichloromethyl-3-oxa-1-azabicyclo[3.3.0]octan-4-one E0469 E0450 H0904 L0162 M1344 M1273 N0655 N0679 T1241 H0958 L0115 A1383 B2139 B2140 C1633 C1634 D2562 H0703 H0956 L0136 L0163 M1349 M1350 M2350 M2198 P0011 R0063 T2902 A1169 B3756 O CH3 O N NH2 NH2 5g 25g 1g 1g 1g 25g 25g 1g A1124 O O NH C CH3 O (CH3)3C Si O H 3C CH3 CH3 NH O CH3 C Si CH3 CH3 O O E0468 O O O O CO2H D3676 C NH2 CH2CH3 OH D4347 O OH N H C NH2 C NH O CH3 H0867 L0167 O O N CH3 O CH3 CH2 N H H1241 O O NH O E0452 N OC(CH3)3 N H O O H N CH2 NH CH3 CH3 D1539 O C NH2 CH2CH3 O O C CH3 B4026 CH3 O H O H H N H N H H CH3 CH3 CH3 C NH C CH3 C NH2 C2699 CH3 B1776 H O C2678 5g 5g N H C OC(CH3)3 HCl 1g 1g NH C CH3 B3410 5g 5g 5g 500g 25g 25g 25g 25g 25g 5g 250g 5mL 5g 5g 5g 5g 25g 25g 25g 25g 500g 5g 5g 5g 100g 500g 5g 1g 25g 5g 5g 5g 5g 1g 1g 25g A1170 N H A2252 1g 1g HOCH2 N H O HOCH2 N H O CH3 NH2 OH 163 M2198 P2083 N H O P1382 T1702 O OCH3 N H O N H OH H N O C NH2 T1369 C NH2 O O NH C CF3 OH O OH HCl N H T1366 O NH C CF3 HCl N H (3R)-(+)-3-Acetamidopyrrolidine (3S)-(-)-3-Acetamidopyrrolidine (3R,4R)-4-Acetoxy-3-[(R)-(tert-butyldimethylsilyloxy)ethyl]-2-azetidinone (S)-2-Aminobutyramide Hydrochloride N-(tert-Butoxycarbonyl)-L-prolinamide (S)-N-tert-Butyldecahydroisoquinoline-3-carboxamide (3S,4S)-3-[(R)-1-(tert-Butyldimethylsilyloxy)ethyl]-4-[(R)-1-carboxyethyl]-2-azetidinone tert-Butyl L-Pyroglutamate (R)- -(Carbobenzoxyamino)- -butyrolactone N-Carbobenzoxy-L-homoserine Lactone (+)-N,N -Diallyl-L-tartardiamide (S)-(+)-2,2-Dimethylcyclopropanecarboxamide (S)-N-(2,6-Dimethylphenyl)piperidine-2-carboxamide (R)-(+)-1-Ethyl-2-pyrrolidinecarboxamide (S)-(-)-1-Ethyl-2-pyrrolidinecarboxamide (R)-5-(Hydroxymethyl)-2-pyrrolidinone (S)-5-(Hydroxymethyl)-2-pyrrolidinone (R)-(+)-Lactamide Methyl L-Pyroglutamate D-Prolinamide L-Prolinamide (2R,3R)-Tartranilic Acid (3R)-(+)-3-(Trifluoroacetamido)pyrrolidine Hydrochloride (3S)-(-)-3-(Trifluoroacetamido)pyrrolidine Hydrochloride A1169 A1170 A1124 A2252 B3756 B3410 B1776 B4026 C2678 C2699 D1539 D3676 D4347 E0468 E0452 H1241 H0867 L0167 M2198 P2083 P1382 T1702 T1369 T1366 I0468 I0334 CH3 5g 5g 1g 5g 1g 1g 5g 1g 1g 1g 1g 5g 25g 1g 5g 1g 1g 1g I0335 CH3 O 5g 5g 25g 25g 5g 25g 1g 5g 1g 5g 25g 25g 5g 5g 5g 5g 5g 25g 100g 5g 25g 5g 25g 25g CH3 NCO NCO O O O CH3 NCO I0473 I0466 O tBuO 164 CH3 OCH3 NCO I0467 I0472 CH3 OCH3 NCO O O CH3 O CH3 O OCH3 NCO I0471 CH3 OCH3 OCH3 CH3 NCO NCO I0465 I0336 CH3 O CH3 I0398 NCO CH3 NCO OCH3 NCO Diethyl (S)-(-)-2-Isocyanatoglutarate (R)-(+)- -Methylbenzyl Isocyanate (S)-(-)- -Methylbenzyl Isocyanate Methyl (S)-(+)-2-Isocyanato-3-tert-butoxypropionate Methyl (S)-(-)-2-Isocyanato-3-methylbutyrate Methyl (2S,3S)-2-Isocyanato-3-methylvalerate Methyl (S)-(-)-2-Isocyanato-4-methylvalerate Methyl (S)-2-Isocyanato-3-phenylpropionate Methyl (S)-(-)-2-Isocyanatopropionate (R)-(-)-1-(1-Naphthyl)ethyl Isocyanate (S)-(+)-1-(1-Naphthyl)ethyl Isocyanate I0468 I0334 I0335 I0473 I0466 I0471 I0467 I0472 I0465 I0336 I0398 5g 25g 5g 1g 5g 5g 25g 5g 5g 5g 5g 1g 5g 1g 1g 1g A0972 A0973 CH3 1g 5g 1g 1g A2503 CH3 OH OH NH2 CH3 NH2 CH3 OH CH3 NH2 A1230 A1231 A2306 A1623 A1624 NH2 NH2 OH OH OH A2307 OH NH2 A2533 OH NH2 A2504 NH2 A1017 A2002 OH CH3 OH NH2 OH D2128 D2129 CH2OH CH3 Bu NHCH2 NH2 L0160 OH NH OH OH NH2 CH3 N Bu L0236 (CH3)3C CH3 CH3 Bu N Bu I0476 I0462 CH3 OH OH CH3 NH2 OH NH2 OH L0137 CH3 OH NH2 NH2 O2N NH2 B1119 CH3 OH OH CH3 CH3 NH2 A1085 CH3 CH3 M0929 CH3 OH CH3 NH2 CH3S OH NH2 CH3 165 N0608 N0631 P1289 CH3 HO P1028 P1201 CH3 NH2 HO NH2 OH OH OH NH2 NH2 NH2 P1294 P1274 P1087 T1755 T1537 CH2OH OH N H NH2 V0077 CH3 CH2OH OH NH NH2 N H CH3 OH NH2 166 N H V0058 CH3 A0972 A0973 A2503 A1230 A1231 A2306 A1623 A1624 A2307 A2533 A2504 A1017 A2002 A1085 B1119 D2128 D2129 I0462 I0476 L0160 L0236 L0137 M0929 N0608 N0631 P1289 P1028 P1201 P1294 P1274 P1087 T1755 T1537 V0077 V0058 CH2OH CH3 OH NH2 (R)-(-)-2-Amino-1-butanol (S)-(+)-2-Amino-1-butanol (S)-(-)-2-Amino-3,3-dimethyl-1,1-diphenyl-1-butanol (1R,2S)-(-)-2-Amino-1,2-diphenylethanol (1S,2R)-(+)-2-Amino-1,2-diphenylethanol (1R,2R)-(-)-1-Amino-2-indanol (1R,2S)-(+)-1-Amino-2-indanol (1S,2R)-(-)-1-Amino-2-indanol (1S,2S)-(+)-1-Amino-2-indanol (R)-(+)-2-Amino-3-methyl-1,1-diphenyl-1-butanol (S)-(-)-2-Amino-3-methyl-1,1-diphenyl-1-butanol D-(-)-threo-2-Amino-1-(4-nitrophenyl)-1,3-propanediol (R)-(-)-2-Amino-1-propanol (S)-(+)-2-Amino-1-propanol (+)-cis-2-Benzylaminocyclohexanemethanol (1R,2S)-2-(Dibutylamino)-1-phenyl-1-propanol (1S,2R)-2-(Dibutylamino)-1-phenyl-1-propanol L-Isoleucinol (R)-2-Isopropylamino-2-phenylethanol L-tert-Leucinol D-(-)-Leucinol L-(+)-Leucinol L-(-)-Methioninol (1R,2S)-(-)-Norephedrine (1S,2R)-(+)-Norephedrine D-Phenylalaninol L-Phenylalaninol (R)-(-)-2-Phenylglycinol (S)-(+)-2-Phenylglycinol D-Prolinol L-Prolinol (S)-1,2,3,4-Tetrahydroisoquinoline-3-methanol L-(-)-Tryptophanol D-Valinol L-Valinol 1mL 1g 1g 1g 1g 1g 1g 1g 1g 25g 5mL 1mL 5mL 1g 1g 1g 1g 5g 1g 1g 5mL 100mg 1g 5g 5g 5g 5g 5g 5g 1g 5g 5mL 5mL 5g 5g 5g 5g 5g 5g 5g 1g 5g 500g 25mL 25mL 5g 5g 5g 5g 25g 5g 5g 25mL 1g 25g 25g 25g 25g 25g 25g 25g 25g 1g 1g 5g 25g B1953 B2174 CH3 B2123 OH OH OC(CH3)3 HN N O B3662 B4283 HO N HN C OC(CH3)3 B3272 OH OC(CH3)3 HN O O O B3270 OH HN OC(CH3)3 C2629 C1609 CH3 OC(CH3)3 HN O O OC(CH3)3 HN O B3077 OH N OH OC(CH3)3 O B3076 OH OC(CH3)3 O B2604 OH CH2OH N O B1966 CH3S OH OC(CH3)3 OC(CH3)3 OH N O OH HN OC(CH3)3 OH HN O O O O C1610 OH HN O O N-(tert-Butoxycarbonyl)-L-alaninol (R)-1-(tert-Butoxycarbonyl)-2-azetidinemethanol (S)-1-(tert-Butoxycarbonyl)-2-azetidinemethanol (2S,4R)-1-(tert-Butoxycarbonyl)-4-hydroxy-2-(hydroxymethyl)pyrrolidine N-(tert-Butoxycarbonyl)-L-methioninol N-(tert-Butoxycarbonyl)-D-phenylalaninol N-(tert-Butoxycarbonyl)-L-phenylalaninol N-(tert-Butoxycarbonyl)-D-2-phenylglycinol N-(tert-Butoxycarbonyl)-L-2-phenylglycinol N-(tert-Butoxycarbonyl)-D-prolinol N-(tert-Butoxycarbonyl)-L-prolinol N-Carbobenzoxy-L-alaninol N-Carbobenzoxy-D-phenylalaninol N-Carbobenzoxy-L-phenylalaninol B1953 B2174 B2123 B3662 B4283 B1966 B2604 B3270 B3272 B3076 B3077 C2629 C1609 C1610 A2049 1g 100mg 100mg 1g 1g 1g 1g 1g 1g 5g 1g 1g 1g A1979 5g 1g 1g 5g 5g 5g 5g 5g 5g 5g 25g 5g 5g 5g A1980 OH H2N N OH H2N OH OH C CH3 OH O A0974 A0975 A1839 A2635 H1200 HO CH3 H2N OH CH3 H2N OH HO OH HO N relative O CH2OH OH O CH2OH CH2 167 B2899 B2900 O B2901 OH O OH OH B4117 B1532 OH B1533 B4131 OH OH B4119 CH3 OH CH3 CH3 N C O C CH3 C O C CH3 O CH3 B0925 CH3 CH3 CH3 CH3 OH B2909 B2910 C C2423 N C OCH2 C OCH2 O O D4010 OH O O CH3 Cl CH3 OH HS SH OH C1474 OH O N OH C1717 OH Cl CH3 S O OH C1733 Cl D1589 OH O O OH E0455 Cl D2240 O OH CN OH D2239 OH CH3 C2424 OH Cl N OH C OH OH OH M0967 HC CH3 CH3 C2763 OH HC OH OH C2453 OH OH OH (CH3)3CHN CH3 O O CH3 CH3 OH OH C2585 168 OH B1987 OH Cl CH3 OH B3055 HO HO OH OH B0926 OH B3054 N OH CF3 B1161 OH B2404 OH OH CF3 B1160 CH3 HO CH3 CH3 CH2 OH B3137 OH N CH2 OH OH B1343 N B1159 OH CH3 CH3 O OH B4118 OH OH OH OH O O O OH OH B2142 B2141 OH O OH B2902 O H1029 OH O CH3 NC O OH O CH3 CH3 O O CH3 H0975 H1032 OH H0950 O H0939 CH3 CH3 CH3 H0951 OH OH O CH3 H0969 OH OH O OH H1384 OH CH3 CH3 H0887 O O H1368 H1332 HO HO HO O OH HO O T1716 M1788 N H CH3 M1790 CH3O OH H0705 OCH3 H0704 H N S OH OH OH M1483 O M2157 CH3 OH O OH O O M2166 CH3O O OH O CH3 OH O M1937 Cl OCH3 N0784 OH O OCH3 CH3 N0785 M1938 OCH3 CH3 OH CH3 CH3 OH O O0293 OH N N CH3 CH3 O0145 O0144 OH OH CH3 CH3 CH3 CH3 OH O0235 P1411 CH3 C CH CH3 OH OH T1490 P1412 CH3 P0744 CH3 T1491 OH P1150 OH P0796 OH CH3 OH CH3 CH3 P0795 HO OH CH3 OH OH P1930 CH3 CH3 OH CH3 P1151 HO OH CH3 P0743 CH3 OH OH CH3 OH OH OH O OH P1931 OH CH3 P1417 P1780 OH OH OH CH3 CH3 CH3 169 P1152 P1129 CH3 OH P1608 OH OH OH OH S0038 P1140 OH CH3 OH P1667 N H T2359 T2360 HCl N H N H T1499 T1482 O C OH HO OH OH OH OH OH OH OH OH A2049 A1979 A1980 A0974 A0975 A1839 A2635 H1200 B2899 B2900 B2901 B2902 B2141 B2142 B4117 B1532 B1533 B4131 B4118 B4119 B1159 B1160 B1161 B1343 B3137 B2404 B0926 B0925 B3054 B3055 B1987 B2909 B2910 C2585 C2453 C2763 C2423 C2424 M0967 D2239 D2240 D4010 D1589 E0455 C1733 C1717 C1474 H1029 H0975 H1032 170 (R)-1-Acetyl-3-pyrrolidinol (R)-3-Amino-1,2-propanediol (S)-3-Amino-1,2-propanediol (R)-(-)-1-Amino-2-propanol (S)-(+)-1-Amino-2-propanol 1,4-Anhydroerythritol 1,4-Anhydro-D-xylitol (3R,4R)-1-Benzyl-4-hydroxy-3-pyrrolidinemethanol (R)-4-Benzyloxy-1,2-butanediol (S)-4-Benzyloxy-1,2-butanediol (R)-4-Benzyloxy-1,3-butanediol (S)-4-Benzyloxy-1,3-butanediol (R)-(+)-3-Benzyloxy-1,2-propanediol (S)-(-)-3-Benzyloxy-1,2-propanediol (S)-(+)-1-Benzyloxy-2-propanol (R)-1-Benzyl-3-pyrrolidinol (S)-1-Benzyl-3-pyrrolidinol (R)-1-[3,5-Bis(trifluoromethyl)phenyl]ethanol (R)-1,2-Butanediol (S)-1,2-Butanediol (R)-(-)-1,3-Butanediol (S)-(+)-1,3-Butanediol (R,R)-(-)-2,3-Butanediol (S,S)-(+)-2,3-Butanediol (R)-1,2,4-Butanetriol (S)-1,2,4-Butanetriol (R)-(-)-2-Butanol (S)-(+)-2-Butanol (R)-1-(tert-Butoxycarbonyl)-3-pyrrolidinol (S)-1-(tert-Butoxycarbonyl)-3-pyrrolidinol (S)-(-)-3-tert-Butylamino-1,2-propanediol (R)-(+)-3-Butyn-2-ol (S)-(-)-3-Butyn-2-ol (R)-1-Carbobenzoxy-3-pyrrolidinol (S)-1-Carbobenzoxy-3-pyrrolidinol (R)-(+)-4-Chloro-3-hydroxybutyronitrile (R)-(+)-3-Chloro-1-phenyl-1-propanol (S)-(-)-3-Chloro-1-phenyl-1-propanol (R)-(-)-3-Chloro-1,2-propanediol (+)-1,4-Di-O-benzyl-D-threitol (-)-1,4-Di-O-benzyl-L-threitol (S)-3-(Dimethylamino)-1-(2-thienyl)-1-propanol L-Dithiothreitol D-Erythronolactone Ethyl (R)-4-Chloro-3-hydroxybutyrate Ethyl (S)-4-Chloro-3-hydroxybutyrate Ethyl (R)-(-)-4-Cyano-3-hydroxybutyrate Ethyl (R)-(-)-3-Hydroxybutyrate Ethyl (S)-(+)-3-Hydroxybutyrate (2R,5R)-2,5-Hexanediol 1g 1g 1g 5g 1g 20mg 200mg 200mg 100mg 100mg 1g 1g 5g 5g 1g 1g 1g 1g 1g 100mg 1g 5g 1mL 1mL 1g 1g 1g 1g 1g 1g 10g 1g 1g 1g 1g 5g 5g 5g 5g 1g 5g 1g 5g 5g 25g 5g 5g 100mg 200mg 1g 1g 1g 1g 1g 1g 5g 5g 25g 25g 5g 5g 5g 5g 5g 1g 5g 25g 5mL 5mL 5g 5g 5g 5g 1g 5g 5g 5g 1g 1g 25g 1g 1g 5g 5g 25g 25g 25g 25g 5g 25g 1g (2S,5S)-2,5-Hexanediol (R)-(+)- -Hydroxy- -butyrolactone (S)-(-)- -Hydroxy- -butyrolactone (S)-3-Hydroxy- -butyrolactone 4-(cis-4-Hydroxycyclohexyl)phenol (S)-(+)-3-Hydroxy-2,2-dimethylcyclohexanone (S)-(-)-4-Hydroxy-2-pyrrolidone (R)-3-Hydroxytetrahydrofuran (S)-3-Hydroxytetrahydrofuran (R)-4-(4-Methoxybenzyloxy)-1,2-butanediol (S)-4-(4-Methoxybenzyloxy)-1,3-butanediol (R)-(-)-1-Methoxy-2-propanol (S)-3-(Methylamino)-1-(2-thienyl)-1-propanol Methyl (R)-4-Chloro-3-hydroxybutyrate Methyl (R)-(-)-3-Hydroxybutyrate Methyl (S)-(+)-3-Hydroxybutyrate (R)-1-Methyl-3-pyrrolidinol (S)-1-Methyl-3-pyrrolidinol (R)-(+)-1-(2-Naphthyl)ethanol (S)-(-)-1-(2-Naphthyl)ethanol (3R,6R)-3,6-Octanediol (R)-(-)-2-Octanol (S)-(+)-2-Octanol (S)-1-Octyn-3-ol (2R,4R)-(-)-2,4-Pentanediol (2S,4S)-(+)-2,4-Pentanediol (R)-(-)-2-Pentanol (S)-(+)-2-Pentanol (1R,2S)-(-)-trans-2-Phenyl-1-cyclohexanol (1S,2R)-(+)-trans-2-Phenyl-1-cyclohexanol (R)-(-)-1-Phenylethane-1,2-diol (S)-(+)-1-Phenylethane-1,2-diol (R)-(+)-1-Phenylethyl Alcohol (S)-(-)-1-Phenylethyl Alcohol (R)-(+)-1-Phenyl-1-propanol (S)-(-)-1-Phenyl-1-propanol (R)-1-Phenyl-2-propanol (S)-1-Phenyl-2-propanol (R)-(-)-1,2-Propanediol (S)-(+)-1,2-Propanediol (R)-3-Pyrrolidinol (S)-3-Pyrrolidinol (R)-(-)-3-Pyrrolidinol Hydrochloride Shikimic Acid (R)-(-)-1,2,3,4-Tetrahydro-1-naphthol (S)-(+)-1,2,3,4-Tetrahydro-1-naphthol (R)-(+)-1,1,2-Triphenyl-1,2-ethanediol (S)-(-)-1,1,2-Triphenyl-1,2-ethanediol H0969 H0950 H0951 H0939 H1384 H0887 H1368 H1332 T1716 M1788 M1790 M2166 M2157 M1483 H0705 H0704 M1937 M1938 N0784 N0785 O0293 O0145 O0144 O0235 P1411 P1412 P0744 P0743 T1490 T1491 P1150 P1151 P0795 P0796 P1930 P1931 P1417 P1780 P1152 P1129 P1608 P1667 P1140 S0038 T2359 T2360 T1499 T1482 1g 100mg 1g 1g 1g 5g 5g 10mL 5mL 1g 1g 5mL 5mL 1g 1mL 1mL 100mg 100mg 1g 5g 1g 1g 5g 1g 5g 5g 1g 5g 5g 100mg 1g 100mg 100mg 1g 1g A2335 A2512 5g 1g 100mg 5g 1g 100mg 1g 5g 5g 500mg 500mg 25g 25g 5g 25mL 25mL 5g 5g 1g 1g 500mg 25mL 25mL 5g 1g 1g 5mL 5mL 1g 1g 25g 5g 25g 25g 1g 1g 1mL 1mL 25g 5g 5g 25g 25g 5g 1g 1g 5g 1g A1445 NH2 NH2 N CH3 C O C CH3 O A2323 A2324 NH2 HCl N N C OCH2 C OCH2 O O HCl O O HCl O CH3 A2286 NH2 O NH2 HCl A2473 A2533 O C OH N NH2 O CH3 CH2NH2 C OC(CH3)3 OH CH3 NH2 171 A1342 A1301 A2206 A1167 A1168 NH2 N CH2NH2 N CH2CH3 CH2NH2 N H CH2CH3 A1053 A1054 A1174 2HCl N H B1580 B1581 NH C O C CH3 CH3 N N CH2 CH2 N CH2 B1583 NHCH2CH3 CH3 O NH2 B1582 NHCH2CH3 B1932 NH2 NH2 2HCl N H N H A1173 NH2 N H CH2NH2 NH2 B2775 NHCH3 CH3 NHCH3 NH2 CH3 N N N N CH2 CH2 CH2 CH2 CH3 NH2 xH3PO4 CH3 B2776 B3225 B2316 B2317 B3672 CH3 OCH3 NH2 CH3 NH2 CH3 NH2 CH3 NH2 CH3 CH3 CH3 NH2 CH3 CH3 CH3 NH2 xH3PO4 NH2 CH3O CH3 CH3 NH2 CH3 CH3 CH3 NH2 CH3 Br CH3 B3674 B3538 NH2 CH3 B3539 B3591 O O C OH C OH O A1171 A1172 O NH O NH N CH3 N H B3483 B1995 O CH3 NH C OC(CH3)3 O CH3 C1575 C1447 O O CH2O C HN O O CH3 B3478 NH2 N O NH2 CH3 B2918 CH3 O NH C OC(CH3)3 CH3 C O C CH3 CH3 C2699 CH3 NH2 O NH2 B2921 CH3 B2917 CH3 C O C HN CH3 CH3 N H C O C CH3 O O NH C O C CH3 N H NH2 CH3 CH3 N H 172 NH C OC(CH3)3 C O C CH3 CH3 CH3 B2920 CH3 C O C CH3 O NH C O C CH3 O NH C OC(CH3)3 Br B3660 H N CH3 NH2 O C1448 C1541 NH2 NH2 NH2 NH2 O O O C1531 CH3 NH2 CH3 NH2 C1189 D4035 D4036 H2N H 2N NH2 D2827 H2N NH2 O CH3 NH O D4258 N N CH2 CH2 D2149 CH3 CH3 D2176 CH3 CH3 N CH3 E0433 NH2 NH2 2HCl D2460 N H D2175 CH3 2HCl D2459 N CH3 N H CH3 NH2 NH2 D2193 OH N D2828 NHCH3 NHCH3 NHCH3 NHCH3 E0434 I0480 CH3 NH2 NHCH2CH3 NH2 NH2 M1512 CH3 N H NH2 M1511 NH2 M1108 M1746 NHCH3 CH3 CH2NH2 N H OCH3 M1747 N0482 CH3 CH3 CH3 NH2 N H OH HN NHCH3 OCH3 CH3 N H M1107 CH3 NHCH2CH3 N0481 CH3 CH2NH2 N0724 CH3 NH2 NH2 N0726 NH2 NH2 CH3 P0794 P0793 CH3 NH2 P1118 CH3 NH2 T2878 NH2 NH2 CH3 T1380 T2926 CH3 NH2 T1381 CH3 NH2 CH3 A2335 A2512 A1445 A2323 A2324 A2286 CH3 NH2 CH3 (S)-3-Amino-1-tert-butoxycarbonylpiperidine (R)-(+)- -Amino- -butyrolactone Hydrochloride (S)-(-)- -Amino- -butyrolactone Hydrochloride (R)-3-Amino-1-carbobenzoxypyrrolidine Hydrochloride (S)-3-Amino-1-carbobenzoxypyrrolidine Hydrochloride (1S,3R)-3-Aminocyclohexanecarboxylic Acid 1g 5g 1g 1g 5g 1g 5g 200mg 1g 173 A2473 A2533 A1342 A1301 A2206 A1167 A1168 A1053 A1054 A1173 A1174 B1932 B1580 B1581 B1582 B1583 B2775 B2776 B3225 B2316 B2317 B3672 B3674 B3538 B3539 B3591 B3660 A1171 A1172 B2920 B2921 B3478 B3483 B1995 B2917 B2918 C2699 C1575 C1447 C1448 C1541 C1531 C1189 D4035 D4036 D2827 D2828 D4258 D2149 D2193 D2459 D2460 D2176 D2175 E0433 E0434 I0480 M1511 M1512 M1107 M1108 M1746 M1747 N0482 N0481 N0724 N0726 P0794 174 (S)-2-(Aminomethyl)-1-(tert-butoxycarbonyl)pyrrolidine (R)-(+)-2-Amino-3-methyl-1,1-diphenyl-1-butanol (R)-(+)-2-Aminomethyl-1-ethylpyrrolidine (S)-(-)-2-Aminomethyl-1-ethylpyrrolidine (S)-2-(Aminomethyl)pyrrolidine (3R)-(+)-3-Aminopyrrolidine (3S)-(-)-3-Aminopyrrolidine (3R)-(-)-3-Aminopyrrolidine Dihydrochloride (3S)-(+)-3-Aminopyrrolidine Dihydrochloride (3R)-(-)-1-Benzyl-3-aminopyrrolidine (3S)-(+)-1-Benzyl-3-aminopyrrolidine (3R)-(+)-1-Benzyl-3-(tert-butoxycarbonylamino)pyrrolidine (3R)-(-)-1-Benzyl-3-(ethylamino)pyrrolidine (3S)-(+)-1-Benzyl-3-(ethylamino)pyrrolidine (3R)-(-)-1-Benzyl-3-(methylamino)pyrrolidine (3S)-(+)-1-Benzyl-3-(methylamino)pyrrolidine (1R,2R)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate (1S,2S)-1,2-Bis(3,5-dimethylphenyl)-1,2-ethylenediamine Phosphate (1R,2R)-1,2-Bis(4-methoxyphenyl)ethylenediamine (1R,2R)-1,2-Bis(2,4,6-trimethylphenyl)ethylenediamine (1S,2S)-1,2-Bis(2,4,6-trimethylphenyl)ethylenediamine (R)-(+)-1-(4-Bromophenyl)ethylamine (S)-(-)-1-(4-Bromophenyl)ethylamine (1R,3S)-3-(tert-Butoxycarbonylamino)cyclohexanecarboxylic Acid (1S,3R)-3-(tert-Butoxycarbonylamino)cyclohexanecarboxylic Acid (R)-3-(tert-Butoxycarbonylamino)piperidine (S)-3-(tert-Butoxycarbonylamino)piperidine (3R)-(+)-3-(tert-Butoxycarbonylamino)pyrrolidine (3S)-(-)-3-(tert-Butoxycarbonylamino)pyrrolidine (3R)-(+)-1-(tert-Butoxycarbonyl)-3-aminopyrrolidine (3S)-(-)-1-(tert-Butoxycarbonyl)-3-aminopyrrolidine (1R,2S)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine (1S,2R)-N1-(tert-Butoxycarbonyl)-1,2-cyclohexanediamine N-(tert-Butoxycarbonyl)-L-serine -Lactone (R)-(-)-sec-Butylamine (S)-(+)-sec-Butylamine N-Carbobenzoxy-L-homoserine Lactone N-Carbobenzoxy-L-serine -Lactone (1R,2R)-(-)-1,2-Cyclohexanediamine (1S,2S)-(+)-1,2-Cyclohexanediamine (R)-(-)-1-Cyclohexylethylamine (S)-(+)-1-Cyclohexylethylamine D-(+)-Cycloserine (3R,4R)-(-)-3,4-Diamino-1-benzylpyrrolidine (3S,4S)-(+)-3,4-Diamino-1-benzylpyrrolidine (R)-1,2-Diaminopropane Dihydrochloride (S)-1,2-Diaminopropane Dihydrochloride (S)-3-[1-(Dimethylamino)ethyl]phenol (3R)-(+)-3-(Dimethylamino)pyrrolidine (3S)-(-)-3-(Dimethylamino)pyrrolidine (1R,2R)-(-)-N,N -Dimethylcyclohexane-1,2-diamine (1S,2S)-(+)-N,N -Dimethylcyclohexane-1,2-diamine (1R,2R)-(+)-1,2-Diphenylethylenediamine (1S,2S)-(-)-1,2-Diphenylethylenediamine (3R)-(+)-3-(Ethylamino)pyrrolidine (3S)-(-)-3-(Ethylamino)pyrrolidine (S)-2-Isopropylamino-3-methyl-1-butanol (R)-(+)-1-(4-Methoxyphenyl)ethylamine (S)-(-)-1-(4-Methoxyphenyl)ethylamine (3R)-(+)-3-(Methylamino)pyrrolidine (3S)-(-)-3-(Methylamino)pyrrolidine (R)-(+)- -Methylphenethylamine (S)-(-)- -Methylphenethylamine (R)-(+)-1-(1-Naphthyl)ethylamine (S)-(-)-1-(1-Naphthyl)ethylamine (R)-1-(2-Naphthyl)ethylamine (S)-1-(2-Naphthyl)ethylamine (R)-(+)-1-Phenylethylamine 1g 1g 1g 1g 5g 200mg 1g 5g 25g 5g 25g 5g 25g 5g 25g 10g 25g 10g 25g 5g 5g 5g 5g 25g 5g 25g 100mg 100mg Price on request 100mg 500mg 100mg 500mg 1g 5g 5g 25g 1g 1g 1g 5g 1g 5g 5g 25g 5g 25g 1g 5g 1g 5g 1g 5g 1g 5g 1g 5g 100mg 1g 1g 1g 5g 1g 5g 25g 5g 25g 5g 25g 5g 25g 1g 5g 50mg 50mg 1g 1g 1g 5g 1g 5g 1g 5g 100mg 1g 100mg 1g 5g 1g 5g 1g 5g 1g 1g 5g 5g 25g 5g 25g 1g 5g 1g 5g 5g 25g 5g 25g 1g 5g 1g 5g 1g 5g 1g 5g 25mL 100mL 500mL (S)-(-)-1-Phenylethylamine (S)-1-Phenyl-2-(p-tolyl)ethylamine (R)-(-)-1,2,3,4-Tetrahydro-1-naphthylamine (S)-(+)-1,2,3,4-Tetrahydro-1-naphthylamine (R)-(+)-1-(p-Tolyl)ethylamine (S)-(-)-1-(p-Tolyl)ethylamine P0793 P1118 T2926 T2878 T1380 T1381 25mL 100mL 500mL 5g 25g 5g 25g 5g 25g 1mL 1mL 5mL D2265 D3758 O CH3 CH3 O O O HO D2191 CH3 O CH3 O O O CH3 CH3 I0507 CH3 COOH O CH3 HO CH3 CH3 O CH3 O HO OH I0376 CH2OH O O CH3 CH3 D2265 D3758 D2555 D1949 D2191 D2024 D2447 D2616 I0507 I0454 I0400 I0688 I0489 I0376 I0375 I0721 T2755 O CH3 O O O O H3C CH3 CH3 CH3 O O O O CH3 O O O CH3 O O OH I0688 CH3 CH3 HO OH O CH3 CH3 OH HO O O O O CH3 HO CH2OH O O CH3 OH HOH2C O O CH2OH HOCH2 I0489 O I0721 O O CH3 H3C CH3 OH O O CH3 D2616 HO I0375 HOCH2 CH3 CH3 I0400 O O O CH3 O OH O OH O I0454 O O OH O CH3 O O CH3 CH3 D2447 CH3 CH3 O O O CH3 CH3 D2024 OH O O CH3 O O O D1949 D2555 CH3 CH3 O CH3 CH3 CH3 T2755 CH3 OH O O O O O O CH3 CH3 O CH3 CH3 1,2:5,6-Di-O-isopropylidene- -D-allofuranose 2,3:4,5-Di-O-isopropylidene- -D-fructopyranose 1,2:3,4-Di-O-isopropylidene- -D-galactopyranose 1,2:5,6-Di-O-isopropylidene- -D-glucofuranose (-)-2,3:4,6-Di-O-isopropylidene-2-keto-L-gulonic Acid Monohydrate 1,2:5,6-Di-O-isopropylidene-D-mannitol 2,3:5,6-Di-O-isopropylidene-D-mannofuranose 1,2:3,5-Di-O-isopropylidene- -D-xylofuranose (+)-5,6-O-Isopropylidene-L-ascorbic Acid 2,3-O-Isopropylidene-D-erythronolactone 1,2-O-Isopropylidene- -D-glucofuranose 1,2-O-Isopropylidene- -D-glucurono-6,3-lactone 3,4-O-Isopropylidene-D-mannitol (+)-2,3-O-Isopropylidene-L-threitol (-)-2,3-O-Isopropylidene-D-threitol 1,2-O-Isopropylidene- -D-xylofuranose Topiramate CH3 O OSO2NH2 1g 5g 5g 10g 5g 5g 1g 1g 1g 5g 1g 5g 25g 25g 25g 5g 25g 5g 5g 25g 1g 25g 1g 5g 5g 5g 25g 5g 175 B2136 B2137 CH2OCH2 O O B3642 B3690 B3702 CH3 CH3 CH2OCH2 O CH3 CH3 B4214 O O CH3 CH3 C2265 O O H2N OC(CH3)3 C1796 O O CH3 CH2 C O C CH3 CH3 O NCCH2 N H CH3 CH3 O CH3 CH3 N O CH3 F O CH3 O (CH3)3CO D1705 O O HO CH3 CH3 D2549 O CH3 CH3 O O O CH2O O CH3 CH3 O CH3 S HOCH2CH2 O O O CH3 CH(CH3)2 CH(CH3)2 O M1456 CH3OCH2 CH3OCH2 O CH3 CH3 HOCH2CH2 O M1451 CH3 CH3 O D4076 O CH3 S H1189 HOCH2CH2 O O O O O O P1486 CH3 CH3 O O 176 CH3 CH(CH3)2 P1485 B4214 C2265 C1796 D1705 D1691 D2549 D2550 D4076 D4077 H1188 H1189 M1451 M1456 P1485 P1486 O CH(CH3)2 O B2136 B2137 B3702 B3642 B3690 O H1188 HOCH2CH2 O CH3 D2550 O CH3 CH3 D4077 ClCH2 CH3 CH3 CH2OH O O OC(CH3)3 CH2O O O CH3 D1691 CH2OH O ClCH2 O O O O O (R)-4-Benzyloxymethyl-2,2-dimethyl-1,3-dioxolane (S)-4-Benzyloxymethyl-2,2-dimethyl-1,3-dioxolane tert-Butyl 2-[(4R,6R)-6-(2-Aminoethyl)-2,2-dimethyl-1,3-dioxan-4-yl]acetate tert-Butyl (4R,6R)-6-Cyanomethyl-2,2-dimethyl-1,3-dioxane-4-acetate tert-Butyl (4R,6R)-2-[6-[2-[2-(4-Fluorophenyl)-5-isopropyl-3-phenyl-4-(phenylcarbamoyl)pyrrol1-yl]ethyl]-2,2-dimethyl-1,3-dioxan-4-yl]acetate tert-Butyl (4R,6S)-6-(Hydroxymethyl)-2,2-dimethyl-1,3-dioxane-4-acetate (R)-4-Chloromethyl-2,2-dimethyl-1,3-dioxolane (S)-4-Chloromethyl-2,2-dimethyl-1,3-dioxolane (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol 1g (S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol 1g (R)-(-)-2,2-Dimethyl-1,3-dioxolan-4-ylmethyl p-Toluenesulfonate (S)-(+)-2,2-Dimethyl-1,3-dioxolan-4-ylmethyl p-Toluenesulfonate (R)-4-(2-Hydroxyethyl)-2,2-diisopropyl-1,3-dioxolane (S)-4-(2-Hydroxyethyl)-2,2-diisopropyl-1,3-dioxolane (R)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane (S)-4-(2-Hydroxyethyl)-2,2-dimethyl-1,3-dioxolane (R)-(+)-4-(Methoxymethyl)-1,3-dioxolan-2-one (S)-(-)-4-(Methoxymethyl)-1,3-dioxolan-2-one (R)-Propylene Carbonate (S)-Propylene Carbonate 1g 1g 5g 5g 1g 5g 5g 1g 5g 5g 5g 5g 1g 1g 5g 5g 5g 25g 25g 5g 25g 25g 1g 5g 1g 1g 1g 1g 25g 25g 25g 25g B2238 B2239 E0893 H CH2OCH2 B4111 B3832 CH2OCH2 O O B3833 E0581 O E0533 CH3 CH3 CH2O Si CH3 C CH3 CH3 CH3 O G0363 O G0364 O O NO2 CH2O O O T1611 T1612 O N CH2 O N CH2 O O O O O CH3 CH2O S O O G0284 CH2O NO2 O O G0328 O G0409 CH2O S O O G0327 O G0411 CH2O S O O CH2OCH3 (CH2)2CH3 O NO2 CH2O S G0410 O G0287 CH2OCH3 G0280 CH2O C (CH2)2CH3 O G0286 O G0283 CH2O C O G0281 O O CH2OH CH2Cl O G0282 CH2OH O CH2Cl CH3 O O OC(CH3)3 HN CH3 CH2O S O O O G0285 P1396 P0951 I0580 O CH3 CH2O CH2O C O O CH3 O O N O C O N O O N O I0581 O N O O N O O N O B2238 B2239 E0893 B4111 B3832 B3833 Benzyl (R)-(-)-Glycidyl Ether Benzyl (S)-(+)-Glycidyl Ether (2S,3S)-3-(tert-Butoxycarbonylamino)-1,2-epoxy-4-phenylbutane tert-Butyldimethylsilyl (S)-Glycidyl Ether (R)-(+)-Butylene Oxide (S)-(-)-Butylene Oxide 1g 1g 5g 5g 5g 5mL 5mL 25g 25g 25g 5mL 25mL 25mL 177 (R)-Epichlorohydrin (S)-Epichlorohydrin (R)-(+)-Glycidol (S)-(-)-Glycidol (R)-Glycidyl Butyrate (S)-Glycidyl Butyrate (R)-Glycidyl Methyl Ether (S)-Glycidyl Methyl Ether (R)-Glycidyl 3-Nitrobenzenesulfonate (S)-Glycidyl 3-Nitrobenzenesulfonate (S)-Glycidyl 4-Nitrobenzenesulfonate (R)-Glycidyl Phenyl Ether (S)-Glycidyl Phenyl Ether (R)-N-Glycidylphthalimide (S)-N-Glycidylphthalimide (2R)-(-)-Glycidyl p-Toluenesulfonate (2S)-(+)-Glycidyl p-Toluenesulfonate (R)-Glycidyl Trityl Ether (S)-Glycidyl Trityl Ether (R)-(+)-Propylene Oxide (S)-(-)-Propylene Oxide (R,R,R)-Triglycidyl Isocyanurate (S,S,S)-Triglycidyl Isocyanurate E0581 E0533 G0363 G0364 G0282 G0283 G0280 G0281 G0286 G0287 G0411 G0409 G0410 G0327 G0328 T1611 T1612 G0284 G0285 P1396 P0951 I0580 I0581 5g 5g 5g 5g 5g 5g 5g 5g 5g 5g 1mL A1576 B2420 B3694 CN OH O N CH3 B3693 B3299 H O H2N N C H B3695 1g 5g 5g 5g 5g 5g 5g 5mL 5mL 25g 25g 25g 25g 25g 25g 25g 25g 25g 25g 5g 1g 5g 25g 25g 25g 25g 25g 25g 25mL 25mL 1g 1g CH2 B3696 B2779 CH3 N3CH2 O OCH3 CH3 N3CH2 O OCH3 CH3 HOCH2 O OCH3 CH3 HOCH2 O OCH3 CH3 N3CH2 O CH3 OCH3 N3CH2 O CH3 OCH3 HOCH2 O CH3 OCH3 HOCH2 O CH3 OCH3 O Si C(CH3)3 CH3 CH3 BrHC O Si C(CH3)3 CH3 B1759 C1188 O O H C N O CH3 C O C CH3 CH3 CH3 Cl CH3 O OSO2CF3 M1234 OH OH O CH CH3 CH3 C NH CH3 CH Ph O M0966 CH3 OH CH3 C OH M0964 CH3 CH3 N O OH H N CH3 M0965 CH3 OCH3 M0824 N OCH3 CH3 N O O CH3OCH2 M0170 O M1622 O H H CH3O CH3 M0803 CH3O H H O O CH3 CH3 O O D3257 N N CH3 I0390 HO D3259 CN CH3 CH3 E0879 178 C1363 OH CH3 CH3 OH CH3 M0963 M2091 M1424 H N CH3 CH3 P1499 OH P1504 N H P1509 H N CH3 N H P1500 O O CH3 T2551 T2552 T2636 H3C O O CH2NH2 O O CH2NH2 O O V0117 CH2 CH3 CH3 A1576 B2420 B3299 B3693 B3694 B3695 B3696 B2779 B1759 C1188 C1363 D3259 D3257 E0879 I0390 M0803 M1622 M0824 M1234 M0170 M0965 M0964 M0966 M0963 M2091 M1424 P1499 P1500 P1504 P1509 T2551 T2552 T2636 V0117 CH3 (R)-4-Amino-2-methyl-1-butanol (4aS,8aR)-2-Benzoyloctahydro-6(2H)-isoquinolinone (R)-1-Benzyl-3-pyrrolidinecarbonitrile (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane (2S,3S,5R,6R)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane (2R,3R,5S,6S)-5,6-Bis(hydroxymethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane (2S,3S,5R,6R)-5,6-Bis(hydroxymethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane (1R,3R)-5-(Bromomethylene)-1,3-bis(tert-butyldimethylsilyloxy)cyclohexane (S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine (S)-(+)-1-Chloro-2-methylbutane (-)-2-Cyano-6-phenyloxazolopiperidine (5S)-5,6-Dihydro-6,6-dimethyl-5-phenyl-2H-1,4-oxazin-2-one (2S)-2,5-Dihydro-2-isopropyl-3,6-dimethoxypyrazine Ethyl (R)-4-Phenyl-2-(trifluoromethanesulfonyloxy)butyrate Isosorbide Dimethyl Ether (4S,5S)-(-)-4-Methoxymethyl-2-methyl-5-phenyl-2-oxazoline (R)-(+)-N-( -Methylbenzyl)phthalamic Acid (S)-(-)-N-( -Methylbenzyl)phthalamic Acid (S)-(-)-2-Methyl-1,4-butanediol (S)-(-)-2-Methyl-1-butanol (S)-(+)-5-Methyl-1-heptanol (S)-(+)-4-Methyl-1-hexanol (S)-(+)-6-Methyl-1-octanol (S)-(+)-3-Methyl-1-pentanol (R)-(-)-2-Methylpiperazine (S)-(+)-2-Methylpiperazine (R)-3-Phenylcyclohexanone (S)-3-Phenylcyclohexanone (R)-3-Phenylcyclopentanone (S)-3-Phenylcyclopentanone (R)-(-)-Tetrahydrofurfurylamine (S)-(+)-Tetrahydrofurfurylamine (R)-(-)-2,3,7,7a-Tetrahydro-7a-methyl-1H-indene-1,5(6H)-dione Valencene 1g 1g 1g 10mL 1g 1mL 1mL 1mL 5g 1g 100mg 100mg 100mg 100mg 200mg 1g 200mg 5g 50mg 5g 100mg 100mg 200mg 200mg 100mg 5g 25mL 1g 1g 1g 1g 25g 1g 5g 1g 5g 25mL 1mL 5mL 5mL 5mL 25g 5g 1g 1g 1g 1g 5g 1g 1g 5g 179 B3242 C1195 HC C CH2CH2Br C1522 C1984 D1724 HC C CH2CH2CH2Cl CH3(CH2)3 C1493 Cl CH3 CH C CH D1326 C C CH2CH2 C CH HC C (CH2)4Cl D0037 HC C (CH2)6 C CH CH3(CH2)7 C CH C CH B1114 D0997 H0440 H0483 H0048 CH3 CH3 C C CH CH3(CH2)9 C CH CH3(CH2)14 C CH HC C (CH2)3 C CH CH3(CH2)4 C CH CH3 H0433 CH3(CH2)13 H0140 C CH N0301 CH3(CH2)6 C CH CH3(CH2)15 U0033 C CH M0269 C CH CH CH2CH2 C CH HC C CH2Br HC C N0406 CH3 CH3 CH3 O0147 P1272 P0484 CH3CH2CH2 C CH 180 C CH O0128 P0068 CH3(CH2)8 CH3(CH2)3 M0271 CH3 CH CH2 C CH O0050 (CH2)4 C CH P1273 P0810 HC C CH2Cl HC C (CH2)5 C CH P0356 CH3(CH2)5 C CH P1881 CH3(CH2)12 C CH T0761 CH3 C CH CH3(CH2)11 C CH B3242 C1195 C1493 C1522 C1984 D1724 D1326 D0037 B1114 D0997 H0440 H0483 H0048 H0433 H0140 M0271 M0269 N0406 N0301 O0128 O0147 O0050 P0356 P0068 P1272 P0484 P1273 P0810 P1881 T0761 U0033 4-Bromo-1-butyne 3-Chloro-1-butyne 6-Chloro-1-hexyne 5-Chloro-1-pentyne Cyclopropylacetylene 1,5-Decadiyne 1,9-Decadiyne 1-Decyne 3,3-Dimethyl-1-butyne 1-Dodecyne 1-Heptadecyne 1,6-Heptadiyne 1-Heptyne 1-Hexadecyne 1-Hexyne 5-Methyl-1-hexyne 4-Methyl-1-pentyne 1,8-Nonadiyne 1-Nonyne 1-Octadecyne 1,7-Octadiyne 1-Octyne 1-Pentadecyne 1-Pentyne Propargyl Bromide (80% in Toluene, ca 9.2mol/L) (stabilized with MgO) Propargyl Bromide (stabilized with MgO) Propargyl Chloride (70% in Toluene, ca 9.2mol/L) Propargyl Chloride Propyne (ca 3-4% in Heptane) 1-Tetradecyne 1-Undecyne B4521 OCH2 C CH A2607 D2496 Cl H N O H N O O O 25g 25g 100g 100g 25g 5mL B2301 Br (CH2)3CH3 C CH C CH D4233 C CH C CH HC C NH2 C CH E0603 CH2CH3 5mL 25mL 5g 5g 25mL 25mL 25g 5mL 5mL 25mL 100mL 25mL 1g 5mL 25mL 5mL 250mL 5mL 5mL 5mL 5mL 5mL 25mL 250mL 5mL 25mL 500g 500g 250g 25mL 200g 25mL 5mL O C CH E0749 25mL D2151 C CH N 5mL 10mL 5mL B3701 OCH2 C CH C2670 1g 5mL 5mL 5g 1mL E0196 OCH3 C CH E0654 C CH F0470 C CH C CH F C CH E0564 C CH E0933 F E0563 C CH E0967 E0750 C CH C CH C CH C C (CH2)5CH3 (CH2)4CH3 C CH CH2CH2CH3 181 E0939 E0665 C CH E0655 E0626 CH3 C CH P1956 P2226 C CH C CH CF3 P2227 P2190 CH2CH2 C CH T3151 C CH CH2OCH2 C CH CH2 C CH P0358 CH3 OCH2 C CH OCH2 C CH HC C C C CH C CH T2760 T3135 C CH HC C B4521 B3701 B2301 C2670 A2607 D2496 D2151 D4233 E0749 E0603 E0196 E0654 F0470 E0564 E0933 E0563 E0967 E0750 E0939 E0665 E0655 E0626 P0358 P1956 P2226 P2227 P2190 T3151 T2760 T3135 OCH2 C CH C CH HC C CH2O OCH2 C CH 1,3-Bis(2-propynyloxy)benzene 1-Bromo-4-ethynylbenzene 1-Butyl-4-ethynylbenzene 1-Chloro-4-ethynylbenzene 9,15-Diaza-18-DBCO-3,6-dioxa-10,14,18-trioxooctadecylamine 1,3-Diethynylbenzene 1,4-Diethynylbenzene 4,4 -Diethynylbiphenyl 1-Ethyl-4-ethynylbenzene 4-Ethynylanisole Ethynylbenzene 1-Ethynyl-2-fluorobenzene 1-Ethynyl-4-fluorobenzene 1-Ethynyl-4-hexylbenzene 2-Ethynylnaphthalene 1-Ethynyl-4-pentylbenzene 1-Ethynyl-4-(phenylethynyl)benzene 1-Ethynyl-4-propylbenzene 1-Ethynylpyrene 3-Ethynyltoluene 4-Ethynyltoluene 1-Ethynyl-4-(trifluoromethyl)benzene 4-Phenyl-1-butyne 3-Phenyl-1-propyne (stabilized with BHT) 1-[(2-Propynyloxy)methyl]pyrene 1-(2-Propynyloxy)naphthalene 2-(2-Propynyloxy)naphthalene Tetrakis(4-ethynylphenyl)methane 1,3,5-Triethynylbenzene 1,3,5-Tris(2-propynyloxy)benzene B4007 182 C 1g 5g 5g 200mg 5g 200mg 1g 5g 5g 1g 1g 200mg 1g 200mg 100mg 1g 200mg HN D4616 O OH Boc 1g 5g 25g 5g 25mg 5g 5g 1g 25g 5g 500mL 5g 5g 25g 100mg 25g 1g 25g 1g 25g 25g 5g 5mL 5g 1g 5g 1g 1g 5g 1g 1g 1g 200mg 5g 1g 25mL 100mL P1038 O HC 200mg 1g 5g 1g O CH3 HC C C O C CH3 CH3 HC C CH2CH C OCH2CH3 C OCH2CH3 O H0823 P0529 H0964 H0882 H0905 O O HC C CH C OCH2CH3 OH P0528 O HC C C OCH2CH3 P0497 O CH3 OH C O HC C CH C OH OH CH U0054 O O HC C C OCH3 O HC C CH2CH2CH2 C OH HC C C OH HC C (CH2)8 C OH N-(tert-Butoxycarbonyl)-L-propargylglycine tert-Butyl Propiolate Diethyl 2-Propynylmalonate Ethyl 2-Hydroxy-3-butynoate Ethyl Propiolate 2-Hexyl-4-pentynoic Acid 5-Hexynoic Acid 2-Hydroxy-3-butynoic Acid Methyl Propiolate Propiolic Acid 10-Undecynoic Acid B4007 P1038 D4616 H0823 P0529 H0964 H0882 H0905 P0528 P0497 U0054 5mL 5g 5g 100mg 5mL 5g 1g B0799 B2909 B2910 HC HC C CH2CH2OH C CH3 HC C D3710 HC C CH3 HC C D1266 (CH2)8OH OH D2495 E0272 CH3 CH3 D0737 CH3 CHCH2CH2 C C CH H0823 CH3(CH2)3 C C CH E0297 E0548 HO CH3 CH C C CH OH OH E0270 O E0273 CH2CH3 CH2CH3 HC C CH C OCH2CH3 CH3(CH2)3 CH CH C CH CH3CH2 OH OH OH CH3 CH3 CH3 CHCH2 C C CH OH CH2CH3 HC C C OH D1276 CH3 CH3 H0455 CH3 OH OH B0750 B1001 1g 25g 5g 1g 25mL 25g 25g 1g 25mL 25g 5g 5g 1g H0141 C C CH OH H0687 C CH CH3(CH2)3 CH OH HC C C CH CH3CH2CH2 CH C CH OH HC C (CH2)4OH OH 183 H0462 H0905 HC C CH2 CH CH2CH3 OH M0180 O M0860 C C CH CH3 C CH CH3 P0818 HC C CH2CH2CH2OH P0220 HC C CH2OH HC C CH C CH3 OH P0536 HC C CH2 CH CH3 OH P0069 C OH P0817 HC C C CH CH2 OH O0196 CH3 OH CH3 CH CH2 CH C CH OH O0235 CH3OCH2 C CH M1312 CH3 HC C C CH3 OH CH3 CH3CH2 CH3 HC C CH C OH OH M0396 M0961 CH OH U0055 HC C (CH2)9OH OH B0799 B2909 B2910 B0750 B1001 D3710 D1266 D0737 D1276 D2495 E0272 H0823 E0270 E0273 E0297 E0548 H0455 H0141 H0687 H0462 H0905 M0180 M0961 M1312 M0396 M0860 O0235 O0196 P0069 P0817 P0818 P0220 P0536 U0055 184 3-Butyn-1-ol (R)-(+)-3-Butyn-2-ol (S)-(-)-3-Butyn-2-ol 3-Butyn-2-ol (55% in Water, ca 7.5mol/L) 3-Butyn-2-ol 9-Decyn-1-ol 3,6-Dimethyl-1-heptyn-3-ol 3,5-Dimethyl-1-hexyn-3-ol 3,4-Dimethyl-1-pentyn-3-ol 1,1-Diphenyl-2-propyn-1-ol 3-Ethyl-1-heptyn-3-ol Ethyl 2-Hydroxy-3-butynoate 4-Ethyl-1-octyn-3-ol 3-Ethyl-1-pentyn-3-ol 1-Ethynyl-1-cyclohexanol 9-Ethynyl-9-fluorenol 1-Heptyn-3-ol 1-Hexyn-3-ol 5-Hexyn-1-ol 5-Hexyn-3-ol 2-Hydroxy-3-butynoic Acid 2-Methyl-3-butyn-2-ol 5-Methyl-1-hexyn-3-ol 3-Methyl-1-penten-4-yn-3-ol 3-Methyl-1-pentyn-3-ol Methyl Propargyl Ether (S)-1-Octyn-3-ol 1-Octyn-3-ol 1-Pentyn-3-ol 4-Pentyn-1-ol 4-Pentyn-2-ol 1-Phenyl-2-propyn-1-ol 2-Propyn-1-ol 10-Undecyn-1-ol 5mL 1g 25mL 5mL 25mL 5g 25mL 5mL 25g 1mL 5mL 5mL 100mg 25mL 5mL 5mL 1g 25mL 5mL 5g 25mL 100mL 25mL 5g 1g 500mL 25mL 5g 5mL 500mL 10mL 25g 5mL 1g 500mL 25mL 500g 5g 5mL 25mL 25mL 5mL 1g 500mL 5mL 25mL 25mL 25mL 5g 250mL 10g 25mL 5mL 25g 500mL 5g B4472 B2393 O CH3 HC C C CH3 CH3 D4275 E1130 E1093 CH3 CH3 HC C HO O G0445 P1173 O S C CH CH3 O P2171 O O N H (CH2)3CH3 C NH2 P1438 C CH (CH2)3CH3 CH3 P2258 OCH2CH3 O S OCH2 C CH CH2CH3 C CH CH2CH3 OCH2CH3 O T1683 CH3CH2 Si OCH2CH3 HC C CH2O C NH(CH2)3 Si OCH2CH3 T1239 CH(CH3)2 (CH3)2CH Si C CH CH(CH3)2 CH3 CH3 Si C CH CH3 T2992 P CH2 C CH Br B4472 B2393 T2046 T1224 D4275 E1130 E1093 E1074 E0466 G0445 P1173 T1455 P2258 P2171 T1750 T2387 T1683 T1239 P1438 T2992 CH3(CH2)3 Sn O O CH3 T2387 CH3 B C CH T1455 HC C O OH OCH2CH3 CH T1750 O HC C CH3 N O C CH E0466 O CH3 C CH N N H S OCH2CH2 C CH O E1074 C CH S O CH C CH CH3 NH2 SO2NH2 O O O HC C CH2NH C O C CH3 T1224 T2046 HC C N C C CH CH N-(tert-Butoxycarbonyl)propargylamine 3-Butyn-2-one 3-Butynyl p-Toluenesulfonate 1-Butyn-3-yl p-Toluenesulfonate 3,6-Diethynylcarbazole 4-Ethynylbenzenesulfonamide 5-Ethynyl-2 -deoxycytidine 2-Ethynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Ethynyl p-Tolyl Sulfone Glycidyl Propargyl Ether Propargylaldehyde Diethyl Acetal Propargyl p-Toluenesulfonate 2-Propynyl [3-(Triethoxysilyl)propyl]carbamate 2-Propynylurea Tributylethynyltin Triethylsilylacetylene Triisopropylsilylacetylene Trimethylsilylacetylene Triphenylpropargylphosphonium Bromide Tripropargylamine 1g 200mg 200mg 50mg 200mg 1g 1g 5mL 1g 200mg 1g 1g 5mL 5mL 25mL 5g 1g 5g 5g 5g 5g 1g 1g 200mg 1g 5g 5g 25mL 5g 5g 1g 5g 5g 25mL 250mL 25g 5g 185 A1786 A0930 A2474 O SO2N3 C OH N3 O NH C CH3 A2758 O O CH3 CH3 O O A0971 O A2052 O CH3 CH3 N3 A1341 A2738 O N3 O N3 CH3 HN HO CH CH C H O O S CH2N3 N3 N NH2 O O N3 A2524 A2290 A2674 A2729 O HN F OH H S C OH C OH NH H N H N3 N3 F B1111 B3693 O HC CH N3CH2 CH3 S0860 O F O OCH3 CH3 NO2 A1786 A0930 A2474 A0971 A2758 A2052 A1341 A2738 A2524 A2290 A2674 A2729 B1110 B1111 O N3 O CH3 OCH3 N3CH2 O OCH3 CH3 O CH3 OCH3 N3 D1606 H N OH O O S S N H OH N3 N3 N3 CH CH SO3Na NaO3S 4H2O T1184 F N3 O C O N F CH OH B3790 N3CH2 CH3 O C O N 186 O S0952 N3 HC F B3694 N3CH2 N3 O N3 N3 N3 N3 O F O (CH2)4 B1110 O O F O CH3 Si CH2N3 CH3 4-Acetamidobenzenesulfonyl Azide 5g 25g 4-Azidobenzoic Acid 5g 25g 2-Azido-1,3-bis[(2,2-dimethyl-1,3-dioxan-5-yl)oxy]propane 100mg 4-Azidocinnamaldehyde 5g 4-Azidocoumarin 200mg -Azido-3 -deoxythymidine 1g 5g Azidomethyl Phenyl Sulfide 5g 3-Azidopropylamine 100mg N-(3-Azidopropyl)biotinamide 100mg 4-Azidosalicylic Acid 100mg 1g 4-Azido-2,3,5,6-tetrafluorobenzoic Acid 1g 5-Azidovaleric Acid 200mg 2,6-Bis(4-azidobenzylidene)cyclohexanone (wetted with ca 30% Water, containing 25g on a dry weight basis) 25g 2,6-Bis(4-azidobenzylidene)-4-methylcyclohexanone (wetted with ca 30% Water, Price on request containing 25g on a dry weight basis) (2R,3R,5S,6S)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane (2S,3S,5R,6R)-5,6-Bis(azidomethyl)-2,3-dimethoxy-2,3-dimethyl-1,4-dioxane Bis[2-(4-azidosalicylamido)ethyl] Disulfide Disodium 4,4 -Diazidostilbene-2,2 -disulfonate Tetrahydrate Dodecylbenzenesulfonyl Azide (soft type) (mixture) N-Succinimidyl 5-Azido-2-nitrobenzoate N-Succinimidyl 4-Azido-2,3,5,6-tetrafluorobenzoate Trimethylsilylmethyl Azide B3693 B3694 B3790 D1606 D2580 S0860 S0952 T1184 A2523 A2727 A2388 O HN H NH H S A2500 N3 O A2728 O O O OH CH3 O O N H (CH2)4 O O N3 O O N3 O O O NH2 O N3 O O OH A1813 O O Ph O O A1678 O O BnO N3 A1833 N3 AcHN BnO BnO OBn O O N3 AcHN HO O N3 Ph O N3 N O O O O O HO OH O N3 NHAc A1832 Ph OAc O O A1811 NHAc A1616 100mg 25mg 100mg 25mg 100mg 25mg 100mg 1g 5g 1g Price on request A1812 Ph O O A2294 N-[2-[2-[2-(2-Azidoethoxy)ethoxy]ethoxy]ethyl]biotinamide 25-Azido-2,5,8,11,14,17,20,23-octaoxapentacosane Azido-PEG4-NHS Ester 14-Azido-3,6,9,12-tetraoxatetradecanol 13-Azido-2,5,8,11-tetraoxatridecane 11-Azido-3,6,9-trioxaundecan-1-amine 11-Azido-3,6,9-trioxaundecanoic Acid 11-Azido-3,6,9-trioxaundecanol A2523 A2727 A2388 A2500 A2728 A2363 A2293 A2294 AcO AcO N3 A2293 O N3 CH3 N3 A2363 O 100mg 100mg 10mg 25g 25g 10mg 200mg 1g 1g 5g NHAc G0257 Ph O O O AcO O O HO O N3 O N3 O OC(CH3)3 HN Fmoc OAc O AcO O AcO O O O N3 OC(CH3)3 CH3 HN Fmoc 187 A2627 A2172 HO OH O HO O OH O HO HO N3 AcHN A2267 O N3 AcHN D4217 HO AcHN HO AcHN HO O HO O HO HO O OH O AcHN HO HO HO O N3 HO Ph OAc O AcO AcO AcO O N3 OAc G0373 AcO O O HO O HO HO AcO HO O HO O HO HO O OH OH O O O HO AcHN OH NHAc O O O HO AcHN OH O OH O HO O HO OH O O O O OCH3 N3 G0403 AcHN HO HO HO HO HO O HO NaO3SO O O M1643 O O N3 O OCH3 HO OH O HO OH O O AcHN HO O AcHN N3 O O N3 O COONa HO O O HO OH O HO O HO OH HO O O AcHN M1637 A1832 G0257 A2627 A2172 A2267 A2377 D4217 G0330 G0309 G0373 G0403 G0372 G0337 H1333 L0237 M1643 OH O O HO O HO OH O HO OH O O HO HO HO HO O OH O O AcHN HO N3 OH HO O O AcHN OH O O AcHN HO OH O O AcHN M1617 T1731 O OCH3 N3 O O HO O O N3 OCH3 HO BnO AcO OBn O O N3 OCH3 OAc O AcO N3 OAc T1733 AcO OAc O OAc N3 A1812 A1813 A1811 A1616 A1678 A1833 Ph O O OCH3 T2196 AcO AcO O O OH O N3 L0237 Ph Ph O HO N3 M1638 O OH O HO H1333 HO HO N3 OAc HO O O HO AcHN HO O OAc Ph O OH O O O 188 O OAc N3 G0337 COONa HO O O HO O O OAc O AcO HO O O HO O COOH HO O HO G0372 HO NaO3SO HO HO G0330 COOH O OH HO OH O G0309 OH HO A2377 AcO AcO N3 O OAc 2-Acetamido-3-O-allyl-4,6-O-benzylidene-2-deoxy- -D-glucopyranosyl Azide 1g 2-Acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy- -D-glucopyranosyl Azide 1g 1g 5g 2-Acetamido-4,6-O-benzylidene-2-deoxy- -D-glucopyranosyl Azide 2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy- -D-glucopyranosyl Azide 1g 5g 2-Acetamido-3,4,6-tri-O-benzyl-2-deoxy- -D-glucopyranosyl Azide 1g 5g O-(2-Azido-4,6-O-benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]100mg L-serine tert-Butyl Ester O-(2-Azido-4,6-O-benzylidene-2-deoxy- -D-galactopyranosyl)-N-[(9H-fluoren-9-ylmethoxy)carbonyl]100mg L-threonine tert-Butyl Ester 2-[2-(2-Azidoethoxy)ethoxy]ethyl 2,3,4,6-Tetra-O-acetyl-D-galactopyranoside 1g 5g 2-Azidoethyl 2-Acetamido-2-deoxy- -D-galactopyranoside Price on request 500mg 2-Azidoethyl 2-Acetamido-2-deoxy- -D-glucopyranoside 2-Azidoethyl -D-Glucopyranoside 1g 2-Azidoethyl 2,3,4,6-Tetra-O-acetyl- -D-glucopyranoside 1g 5g Disialylnonasaccharide -Ethylazide Price on request Gal[2346Ac] (1-3)GalN3[46Bzd]- -MP 1g 5g 1g 5g Gal[2346Ac] (1-3)GlcN3[46Bzd]- -MP GalNAc (1-3)GlcNAc -Ethylazide Price on request Gb3- -ethylazide Price on request GlcA[3S] (1-3)Gal (1-4)GlcNAc (1-2)Man -Ethylazide Price on request GlcNAc (1-2)Man -1-Ethylazide 100mg HNK-1 Ethylazide Price on request LacDiNAc Dimer Ethylazide Price on request 1g 4-Methoxyphenyl 3-O-Allyl-2-azido-4,6-O-benzylidene-2-deoxy- -D-galactopyranoside N3 M1638 M1637 M1617 T1731 T2196 T1733 4-Methoxyphenyl 3-O-Allyl-2-azido-4,6-O-benzylidene-2-deoxy- -D-glucopyranoside 4-Methoxyphenyl 2-Azido-4,6-O-benzylidene-2-deoxy- -D-glucopyranoside 4-Methoxyphenyl 2-Azido-3,6-di-O-benzyl-2-deoxy- -D-glucopyranoside 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy- -D-galactopyranose 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy- -D-glucopyranose 1,3,4,6-Tetra-O-acetyl-2-azido-2-deoxy- -D-mannopyranose 1g 5g 1g 100mg 200mg 1g 100mg 1g 189 OCH3 O C60 [60]PCBM [B1641, B1660] [M2088] C70 [60]ICBA [B1694] 190 [I0900] B1642 B1641 B1660 B1694 C2415 I0900 CH3 N P2013 P2014 P2015 M2088 O O M2550 O (CH2)3 C O(CH2)7CH3 (CH2)3 C O(CH2)3CH3 (CH2)11CH3 (CH2)3 C O(CH2)11CH3 OCH3 OCH3 O O B4576 OCH3 O O OCH3 B1641 B1660 B1642 B1694 C2415 I0900 P2013 P2014 P2015 M2088 M2550 B4576 mixture of isomers Fullerene C60 (pure) Fullerene C60 Fullerene Extract, C60 (contains ca 20% C70) Fullerene C70 C60MC12 ICBA [60]PCB-C4 ([6,6]-Phenyl-C61-butyric Acid Butyl Ester) [60]PCB-C8 ([6,6]-Phenyl-C61-butyric Acid n-Octyl Ester) [60]PCB-C12 ([6,6]-Phenyl-C61-butyric Acid Dodecyl Ester) [60]PCBM (Methyl [6,6]-Phenyl-C61-butyrate) [70]PCBM (Methyl [6,6]-Phenyl-C71-butyrate) (mixture of isomers) Bis-PCBM (mixture of isomers) 100mg 100mg 100mg 1g 1g 1g 100mg 100mg 50mg 100mg 100mg 100mg 100mg 50mg 50mg 1985 1970 1991 2008 1995 2010 2007 2005 2000 2012 2013 2011 191 C60Peapod Squarylium@CNT Single-WalledCarbonNanotube (SWCNT) 192 C3133 C2143 C2149 C2148 C2150 C2153 C2152 C2155 C2154 C2157 C2156 C2159 C2158 C2151 C2147 C2146 Carbon Nanotube Single-walled (>85%) below 3nm(Average diam.), over m(Average length) 200mg 200mg Carbon Nanotube Double-walled (>50%) below 5nm(diam.), 5-15 m(length) Price on request Carbon Nanotube Multi-walled below 10nm(diam.), 1-2 m(length) Carbon Nanotube Multi-walled below 10nm(diam.), 5-15 m(length) 1g 1g 5g Carbon Nanotube Multi-walled 10-20nm(diam.), 5-15 m(length) Carbon Nanotube Multi-walled 10-30nm(diam.), 1-2 m(length) 1g Carbon Nanotube Multi-walled 10-30nm(diam.), 5-15 m(length) 1g 1g Carbon Nanotube Multi-walled 20-40nm(diam.), 1-2 m(length) Carbon Nanotube Multi-walled 20-40nm(diam.), 5-15 m(length) 1g 5g 1g Carbon Nanotube Multi-walled 40-60nm(diam.), 1-2 m(length) Carbon Nanotube Multi-walled 40-60nm(diam.), 5-15 m(length) 1g 5g Carbon Nanotube Multi-walled 60-100nm(diam.), 1-2 m(length) 1g 1g 5g Carbon Nanotube Multi-walled 60-100nm(diam.), 5-15 m(length) Carbon Nanotube Aligned Multi-walled 10-20nm(diam.), 5-15 m(length) 1g Carbon Nanotube Bundled Multi-walled below 10nm(diam.), 5-15 m(length) (allowable temperature limit : 620 ) 200mg Carbon Nanotube Herringbone 10-20nm(diam.), 5-15 m(length) 200mg 1991 2012 2011 2012 2012 2012 2011 2008 2011 2013 2008 2011 2013 2007 2014 193 COOH OH HOOC OH O Graphene [G0438, G0441, G0442] G0441 G0442 G0438 G0443 G0444 194 Graphene Nanoplatelets 6-8nm(thick), m(wide) Graphene Nanoplatelets 6-8nm(thick), 15 m(wide) Graphene Nanoplatelets 6-8nm(thick), 25 m(wide) Graphene Oxide Graphene Oxide (10mg/mL, Dispersion in Water) O O OH OH Graphene oxide [G0443, G0444] 5g 5g 5g 25g 25g 25g 100mg 5mL 25mL 2004 2008 2009 2005 2005 2012 2014 2014 2014 2014 2013 2013 2013 195 Nanodiamond (ND) ND CO2H SOCl2 COCl ND C18H37NH2 CONHC18H37 ND [N0969] N3 HO2C ND NH2 ND HNOC N3 [N0968] N0962 N0968 N0969 Nanodiamond (particle size : B, it is desirable that the boiling point is A < B and the density is A > B Freezing mixtures Ice Ethylene Glycol / CO2 Ice(100) / NH4Cl (25) Ice(100) / NaCl(33) Carbon Tetrachloride / N2 Carbon Tetrachloride / CO2 Ice(100) / EtOH (100) Acetonitrile / N2 Ice(100) / CaCl2 (150) Temp ° -15 -15 -21 -23 -23 -30 -41 -49 C Freezing mixtures Chloroform / N2 Chloroform / CO2 Ethanol / CO2 Ether / CO2 Acetone / CO2 Methanol / N2 n-Pentane / N2 N2 Temp ° C -63 -63 -72 -77 -78 -98 -131 -180 References 1"Yuki Kagaku Jikken no Tebiki 1", editors : T Goto, T Shiba, T Matsuura, Kagaku Dojin 2"Shinhan Kiso Yuki Kagaku Jikken", K Hata, K Watanabe, Maruzen 363 364 365 366 367 368 369 370  ...Reagent Guide 8th Edition Synthetic Organic Chemistry & Materials Chemistry www.TCIchemicals.com Cyclooctyl group [2+3] cycloaddition with