Nghiên cứu chế tạo compozit cacbon cacbon chứa cốt sợi ống nano cacbon định hướng ứng dụng trong công nghệ kỹ thuật cao

I HC QUC GIA H NI TRNG I HC KHOA HC T NHIấN V MINH THNH NGHIấN CU CH TO COMPOZIT CACBON-CACBON CHA CT SI NG NANO CACBON NH HNG NG DNG TRONG CễNG NGH K THUT CAO LUN N TIN S: NGNH HO HC H Ni - 2016 I HC QUC GIA H NI TRNG I HC KHOA HC T NHIấN V Minh Thnh NGHIấN CU CH TO COMPOZIT CACBON-CACBON CHA CT SI NG NANO CACBON NH HNG NG DNG TRONG CễNG NGH K THUT CAO Chuyờn ngnh: Hoỏ lớ thuyt v húa lớ Mó s: 62 44 01 19 LUN N TIN S: NGNH HO HC NGI HNG DN KHOA HC: PGS TS Lờ Kim Long GS TS Nguyn c Ngha LI CM N Lun ỏn ny c thc hin v hon thnh ti B mụn Hoỏ lý, Khoa Hoỏ hc, i Hc Khoa hc T nhiờn, i hc Quc gia H Ni v Vin Hoỏ hc-Vt liu, Vin Khoa hc v Cụng ngh Quõn s, B Quc phũng Xin by t lũng bit n sõu sc n PGS.TS Lờ Kim Long, GS.TS Nguyn c Ngha, nhng ngi Thy ó nh hng khoa hc v tn tỡnh hng dn sut thi gian hc v thc hin lun ỏn ny Xin chõn thnh cm n B mụn Hoỏ lý, Khoa Hoỏ hc, i hc Khoa hc T nhiờn; i hc Giỏo dc, i hc Quc gia H Ni; Trung tõm Phỏt trin Cụng ngh cao, Vin Hn lõm Khoa hc v Cụng ngh Vit Nam; Vin Hoỏ hc-Vt liu; Phũng Gm-Kim loi-Hp kim; Phũng Hoỏ lý/Vin Hoỏ hc-Vt liu; cỏc ng nghip, ng ó giỳp v to iu kin nghiờn cu thun li cho tỏc gi thi gian thc hin lun ỏn Xin chõn thnh cm n PGS TS ng Vn ng, KS Phan Vn Bỏ, TS Nguyn Mnh Tng, ThS H Ngc Minh, TS Lờ Vn Th, TS Ngụ Quc Dng, ThS Ngụ Minh Tin, ThS on Tun Anh, ThS Ngụ Cao Long, KS Phm Tun Anh ó cựng tỏc gi tin hnh nhng thớ nghim ch to mu v tho lun úng gúp ý kin cho lun ỏn Cui cựng, xin gi li cm n ti gia ỡnh, ngi thõn, bn bố ó ng viờn, c v tụi hon thnh bn lun ỏn ny Nghiờn cu sinh V Minh Thnh i LI CAM OAN Tụi xin cam oan õy l cụng trỡnh nghiờn cu ca riờng tụi Cỏc s liu, kt qu c nờu lun ỏn l trung thc v cha c cụng b bt k cụng trỡnh no khỏc Nghiờn cu sinh V Minh Thnh ii MC LC LI CM N i LI CAM OAN ii MC LC iii DANH MC CC Kí HIU, CC CH VIT TT vi DANH MC BNG BIU vii DANH MC HèNH V viii M U CHNG TNG QUAN Error! Bookmark not defined 1.1 Tỡnh hỡnh nghiờn cu v ng dng vt liu compozit cacbon-cacbon trờn th gii v nc Error! Bookmark not defined 1.2 Vt liu compozit cacbon-cacbon Error! Bookmark not defined 1.2.1 Thnh phn compozit cacbon-cacbon Error! Bookmark not defined 1.2.1.1 ng nano cacbon (Carbon nanotubes-CNT)Error! Bookmark not defined 1.2.1.2 Si cacbon Error! Bookmark not defined 1.2.1.3 Vt liu nn cacbon Error! Bookmark not defined 1.2.2 Cu trỳc vt liu compozit cacbon-cacbonError! Bookmark not defined 1.2.3 Tớnh cht vt liu compozit cacbon-cacbonError! Bookmark not defined 1.3 Cụng ngh ch to vt liu compozit cacbon-cacbonError! Bookmark not defined 1.3.1 Phng phỏp pha khớ Error! Bookmark not defined 1.3.2 Phng phỏp pha lng Error! Bookmark not defined 1.3.3 Phng phỏp kt hp Error! Bookmark not defined 1.4 To mng ph chu nhit, chng xúi mũn cho compozit cacbon-cacbonError! Bookmark n CHNG I TNG V PHNG PHP NGHIấN CUError! Bookmark not def 2.1 Nguyờn vt liu, hoỏ cht Error! Bookmark not defined 2.2 Thit b Error! Bookmark not defined 2.2.1 Thit b ch to Error! Bookmark not defined 2.2.2 Thit b phõn tớch Error! Bookmark not defined iii 2.3 Thc nghim Error! Bookmark not defined 2.3.1 Bin tớnh b mt CNT Error! Bookmark not defined 2.3.2 X lý nhit b mt si cacbon Error! Bookmark not defined 2.3.3 S ch bt graphit Error! Bookmark not defined 2.3.4 Tng hp nha nn phenolformaldehit dng novolacError! Bookmark not defined 2.3.5 Ch to compozit cacbon-cacbon Error! Bookmark not defined 2.3.6 Ph chng oxi hoỏ b mt nhit caoError! Bookmark not defined 2.4 Phng phỏp nghiờn cu Error! Bookmark not defined 2.4.1 Phng phỏp hin vi in t quột ph tỏn sc nng lng tia X (SEMEDX) v kớnh hin vi in t quột phỏt x trng (FESEM)Error! Bookmark not define 2.4.2 Phng phỏp hin vi in t truyn qua (TEM)Error! Bookmark not defined 2.4.3 Phng phỏp phõn tớch nhit (DSC/TGA)Error! Bookmark not defined 2.4.4 Phng phỏp ph hng ngoi (FT-IR) Error! Bookmark not defined 2.4.5 Phng phỏp nhiu x Rnghen (XRD) Error! Bookmark not defined 2.4.6 Phng phỏp phõn tớch c ht Error! Bookmark not defined 2.4.7 Phng phỏp cõn thy tnh Error! Bookmark not defined 2.4.8 Phng phỏp xỏc nh tớnh cht c hc ca vt liuError! Bookmark not defined 2.4.9 Kim tra kh nng chu sc nhit v xúi mũn ca vt liuError! Bookmark not def CHNG KT QU V THO LUN Error! Bookmark not defined 3.1 Kho sỏt v bin tớnh nguyờn liu u Error! Bookmark not defined 3.1.1 Kho sỏt v bin tớnh ng nano cacbon Error! Bookmark not defined 3.1.2 Kho sỏt tớnh cht ca si cacbon Error! Bookmark not defined 3.1.3 Kho sỏt tớnh cht ca bt graphit Error! Bookmark not defined 3.1.4 Tng hp v kho sỏt nha nn phenolformaldehit dng novolac (PF)Error! Bookm 3.2 Ch to compozit cacbon-cacbon Error! Bookmark not defined 3.2.1 Nghiờn cu ch to compozit trờn c s bt graphit, vi cacbon, CNTbt v nha PF Error! Bookmark not defined 3.2.1.1 nh hng ca hm lng nha PFError! Bookmark not defined 3.2.1.2 nh hng ca hm lng CNTbt Error! Bookmark not defined 3.2.1.3 nh hng ca ỏp lc ộp Error! Bookmark not defined iv 3.2.1.4 nh hng ca thi gian ộp Error! Bookmark not defined 3.2.2 Nghiờn cu quỏ trỡnh nhit phõn compozitError! Bookmark not defined 3.2.2.1 nh hng ca nhit Error! Bookmark not defined 3.2.2.2 nh hng ca tc nõng nhit Error! Bookmark not defined 3.2.2.3 nh hng ca thi gian nhit phõnError! defined Bookmark not 3.2.3 Nghiờn cu quỏ trỡnh thm cacbon t pha hiError! Bookmark not defined 3.2.3.1 nh hng ca nhit CVI Error! Bookmark not defined 3.2.3.2 nh hng ca thi gian CVI Error! Bookmark not defined 3.2.3.3 nh hng ca lu lng khớ Error! Bookmark not defined 3.2.3.4 nh hng ca hm lng CNT Error! Bookmark not defined 3.2.4 nh hng ca quỏ trỡnh x lý nhit n tớnh cht ca CCCError! Bookmark not d 3.2.5 To lp ph chng xúi mũn cho compozit cacbon-cacbonError! Bookmark not de 3.2.6 Kt qu th nghim thc t Error! Bookmark not defined KT LUN V KIN NGH Error! Bookmark not defined TI LIU THAM KHO 13 v DANH MC CC Kí HIU, CC CH VIT TT CCC Compozit cacbon-cacbon CCC0 Compozit cacbon-cacbon khụng cha ng cha CNTbt CCCCNT Compozit cacbon-cacbon cha ng cha CNTbt Cf Si cacbon CNT ng nano cacbon CNTbt ng nano cacbon bin tớnh CVD Quỏ trỡnh lng ng hoỏ hc t pha hi CVI Quỏ trỡnh thm cacbon t pha hi DTA Phõn tớch nhit vi sai F Formaldehit FESEM Kớnh hin vi in t quột phỏt x trng IR Ph hng ngoi MWCNT ng nano cacbon a tng P Phenol PAN Polyacrylonitril PF Phenolformaldehit SEM-EDX Kớnh hin vi in t quột-ph tỏn sc nng lng tia X SWCNT ng nano cacbon n tng XLN X lý nhit X-ray Nhiu x tia-X h xp h, % kớn xp kớn, % tng xp tng, % bk T trng biu kin vi DANH MC BNG BIU Bng 1.1 Tớnh cht c hc ca CNT v mt s vt liu thụng dngError! Bookmark not de Bng 1.2 S ph thuc tớnh cht ca pirocacbon vo nhit lng ngError! Bookmark no Bng 1.3 Tớnh cht nn cacbon trờn c s hc ớn thu c 900CError! Bookmark not de Bng 1.4 Tớnh cht ca mt s vt liu compozit cacbon-cacbonError! Bookmark not defin Bng 1.5 Tớnh cht ca compozit cacbon-cacbon ch to bng cỏc phng phỏp to pha nn khỏc Error! Bookmark not defined Bng 1.6 Mt s lp ph lng ng theo cụng ngh CVDError! Bookmark not defined Bng 1.7 Mt s tớnh cht v c tớnh ca ZrC Error! Bookmark not defined Bng 3.1 Phi liu cỏc mu compozit cú thnh phn nha PF thay iError! Bookmark not Bng 3.2 T trng biu kin, xp h, xp kớn ca cỏc mu compozit.Error! Bookmark Bng 3.3 Phi liu cỏc mu compozit cú thnh phn CNTbt thay iError! Bookmark not d Bng 3.4 T trng biu kin, xp h, xp kớn ca cỏc mu compozitError! Bookmark no Bng 3.5 Ch nhit phõn cỏc mu compozit Error! Bookmark not defined Bng 3.6 Ch nhit phõn cỏc mu compozit Error! Bookmark not defined Bng 3.7 Ch nhit phõn cỏc mu compozit Error! Bookmark not defined Bng 3.8 Mt s tớnh cht ca cỏc mu CCC2CNT trc v sau XLNError! Bookmark no Bng 3.9 Tớnh cht ca CCC0 trc v sau x lý nhit chu kError! Bookmark not de Bng 3.10 cng t vi ca mng ZrC Error! Bookmark not defined vii DANH MC HèNH V Hỡnh 1.1 S tng hp CNT bng phng phỏp CVD trờn xỳc tỏc kim loiError! Bookm Hỡnh 1.2 S quỏ trỡnh bin tớnh CNT bng axitError! Bookmark not defined Hỡnh 1.3 Ch to CNT polyme nanocompozit theo phng phỏp trựng hp In-situError! Bookm Hỡnh 1.4 Ch to CNT polyme nanocompozit theo phng phỏp trn hp dung mụi Error! Bookmark not defined Hỡnh 1.5 S quỏ trỡnh cacbon húa vi nhng phng ỏn kộo cng si khỏc nhauError! Bookm Hỡnh 1.6 Tng quan gia gii hn bn B v mụ un n hi E ca si cacbon trờn c s xenlulo Error! Bookmark not defined Hỡnh 1.7 S ph thuc ca gii hn bn kộo B v mụ un n hi ca si cacbon trờn c s hc ớn vo nhit x lý nhit Error! Bookmark not defined Hỡnh 1.8 S thay i gim lng theo nhit vi tc nung si khỏc nhau: - 0,5; - 15; - 2; - 4; - 8; - 25C/phỳtError! Bookmark not defined Hỡnh 1.9 S ph thuc lng riờng pirocacbon vo nhit b mt lng ngError! Bookm Hỡnh 1.10 S ph thuc lng riờng ca hc ớn vo nhit húa mmError! Bookmark n Hỡnh 1.11 S ph thuc lng riờng v nht ca hc ớn vo nhit húa mm khỏc (1-65C; 2-83C; 3-145C) vo nhit nungError! Bookmark not defined Hỡnh 1.12 Cu trỳc vt liu compozit cacbon-cacbonError! Bookmark not defined Hỡnh 1.13 S ph thuc bn kộo ca compozit cacbon-cacbon 3D vo nhit (1 - theo hng x; - theo hng z) Error! Bookmark not defined Hỡnh 1.14 S ph thuc ca h s dón n nhit (a) v dn nhit (b) ca vt liu compozit cacbon-cacbon 3D vo nhit (1 - lý thuyt; - thc nghim)Error! Bookmark not d Hỡnh 1.15 S chung ch to vt liu compozit cacbon-cacbonError! Bookmark not defi Hỡnh 1.16 S bung lũ phng phỏp ng nhit thu lng pirocacbonError! Bookmark not Hỡnh 1.17 S bung lũ phng phỏp gim nhit lng ng pirocacbon Error! Bookmark not defined Hỡnh 1.18 Chu k cacbon húa (a) v graphit húa (b) c trngError! Bookmark not define Hỡnh 1.19 Quỏ trỡnh hỡnh thnh lp ph bng cụng ngh CVDError! Bookmark not define Hỡnh 1.20 Thang im chy ca mt s hp chtError! Bookmark not defined viii 10 Berenguer R., Marco-Lozar J.P., Quijada C., Cazorla-Amorús D., Morallún E (2009), "Effect of electrochemical treatments on the surface chemistry of activated carbon", Carbon 47, pp 1018-1027 11 Bertrand S., Lavaud J.F., Hadi E.R., Vignoles G., Pailler R (1998), "The thermal gradient-pulse flow CVI process: a new chemical vapor infiltration technique for the densification of fibre preforms", Journal of the European Ceramic Society 18, pp 857-870 12 Blanco C., Bermejo J., Marsh H., Menendez R (1997), "Chemical and physical properties of carbon as related to brake performance ", Wear 213, pp 1-12 13 Chen J., Xiong Xiang, Xiao Peng (2009), "The effect of carbon nanotube growing on carbon fibers on the microstructure of the pyrolytic carbon and the thermal conductivity of carbon/carbon composites", Materials Chemistry and Physics 116, pp 57-61 14 Choi J.Y., Han S.W., Huh W.S., Tan L.S., Baek J.B (2007), In situ grafting of carboxylic acid-terminated hyperbranched poly(ether-ketone) to the surface of carbon nanotubes, Polymer 48, pp 4034-4040 15 Compan J., HiraT i, Pintsuk G., Linke J (2009), "Microstructural and thermomechanical characterization of carbon/carbon composites", Journal of Nuclear Materials 386-388, pp 797-800 16 Curry, Donald M (1988), "Carbon-Carbon Materials Development and Flight Certification Experience From Space Shuttle", Oxidation-Resistant Carbon Carbon Composite for Hypersonic Vehicle Applications, Howard G.Maahs, ed., NASA CP- 2051, pp 29-50 17 Czerw R., Guo Z., Sun Y.P., et al (2001), Organization of polymers on to carbon nanotubes: a route to nanoscale assembly, Nano LettersVol 1, pp 423-427 18 Devi G.R and Rao K.R (1993), "Carbon-Carbon Overview", Defence Science Journal 43(4), pp 369-383 14 Composites -An 19 Dhakate S.R., Bahl O.P (2003), "Effect of carbon fiber surface functional groups on the mechanical properties of carboncarbon composites with HTT", Carbon 41, pp 1193-1203 20 Dhakate S.R., Mathur R.B., Kakati B.K., Dhami T.L (2007), "Properties of graphite-composite bipolar plate prepared by compression molding technique for PEM fuel cell", International Journal of Hydrogen Energy 32, pp 45374543 21 Diaz L.J.L., Yasuhiro T., Takashi E., Kazumasa N., Morinobu E., Eiichi Y (2009), "The effect of nanotube alignment on stress graphitization of carbon/carbon nanotube composites", Carbon 47, pp 974-980 22 Donnet J B., Wang T K., Shen Z M (1996), "Atomic scale STM study of pitch-based carbon fibers: influence of mesophase content and the heat treatment temperature", Carbon 34, pp 1413-1420 23 Eesaee M., Shojaei A (2014), "Effect of nanoclays on the mechanical properties and durability of novolac phenolic resin/woven glass fiber compositeat various chemical environments", Composites Part A 63, pp 149158 24 Fukushima T., Kosaka A., Yamamoto Y., Aimiya T., Notazawa S., Taki-gawa T (2006), Dramatic effect of dispersed carbon nanotubes on the mechanical and electroconductive properties of polymers derived from ionic liquids, Small 2, pp 554-560 25 Galiguzov A., Malakho A., Kulakov V., Kenigfest A., Kramarenko E and Avdeev V (2013), "The Influence of Carbon FiberHeat Treatment Temperature on Carbon-Carbon Brakes Characteristics", Carbon Letters 14(1), pp 22-26 26 Gao J., Itkis M.E., Yu A., Bekyarova E., Zhao B., Haddon R.C (2005), Continuous spinning of a SWCNTnylon composite ber, Journal of the American Chemical Society 127, pp 3847-3854 15 27 Gibson R.F., Ayorinde E.O., Wen Y.F (2007), "Vibrations of carbon nanotubes and their composites: A review", Composites Science and Technology 67, pp 1-28 28 Golecki I., Morris R.C., Narasimhan D., Clements N (1995), "Rapid densification of porous carbon/carbon composites by thermal-gradient chemical vapor infiltration", Applied Physics Letters 66 (18), pp 2334-2336 29 Guignier C., Bueno M.A, Camillieri B., Tourlonias M., Durand B (2015), "Tribological behaviour and wear of carbon nanotubes grafted on carbon fibres", Composites Part A 71, pp 168-175 30 Guixiang D., Chang S., Jianghong Z., Shouai F., Zhenping Z (2008), "Solidphase transformation of glass-like carbon nanoparticles into nanotubes and the related mechanism", Carbon 46, pp 92-98 31 Han S.J., Kim B., Suh K.D (2007), Electrical properties of a composite lm of poly(acrylonitrile) nanoparticles coated with carbon nanotubes, Macromolecules Chemical Physics 208, pp 377-383 32 Harry D., Saha B., Cumming I.W (2007), "Surface properties of electrochemically oxidized viscose rayon based carbon fibers", Carbon 28, pp 766 33 Homenick C.M., Lawson G., Adronov A (2007), Polymer grafting of carbon nanotubes using living free radical polymerization, Polymer reviews 47, pp 265-290 34 Hong U.S., Jung S.L., Cho K.H., Cho M.H., Kim S.J., Jang H (2009), "Wear mechanism of multiphase friction materials with different phenolic resin matrices", Wear 266, pp 739-744 35 Hugh O P (1999), Handbook of chemical vapor deposition (CVD), Noyes Publications Park Ridge, New Jersey, U.S.A, pp 416 36 Hua Y., Chingombe P., Saha B., Wakeman R.J., (2005), " Effect of surface modification on carbon", Carbon 43, pp 3132-3143 16 37 Huang H C., Ye D.Q., Huang B C (2007), "Nitrogen plasma modification of viscose-based activated carbon fibers", Surface and Coatings Technology 45, pp 9533-9540 38 Hyeok J.J, Hee D.P., Jae D.L., Jong O.P (1996), "Densification of carbon/carbon composites by pulse chemical vapor infiltration", Carbon 34 (3), pp 417-421 39 Haiyun J., Wang J., Wu S., Wang B., Wang Z (2010), "Pyrolysis kinetics of phenolformaldehyde resin by non-isothermal thermogravimetry", Carbon 48, pp 352358 40 Haiyun J., Wang J., Wu S., Yuan Z., Hu Z., Wu R., Liu Q (2012), "The pyrolysis mechanism of phenol formaldehyde resin", Polymer Degradation and Stability 97, pp 1527-1533 41 Jigang W., Jiang N., Haiyun J (2010), "Micro-structural evolution of phenolformaldehyde resin modified by boron carbide at elevated temperatures", Materials Chemistry and Physics 120 , pp 187-192 42 Jigang W., Haiyun J., Jiang N (2009), "Study on the pyrolysis of phenolformaldehyde (PF) resin and modified PF resin", Thermochimica Acta 496 (Issues 1-2), pp 136-142 43 Jigang W., Jiang N., Haiyun J (2010), "Micro-structural evolution of phenolformaldehyde resin modified by boron carbide at elevated temperatures", Materials Chemistry and Physics 120, pp 187192 44 Jinggeng Z., Yang L., Li F., Yu R., Jin C (2009), "Structural evolution in the graphitization process of activated carbon by high-pressure sintering", Carbon 47, pp 744-751 45 Khorasani S., Manesh S.H., Abdizadeh H (2015), "Improvement of mechanical properties in aluminum/CNTs nanocomposites by addition of mechanically activated graphite", Composites Part A 68, pp 177-183 17 46 Kim M., Park Y.B., Okoli O.I., Zhang C (2009), "Processing, characterization, and modeling of carbon nanotube-reinforced multiscale composites", Composites Science and Technology 69, pp 335-342 47 Ko T.H., Kuo W.S., Lu Y.R (2000), "The influence of post-cure on the properties of Carbon/ Phenolic resin cured composites and their final Carbon/carbon composites", Polymer Composites 21 (1), pp 96-103 48 Ko T.H., Kuo W.S., Chang Y.H (2000), "Raman study of the microstructure changes of phenolic resin during pyrolysis", Polymer Composites 21 (5), pp 745-750 49 Ko T.H., Kuo W.S and Chang Y.H (2003), "Influence of carbon-fiber felts on the development of carboncarbon composites", Composites Part A: Applied Science and Manufacturing 34 (5), pp 393-401 50 Ko T.H (1992), "The effects of activation by carbon dioxide on the mechanical properties and structure of pan-based activated carbon fibers", Carbon 30(4), pp 647-655 51 Koshio A., Yudasaka A.M., Zhang M., Iijima S (2001), A simple way to chemically react single-wall carbon nanotubes with organic materials using ultrasonication, Nano Letters 1, pp 361-363 52 Kumar N.A., Ganapathy H.S., Kim J.S., Jeong Y.S., Jeong Y.T (2008), Preparation of poly 2-hydroxyethyl methacrylate functionalized carbon nanotubes as novel biomaterial nanocomposites, European Polymer Journal 44, pp 579-586 53 Leslie J.L., Yasuhiro T., Takashi E., Kazumasa N., Morinobu E., Eiichi Y (2009), "The effect of nanotube alignment on stress graphitization of carbon/carbon nanotube composites", Carbon 47, pp 974-980 54 Lee J S., Kang T J (1997), "Changes in physico-chemical and morphological properties of carbon fiber by surface treatment", Carbon 35, pp 209 55 Lee K.J., Hsu M.H., Cheng H.Z., Jang J.S.C., Lin S.W., Lee C.C and Lin S.C., Journal of Alloys and Compounds, 2009, 483(12), 389393 18 56 Lee W.H., Lee J.G., Reucroft P.J (2001), "XPS study of carbon fiber surfaces treated by thermal oxidation in a gas mixture of O2/(O2+N2)", Applied Surface Science 171, pp 136-142 57 Lee H.J , Oh S.J., Choi J.Y., Kim J.W., Han J., Tan L.S (2005), In situ synthesis of poly(ethylene terephthalate) (PET) in ethylene glycol containing terephthalic acid and functionalized multiwalled carbon nanotubes (MWNTs) as an approach to MWNT/PET nanocomposites, Chemistry of materials 17, pp 5057-5064 58 Lee S.M (1990), International Encyclopedia of Composites, 1, VCH Publishers, New York, NY, USA 59 Li J., Luo R (2008), "Study of the mechanical properties of carbon nanofiber reinforced carbon/carbon composites", Composites Part A 39, pp 1700-1704 60 Li K., Li L., Li H., Song Q., Lu J., Fu Q.(2014), "Electrophoretic deposition of carbon nanotubes onto carbon fiber felt for production of carbon/carbon composites with improved mechanical and thermal properties", Vacuum 104, pp 105-110 61 Li X., Li K., Li H., Wei J., Wang Ch (2007), "Microstructures and mechanical properties of carbon/carbon composites reinforced with carbon nanofibers/ nanotubes produced in situ", Carbon 45, pp 1662-1668 62 Li J., Luo R., Bi Y., Xiang Q., Lin Ch., Zhang Y., An N (2008), "The preparation and performance of short carbon fiber reinforced adhesive for bonding carbon/carbon composites", Carbon 46, pp 1957-1965 63 Li J., Luo R (2008), "Kinetics of chemical vapor infiltration of carbon nanofiber-reinforced carbon/carbon composites", Materials Science and Engineering A 480, pp 253-258 64 Lim D.S., An J.W and Lee H.J (2002), "Effect of carbon nanotube addition on the tribological behavior of carbon/carbon composites", Wear 252(5-6), pp 512-517 19 65 Liu L (2004), Resistance to ablation of pitch-derived ZrC/C composites, Carbon 42, pp 24952500 66 Lindsay B., Abel M.L., Watts J F (2007), "A study of electrochemically treated PAN based carbon fibers by IGC and XPS", Carbon 45 pp 2433 67 Liu Y., Tang J., Xin J.H (2004), Fabrication of nanowires with polymer shells using treated carbon nanotube bundles as macro-initiators, Chemical communications, pp 2828-2829 68 Luthra K.L (1988), Oxidation of carbon/carbon composites-a theoretical analysis, Carbon 26, pp 217-224 69 Maitra T., Sharma S., Srivastava A., Cho Y.K., Madoub M., Sharma A (2012), "Improved graphitization and electrical conductivity of suspended carbon nanofibers derived from carbon nanotube/polyacrylonitrile composites by directed electrospinning", Carbon 50, pp 1753-1761 70 Masahiro T., Masato K., Michio I (2001), Intercalation of nitric acid into carbon fibers, Carbon 39, pp.2231-2237 71 Masahiro T., Masato K., Michio I (2004), Intercalation and exfoliation behavior of carbon fibers during electrolysis in H2SO4, Journal of Physics and Chemistry of Solids 65, pp 257-261 72 Matsui K., Lanticse L.J., Yasuhiro T., Eiichi Y., Morinobu E (2005), "Stress graphitization of C/C composite reinforced by carbon nanofiber", Carbon 43, pp 1557-1583 73 Mauricio T (2003), Science and technology of the twenty-first century: Synthesis, properties, and applications of carbon nanotubes, Annual review of Materials research, 33, pp 419501 74 Meng L.H., Chen Z.W., Song X.L., Liang Y.X., Huang Y.D., Jiang Z.X (2009), Influence of High Temperature and Pressure Ammonia Solution Treatment on Interfacial Behavior of Carbon Fiber/Epoxy Resin Composites, Journal of Applied Polymer Science 113 (6), pp 3436-3441 20 75 Mentz J., Mỹller M., Buchkremer H.P., et al (2006), "Carbon-fibre-reinforced carbon composite filled with SiC particles forming a porous matrix", Materials Science and Engineering-A 425, pp 64 76 Moaseri E., Karimi M., Maghrebi M., Baniadam M (2014), "Fabrication of multi-walled carbon nanotubecarbon fiber hybrid material via electrophoretic deposition followed by pyrolysis process", Composites Part A 60, pp 8-14 77 Monika K., Filip P., Weiss Z., Peter R (2004), "Influence of metals on the phenolformaldehyde resin degradation in friction composites", Polymer Degradation and Stability 84, pp 49-60 78 Monthioux M., Allouche H and Jacobsen R L., "Chemical vapour deposition of pyrolytic carbon on carbon nanotubes: Part 3: Growth mechanisms ", Carbon, 2006, 44(15), pp 31833194 79 Nakamura K., Sano T., Shindo H (2008), "Frictional property of glass-like carbon heat-treated at 1000-3000C", Materials Science and Engineering B 148, pp 242-244 80 Nakamura K., Yasuhiro T., Fukushima M., Teranishi Y., Akatsu T., Eiichi Y (2009), "Analysis of surface oxidation behavior at 500C under dry air of glass-like carbon heat-treated from 1200 to 3000C", Materials Science and Engineering B 161, pp 40-45 81 Naslain R.R., Pailler R., Bourrat X., Bertrand S., Heurtevent F., Dupel P., Lamouroux F (2001), "Synthesis of highly tailored ceramic matrix composites by pressure-pulsed CVI", Solid State Ionics 141-142, pp 541-548 82 Palaninathan R (2010), "Behavior of Carbon-Carbon Composite under Intense Heating", International Journal of Aerospace Engineering Volume 2010, pp 1-8 83 Park S.J., Kim B.J (2005), Roles of acidic functional groups of carbon fiber surfaces in enhancing interfacial adhesion behavior, Materials Science and Engineering-A 408, pp 1-2 21 84 Patel H., Manocha L.M., Manocha S (2014), "Synthesis and microstructure analysis of aligned carbon nanotube/pyrocarbon composites ", New carbon materials 29, pp 374-379 85 Paulmier T., Pichelin M.B., Quộau D.L (2005), "Structural modifications of carboncarbon composites under high temperature and ion irradiation", Applied Surface Science 243, pp 376-393 86 Policandriotes T., Filip P (2011), "Effects of selected nanoadditives on the friction and wear performance of carboncarbon aircraft brake composites", Wear 271, pp 2280-2289 87 Policandriotes T., Filip P (2011), "Effects of selected nanoadditives on the friction and wear performance of carboncarbon aircraft brake composites", Wear 271, pp 2280-2289 88 Probst K.J., Bermann T.M., Stinto D.P., Lowden R.A., Anderson T.J., Starr T.L (1999), "Recent advances in forced-flow, thermal-gradient CVI for refractory composites", Surface and Coating Technology 120-121, pp 250258 89 Qian M., Li Z., Zhou X.W., Wu J., Wang Y., Liang J (2005), "Synthesis and characterization of in situ grown carbon nanofiber/nanotube reinforced carbon/carbon composites", Carbon 43(11), pp 2426-2429 90 Qin S., Qin D., Ford W.T., Herrera J.E (2004), Solubilization and purication of single-wall carbon nanotubes in water by in situ radical polymerization of sodium 4-styrenesulfonate, Macromolecules 37, pp 39653967 91 Qiuhong Z., Liu J., Sager R., Dai L., Baur J (2009), "Hierarchical composites of carbon nanotubes on carbon fiber: Influence of growth condition on fiber tensile properties", Composites Science and Technology 69, pp 594-601 92 Riggs J.E., Guo Z., Carroll D.L., Sun Y.P (2000), Strong luminescence of solubilized carbon nanotubes, Journal of the American Chemical Society 22 122, pp 5879-5880 93 Rovillain D., Trinquecoste M., Bruneton E., Derrộ A., David P., Delhaốs P (2001), "Film boiling chemical vapor infiltration: an experimental study on carbon/carbon composite materials", Carbon 39, pp 1355-1365 94 Sharma M., Gao S., Mọder E., Sharma H., Wei L.Y., Bijwe J (2014), "Carbon fiber surfaces and composite interphases", Composites Science and Technology 102, pp 35-50 95 Sharma R., Mahajan P., and Mittal R.K (2010), "Image Based Finite Element Analysis of 3D-Orthogonal Carbon-Carbon (C/C) Composite ", World Congress on Engineering II 96 Sheehan J.E., Buesking K.W and Sullivan B.J (1994), "Carbon-carbon composite", Annu Rev Mater Sci 24, pp 19-44 97 So H.H., Cho J.W., Sahoo N.G (2007), Effect of carbon nanotubes on mechanical and electrical properties of polyimide/carbon nanotubes nanocomposites, European Polymer Journal 43, pp 3750-3756 98 Song Q., Li K., Li H., Li H., Ren C (2012), "Grafting straight carbon nanotubes radially onto carbon fibers and their effect on the mechanical properties of carbon/carbon composites", Carbon 50, pp 3943-3960 99 Song Q., Li K., Zhang L., Qi L., Li H., Fu Q., Deng H.(2013), "Increasing mechanical strength retention rate of carbon/carbon composites after graphitization by grafting straight carbon nanotubes radially onto carbon fibers", Materials Science & Engineering A 560, pp 831-836 100 Song Q., Li K., Qi L., Li H., Lu J., Zhang L., Fu Q.(2013), "The reinforcement and toughening of pyrocarbon-based carbon/carbon composite by controlling carbon nanotube growth position in carbon felt", Materials Science & Engineering A 564, pp 71-75 101 Song L., Khoerunnisa F., Gao W., Dou W., Hayashi T., Kaneko K., Morinobu E., Ajayan P.M (2013), "Effect of high-temperature thermal treatment on the 23 structure and adsorption properties of reduced graphene oxide", Carbon 52, pp 605-620 102 Song H.H., Hyun J.O., Seong S.K (2014), "Evaluation of fiber surface treatment on the interfacial behavior of carbon fiber-reinforced polypropylene composites", Composites Part B 60, pp 98-105 103 Song Q., Li K., Li H., Fu Q (2013), "Increasing the Tensile Property of Unidirectional Carbon/Carbon Composites by Grafting Carbon Nanotubes onto Carbon Fibers by Electrophoretic Deposition", J Mater Sci Technol 29(8), pp 711-714 104 Spitalsky Z., Tasis D., Papagelis K., Galiotis C (2010), Carbon nanotube polymer composites: Chemistry, processing, mechanical and electrical properties, Progress in Polymer Science 35, pp 357-401 105 Terrones M (2003), "Science and technology of the twenty-first century: Synthesis, properties, and applications of carbon nanotubes", Annual review of Materials research 33, pp 419-501 106 Thornton E.A (1996), "Thermal Structures for Aerospace Applications", AIAA Education Series, Ohio, USA 107 Thostenson E.T., Chou T.W (2002), Aligned MWCNT reinforced composites: processing and mechanical characterization, Applied Physics 35, pp 77-80 108 Thostenson E.T., Ren Z., Chou T.W (2001), "Advances in the science and technology of carbon nanotubes and their composites: a review", Composites Science and Technology 61(13), pp 1899-1912 109 Tiwari S., Bijwe J (2014), "Surface Treatment of Carbon Fibers", Pocedia Technology 14, pp 505 -512 110 Toyoda M., Katoh H., Inagaki M (2001), "Intercalation of nitric acid into carbon fibers", Carbon 39, pp 2231-2237 111 Tzeng S.S., Lin Y.H (2013), "Formation of graphitic rods in carbon/carbon composites reinforced with carbon nanotubes", Carbon 52, pp 605-620 24 112 Unterweger C., Duchoslav J., Stifter D., Fỹrst C (2015), "Characterization of carbon fiber surfaces and their impacton the mechanical properties of short carbon fiber reinforced polypropylene composites", Composites Science and Technology 108, pp 41-47 113 Vaidyaraman S., Lackey W.J., Freeman G.B., Agrawal P.K., Langman M.D (1995), "Fabrication of carbon-carbon composites by force", Journal of Materials Research 10(6), pp 1469-1477 114 Valle C., Mendoza M.P., Maser W.K., Martnez M.T., Alvarez L., Sauvajol J.L., Benito A.M (2009), "Effects of partial and total methane flows on the yield and structural characteristics of MWCNTs produced by CVD", Carbon 47, pp 998-1004 115 Venkat R.M., Mahajan P., Mittal R.K (2008), Effect of architecture on mechanical properties of carbon/carbon composites, Composite Structures 83(2), pp 131142 116 Venugopalan R and Sathiyamoorthy D (2012), "Development of Carbon / Carbon Composites for Nuclear Reactor Applications", ISSUE No 325, pp 16-20 117 Viswanathan G., Chakrapani N., Yang H (2003), Single-step in situ synthesis of polymer-grafted single-wall nanotube composites, Journal of the American Chemical Society 125, pp 9258-9259 118 Vix-Guterl C., Shah S., Dentzer J., Ehrburger P., Manocha L.M., Patel M and Manocha S (2001), "Carbon/carbon composites with heat-treated pitches: II Development of porosity in composites", Carbon 39, pp 673-683 119 Wan Y.Z., Wang Y.L., Zhou F.G., Cheng G.X., Han K.Y (2002), ThreeDimensionally Braided Carbon FiberEpoxy Composites, A New Type of Materials for Osteosynthesis Devices II Influence of Fiber Surface Treatment, Journal of Applied Polymer Science 85(5), pp 1040-1046 120 Wan Y Z., Wang Y.L., Li Q.Y., Dong X H (2001), Influence of Surface Treatment of Carbon Fibers on Interfacial Adhesion Strength and Mechanical 25 Properties of PLA-Based Composites, Journal of Applied Polymer Science 80(3), pp 367-376 121 Wang S., Chen Z.H., Ma W.J., et al (2006), "Influence of heat treatment on physicalchemical properties of PAN-based carbon fiber", Ceramics International 32, pp 291 122 Wang J.G., Guo Q.G., Liu L., Song J.R (2002), "Study on the microstructural evolu-tion of high temperature adhesives for graphite bonding", Carbon 40, pp 2447-2452 123 Wang J.G., Guo Q.G., Liu L., Song J.R (2005), "The preparation and performanceof high- temperature adhesives for graphite bonding", Int J Adhes Adhes 25, pp 495-501 124 Windhorst T and Blount G (1997), "Carbon-carbon composites: a summary of recent developments and applications", MateriaIs & Design 18(1), pp 11-15 125 Wu C.S (2007), Characterizing composite of multiwalled carbon nanotubes and POE-g-AA prepared via melting method, Journal of applied Polymer Science 104, pp 1328-1337 126 Xiao P., Lu X., Liu Y., He L (2011), "Effect of in situ grown carbon nanotubes on the structure and mechanical properties of unidirectional carbon/carbon composites", Materials Science and Engineering A 528, pp 3056-3061 127 Xu H., Wang X., Zhang Y., Liu S (2006), Single-step in situ preparation of polymer-grafted multi-walled carbon nanotube composites under 60Co -ray irradiation, Chemistry of materials 18, pp 2929-2934 128 Yu A., Hu H., Bekyarova E., Itkis M.E., Gao J., Zhao B (2006), Incorporation of highly dispersed SWCNTs into a polyimide matrix, Composites Science and Technology 66, pp 1190-1197 129 Yu L., Lu Z., Chen X., Wang D., Liu J., and Hu L (2009), "Study on Phenolic-Resin/Carbon-fiber Ablation Composites Modified with Polyhedral 26 Oligomeric Silsesquioxanes", Conference on Nano/Micro Engineered and Molecular System, pp 605-608 130 Yuguang J., Zhang Y., Zhang Q., Zhang A.R., Li P., Qiana W and Wei F (2013), Nanoscale 5, pp 6181-6186 131 Zhang R.L., Liu Y., Huang Y.D., Liu L (2013), "Effect of particle size and distribution of the sizing agent on the carbon fibers surface and interfacial shear strength (IFSS) of its composites", Applied Surface Science 287, pp 423-427 132 Zhao B., Hu H., Mandal S.K., Haddon R.C (2005), A bone mimic based on the self-assembly of hydroxyapatite on chemically functionalized singlewalled carbon nanotubes, Chemistry of materials 17, pp 3235-3241 133 Zhao J., Li K., Li H., Wang C (2006), "The influence of thermal gradient on pyrocarbon deposition in carbon/carbon composites during the CVI process", Carbon 44, pp 786-791 134 Zhi-hai F., Zhen F., Qing K., Xiang X., Bo-yun H (2014), "Effect of high temperature treatment on the structure and thermal conductivity of 2D carbon/carbon composites with a high thermal conductivity", New Carbon Materials 29(5), pp 357-362 135 Zhishuang D., Zhang B., Shi F., Li M., Zhang Z., Gu Y (2011), Effect of heat treatment on carbon fiber surface properties and fibers/epoxy interfacial adhesion, Applied Surface Science 257, pp 8457-8461 136 Zhonghua T., Qu D., Jie X., Zou Z (2003), "Effects of infiltration conditions on the densification behavior of carbon/carbon composites prepared by a directional-flow thermal gradient CVI process", Carbon 41, pp 2703-2710 137 Zhou Z., Wang X., Faraji S., Bradford P.D., Li Q., Zhu Y (2014), "Mechanical and electrical properties of aligned carbon nanotube/carbon matrix composites", Carbon 75, pp 307-313 Ting Nga 138 (2002), - 27 , , - .. , 160-255 c (Berveno A (2002), Ch to vt liu compozit cacbon-cacbon th h mi s dng ng nano cacbon, NXB "MGTU Bauman N E.", trang 160-255) 139 .., . (1998), , - .. , 318-382 c (Buranov I M., Vorobei V B (1998), Cụng ngh cỏc kt cu tờn la v hng khụng v tr t vt liu compozit, NXB "MGTU Bauman N E.", trang 318-392) 140 .., .., . (1994), - , , , 68-82 c (Bushuev Yu G, Persin M I, Sokolov V A (1994), S tay vt liu compozit cacbon-cacbon, NXB "Luyn kim", trang 68-82) 141 (1988), , , , 319-323 (Lyubin Dj (1988), S tay vt liu compozit, NXB "Ch to mỏy", trang 319-323) 142 ., (2007), , , , "-", 176-183 (Meleshko A I, Polivnhikov C P (2007), Cacbon, si cacbon, compozit cacbon, NXB "SAINZ-PRESS", trang 176-183) 143 (1988), : ., : , 125-133 (Fitzer E (1988), Si cacbon v compozit ca chỳng: bn dch t ting Anh, NXB "Hũa Bỡnh", trang 125-133) 144 . (2009), , 216226 (Tshurik A G (2009), Vt liu cacbon nhõn to, NXB "Perm", trang 216-226) 28 [...]... chí Khoa học công nghệ quân sự số 8, tr.113-117 3 Nguyễn Đức Nghĩa (2007), Hóa học Nano- Công nghệ nền và vật liệu nguồn, NXB Khoa học tự nhiên và công nghệ, Hà Nội 4 Nguyễn Hoa Thịnh, Nguyễn Đình Đức (2001), Vật liệu composite - Cơ học và công nghệ, NXB Khoa học và kỹ thuật 5 Lê Quốc Trung, Vũ Đình Khiêm, Ngô Cao Long, Lê Văn Thụ (2010), Công nghệ nano – Công nghệ của thể kỷ XXI, NXB Công an Nhân... Khôi (2005), Nghiên cứu công nghệ chế tạo màng mỏng giả kim cƣơng và ống nano cacbon bằng phƣơng pháp lắng đọng hóa học (CVD) và phƣơng pháp lắng đọng hóa học kết hợp sóng micromet (MWCVD), Báo cáo tổng kết đề tài NCKH&CN cấp Viện Khoa học và Công nghệ Việt Nam 2 Hồ Ngọc Minh, Trần Nhƣ Thọ (2010), “Một số kết quả nghiên cứu độ bền ở nhiệt độ cao của vật liệu compozit phenolic/vải cacbon, sử dụng làm vật... lửa đẩy chế tạo bằng CCC đƣợc phủ ZrC trƣớc và sau thử nghiệm Error! Bookmark not defined Hình 2.1 Sơ đồ khối quá trình chế tạo mẫu vật liệu compozit cacbon- cacbonError! Bookmark Hình 2.2 Sơ đồ công nghệ nhiệt phân Error! Bookmark not defined Hình 2.3 Sơ đồ công nghệ CVI Error! Bookmark not defined Hình 2.4 Sơ đồ công nghệ graphit hóa Error! Bookmark not defined Hình 2.5 Sơ đồ công nghệ tổng... nhiệt trong môi trƣờng không khí của CNT ban đầu (a) và CNT biến tính (b) Error! Bookmark not defined Hình 3.7 Trạng thái của CNT trƣớc và sau biến tính với thời gian sa lắng khác nhau Error! Bookmark not defined Hình 3.8 Hình ảnh vải và sợi cacbon sử dụng để nghiên cứu chế tạo compozit cacbon- cacbon Error! Bookmark not defined Hình 3.9 Giản đồ phân tích nhiệt lƣợng vi sai của mẫu sợi. .. liệu compozit, NXB "Chế tạo máy", trang 319-323) 142 Мелешко А И., Половников С П (2007), Углерод, углеродные волокна, углеродные композиты, Москва "САЙНС-ПРЕСС", 176-183 с (Meleshko A I, Polivnhikov C P (2007), Cacbon, sợi cacbon, compozit cacbon, NXB "SAINZ-PRESS", trang 176-183) 143 Фитцер Э (1988), Углеродные волокна и композиты: пер с англ., Москва: Мир, 125-133 с (Fitzer E (1988), Sợi cacbon và compozit. .. electrical properties of aligned carbon nanotube/carbon matrix composites", Carbon 75, pp 307-313 Tiếng Nga 138 Бервено А (2002), Создание новых углерод-углеродных композиционных 27 материалов с применением углеродных нанотрубок, Москва, Из-во МГТУ им.Н.Э Баумана, 160-255 c (Berveno A (2002), Chế tạo vật liệu compozit cacbon- cacbon thế hệ mới sử dụng ống nano cacbon, NXB "MGTU Bauman N E.", trang 160-255)... 300; 400; 500; 600 và 700oC trong môi trƣờng không khíError! Bookmark not Hình 3.12 Ảnh FESEM bề mặt gẫy của compozit G-CF-CNT/P đƣợc chế tạo từ sợi cacbon ban đầu (Cf), và xử lý ở 300; 400; 500; 600 và 700oCError! Bookmark not defined Hình 3.13 Bột graphit dùng gia cƣờng chế tạo compozit cacbon- cacbonError! Bookmark no Hình 3.14 Ảnh SEM bột graphit với độ phóng đại khác nhauError! Bookmark not defined... nhiệt lƣợng vi sai của mẫu sợi cacbon trong môi trƣờng không khí Error! Bookmark not defined Hình 3.10 Ảnh FESEM bề mặt của sợi cacbon trƣớc xử lý (Cf), xử lý ở 300; 400; 500; 600 và 700oC trong môi trƣờng không khí Error! Bookmark not defined Hình 3.11 Phổ phân tích thành phần hoá học bề mặt của sợi cacbon trƣớc xử lý (Cf), xử lý ở 300; 400; 500; 600 và 700oC trong môi trƣờng không khíError!... c (Buranov I M., Vorobei V B (1998), Công nghệ các kết cấu tên lửa và hàng không vũ trụ từ vật liệu compozit, NXB "MGTU Bauman N E.", trang 318-392) 140 Бушуев Ю.Г., Персин М.И., Соколоь В.А (1994), Углерод-углеродные композиционные материалы Справочник, Москва, “Металлугия”, 68-82 c (Bushuev Yu G, Persin M I, Sokolov V A (1994), Sổ tay vật liệu compozit cacbon- cacbon, NXB "Luyện kim", trang 68-82)... nanotubes grafted on carbon fibres", Composites Part A 71, pp 168-175 30 Guixiang D., Chang S., Jianghong Z., Shouai F., Zhenping Z (2008), "Solidphase transformation of glass-like carbon nanoparticles into nanotubes and the related mechanism", Carbon 46, pp 92-98 31 Han S.J., Kim B., Suh K.D (2007), “Electrical properties of a composite film of poly(acrylonitrile) nanoparticles coated with carbon nanotubes”,