1 Chú ý VD1: CH3NH2 CH3NHCH3 hay (CH3)2NH • VD2: CH3NH2 3NHC2H5 • CnH2n+2+a–2kNa không A) CH3NH2 C) NH4Cl B) C3H7NH2 D) (C2H5)2NH A) C6H5COOH C) C6H5NH3Cl B) C6H5NH2 D) C6H5NO2 A) CH3NH2 C) C2H5NHCH3 B) (CH3)3N D) C2H5NH2 A) (CH3)3COH (CH3)3CNH2 B) (C6H5)2NH C6H5CH2OH C) (CH3)2CHOH (CH3)2CHNH2 D) C6H5NHCH3 C6H5CH(OH)CH3 A) CH3NH2 C) (CH3)3N B) CH3NHC2H5 D) C2H5NH2 A) CnH2nN C) CnH2n+2N B) CnH2n+1N D) CnH2n+3N A) CnH2n+1N C) CnH2nN B) CnH2n+1N D) CnH2n–2N A) CnH2n+1N2 C) CnH2n+4N2 B) CnH2n+2N2 D) CnH2n+3N2 nH2n+3 n (n < 5) 3H9N A) B) C) D) B) C) D) B) C) D) A 4H11N A) B x Hy A) C A) C3H9N C) C3H8O B) C3H7Cl D) C3H8 D 7H9N A) B) C) D) 2 Danh pháp C1: C2: VD3: CH3–CH–CH3 NH2 + "amin" –2–amin VD4: CH3NHC2H5 etylmetylamin (do e m) VD5: (CH3)2 NH2 • Anilin (hay phenylamin): (hay hexan–1,6 • E 3CH(NH2)CH2CH3 A) butan–2–amin C) propylamin F 3NHC2H5 A) metyletylamin C) etylmetylamin G 6H5NH2 H2N–(CH2)6–NH2 B) isobutylamin D) D) propylamin D) propan–2–amin A) anilin C) phenylamin B) phenol D) A) CH3NHCH2CH3 C) (CH3)3N B) (CH3)2CHNH2 D) CH3CH2CH2NH2 H 3 Chú ý — – hóa Chú ý Amin không no VD6: < Amoniac 6H5NH2 < Amin no < NH3 < CH3NH2 < (CH3)2NH – • • CH3NH2 + H2O CH3NH3+ + OH không C6H5NH2 + H2O không tím hóa xanh • hóa xanh • CH3NH2 + HCl CH3NH3+Cl C6H5NH2 + HCl C6H5NH3+Cl – RNH2 + HNO2 – HNO2 N2 + ROH + H2O VD7: CH3CH2CH2NH2 + HNO2 N2 + CH3CH2CH2OH + H2O I A) metylamin, anilin, amoniac B) amoniac, metylamin, anilin C) anilin, amoniac, metylamin D) anilin, metylamin, amoniac J (D A); metylamin (B E A) A < B < D < E < C C) A < D < B < C < E C); amoniac B) A < B < C < D < E D) E < C < B < D < A K A) C2H5NH2, (C2H5)2NH, NH3, C6H5NH2 B) (C2H5)2NH, NH3, C6H5NH2, C2H5NH2 C) C6H5NH2, NH3, (C2H5)2NH, C2H5NH2 D) C6H5NH2, NH3, C2H5NH2, (C2H5)2NH L (C2H5)2NH (4); NH3 (5 A) 3, 1, 5, 2, C) 4, 2, 3, 1, 6H5NH2 (1); C2H5NH2 (2); (C6H5)2NH (3); 6H5– B) 4, 1, 4, 2, D) 4, 2, 5, 1, M A) anilin, metylamin, amoniac B) C) D) metylamin, amoniac, natri axetat N A) (C6H5)2NH, C6H5NH2, NH3, C2H5NH2, (C2H5)2NH, NaOH B) C6H5NH2, (C6H5)2NH, NaOH, (C2H5)2NH, C2H5NH2, NH3 C) NaOH, (C2H5)2NH, C2H5NH2, NH3, C6H5NH2, (C6H5)2NH D) NaOH, (C2H5)2NH, C2H5NH2, C6H5NH2, (C6H5)2NH, NH3 O (A) CH3NH2 + HNO2 (B) H2N(CH2)6NH2 + HNO2 (C) CH3CH2CH2NH2 + HNO2 5 2 / HCl) – – 2 NH2 VD7: NH2 + 3Br2 Br Br + 3HBr Br VD8: NH3 + CH3I CH3NH2 + HI (CH3)2NH + HI CH3NH2 + CH3I VD9: C6H5NO2 Fe HCl to C6H5NH2 P 2: B) etylmetylamin D) trietylamin A) C) butylamin Q A) B) C) D) R A) B) C) D) S A) C2H5OH, HCHO C) CH3OH, HCHO CH3 I (1:1) X HNO2 Y CuO to Z B) C2H5OH, CH3CHO D) CH3OH, HCOOH T Benzen HNO3 H2SO4 ,to Nitrobenzen Fe HCl Anilin A) 186 gam C) 93 gam B) 55,8 gam D) 111,6 gam A) 346,7 gam C) 436,4 gam B) 362,7 gam D) 358,7 gam U Câu C Câu G D B H B C I C D J C B K D D L D A M D C N C C O A D P C B C Q C C A R B D D S C E A T B F C U B O (a) CH3NH2 + HNO2 CH3OH + N2 + H2O (b) H2N(CH2)6NH2 + 2HNO2 HO(CH2)6OH + 2N2 + 2H2O (c) CH3CH2CH2NH2 + HNO2 CH3CH2CH2OH + N2 + H2O