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Micromachining of silicon via ION irradiation with porous silicon formation 1

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Chapter ■♥tr♦❞✉❝t✐♦♥ ✶✳✶ ▼♦t✐✈❛t✐♦♥ ❙✐❧✐❝♦♥ ❤❛s ❜❡❡♥ ❢♦r t❤❡ ♣❛st ❢❡✇ ❞❡❝❛❞❡s✱ t❤❡ ♣r❡❢❡rr❡❞ ♠❛t❡r✐❛❧ ❢♦r t❤❡ ♠✐❝r♦❡❧❡❝tr♦♥✐❝s ✐♥❞✉str② ❧❛r❣❡❧② ❜❡❝❛✉s❡ ✐ts ♥❛t✐✈❡ ♦①✐❞❡ ♠❛② ❜❡ ❣r♦✇♥ ❡❛s✐❧② ❛♥❞ ✐s ✈❡r② st❛❜❧❡ ❝♦♠♣❛r❡❞ t♦ t❤❡ ♦①✐❞❡ ♦❢ ♦t❤❡r s❡♠✐❝♦♥❞✉❝t♦r ♠❛t❡r✐❛❧s✳ ■ts ♦①✐❞❡ ❢♦r♠s ✈❡r② ❣♦♦❞ s❡♠✐❝♦♥❞✉❝t♦r ❛♥❞ ❞✐❡❧❡❝tr✐❝ ✐♥t❡r❢❛❝❡s ✇❤✐❝❤ ✐s ❛♥ ✐♠♣♦rt❛♥t ❝♦♥s✐❞❡r❛t✐♦♥ ❢♦r ♠❛♥② ❞❡✈✐❝❡s✳ ■♥ ❛❞❞✐t✐♦♥ t♦ t❤❡s❡✱ ✐ts ❧♦✇ ❝♦st✱ ❛♠❡♥❛❜✐❧✐t② t♦ ❧✐t❤♦❣r❛♣❤✐❝ ♣❛tt❡r♥✐♥❣✱ ❛♥❞ ❝♦♠♣❛t✐❜✐❧✐t② ✇✐t❤ ♠❛ss ♣r♦❞✉❝t✐♦♥ t❡❝❤♥✐q✉❡s ♠❛❞❡ ✐t ❡✈❡♥ ♠♦r❡ ♣♦♣✉❧❛r✳ ❆s ❛ r❡s✉❧t✱ ♠✉❝❤ ❡☛♦rts ❤❛✈❡ ❜❡❡♥ ♣✉t ✐♥t♦ ❞❡✈❡❧♦♣✐♥❣ t❡❝❤♥✐q✉❡s t♦ ♠❛❝❤✐♥❡ s✐❧✐❝♦♥ ✐♥t♦ ✈❛r✐♦✉s str✉❝t✉r❡s ❛♥❞ ❞❡✈✐❝❡s ❢♦r ❞✐☛❡r❡♥t ❛♣♣❧✐❝❛t✐♦♥s ✐♥ t❤❡ ❧❛st ❢❡✇ ❞❡❝❛❞❡s✳ ❚♦ ❞❛t❡✱ t❤❡r❡ ❡①✐st ♠❛♥② ❞✐☛❡r❡♥t ❦✐♥❞s ♦❢ t❡❝❤♥✐q✉❡s ❛♥❞ t♦♦❧s ❛✈❛✐❧❛❜❧❡ t♦ ♠❛❝❤✐♥❡ s✐❧✐❝♦♥✳ ❍♦✇❡✈❡r✱ t❤❡s❡ t❡❝❤♥✐q✉❡s ♦❢t❡♥ r❡q✉✐r❡s ♠❛♥② ❝♦♠♣❧✐❝❛t❡❞ st❡♣s✱ ❛r❡ t✐♠❡ ❝♦♥s✉♠✐♥❣ ❛♥❞ ♠❛② ❜❡ ❝♦st ✐♥❡☛❡❝t✐✈❡✳ ❚❤✐s ✐s ❡s♣❡❝✐❛❧❧② tr✉❡ ❢♦r t❤r❡❡ ❞✐♠❡♥s✐♦♥❛❧ ♠❛❝❤✐♥✐♥❣ t❡❝❤♥✐q✉❡s✳ ❚❤❡ ♠❛✐♥ ♠♦t✐✈❛t✐♦♥ ❢♦r t❤❡ ✇♦r❦ ❞❡s❝r✐❜❡ ✐♥ t❤✐s t❤❡s✐s ✐s t♦ ❞❡✈❡❧♦♣ ❛♥❞ ❡①♣❧♦r❡ t❤❡ ♠✐❝r♦♠❛❝❤✐♥✐♥❣ t❡❝❤♥✐q✉❡ ❢♦r s✐❧✐❝♦♥ ✐♥ ❛ s✐♠♣❧❡✱ ❞✐r❡❝t ❛♥❞ ❝♦st ❡☛❡❝t✐✈❡ ✇❛②✱ ✉s✐♥❣ ✐♦♥ ✐rr❛❞✐❛t✐♦♥ ❛♥❞ t❤❡ ❢♦r♠❛t✐♦♥ ♦❢ ♣♦r♦✉s s✐❧✐❝♦♥✳ ✶ ✷ ✶✳✷ ❖❜❥❡❝t✐✈❡ ❚❤❡ ♠❛✐♥ ♦❜❥❡❝t✐✈❡ ♦❢ t❤✐s t❤❡s✐s ✐s t♦ ❞❡✈❡❧♦♣ ❛ ♥♦✈❡❧ ♠❡t❤♦❞ ❢♦r t✇♦ ❛♥❞ t❤r❡❡ ❞✐♠❡♥✲ s✐♦♥❛❧ ♠✐❝r♦✲♠❛❝❤✐♥✐♥❣ ♦❢ s✐❧✐❝♦♥ ❛♥❞ ♣♦r♦✉s s✐❧✐❝♦♥ str✉❝t✉r❡s ✉s✐♥❣ ✐♦♥ ❜❡❛♠ ✐rr❛❞✐❛t✐♦♥ t♦❣❡t❤❡r ✇✐t❤ t❤❡ ❢♦r♠❛t✐♦♥ ♦❢ ♣♦r♦✉s s✐❧✐❝♦♥✳ ❚❤✐s t❤❡s✐s ❛❧s♦ ❛✐♠s t♦ ❛♣♣❧② t❤✐s ♠✐❝r♦✲ ♠❛❝❤✐♥✐♥❣ ♠❡t❤♦❞ ❢♦r t❤❡ ❢❛❜r✐❝❛t✐♦♥ ♦❢ ✈❛r✐♦✉s ❞❡✈✐❝❡s ❛♥❞ str✉❝t✉r❡s ❢♦r ❛♣♣❧✐❝❛t✐♦♥s ✐♥ ☞❡❧❞s ❧✐❦❡ s✐❧✐❝♦♥ ♣❤♦t♦♥✐❝s✱ ♦♣t♦❡❧❡❝tr♦♥✐❝s ❛♥❞ ♠✐❝r♦❡❧❡❝tr♦♠❡❝❤❛♥✐❝❛❧ s②st❡♠s ✭▼❊▼❙✮✳ ✶✳✸ ❚❤❡s✐s ❖✉t❧✐♥❡ ❚❤✐s t❤❡s✐s ✐s ❞✐✈✐❞❡❞ ✐♥t♦ t❤r❡❡ ♠❛✐♥ ♣❛rts✳ ❈❤❛♣t❡r ✶ ❛♥❞ ✷ ❢♦r♠ t❤❡ ☞rst ♣❛rt ♦❢ t❤✐s t❤❡s✐s✳ ❈❤❛♣t❡r ✶ ❞❡s❝r✐❜❡s t❤❡ ♠♦t✐✈❛t✐♦♥ ❛♥❞ ♦❜❥❡❝t✐✈❡s ♦❢ t❤✐s t❤❡s✐s ✇❤✐❧❡ ❝❤❛♣t❡r ✷ ✐♥tr♦❞✉❝❡s ♣♦r♦✉s s✐❧✐❝♦♥ ❛s ❛ ♠❛t❡r✐❛❧ ❛s ✇❡❧❧ ❛s t❤❡ ♣r✐♥❝✐♣❧❡s ❛♥❞ t❤❡♦r② ♦❢ t❤❡ ❢♦r♠❛t✐♦♥ ♦❢ ♣♦r♦✉s s✐❧✐❝♦♥✳ ❚❤❡ ✐♦♥ ❜❡❛♠ ❛❝❝❡❧❡r❛t♦r ❢❛❝✐❧✐t✐❡s✱ ✐ts t❡❝❤♥✐❝❛❧ ❛s♣❡❝ts ❛♥❞ ❝❛♣❛❜✐❧✐t✐❡s ❛r❡ ❛❧s♦ ❞❡s❝r✐❜❡❞✳ ❈❤❛♣t❡r ✸ ❛♥❞ ✹ ❢♦r♠ t❤❡ s❡❝♦♥❞ ♣❛rt ♦❢ t❤✐s t❤❡s✐s✳ ❚❤❡s❡ t✇♦ ❝❤❛♣t❡rs s✉♠♠❛r✐③❡ t❤❡ ✈❛r✐♦✉s ❣❡♥❡r❛❧ ❝❤❛r❛❝t❡r✐③❛t✐♦♥s ❛♥❞ ❢✉♥❞❛♠❡♥t❛❧ st✉❞✐❡s ✇❤✐❝❤ ✇❡r❡ ❝❛rr✐❡❞ ♦✉t✳ ❚❤❡② ✐♥❝❧✉❞❡ t❤❡ ❛♥♦❞✐③❛t✐♦♥ s❡t✉♣ ❛♥❞ ♣r❡♣❛r❛t✐♦♥✱ ❝❤❛r❛❝t❡r✐③❛t✐♦♥ ♦❢ t❤❡ ✈❛r✐♦✉s ❛♥♦❞✐③❛t✐♦♥ ♣❛r❛♠❡t❡rs ❢♦r s✐❧✐❝♦♥ ✇❛❢❡rs ♦❢ ❞✐☛❡r❡♥t r❡s✐st✐✈✐t✐❡s ❛s ✇❡❧❧ ❛s t❤❡ ❝❤❛r❛❝t❡r✐③❛t✐♦♥ ♦❢ t❤❡ r❡❞✉❝❡❞ ♣♦r♦✉s s✐❧✐❝♦♥ ❢♦r♠❛t✐♦♥ r❛t❡ ❢♦r ✐rr❛❞✐❛t❡❞ s✐❧✐❝♦♥ ✇❛❢❡rs ♦❢ ❞✐☛❡r❡♥t r❡s✐st✐✈✐t✐❡s✳ ■♥ ❛❞❞✐t✐♦♥✱ ❛s t❤❡ r♦✉❣❤♥❡ss ♦❢ ♠✐❝r♦♠❛❝❤✐♥❡❞ s✐❧✐❝♦♥ str✉❝t✉r❡s ❛r❡ ♦❢t❡♥ ✈❡r② ✐♠♣♦rt❛♥t ❢♦r ♠❛♥② ❞✐☛❡r❡♥t ❛♣♣❧✐❝❛t✐♦♥s✱ ❛ ❞❡t❛✐❧❡❞ st✉❞② ♦❢ t❤❡ r♦✉❣❤♥❡ss ♦❢ t❤❡ s✐❧✐❝♦♥ str✉❝t✉r❡s ♠❛❝❤✐♥❡❞ ✉s✐♥❣ ✐♦♥ ❜❡❛♠ ✐rr❛❞✐❛t✐♦♥ ❛♥❞ ♣♦r♦✉s s✐❧✐❝♦♥ ❢♦r♠❛t✐♦♥ ✇❛s ❝❛rr✐❡❞ ♦✉t ❛♥❞ ✐s ♣r❡s❡♥t❡❞ ✐♥ ❝❤❛♣t❡r ✹✳ ❚❤❡ r❡s✉❧ts ❢r♦♠ t❤❡ ❝❤❛r❛❝t❡r✐③❛t✐♦♥ ❛♥❞ st✉❞✐❡s ❞♦♥❡ ✐♥ t❤✐s ♣❛rt ♦❢ t❤❡ t❤❡s✐s ✐s ✉s❡❞ ❡①t❡♥s✐✈❡❧② ❢♦r t❤❡ ❢❛❜r✐❝❛t✐♦♥ ♦❢ ✈❛r✐♦✉s str✉❝t✉r❡s ❞✐s❝✉ss❡❞ ✐♥ t❤❡ ❧❛st ♣❛rt ♦❢ t❤✐s t❤❡s✐s✳ ❈❤❛♣t❡r ✺✲✽ ❢♦r♠ t❤❡ ❧❛st ♣❛rt ♦❢ t❤✐s t❤❡s✐s✳ ❊❛❝❤ ❝❤❛♣t❡r ♣r❡s❡♥ts t❤❡ ✈❛r✐♦✉s s✐❧✐❝♦♥ ♦r ♣♦r♦✉s s✐❧✐❝♦♥ str✉❝t✉r❡s ❛♥❞ ❞❡✈✐❝❡s ✇❤✐❝❤ ✇❡r❡ ❢❛❜r✐❝❛t❡❞ ✉s✐♥❣ t❤✐s t❡❝❤♥✐q✉❡ ♦❢ ♠✐❝r♦✲♠❛❝❤✐♥✐♥❣ s✐❧✐❝♦♥✳ ❊❛❝❤ ❝❤❛♣t❡r ❞✐s❝✉ss❡s t❤❡ ❞❡t❛✐❧s ✐♥✈♦❧✈❡❞ ✐♥ t❤❡ ❡①♣❡r✐♠❡♥t❛❧ ❛♥❞ ❢❛❜r✐❝❛t✐♦♥ ♣r♦❝❡ss❡s ❛♥❞ ♣r❡s❡♥ts t❤❡ r❡s✉❧ts ❢♦r ❞✐☛❡r❡♥t s✐❧✐❝♦♥ str✉❝t✉r❡s ❛♥❞ ❞❡✈✐❝❡s r❡s♣❡❝t✐✈❡❧②✳ Chapter ❇❛❝❦❣r♦✉♥❞ ❚❤✐s ❝❤❛♣t❡r ♣r♦✈✐❞❡s r❡❧❡✈❛♥t ❜❛❝❦❣r♦✉♥❞ ✐♥❢♦r♠❛t✐♦♥ ♦♥ ✈❛r✐♦✉s t♦♣✐❝s ❡ss❡♥t✐❛❧ ❢♦r ❜❡t✲ t❡r ✉♥❞❡rst❛♥❞✐♥❣ ♦❢ t❤❡ ❡①♣❡r✐♠❡♥t❛❧ ✇♦r❦ ✇❤✐❝❤ ✇✐❧❧ ❜❡ ❞✐s❝✉ss❡❞ ✐♥ ❧❛t❡r ❝❤❛♣t❡rs✳ ❋✐rst❧②✱ ❛ s❤♦rt ❤✐st♦r② ❛♥❞ t❤❡ ❢♦r♠❛t✐♦♥ ♠❡❝❤❛♥✐s♠ ♦❢ ♣♦r♦✉s s✐❧✐❝♦♥ ✇✐❧❧ ❜❡ ❞✐s❝✉ss❡❞✱ ❢♦❧❧♦✇❡❞ ❜② ❛ s✉♠♠❛r② ♦♥ t❤❡ t②♣❡s ♦❢ ✐♦♥ ❜❡❛♠ ✐rr❛❞✐❛t✐♦♥ ❢❛❝✐❧✐t✐❡s ❛♥❞ t❡❝❤♥✐q✉❡s ✇❤✐❝❤ ✇❡r❡ ✉s❡❞ ❢♦r t❤❡ ✇♦r❦ ✐♥ t❤✐s t❤❡s✐s✳ Pr❡✈✐♦✉s ✇♦r❦ ♦♥ ✐♦♥ ✐rr❛❞✐❛t✐♦♥ ♦♥ s✐❧✐❝♦♥ ✐s ❛❧s♦ ❜r✐❡✌② ❞✐s❝✉ss❡❞✳ ▲❛st❧②✱ ❛ s❤♦rt r❡✈✐❡✇ ♦♥ ❡①✐st✐♥❣ s✐❧✐❝♦♥ ♠✐❝r♦♠❛❝❤✐♥✐♥❣ t❡❝❤♥✐q✉❡s ✇✐❧❧ ❜❡ ❜r✐❡✌② ♣r❡s❡♥t❡❞✳ ✷✳✶ ■♥tr♦❞✉❝✐♥❣ ♣♦r♦✉s s✐❧✐❝♦♥ P♦r♦✉s s✐❧✐❝♦♥ ✭P❙✐✮ ✇❛s ❞✐s❝♦✈❡r❡❞ ❜② ❛❝❝✐❞❡♥t ✐♥ ✶✾✺✻ ❜② ❯❤❧✐r ❬✶❪ ❛t t❤❡ ❇❡❧❧ ▲❛❜♦r❛t♦✲ r✐❡s ✇❤❡♥ ❤❡ ✇❛s ❝❛rr②✐♥❣ ♦✉t ❡❧❡❝tr♦♣♦❧✐s❤✐♥❣ ❡①♣❡r✐♠❡♥ts ♦♥ s✐❧✐❝♦♥ ✇✐t❤ ❛♥ ❡❧❡❝tr♦❧②t❡ ❝♦♥t❛✐♥✐♥❣ ❤②❞r♦✌✉♦r✐❝ ❛❝✐❞ ✭❍❋✮✳ ❆t ❛ ❧♦✇ ❛♣♣❧✐❡❞ ❜✐❛s✱ t❤❡ ♥♦♥✲✉♥✐❢♦r♠ ❡t❝❤✐♥❣ ♦❢ s✐❧✐✲ ❝♦♥ r❡s✉❧t❡❞ ✐♥ ❛ s②st❡♠ ♦❢ ❞✐s♦r❞❡r❡❞ ♣♦r❡s ✇✐t❤ ♥❛♥♦❝r②st❛❧s r❡♠❛✐♥✐♥❣ ✐♥ t❤❡ ✐♥t❡r✲♣♦r❡ r❡❣✐♦♥s✳ ❆s t❤❡s❡ ❞✐❞ ♥♦t ♣r♦❞✉❝❡ ❛ s♠♦♦t❤ ♣♦❧✐s❤❡❞ s✉r❢❛❝❡ ❛s ❞❡s✐r❡❞✱ t❤❡ r❡s✉❧ts ✇❡r❡ ♠❡r❡❧② r❡♣♦rt❡❞ ✐♥ ❛ s♠❛❧❧ ❇❡❧❧ ▲❛❜s t❡❝❤♥✐❝❛❧ ♥♦t❡✳ ■♥ t❤❡ ✶✾✽✵s✱ t❤❡ ♠❛✐♥ ❢♦❝✉s ♦❢ P❙✐ r❡s❡❛r❝❤ ✇❛s t♦ ✉s❡ ✐t t♦ ❞❡✈❡❧♦♣ s✐❧✐❝♦♥ ♦♥ ✐♥s✉❧❛t♦r ✭❙❖■✮ t❡❝❤♥♦❧♦❣✐❡s ❢♦r ❞❡✈✐❝❡ ✐s♦❧❛t✐♦♥ ✐♥ ✐♥t❡❣r❛t❡❞ ❝✐r❝✉✐ts ❬✷❪✳ ❚❤❡s❡ ✇❡r❡ ❞❡✈❡❧♦♣❡❞ ❛s ❛♥ ❛❧t❡r♥❛t✐✈❡ t♦ t❤❡ ❝♦♥✈❡♥t✐♦♥❛❧ ♠❡t❤♦❞s ♦❢ ✐s♦❧❛t✐♦♥ ❜② ❞♦♣❡❞ ❝❤❛♥♥❡❧✲st♦♣s ❛♥❞ t❤✐❝❦ ✸ ✹ ❞✐❡❧❡❝tr✐❝ ❧❛②❡rs✳ ❚❤❡ ✉s❛❣❡ ♦❢ ❢✉❧❧ ✐s♦❧❛t✐♦♥ ❜② ♣♦r♦✉s ♦①✐❞✐s❡❞ s✐❧✐❝♦♥ ✭❋■P❖❙✮ t♦ ❢❛❜r✐❝❛t❡ ❙❖■ ♦☛❡rs t❤❡ s❛♠❡ ❛❞✈❛♥t❛❣❡s ❛s ❝♦♥✈❡♥t✐♦♥❛❧ ❙❖■ ✇✐t❤ ❛ r❡❞✉❝❡❞ ♥✉♠❜❡r ♦❢ ❢❛❜r✐❝❛t✐♦♥ st❡♣s ❬✸❪✳ P❙✐ ❜❡❝❛♠❡ ♠♦r❡ ♣♦♣✉❧❛r ❛s ❛ ♠❛t❡r✐❛❧ ✐♥ ✶✾✾✵✱ ✇❤❡♥ ▲❡✐❣❤ ❈❛♥❤❛♠ ❛t t❤❡ ❉❡❢❡♥s❡ ❘❡s❡❛r❝❤ ❆❣❡♥❝② ✭▼❛❧✈❡r♥✱ ❯❑✮ r❡♣♦rt❡❞ t❤❡ ❡✍❝✐❡♥t ❡♠✐ss✐♦♥ ♦❢ ✈✐s✐❜❧❡ ❧✐❣❤t ♣❤♦t♦❧✉✲ ♠✐♥❡s❝❡♥❝❡ ❛t r♦♦♠ t❡♠♣❡r❛t✉r❡ ❬✹❪✱ ❞✉❡ t♦ q✉❛♥t✉♠ ❝♦♥☞♥❡♠❡♥t ❡☛❡❝ts ♣r♦❞✉❝❡❞ ❛s ❛ r❡s✉❧t ♦❢ t❤❡ ❧♦✇ ❞✐♠❡♥s✐♦♥❛❧✐t② ♦❢ t❤❡ s✐❧✐❝♦♥ s❦❡❧❡t♦♥ r❡♠❛✐♥✐♥❣ ❛❢t❡r ❡❧❡❝tr♦❝❤❡♠✐✲ ❝❛❧ ❛♥♦❞✐③❛t✐♦♥✳ ❇✉❧❦ s✐❧✐❝♦♥ ❤❛s ❛♥ ✐♥❞✐r❡❝t ❜❛♥❞ ❣❛♣ ❛♥❞ ❛s ❛ r❡s✉❧t ✐t ❞♦❡s ♥♦t ❡♠✐t ❧✐❣❤t ❡✍❝✐❡♥t❧②✳ P❙✐ ♣❤♦t♦❧✉♠✐♥❡s❝❡♥❝❡✱ ♦r ❧✉♠✐♥❡s❝❡♥❝❡ ❜② ♣❤♦t♦♥ ❡①❝✐t❛t✐♦♥✱ ✇❛s t❤✉s ❝♦♥s✐❞❡r❡❞ ❛ ❣r❡❛t ❞✐s❝♦✈❡r②✳ ❊❧❡❝tr♦❧✉♠✐♥❡s❝❡♥❝❡ ✇❛s s✉❜s❡q✉❡♥t❧② r❡♣♦rt❡❞ ❛s ✇❡❧❧ ❬✺❪✳ ■♥t❡r❡st ✐♥ t❤❡ ♠❛t❡r✐❛❧ ❡①♣❧♦❞❡❞ ❞✉❡ t♦ t❤❡ ♣♦ss✐❜✐❧✐t② ♦❢ ♣✉r❡❧② s✐❧✐❝♦♥✲❜❛s❡❞ ♦♣t♦❡❧❡❝✲ tr♦♥✐❝ s✇✐t❝❤❡s✱ ❞✐s♣❧❛②s✱ ❛♥❞ ❧❛s❡rs✳ ❚❤❡ ♣r♦♣❡rt✐❡s ♦❢ P❙✐ ❤❛✈❡ ❜❡❡♥ ✐♥t❡♥s✐✈❡❧② st✉❞✐❡❞ ❢♦r t❤❡ ♣❛st ❞❡❝❛❞❡ ❛♥❞ ✐t ❤❛s ❢♦✉♥❞ ❛♣♣❧✐❝❛t✐♦♥s ✐♥ ♠❛♥② ❛r❡❛s ❧✐❦❡ ♣❤♦t♦♥✐❝s ❬✻✱ ✼❪✱ s✐❧✐❝♦♥ ❜❛s❡❞ ✇❛✈❡❣✉✐❞❡ ❬✽④✶✵❪✱ s✐❧✐❝♦♥ ♠✐❝r♦♠❛❝❤✐♥✐♥❣ ✈✐❛ s❛❝r✐☞❝✐❛❧ P❙✐ ❬✶✶✱ ✶✷❪ ❛♥❞ t❤❡r❡ ✐s ❡✈❡♥ ❛❝t✐✈❡ ♦♥❣♦✐♥❣ r❡s❡❛r❝❤ ❢♦r P❙✐ t♦ t❛❦❡ t❤❡ r♦❧❡ ♦❢ ❜✐♦s❡♥s♦rs ✐♥ ❜✐♦t❡❝❤♥♦❧♦❣② ❬✶✸④✶✺❪✳ ❚❤❡ ✇♦r❦ ✐♥ t❤✐s t❤❡s✐s r❡✈♦❧✈❡s ❛r♦✉♥❞ ♠❛❝❤✐♥✐♥❣ P❙✐ str✉❝t✉r❡s ❢♦r ✈❛r✐♦✉s ❛♣♣❧✐❝❛t✐♦♥s ❛s ✇❡❧❧ ❛s ✉s✐♥❣ P❙✐ ❛s ❛ s❛❝r✐☞❝✐❛❧ ♠❛t❡r✐❛❧ ❢♦r t❤❡ ♠❛❝❤✐♥✐♥❣ ♦❢ s✐❧✐❝♦♥ str✉❝t✉r❡s✳ ✷✳✶✳✶ ❊❧❡❝tr♦❝❤❡♠✐❝❛❧ ❛♥♦❞✐③❛t✐♦♥ P❙✐ ✐s ❝r❡❛t❡❞ ✈✐❛ ❡❧❡❝tr♦❝❤❡♠✐❝❛❧ ❛♥♦❞✐③❛t✐♦♥ ✐♥ ❛ ❍❋ s♦❧✉t✐♦♥ t♦❣❡t❤❡r ✇✐t❤ ❛ ♣❧❛t✐♥✉♠ ❡❧❡❝tr♦❞❡✳ P❧❛t✐♥✉♠ ✐s ✉s❡❞ ❛s ✐t ❞♦❡s ♥♦t r❡❛❝t ✇✐t❤ ❍❋✳ ❚❤❡ ❢♦r♠❛t✐♦♥ ✐s ❡❧❡❝tr♦❝❤❡♠✐❝❛❧ ✐♥ ♥❛t✉r❡ ❛♥❞ P❙✐ ❢♦r♠s ♦♥❧② ✐♥ t❤❡ ♣r❡s❡♥❝❡ ♦❢ ❡❧❡❝tr✐❝❛❧ ❤♦❧❡s✳ ❚❤❡ t②♣❡ ♦❢ ♣♦r❡s ♣r♦❞✉❝❡❞ ❝❛♥ ❜❡ ❣r♦✉♣❡❞ ✐♥t♦ ✸ ❝❛t❡❣♦r✐❡s ❛❝❝♦r❞✐♥❣ t♦ t❤❡✐r ♣♦r❡ ❣❡♦♠❡tr✐❡s✳ ❚❤❡② ❛r❡ ♠✐❝r♦♣♦r❡s ✭❁✶✵♥♠✮✱ ♠❡s♦♣♦r❡s✭✶✵✲✺✵♥♠✮ ❛♥❞ ♠❛❝r♦♣♦r❡s ✭❃✺✵♥♠✮ ❬✶✻❪ ❛♥❞ t❤❡ t②♣❡ ♦❢ ♣♦r❡s ❢♦r♠❡❞ ❞❡♣❡♥❞s ❧❛r❣❡❧② ♦♥ t❤❡ r❡s✐st✐✈✐t② t②♣❡ ♦❢ t❤❡ s✐❧✐❝♦♥ ✇❛❢❡rs❀ ❧♦✇ r❡s✐st✐✈✐t② s✐❧✐❝♦♥ ✇❛❢❡rs ✭❁✵✳✶ ✡✳❝♠✮ ❢♦r♠s ♠❡s♦♣♦r❡s✱ ♠♦❞❡r❛t❡ r❡s✐st✐✈✐t② ✇❛❢❡rs ✭✵✳✶✲✺✵ ✡✳❝♠✮ ❢♦r♠ ♠✐❝r♦♣♦r❡s ✇❤✐❧❡ ❤✐❣❤ r❡s✐st✐✈✐t② ✇❛❢❡rs ✭❃✺✵ ✡✳❝♠✮ ❢♦r♠ ♠❛❝r♦♣♦r❡s✳ ❍♦✇❡✈❡r✱ ❥✉st ❍❋ ❛❧♦♥❡ ✐s ✉♥s✉✐t❛❜❧❡ ❢♦r t❤❡ ❡❧❡❝tr♦❝❤❡♠✐❝❛❧ ❡t❝❤✐♥❣ ♣r♦❝❡ss ❛s t❤❡ s✐❧✐❝♦♥ s✉r❢❛❝❡ ✐s ❤②❞r♦♣❤♦❜✐❝✳ ✼ ❚❤✐s ❝❤❛✐♥ ♦❢ r❡❛❝t✐♦♥s t❤❡♥ ♦❝❝✉rs t♦ ♦t❤❡r s✉rr♦✉♥❞✐♥❣ s✐❧✐❝♦♥ ❛t♦♠s✱ ❡☛❡❝t✐✈❡❧② ❜r❡❛❦✐♥❣ ❞♦✇♥ t❤❡ s✐❧✐❝♦♥ str✉❝t✉r❡ ♦♥ t❤❡ s✉r❢❛❝❡ ♦❢ t❤❡ s✉❜str❛t❡ ❛♥❞ ♣♦r❡s st❛rts t♦ ❢♦r♠✳ ✷✳✶✳✸ ❋♦r♠❛t✐♦♥ ♦❢ ♣❛ss✐✈❛t❡❞ ❧❛②❡r ❋✐❣✉r❡ ✷✳✸✿ ✭❛✮ ❊♥❧❛r❣❡♠❡♥t ♦❢ t❤❡ s✐❧✐❝♦♥ ❜❛♥❞❣❛♣ ❛r✐s✐♥❣ ❢r♦♠ q✉❛♥t✉♠ ❝♦♥☞♥❡♠❡♥t ❡☛❡❝t ❛s t❤❡ r❡♠❛✐♥✐♥❣ s✐❧✐❝♦♥ ✐s❧❛♥❞s ❣❡ts s♠❛❧❧❡r✳ ❋r♦♠ ❬✶✻❪✳ ✭❜✮ ■✲❱ ♣❧♦ts s❤♦✇✐♥❣ r❡❣✐♦♥s ♦❢ P❙✐ ❢♦r♠❛t✐♦♥ ❛♥❞ r❡❣✐♦♥ ♦❢ ❡❧❡❝tr♦♣♦❧✐s❤✐♥❣✳ ❆t s♠❛❧❧ ❛♣♣❧✐❡❞ ❜✐❛s✱ ❢♦r♠❛t✐♦♥ ♦❢ P❙✐ ♦❝❝✉rs✱ ❤♦✇❡✈❡r✱ ❜❡②♦♥❞ t❤❡ ❝r✐t✐❝❛❧ ✈♦❧t❛❣❡ ✈❛❧✉❡✱ ❡❧❡❝tr♦♣♦❧✐s❤✐♥❣ t❛❦❡s ♦✈❡r✳ ❋r♦♠ ❬✶✾❪ ❚❤❡ ♣r❡✈✐♦✉s s❡❝t✐♦♥ ❡①♣❧❛✐♥s t❤❡ ♠❡❝❤❛♥✐s♠ ❢♦r s✐❧✐❝♦♥ r❡♠♦✈❛❧✴❞✐ss♦❧✉t✐♦♥✱ ❤♦✇❡✈❡r✱ ✐t ❞♦❡s ♥♦t ❡①♣❧❛✐♥ ✇❤② t❤❡ ❞✐ss♦❧✉t✐♦♥ st♦♣s ❛♥❞ ❢♦r♠s ❛ ♣♦r♦✉s ❧❛②❡r ✐♥st❡❛❞ ♦❢ t❤❡ ✽ ❝♦♠♣❧❡t❡ r❡♠♦✈❛❧ ♦❢ s✐❧✐❝♦♥ ❛t♦♠s ❢r♦♠ t❤❡ s✉r❢❛❝❡ ✭❡❧❡❝r♦♣♦❧✐s❤✐♥❣✮✳ ❋♦r ♣♦r❡ ❢♦r♠❛t✐♦♥✱ ✐t ✐s ❜❡❧✐❡✈❡❞ t♦ ❜❡ t❤❡ r❡s✉❧t ♦❢ t❤❡ ❞❡✈❡❧♦♣♠❡♥t ♦❢ ❛ ♣❛ss✐✈❛t✐♦♥ ✭❝❤❡♠✐❝❛❧❧② ✐♥❛❝t✐✈❡✮ ❧❛②❡r✳ ❍❡r❡✱ ♣❛ss✐✈❛t✐♦♥ ♦❢ t❤❡ P❙✐ ❧❛②❡r ✐s ❝❛✉s❡❞ ❜② q✉❛♥t✉♠ ❝♦♥☞♥❡♠❡♥t ❡☛❡❝ts ❛r✐s✐♥❣ ❢r♦♠ t❤❡ r❡♠❛✐♥✐♥❣ s✐❧✐❝♦♥ ✐s❧❛♥❞s ❛❢t❡r t❤❡ ✐♥✐t✐❛❧ r❡♠♦✈❛❧ ♦❢ s♦♠❡ s✐❧✐❝♦♥ ❛t♦♠s✳ ❆s s✐❧✐❝♦♥ ❛t♦♠s ❛r❡ ❝♦♥t✐♥✉❛❧❧② r❡♠♦✈❡❞ ❛t t❤❡ s✉r❢❛❝❡✱ ♣♦r❡s✴✈♦✐❞s ❛r❡ ❢♦r♠❡❞✳ ❚❤❡ s♠❛❧❧ s✐③❡ ♦❢ t❤❡ r❡♠❛✐♥✐♥❣ s✐❧✐❝♦♥ ✐s❧❛♥❞s ✐♥❞✉❝❡s ❛ q✉❛♥t✉♠ ❝♦♥☞♥❡♠❡♥t ❡☛❡❝t✳ ◗✉❛♥t✉♠ ❝♦♥☞♥❡♠❡♥t r❡s✉❧ts ✐♥ t❤❡ q✉❛♥t✐③❛t✐♦♥ ♦❢ ❡♥❡r❣② ♦❢ ❜♦t❤ t❤❡ ❡❧❡❝tr♦♥s ❛♥❞ ❤♦❧❡s✳ ❚❤❡ ❛♣♣❡❛r❛♥❝❡ ♦❢ ❜♦✉♥❞ st❛t❡s ❢♦r ❤♦❧❡s r❡s✉❧ts ✐♥ t❤❡ ❧♦✇❡r✐♥❣ ♦❢ t❤❡ ✈❛❧❡♥❝❡ ❜❛♥❞ ♠❛①✐♠✉♠ ✇❤✐❧❡ t❤❡ ❛♣♣❡❛r❛♥❝❡ ♦❢ ❜♦✉♥❞ st❛t❡s ❢♦r ❡❧❡❝tr♦♥s ❤❡✐❣❤t❡♥s t❤❡ ❝♦♥❞✉❝t✐♦♥ ❜❛♥❞ ♠✐♥✐♠✉♠ ✭❋✐❣ ✷✳✸✭❛✮✮✳ ❚❤✐s ❡☛❡❝t✐✈❡❧② ♠❡❛♥s t❤❡ ❡♥❧❛r❣❡♠❡♥t ♦❢ t❤❡ s✐❧✐❝♦♥ ❜❛♥❞ ❣❛♣ ❬✶✾❪✳ ❆ s♠❛❧❧ ♣♦t❡♥t✐❛❧ ❜❛rr✐❡r ✐s t❤✉s s❡t ✉♣ ❛t t❤❡ ✐♥t❡r❢❛❝❡ ❜❡t✇❡❡♥ t❤❡ ❜✉❧❦ s✐❧✐❝♦♥ ❛♥❞ t❤❡ ❜♦tt♦♠ ♦❢ t❤❡ ♣♦r♦✉s ❧❛②❡r✳ ❊❧❡❝tr✐❝ ❤♦❧❡s✱ ✇❤✐❝❤ ❛r❡ r❡q✉✐r❡❞ t♦ ❢❛❝✐❧✐t❛t❡ t❤❡ ♥✉❝❧❡♦♣❤✐❧✐❝ ❛tt❛❝❦s ♦♥ t❤❡ s✐❧✐❝♦♥ ❛t♦♠s ❜② ✌✉♦r✐♥❡ ❛t♦♠s✱ ♥♦✇ ♥❡❡❞ ♠♦r❡ ❡♥❡r❣② ❥✉st t♦ ♦✈❡r❝♦♠❡ t❤❛t ❜❛rr✐❡r✱ ✇❤✐❝❤ ✐s ❤✐❣❤❧② ✐♠♣r♦❜❛❜❧❡ ❣✐✈❡♥ ❛ ☞①❡❞ ❜✐❛s✳ ❚❤❡ ❤♦❧❡s ❛r❡ t❤✉s ♠♦r❡ ❧✐❦❡❧② ❛❝❝✉♠✉❧❛t❡ ❛t t❤❡ ♣♦r❡ t✐♣s r❛t❤❡r t❤❛♥ t♦ tr❛✈❡❧ ✐♥t♦ t❤❡ ♣♦r♦✉s ❧❛②❡r✳ ❍❡♥❝❡✱ s✐❧✐❝♦♥ ❛t♦♠ r❡♠♦✈❛❧ ♥♦✇ t❛❦❡s ♣❧❛❝❡ ❛t t❤❡ ♣♦r❡ t✐♣s r❛t❤❡r t❤❡♥ ❝♦♥t✐♥✉❡❞ r❡♠♦✈❛❧ ♦❢ s✐❧✐❝♦♥ ❢r♦♠ t❤❡ P❙✐ ❧❛②❡r✳ ❲✐t❤ ❝♦♥t✐♥✉❡❞ ❜✐❛s ❛♣♣❧✐❡❞✱ t❤❡ ♣♦r❡s ❣r♦✇ ❞❡❡♣❡r✳ ❲❤✐❧❡ t❤❡ ♣♦r❡ ✇❛❧❧s ❛r❡ ♣❛ss✐✈❛t❡❞✱ t❤❡ ♣♦r❡ t✐♣s ❝♦♥t✐♥✉❡s t♦ ❜❡ ❛❝t✐✈❡ ✐♥ t❤❡ ❞✐ss♦❧✉t✐♦♥ r❡❛❝t✐♦♥✳ ❚❤✐s ❤❛s t✇♦ ✐♠♣❧✐❝❛t✐♦♥s✳ ❋✐rst❧②✱ t❤❡ ❡❧❡❝tr♦❝❤❡♠✐❝❛❧ ❡t❝❤✐♥❣ ✐s s❡❧❢✲❧✐♠✐t✐♥❣ ❬✷✵❪❀ ♠❡❛♥✐♥❣ t❤❛t ✇❤❡♥ t❤❡ ❛♣♣❧✐❡❞ ❜✐❛s ✐s ♣❛✉s❡❞ ❛♥❞ r❡❛♣♣❧✐❡❞✱ s✐❧✐❝♦♥ r❡♠♦✈❛❧ ❝♦♥t✐♥✉❡s ❢r♦♠ ✇❤❡r❡ ✐t ❤❛❞ st♦♣♣❡❞ ♣r❡✈✐♦✉s❧②✳ ❙❡❝♦♥❞❧②✱ ❤♦❧❡ ❞❡♣❧❡t✐♦♥ ♦❝❝✉rs ✇❤❡♥ ❡✈❡r② ❤♦❧❡ t❤❛t r❡❛❝❤❡s t❤❡ s✉r❢❛❝❡ r❡❛❝ts ✐♠♠❡❞✐❛t❡❧②✳ ❚❤✉s✱ t❤❡ ❡t❝❤❡❞ ❧❛②❡r ✐s ❛❧✇❛②s ♣❛r❛❧❧❡❧ ❛♥❞ ❢♦❧❧♦✇s t❤❡ ♣r♦☞❧❡ ♦❢ t❤❡ s❛♠♣❧❡ s✉r❢❛❝❡✳ ❊✈✐❞❡♥t❧② t❤❡♥✱ t❤❡ ❡♥❡r❣② ✇❤✐❝❤ t❤❡ ❤♦❧❡s ❝❛rr✐❡s ✐♥✌✉❡♥❝❡s t❤❡ s✐③❡ ♦❢ t❤❡ ♣♦r❡s s✐♥❝❡ ✐t ❛☛❡❝ts t❤❡✐r ❛❜✐❧✐t② t♦ ♦✈❡r❝♦♠❡ t❤❡ ❜❛rr✐❡r✳ ❚❤✐s ❡♥❡r❣② ✐s ❞❡t❡r♠✐♥❡❞ ❜② t❤❡ ✈♦❧t❛❣❡ ❛♣♣❧✐❡❞ ✇❤❡♥ t❤❡ ❛♥♦❞✐③❛t✐♦♥ ♣r♦❝❡ss ✐s ❝❛rr✐❡❞ ♦✉t✳ ❇✐❣❣❡r ❛♣♣❧✐❡❞ ❜✐❛s ❣✐✈❡s r✐s❡ t♦ ♠♦r❡ ❡♥❡r❣❡t✐❝ ❤♦❧❡s ✇❤✐❝❤ r❡s✉❧ts ✐♥ t❤❡ ❢♦r♠❛t✐♦♥ ♦❢ ❜✐❣❣❡r ♣♦r❡s✳ ❍❡♥❝❡✱ t❤❡r❡ ❡①✐sts ❛ ❝r✐t✐❝❛❧ ❛♥♦❞✐③❛t✐♦♥ ✈♦❧t❛❣❡ ❛❜♦✈❡ ✇❤✐❝❤ ♣❛rt✐❛❧ ❞✐ss♦❧✉t✐♦♥ ❝❡❛s❡s ❛♥❞ ❡❧❡❝tr♦♣♦❧✐s❤✐♥❣ ✾ t❛❦❡s ♦✈❡r✳ ❋♦r ✈♦❧t❛❣❡s ❛❜♦✈❡ s✉❝❤ ❛ ✈❛❧✉❡✱ t❤❡ s✉r❢❛❝❡ ✐s ☞❧❧❡❞ ✇✐t❤ ❤♦❧❡s ❛♥❞ t❤✐s ❧❡❛❞s t♦ ❛ ❝♦♠♣❧❡t❡ r❡♠♦✈❛❧ ♦❢ s✐❧✐❝♦♥ ❛t♦♠s ❢r♦♠ t❤❡ s✉r❢❛❝❡ ✭❋✐❣ ✷✳✸✭❜✮✮✳ ❚❤✐s ❜❡❤❛✈✐♦r ❛t ❤✐❣❤ ✈♦❧t❛❣❡s ✐s ✉s❡❢✉❧ ❢♦r ♣r♦❞✉❝✐♥❣ ❢r❡❡ st❛♥❞✐♥❣ P❙✐ str✉❝t✉r❡s ♦r t♦ ❛❝❤✐❡✈❡ ❛ s♠♦♦t❤ r❡❧✐❡✈❡❞ ♠❛❝❤✐♥❡❞ s✐❧✐❝♦♥ s✉r❢❛❝❡✳ ❆❢t❡r t❤❡ ❛♥♦❞✐③❛t✐♦♥ ❛♥❞ ❝r❡❛t✐♥❣ ❛ ❧❛②❡r✴❧❛②❡rs ♦❢ P❙✐✱ r❛✐s✐♥❣ t❤❡ ✈♦❧t❛❣❡ ❛❜♦✈❡ t❤❡ ❝r✐t✐❝❛❧ ✈❛❧✉❡ ✇♦✉❧❞ ❛❧❧♦✇ ❢♦r t❤❡ t♦t❛❧ ❞✐ss♦❧✉t✐♦♥ ♦❢ s✐❧✐❝♦♥ ❛t♦♠s ❛t t❤❡ ❡♥❞ ♦❢ t❤❡ P❙✐ ❧❛②❡r ❛♥❞ r❡s✉❧t ✐♥ t❤❡ ❞❡t❛❝❤♠❡♥t ♦❢ t❤❡ P❙✐ ☞❧♠ ❢r♦♠ t❤❡ ❜✉❧❦ s✐❧✐❝♦♥ s✉❜str❛t❡✳ ✷✳✷ ■♦♥ ✐rr❛❞✐❛t✐♦♥ ❆ ♥❡✇ ❞✐r❡❝t✲✇r✐t✐♥❣ ❧✐t❤♦❣r❛♣❤✐❝ ♣r♦❝❡ss t❤❛t ✉s❡s ❛ ❢♦❝✉s❡❞ ❜❡❛♠ ♦❢ ▼❡❱ ♣r♦t♦♥s t♦ ♣❛tt❡r♥ r❡s✐st ♠❛t❡r✐❛❧ ❛t ♥❛♥♦ ❞✐♠❡♥s✐♦♥s ❬✷✶④✷✽❪ ❤❛s ❜❡❡♥ ❞❡✈❡❧♦♣❡❞ ❛t t❤❡ ❈❡♥tr❡ ❢♦r ■♦♥ ❇❡❛♠ ❆♣♣❧✐❝❛t✐♦♥s ✭❈■❇❆✮✳ ❚❤✐s ♣r♦❝❡ss✱ ❦♥♦✇♥ ❛s ♣r♦t♦♥ ❜❡❛♠ ✇r✐t✐♥❣ ✭P❇❲✮ ✐s ✈❡r② s✐♠✐❧❛r t♦ ❡❧❡❝tr♦♥ ❜❡❛♠ ❧✐t❤♦❣r❛♣❤② ✇❤❡r❡ t❤❡ ❞✐r❡❝t ✇r✐t✐♥❣ ✐s ♣❡r❢♦r♠❡❞ ✉s✐♥❣ ❡❧❡❝tr♦♥s✳ ❍♦✇❡✈❡r✱ t❤✐s ♥❡✇ ❧✐t❤♦❣r❛♣❤✐❝ ♣r♦❝❡ss ♦☛❡rs s❡✈❡r❛❧ ✐♥t❡r❡st✐♥❣ ❛♥❞ ✉♥✐q✉❡ ❛❞✈❛♥t❛❣❡s ♦✈❡r ❡❧❡❝tr♦♥ ❜❡❛♠ ❧✐t❤♦❣r❛♣❤②✳ Pr♦t♦♥s ❛r❡ ♠♦r❡ ♠❛ss✐✈❡ t❤❛♥ ❡❧❡❝tr♦♥ ❛♥❞ ❤❡♥❝❡✱ ♣❡♥❡tr❛t❡ ❞❡❡♣❡r ❛♥❞ ♠❛✐♥t❛✐♥ ❛ str❛✐❣❤t ♣❛t❤ ✐♥ ♠❛t❡r✐❛❧s✳ ❚❤✐s ♣r♦♣❡rt② ❛❧❧♦✇s P❇❲ t♦ ❢❛❜r✐❝❛t❡ t❤r❡❡✲❞✐♠❡♥s✐♦♥❛❧✱ ❤✐❣❤ ❛s♣❡❝t r❛t✐♦ str✉❝t✉r❡s ✇✐t❤ ✈❡rt✐❝❛❧ ❛♥❞ s♠♦♦t❤ s✐❞❡✇❛❧❧s✳ ❊❧❡❝tr♦♥ ❜❡❛♠ ✇r✐t✐♥❣ ✇❛s s✐♠✉❧❛t❡❞ ✉s✐♥❣ ❛ s♦❢t✇❛r❡ ❦♥♦✇♥ ❛s ❈❆❙■◆❖ ❬✷✾❪ ❛♥❞ ❛ ❝♦♠♣❛r✐s♦♥ ✇❛s ♠❛❞❡ ❜❡t✇❡❡♥ P❇❲✱ ❋♦❝✉s❡❞ ■♦♥ ❇❡❛♠ ✭❋■❇✮ ❧✐t❤♦❣r❛♣❤② ✭✇✐t❤ ❤❡❛✈② ✐♦♥s✮✱ ❛♥❞ ❡❧❡❝tr♦♥ ❜❡❛♠ ✇r✐t✐♥❣ ✐♥ ❋✐❣ ✷✳✹✳ ❚❤❡ ♣r♦❝❡ss ♦❢ ♣r♦t♦♥s tr❛✈❡❧✐♥❣ t❤r♦✉❣❤ r❡s✐st ♠❛t❡r✐❛❧s ❝❛♥ ❜❡ s✉♠♠❛r✐③❡❞ ❜② t❤❡ ❢♦❧❧♦✇✐♥❣✿ ✎ Pr♦t♦♥s tr❛✈❡❧ ✐♥ ❛ str❛✐❣❤t ❧✐♥❡ ✐♥ ❛ r❡s✐st ♠❛t❡r✐❛❧ ❛♥❞ ✇✐❧❧ ♦♥❧② ❡①♣❡r✐❡♥❝❡ ❛ s♠❛❧❧ ❛♠♦✉♥t ♦❢ ❧❛t❡r❛❧ ❜r♦❛❞❡♥✐♥❣ ❛t t❤❡ ❡♥❞✲♦❢✲r❛♥❣❡ ✇❤❡♥ ♥✉❝❧❡❛r ❝♦❧❧✐s✐♦♥s ❛r❡ ♠♦r❡ ❧✐❦❡❧② t♦ ♦❝❝✉r✳ ❚❤✐s ✐s ❛♥ ❛❞✈❛♥t❛❣❡ ♦✈❡r ❧✐t❤♦❣r❛♣❤✐❝ t❡❝❤♥✐q✉❡s ❧✐❦❡ ❡❧❡❝tr♦♥ ❜❡❛♠ ♦r ✉❧tr❛✈✐♦❧❡t ❧✐t❤♦❣r❛♣❤②✱ ❡s♣❡❝✐❛❧❧② ✐♥ t❤❡ ❝❛s❡ ❢♦r ❢❛❜r✐❝❛t✐♥❣ ❤✐❣❤ ❛s♣❡❝t r❛t✐♦ ♦r t❤r❡❡ ❞✐♠❡♥s✐♦♥❛❧ str✉❝t✉r❡s ❛s ❛ ❢♦❝✉s❡❞ ❡❧❡❝tr♦♥ ❜❡❛♠ st❛rts ❜r♦❛❞❡♥✐♥❣ ❧❛t❡r❛❧❧② ♦♥❝❡ ✐t ❡♥t❡rs ❛ r❡s✐st ♠❛t❡r✐❛❧✳ ✶✹ ❛❝❤✐❡✈❡❞ ❢♦r ❧♦✇ r❡s✐st✐✈✐t② ✇❛❢❡rs✳ ❋✐❣✉r❡ ✷✳✼✿ ▼❊❉■❈■ ♣❧♦ts ♦❢ ❝✉rr❡♥t ❞❡♥s✐t② ❏ ❛❝r♦ss ❛ r❡❣✐♦♥ ❝♦♥t❛✐♥✐♥❣ ❛ s✐♥❣❧❡ ✐rr❛❞✐❛t❡❞ ❧✐♥❡ ✭❣r❛② ❛r❡❛✮ ❢♦r ❞✐☛❡r❡♥t ✌✉❡♥❝❡s✳ ❚❤❡ ❝✉r✈❡s ❛r❡ ♥♦r♠❛❧✐③❡❞ t♦ t❤❡ s❛♠❡ ❏ ✐♥ t❤❡ ❜❛❝❦❣r♦✉♥❞ ❢♦r ❡❛s✐❡r ❝♦♠♣❛r✲ ✐s♦♥✳ ❋r♦♠ ❬✸✷❪ ■♥ ❋✐❣ ✷✳✼✱ ♣❧♦ts ♦❢ ❝✉rr❡♥t ❞❡♥s✐t② ❏ ❛❝r♦ss ❛ r❡❣✐♦♥ ♦❢ ❛ ✸ ✡✳❝♠ ✇❛❢❡r ❝♦♥t❛✐♥✐♥❣ ❛ ❧✐♥❡ ✐rr❛❞✐❛t❡❞ ✇✐t❤ ❞✐☛❡r❡♥t ♣r♦t♦♥ ✌✉❡♥❝❡s ✐s s❤♦✇♥ ❬✸✷❪✳ ❆t ❧♦✇ ✌✉❡♥❝❡s✱ ❏ t❤r♦✉❣❤ t❤❡ ✐rr❛❞✐❛t❡❞ ❧✐♥❡ r❡♠❛✐♥s s✐❣♥✐☞❝❛♥t✱ s♦ P❙✐ ✇✐❧❧ st✐❧❧ ❢♦r♠ ❛t t❤❡ ✐rr❛❞✐❛t❡❞ ❧✐♥❡ ❜✉t ❛t ❛ ❧♦✇❡r r❛t❡ t❤❛♥ t❤❡ ✉♥✐rr❛❞✐❛t❡❞ ❜❛❝❦❣r♦✉♥❞✳ ■♥ t❤✐s ❧♦✇✲✌✉❡♥❝❡ r❛♥❣❡✱ ❏✱ ❛♥❞ ❤❡♥❝❡ t❤❡ ♣❤②s✐❝❛❧ ❛♥❞ ❡❧❡❝tr♦♥✐❝ ♣r♦♣❡rt✐❡s ♦❢ t❤❡ P❙✐ ✐♥ t❤❡ ✐rr❛❞✐❛t❡❞ ❧✐♥❡✱ ✈❛r✐❡s r❛♣✐❞❧② ✇✐t❤ ✌✉❡♥❝❡✳ P❙✐ ❛♥❞ s✐❧✐❝♦♥ ✇✐t❤ ✈❛r✐❛❜❧❡ ❤❡✐❣❤t ♦❢ ♠❛❝❤✐♥❡❞ ❢❡❛t✉r❡s ❝❛♥ ❜❡ ♣r♦❞✉❝❡❞ ✇✐t❤ ❛❝❝✉r❛t❡ ❝♦♥tr♦❧ ♦✈❡r t❤❡ ✌✉❡♥❝❡ ✭❋✐❣ ✷✳✽✮✳ ❲✐t❤ ✐♥❝r❡❛s✐♥❣ ✌✉❡♥❝❡✱ ✭✶✵✶✻ ✴❝♠✷ ✮ ❏ r❡❞✉❝❡s t♦ ③❡r♦ ❛❝r♦ss t❤❡ ✐rr❛❞✐❛t❡❞ ❧✐♥❡✱ s♦ ❧✐tt❧❡ ♦r ♥♦ P❙✐ ✐s ❡①♣❡❝t❡❞ t♦ ❢♦r♠✳ ❚❤❡ ❛❜♦✈❡ ❞❡s❝r✐❜❡❞ t❤❡ ❡☛❡❝ts ♦❢ ✐♦♥ ✐rr❛❞✐❛t✐♦♥ ♦♥ P❙✐ ❢♦r♠❛t✐♦♥✳ ❚❤✐s ❢♦r♠s t❤❡ ❜❛❝❦❜♦♥❡ ♦❢ ❛❧❧ t❤❡ ✇♦r❦ ♣r❡s❡♥t❡❞ ✐♥ t❤✐s t❤❡s✐s✳ ■♥ ❣❡♥❡r❛❧✱ ♠✐❝r♦♠❛❝❤✐♥✐♥❣ ♦❢ P❙✐ ♦r s✐❧✐❝♦♥ str✉❝t✉r❡s ❛♥❞ ❞❡✈✐❝❡s ❛r❡ ❛❝❝♦♠♣❧✐s❤❡❞ ❜② t❤❡ ❢♦❧❧♦✇✐♥❣ st❡♣s✿ ✶✳ Pr❡♣❛r❛t✐♦♥ ♦❢ ♣❛tt❡r♥ t♦ ❜❡ ✐rr❛❞✐❛t❡❞✳ ❉❡♣❡♥❞✐♥❣ ♦♥ t❤❡ t②♣❡ ♦❢ ✐rr❛❞✐❛t✐♦♥ ✉s❡❞ ✭❧❛r❣❡ ❛r❡❛ ♦r P❇❲✮✱ t❤❡ ♣❛tt❡r♥s ❛r❡ ♣r❡♣❛r❡❞ ❞✐☛❡r❡♥t❧②✳ ❋♦r P❇❲✱ ❛♥ ✐♠❛❣❡ ✐♥ ✶✻ ✷✳✹ ❈❡♥tr❡ ❢♦r ■♦♥ ❇❡❛♠ ❆♣♣❧✐❝❛t✐♦♥s ✭❈■❇❆✮ ❆t ❈■❇❆✱ ❡♥❡r❣❡t✐❝ ✐♦♥s ❛r❡ ♣r♦❞✉❝❡❞ ❜② ❛ ✸✳✺ ▼❱ ❤✐❣❤ ❜r✐❣❤t♥❡ss ❍✐❣❤ ❱♦❧t❛❣❡ ❊♥❣✐✲ ♥❡❡r✐♥❣ ❊✉r♦♣❛ ❙✐♥❣❧❡tr♦♥❚ ▼ ✐♦♥ ❛❝❝❡❧❡r❛t♦r ❬✸✸✱ ✸✹❪✳ ■♦♥s ❛r❡ ❝r❡❛t❡❞ ❜② ❡①❝✐t✐♥❣ ❛ ❣❛s ✇✐t❤ ❛ ❘❛❞✐♦ ❋r❡q✉❡♥❝② s♦✉r❝❡✳ ❚❤♦✉❣❤ ✈❛r✐♦✉s t②♣❡s ♦❢ ✐♦♥s ♠❛② ❜❡ ❝r❡❛t❡❞ ✉s✐♥❣ t❤✐s ♣r♦❝❡ss✱ t❤❡ ♦♥❡s ✉s❡❞ ✐♥ t❤✐s t❤❡s✐s ❛r❡ ♣r✐♠❛r✐❧② ♣r♦t♦♥s ✭❍✰ ✮ ❛♥❞ s✐♥❣❧②✲❝❤❛r❣❡❞ ❤❡❧✐✉♠ ✭❍❡✰ ✮✳ ❚❤❡ ❛❝❝❡❧❡r❛t♦r ✭❋✐❣ ✷✳✾ ✭✶✮✮ t❤❡♥ ❣❡♥❡r❛t❡s ❛♥ ❡❧❡❝tr✐❝ ☞❡❧❞ t♦ ❣r❛❞✉❛❧❧② ❛❝❝❡❧❡r❛t❡ t❤❡ ✐♦♥s t♦ t❤❡ ❞❡s✐r❡❞ ❡♥❡r❣②✳ ❚❤❡ ❡♥❡r❣✐❡s ✉s❡❞ ❢♦r t❤✐s t❤❡s✐s r❛♥❣❡s ❢r♦♠ ❛ ❢❡✇ ❤✉♥❞r❡❞ ❦❡❱ t♦ ✷▼❡❱✳ ❊♠❡r❣✐♥❣ ❢♦r♠ t❤❡ ❛❝❝❡❧❡r❛t♦r✱ t❤❡ ✐♦♥ ❜❡❛♠ ❣♦❡s t❤r♦✉❣❤ t❤❡ ✾✵♦ ♠❛❣♥❡t ✭❋✐❣ ✷✳✾ ✭✷✮✮✳ ❚❤✐s ♠❛❣♥❡t ❜❡♥❞s t❤❡ tr❛❥❡❝t♦r② ♦❢ t❤❡ ✐♦♥ ❜❡❛♠ ❜② ✾✵♦ ❛♥❞ ✐s ❛❜❧❡ t♦ s❡❧❡❝t ♣r❡❝✐s❡❧② t❤❡ ❞❡s✐r❡❞ ❡♥❡r❣② ♦❢ t❤❡ ✐♦♥s ✐♥ t❤❡ ♣r♦❝❡ss✳ ❚❤❡ ❜❡❛♠ ♣❛ss❡s t❤r♦✉❣❤ ❛ ♠❛❣♥❡t✐❝ ☞❡❧❞ ❛♥❞ ✐s ❝✉r✈❡❞ ❛t ❛♥ ❛♠♦✉♥t ❞❡♣❡♥❞✐♥❣ ♦♥ t❤❡ ❝❤❛r❣❡ ♦❢ t❤❡ ✐♦♥s ❛s ✇❡❧❧ ❛s t❤❡ ❡♥❡r❣② t❤❡② ♣♦ss❡ss✳ ❋✐❣✉r❡ ✷✳✾✿ ✭▲❡❢t✮ ❚♦♣ ❞♦✇♥ s❝❤❡♠❛t✐❝ ❞✐❛❣r❛♠ ♦❢ t❤❡ ♠✐❝r♦ ❜❡❛♠ s❡t✉♣ ✐♥ ❈■❇❆✳ ✭❘✐❣❤t✮ ❆❝t✉❛❧ ✐♠❛❣❡ ♦❢ t❤❡ ❈■❇❆ ♠✐❝r♦ ❜❡❛♠ ❢❛❝✐❧✐t✐❡s✳ ✭✶✮✿ t❤❡ ❛❝❝❡❧❡r❛t♦r✱ ✭✷✮ ✾✵ ❞❡❣r❡❡ ♠❛❣♥❡t✱ ✭✸✮ s✇✐t❝❤✐♥❣ ♠❛❣♥❡t✱ ✭✹✮ ❡♥❞st❛t✐♦♥s ❋✐❣ ✷✳✶✵ s❤♦✇s t❤❡ s❝❤❡♠❛t✐❝s ♦❢ t❤❡ ✾✵✍ ♠❛❣♥❡t✳ ❚❤❡r❡ ✐s ❛ str♦♥❣ ♠❛❣♥❡t✐❝ ☞❡❧❞ t❤❛t ✐s ♣♦✐♥t✐♥❣ ♦✉t ♦❢ t❤❡ ♣❛❣❡✳ ❆s t❤❡ ✐♦♥s ♣❛ss t❤r♦✉❣❤ t❤❡ ♠❛❣♥❡t✐❝ ☞❡❧❞✱ ❛ ▲♦r❡♥t③ ❢♦r❝❡ ✐s ✐♥❞✉❝❡❞✳ ❯s✐♥❣ t❤❡ ❧❡❢t ❤❛♥❞ r✉❧❡✱ ✇❡ ☞♥❞ t❤❛t t❤❡ ❢♦r❝❡ ✐♥❞✉❝❡❞ ✐s t♦ t❤❡ ❧❡❢t ♦❢ t❤✐s ♣❛❣❡ ❛♥❞ ✐t ❛❝ts ❧✐❦❡ ❛ ❝❡♥tr✐♣❡t❛❧ ❢♦r❝❡ ✇❤✐❝❤ ❝✉r✈❡s t❤❡ tr❛❥❡❝t♦r② ♦❢ t❤❡ ❜❡❛♠ t♦✇❛r❞s t❤❡ ❧❡❢t✳ ❆t t❤❡ t♦♣ ❧❡❢t ❤❛♥❞ ❝♦r♥❡r✱ t❤❡r❡ ✐s ♦♥❧② ❛ s♠❛❧❧ ♦♣❡♥✐♥❣ ❢♦r t❤❡ ❜❡❛♠ t♦ ❡①✐t✳ ❚❤❡ str❡♥❣t❤ ♦❢ t❤❡ ♠❛❣♥❡t✐❝ ☞❡❧❞ ✐s ❛❞❥✉st❡❞ s✉❝❤ t❤❛t ♦♥❧② ✐♦♥s ✇✐t❤ ❡①❛❝t❧② t❤❡ ❞❡s✐r❡❞ ✶✼ ❋✐❣✉r❡ ✷✳✶✵✿ ❚♦♣✲❞♦✇♥ ❙❝❤❡♠❛t✐❝s ♦❢ t❤❡ ✐♥t❡r✐♦r ♦❢ t❤❡ ✾✵✍ ♠❛❣♥❡t s❡❧❡❝t✐♥❣ ✷▼❡❱ ♣r♦t♦♥s✳ ❡♥❡r❣② ✇✐❧❧ ❡①✐t ❢r♦♠ t❤✐s ♦♣❡♥✐♥❣ ✇❤✐❧❡ ✐♦♥s ✇✐t❤ ❣r❡❛t❡r ♦r s♠❛❧❧❡r ❡♥❡r❣② ✇♦✉❧❞ ❜❡ tr❛♣♣❡❞✳ ❆ s✇✐t❝❤✐♥❣ ♠❛❣♥❡t ✭❋✐❣ ✷✳✾ ✭✸✮✮ t❤❡♥ ❣✉✐❞❡s t❤❡ ❜❡❛♠ t♦ t❤❡ ❞❡s✐r❡❞ ❡♥❞st❛t✐♦♥ ✇❤❡r❡ t❤❡ s❛♠♣❧❡ ✐s ❧♦❝❛t❡❞✳ ❚❤❡r❡ ❛r❡ t❤r❡❡ ❡♥❞st❛t✐♦♥s ❧♦❝❛t❡❞ ❛t ✶✵♦ ✱ ✸✵♦ ✱ ✹✺♦ ✭❋✐❣ ✷✳✾ ✭✹✮✮ ❜✉t ♦♥❧② t❤❡ ✶✵♦ ❛♥❞ ✸✵♦ ❡♥❞st❛t✐♦♥s✱ ❢♦r P❇❲ ❛♥❞ ❧❛r❣❡ ❛r❡❛ ✐rr❛❞✐❛t✐♦♥ r❡s♣❡❝t✐✈❡❧②✱ ❛r❡ ✉s❡❞ ❢♦r t❤❡ ✇♦r❦ ❞❡s❝r✐❜❡❞ ✐♥ t❤✐s t❤❡s✐s✳ ❚❤❡ ❝♦♠♣❧❡t❡ ❜❡❛♠ ❧✐♥❡✱ ✐♥❝❧✉s✐✈❡ ♦❢ t❤❡ ❡♥❞st❛t✐♦♥s✱ ♥❡❡❞s t♦ ❜❡ ✉♥❞❡r ❤✐❣❤ ✈❛❝✉✉♠ ✭ ✶✵ ✻ ♠✐❧❧✐❜❛r✮✳ ❚❤❡ ✐♦♥ ❜❡❛♠ ❝✉rr❡♥t ✐s ♠❡❛s✉r❡❞ ❜② ❛ ❜❡❛♠ ♣r♦☞❧❡ ♠♦♥✐t♦r ✇❤✐❝❤ ✐s s✐t✉❛t❡❞ ❥✉st ❛❢t❡r t❤❡ ❛❝❝❡❧❡r❛t♦r ❜❡❢♦r❡ t❤❡ ✾✵♦ ♠❛❣♥❡t ❛♥❞ ✐t ❛♥❛❧②③❡s t❤❡ ❜❡❛♠ ❛♥❞ ❣❛t❤❡rs ❞❛t❛ ♦♥ t❤❡ ✐♥t❡♥s✐t②✱ ♣r♦☞❧❡ ❛♥❞ ♣♦s✐t✐♦♥ ♦❢ t❤❡ ❜❡❛♠✳ ❆♥♦t❤❡r ✇❛② t♦ ♠❡❛s✉r❡ t❤❡ ❜❡❛♠ ❝✉rr❡♥t ✐s t♦ ✉s❡ ❛ ❋❛r❛❞❛② ❈✉♣✳ ❚❤✐s ❝✉♣ ❣❛t❤❡rs t❤❡ ❝❤❛r❣❡❞ ♣❛rt✐❝❧❡s t♦ ♠❡❛s✉r❡ t❤❡ ❝✉rr❡♥t ❛♥❞ ❣✐✈❡s q✉❛♥t✐t❛t✐✈❡ ✐♥❢♦r♠❛t✐♦♥ ✇❤✐❝❤ ❤❡❧♣s t♦ ♦♣t✐♠✐③❡ t❤❡ ❜❡❛♠ ❜r✐❣❤t♥❡ss✴❝✉rr❡♥t✳ ❚❤❡r❡ ✐s ♦♥❡ s✐t✉❛t❡❞ r✐❣❤t ❛❢t❡r t❤❡ ❛❝❝❡❧❡r❛t♦r ❛♥❞ ❛♥♦t❤❡r ♦♥❡ ❥✉st ❛❢t❡r t❤❡ ✾✵♦ ♠❛❣♥❡t✳ ✶✾ ❇❡❛♠ s❝❛♥♥✐♥❣ ❛♥❞ ❜❧❛♥❦✐♥❣ ❜❡❛♠ s❝❛♥♥✐♥❣ ❱❡r② ♦❢t❡♥ ✐t ✐s ♥❡❝❡ss❛r② t♦ s❝❛♥ ♣r❡✲❞❡☞♥❡❞ ♣❛tt❡r♥s ♦♥ t❤❡ s✉r❢❛❝❡ ♦❢ ❛ s❛♠♣❧❡✳ ❚❤✐s ✐s ❛❝❤✐❡✈❡❞ ✉s✐♥❣ ❛ ❙❝❛♥ ❆♠♣❧✐☞❡r✱ ✇❤✐❝❤ ❞❡✌❡❝ts t❤❡ ❜❡❛♠ ✐♥ ❛ ❢❛s❤✐♦♥ s✐♠✐❧❛r t♦ ❛♥ ❡❧❡❝tr♦♥ ❜❡❛♠ ❜❡✐♥❣ ❞❡✌❡❝t❡❞ ✐♥ ❛ ❈❘❚ ♠♦♥✐t♦r✳ ❚❤❡ s❝❛♥ s✐③❡ ✐s s❡t ♦♥ t❤❡ s❝❛♥ ❛♠♣❧✐☞❡r✱ ❛❧♦♥❣ ✇✐t❤ t❤❡ ❳ t♦ ❨ ❛①✐s r❛t✐♦ ♦❢ t❤❡ ❛r❡❛ t♦ s❝❛♥✳ ❚❤✐s ❛❧❧♦✇s t❤❡ ✐rr❛❞✐❛t✐♦♥ ♦❢ s✐♠♣❧❡ ♣❛tt❡r♥s s✉❝❤ ❛s sq✉❛r❡s ❛♥❞ r❡❝t❛♥❣❧❡s✳ ❋♦r ✐rr❛❞✐❛t✐♦♥ ♦❢ ❝♦♠♣❧❡① ♣❛tt❡r♥s✱ t❤❡ s❝❛♥ ❛♠♣❧✐☞❡r ✐s ✉s❡❞ ✇✐t❤ ❛ ❝♦♠♣✉t❡r r✉♥♥✐♥❣ ■❖◆❙❈❆◆ ❬✸✽✱ ✸✾❪✱ ❛ s♦❢t✇❛r❡ ♣❛❝❦❛❣❡ ❞❡✈❡❧♦♣❡❞ ❛t ❈■❇❆✳ ❚❤✐s s♦❢t✇❛r❡ ❛❧❧♦✇s ❛♥② s❝❛♥♥✐♥❣ ♠♦❞✐☞❝❛t✐♦♥ ✐♥s✐❞❡ t❤❡ ❛r❡❛s ☞①❡❞ ❜② t❤❡ s❝❛♥ ❛♠♣❧✐☞❡r✳ ❚❤❡ s❝❛♥ ♣❛tt❡r♥ ✐s r❡❛❞ ❜② ■❖◆❙❈❆◆ ✐♥ ❛ ♣✐①❡❧ ❢♦r♠❛t ❛♥❞ ❡❛❝❤ ♣✐①❡❧ ✐s tr❡❛t❡❞ ❛s ❛ ♣♦✐♥t ♦❢ ✐rr❛❞✐❛t✐♦♥✳ ■❖◆❙❈❆◆ ✐s ❛❜❧❡ t♦ ❝♦♥tr♦❧ t❤❡ s❤❛♣❡ ♦❢ t❤❡ s❝❛♥♥❡❞ ♣❛tt❡r♥ ❛♥❞ t❤❡ ❞✇❡❧❧ t✐♠❡ t❤❡ ✐♦♥ ❜❡❛♠ s♣❡♥❞s ❛t ❡❛❝❤ ❧♦❝❛t✐♦♥ ✭✐✳❡✳ ❝♦♥tr♦❧❧✐♥❣ t❤❡ ✌✉❡♥❝❡✮✳ ❚❤❡ ❞✇❡❧❧ t✐♠❡ ✐s ❛ ♣❛r❛♠❡t❡r ✇❤✐❝❤ ✐s ❝❛❧❝✉❧❛t❡❞ ❜❛s❡❞ ♦♥ t❤❡ ✐♦♥ ❜❡❛♠ ❝✉rr❡♥t ❛✈❛✐❧❛❜❧❡ ❛♥❞ ✌✉❡♥❝❡ r❡q✉✐r❡❞ ♣r✐♦r t♦ t❤❡ ✐rr❛❞✐❛t✐♦♥ ♦❢ t❤❡ s✐❧✐❝♦♥ s❛♠♣❧❡s ✳ ❱❛r②✐♥❣ ❛♠♦✉♥t ♦❢ ✐rr❛❞✐❛t✐♦♥ ✌✉❡♥❝❡ ✭♥✉♠❜❡r ♦❢ ✐♦♥s✴❝♠✷ ✮ ❝❛♥ ❤❡♥❝❡ ❜❡ ✐rr❛❞✐❛t❡❞ ❛t ❞✐☛❡r❡♥t ♣❛rts ♦❢ ❛ s✐♥❣❧❡ s✐❧✐❝♦♥ s❛♠♣❧❡✳ ❲✐t❤ ❦♥♦✇❧❡❞❣❡ ♦❢ t❤❡ ❜❡❛♠ ❝✉rr❡♥t✱ t❤❡ t♦t❛❧ ♥✉♠❜❡r ♦❢ ♣♦✐♥ts ✐♥ ❛ ♣❛tt❡r♥✱ ❛♥❞ t❤❡ ✌✉❡♥❝❡ r❡q✉✐r❡❞✱ t❤❡ ❛♠♦✉♥t ♦❢ t✐♠❡ ✇❤✐❝❤ t❤❡ ❜❡❛♠ ♥❡❡❞s t♦ ❞✇❡❧❧ ❛t ❛ ♣❛rt✐❝✉❧❛r ♣♦✐♥t ❝❛♥ ❜❡ ❝❛❧❝✉❧❛t❡❞✳ ■❖◆❙❈❆◆ ❛❧s♦ ❝♦♥tr♦❧s ❛ ❜❧❛♥❦✐♥❣ s②st❡♠ ✇❤✐❝❤ ✐s ✐♥st❛❧❧❡❞ ❥✉st ❜❡❢♦r❡ t❤❡ s✇✐t❝❤✐♥❣ ♠❛❣♥❡t ✭❋✐❣ ✷✳✾✭✸✮✮✳ ❚❤✐s ❜❧❛♥❦✐♥❣ s②st❡♠ s✐♠♣❧② ❞❡✌❡❝ts t❤❡ ❜❡❛♠ ❛✇❛② ❢r♦♠ t❤❡ ♦r✐❣✐♥❛❧ ❜❡❛♠ ❛①✐s ❛♥❞ ♦✉t ♦❢ t❤❡ ❝❤❛♠❜❡r ✇❤❡♥ s✇✐t❝❤❡❞ ♦♥✱ ❛♥❞ ✐s ✉s❡❞ t♦ ❜❧❛♥❦ t❤❡ ❜❡❛♠ ✇❤❡♥ ♥♦ ✐rr❛❞✐❛t✐♦♥ ✐s ♥❡❡❞❡❞✳ ▼♦r❡ ❝♦♠♣❧✐❝❛t❡❞ ♣❛tt❡r♥s ❝❛♥ t❤❡r❡❢♦r❡ ❜❡ ✐rr❛❞✐❛t❡❞ ✇✐t❤✐♥ t❤❡ s❛♠❡ ❛r❡❛ ☞①❡❞ ❜② t❤❡ s❝❛♥ ❛♠♣❧✐☞❡r✱ t❤❡ ❜❡❛♠ ❜❡✐♥❣ ❜❧❛♥❦❡❞ ✇❤❡♥ ♠♦✈✐♥❣ ❢r♦♠ ♦♥❡ ☞❣✉r❡ t♦ t❤❡ ♦t❤❡r✳ ✷✳✹✳✷ ▲❛r❣❡ ❛r❡❛ ✐rr❛❞✐❛t✐♦♥ ❚❤❡ ❧❛r❣❡ ❛r❡❛ ✐rr❛❞✐❛t✐♦♥ ✐s ❝❛rr✐❡❞ ♦✉t ♦♥ t❤❡ ✸✵✍ ❡♥❞st❛t✐♦♥ ❛♥❞ ✇❛s ❞❡✈❡❧♦♣❡❞ ❜❡❝❛✉s❡ ♦❢ t❤❡ ❡①✐st❡♥❝❡ ♦❢ s❡✈❡r❛❧ ❧✐♠✐t❛t✐♦♥s t♦ ✉s✐♥❣ P❇❲ ❢♦r ✐rr❛❞✐❛t✐♥❣ ❧❛r❣❡ ❛r❡❛ ♣❛tt❡r♥s ♦♥ s✐❧✐❝♦♥ ✇❛❢❡rs✳ ❋♦r ♦♥❡✱ t❤❡ ♠❛①✐♠✉♠ s❝❛♥ s✐③❡ ✇❤✐❝❤ ♠❛② ❜❡ ❛❝❤✐❡✈❡❞ ✉s✐♥❣ t❤❡ ✶✵✍ ✷✹ t❤❡ ▼❛s❦ ❛♥❞ ❇♦♥❞ ❆❧✐❣♥❡r✱ ▼❆✽✴❇❆✻ ✭❙❯❙❙ ▼✐❝r♦❚❡❝✮ ♠❛❝❤✐♥❡ ✭❋✐❣ ✷✳✶✺✮✳ ❋✐❣✉r❡ ✷✳✶✻✿ P❧♦t ♦❢ ❆❩ ✹✻✷✵ t❤✐❝❦♥❡ss✴❞❡♣t❤ ✭♠❡❛s✉r❡❞ ✇✐t❤ ❛ ♣r♦☞❧♦♠❡t❡r ❢r♦♠ t❤❡ s✐❧✐❝♦♥ s✉r❢❛❝❡✮ ✈s t❤❡ ❯❱ ❡①♣♦s✉r❡ t✐♠❡✳ ❚❤❡ r❡s✐st ✉s❡❞ ❢♦r ♠♦st ♦❢ t❤❡ ❧❛r❣❡ ❛r❡❛ ✇♦r❦ ✇❛s ❆❩✹✻✷✵ ❛♥❞ ❝❛r❡❢✉❧ ❝❤❛r❛❝t❡r✐③❛t✐♦♥ ✇❛s ❞♦♥❡ t♦ ❡♥s✉r❡ t❤❛t ✐t ✐s ♣♦ss✐❜❧❡ t♦ r❡♣r♦❞✉❝❡ r❡s✐st ❧❛②❡rs ✇✐t❤ s♣❡❝✐☞❝ t❤✐❝❦♥❡ss✳ ❚❤✐s ✐s ❡s♣❡❝✐❛❧❧② ✐♠♣♦rt❛♥t ❢♦r ♠❛❦✐♥❣ t❤❡ ♠✉❧t✐❧❡✈❡❧❡❞ P❘ ♠❛s❦s✳ ❙✐❧✐❝♦♥ ✇❛❢❡rs ✇❡r❡ ❝♦❛t❡❞ ✇✐t❤ ❍▼❉❙ ✭❤❡①❛♠❡t❤②❧❞✐s✐❧❛③❛♥❡✮ ❜② ✈❛♣♦r ♣r✐♠✐♥❣ t♦ ❝r❡❛t❡ t❤❡ ❛❞❤❡s✐♦♥ ❜❡t✇❡❡♥ t❤❡ s❛♠♣❧❡ ❛♥❞ t❤❡ P❘✳ ❙✉❜s❡q✉❡♥t❧② ❛ t❤✐❝❦ ❆❩✹✻✷✵ ✭✼✳✺✖✮ ✇❛s s♣✉♥ ♦♥t♦ t❤❡ ✇❛❢❡r ❛♥❞ ♣r❡✲❜❛❦❡❞ t♦ ✾✺✍ ❈ ❢♦r ✹ ♠✐♥✉t❡s✳ ❆ ❧❛s❡r ❧✐t❤♦❣r❛♣❤② s②st❡♠ ✇❛s ✉s❡❞ t♦ ❢❛❜r✐❝❛t❡ ❝❤r♦♠❡ ♣❤♦t♦♠❛s❦s ✭P▼✮ ✇✐t❤ t❤❡ ❞❡s✐r❡❞ ♣❛tt❡r♥ ❛♥❞ t❤❡ ♣❛tt❡r♥ tr❛♥s❢❡rr❡❞ ♦♥t♦ t❤❡ P❘ ✇✐t❤ ❯❱ ❡①♣♦s✉r❡ ✭✸✻✺♥♠✮ t❤r♦✉❣❤ t❤❡ P▼✳ ❆❢t❡r t❤❡ ❡①♣♦s✉r❡✱ t❤❡ s❛♠♣❧❡s ✇❡r❡ ❞❡✈❡❧♦♣❡❞ ✇✐t❤ ❆❩ ❞❡✈❡❧♦♣❡r ❢♦r ♦♥❡ ♠✐♥✉t❡ ❛♥❞ ❜❧♦✇♥ ❞r② ✇✐t❤ ♥✐tr♦❣❡♥ ❣❛s✳ ❇❡✐♥❣ ❛ ♣♦s✐t✐✈❡ P❘✱ ❯❱ ❡①♣♦s❡❞ r❡❣✐♦♥s ✇✐❧❧ r❡❛❝t ✇✐t❤ t❤❡ ❞❡✈❡❧♦♣❡r ❛♥❞ ❜❡ ♣❛rt✐❛❧❧②✴❢✉❧❧② r❡♠♦✈❡❞✳ ❚❤❡ ❡①♣♦s✉r❡ t✐♠❡ ✇❛s ✈❛r✐❡❞ ❢♦r ❞✐☛❡r❡♥t s❛♠♣❧❡s t♦ ❛❝❤✐❡✈❡❞ ❞✐☛❡r❡♥t ☞♥❛❧ P❘ t❤✐❝❦♥❡ss ❛❢t❡r t❤❡ ❞❡✈❡❧♦♣♠❡♥t✳ ❚❤❡ t❤✐❝❦♥❡ss❡s ✇❡r❡ t❤❡♥ ♠❡❛s✉r❡❞ ✇✐t❤ ❛ ♣r♦☞❧♦♠❡t❡r ❛♥❞ ♣❧♦tt❡❞ ✐♥ ❋✐❣ ✷✳✶✻✳ ❚❤✐s ♣❧♦t ✐s ✉s❡❞ ❡①t❡♥s✐✈❡❧② ❢♦r t❤❡ ♣r❡♣❛r❛t✐♦♥ ♦❢ P❘ ♠❛s❦s ♣r✐♦r t♦ ✐rr❛❞✐❛t✐♦♥ ❢♦r ♠♦st ♦❢ t❤❡ ❧❛r❣❡ ❛r❡❛ ✐rr❛❞✐❛t✐♦♥ ✇♦r❦ ♣r❡s❡♥t❡❞ ✐♥ t❤✐s t❤❡s✐s✳ ✷✺ ✷✳✺ ❙✐❧✐❝♦♥ ♠✐❝r♦✲♠❛❝❤✐♥✐♥❣ ✲ ❆ s❤♦rt r❡✈✐❡✇ ❙✐❧✐❝♦♥ ♠❛❝❤✐♥✐♥❣ ❝❛♥ ❜❡ ❧♦♦s❡❧② ❞❡☞♥❡❞ ❛s t❤❡ ♣r♦❝❡ss✴♣r♦❝❡ss❡s ♦❢ s❡❧❡❝t✐✈❡ r❡♠♦✈❛❧ ♦❢ s✐❣♥✐☞❝❛♥t ❛♠♦✉♥ts ♦❢ s✐❧✐❝♦♥ ❢r♦♠ t❤❡ s✉❜str❛t❡ t♦ ❢♦r♠ ❞❡s✐r❡❞ str✉❝t✉r❡s✳ ❚❤❡r❡ ❛r❡ ♠❛♥② ❡①✐st✐♥❣ t❡❝❤♥✐q✉❡s ❛♥❞ ♠❡t❤♦❞s ❢♦r ♠❛❝❤✐♥✐♥❣ s✐❧✐❝♦♥✳ ❚❤❡r❡ ✐s t❤❡ ✐s♦tr♦♣✐❝ ✇❡t ❡t❝❤✐♥❣ ✉s✐♥❣ ❝❤❡♠✐❝❛❧s ❧✐❦❡ ❍◆❆✱ ❍❋✱ ❍◆❖✸ ❛♥❞ ❈❍✸ ✇✐t❤ ❙✐✸ ◆✹ ♦r ❙✐❖✷ ❛s ❡t❝❤ ♠❛s❦s ❬✹✸❪✳ ❚❤❡r❡ ✐s ❛❧s♦ ❛♥✐s♦tr♦♣✐❝ ✇❡t ❡t❝❤✐♥❣ ✉s✐♥❣ ❑❖❍ ♦r ◆❍✹ ❖❍ ✇✐t❤ ❙✐✸ ◆✹ ♦r ❙✐❖✷ ❛s ❡t❝❤ ♠❛s❦s ❬✹✸❪✳ ■♥ t❡r♠ ♦❢ ❞r② ❡t❝❤✐♥❣✱ t❤❡r❡ ❛r❡ t❡❝❤♥✐q✉❡s ✇❤✐❝❤ ✉s❡s ❛♥ ❡①t❡r♥❛❧ ♣♦✇❡r s♦✉r❝❡ ❧✐❦❡ ❘❋ ♣♦✇❡r t♦ ❢♦r♠ ✐♦♥s ❛♥❞ ❡❧❡❝tr♦♥s ✇❤✐❝❤ ❞r✐✈❡s t❤❡ ❝❤❡♠✐❝❛❧ r❡❛❝t✐♦♥ ❢♦r ❡t❝❤✐♥❣ ✇✐t❤ ❈❤❧♦r♦✌✉♦r♦❝❛r❜♦♥s✱ ❙❋✻ ✱ ❇r ❝♦♠♣♦✉♥❞s ❛♥❞ ♦①②❣❡♥ ❜❡✐♥❣ t❤❡ ✐♦♥s ❝♦♠♠♦♥❧② ✉s❡❞✳ ❖♥❡ ♠❛✐♥ ❛❞✈❛♥t❛❣❡ ♦❢ t❤✐s t❡❝❤♥✐q✉❡ ✐s t❤❡ ❛❜✐❧✐t② t♦ ❛❝❤✐❡✈❡ t❤❡ ❢✉❧❧ s♣❡❝tr✉♠ ♦❢ ✐s♦tr♦♣✐❝ t❤r♦✉❣❤ ❛♥✐s♦tr♦♣✐❝ ✭❱❛r✐❛❜❧❡ ❆♥✐s♦tr♦♣②✮ ❡t❝❤✐♥❣ ❜② ✈❛r②✐♥❣ t❤❡ ❝♦♥❞✐t✐♦♥s ❛♥❞✴♦r ✐♦♥s ✉s❡❞ ❬✹✹❪✳ ❙✐❧✐❝♦♥ ♠❛❝❤✐♥✐♥❣ ✐s ✐♠♣♦rt❛♥t ❢♦r ♠❛♥② ✐♠♣♦rt❛♥t ☞❡❧❞s ✐♥❝❧✉❞✐♥❣✿ ✎ ▼✐❝r♦ ❊❧❡❝tr♦ ▼❡❝❤❛♥✐❝❛❧ ❙②st❡♠s ✭▼❊▼❙✮❀ ✇❤✐❝❤ ✐♥✈♦❧✈❡s t❤❡ ✐♥t❡❣r❛t✐♦♥ ♦❢ ♠❡✲ ❝❤❛♥✐❝❛❧ ❡❧❡♠❡♥ts✱ s❡♥s♦rs✱ ❛❝t✉❛t♦rs✱ ❛♥❞ ❡❧❡❝tr♦♥✐❝s ♦♥ ❛ ❝♦♠♠♦♥ s✐❧✐❝♦♥ s✉❜str❛t❡ ✎ ❙✐❧✐❝♦♥ ♣❤♦t♦♥✐❝s❀ ❛ r❛♣✐❞❧② ❡✈♦❧✈✐♥❣ t❡❝❤♥♦❧♦❣② ✐♥ ✇❤✐❝❤ ❞❛t❛ ✐s tr❛♥s❢❡rr❡❞ ❛♠♦♥❣ ❝♦♠♣✉t❡r ❝❤✐♣s ❜② ♦♣t✐❝❛❧ r❛②s ❛♥❞ ✐♥✈♦❧✈❡s ♣r✐♠❛r✐❧② t❤❡ ✐♥t❡❣r❛t✐♦♥ ♦❢ ❡①✐st✐♥❣ ♣❤♦t♦♥✐❝s ❛♥❞ s✐❧✐❝♦♥ ♠✐❝r♦❡❧❡❝tr♦♥✐❝s t❡❝❤♥♦❧♦❣② ♦♥ t❤❡ s❛♠❡ ❝❤✐♣ ✎ ❚❡❧❡❝♦♠♠✉♥✐❝❛t✐♦♥s❀ s✐♥❝❡ s✐❧✐❝♦♥ ✐s tr❛♥s♣❛r❡♥t t♦ t❤❡ ❢r❡q✉❡♥t❧② ✉s❡❞ ✶✳✺✖♠ ✇❛✈❡✲ ❧❡♥❣t❤ ✐♥ t❡❧❡❝♦♠♠✉♥✐❝❛t✐♦♥s ✎ ▼✐❝r♦❡❧❡❝tr♦♥✐❝s❀ ✇❤❡r❡ t❤❡ ♣r✐♠❛r② ♠❛t❡r✐❛❧ ✉s❡❞ ✐s s✐❧✐❝♦♥ ❉❡s✐r❡❞ s✐❧✐❝♦♥ str✉❝t✉r❡s ✐♥❝❧✉❞❡s ♠✉❧t✐❧❡✈❡❧ s✐❧✐❝♦♥ st❡♣s✱ ❝♦♥❝❛✈❡✴❝✉r✈❡ s✐❧✐❝♦♥ ♣r♦✲ ☞❧❡s✱ ✉♥❞❡r❝✉t str✉❝t✉r❡s ❛♥❞ ❢r❡❡st❛♥❞✐♥❣ t❤r❡❡ ❞✐♠❡♥s✐♦♥❛❧ str✉❝t✉r❡s✳ ❉✐☛❡r❡♥t ♠❛✲ ❝❤✐♥✐♥❣ t❡❝❤♥✐q✉❡s ❛r❡ ✉s❡❞ ❞❡♣❡♥❞✐♥❣ ♦♥ t❤❡ r❡q✉✐r❡♠❡♥t ❛♥❞ t❤❡ t②♣❡ ♦❢ str✉❝t✉r❡s t♦ ♠❛❝❤✐♥❡ ❞✉❡ t♦ ✐♥❞✐✈✐❞✉❛❧ ❧✐♠✐t❛t✐♦♥s ♦❢ t❤❡ ❞✐☛❡r❡♥t ♠❛❝❤✐♥✐♥❣ t❡❝❤♥✐q✉❡s✳ ▼♦r❡♦✈❡r✱ ♠❛♥② ❝♦♠♣❧✐❝❛t❡❞ ♣r♦❝❡ss ✐♥✈♦❧✈✐♥❣ ❞✐☛❡r❡♥t s❛❝r✐☞❝✐❛❧ ♠❛t❡r✐❛❧s✱ ♠✉❧t✐♣❧❡ ❝♦❛t✐♥❣s✱ ❞✐❢✲ ✷✼ ✐rr❛❞✐❛t✐♦♥ ✐s ❛❜❧❡ t♦ ❛❝❤✐❡✈❡ ❛❧❧ t❤❡s❡ ❞✐☛❡r❡♥t str✉❝t✉r❡s ❜② ❝♦♥tr♦❧❧✐♥❣ ❛♥❞ ❧✐♠✐t✐♥❣ P❙✐ ❢♦r♠❛t✐♦♥✱ ❜♦t❤ ✐♥ t❤❡ ❧❛t❡r❛❧❧② ❛♥❞ ✈❡rt✐❝❛❧ s❡♥s❡✱ t♦ ❛❝❤✐❡✈❡ tr✉❡ t❤r❡❡ ❞✐♠❡♥s✐♦♥❛❧ s✐❧✐❝♦♥ ♠❛❝❤✐♥✐♥❣✳ [...]... of reactions then occurs to other surrounding silicon atoms, e ectively breaking down the silicon structure on the surface of the substrate and pores starts to form 2 .1. 3 Formation of passivated layer Figure 2.3: (a) Enlargement of the silicon bandgap arising from quantum con nement e ect as the remaining silicon islands gets smaller From [16 ] (b) I-V plots showing regions of PSi formation and region... proton irradiation on silicon is very di erent Nevertheless, most of the advantages mentioned for proton beam lithography on resist materials applies The e ects and modi cations to silicon by ion irradiation will be discussed in greater details in the next section For this thesis, two main methods of irradiation will be employed; they are the above mentioned direct proton beam writing (Chapter 2.4 .1) and... and silicon with variable height of machined features can be produced with accurate control over the uence (Fig 2.8) With increasing uence, (10 16 /cm2 ) J reduces to zero across the irradiated line, so little or no PSi is expected to form The above described the e ects of ion irradiation on PSi formation This forms the backbone of all the work presented in this thesis In general, micromachining of PSi... area irradiation (Chapter 2.4.2) 2.3 E ects of irradiations on silicon Proton and helium ion irradiation in silicon results in damages to the crystal lattice and this may be used in many di erent ways Protons lose energy as they penetrate the silicon wafer and stop at a well-de ned end of range This stopping process damages the silicon crystal by producing additional vacancies/defects in the silicon. .. of PSi formation and region of electropolishing At small applied bias, formation of PSi occurs, however, beyond the critical voltage value, electropolishing takes over From [19 ] The previous section explains the mechanism for silicon removal/dissolution, however, it does not explain why the dissolution stops and forms a porous layer instead of the 8 complete removal of silicon atoms from the surface... For pore formation, it is believed to be the result of the development of a passivation (chemically inactive) layer Here, passivation of the PSi layer is caused by quantum con nement e ects arising from the remaining silicon islands after the initial removal of some silicon atoms As silicon atoms are continually removed at the surface, pores/voids are formed The small size of the remaining silicon islands... for irradiation are the defect generation rate per ion their end of range in silicon given the same energy Fig 2.5(a) and (c) were plotted using the SRIM software [30] and they show the di erence in the defect density generated by 10 00 2MeV protons and 10 00 2MeV helium per ion per Angstrom From these two plots, it can be seen that the end of range of helium is much lesser than proton at 2MeV In addition,... relieved machined silicon surface After the anodization and creating a layer/layers of PSi, raising the voltage above the critical value would allow for the total dissolution of silicon atoms at the end of the PSi layer and result in the detachment of the PSi lm from the bulk silicon substrate 2.2 Ion irradiation A new direct-writing lithographic process that uses a focused beam of MeV protons to pattern... PSi or silicon structures and devices are accomplished by the following steps: 1 Preparation of pattern to be irradiated Depending on the type of irradiation used (large area or PBW), the patterns are prepared di erently For PBW, an image in 16 2.4 Centre for Ion Beam Applications (CIBA) At CIBA, energetic ions are produced by a 3.5 MV high brightness High Voltage Engineering Europa SingletronT M ion. .. quantization of energy of both the electrons and holes The appearance of bound states for holes results in the lowering of the valence band maximum while the appearance of bound states for electrons heightens the conduction band minimum (Fig 2.3(a)) This e ectively means the enlargement of the silicon band gap [19 ] A small potential barrier is thus set up at the interface between the bulk silicon and .

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