lý thuyết hóa hữu cơ

LTĐH Tổng hợp Hữu cơ 1  Trong một vài năm gần đây, đề thi hóa học có phần khó hơn các năm trước-đặc biệt khó ở các câu lý thuyết. Đối với các câu hỏi lý thuyết thì ngoài việc nắm vững kiến thức về tính chất, hiện tượng, phương trình…Các em cần “ tỉnh táo” đọc thật kỹ và phân tích câu hỏi sẽ giúp các em phá bẫy gài trong các câu hỏi.  Nhằm hướng kỳ thi tuyển sinh ĐH- CĐ 2012, Tài liệu tổng hợp lý thuyết hóa vô cơ giúp các em bước đầu làm quen và dần trở thành phản xạ với các dạng câu hỏi lý thuyết hữu cơ đếm, đúng-sai…Tài liệu được tổng hợp từ diễn đàn học tập http://www.facebook.com/groups/nhungnguoiyeuhoa/ và các đề thi thử từ các năm của các trường THPT trên cả nước. Hi vọng với bộ tài liệu này sẽ giúp các em tự tin hơn trước kỳ thi ĐH-CĐ đang tới gần. Chúc các em thành công ! Vi Nhân Nan Câu 1.  : propen ; isobutilen; propin, buta-1,3- stiren    A. 5 B. 6 C. 3 D. 4 Câu 2. -metylbutan-2- A. 2-metyl but-2-en B. 2-metyl but-1-en C. 3-metyl but-1-en D. Pent-1-en Câu 3. -(CH 2 ) 4 - 1  Y 2  1  8 H 14 O 4  A. C 2 H 5 OH B. CH 3 OH C. CH 3  2 H 5 OH D. C 3 H 5 OH Câu 4. - : A. cacbonyl B.  C. amin D. cacboxyl Câu 5.    NaOH X 1    duHCl X 2  2  A. H 2 N-CH 2 -COONa B. H 2 N-CH 2 -COOH C. ClH 3 N-CH 2 -COOH D. ClH 3 NCH 2 COONa Câu 6. Câu 6.   3 COOH, CH 3 OH, C 3 H 5 (OH) 3  3 CH=O. A.  B.  3 , dd AgNO 3  3 C.  2 D. O 3  3 Câu 7.  [- NH-(CH 2 ) 6 - NH-CO - (CH 2 ) 4 - CO-] n (1); [-NH-(CH 2 ) 5 -CO -] n (2) ; [-NH-(CH 2 ) 6 - CO-] n (3) ; [C 6 H 7 O 2 (OOCCH 3 ) 3 ] n (4) ; (-CH 2 -CH 2 -) n (5) ; (-CH 2 -CH=CH-CH 2 -) n (6) .  A. (5); (6) B. (4); (5); (6) C. (1); (2); (3); (4) D. (3); (4); (5); (6) Câu 8.  4 H 6 O 2 . Y   A. HCOO-CH=CH-CH 3 B. CH 2 =CH-COOCH 3 C. HCOO-C(CH 3 )=CH 2 D. HCOO-CH 2 -CH=C Câu 9.  3 H 7 O 2 N.  1  2 H 4 O 2 NNa.   : A. H 2 N-CH 2 -COOCH 3 B. H 2 N-CH 2 -COOCH 2 CH 3 C. CH 3 -CH(NH 2 )-COOH D. CH 3 -CH 2 COONH 4 Câu 10.  8 H 10 O 2   8 H 6 O 2  A. 4 B. 5 C. 3 D. 2 Câu 11.  : axit axetic (1) ; axit acrylic (2)    A. (2) < (3) < (1) < (4) B. (3) < (1) < (2) < (4) C. (3) < (4) < (1) < (2) D. (1) < (2) < (3) < (4) Câu 12.  2  1 ; X + O 2  2 ; X 2 + X 1  6 H 10 O 2 + H 2 O.  : A. CH 3 CH=O B. CH 3 CH 2 CH=O C. CH 2 =C(CH 3 )-CH=O D. CH 2 =CH-CH=O Câu 13.   2  A. 1,2- B. 1,1- C. 1,1,2,2-tetraclo etan D. 1,1,1-triclo etan Câu 14.   2  3 /NH 3   A. -CH=O B.  3 CH=O C. O=CH--CH 2 -CH=O D. CH 3 --CH 2 -CH=O Câu 15.  2 SO 4   A.  B.  LTĐH Tổng hợp Hữu cơ 2 C.  D.  Câu 16.  5 H 10  4   5 H 12 O 2   A. But-2-en B. But-1-en C. 2-metyl buten-2 D. 2-metyl but-1-en Câu 17.  2  - alanin.  A. H 2 N-C(CH 3 ) 2 -COOC 2 H 5 B. ClH 3 N-CH(CH 3 )-COOC 2 H 5 C. H 2 N-CH(CH 3 )-COOC 2 H 5 D. ClH 3 N-CH 2 -COOC 2 H 5 Câu 18.  3 / NH 3  ? A.  B.  C.  D.  Câu 19.  : X (C x H y Br z ) + NaOH (t 0   A. C 6 H 10 Br 4 B. C 6 H 8 Br 2 C. C 6 H 6 Br 2 D. C 6 H 8 Br 4 Câu 20.  (X) + dd NaOH (t 0  (1);  0  4 + (P) (2) CH 4 (t 0  2 (3); (Q) + H 2 O (xt, t 0  (4)  A. CH 3 COOCH=CH 2 CHO B. HCOOCH=CH 2  C. CH 3 COOCH=CH 2  3 CHO D. CH 3 COOC 2 H 5  3 CHO Câu 21.   A. 4 B. 5 C. 6 D. 3 Câu 22.  3 H 9 O 2   A. HCOONH 2 (CH 3 ) 2 B. CH 3 COONH 3 -CH 3 C. CH 3 CH 2 COONH 4 D. HCOONH 3 -CH 2 CH 3 Câu 23.  : benzen (1) ; toluen (2); p- A. (4) < (1) < (2) < (3) B. (1) < (2) < (3) < (4) C. (4) < (1) < (3) < (2) D. (3) < (4) < (1) < (2) Câu 24.  2 SO 4  0   : nCO 2 : nH 2 O = 0,25 : 1 :   A. CH 3  2 H 5 OH B. CH 3  2 =CH-CH 2 OH C. C 2 H 5  2 =CH-CH 2 OH D. C 2 H 5  2 =CHOH Câu 25.  3 H 6 O 2  3  3 ,t 0   0  A. HO-CH 2 -CH 2 -CH=O B. CH 3 -CH 2 -COOH C. CH 3 -CH(OH)-CH=O D. HCOO-CH 2 CH 3 Câu 26.   3 / NH 3 thu  A. 2 B. 4 C. 1 D. 3 Câu 27.     A. CH 4 . B. C 2 H 6 . C. C 3 H 8 . D. C 4 H 10 . Câu 28.  2 .  A. C 2 H 4 . B. C 4 H 8 . C. C 3 H 6 . D. C 5 H 10 . Câu 29.  A. metylamin. B. etylamin. C. pentylamin. D. phenylamin. Câu 30.  (1) NH 3 , (2) CH 3 NH 2 , (3) C 6 H 5 NH 2 , (4) (CH 3 ) 2 NH, (5) C 2 H 5 NH 2 , (6) p-O 2 N-C 6 H 4 NH 2 . A. 6, 3, 1, 2, 5, 4. B. 3, 6, 1, 2, 4, 5. C. 4, 5, 2, 3, 1, 6. D. 1, 2, 3, 4, 5, 6. Câu 31.  3 ) 2 CHCH(OH)CH 3   A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-2. Câu 32. C 4 H 8 - -2----2-  A. 2--2. B. 2-. C. buten--2. D. buten- Câu 33. :  Metylamin (2), Amoniac (3), Anilin (4), p-metylanilin (5), p-nitroanilin (6). LTĐH Tổng hợp Hữu cơ 3  A. (1), (2), (3), (4), (5), (6) B. (3), (2), (1), (4), (5), (6) C. (6), (4), (5), (3), (2), (1) D. (6), (5), (4), (3), (2), (1) Câu 34.   A. Na. B.  C.  D.  2 . Câu 35.  6 H 5 NH 3     2 . C.  3 , NaOH, Br 2 .  3 , Br 2 Câu 36.   CH 3 OH(1), C 2 H 5 OH(2), CH 3 COOH(3), CH 3 COOC 2 H 5 (4), HCHO(5). A. 5, 4, 1, 2, 3. B. 1, 2, 3, 4, 5. C. 5, 4, 3, 2, 1. D. 3, 2, 1, 5, 4. Câu 37. Tron 8 H 10        OH 2 (Y)   xtpt ,,  A. 1. B. 3. C. 4. D. 2. Câu 38.    A. C 7 H 8 O. B. C 8 H 10 O. C. C 9 H 12 O. D. C 10 H 14 O. Câu 39.  3 H 4 O 2 , C 3 H 6 O 2 , C 4 H 6 O 2 , C 4 H 8 O 2    A. C 3 H 4 O 2  4 H 8 O 2 . B. C 3 H 4 O 2  4 H 6 O 2 . C. C 3 H 4 O 2  3 H 6 O 2 . D. C 4 H 6 O 2  4 H 8 O 2 . Câu 40.  2 (OCOC 17 H 33 )-CH(OCOC 15 H 31 )-CH 2 (OCOC 17 H 29  2   A. 1. B. 3. C. 4. D. 5. Câu 41.   A. CH 2 =CH-COOCH 3 . B. CH 2 =CH-COOH. C. CH 2 =CH-COOC 2 H 5 . D. CH 2 =CH-OCOCH 3 . Câu 42.    len (3);   Nilon-6,6 (6);    A. (1), (2), (3). B. (2), (3), (4) C. (1), (4), (5). D. (4), (6), (7). Câu 43.  2 O o axit,t         Câu 44.   B. phenolphtalein.   Câu 45.  2   A. 4 B. 6 C. 5 D. 3 Câu 46.  a) 6X xt  Y b) X + O 2 xt  Z c) E + H 2 O xt  G d) E + Z xt  F e) F + H 2 O H   Z + G.  A.  B.  C.  2 O trong NH 3 . D.  Câu 47. S  4 H 9 NO 2    A. 2 B. 3 C. 4 D. 5 Câu 48. --   C.  3 /NH 3   4 . Câu 49.   A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2-. LTĐH Tổng hợp Hữu cơ 4 Câu 50.     A.CH 2 H 2 . B. CH 3  3 C. HCOOCH=CHCH 3  3 CH=CHCOOH D. CH 2 =CHCH 2  3 COOCH=CH 2 Câu 51.  2 t A. 2 B. 3 C.4 D.5 Câu 52.   A. H 2 NCH 2 COOH B.H 2 NCH(COOH) 2 C. H 2 NCH 2 CH 2 COOH D. H 2 NCH 2 CH(COOH) 2 Câu 53.  2 CO 3   3 /NH 3  A. HCOOH B. HCOOCH 3 C. HCHO D. CH 3 COOH Câu 54.    A. 15,1 gam. B. 16,1 gam. C. 17,1 gam. D. 18,1 gam. Câu 55.  2   2  2 O trong dun 3 sinh  A. HCOOC 2 H 5 B. C 2 H 5 COOH C. HOOC-CHO D. HOCH 2 CH 2 CHO Câu 56.  A. CuO(t o ) ; Ag 2 O/NH 3 B. CH 3 COOH; NaOH C. H 2 SO  (170 o C) D. O 2 (men gi Câu 57. Cho H 2 SO 4    2 SO 4 .  2 .  2 .  2 S. Câu 58.  A.  B. etyl sec- C.  D.  Câu 59.  A. Axit no. B. Axit    Câu 60.  A. H 2 SO 4  B. H 2 SO 4  C.   Câu 61.   B.   D Câu 62.  6 H 14  2 SO 4  o  A. 2,3--2. B. 2,3--1. C. 2-metyl pentanol-3. D. 3,3--2. Câu 63.  4 H 8  brom 2-metyl propan  A. 2--2. B. 2- C. buten--2. D. buten- Câu 64.  2 , (2) Ag 2 O/NH 3 , (3) H 2 /Ni, t 0 , (4) H 2 SO 4   A. (2), (3), (4). B. (2), (4). C. (1), (2), (4). D. (3), (4). Câu 65.   A. 609,83 kg. B. 619,83 kg. C. 629,83 kg. D. 639,83 kg. Câu 66.  6 H 6    .  Câu 67.   2 , 6,3 gam H 2  2    A. CH 3 COOCH 2 NH 2 . B. H 2 NCH 2 COOCH 3. C. CH 3 CH(NH 2 )COOCH 3 D. H 2 NCH 2 CH 2 COOCH 3 Câu 68. Cho 1,47 gam  -  A. H 2 NCH 2 COOH. B. CH 3 CH(NH 2 )COOH. C. CH 3 (CH 2 ) 4 CH(NH 2 )COOH. D. HOOCCH 2 CH 2 CH(NH 2 )COOH. LTĐH Tổng hợp Hữu cơ 5 Câu 69.  3 -CH=CH 2, CH 2 (OH)CH 2 (OH), NH 2 -CH 2 -COOH, CH 2    A. HO-CH 2 -CH 2 - 2 -CH 2 -COOH. B. HO-CH 2 -CH 2 - 3 -CH=CH 2 . C. CH 2  3 -CH=CH 2 . D. CH 3 -CH=CH 2  2 -CH 2 -COOH. Câu 70.    len (3), (4),   -6,6 (7).  A.(2), (3), (4), (6). B. (1), (2), (5). C. (1), (4), (6). D. (2), (3), (5), (7). Câu 71.  3 ) 2 CHCH(OH)CH 3   A. 2-metylbuten-1. B. 2-metylbuten-2. C. 3-metylbuten-1. D. penten-1. Câu 72.  7 H 8  A. 2. B. 3. C. 4. D. 5. Câu 73.  n H 2n -2 O 2   A. axit acrylic. B. axit metacrilic. C. axit oleic. D. axit linoleic. Câu 74.    3 COOH. B. CH 3  2 H 5 COOH. C. C 2 H 5  3 H 7 COOH. D. C 3 H 7  4 H 9 COOH. Câu 75.  3 H 4 O 2 , C 3 H 6 O 2 , C 4 H 6 O 2 , C 4 H 8 O 2  không  A. C 3 H 4 O 2  4 H 8 O 2 . B. C 3 H 4 O 2  4 H 6 O 2 . C. C 3 H 4 O 2  3 H 6 O 2 . D. C 3 H 6 O 2  4 H 8 O 2 . Câu 76.     A. C 3 H 5 (OOCC 17 H 35 ) 3 . B. C 3 H 5 (OOCC 17 H 33 ) 3. C. C 3 H 5 (OOCC 17 H 31 ) 3 . D. C 3 H 5 (OOCC 15 H 31 ) 3 . Câu 77.   A. pentan. B. xiclopentan. C. 2- metylbutan. D. 2,2- Câu 78.       phenic, axit picric, axit axetic, axit propionic. Câu 79.  8 H 14 O 4   3   A. CH 3 OCOCH 2 CH(CH 3 )CH 2 COOCH 3 . B. CH 3 OCOCH(CH 3 )CH(CH 3 )COOCH 3 . C. CH 3 OCOCH 2 C(CH 3 ) 2 COOCH 3 . D. CH 3 OCOCH 2 CH 2 CH 2 CH 2 COOCH 3 . Câu 80.     A. H 2 N-CH 2 -CH 2 -COOH B. CH 3 -CH(NH 2 )-COOH C. H 2 N-CH 2 -COO-CH 3 D. CH 2 =CH-COO-NH 4 Câu 81.  2   2  2  3 sinh ra A A. HCOOCH 2 CH 3 B. C 2 H 5 COOH C. HOOC-CHO D. HOCH 2 CH 2 CHO Câu 82.  4 H 6 O 2   2  o     A. CH 3 -COO-CH=CH 2 . B. CH 2 =CH-CH 2 -COOH. C. CH 2 =CH-O-CH 2 -CHO. D. CH 3 -CH=CH-COOH. Câu 83.  n H m O z  A. m = 2n + 2. B. m = 2n + 1. C. m = 2n  z. D. m = 2n + z. Câu 84.  cb   A. 0,155 mol B. 0,55 mol C. 0,645 mol D. 0,845 mol LTĐH Tổng hợp Hữu cơ 6 Câu 85.  2 SO 4  o   2 SO 4  o    A. X: CH 3 CH 2 OH 43,39%; Y: CH 3 CH 2 CH 2 OH ; Z: CH 3 CHOHCH 3 B. X: CH 3 CH 2 OH 33,39%; Y: CH 3 CH 2 CH 2 OH Z: CH 3 CHOHCH 3 C. X: CH 3 CH 2 CH 2 OH 43,39%; Y: CH 3 CH 2 CH 2 CH 2 OH Z: CH 3 CH 2 CHOHCH 3 D. X: CH 3 CH 2 CH 2 OH 33,39%; Y: CH 3 CH 2 CH 2 CH 2 OH Z: CH 3 CH 2 CHOHCH 3 Câu 86.  A. Poli(vinyl clorua) B. Poliacrilonitrin C. Polimetylmetacrylat  Câu 87. không  A.  2 SO 4  o  B.  C.   D.  2  Câu 88.    2  2  4  2 Câu 89.  2   2    A. C n H 2n  1 CHO B. C n H 2n (CHO) 2 C. C n H 2n + 1 CHO D. C n H 2n  2 (CHO) 2 . Câu 90.      Câu 91.  C 2 H 6  C 2 H 5 Cl  C 2 H 5 OH  CH 3 CHO  CH 3 COOH  CH 3 COOC 2 H 5  C 2 H 5 OH  A. 2 B. 3 C. 4 D. 6 Câu 92.  2  2    B. X l    Câu 93.      Câu 94.  2 O/NH 3  A. axetandehit, butin -1, eten B. axetandehit, butin -2, etin C. natri fomiat, vinylaxetilen, etin D. natri fomiat, vinylaxetilen, eten. Câu 95.  -NH 2   A. H 2 NCH 2 COOH B. H 2 NCH 2 CH 2 COOH C. CH 3 CH 2 CH(NH 2 )COOH D. CH 3 CH(NH 2 )COOH Câu 96.  2   A. HOOC-CH 2 CH 2 -COOH B. C 2 H 5 COOH C. CH 3 -COOH D. HOOC-COOH. Câu 97.  6 H 6 O 2    A. 3. B. 4. C. 1. D. 2. Câu 98.  A. 5. B. 4. C. 3. D. 2. Câu 99.  2 H 5 OH, CH 3 CHO, CH 3  3 COOH b A.  2 SO 4 . B. Ag 2 O/NH 3  2 SO 4 . C. Cu(OH) 2  D.  2 SO 4 . Câu 100.   anken  polime.  5 H 12  A. 3. B. 4. C. 5. D. 6. Câu 101.  2 H 6 , C 2 H 4 , CH 3 CHO, CH 3 COOCH=CH 2  C 2 H 2  X  Y  CH 3 COOH. A. 4. B. 3. C. 2. D. 1. Câu 102. C 4 H 8 O 2  -  A. 3. B. 4. C. 5. D. 6. Câu 103.  + CuO + O 2 + CH 3 OH trùng hợp LTĐH Tổng hợp Hữu cơ 7 X  Y  D  E    A. CH 3 CH(CH 3 )CH 2 OH. B. CH 2 =C(CH 3 )CH 2 OH. C. CH 2 =C(CH 3 )CH 2 CH 2 OH. D. CH 3 CH(CH 3 )CH 2 CH 2 OH. Câu 104.  1-  2-  3-  4-  3  2 SO 4 - 5- -bromanilin.  A. 1, 2, 4. B. 2, 3, 4. C. 1, 4, 5. D. 1, 3, 4. Câu 105. Cho   A.  B.  C.  D.  Câu 106.   A. metyl propionat. B. metyl panmitat. C. metyl oleat. D. metyl acrylat. Câu 107.   A. HCOOH. B. CH 3 COOH. C. C 2 H 5 COOH. D. C 2 H 3 COOH. Câu 108.   1) X, Y l  3) t.   A. (1), (2). B. (2), (3). C. (3), (4). D. (1), (3). Câu 109. - 2 SO 4  o  o   A. 5. B. 6. C. 8. D. 9. Câu 110.  4 H 10 O, C 4 H 9 Cl, C 4 H 10 , C 4 H 11  A. C 4 H 9 Cl, C 4 H 10 , C 4 H 10 O, C 4 H 11 N. B. C 4 H 11 N, C 4 H 9 Cl, C 4 H 10 O, C 4 H 10 . C. C 4 H 11 N, C 4 H 10 O, C 4 H 9 Cl, C 4 H 10 . D. C 4 H 11 N, C 4 H 10 O, C 4 H 10 , C 4 H 9 Cl. Câu 111.  CH 2 =CH 2 + KMnO 4 + H 2 SO 4  (COOH) 2 + MnSO 4 + K 2 SO 4 + H 2 O  A. 5 : 2. B. 2 : 5. C. 2 : 1. D. 1 : 2. Câu 112.  5 H 10 O 2  2 SO 4  o   A. CH 3 COOCH 2 CH 2 CH 3 . B. CH 3 COOCH(CH 3 ) 2 . C. HCOOCH(CH 3 )C 2 H 5 . D. HCOO(CH 2 ) 3 CH 3 . Câu 113.  2   n t o   A. C 2 H 4 . B. C 4 H 4 . C. C 3 H 4 . D. C 2 H 2 . Câu 114.   3    Ba(OH) 2  A. CH 4 , C 2 H 4 , C 2 H 2 . B. C 3 H 8 , C 2 H 4 , C 3 H 4 . C. C 3 H 8 , C 2 H 4 , C 2 H 2 . D. CH 4 , C 2 H 4 , C 3 H 4 . Câu 115.  CH 2 =CH-Cl (1) ; CH 3 -CH 2 -Cl (2) ; CH 2 =CH-CH=O (3) ; CH 3 -CH=O (4).  A. 1, 2, 3, 4 B.3, 4, 2, 1 C. 3, 4, 1, 2 D. 4, 3, 2, 1. Câu 116.  Z   A. 3. B. 6. C. 5. D. 7. Câu 117.  X + H 2  X + O 2   4 H 4 O 4 + 2H 2 O.  A. Y : CH 3 OH ; Z : C 2 H 2 O 4 B. Y : C 2 H 4 (OH) 2 ; Z : H 2 CO 2 C. Y : C 2 H 5 OH ; Z : C 2 H 2 O 4 D. Y : C 2 H 4 (OH) 2 ; Z : C 2 H 2 O 4 LTĐH Tổng hợp Hữu cơ 8 Câu 118.   3 H 8   1  1  1  1   A. propanol--2 B. propanol--1 C. propanol- -1 Câu 119.  1   1  1   2  3  2   2  3   2 CH 2 CH 2 CH 2 OH B. CH 3 CH 2 COO 3 CH 2 CH 2 OH C. CH 3  2 CH 2 OH D. NaOOCCH 2  3 OH. Câu 120.   c.    Câu 121.   2  2  2   1  1  1   A. HCOOH 3 NCH 3 B. CH 3 COONH 4 C. CH 3 CH 2 COONH 4 D. CH 3 COOH 3 NCH 3 Câu 122.  8 H 14 O 4  a) C 8 H 14 O 4  1 + X 2 + H 2 O. b) X 1 + H 2 SO 4  3 + Na 2 SO 4 c) nX 3 + nX 4 -6,6 + nH 2 O d) 2X 2 + X 3  5 + 2H 2 O X (C 8 H 14 O 4  A. HCOO(CH 2 ) 6 OOCH B. CH 3 OOC(CH 2 ) 4 COOCH 3 C. CH 3 OOC(CH 2 ) 5 COOH D. CH 3 CH 2 OOC(CH 2 ) 4 COOH Câu 123.  HOOCC 6 H 4   A. Nilon-6,6 B. Capron C. Lapsan D. Enang. Câu 124.       Câu 125.  2 HO n < 2 CO n      Câu 126.  5 H 8 : A. 10. B. 11. C. 9. D. 8. Câu 127.  2  2   2  C=12) A. CH 2 =CH 2 . B. CH 2 =CH-CH 2 -CH 3 . C. CH 3 -C(CH 3 )=C(CH 3 )-CH 3 . D. CH 3 -CH=CH-CH 3 . Câu 128.  A.  6,6. B.  C.  D. visco. Câu 129.  3 H 7 O 2  A. 5. B. 8. C. 7. D. 6. Câu 130.  2 O/NH 3  2  2   A.  B.  C.  D.  Câu 131.  3  2 SO 4    A. [C 6 H 7 (OH) 3 ] n , [C 6 H 7 (OH) 2 NO 3 ] n B. [C 6 H 7 (OH) 2 NO 3 ] n , [C 6 H 7 OH(NO 3 ) 2 ] n . C. [C 6 H 7 OH(NO 3 ) 2 ] n , [C 6 H 7 (NO 3 ) 3 ] n . D. [C 6 H 7 (OH) 2 NO 3 ] n , [C 6 H 7 (NO 3 ) 3 ] n . Câu 132.  C 2 H 5 O-H (1), CH 3 CO(O-H) (2), HCO(O-H) (3), C 6 H 5 O-H (4), R-C=CH-H (5), R--H (6)  A. 1 < 4 < 3 < 2 < 5 < 6. B. 5 < 6 < 1 < 4 < 2 < 3. LTĐH Tổng hợp Hữu cơ 9 C. 4 < 1 < 3 < 2 < 6 < 5. D. 6 < 5 < 4 < 1< 2 < 3. Câu 133. -  A. 1. B. 2. C. 3. D. 4. Câu 134.                 A.  B.  C.  D.  Câu 135.  6 H 14   A. 2. B. 3. C. 4. D. 5. Câu 136. Phenol không  A. Na. B. HCl. C. NaOH. D.  2 . Câu 137. không đúng   A. H 2 xt Ni, t 0 . B. K 2 ZnO 2 . C. Ag 2 O/NH 3 . D. Zn. Câu 138.   Y/X = xx  A. 1 < x < 1,36. B. 1,36 < x < 1,53. C. 1,53 < x < 1,62. D. 1,62 < x < 1,75. Câu 139.    A. CH(COOCH 3 ) 3 . B. CH 3 CH 2 OOC  COOCH 2 CH 3 C. C 2 H 5 OOC  CH 2  COOC 2 H 5 . D. C 2 H 5 OOC  CH 2  CH 2  COOC 2 H 5. Câu 140.  A. Cu(OH) 2 . B.  2 . C. DD CuSO 4 . D.  Câu 141.  2 H 3 COOH, HCOOCH 3 , C 2 H 3 COOCH 3   A. CaCO 3  B. dd Br 2 , dd Ag 2 O/NH 3 . C. dd Ag 2 O/NH 3 , Zn. D. dd NaOH, dd Br 2 . Câu 142. uen  X  Y  p-  A. HNO 3  2 SO 4  B. Fe, CO 2  2 . C. Cl 2 , HCl, NH 3 , dd NaOH. D. Fe, HCl, NaOH, HNO 3  Câu 143.    A. HCOO-CH 2 -CH 2 -COO-CH 3 . B. HCOO-CH 2 -CH 2 -OOC-CH 3 . C. HCOO-CH 2 -CH 2 -OOC-C 2 H 5 . D. CH 3 -COO-CH 2 -CH(OOCH)-CH 2 -OOC-CH 3 . Câu 144.  A. dd NH 3 . B. dd H 2 S. C. dd H 2 SO 4  D. dd H 2 SO 4  Câu 145.    A. HCOOH, CH 3 OH, HCOOCH 3 . B. CH 3 COOH, CH 3 OH, CH 3 COOCH 3 . C. CH 3 COOH, C 2 H 5 OH, CH 3 COOC 2 H 5 . D. HCOOH, C 3 H 7 OH, HCOOC 3 H 7 . Câu 146.    A. AgNO 3 /NH 3 . B. HNO 3 /H 2 SO 4 . C. Cu(OH) 2  D. I 2 /CCl 4 . Câu 147.   A. dd Br 2  4 . B. dd Br 2  2 O/NH 3 . C. dd HNO 3  D.  2 O/NH 3 . Câu 148.    A. 7,725 gam. B. 3,3375 gam. C. 6,675 gam. D. 5,625 gam. Câu 149. C 4 H 8 O 2 a b   2 O/NH 3 a b  A. 5; 1. B. 6; 2. C. 4; 1. D. 7; 2. Câu 150.  LTĐH Tổng hợp Hữu cơ 10 A. CH 2 =CH 2 , CH 2 =CHCHO, C 6 H 5 CHO. B. CH 3 CHO, HCOOH, HCOOCH 3 . C. CHCH, CH 3 CHO, HCO-CHO. D. HCHO, CH 3 COCH 3 , HCOOH. Câu 151.  .    Câu 152. Axit axetic CH 3  A. CH 3 CHO, C 2 H 5  6 H 5 Cl. B. C 2 H 4 , C 2 H 5  3 OCH 3 . C. CH 3 CHO, CH 3 COOCH 3 , C 2 H 5 OH. D. C 2 H 5 OH, C 2 H 5 Cl, CH 3 CHCl 3 . Câu 153.  3 CHO, C 6 H 12 O 6    3 / NH 3 .  .  D. Cu(OH) 2 . Câu 154.  2 H 5 O) n    A. HO-CH 2 -CH(CH 3 )-CH 2 -OH. B. CH 3 -CH 2 -CHOH-CH 2 OH. C. HO-CH 2 -CH 2 -CH 2 -CH 2 -OH. D. CH 3 -CHOH-CHOH-CH 3 . Câu 155.      Câu 156.  . B  Câu 157.  6 H 10 O 5 ) : A. 56. B. 57. C. 58. D. 59. Câu 158.  A. C 6 H 5 OH, C 2 H 5 NH 2 ,CH 3 COOH. B. CH 3 NH 2 , C 2 H 5 NH 2 , CH 3 COOH. C. C 6 H 5 NH 2  3 NH 2 , C 2 H 5 NH 2 . D. (C 6 H 5 ) 2 NH, (CH 3 ) 2 NH, NH 2 CH 2 COOH. Câu 159.    A. NH 2 CH 2 CH 2 C OOH. B. CH 2 =CHCOONH 4 . C. HCOOCH 2 CH 2 NH 2 . D. NH 2 CH 2 COOCH 3 Câu 160.  C 2 H 2 A B D C 6 H 5 NH 2  A. C 6 H 6 , C 6 H 5 NO 2 , C 6 H 5 NH 3 Cl. B. C 6 H 6 , C 6 H 5 Cl, C 6 H 5 NO 2 . C. C 6 H 12 , C 6 H 6 , C 6 H 5 NO 2 . D. C 6 H 6 , C 6 H 5 NO 2 , C 6 H 4 (NO 2 ) 2 . Câu 161.  A. tinh b-6,6 B. xenl-6,6. C. PE, PVC, polistiren. -6,6. Câu 162. -2-en-1-  B. CO 2 . .  2 . Câu 163.   2 . B. Na, NaOH, CaCO 3 . C. Na, H 2 , NaOH. D. CaCO 3 , Cu, NaOH. Câu 164.  xit axetic.    Câu 165.  3 H 6 O 2   A. CH 3 CH 2 COOH . B. CH 3 COOCH 3 . C. HO-CH 2 CH 2 CHO D. HO-CH 2 COCH 3 . Câu 166.  A. axit lactic. B. axit axetic. C. axit fomic. D. axit glutamic. Câu 167.  2  C: A. CH 3 COOCH=CH-CH 3 . B. C 2 H 5 COOCH=CH 2 . C. HCOOCH=CH-CH 2 -CH 3 . D. CH 2 =CH-COO-C 2 H 5 . Câu 168. - A. 3. B. 4. C. 5. D. 6. Câu 169.  C 2 H 6  2 H 5  2 H 5  3  3 COO 3 COOC 2 H 5  2 H 5 OH   A. 2. B. 3. C. 4. D. 5. Câu 170.   A. butan. B. 2-metylpropan. C. 3-metylpentan. D. 2,3- Câu 171.    (Cho H = 1; C = 12; O = 16) [...]... metacrilat C etyl metacrilat D metyl isobutirat Cõu 370 A ch cha mt loi nhúm chc, cú CTPT C4H6O2 v{ phự hp vi d~y bin húa sau: H2 H2 O truứ ng hụù p A B C caosu buna Ni,t o xt, t o Cụng thc cu to hp lý cú th cú ca A l{ A 1 B 2 C 3 D 4 Cõu 371 Đốt cháy hoàn toàn hỗn hợp 2 r-ợu no mạch hở, thu đ-ợc 15,4gam CO2 v 8,1 gam H2O Số mol hỗn hợp r-ợu là: A 0,01mol B 0,05mol C 0,1mol D 0,2mol Cp nht T4/2012 . lý thuyết hữu cơ đếm, đúng-sai…Tài liệu được tổng hợp từ diễn đàn học tập http://www.facebook .com/ groups/nhungnguoiyeuhoa/ và các đề thi thử từ các năm của các trường THPT trên cả nước. Hi