Thermodynamic Data of Copolymer Solutions Part 8 pot

7. SECOND VIRIAL COEFFICIENTS (A 2 ) OF COPOLYMER SOLUTIONS 7.1. Experimental A 2 data Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ Acrylonitrile/α-methylstyrene copolymer 46.0 mol% acrylonitrile AN-αMS/46x 79GL2 _____________________________________________________________________________ Acrylonitrile/vinylidene chloride copolymer 59.0 wt% acrylonitrile AN-VdC/59w 86KAM _____________________________________________________________________________ Butadiene/styrene copolymer 14.6 mol% styrene B-S/15x(1) 79STA 15.5 mol% styrene B-S/15x(2) 79STA 23.9 mol% styrene B-S/24x 79STA 25.0 mol% styrene B-S/25x 79STA 25.0 mol% styrene B-S/25x(9/51) 61COO (9 mol% 1,4-cis, 51 mol% 1,4-trans) 25.0 mol% styrene B-S/25x(9/54) 61COO (9 mol% 1,4-cis, 54 mol% 1,4-trans) 29.0 mol% styrene B-S/29x(8/50) 61COO (7.8 mol% 1,4-cis, 50.4 mol% 1,4-trans) 30.0 mol% styrene B-S/30x(13/45) 61COO (12.6 mol% 1,4-cis, 44.8 mol% 1,4-trans) 38.7 mol% styrene B-S/39x(1) 79STA 39.4 mol% styrene B-S/39x(2) 79STA 62.4 mol% styrene B-S/62x 79STA 63.6 mol% styrene B-S/64x 79STA _____________________________________________________________________________ Butyl acrylate/methyl methacrylate copolymer 29.5 wt% methyl methacrylate BA-MMA/30w 70WU1 56.0 wt% methyl methacrylate BA-MMA/56w 70WU1 79.5 wt% methyl methacrylate BA-MMA/80w 70WU1 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B)Acronym Ref. _____________________________________________________________________________ Butyl methacrylate/methyl methacrylate copolymer 50.0 wt% methyl methacrylate BMA-MMA/50w 70WU2 _____________________________________________________________________________ Butylene/ethylethylene copolymer 1:1, alternating B-EE/50x 84MAY _____________________________________________________________________________ Ethyl acrylate/methyl methacrylate copolymer 50.0 wt% methyl methacrylate EA-MMA/50w 70WU2 _____________________________________________________________________________ Ethylene/propylene copolymer 1:1, alternating E-P/50x 84MAY _____________________________________________________________________________ Ethylene/tetrafluoroethylene copolymer 1:1, alternating E-TFE/50x 89CHU _____________________________________________________________________________ Ethylene oxide/propylene oxide copolymer 72.4 mol% ethylene oxide EO-PO/72x 91LOU 79.5 mol% ethylene oxide EO-PO/80x 91LOU 86.6 mol% ethylene oxide EO-PO/87x 91LOU _____________________________________________________________________________ 9,9-bis(4-Hydroxyphenyl)fluorene/terephthaloyl chloride copolymer 1:1, alternating HPF-TPC/50x 77TA1 _____________________________________________________________________________ N-Isopropylacrylamide/acrylamide copolymer 15 mol% acrylamide NIPAM-AM/15x 94MUM 30 mol% acrylamide NIPAM-AM/30x 94MUM 45 mol% acrylamide NIPAM-AM/45x 94MUM 60 mol% acrylamide NIPAM-AM/60x 94MUM _____________________________________________________________________________ Isopropylethylene/1-methylbutylene copolymer 1:1, alternating IPE-MB/50x 84MAY _____________________________________________________________________________ Isopropylethylene/1-methyl-1-ethylethylene copolymer 1:1, alternating IPE-MEE/50x 84MAY _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) Acronym Ref. _____________________________________________________________________________ Methyl acrylate/methyl methacrylate copolymer 50.0 wt% methyl methacrylate MA-MMA/50w 70WU2 _____________________________________________________________________________ Methyl methacrylate/acrylonitrile copolymer 23.6 mol% acrylonitrile MMA-AN/24x 82MA2 50.0 mol% acrylonitrile MMA-AN/50x 82MA2 74.0 mol% acrylonitrile MMA-AN/74x 82MA2 _____________________________________________________________________________ 1-Octadecene/maleic anhydride copolymer 1:1, alternating ODC-MAH/50x 85MAT _____________________________________________________________________________ Oxyethylene/oxymethylene copolymer <5 wt% oxyethylene OE-OM/05w 65WAG _____________________________________________________________________________ Pyromellitic acid/4-amino-1,4-phenyleneoxy- 1,4-phenyleneamine copolymer 1:1, alternating P-AA1/50x 77BIR _____________________________________________________________________________ Pyromellitic acid/4-amino-1,4-phenyleneoxy-1, 4-phenylenoxy-1,4-phenyleneamine copolymer 1:1, alternating P-AA2/50x 77BIR _____________________________________________________________________________ Styrene/acrylonitrile copolymer 25.0 wt% acrylonitrile S-AN/25w 98SCH 38.5 mol% acrylonitrile S-AN/38x 77GL1 38.5 mol% acrylonitrile S-AN/38x 77GL2 38.5 mol% acrylonitrile S-AN/38x 79GL1 40.0 mol% acrylonitrile S-AN/40x 89EGO 41.0 mol% acrylonitrile S-AN/41x 89EGO 51.0 mol% acrylonitrile S-AN/51x 82MA1 _____________________________________________________________________________ Styrene/p-methoxystyrene copolymer 26.0 mol% p-methoxystyrene S-pMOS/26x(1) 72PIZ 26.4 mol% p-methoxystyrene S-pMOS/26x(2) 72PIZ 53.0 mol% p-methoxystyrene S-pMOS/53x 72PIZ 53.8 mol% p-methoxystyrene S-pMOS/54x 72PIZ 75.6 mol% p-methoxystyrene S-pMOS/76x(1) 72PIZ 75.6 mol% p-methoxystyrene S-pMOS/76x(2) 72PIZ _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) Acronym Ref. _____________________________________________________________________________ Styrene/methyl methacrylate copolymer 29.8 mol% methyl methacrylate S-MMA/30x 66KOT 43.8 mol% methyl methacrylate S-MMA/44x 66KOT 46.4 wt% methyl methacrylate S-MMA/46w 55STO 70.7 mol% methyl methacrylate S-MMA/71x 66KOT _____________________________________________________________________________ Tetrafluoroethylene/trifluoronitrosomethane copolymer 1:1, alternating TFE-TFNM/50x 61MOR _____________________________________________________________________________ Vinyl acetate/vinyl chloride copolymer 11.4 mol% vinyl acetate VA-VC/11x 85MIN 25.0 mol% vinyl acetate VA-VC/25x 85MIN 40.0 mol% vinyl acetate VA-VC/40x 85MIN 66.0 mol% vinyl acetate VA-VC/66x 85MIN _____________________________________________________________________________ Vinyl acetate/1-vinyl-2-pyrrolidinone copolymer 65.0 mol% 1-vinyl-2-pyrrolidinone VA-NVP/65x 89EGO 71.0 mol% 1-vinyl-2-pyrrolidinone VA-NVP/71x 89EGO 81.0 mol% 1-vinyl-2-pyrrolidinone VA-NVP/81x 89EGO 86.0 mol% 1-vinyl-2-pyrrolidinone VA-NVP/86x 89EGO _____________________________________________________________________________ Vinyl chloride/butyl acrylate copolymer 16.6 mol% butyl acrylate VC-BA/17x 85MIN 40.0 mol% butyl acrylate VC-BA/40x 85MIN _____________________________________________________________________________ Vinyl chloride/butyl ether copolymer 9.2 mol% butyl ether VC-BE/09x 85MIN _____________________________________________________________________________ Vinyl chloride/methyl acrylate copolymer 25.5 mol% methyl acrylate VC-MA/25x 85MIN 41.6 mol% methyl acrylate VC-MA/42x 85MIN 64.0 mol% methyl acrylate VC-MA/64x 85MIN _____________________________________________________________________________ Vinyl chloride/vinylidene chloride copolymer 15.0 mol% vinylidene chloride VC-VdC/15x 85MIN 42.0 mol% vinylidene chloride VC-VdC/42x 85MIN _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer-solvent systems, measuring temperatures and A 2 -values: _____________________________________________________________________________ Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ AN-αMS/46x 45000 tetrahydrofuran 298.15 7.19 AN-αMS/46x 54000 tetrahydrofuran 298.15 7.14 AN-αMS/46x 65000 tetrahydrofuran 298.15 7.28 AN-αMS/46x 72000 tetrahydrofuran 298.15 9.42 AN-αMS/46x 75000 tetrahydrofuran 298.15 9.06 AN-αMS/46x 79000 tetrahydrofuran 298.15 7.99 AN-αMS/46x 93000 tetrahydrofuran 298.15 8.35 AN-αMS/46x 104000 tetrahydrofuran 298.15 8.44 AN-αMS/46x 105000 tetrahydrofuran 298.15 6.48 AN-αMS/46x 137000 tetrahydrofuran 298.15 7.83 AN-αMS/46x 160000 tetrahydrofuran 298.15 8.26 AN-αMS/46x 170000 tetrahydrofuran 298.15 7.64 AN-αMS/46x 208000 tetrahydrofuran 298.15 8.88 AN-αMS/46x 218000 tetrahydrofuran 298.15 7.55 AN-αMS/46x 226000 tetrahydrofuran 298.15 6.40 AN-αMS/46x 268000 tetrahydrofuran 298.15 7.64 AN-αMS/46x 313000 tetrahydrofuran 298.15 6.93 AN-αMS/46x 332000 tetrahydrofuran 298.15 7.19 AN-αMS/46x 417000 tetrahydrofuran 298.15 6.66 _____________________________________________________________________________ AN-VdC/59w 204000 γ-butyrolactone 298.15 0.119 AN-VdC/59w 42000 N,N-dimethylacetamide 298.15 0.132 AN-VdC/59w 62000 N,N-dimethylacetamide 298.15 0.121 AN-VdC/59w 90000 N,N-dimethylacetamide 298.15 0.120 AN-VdC/59w 140000 N,N-dimethylacetamide 298.15 0.120 AN-VdC/59w 204000 N,N-dimethylacetamide 298.15 0.115 AN-VdC/59w 270000 N,N-dimethylacetamide 298.15 0.110 AN-VdC/59w 348000 N,N-dimethylacetamide 298.15 0.095 AN-VdC/59w 500000 N,N-dimethylacetamide 298.15 0.090 AN-VdC/59w 204000 N,N-dimethylformamide 298.15 0.137 _____________________________________________________________________________ B-S/15x(1) 30300 54800 tetrahydrofuran 296.15 14.4 B-S/15x(2) 131000 143000 tetrahydrofuran 296.15 11.2 B-S/24x 122000 132000 tetrahydrofuran 296.15 10.9 B-S/25x 50400 52900 tetrahydrofuran 296.15 13.9 B-S/25x 153000 200000 tetrahydrofuran 296.15 9.2 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ B-S/25x(9/51) 112000 800000 benzene 301.75 14.2 B-S/25x(9/51) 112000 800000 cyclohexane 301.75 0.46 B-S/25x(9/54) 84100 740000 benzene 301.75 12.0 B-S/25x(9/54) 84100 740000 cyclohexane 301.75 1.39 B-S/29x(8/50) 116000 1700000 benzene 301.75 12.8 B-S/29x(8/50) 116000 1700000 cyclohexane 301.75 1.62 B-S/30x(13/45) 58400 2670000 benzene 301.75 14.9 B-S/30x(13/45) 58400 2670000 cyclohexane 301.75 0.14 _____________________________________________________________________________ B-S/39x(2) 49700 52200 tetrahydrofuran 296.15 12.9 B-S/39x(1) 118000 131000 tetrahydrofuran 296.15 8.8 B-S/62x 137000 148000 tetrahydrofuran 296.15 7.8 B-S/64x 47200 50500 tetrahydrofuran 296.15 10.5 _____________________________________________________________________________ BA-MMA/30x 27000 2-propanone 293.15 9.5 BA-MMA/30x 46000 2-propanone 293.15 7.8 BA-MMA/30x 150000 2-propanone 293.15 5.0 BA-MMA/30x 240000 2-propanone 293.15 4.5 BA-MMA/30x 320000 2-propanone 293.15 4.3 BA-MMA/30x 500000 2-propanone 293.15 3.9 BA-MMA/30x 800000 2-propanone 293.15 3.6 _____________________________________________________________________________ BA-MMA/56x 24000 2-propanone 293.15 11.0 BA-MMA/56x 49000 2-propanone 293.15 8.5 BA-MMA/56x 91000 2-propanone 293.15 6.4 BA-MMA/56x 160000 2-propanone 293.15 5.3 BA-MMA/56x 300000 2-propanone 293.15 4.7 BA-MMA/56x 530000 2-propanone 293.15 4.25 BA-MMA/56x 710000 2-propanone 293.15 4.0 _____________________________________________________________________________ BA-MMA/80x 22000 2-propanone 293.15 8.0 BA-MMA/80x 43000 2-propanone 293.15 6.0 BA-MMA/80x 87000 2-propanone 293.15 5.2 BA-MMA/80x 125000 2-propanone 293.15 4.6 BA-MMA/80x 280000 2-propanone 293.15 3.5 BA-MMA/80x 530000 2-propanone 293.15 3.2 BA-MMA/80x 740000 2-propanone 293.15 2.6 _____________________________________________________________________________ BMA-MMA/50x 70000 2-propanone 293.15 3.2 BMA-MMA/50x 160000 2-propanone 293.15 2.8 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ BMA-MMA/50x 210000 2-propanone 293.15 2.5 BMA-MMA/50x 330000 2-propanone 293.15 2.3 BMA-MMA/50x 430000 2-propanone 293.15 2.2 _____________________________________________________________________________ B-EE/50x 19500 19600 toluene 310.15 9.5 B-EE/50x 54500 56700 toluene 310.15 8.4 B-EE/50x 95500 103000 toluene 310.15 7.8 B-EE/50x 129000 137000 toluene 310.15 7.55 B-EE/50x 209000 228000 toluene 310.15 7.1 _____________________________________________________________________________ EA-MMA/50w 95000 2-propanone 293.15 5.0 EA-MMA/50w 140000 2-propanone 293.15 4.3 EA-MMA/50w 220000 2-propanone 293.15 3.8 EA-MMA/50w 240000 2-propanone 293.15 3.8 EA-MMA/50w 500000 2-propanone 293.15 3.5 EA-MMA/50w 660000 2-propanone 293.15 3.5 _____________________________________________________________________________ E-P/50x 8200 8400 toluene 310.15 22.3 E-P/50x 14500 14900 toluene 310.15 18.4 E-P/50x 22500 24500 toluene 310.15 15.8 E-P/50x 34600 36300 toluene 310.15 13.7 E-P/50x 41600 46400 toluene 310.15 12.85 E-P/50x 91400 96000 toluene 310.15 9.8 E-P/50x 267000 301000 toluene 310.15 6.8 E-P/50x 293000 316000 toluene 310.15 6.6 E-P/50x 545000 600000 toluene 310.15 5.35 _____________________________________________________________________________ E-TFE/50x 540000 diisobutyl adipate 513.15 1.97 E-TFE/50x 1160000 diisobutyl adipate 513.15 1.02 E-TFE/50x 1605000 3210000 diisobutyl adipate 513.15 0.511 _____________________________________________________________________________ EO-PO/72x 36000 water 298.15 6.0 EO-PO/80x 30800 water 298.15 10.5 EO-PO/80x 32500 water 298.15 12.5 EO-PO/87x 30100 water 298.15 21.5 _____________________________________________________________________________ HPF-TPC/50x 90000 trichloromethane 298.15 5.0 HPF-TPC/50x 90000 1,1,2,2-tetrachloroethane 298.15 7.8 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ NIPAM-AM/15x 3100000 water 298.15 3.01 NIPAM-AM/30x 4500000 water 298.15 3.31 NIPAM-AM/45x 3900000 water 298.15 3.46 NIPAM-AM/60x 2200000 water 298.15 3.62 _____________________________________________________________________________ IPE-MB/50x 11000 11300 toluene 310.15 13.2 IPE-MB/50x 17400 17600 toluene 310.15 11.5 IPE-MB/50x 37100 37800 toluene 310.15 9.2 IPE-MB/50x 97500 101000 toluene 310.15 6.9 IPE-MB/50x 115000 119000 toluene 310.15 6.55 IPE-MB/50x 216000 227000 toluene 310.15 5.4 IPE-MB/50x 275000 286000 toluene 310.15 5.0 IPE-MB/50x 393000 425000 toluene 310.15 4.5 _____________________________________________________________________________ IPE-MEE/50x 14600 15000 toluene 310.15 5.9 IPE-MEE/50x 27000 29200 toluene 310.15 5.6 IPE-MEE/50x 68300 72900 toluene 310.15 5.1 IPE-MEE/50x 90300 107000 toluene 310.15 5.0 IPE-MEE/50x 127000 133000 toluene 310.15 4.9 IPE-MEE/50x 157000 170000 toluene 310.15 4.8 IPE-MEE/50x 258000 278000 toluene 310.15 4.6 _____________________________________________________________________________ MA-MMA/50w 80000 2-propanone 293.15 5.5 MA-MMA/50w 115000 2-propanone 293.15 4.8 MA-MMA/50w 135000 2-propanone 293.15 4.5 MA-MMA/50w 155000 2-propanone 293.15 4.2 MA-MMA/50w 200000 2-propanone 293.15 4.0 MA-MMA/50w 240000 2-propanone 293.15 3.9 MA-MMA/50w 420000 2-propanone 293.15 3.4 MA-MMA/50w 525000 2-propanone 293.15 3.5 _____________________________________________________________________________ MMA-AN/24x 400000 acetonitrile 303.15 1.522 MMA-AN/24x 440000 acetonitrile 303.15 1.52 MMA-AN/24x 580000 acetonitrile 303.15 1.46 MMA-AN/24x 750000 acetonitrile 303.15 1.415 MMA-AN/24x 1016000 acetonitrile 303.15 1.304 MMA-AN/24x 1240000 acetonitrile 303.15 1.24 MMA-AN/24x 1560000 acetonitrile 303.15 0.991 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ MMA-AN/50x 270000 acetonitrile 303.15 0.525 MMA-AN/50x 460000 acetonitrile 303.15 0.51 MMA-AN/50x 676000 acetonitrile 303.15 0.478 MMA-AN/50x 758000 acetonitrile 303.15 0.45 MMA-AN/50x 1150000 acetonitrile 303.15 0.422 MMA-AN/50x 1200000 acetonitrile 303.15 0.40 MMA-AN/50x 1830000 acetonitrile 303.15 0.315 _____________________________________________________________________________ MMA-AN/74x 600000 acetonitrile 303.15 0.292 MMA-AN/74x 832000 acetonitrile 303.15 0.255 MMA-AN/74x 871000 acetonitrile 303.15 0.248 MMA-AN/74x 1000000 acetonitrile 303.15 0.234 MMA-AN/74x 1047000 acetonitrile 303.15 0.225 MMA-AN/74x 1175000 acetonitrile 303.15 0.2075 MMA-AN/74x 1352000 acetonitrile 303.15 0.185 MMA-AN/74x 1530000 acetonitrile 303.15 0.16 MMA-AN/74x 1700000 acetonitrile 303.15 0.14 _____________________________________________________________________________ ODC-MAH/50x 28000 ethyl acetate 298.15 3.0 ODC-MAH/50x 37000 ethyl acetate 298.15 2.9 ODC-MAH/50x 51000 ethyl acetate 298.15 2.8 ODC-MAH/50x 68000 ethyl acetate 298.15 2.5 ODC-MAH/50x 99000 ethyl acetate 298.15 2.1 _____________________________________________________________________________ OE-OM/05w 34000 62000 1H,1H,5H-octafluoro- 383.15 22.0 1-pentanol OE-OM/05w 40000 72000 1H,1H,5H-octafluoro- 383.15 19.0 1-pentanol OE-OM/05w 44000 96000 1H,1H,5H-octafluoro- 383.15 16.0 1-pentanol OE-OM/05w 56000 129000 1H,1H,5H-octafluoro- 383.15 17.5 1-pentanol _____________________________________________________________________________ P-AA1/50x 90000 N,N-dimethylacetamide 298.15 11.0 P-AA1/50x 130000 N,N-dimethylacetamide 298.15 10.0 P-AA1/50x 150000 N,N-dimethylacetamide 298.15 10.5 P-AA1/50x 350000 N,N-dimethylacetamide 298.15 9.5 _____________________________________________________________________________ © 2001 by CRC Press LLC Copolymer (B) M n / M w / Solvent (A) T/ A 2 10 4 / g/mol g/mol K cm 3 mol/g 2 _____________________________________________________________________________ P-AA2/50x 20000 N,N-dimethylacetamide 298.15 20.0 P-AA2/50x 50000 N,N-dimethylacetamide 298.15 17.0 P-AA2/50x 80000 N,N-dimethylacetamide 298.15 15.0 P-AA2/50x 90000 N,N-dimethylacetamide 298.15 20.0 _____________________________________________________________________________ S-AN/25w 90000 147000 tetrahydrofuran 298.15 11.5 _____________________________________________________________________________ S-AN/38x 96000 2-butanone 298.15 4.72 S-AN/38x 197000 2-butanone 298.15 7.70 S-AN/38x 197000 2-butanone 298.15 7.72 S-AN/38x 238000 2-butanone 298.15 4.15 S-AN/38x 264000 2-butanone 298.15 5.45 S-AN/38x 265000 2-butanone 298.15 5.43 S-AN/38x 323000 2-butanone 298.15 4.04 S-AN/38x 543000 2-butanone 298.15 3.67 S-AN/38x 601000 2-butanone 298.15 5.25 S-AN/38x 602000 2-butanone 298.15 5.23 S-AN/38x 647000 2-butanone 298.15 4.62 S-AN/38x 648000 2-butanone 298.15 4.62 S-AN/38x 756000 2-butanone 298.15 4.80 S-AN/38x 761000 2-butanone 298.15 4.77 S-AN/38x 832000 2-butanone 298.15 5.03 S-AN/38x 836000 2-butanone 298.15 5.01 S-AN/38x 1130000 2-butanone 298.15 4.89 S-AN/38x 1390000 2-butanone 298.15 3.59 _____________________________________________________________________________ S-AN/38x 144000 tetrahydrofuran 298.15 8.47 S-AN/38x 145000 tetrahydrofuran 298.15 8.29 S-AN/38x 150000 tetrahydrofuran 298.15 8.88 S-AN/38x 230000 tetrahydrofuran 298.15 7.40 S-AN/38x 286000 tetrahydrofuran 298.15 6.11 S-AN/38x 605000 tetrahydrofuran 298.15 7.81 S-AN/38x 645000 tetrahydrofuran 298.15 7.38 S-AN/38x 825000 tetrahydrofuran 298.15 7.55 S-AN/38x 1072000 tetrahydrofuran 298.15 7.74 S-AN/38x 1123000 tetrahydrofuran 298.15 6.83 S-AN/38x 1873000 tetrahydrofuran 298.15 4.30 _____________________________________________________________________________ S-AN/40x 77000 50 mol% acrylonitrile + 298.15 12.0 50 mol% styrene _____________________________________________________________________________ © 2001 by CRC Press LLC [...]... tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.119 0.1 18 0. 089 _ VA-VC/25x VA-VC/25x VA-VC/25x 21000 49900 185 000 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.1 48 0. 082 0.050 _ VA-VC/40x VA-VC/40x VA-VC/40x 43000 79000 179000 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15... S-pMOS/76x(1) S-pMOS/76x(1) 44000 61000 79000 1 180 00 119000 169000 184 000 187 000 232000 279000 294000 421000 431000 730000 1149000 1717000 toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 5.9 5.4 4.54 4.50 4.1 3.9 3.92 4.2... 302000 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.052 0.055 0.065 _ VC-BA/40x VC-BA/40x 205000 632000 tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 0.024 0.0 18 _ VC-BE/09x VC-BE/09x VC-BE/09x 30000 53000 980 00 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.115 0. 083 0.077 ... 1346000 1 783 000 toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 5.46 5.33 4. 68 4.26 4.22 3.97 3. 98 3 .86 3 .82 3 .81 3.41 _ © 2001 by CRC Press LLC M w/ Solvent (A) T/ A2 104/ Mn/ g/mol g/mol K cm3mol/g2 _ Copolymer. .. toluene toluene toluene 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 5.34 5.0 5.6 5.62 4.6 5.54 4.3 4.3 4.99 4.64 4.69 3 .8 4.67 3.0 4.49 4.29 _ S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x S-pMOS/53x 66000 104000 1 680 00 269000 292000 446000... tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 2 98. 15 0.014 0.022 0.033 0.022 _ VC-VdC/15x VC-VdC/15x VC-VdC/15x VC-VdC/42x VC-VdC/42x VC-VdC/42x 50000 121000 223000 79000 133000 187 000 tetrahydrofuran tetrahydrofuran tetrahydrofuran tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 0.091 0.070 0.045 0.026 0.027 0.040... tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 0.057 0.052 _ VC-MA/42x VC-MA/42x VC-MA/42x 121000 320000 89 1000 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0. 080 0.047 0.032 _ VC-MA/64x VC-MA/64x VC-MA/64x VC-MA/64x 379000 1060000 1340000 2510000 tetrahydrofuran tetrahydrofuran tetrahydrofuran tetrahydrofuran... 121000 154000 234000 400000 660000 701000 toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene toluene 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 4.1 5.2 4.2 3.6 4.0 3.6 3.5 3.2 4.2 3 .8 3.9 3.2 _ S-pMOS/76x(2) S-pMOS/76x(2) S-pMOS/76x(1) S-pMOS/76x(1) S-pMOS/76x(2) S-pMOS/76x(2) S-pMOS/76x(1)... tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.1 18 0.092 0.064 _ © 2001 by CRC Press LLC M w/ Solvent (A) T/ A2 104/ Mn/ g/mol g/mol K cm3mol/g2 _ Copolymer (B) VA-VC/66x VA-VC/66x VA-VC/66x 100000 2 480 00 7 080 00 tetrahydrofuran tetrahydrofuran tetrahydrofuran 2 98. 15 2 98. 15 2 98. 15 0.0 28 0.025 0.012 ... 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 2 98. 15 1 .8 3.3 1.5 2.3 1.5 3.6 1.2 2.4 _ © 2001 by CRC Press LLC M w/ Solvent (A) T/ A2 104/ Mn/ g/mol g/mol K cm3mol/g2 _ Copolymer (B) S-MMA/71x S-MMA/71x 354000 354000 cyclohexanol 2-ethoxyethanol 341.15 313.15 0.0 0.0 _ TFE-TFNM/50x 283 000 . tetrahydrofuran 2 98. 15 8. 88 S-AN/38x 230000 tetrahydrofuran 2 98. 15 7.40 S-AN/38x 286 000 tetrahydrofuran 2 98. 15 6.11 S-AN/38x 605000 tetrahydrofuran 2 98. 15 7 .81 S-AN/38x 645000 tetrahydrofuran 2 98. 15. tetrahydrofuran 2 98. 15 7 .83 AN-αMS/46x 160000 tetrahydrofuran 2 98. 15 8. 26 AN-αMS/46x 170000 tetrahydrofuran 2 98. 15 7.64 AN-αMS/46x 2 080 00 tetrahydrofuran 2 98. 15 8. 88 AN-αMS/46x 2 180 00 tetrahydrofuran 2 98. 15. 2 98. 15 7. 38 S-AN/38x 82 5000 tetrahydrofuran 2 98. 15 7.55 S-AN/38x 1072000 tetrahydrofuran 2 98. 15 7.74 S-AN/38x 1123000 tetrahydrofuran 2 98. 15 6 .83 S-AN/38x 187 3000 tetrahydrofuran 2 98. 15 4.30 _____________________________________________________________________________ S-AN/40x