4. HIGH-PRESSURE PHASE EQUILIBRIUM (HPPE) DATA OF COPOLYMER SOLUTIONS IN SUPERCRITICAL FLUIDS 4.1. Experimental data of quasibinary copolymer solutions _____________________________________________________________________________ Copolymers from butylene oxide and ethylene oxide _____________________________________________________________________________ Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ poly(butylene oxide)-b-poly(ethylene oxide) diblock copolymer 44.4 mol% ethylene oxide BO-EO/44x 98ONE _____________________________________________________________________________ Characterization: _____________________________________________________________________________ Copolymer (B) M n / Further information g/mol _____________________________________________________________________________ BO-EO/44x 1620 ( = 960 + 660) SAM 185, hydroxyl terminated _____________________________________________________________________________ Experimental HPPE data: _____________________________________________________________________________ copolymer (B): BO-EO/44x 98ONE solvent (A): carbon dioxide CO 2 124-38-9 Type of data: cloud-points w B 0.001 T/K 308.15 P/MPa 27.58 © 2001 by CRC Press LLC _____________________________________________________________________________ Copolymers from ethylene and acrylic acid _____________________________________________________________________________ Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ Ethylene/acrylic acid copolymer 3.0 wt% acrylic acid E-AA/03w 92WIN 6.0 wt% acrylic acid E-AA/06w 92WIN 7.3 wt% acrylic acid E-AA/07w 92WIN _____________________________________________________________________________ Characterization: _____________________________________________________________________________ Copolymer (B) M n / M w / M η / Further information g/mol g/mol g/mol _____________________________________________________________________________ E-AA/03w 37500 183000 synthesized in the laboratory E-AA/06w 30000 150000 synthesized in the laboratory E-AA/07w 25000 126000 synthesized in the laboratory _____________________________________________________________________________ Experimental HPPE data: _____________________________________________________________________________ copolymer (B): E-AA/03w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.019 0.019 0.019 0.019 0.019 0.082 0.082 0.082 0.082 T/K 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15 P/MPa 196.8 178.4 163.1 152.2 141.7 186.7 166.6 153.1 143.3 w B 0.082 0.128 0.128 0.128 0.128 0.128 0.186 0.186 0.186 T/K 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15 453.15 P/MPa 135.4 181.2 162.8 150.1 140.3 132.2 172.1 154.3 142.5 continue © 2001 by CRC Press LLC continue w B 0.186 0.186 0.231 0.231 0.231 0.231 0.231 0.295 0.295 T/K 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15 433.15 P/MPa 134.0 128.5 165.6 148.9 137.7 129.8 124.2 153.1 139.8 w B 0.295 0.295 0.295 0.318 0.318 0.318 0.318 0.318 0.338 T/K 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15 413.15 P/MPa 130.2 123.1 118.0 150.4 136.6 127.9 121.3 115.8 146.0 w B 0.338 0.338 0.338 0.338 0.428 0.428 0.428 0.428 0.428 T/K 433.15 453.15 473.15 493.15 413.15 433.15 453.15 473.15 493.15 P/MPa 134.1 125.3 118.9 113.4 127.5 119.4 113.4 108.7 105.1 w B 0.510 0.510 0.510 0.510 0.510 T/K 413.15 433.15 453.15 473.15 493.15 P/MPa 109.8 105.5 102.0 99.0 96.0 copolymer (B): E-AA/03w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: coexistence data T/K = 403.15 Total feed concentration of the copolymer in the homogeneous system: w B = 0.155 _____________________________________________________________________________ Demixing w A Fractionation during demixing pressure bottom phase top phase bottom phase top phase _____________________________________________________________________________ P/ M n / M w / M z / M n / M w / M z / MPa g/mol g/mol g/mol g/mol g/mol g/mol _____________________________________________________________________________ 116.0 0.508 0.982 2818 8803 18920 161.0 0.711 0.951 9188 31060 73720 178.5 0.789 0.918 42880 176300 510700 13170 52620 156100 188.0 0.845 (cloud-point) 37500 183000 601000 (feed sample) _____________________________________________________________________________ copolymer (B): E-AA/03w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: coexistence data T/K = 433.15 continue © 2001 by CRC Press LLC continue The total feed concentration of the copolymer in the homogeneous system is: w B = 0.164 _____________________________________________________________________________ Demixing w A Fractionation during demixing pressure bottom phase top phase bottom phase top phase _____________________________________________________________________________ P/ M n / M w / M z / M n / M w / M z / MPa g/mol g/mol g/mol g/mol g/mol g/mol _____________________________________________________________________________ 94.0 0.438 0.993 1520 6745 13920 113.0 0.536 0.982 2500 8300 17620 129.0 0.633 0.966 8200 29070 69600 147.7 0.766 0.939 41500 173700 472800 11600 47030 146200 157.5 0.836 (cloud-point) 37500 183000 601000 (feed sample) _____________________________________________________________________________ copolymer (B): E-AA/06w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.038 0.038 0.038 0.038 0.057 0.057 0.057 0.057 0.076 T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15 P/MPa 203.4 176.8 157.3 142.0 195.7 170.5 152.3 138.9 191.2 w B 0.076 0.076 0.076 0.116 0.116 0.116 0.116 0.150 0.150 T/K 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15 P/MPa 167.2 148.9 134.0 189.5 164.2 146.2 132.5 183.9 161.1 w B 0.150 0.150 0.215 0.215 0.215 0.215 0.260 0.260 0.260 T/K 473.15 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15 P/MPa 145.2 130.5 172.4 152.2 135.4 125.4 165.3 146.3 132.6 w B 0.260 0.295 0.295 0.295 0.295 0.335 0.335 0.335 0.335 T/K 493.15 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 P/MPa 121.8 158.3 142.0 129.8 119.0 147.5 135.9 125.6 115.5 w B 0.383 0.383 0.383 0.383 0.430 0.430 0.430 0.430 0.505 T/K 433.15 453.15 473.15 493.15 433.15 453.15 473.15 493.15 433.15 P/MPa 137.5 126.9 118.5 112.2 130.1 120.2 112.0 106.3 114.4 w B 0.505 0.505 0.505 T/K 453.15 473.15 493.15 P/MPa 108.0 103.1 99.2 © 2001 by CRC Press LLC copolymer (B): E-AA/06w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: coexistence data T/K = 433.15 The total feed concentration of the copolymer in the homogeneous system is: w B = 0.1565 _____________________________________________________________________________ P/ w A MPa bottom phase top phase _____________________________________________________________________________ 124.9 0.5550 0.9870 138.1 0.6130 0.9735 158.6 0.7130 0.9540 172.0 0.7855 0.9300 182.0 0.8435 (cloud-point) _____________________________________________________________________________ copolymer (B): E-AA/07w 92WIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.043 0.043 0.043 0.102 0.102 0.102 0.102 0.160 0.160 T/K 453.15 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15 P/MPa 192.4 165.6 143.9 196.2 181.4 157.7 140.2 186.0 171.4 w B 0.160 0.160 0.203 0.203 0.203 0.203 0.272 0.272 0.272 T/K 473.15 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15 P/MPa 150.8 135.3 178.2 165.3 146.3 132.5 166.0 156.4 140.6 w B 0.272 0.330 0.330 0.330 0.330 0.410 0.410 0.410 0.410 T/K 493.15 443.15 453.15 473.15 493.15 443.15 453.15 473.15 493.15 P/MPa 126.8 155.5 147.0 134.0 122.5 141.0 134.3 123.6 114.9 w B 0.500 0.500 0.500 0.500 T/K 443.15 453.15 473.15 493.15 P/MPa 121.4 117.0 110.8 104.8 © 2001 by CRC Press LLC _____________________________________________________________________________ Copolymers from ethylene and butyl acrylate _____________________________________________________________________________ Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ Ethylene/butyl acrylate copolymer 15.0 wt% butyl acrylate E-BA/15w 96MUE 19.0 wt% butyl acrylate E-BA/19w 96MUE 35.0 wt% butyl acrylate E-BA/35w 96MUE 67.0 wt% butyl acrylate E-BA/67w 96MUE 75.0 wt% butyl acrylate E-BA/75w 96MUE _____________________________________________________________________________ Characterization: _____________________________________________________________________________ Copolymer (B) M n / M w / M η / Further information g/mol g/mol g/mol _____________________________________________________________________________ E-BA/15w 6980 34900 sample from BASF AG, Ger. E-BA/19w 7740 38700 sample from BASF AG, Ger. E-BA/35w 7960 39800 sample from BASF AG, Ger. E-BA/67w 11500 37000 synthesized in the laboratory E-BA/75w 13900 35200 synthesized in the laboratory _____________________________________________________________________________ Experimental HPPE data: _____________________________________________________________________________ copolymer (B): E-BA/15w 96MUE solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050 T/K 522.85 498.05 473.05 448.55 423.85 524.05 498.35 473.85 449.15 P/MPa 117.7 121.5 126.3 132.3 139.6 116.9 120.8 125.5 131.3 continue © 2001 by CRC Press LLC continue w B 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 T/K 423.75 522.85 498.05 473.15 448.95 424.15 524.15 498.25 473.55 P/MPa 138.8 121.2 124.1 127.5 132.1 139.4 120.8 122.5 125.1 w B 0.150 0.150 0.200 0.200 0.200 0.200 0.200 T/K 448.95 424.35 523.35 498.05 473.35 449.15 423.35 P/MPa 128.5 133.6 117.3 118.8 121.5 124.8 128.7 copolymer (B): E-BA/19w 96MUE solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.034 0.034 0.034 0.034 0.034 0.050 0.050 0.050 0.050 T/K 523.05 498.55 472.65 448.15 423.15 523.95 497.85 473.05 449.25 P/MPa 116.8 120.6 125.4 131.6 138.4 118.4 121.3 125.3 130.8 w B 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 T/K 423.95 523.55 498.85 473.45 449.05 424.25 524.85 498.15 472.65 P/MPa 139.0 121.7 123.6 128.2 131.6 139.4 120.3 122.1 128.4 w B 0.150 0.150 0.199 0.199 0.199 0.199 T/K 448.95 424.25 523.25 498.55 473.35 448.95 P/MPa 130.6 134.7 120.7 123.0 126.1 129.8 copolymer (B): E-BA/35w 96MUE solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.025 0.025 0.025 0.025 0.025 0.050 0.050 0.050 0.050 T/K 523.65 498.55 473.05 448.55 423.45 523.75 498.05 472.95 448.05 P/MPa 111.5 115.9 120.4 127.2 134.4 109.4 113.1 117.2 122.3 w B 0.050 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 T/K 423.25 523.45 498.05 473.15 448.45 423.45 523.85 498.35 472.95 P/MPa 129.7 107.1 109.8 113.1 116.9 121.9 105.9 108.1 111.5 w B 0.150 0.150 0.199 0.199 0.199 0.199 0.199 T/K 448.05 423.85 523.75 498.05 473.25 449.15 424.05 P/MPa 115.1 119.8 104.9 106.7 109.5 115.4 120.5 copolymer (B): E-BA/67w 96MUE solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.168 0.168 0.168 0.168 0.168 T/K 522.35 498.15 473.65 448.35 424.65 P/MPa 96.6 98.4 100.1 102.3 104.0 © 2001 by CRC Press LLC copolymer (B): E-BA/75w 96MUE solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.069 0.069 0.069 0.069 0.069 0.069 T/K 524.05 499.05 474.45 448.65 423.75 398.75 P/MPa 89.4 90.3 92.9 96.5 99.8 102.1 _____________________________________________________________________________ Copolymers from ethylene and 1-hexene _____________________________________________________________________________ Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ Ethylene/1-hexene copolymer 10.6 wt% 1-hexene E-H/11w 2000CH3 16.1 wt% 1-hexene E-H/16w 99KIN 20.6 wt% 1-hexene E-H/21w 2000CH2 35.0 wt% 1-hexene E-H/35w(1) 2000CH3 35.0 wt% 1-hexene E-H/35w(2) 2000CH3 _____________________________________________________________________________ Characterization: _____________________________________________________________________________ Copolymer (B) M n / M w / M η / Further information g/mol g/mol g/mol _____________________________________________________________________________ E-H/11w 52600 80000 E-H/16w 60000 129000 E-H/21w 51300 126000 E-H/35w(1) 48100 103000 E-H/35w(2) 112100 139000 _____________________________________________________________________________ © 2001 by CRC Press LLC Experimental HPPE data: _____________________________________________________________________________ copolymer (B): E-H/11w 2000CH3 solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.148 0.148 0.148 0.148 T/K 393.25 413.15 433.25 453.15 P/MPa 168.0 154.5 146.0 138.9 copolymer (B): E-H/16w 99KIN solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.150 0.150 0.150 0.150 0.150 0.150 T/K 393.15 413.15 433.15 453.15 473.15 493.15 P/MPa 156.0 144.3 137.3 129.1 123.1 118.6 copolymer (B): E-H/35w(1) 2000CH3 solvent (A): ethene C 2 H 4 74-85-1 Type of data: cloud-points w B 0.050 0.050 0.050 0.050 0.050 0.050 0.050 0.100 0.100 T/K 393.15 403.15 413.15 423.15 433.15 443.15 453.15 393.15 403.15 P/MPa 136.3 132.6 129.6 127.0 124.9 122.9 121.0 134.8 131.4 w B 0.100 0.100 0.100 0.100 0.100 0.150 0.150 0.150 0.150 T/K 413.15 423.15 433.15 443.15 453.15 393.15 403.15 413.15 423.15 P/MPa 128.3 125.8 123.7 121.8 120.8 129.4 126.1 123.6 121.5 w B 0.150 0.150 0.150 T/K 433.15 443.15 453.15 P/MPa 119.8 118.7 119.4 copolymer (B): E-H/11w 2000CH3 solvent (A): propane C 3 H 8 74-98-6 Type of data: cloud-points w B 0.010 0.010 0.010 0.010 0.051 0.051 0.051 0.051 0.148 T/K 363.15 373.25 413.15 453.15 363.15 373.15 413.15 453.15 373.25 P/MPa 50.3 50.0 49.9 50.7 51.0 50.4 50.4 50.4 50.6 w B 0.148 0.148 T/K 413.15 453.15 P/MPa 50.4 51.1 © 2001 by CRC Press LLC copolymer (B): E-H/21w 2000CH2 solvent (A): propane C 3 H 8 74-98-6 Type of data: cloud-points T/K = 453.15 w B 0.018 0.031 0.055 0.066 0.075 0.079 0.089 0.098 0.100 P/bar 446.0 454.0 456.0 459.0 468.0 475.0 478.0 470.0 474.0 w B 0.108 0.114 0.148 P/bar 471.0 466.0 459.0 copolymer (B): E-H/35w(1) 2000CH3 solvent (A): propane C 3 H 8 74-98-6 Type of data: cloud-points w B 0.150 0.150 0.150 0.150 0.150 0.150 T/K 313.15 343.15 363.05 373.05 413.15 453.15 P/MPa 37.3 38.1 39.1 39.7 42.3 44.6 copolymer (B): E-H/35w(2) 2000CH3 solvent (A): propane C 3 H 8 74-98-6 Type of data: cloud-points w B 0.009 0.009 0.009 0.009 0.009 0.009 0.152 0.152 0.152 T/K 313.25 353.25 368.25 373.15 413.15 453.15 353.25 373.15 413.15 P/MPa 39.0 36.8 37.6 37.9 40.6 42.9 37.8 39.2 41.5 w B 0.152 T/K 453.15 P/MPa 43.7 _____________________________________________________________________________ Copolymers from ethylene and methyl acrylate _____________________________________________________________________________ Average chemical composition of the copolymers, acronyms and references: _____________________________________________________________________________ Copolymer (B) Acronym Ref. _____________________________________________________________________________ Ethylene/methyl acrylate copolymer 25.0 wt% methyl acrylate E-MA/25w 96MUE 58.0 wt% methyl acrylate E-MA/58w 96MUE 68.0 wt% methyl acrylate E-MA/68w 96MUE _____________________________________________________________________________ © 2001 by CRC Press LLC [...]... 74- 85- 1 C2H4 cloud-points wB T/K P/MPa 0. 05 393. 15 126.8 0.10 393. 15 126.0 0. 15 393. 15 1 25. 8 0.20 393. 15 124 .5 0.30 393. 15 119 .5 0. 05 413. 15 123.0 0.10 413. 15 122.2 0. 15 413. 15 121.0 0.20 413. 15 120.0 wB T/K P/MPa 0.30 413. 15 1 15. 5 0. 05 433. 15 119.7 0.10 433. 15 119 .5 0. 15 433. 15 117 .5 0.20 433. 15 1 15. 5 0.30 433. 15 111 .5 0. 05 453 . 15 116.0 0.10 453 . 15 1 15. 7 0. 15 453 . 15 114.0 wB T/K P/MPa 0.20 453 . 15 112.0... 0. 05 433. 15 121.0 0.10 433. 15 120.0 0. 15 433. 15 118.0 0.20 433. 15 1 15. 5 0.30 433. 15 109.0 0. 05 453 . 15 118 .5 0.10 453 . 15 117.0 0. 15 453 . 15 1 15. 0 wB T/K P/MPa 0.20 453 . 15 112.0 0.30 453 . 15 1 05. 0 0. 05 473. 15 1 15. 5 0.10 473. 15 113 .5 0. 15 473. 15 111 .5 0.20 473. 15 109.0 0.30 473. 15 102 .5 copolymer (B): solvent (A): Type of data: E-VA/28w(1) ethene C2H4 91NIE 74- 85- 1 coexistence data T/K = 433. 15 The total... 413. 15 137.8 0.0 75 413. 15 137.3 0.10 413. 15 134.8 wB T/K P/MPa 0. 15 413. 15 130.4 0.20 413. 15 127.0 0.30 413. 15 119.6 0. 05 433. 15 132.4 0.0 75 433. 15 130.4 0.10 433. 15 128 .5 0. 15 433. 15 1 25. 0 0.20 433. 15 121.6 0.30 433. 15 114.7 wB T/K P/MPa 0. 05 453 . 15 127 .5 0.0 75 453 . 15 1 25. 5 0.10 453 . 15 124.0 0. 15 453 . 15 120.6 0.20 453 . 15 117.7 0.30 453 . 15 109.8 0. 05 473. 15 122.6 0.0 75 473. 15 121.1 0.10 473. 15 119.6 wB T/K... 0.07 413. 15 118.7 0.10 413. 15 118.1 0. 15 413. 15 118.7 0.20 413. 15 1 15. 2 0. 25 413. 15 112.8 0.30 413. 15 110.3 0.014 433. 15 116.2 0.04 433. 15 118.2 wB T/K P/MPa 0.07 433. 15 1 15. 7 0.10 433. 15 114 .5 0. 15 433. 15 114 .5 0.20 433. 15 110.8 0. 25 433. 15 110.3 0.30 433. 15 108.4 0.014 453 . 15 114.2 0.04 453 . 15 1 15. 2 0.07 453 . 15 112.8 wB T/K P/MPa 0.10 453 . 15 111.8 0. 15 453 . 15 111.8 0.20 453 . 15 108.8 0. 25 453 . 15 108.8... 0. 050 52 2. 95 124.9 0. 050 498. 65 130.8 0. 050 473. 95 138.2 0. 050 449. 05 148 .5 wB T/K P/MPa 0. 050 423. 95 163.1 0. 050 404. 05 178.8 0.101 52 4. 65 123.0 0.101 499. 15 128.4 0.101 473. 25 1 35. 6 0.101 448. 45 1 45. 0 0.101 424. 05 162.0 0. 150 52 4. 05 122.7 0. 150 498. 95 127.8 wB T/K P/MPa 0. 150 473. 45 132.3 0. 150 448. 95 140.6 0. 150 423 .55 150 .6 0.200 52 3. 75 117.3 0.200 498. 45 122.1 0.200 473. 85 128.2 0.200 448. 45 136.2... 92CH1 1 15- 07-1 C3H6 cloud-points wB = 0. 158 T/K P/bar 264. 15 354 .0 2 65. 85 347.0 271. 15 337.0 274. 15 331.0 277. 95 3 25. 5 280. 35 322 .5 2 85. 25 316.7 287. 05 3 15. 0 293 .55 311.0 T/K P/bar 303. 05 310.6 317. 15 319 .5 322 .55 322.3 331. 15 330.0 354 . 65 352 .0 373. 05 371.0 397. 75 396.4 423. 35 423.0 447. 95 442.3 T/K P/bar 473 .55 461.0 copolymer (B): solvent (A): Type of data: wB T/K P/bar 93GRE, 94GR1, 94GR2 1 15- 07-1... Type of data: wB T/K P/bar 0. 156 323. 15 1018.6 0. 152 4 75. 15 689.6 93GRE, 94GR1 74- 85- 1 C2H4 0. 156 3 25. 65 1001.1 0. 158 348. 15 941.9 E-P /50 x(4) ethene 0. 158 373. 15 897.9 C2H4 0. 157 398. 15 899.9 0. 158 448. 15 899.1 0. 158 468. 15 892.8 0. 158 473. 15 900.0 93GRE, 94GR1 74- 85- 1 cloud-points 0.038 353 . 15 1722 .5 0.038 373. 15 156 9.0 copolymer (B): solvent (A): Type of data: 0. 152 423. 15 600.9 E-P /50 x(2) ethene copolymer. .. LLC copolymer (B): solvent (A): Type of data: E-MA/68w ethene 96MUE 74- 85- 1 C2H4 cloud-points wB T/K P/MPa 0.011 52 3. 85 136 .5 0.011 498. 95 1 45. 5 0.011 473 .55 157 .8 0.011 448. 45 1 65. 2 0.011 423. 75 206.4 0. 050 52 3. 25 136.1 0. 050 498. 35 1 45. 2 0. 050 473. 15 157 .7 0. 050 448. 85 174.4 wB T/K P/MPa 0. 050 423. 85 201.3 0. 050 403. 65 234.3 0.101 52 3. 65 133.6 0.101 498. 25 142.0 0.101 473. 25 153 .0 0.101 448. 25 167.4... 433. 15 1 05. 4 0.12 433. 15 104.4 0.16 433. 15 102 .5 0.20 433. 15 102.0 0. 25 433. 15 102.0 0.30 433. 15 100 .5 0.01 05 453 . 15 106.9 0.04 453 . 15 106.4 0.08 453 . 15 103.0 continue © 2001 by CRC Press LLC continue wB T/K P/MPa 0.12 453 . 15 101 .5 0.16 453 . 15 100 .5 0.20 453 . 15 100.1 0. 25 453 . 15 100.1 wB T/K P/MPa 0.16 473. 15 98 .5 0.20 473. 15 98.0 0. 25 473. 15 97.6 0.30 473. 15 96.6 copolymer (B): solvent (A): Type of data: ... 0.010 498. 15 119.8 0.010 473. 85 123.6 0.010 448 .55 128.8 0.010 424. 05 133.0 0. 050 52 3. 95 1 15. 9 0. 050 498. 85 119.4 0. 050 472. 75 123.2 0. 050 449. 15 127 .5 wB T/K P/MPa 0. 050 423. 95 134.2 0. 050 404. 15 140.0 0.100 52 5. 05 117.3 0.100 498. 35 117.4 0.100 474. 35 120.2 0.100 448. 65 124.6 0.100 424. 95 129.2 0.113 52 3. 15 117.2 0.113 498. 35 119.0 wB T/K P/MPa 0.113 473 .55 122.7 0.113 448. 85 1 25. 5 0.113 423. 45 131.2 . 453 . 15 473. 15 P/MPa 1 45. 2 130 .5 172.4 152 .2 1 35. 4 1 25. 4 1 65. 3 146.3 132.6 w B 0.260 0.2 95 0.2 95 0.2 95 0.2 95 0.3 35 0.3 35 0.3 35 0.3 35 T/K 493. 15 433. 15 453 . 15 473. 15 493. 15 433. 15 453 . 15 473. 15 493. 15 P/MPa. 363. 15 373. 25 413. 15 453 . 15 363. 15 373. 15 413. 15 453 . 15 373. 25 P/MPa 50 .3 50 .0 49.9 50 .7 51 .0 50 .4 50 .4 50 .4 50 .6 w B 0.148 0.148 T/K 413. 15 453 . 15 P/MPa 50 .4 51 .1 © 2001 by CRC Press LLC copolymer. 0. 050 0. 050 T/K 52 3. 85 498. 95 473 .55 448. 45 423. 75 523. 25 498. 35 473. 15 448. 85 P/MPa 136 .5 1 45. 5 157 .8 1 65. 2 206.4 136.1 1 45. 2 157 .7 174.4 w B 0. 050 0. 050 0.101 0.101 0.101 0.101 0.101 0. 150