Cd can dung dich sau phin img, thu duo-c 2l gam ch6t rin khan Y.. Ch6t Y tac dung cluoc vdi CuO nung nong sinh ra sAn ph6m c6 th€ tham gia phin fng tr6ng bpc.. Hod tan Y trong luo.ng du
Trang 1SO CIAO DUC VA EAO TAO HA NQI NN rHr rNff O4T HQC LAN TII[' NUAT
vlolq: noA Hoc
(Di thi g6m cd 5 trang) rn* ii'n* ii| io pn t,
ivre ae thi 132
Chnbi6t nguyAnfikfuitcilacdcngwyAntij: H: l;Li:7; C: 12;N: gffi
Mg:24;AI:27; P:31; S:32; Cl:35,5; K 39; Ca:40; Cr:52; Mn:55; Fe:56; Cu: 64; Br : 80; Rb : 85,5; Ag : 108; Cs L 1.33; Ba: 137.
I PHAN CHUNG CHo TAr cA cAc THi SINH (40 cf,u, tir ciu 1 d6n cf;u 40)
CAu 1: Cho so i10 chuy6n ho6 sau:
khi clo, ti lg mol I :1 NaOH ddq du lIBr
Benzen _ _> X _+ f _- - *
z
Fe, to to, p Bi6t X, Y, Z ldc6c sdn phAm chfnh Chc chdtx,Y, Ztrong so il6 tren Bn luo.t ld
A" CrHsCl, CeHsONa, C6}I5OH,
C CoHsCl, CeHsOH, CeHsBr
B CeFI+Clz, C5Ha(ONa)2, C6FI+(OH)z
D CeHsCI{zCl, CoHsCHzOH,CeHsCI{zBr
Cdu ?: D6y cluqc sip x6p theo chidu giAm ddn nhigt ctQ s6i ld
A C2H5CHO, CgHzOH, CH3COOH B CH3COOH, CrHzOH, CzHsCHO
C C3HzOH, CH:COOH, CzHsCHO D C2HsCHO, CHgCOOH, C3H7OH
Cffu 3; Cho c6c dung dich: dung dich HCI (X1), dung dieh g6m HzSO+ lodng vi KNO3 (Xz), dung dich KNOr (X3), dgng dich Fez(SO+)3 (&) Cdc dung dich c6 th6 hod tan hodn todn hdn hqp g6m Cu
vi Fe2O3 (c6 ti lQ s6 mol I : 1) ld
A Xr, Xz 8.X2,X4 C Xu, X: D Xr, &.
' Cflu 4: Este tlo'n chtlc X c6 ti ttrOi troi so vdi khi oxi bing 3,125 Cho 0,15 mol X t6c dung vla dri
vdi dung dich NaOH Cd can dung dich sau phin img, thu duo-c 2l gam ch6t rin khan Y Ch6t Y tac
dung cluoc vdi CuO nung nong sinh ra sAn ph6m c6 th€ tham gia phin fng tr6ng bpc Cdng thric cdu tao cria X ld
"rtr7:o
B GH2:CHCOOCzHs
D CzHsCOOCH:CH2
o
Cdu 5: MQt h5n hqp g6m kali vd kim lopi kiAm X Hodtan h6t 12,15 gam h6n hqp tr€n vio nu6c, thu duoc 3,78 lft khi Hz (dktc) Bi6t ti lQ s5 mol cria X vd kali trong h5n hq p nhd hon 119 Nguy6n tO X h
A CHi-CH-ICHrb-C:O - \' -"7
\o,
CAu 6: Cho 4,48 gam h6n ho p etyl axetat vd phenyl axetat (c6 tt lQ s6 mol ld 1:1) tdc dung h6t v6i
800 ml dung dich NaOH 0,1M, thu duo.'c dung dich X CO c4n dung dich X, thu ituo.c m gam chdt r[n khan Gi6 tri cria m ld
CAu 7: Thu! phAn hodn toan 0,1 mol este X (X tfuo c tao thinh ttr axit hopc ancol don chrlc) can ZOO
ml dung dfch KOH 1M MAt khdc, khi thuf phdn 10,95 gam X cAn vira rtri 8,4 gam KOH, thu duqc
1}{ gam mu6i khan Cdng th6'c crla X li
l)(cooczHs)2 B c2ll4(coocHr)2 c cH(coocHr)r D (cH3coo)zczril.
Cf,f, Q: Cho khi CO qua 6ng sri dlrng 0,5 mol h6n ho p X gdm Fe3Oa vd FezOr nung n6ng, thu dugc
100 gdm ch6t rin Y g6m 4 ch6t Hod tan Y trong luo.ng du dung dfch HNO3 lodng, thu dugc ll,2lit
khi Ndr(san phAm khir duy nh6t,dktc) Phin tr[m vA khtii lu-o ng cria Fe:O+ trong X li
Trang 1/5 - Ma dA thi 132
() ^ 1S- \ z -' I\ r e- ' r\ t',l L4 (/{h4 : V tz- /J://\*Lu-t
Trang 2CAu 9: Hdn hgp X gbm 2 anclehit Cho 0,04 mol X phin rlng hodn todn v6i luqng du dung dich AgNO3 trong t Ii{, Oun n6ng, thu tlu-o c 11,88 gam Ag Mat kh6c, n6u d5t cnay hodn toin 0,04 mol X
trJng khi o*i thi thu dugc Z,OrcVtkhi CO2 (dktc) Hai andehit trong X g6m
Ciu 10: Trong quf trinh itipn phdn dung dlch NaCl (v6i di$n cqc trq ming ng[n xdp), O catot xiry n
A s1r khrl ionNa* B sg oxi ho6 ion Na+.
C s1r khtr phdn tu I{zO D sg oxi ho6 phdn tti H2O
CAu 11: Cho c6c chAt: C+Hro, C4H16O, C+HgCl,,C+HirN ChAt c6 s6 e6ng phdn c6u tpo nhiAu ntrAt h
A CH3CHO vd CzHsCHO
C (CHO)2 vi CHTCHO
A CaHro. B C+Hr rN
A.6,6 8,7,7.
A axit a-aminoisovaleric
C axit p-aminopropionic
,4, AgNO3 vdAu(NO:):.
C Fe(i.{O:): vd Mg$.{Og)2
B HCHO vd CH:CHO
D HCHO vd CzHsCHO
C C+HroO D C4HeCl
B alanin
D glyxin
B MgO{Og)2 vd Cu(t'{O3)2
D CuQ'{O:)z vd AgNOr'
CAu 12: Cho a mol h6n hqp X g6m H2, CzHz, CzH+ (s6 mol CzI{z bang pO rnol CzFI+) di qua xfc tr{c
Ni nung n6ng d6n khi c6c pfran n'ng yhy rahodn todn, thu duo.'c Ll,Zlith6n hgp khi Y (dktc) Ti khgi
cria Y so v6'i khi hidro bing 6,6 N6u cho a mol h6n ho.p X vio lugng du dung dich brom, thi kh6i
luo ng blnh dyng dung dich brom tdng m gam' Gi6 tri cria m ld
Cfiu 13; HoiL tan htit m gam A12(SOa): vdo nu6c, thu, dugc dung dich X Cho 220 ml dung dich NaOH iM vio X, thu du,gc a gam k6t tfia M{t kh6c, ntiu cho 60 ml dung dich NaOH lM vio X thi
cflng thu duo c a gam k6t tria Gi6 tri ctra m ld
A.8,55 B.10,26 c.5,13 D 17,10
CAu 14; Hdn h$,p X (c6 ti kh6i so v6i khf hidro bing 3,6) gOm Nu vd Hz Sau khi ti6n hdnh phen fng
t6ng hqp u-oniu", clugc h6n hqp Y c6 ti khdi so vdi khf hidro bing 4 HiQu suAt cria phin rtng t6ng ho-p amoniac ld
Cflu 1.5: Cho V lit khi CO2 (dktc) h6p thg hodn toin vdo 200 ml dung dich Ba(OH)2 0,751\4 thu ducr c
27,58 gamkiSt tria Gi6 tri cria V ld
A 3,584 B 3,136 C 3,136 ho{c 2,688 D 3,584 ho{c 3,136 CAu 16: Cho 0,1 mol arninoaxit X t6c dgng vtra dri vdi 80 ml dung dlch HCI 1,25IvI, lim bay hoi
dung dich, thu clury c 12,55 gam mu6i khan fhi no X t6c dgng vdi glyxin thi thu duo c sdrn ptrAm ta dipeptit TOn ggi cta X ld
Cflu 17: MOt h6n hqp X gd;m axetilen vd andehit axetic c6 ti kh6i hoi so vdi khf hidro bing 17,5 Cho
0,2 mol h$n hqp X vbo to-qng du dung dich AgNO3 trongNHr, thu dugc m gam k6t tua Gi6 tr! crla m
le
Cflu 18r Cho c6c chAt sau: f6 ftCilNaOil, g{$a)zCor Khi cho c6c chht tr6n phf,n img vdi nhau tirng cldi m6.t (trong dung d!ch) th-l@et-ao-nhi6u ch6t khf?
Ciu 19: M6t rnflu chAt b€o X c6 chi s6 axit bing 7 chrla tristearin c6 lln mQt lugng axit stearic Chi
si5 xd phdng ho6 cria m5u ch6t b6o X ld
Cflu 20: Cha 62,42 gam hdn hqp X g6m BaClz vd CaClz vlo I lit dung dich Y gdm hdn hqp KzCOr 0,2M vd 61r1110)2CO:-0,25M, thu duqc 57,58 garn kiit tUa PhAn tr[m vA ttrOi lugng cria CaCl2 trong X
le
A.53,35% 8.44,17Yo c.55,83yo. D,46,65ya
Cf,u 21: Nhi-6t phdn hodn toin 2 mu6i nitrat, thu dug'c ch6t rfn X Ni5u cho X t6c dgng vdi luqng du dung dich HCI iodng thi th6y X tan mQt phdn Hai muSi nitrat et6 li
Cda22: Phdn supephotphat kdp thuc t6 s6n xuAt dugc thudng chi ri'ng vli 40,0Yo PzOs Phdn trdm vA
khdi luqng cfia canxi dihidrophotphat trong ph6n b6n d6 ld
D.65,920/o
Trang2ll - Me dA thi 132
Trang 3Ciu 23: Dung dich duo" c dirng d6 ldm mAm nudc c6 tfnh crtng vTnh criu gdy n6n bdi c6c mu5i Caclz,
CaSƠ ld
Ạ CăOH)2 B CăHCO3)2 C Na2CO3 D BaClz
Ciu24: Cho phdn rlng ho6 hgc sau
Al + HNO3 -+ Al(NOr)r + NzO + NO + H2Ọ giist U l$ n",o irNo: 3 :4 Sau khi c6n bdng
phucmg trinh ho6 hgc tr6n v6'i h9 s5 h nhfmg s5 nguy6n t6i gian, thi hg s6 cria HNOg ld
CAu 25: Cho c6c nguy6n trl X(Z:1 |),Y(Z:12),T(Z=19) Ddy duo-c x6p theo chiAu ting dAn bdn kinh
nguyOn tu ld
Ạ Y, X, T B X, Y, T C T, X, Ỵ D X, T, Ỵ
Chu26: C6u hinh electron l6p ngodi cirng ctra ion X2'ld 3s23p6 Nguy6n t6 X thuQc
Ạ chu ki 3, nh6m VIIIẠ B chu ki 4, nh6m IIẠ
C chu ki 3, nh6m VIA" D chu ki 3, nh6m IVẠ
Cdt-27z Day gdm c6c loai to t6ng hgp ln
' Ạ to capron, to axetat, nilon -6,6 B to tim, xenlulozo, nilon -6.
C nilon-6, to visco, tónitron D to nitron, to capron, nilon-6,6
Ciu 28: Trong mQt binh kfn c6 c6n bing ho5 hgc sau:
H, (k) + 12 (k) GJ 2HI (k); AH : 51,88 kJ CAn bing ho6 hoc trdn sE chuytin dich theo chiAu thu$n khi
Ạ cho th0m chAt xtlc t6c
B t[ng ndng dQ crla HỊ
C ting 6p su6t chung bing c6ch giim dung tich binh
D tdng ndng dQ cria Hz hoflc 12.
Cf;u 29: Thuf phin khOng hodn todn pentapeptit mpch hd X, thu duọc h6n hgp sin phAm chria c6c
dipeptit Ala-Gly, Gly-Ala vd tri peptit GlýGly-Val Trflt tU sip x6p c6c aminoaxit trong pentapeptit
Xb
Ạ Gly-Gly-Val-Gly-Alạ B Gly-Ala-Gly-Gly-Va1
C Val-Gly-Gly-Gly-Alạ D Ala-Gly-Va1-Gly-Giỵ
CAu 30: C6ng thric ph8n trícfia mdt hA"p chAt htu cóX ld CgHroN2O3 Dun n6ng 18,3 gam X v6i mQt
lugng vila dri dung dich NaOH, thu duọ c dung dich Ỵ CO cAn Y, thu duọ c phAn hoi chrla hqrp chAt
htu co Z c6banguy€n trl cacbon vd cdn lpi a gam ch6t ran khan Gi6 tri cria a li
Cflu 31: Tr$n 3 dung dich HCI 0,3M, HzSƠ 0,2M vi HNO3 0,3M v6'i tir,5 tictr bíng nhau, thu duqc
dung dlch X D6 trung hod 300 ml dung dich X cAn ding V ml dung dich gdm h6n hqp NaOH 0,lM
vi BăOlIlz 0,2M, thu iluọ c dung dich Y c6 pH = 13 Gi6 tr! cta V li
Ciu 32: Thu! phAn hodn todn 31,25 gam dung dich saccarozo l3,68yo trong m6i truhng axit, thu
du-oc dung dich X Trung hod X bing dung dich NaOH, sau d6 cho tiSp lugng du dung dich AgNO:
trong NH3 dun n6ng nhg, sau khi c6c phin rlng xAy ra hoin todn thi kh6i lu-ọ ng Ag thu ttugc ld
Ạ2,565 gam 8.2,700 gam C 5,130 gam D 5,400 gam
Cf;u 33: Cho 0,la mol Fe vdo 250 ml dung dich AgNOr a molll (H = 100%), thu dugc dung dich X
Ạ chi c6 Fe(NO3)3' B BQm Fe(tlO3)2 vd AgNO:
C chi c6 Fe(NO3)2 D g6m Fe(NO:)r vd Fo(NO:)2
Cflu 34: Cho c6c ch6t: CzHo, C2Ha, CH3CHO, CHgCooCH:CH2 So ch6t phri họ p v6'i X theo so đ
CzHz-+ X -+Y -+CHECOOH ld
Ciu 35: 56 edng phdn c6u tao thuQc lopi hgp ch6t thom c6 cdng thric phdn trl CgHrz li
Cflu 36: ThC tich khi Cl2 (dktc) sinh ra nhiAu nh6t khi cho luo-ng du dung dich HCI d[c vdo m gam
Ạ MnO2, dun n6ng B KMnỢ C.KzCrzOt D KClOr
Trang3l5 - Ma dA thi 132
Trang 4Cflu 37: Cho c6c ch6t h dbng phdn cAu tao d4ng mpch hd cria CzH+@.ldn luE t6c dung vdi Na, NaOH, NaHCO: S6 ttri nghiQm x&y ra phin fng ho6 hgc ld
CuClz 56 trub'ng hgp xAy ra sg [n mdn diQn ho6li
Cflu 40: Cho V lit khi CO2 (dktc) h6p thg hodn toin vdo 250 ml dung dich NaOH 2M, thu duọ c dung dich X Cho luọ ng du dung airfr buifr vio X, thu duọ c 39,4 gamtrtit tuạ Gi6 tri cria V ld
Ạ4,48 hoac 8,96 -p.6,72 ho6c 8,96 C.4,48 ho[c 5,60 D 4,48 ho6c 6,72
rr PHAN RrtNG [10 caul
Thi sinh chi cluqrc chqn mQt trong hai phin tptttl ho[c_B)
Ạ Theo chuang trinh ChuAn (10 cAu, tir ciu 41 cl€n cAu 50)
Ciu 41: Cho 4 thanh sit nguy€n ch6t vao c6c dung dlch sau: FeCl:, HCl, CuSƠ, HCI c6 l6n mQt it
c.3.
c.0,5.
c.4.
D.0,4.
D.3.
D.8.
Cflu 38: M6t h6n họp X gdm hai anken ld đng ding.k6 ti6p cria nhaụ Cho 1,68 gam X phin fmg
vila hiit v6{ 8 gam Urom trong dung dich M{t khi4c, ntiu hiclrat ho6 hodn todn 1,68 gam X, thu du-rỵ c h6n hqp *"oiỵ Cho Y phan ung hodn todn vdi CuO nung n6ng thu tluqg h6n hqp Z Cho Z vdo luqne du dung dlch AgNO3 trong NH3 dun n6ng, thu tlugc 7,56 gam Ag (bi6t rlng c6c phan img dat
hiQu suAt lO0%) Phdn trim leir6i lugng cua ancol b6c 2 trong Y ld
Ạ 19,58% 8.34,88% ' C ll,63yọ D' 18,34%'
C6u 39: Cho 1 1,34 gambqt Al vdo 300 ml dungcilch hdn họ p gdm FeCl3 1,2M.vd CuClz aM, sau khi
c6c phin rlng xiy ,u-ho* toan, thu dugc dung dich Xvd26,4 gam h6n họ p g6m 2 kim lơị Gi6 tri ctla a ld
Ciu 42: Hoi tan hoin todn h5n h-ọp gdm 0,02 mol FeS2 vd 0,03 m91 FẹS vdo lugng du d]1e-dich
HzSƠ d6c, n6ng thu duọ c lrhf SOz (san phAm Lhri duy nh6t cua 5*6; Hdp thp hodn todn SOz blng luqng yrra An aung Oich fUnƠ, thu cfuo-i V lit dung dich khOng mdu c6 pH:2' Gi6 tri cfia V ld
16,8-Cf,u 43: Cho tir tir di5n du dung dleh NHr vio cdc dung dich ri6ng biQt sau: Fe(NO3)3,.2n(l'{.O3)2,
AgNO3, Al(NOg)r, Cug{O3)2, NiSOọ Sau khi tiitttilic phin irng, s5 thf nghiem.thu dugc k€ttria li
CAu 44: Cho r6t tir tir 250 ml dung dich HCI lM vdo 100 ml dung dich hdn hqp g6m NazCOr a mol/l
vd KHCO, b mol/I, thu duọ c z,z6 rc khi (dktc) vd dung dich X cho lu-ọ ng du dung dich căoH)2
vdo dung di"h x, thu dugc 5 gam kct triạ Gi6 tri cfia a vd b ldn luqt li
Ạ lM vd 0,5M n zvr vd 2M c lM vd 1M D 1,5M vd 2M
ciu 45: Thu6c thrl duọc dnng d6 phan biQt c6c dung dich ri6ng bigt Nll4cl, MgCl2, 0{H+)zsơ,
A1Cl3, FeClz, FeClg li
cf;u 46: H6n họp X gom .2 axitcacboxylic no, m4ch-họ 9ot ch6y hoantgal-O:3 mol X, thu dugc
Il,Z litkhi COz t6f.Lị lj6 t*ng ftoa 0,i mol X c6n dirng 500 ml dung dich NaOH 1M' COng thtc
cria 2 axit trong X ld
ẠHCooHvd(Cootf)2.B.CHlCooHviCzHsCooH.
c1u 41tph6n tí kh5i trung binh ctra nilon-6,6 lit2g832 sd mit xfch trung binh ctra polime d6 ld
cau 48: Thuoc thrl dugc dnng d0 phan biQt c6c dung dich ri€ng biet: NaoH, Ala-Gly, Gly-A-la-Gly ld
Ạ dung dich CuSỢ n.-Oung dich BaClz' í CulOU;t' D' dung dich CaClz' CAu 49: Dun n6ng anccl don chf'c, m4ch h6'X v6'i HzSƠ đc, 6 nhiet dQ thich hgp, thu duqc mQt
chft hnu co Ỵ Ti khSi hoi cria y so vOiX bing 1,7 Cho X t6c dgng vdi CuO ilun n6ng t*o ra chit
hfl.u cọZ c6 th€ tham gia phf,n ríng tr*ng b4c c6ng thtíc cin_X ld
Ạ (CH3)2CHOIL B CH3CH2iH2OH' c' cH3oH' D' CzHsoH'
Ciu 5b: Cho sóđ chuY6n ho6 sau:
Trang4/5 -MadCthi 132
Trang 51800C, H2So4 d4c H2O, H2Soa lodng, to Cuo, t0
cI{3cH2cH2oH
-+ X
-*
y (sin pham chfnh) -+ z ChiitZtrong sCI dO trCn la
A CH3CHO B CH:CHzCHO C CI{3CH2COOH D CI{3COCH3
B Theo chuong trinh Nflng cao (10 cfiuo tir cAu 51 d6n cflu 60)
Ciu 51: ChAt X ln mQt disaccarit duoc t4o boi 2 g6c o-glucozo li€n ktit vdi nhau boi liOn ki5t
CI-1,4-glicozit ChAt X khdng thd tham gia phAn rlng
A thuy phAn trong mdi trudng axit
B vdi CH:OH (HCl khan ld xric tilc) theo ti'lQ.mol nx :nca,oa : I :2.
C vdi dung dich AgNOr trong NH3
D hodtan Cu(OH)2 o nhi$t dQ thucrng
Ciu 52: Cho h6n hgp gdm a mol CuSO+ vd b mol KCI vdo nudc (du), thu dugc dung dich X DiQn phdn dung dlch X vfi dign cgc tro vd mdng ng6n xdp, thu dugc mQt dung dlch c6 th6 hoa tan AlzO:
Mdi quan h0 gifta a vd b li
A.b<2a B.b>2a C.b>2aho{cb<2a D.b:2a"
Cflu 53: Cho dung dich X chfa h6n hqp g6m NHr 0,1M vi NH+CI 0,lM ni6t O ZSOC hing s5 phin li
bazo criaNH3 ld 1,8.10'5 vi bo qua sU pnan U cfa nudc Dung dich X c6 gi6 tri pH O ZSoC bang
Cflu 54: Hod tan hodn todn a gam FeSO+"7HzO vdo nudc, thu tluqc I.lit dung dich X Ldy 250 ml
dung dlch X cho th6m dung dich HzSO+ lodng ldm m6i tru'dng r6i chudn dQ b[ng dung dich KMnO+ 0,lM thi dtng vla tri5t +O ml dung dich Gi6 tr! cria a ld
Cdu 55: Phenol CoHsOH khdng tdc dgng v6i t6t ctt citc chlit trong d6y:
A CH3COOH, CzHsOH, HCl B Brz (dung dich), H2, NaOH
C Na NaOH, (CH3CO)2O D CH3COCI, (CFI3CO)2O, HNO:
CAu 56: Cho so'dd chuyCn ho6 sau:
HCN H2SOa lodng, to HzSO+ d{c, to
CH:-CH=O -* X -+ Y -+ Z.
C6c chAt htu co X,Y, Ztrong so db tr6n lin luqt li
A CH3CH(OH)CN, CH3CH(OH)COOH, CHz=gHaOO".
B CHrCH(OI!CN, CH3CH(OH)COONru, CHt=61taOONH+
C CH3-CH2-CN, CH:CHzCOOH, CHz=CHCOOH
D CHr-CHz-CN, CHTCHzCOONH4, CHr:gltaOONH+'
COu 57: Dung dfch ndo sau ddy c6 the hodtan hodn todn 1,92 gam Cu?
A dung dich HzSOq lo6ng, du c6 hoi tan 0,32 gam khi oxi
8.200 ml dung dich gdm HzSO+ 0,175M viNaNOr 0,1M
C 200 ml ciung dich g6m HzSO+ 0,2M vd KNOr 0,l5M'
D.200 ml dung dich Fe2(SOa)3 0,1M
CAu 58: Ddy gdm cdc chht khi tdc dgng v6i dung dlch gdm NaNOz vd axit axetic dAu sinh ra khi Nz le
A glyxin, etylamin, anilin B glyxin, dimetylamin, alanin.
C etylamin, dimetylamin, anilin D anilin, glixerol, etanal
Ciu 59: OA tacn Al(Of& ra kh6i h6n h-o'p gOm AgCl, AI(OH), Zn(OH)2, Ni(OH)2 ngudi ta dtng lugng du
C0u 60: Thutic thrl kh6ng th6 dnng d6 phdn biQt propanal vd axeton ld
C dung dich AgNO3 trong NH3 D Cu(OH)2 o nhiQt d$ thud'ng
Trang 5/5 - Ma dB thi 132