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GIAI RAT CHI TIET HOA KHOI A,B CAO DANG

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ĐỀ THI TUYỂN SINH CAO ĐẲNG NĂM 2010 Môn thi : HOÁ, khối A, B - Mã đề : 516                 !  "    #      $  %    !  &'    (  )    $  '    $*+*  ,$-!./*+0*##!1#*2/3.&.32$(4 I. PHẦN CHUNG CHO TẤT CẢ THÍ SINH (40 câu, từ câu 1 đến câu 40) Câu 15/6789:;<<='>?<<=@4AA<<=  $ <>B< <=@+CD5ED+FG+>?<<=HBDIH457'B &40" 240 4" J4 Câu 2 K?8LH#+(H%B.+3H%"<M;'>?<><<= " $ 4) 89:D9/BB+>?.+3-#'NHON7B<<=@4PBHQ<<=@ >?!#HH4,N7'B &4 "  24  " 4 " J4  R9 .+3 .+. Mg MgO n n= = GH H  $    .+3 .+.4!3 !!+!  Mg NO m g= + = SHLH% " $   B  ! " $ S ! $ ! $ !# !!+! +#  .+. NH NO NH NO m g n= − = => = TUN7 D "  % →  Mg e + +   *  *    y x x x y y x N xe N N O x + + + − →  * $ ! $ 3  N e N NH NO + − + → .+3.+*#*DV.+.!.+.!.+#.+. G.+*#*DV.+.!W.+#S*DV.XD. YZ7'B  Câu 3 +*#HK?8LH&'B&'  " $ 89:;<<='<>+>?Y'NN  B<<=74 [AA<<=  $ <>B<<=7>?+'X'>? +'>?\]>?+.!H5/64R/=Y'B &4.+#( 24.+! 4.+!!3 J4+$!! R9FQL . $  <<  <<'< $ $  $  $  <<&''    du t H Al x Al OH Al O Al O y HCldu + + → → → H /5   $  $ +.! .+. Al O Al O m n= => = G ( . +*#  .+.! x y x y + =   + =  SD.+.S   $ .+.$ .+#(   H Al H n n V lit= = => = Câu 4 ^_8`BBO/<<=D\Q'a+>?5bQ74789 :;N  Dc + . +>?5bQ@457+@'C'>?'B &4'dQ+F/dQ 24'dQ+F' 4'dQ+e/dQ J4'dQ+' Câu 5 #+!HK?87LHDD''BLf889:BB; H'<<= "%B,"%>?<<=@4\g<<=@+>?$+HK?8 5/64\:D/7'B &4   ! "  B $  ! "   24   ! "  B $  # "   4 $  ! "  B !  # "   J4 $  # "  B !  3 "  R9JhB8SDD''BQ: TU\:D ""RC ""RC W " → "" RC W  " DDD ""RC W," → "",RC W  "  ^G  !*  #+!  #(  3$ !..+  *#.+  $+ R x y R x R y x y  + + =   + + + + − + − =   S  !*  #+!  (  +- R x y R x y  + + =   + + =   SDW.+*S #+! !* #*+# .+# * - .+* R R R R+ = = => = => = = YZ\:D/7'B   ! "  B $  # "  Câu 6 J<=BF`'BHijNHkHBDl &4R'D  24m'H  4&'  J4n'H'/ Câu 7 K?81LHF7B@gopHO'BDD'8/<a Lf% 7 q% @ 4TBBHH1C<p#+#'NN"  +>?*+#'NN"  B!+*H  "4\:F7B/=H>Q:'B &4 $ "" $ B#+( 24""   * B-+*  4"" $ B#+(  J4""     ! B#+# R9   .+* .+* CO H O n n= = S7+@'BFQ: r8<MTP2^,PH *+# 4!! +! W!+*V #+# 4$ +! #+( TU\:7+@  n n C H O S     .+* n n C H O CO n n n n = = S #+( ! $ #+3 .+* n n n+ = = S +*n = S$7   ! "  "" $ @ $  # "   $ "" $ Câu 8 :hA/F89U8DV/<aE<aEhs >F1 W t10 W t0 W t0 $W t0 W & W t& H'gBu89:>?;0 W /<<='B &41+ W  24&+0 $W  4&+ W  J41+& W Câu 9 n'HBF`>?]?8v89:/p>l &48'/'/  248'H'H/'  48'F/ J48''/8' Câu 10 w;\:8`   ( "  G5A89:>?;<<= "A 89:>?;<<='l &4 24$ 4 J4! Câu 11 BK?8LH,  "+2"+&'  " $ +0 $ " ! B>;<>+>?<<=7B5/6@4 )MN"  <>B<<=7+F89:D9/BB>?'B &4,  " $ 240" $  4&'" $  J42" $  Câu 12 -+*HH/89:;<<=  )" ! <>+>?<<=: (+*HHFe/B4\:H/'B &4 " $  24%" $    42" $    J4" $   R9X\:H/%" $    )QL%" $    → %  )" !   H'H''>?9H4#V-## u +#*4 .+* #n n = -+*V(+*+#* %W# -+* ($ .+* n n= S%S%!% \:H/'B%" $    Câu 13 ^_8`BB$+!HF/dQ/H\/>xD+>?<<=74BO <<=789:;'>?<><<=& " $ /  $ +G+>?HH&4R/= H'B &4+#. 24+# 4!+$ J4!$+. R9    "  W  " →  #   " # W #   " # .+..+..+.  #   " # W& " $ W  $ W  " → & .+..+.!SH & .+.!4.3!+$ Câu 14 PGXb/8`  "'B' &4O/=\8`h 24/ 4  J4O/=8`h Câu 15 nkc'B &4n'89:>?;<<= " $  24n'89:>?;>;/H  4Y'D89:;<<= "F/''  J4^_8`d''/>?8' Câu 16 ^_8s5bQ7/<<= "<>+G+>?F98sHLHHB ''457'B &4 $ ""   $  24 $ ""    '  4'  ""   *  J4 $ ""' $ Câu 17 nkBF`cl &4J<= 089:;<<=& " $ F/&0  24yGN';Q/H  4&D2/GNDQD'  J40'GNDQ' Câu 18 <<='a0' $ +0'  +$  )" ! +! " $ +*K?8LH'B  " $ 4 b<<=89:>?;H'g'B &4++$ 24+$+* 4+!+* J4+$+! Câu 19 .H'<<=''!# . 89:;H'g <>+>?Y'NN  4 2'>?/''5v.+3tH'4R/=Y'B &4!+*# 24.+3-# 4$+$#. J4+3 R9  *  * .4!# !+#  .+34!+# $+#3   C H OH C H OH V ml m g= = => = =     . !+# *+!  *+!4 *+!  H O H O V ml m g= − = => = = z   t H O D g ml=  S   *     $+#3 *+!   .+-    !# 3 H C H OH H O n n n= + = + = S  H V = !+*# Câu 20  H'g 7+ @+1G 5z '/'C'>?'B F  F  8 # $F  F  F  8 # $F   F  F  8 # $F  $8  4JaLHH'gD8u{<CNA/F89'B &47+@+1 241+7+@ 41+@+7 J4@+1+7 Câu 21 TBB#+('NK?8LH/7B@% @ S% 7 +>?+'N "  B.+3H  "4\:7'B &4   #  24   !  4 !  J4    R9 7+@ .+.$"  .+*  ".+# 7+@'B/S 7+@ .+#V.+.+ ≠ .+$ YZ/LHB G   W  → "   H  H  → H"  .+.+.+$V.+.+H ^u.+W.+H.+*SWH*XHz% @ S% 7  \:7'B ! Câu 22 JaLHpLg/HO<<='B &4, W +2 W +" V +' V  24&' $W +n" ! $V +' V +2 W  4  W +, W +" V +" $ V  J4 W +' V +  W +" $ V Câu 23 `vX * $  n'  n'  '   .+ ∆ >€ `vk<=uZ &4Hn' $ BE89: 24{EOE89:  4H'  BE89: J4{8F5E89: Câu 24 TBB+(#HK?87LH D   ""+ D   "" $ + $ ">?+#33'N "  B+3H  "4%U++(#H789:A;$.H'<<= "%+ >?.+-#H $ "4\: D   ""'B &4   * "" 24 $ "" 4   $ "" J4 $  * "" R9"  .+  ".+HB $ "'Q: D   ""\Q:    V ""W"  W  " W    V "" $ W"  WW  " WW  $ ""  W  "  ^G     .+    .+ .+.$ .+.$ n a n b c na n b c a b b c + + + + =   + + + =   + =   + =  \: D   ""'B   $ "" Câu 25  )G/|A'B5+A'B5D/89:BF`l &4!)W# " U  .  →    )W   )  " $ W$  "  24)W$0   .  → )0 #  4)W# " $U .  →   )" ! W# "  W  "  J4)W  .  →    ) Câu 26 JaLHH'gG5gHgk'Z88>Q`H'B &4 +,+% 242+%+ 4P+ + J4P+ +, Câu 27 H0B H'<<=K?8LH " $ .+3%B " $   %4)89 :D9/BB+>?.+-HK?8H'gBN "F98sH<5 * + 4RN/= 'B &43+! 24*+# 4+ J4+. R9G  $ .+.3 .+3 .+ H NO Cu n n n + − + = = = 0W $ !H NO + − +  → 0 $W W "W  " .+..+.3.+. 0W0 $W  → $0 W  .+..+. 0W W  → 0 W W .+.+.+ GV.+$4*#W.+4#!.+-S Câu 28 w;\:8` $  # "G?85Hgou<M;N  Dc + . F/'l &4$ 24! 4 J4 Câu 29 89:   )" $ W,%" ! W )" ! →   )" ! W%)" ! W,  )" ! W  " ^]EF5'BbF+9/8>Q/z89:'B &4$ 24( 4!( J4$ Câu 30  [AA<<= "<>B<<=74)89:D9/BB} >?<<=/F45/<<='B &4&'' $  24)" !  40 " $  $ J4" $    Câu 31 !*HDD89:;#-H''Dc  )" ! U+G+>? !+*H'D4EF589:F'B &4#+*.~ 24*.+ ~ 4!.+ ~ J4$+*~ R9 DD .+(* '' +*S'<>SHF'•.+(*433## ~ !+* 4 #+*~ ## = Câu 32 -+3HK?8OLH1B0B# H'<<=)" ! .+*%4)89: D9/BB+>?<<=7B$.+!HK?8H'g4nC/{Hu'>?0/ K?8C'B SWV.+. S.+. .+.  &4*#+$(~ 24$(+*3~ 4#!+!~ J4!$+#~ R9)" ! .+.$ 1W W  → 1 W W DDD 0W W  → 0 W W .+.$VD.+.$VD.+.$VD uHH'g*#V.+.$WDW#!4.+.$$.+!SDW.+* HU#*DW*#-+3 S.+$S~H0 .+$4*# 4 -+3 *#+$(~ Câu 33 57B@Gp\:8`   ! "  45789:>?;H'g BH 89:/g45@89:>?;H'g BB>?" $ 4\:7+@ 'C'>?'B &4"  "+ $ "" 24"" $ +"  "  4 $ ""+"  " J4"" $ + $ "" Câu 34 &Hgo7G\:Q95   $ "4\:8`7'B &4 3   " !  24 #  - " $  4   $ " J4 !  # "  Câu 35 FQLkF 7 @ 1  $  $ " '  "  " + + + → → → \:7+@+1'C'>?'B &4'  +& " $ +%" $  24'  + " $ +"   4'+ " $ +   " $  J4'+& " $ +  !   " $ Câu 36 .+.*H'HO'g?85'HB>;>? H'<<=74Tk/B H' <<=7C<p H'<<= ".+*%4nC/{Hu'>?'>j/ 'H/'B &4$(+3#~ 24$*+-*~ 4$+-(~ J4$+#*~ R9  )" ! 4)" $ WW  " → W  )" ! W .+.*.+.#   )" ! W " →  )" ! W  " .+.$.+.$ Câu 37 Tk/B*HHO'g5€G}FDv(+C<p<<=:H "4 R/='B &4.+*. 24.+3. 4.+.(* J4.+ R9," H 4 chÊt bÐo chØ sè axit 1000.56  *4( 1000.56 +3(*4. V$  "SH ".+.(* Câu 38 +HK?87LHH+Q:+8/<aLf89:; <<='<>+>?$+-*HK?8H4\:H/K?87'B &4 $   B   *    24   *   B $  (    4 $  (   B !  -    J4 $   B $  $  R9HQ:  $n n C H N + G' $+-* + .+.* $#+* − =   $n n C H N + S + ! ( ! .+.* n + = = S +(3n = \:H/K?87'B $   B   *    Câu 39 )'8σDNHG/HK8`'D'V+$V'C'>?'B &4$*- 24*$- 4!# J4!$# Câu 40 58MBB$+$#'NN"  B*H'<<=2"  %+>?<<=74 kN<<=\]+LOH'5/<<=7'B &4.+!% 24.+% 4.+#% J4.+% R9"  .+*" V .+*4.+*Gq  .+* +#  .+* OH CO n n − = = < SW!S$ S~) 3 4 $(+3#~ $$3 = "  W" V  →  $ CO − W  "  "  W" V  →  $ HCO −     $  .+.* .+  .+* Ba HCO M C M= = PHẦN RIÊNG [10 câu] Thí sinh chỉ được làm một trong hai phần (phần A hoặc B) A. Theo chương trình Chuẩn (10 câu, từ câu 41 đến câu 50) Câu 41 $+H789:;.+H'  Dcn<tn" $ + . +>?K?8@}G /4\:8`7'B &4     24 *  3  4 !  #  J4 $  !  R9^uK?8@LH<>Bz   V W   $ tPb PbCO →      JhB87'B    z   $+ .+ # C H n = = G    H;<> Câu 4289:2/  W""→2/W"  LOC2/  'BH't'N+F*.`LO2/  |'g'B.+.H't'N4^O/z 89:/N2/  'B!4. V* H'l.s)4R/='B &4.+.3 24.+.# 4.+. J4.+.! R9A89:2/  W""→2/W"  •‚   •‚ 8: V.+.V.+.    Y *   •" ‚ .+. 4 !4.   *. a − ∆ − = = ∆ S.+. Câu 43 "D\BB'F8/8'v"G+>?5bQ74^X 7'B &4H'8'D 248/8' 4H''D J4H'D Câu 44 ^<pk8`E<<=  ! " $ ;<<=  !   )" ! 'B &4<<= "B<<=' 24LyyDB<<='  4LyyDB<<= " J4H'gB<<=' Câu 45 nkBF`khôngcl &4/HYyD'BDdQ 24&''8Dc;/" $  4,89:;<<='+H'g/=DB/ W  J4/HyyyDB/Hyy/Du'B5GN'>ƒN Câu 46 )98sH89:E8`BB& " $ 'B &4&+ "  +"   24&  "+ "+"   4&+ "+"   J4&  "+ "  +"  Câu 47 U85BF`không 89'BL8`l &4&''BH' 24R'dQBe/dQ 4)/dQBD''dQ J4VH'8/8VV'BVV' Câu 48  _8`\BB888R'V&'VR'V&'VR'z>? 88l &4$ 24 4 J4! Câu 49 &DD'7G\:Q95'B $  * "  4, H'<<=D7LO .+%89:;<<= " $ <>+>?YH'N"  4R/=Y'B &4 24! 4!!3 J4$$# R9^n^7 $  * "     $  * "     ! ""  S !  3 ""  G!4WVS  !  3 ""  W " $  →  !  3 ""   W"  W  " .+..+..+!!3'N .+* .+  .+* .+.* a b a a b b + = =   =>   + = =   $  $     4.+.*   .+.* Ba HCO HCO n n − = = = Câu 50 ,H'g%Gk>?uvG/DoN  oEO4%U +H'g%>? W /<<=D'aB  4,H'g%'B &4&' 24% 40 J4 B.Theo chương trình Nâng cao (10 câu, từ câu 51 đến câu 60) Câu 515BF`GL8`zXl &42VV 242VV 4+V' J4V'8/8 Câu 52)HQHZHO:;\:8` (  - 'B &4 24! 4* J4$ Câu 53HHO/H89:BB;<<='<>>?Y'NN  4%U „HHO/H/89:BB;N"  <>>?*+HD<54R/= Y'B &4+! 24!+!3 4$+$# J4#+( R9!/W$"   →   $ Cr O /W' → /'  W  .+.+.+.+4+!!+!3'N Câu 54   % t% m + −+$(Y   1 t1 m + −.+(#Y   n tn m + −.+$Y    t m + W.+$!Y4 nEGGF5EOsv+#Y>?5goU8DGV4 &4n W tnB W t 241 W t1Bn W tn 41 W t1B W t J4% W t%B1 W t1 R9 . . . pin pin pin E E E= cùc d ¬ng- cùc ©m G}G   . . t tZn Zn Mg Mg E E + + − V.+(#VV+($+#Y Câu 55!+#HHO'+Q:89:;"G+>?#+HK?87LH +>;B'<>4BO'>?K?8789:BB;'>?<><<=& " $ /  $ +G+>?HH&4R/=H'B &4#+ 24!$+ 4.+3 J4+# R9…  "W" → …"WW  " H"#+V!+#+#S " .+. …"W& "$W  $ W  " → & .+..+.!4.3!+$ Câu 56TE8`<<=)" ! ;vLBE8`<<=)" ! ; v/8Eh/QuGUkH'B &4oD9/FhDG  "W→" − W  24oD9/Fh  "→"  W! W W! 4oD9/FhDG→ W W J4oD9/Fh W W→ Câu 57J<=BF`G8S(l &4J<= ' 24J<=  ! ' 4J<=&'  )" !  $ J4J<= $ ""  Câu 58†uEN?85789:;5@g/D5789:;51 g/''457+@+1'C'>?'B &4   ! +"  +  " 24    +  "+  4   ! +  "+" J4    +"  +  " Câu 59^<pk8`E$<<=/E '+ )" ! +''B &4  ! ' 24  !   " $ 42'  J42" $ Câu 60,9{89:'vGH‡"5>?D8u{<CA /F89'B &4'''/+8''/+8/8''/ 24'''/+8/8''/+8''/ 48''/+'''/+8/8''/ J48''/+8/8''/+'''/ Giáo viên : Ngô Hữu Tài - Trường THPT Hương Thủy - Huế Địa chỉ : 1 Nguyễn Du - Huế . 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