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Nonferrous Aircraft Metals

Heat Treatment of Nonferrous Aircraft Metals

Mechanics of Aircraft Materials

Department of Aerospace Engineering – Faculty of Transportation Engineering

Dr Ly Hung Anh

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N ONFERROUS A IRCRAFT M ETALS

 “nonferrous” metals: all metals which have elements other than iron as their base or principal constituent.

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A LUMINUM

 Aluminum is one of the most widely used metals in modern aircraft construction.

 Properties of pure aluminum:

 white lustrous metal

 second in the scale of malleability

 sixth in ductility

 ranks high in its resistance to corrosion.

 high strength to weight ratio

 comparative ease of fabrication

 low melting temperature of 1,250 °F

 nonmagnetic

 excellent conductor.

 tensile strength of about 13,000 psi 4

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 magnesium and silicon

 Alloys in which substantial percentages of copper are used are more susceptible to corrosive action.

 The total percentage of alloying elements is seldom more than 6 or 7 percent in the wrought alloys.

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A LUMINUM A LLOYS

 The tensile strength may be raised to as high as 65,000 psi or to within the strength range of structural steel.

 Aluminum alloys, although strong, are easily worked because they are malleable and ductile.

 They may be rolled into sheets as thin as 0.0017 inch or

 They may be rolled into sheets as thin as 0.0017 inch or drawn into wire 0.004 inch in diameter.

 Most aluminum alloy sheet stock used in aircraft

construction range from 0.016 to 0.096 inch in thickness; however, some of the larger aircraft use sheet stock

which may be as thick as 0.356 inch.

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C LASSIFICATIONS OF A LUMINUM A LLOYS

 Casting alloys: suitable for casting in sand, permanent mold, or die castings.

 Wrought alloys: may be shaped by rolling, drawing, or forging.

 The wrought alloys are the most widely used in aircraft

 The wrought alloys are the most widely used in aircraft

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C ASTING A LUMINUM A LLOYS

 2 types:

 The physical properties are determined by the alloying elements and cannot be changed after the metal is cast.

 The alloying elements make it possible to heat treat the casting to produce the desired physical properties.

 Identification: by a letter preceding the alloy number.

 addition of zinc in casting alloy 214: A214.

 heat treatment of casting alloy 355: T355.

 Casting methods:

 sand mold

 permanent mold

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M OLD C ASTINGS

 Mold castings:

 pouring molten metal into a previously prepared mold

 allowing the metal to solidify or freeze

 removing the part

 Molds:

 Molds:

 Sand: sand casting.

 Metals (cast iron): permanent mold casting

 Properties: metal flowing under the force of gravity alone.

 Examples: casting alloys 112 and 212.

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P ERMANENT M OLD C ASTING

 Properties: fewer openings (called porosity) than in sand castings.

 Using for obtain

 higher mechanical properties

 better surfaces

 better surfaces

 more accurate dimensions.

 Two specific types :

 Permanent metal mold with metal cores.

 Semi-permanent types containing sand cores.

 Examples: Alloys 122, A132, and 142

 Applications: used in internal combustion engines. 10

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D IE C ASTING

 Die castings used in aircraft are usually aluminum or magnesium alloy.

 Aluminum alloys: stronger

 Magnesium alloys: lighter A die casting:

 A die casting:

 forcing molten metal under pressure into a metallic die

 allowing it to solidify

 the die is opened and the part removed

 Die castings are used where relatively large production of a given part is involved.

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F IRST G ROUP

 The second digit indicates specific alloy modifications.

 0: indicate no special control over individual impurities

 1-9: indicate the number of controls over individual impurities in the metal.

 The last two digits: indicate the hundredths of 1 percent above the original 99 percent designated by the first

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S ECOND G ROUP

 The second digit in the alloy designation indicates alloy modifications.

 if the second digit is zero, it indicates the original alloy,

 digits 1 through 9 indicate alloy modifications.

 The last two of the four digits in the designation identify

 The last two of the four digits in the designation identify the different alloys in the group.

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E FFECT OF A LLOYING E LEMENTS

 Copper

 It gives the alloy excellent mechanical characteristics

 It especially facilitates machining in the quenched state

 It improves the creeping strength as well as the resistance to high temperatures

 It increases the alloy’s aptitude for surface treatments

 It decreases the corrosion resistance

 It makes welding difficult

 It reduces the capacity of the alloy to be deformed

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E FFECT OF A LLOYING E LEMENTS

 It forms alloys insensitive to structural hardening

 It forms alloys having an excellent corrosion resistance

 It can be easily worked on.

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P ROPERTIES OF A LUMINUM A LLOYS

 1000 series:

 99 percent aluminum or higher

 excellent corrosion resistance

 high thermal and electrical conductivity

 low mechanical properties

 low mechanical properties

 excellent workability

 major impurities: Iron and silicon

 2000 series

 Solution heat treatment

 optimum properties equal to mild steel

 poor corrosion resistance unclad

 Its best known alloy is 2024 18

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P ROPERTIES OF A LUMINUM A LLOYS

 3000 series

 generally non-heat treatable

 percentage of manganese: effective at 5 percent

 most popular is 3003, which is of moderate strength and has good working characteristics.

 4000 series

 lower melting temperature

 primary use is in welding and brazing

 respond to a limited amount of heat treatment.

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P ROPERTIES OF A LUMINUM A LLOYS

 5000 series

 good welding and corrosion resistant characteristics

 high temperatures (over 150 °F) or excessive cold working will increase susceptibility to corrosion.

 heat-treatable alloys of very high strength

 usually has copper and chromium added

 principal alloy of this group is 7075 20

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 H1 (plus one or more digits) — strain hardened only

 H2 (plus one or more digits) — strain hardened and partially annealed

 H3 (plus one or more digits) — strain hardened and stabilized

The digit following the designations H1, H2, and H3 indicates

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M AGNESIUM

 Magnesium is the world’s lightest structural metal.

 Properties:

 silvery white material

 weighing only two-thirds as much as aluminum

 insufficient strength in its pure state for structural uses

 insufficient strength in its pure state for structural uses

 highest strength to weight ratio in alloying state.

 widely distributed in nature than any other metal.

 can be obtained from such and from sea

 high thermal conductivity

 in large sections: not burn until the melting point of 1,204 °F

 in dust and fine chips: ignited easily.

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M AGNESIUM A LLOYS

 Magnesium obtained from

 ores: dolomite and magnesite

 sea water

 underground brines

 waste solutions of potash

 waste solutions of potash

 Magnesium alloying elements: aluminum, manganese, and zinc.

 Identification:

 Designated by a letter of the alphabet, with the number 1 indicating high purity and maximum corrosion resistance.

 by the Dow Chemical Company: Downmetal J or M

 By the American Magnesium Corporation: AM240C 24

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M AGNESIUM A LLOYS P ROPERTIES

 Good casting characteristics

 Subject to such treatments as annealing, quenching, solution heat treatment, aging, and stabilizing

 Sheet and plate magnesium are annealed at the rolling mill

 Solution heat treatment: to get high tensile strength and maximum ductility

 Aging: to castings following heat treatment to get high hardness and yield strength

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M AGNESIUM A LLOYS A PPLICATIONS

 Wing panels: weigh 18 percent less than standard aluminum panels, and have flown hundreds of satisfactory hours

 Nose wheel doors

 Flap cover skin

 Aileron cover skin

 Oil tanks

 Floorings

 Fuselage parts, wingtips, engine nacelles, instrument panels, radio masts

 Hydraulic fluid tanks, oxygen bottle cases, ducts, and

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T ITANIUM

 Titanium, in appearance, is similar to stainless steel.

 Properties:

 elasticity, density, and elevated temperature strength: between aluminum and stainless steel

 melting point of from 2,730 °F to 3,155 °F

 melting point of from 2,730 °F to 3,155 °F

 low thermal conductivity

 low coefficient of expansion

 light, strong, and resistant to stress corrosion cracking

 60 percent heavier than aluminum and about 50 percent lighter than stainless steel

 yield strength drops rapidly above 800 °F

 nonmagnetic and has an electrical resistance 28

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T ITANIUM A LLOYS

 Titanium alloying elements: Iron, molybdenum, and chromium

 Production: by quench harden and age harden

 The addition of these metals also adds ductility.

The fatigue resistance of titanium is greater than that of

 The fatigue resistance of titanium is greater than that of aluminum or steel.

 Some of the base alloys of titanium are quite hard.

 Heat treating and alloying do not develop the hardness of titanium to the high levels of some of the heat-treated

alloys of steel.

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T ITANIUM A LLOYS A PPLICATIONS

 Turbine housings and liners

 Miscellaneous hardware for turbine engines. 30

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BASIC TYPES OF CRYSTALS

 excellent bend ductility

 strong both cold and hot

 vulnerable to contamination

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BASIC TYPES OF CRYSTALS

 C (combined alpha and beta for compromise performances):

 strong when cold and warm, but weak when hot

 good bendability

 moderate contamination resistance

 moderate contamination resistance

 excellent forgeability

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 high electrical and heat conductivity

 high electrical and heat conductivity

 malleable and ductile

 corroded by salt water but not affected by fresh water

 ultimate tensile strength of copper varies greatly:

25,000 psi for cast copper

40,000 to 67,000 psi for cold rolled copper

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C OPPER A LLOYS

 One of the most successful of all the copper base alloys

 Composition: about 97 percent copper, 2 percent beryllium, and sufficient nickel to increase the percentage of elongation

 Properties:

 the tensile strength rising from 70,000 psi in the annealed state to 200,000 psi in the heat-treated state

 Resistance to fatigue and wear

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C OPPER A LLOYS

B RASS

 Composition: zinc and small amounts of aluminum, iron, lead, manganese, magnesium, nickel, phosphorous, and tin.

 Brass with a zinc content of 30 to 35 percent is very ductile.

 Brass containing 45 percent zinc has relatively high strength.

 Muntz metal:

 Muntz metal:

composed of 60 percent copper and 40 percent zinc.excellent corrosion resistant qualities in salt water.

strength can be increased by heat treatment (50,000 psi in cast).used in making bolts and nuts, parts that come in contact with salt

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C OPPER A LLOYS

 The true bronzes have up to 25 percent tin.

 In aircraft: less than 11 percent are most useful.

 about 95 percent copper, 3 percent silicon, and 2 percent manganese, zinc, iron, tin, and aluminum

 high strength

 great corrosion resistance

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C OPPER A LLOYS

ALUMINUM BRONZE

 Composition: contain up to 16 percent of aluminum

(usually 5 to 11 percent), and other metals, such as iron, nickel, or manganese.

 Properties:

 good tearing qualities

 good tearing qualities

 great strength and hardness

 resistance to both shock and fatigue

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N ICKEL A LLOYS

M ONEL

 Monel is the leading high nickel alloy.

 Composition: 68 percent nickel, 29 percent copper, 0.2 percent iron, 1 percent manganese, and 1.8 percent of other elements.

 Properties:

 Properties:

 cannot be hardened by heat treatment

 adaptable to casting and hot or cold working

 tensile strength of 80,000 psi

 Applications:

 gears and chains to operate retractable landing gears

 exhaust manifolds , carburetor needle valves and sleeves.

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N ICKEL A LLOYS

 Inconel and stainless steel are similar in appearance and are frequently found in the same areas of the engine.

 Composition: approximately 80 percent nickel, 14

percent chromium, and small amounts of iron and other elements.

 Properties:

 high strength

 high working temperature

 corrosion resistance under extremely high temperature conditions.

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HEAT TREATMENT OF NONFERROUS METALS

NONFERROUS METALS

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A LUMINUM A LLOYS HEAT TREATMENT IDENTIFICATION

 O — Soft or annealed condition

 H — Strain hardened condition

 W — Solution heat treated, unstable temper

 T — Treated to produce stable tempers other than O, or H

 T2 — Annealed (cast products only)

T3 — Solution heat treated and then cold worked

 T3 — Solution heat treated and then cold worked

 T4 — Solution heat treated

 T5 — Artificially aged only

 T6 — Solution heat treated and then artificially aged

 T7 — Solution heat treated and then stabilized

 T8 — Solution heat treated, cold worked, and then artificially aged

 T9 — Solution heat treated, artificially aged, and then cold worked

 T10 — Artificially aged and then cold worked 44

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A LUMINUM A LLOY H EAT T REATMENT

 2 types:

 solution heat treatment

 precipitation heat treatment

 Heat treatment process:

 Heating to a predetermined temperature.

 Heating to a predetermined temperature.

 Soaking at temperature for a specified length of time.

 Rapidly quenching to a relatively low temperature.

 Aging or precipitation hardening either spontaneously at

room temperature, or as a result of a low temperature thermal treatment.

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S OLUTION H EAT T REATMENT

 The temperatures used for solution heat treating vary with different alloys and range from 825 °F to 980 °F.

 The time at temperature: soaking time

 measured from the time the coldest metal reaches the minimum limit of the desired temperature range

 varies, depending upon the alloy and thickness, from 10 minutes for thin sheets to approximately 12 hours for heavy forgings

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Q UENCHING

 Quenching is used to prevent or retard immediate reprecipitation.

 Three distinct quenching methods:

 Cold Water Quenching

 Hot Water Quenching

 Hot Water Quenching

 Spray Quenching

 Cold Water Quenching

 quenched in a cold water bath

 temperature before quenching should not exceed 85 °F

 using a sufficient quantity of water keeps the temperature rise under 20 °F

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Q UENCHING

 Hot Water Quenching

 quenched in hot or boiling water

 minimizes distortion and alleviates cracking

 temperature of the quench water does not critically affect the resistance to corrosion of the forging alloys

 Spray Quenching

 quenched in high velocity water sprays

 minimizes distortion and alleviates quench cracking

 The aluminum alloys are in a comparatively soft state immediately after quenching from a solution heat-treating temperature

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P RECIPITATION H EAT T REATMENT

 Aging or precipitation hardening are applied to obtain the maximum strength of aluminum alloys.

 Precipitation hardening process:

 Precipitation of the soluble constituents from the super -saturated solid solution

Strength is due to the uniform distribution of a finely

 Strength is due to the uniform distribution of a finely

dispersed submicroscopic precipitate and its effects upon the crystal structure of the alloy

 Increase the strength and hardness of the material

 Decreases in the ductile properties

 Aging:

 Natural aging: 4 or 5 days at room temperature

 Artificially aging: temperatures ranging from 250 °F to 375 °F.

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