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Ngày đăng: 01/04/2014, 10:07
Xem thêm: adsorption theory, modeling, and analysis, adsorption theory, modeling, and analysis, A. The Main Goal of Thermodynamical Treatment, D. Derivation of the Gibbs Equation for Adsorption on Gas=Solid Interfaces, C. The Uniform and Consistent Interpretation of the Modified Langmuir Equation, General Considerations, D. The Uniform and Consistent Interpretation of the Modified Fowler–Guggenheim Equation, E. The Uniform and Consistent Interpretation of the Modified Volmer Equation, G. Physical Interpretation of Constants Kx Present in the Modified Isotherm Equations Applied to Homogeneous Surfaces, H. Properties of the Function c(P) Corresponding to the Modified Langmuir, FG, Volmer, and BH Isotherm Equations, B. The Modified Fowler–Guggenheim Equation Applied to Heterogeneous Surfaces (FT Equation), E. The Mathematically Generalized Form of mL, mFG, mV, mBH, To´th, FT, VT, and BT Equations, G. Inapplicability of the To´th Equation to Isotherms of Type I Measured on Heterogeneous Surfaces, A. The Brunauer–Emmett–Teller Equation and Its Thermodynamical Properties, D. The Cloud Model of Multilayer Adsorption, A. Calculation of the Specific Surface Area from Isotherms of Type II Without and With the Monolayer Domain, C. Calculation of the Specific Surface Area from Isotherms of Type I Without a Multilayer Plateau and Measured Below the Critical Temperature, A. Consequences of the Calculations Made with Data of Isotherms of Type II Measured in a Narrower Domain of Equilibrium Relative Pressure, B. Consequences of the Calculations Made with Data of Isotherms of Type I Measured in a Narrower Domain of Relative (or Absolute) Equilibrium Pressure, III. THE INTEGRAL EQUATION APPROACH, C. Adsorption of Gas Mixtures, E. Adsorption from Binary Solutions, C. Monte Carlo Simulation of Adsorption, II. MODELS BASED ON THEORY OF VOLUME FILLING, III. MODELS BASED ON STATISTICAL MECHANICS, B. Limitations of DFT and Suggestions for Improvement, IV. MODELS BASED ON THE HORVATH–KAWAZOE APPROACH, D. Corrections to HK Methods, V. SURVEY OF PSD TECHNIQUES USED IN LITERATURE, A. Experimental Datasets of the Adsorption Equilibria for the Supercritical Region, B. Determination of Gas-Phase State, D. Determination of Isosteric Heat of Adsorption, F. Determination of the Absolute Adsorption, D. Illustration of Modeling Supercritical Isotherms, B. What to Do Next for Supercritical Adsorption Study?, C. Superposition of Interactions and the Energy Profiles, II. THERMODYNAMICS OF INTERFACES: THE CONCEPT OF THE ‘‘BLACK BOX’’, B. Capillary Equilibrium in Porous Media, C. Problems and Numerical Algorithms, E. Phase Diagrams of Capillary Equilibrium, F. The Multicomponent Kelvin Equation, A. Overview of Possible Approaches, B. Fundamentals of the Potential Theory of Adsorption, D. Testing the Potential Theory, E. Potential Theory of Adsorption and Thermodynamics of Surface Excesses, F. The Asymptotic Adsorption Equation, II. OVERVIEW OF EXPERIMENTAL RESULTS, A. Phase Diagrams for Rare Gases on Graphite, B. Statistical Mechanics of Physisorption, E. Steele’s Theory of Monolayer Adsorption, A. The Two-Dimensional Lennard–Jones Model, B. Equations of State for 2D L-J Fluids, D. Comparison with Experimental Results, E. Overview of Computer Simulations, V. ADSORPTION ON HETEROGENEOUS SURFACES: FERMI–DIRAC STATISTICS, E. The Ab Fine Problem, B. Desorption Kinetics in Isothermal Conditions, D. Accounting for the Experimental Desorption Kinetics, II. STOCHASTIC PROCESS AND ITS APPLICATION, III. STOCHASTIC MODELING OF A BATCH ADSORBER IN THE CASE OF LINEAR ISOTHERM, IV. STOCHASTIC MODELING OF A BATCH ADSORBER IN THE CASE OF NONLINEAR ISOTHERM, A. Model Development and Parameter Estimation, A. Model Description and Parameter Estimation, C. Model Sensitivity and Verification, D. Comparison Between Deterministic and Stochastic Solutions, I. ADSORPTION OF BINARY LIQUID MIXTURES ON SOLID SURFACES, III. ENTHALPY OF IMMERSION ON SOLIDS IN BINARY LIQUID MIXTURES, A. U-Shaped Excess Isotherms and Enthalpy Isotherms, D. Adsorption of n-Butanol from Water on Modified Silicate Surfaces, B. The Lattice Model and Its Application to Multimolecular Adsorption, J. Adsorption in Real Mixtures Far from Demixing (a=kT ¼ 1:4), K. Adsorption in Real Mixtures, Close to Demixing (a=kT ¼ 1:95), II. EXPERIMENTAL PROCEDURES AND DATA AND THEIR USE IN MODELS, B. Experimental Data Used in Inverse Modeling, D. Use of Modeling Results, C. Nonscientific Influences on the Choice of Models, D. Use of Previously Published Model Parameters, A. Interaction of Solid with Water: Hydration, Hydrolysis, Dissolution, and Dissociation, C. Distribution of Ions at the Charged Surface, III. PROBLEMS, PROBABLE SOLUTIONS: CASES FROM RECENT LITERATURE, B. Cases from Recent Literature, III. MACROMOLECULE IN THE ADSORPTION LAYER, A. The Stage of Fast Adsorption, D. Adsorption of Homodisperse Polymers, F. Polymer Adsorption Accompanied by Flocculation, G. Adsorption Accompanied by Reaction, V. FORCES IN ADSORPTION LAYER, B. A Simple Mechanism for Protein Adsorption, A. Parameters a and AC, E. The Affinity and Extent of Adsorption, III. A KINETIC MODEL FOR PROTEIN ADSORPTION, IV. APPLICABILITY OF THE MODEL, B. Determination of the Adsorption Rate Constant, ka, C. The Extent of Surface-Induced Unfolding