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Hazardous ChemicalsSecond edition Phillip Carson docx

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  • Contents

  • Preface to the second edition

  • Preface to the first edition

  • 1 Introduction

  • 2 Terminology

  • 3 General principles of chemistry

    • 3.1 Introduction

    • 3.2 Atoms and molecules

    • 3.3 Periodic table

    • 3.4 Valency

    • 3.5 Chemical bonds

    • 3.6 Oxidation/reduction

    • 3.7 Physical state

    • 3.8 Acids

    • 3.9 Bases

    • 3.10 Halogens

    • 3.11 Metals

    • 3.12 Oxygen and suphur

    • 3.13 Nitrogen, phsphorus, arsenic and antimony

    • 3.14 pH

    • 3.15 Salts

    • 3.16 Organic chemistry

    • 3.17 Combustion chemistry

    • 3.18 Chemical reactivity

  • 4 Physicochemistry

    • 4.1 Vapour pressure

    • 4.2 Gas-liquid solubility

    • 4.3 Liquid-to-vapour phase change

    • 4.4 Solid-to-liquid phase change

    • 4.5 Density differences of gases and vapours

    • 4.6 Density differences of liquids

    • 4.7 Immiscible liquid-liquid systems

    • 4.8 Vapour flashing

    • 4.9 Effects of particle or droplet size

    • 4.10 Surface area effects in mass transfer or heterogeneous reactions

    • 4.11 Enthalpy changes on mixing of liquids

    • 4.12 Critical temperature of gases

    • 4.13 Chemical reaction kinetics

    • 4.14 Corrosion

    • 4.15 Force and pressure

    • 4.16 Expansion of contraction of solids

  • 5 Toxic chemicals

    • 5.1 Introduction

    • 5.2 Hazard recognition

    • 5.3 Types of toxic chemicals

    • 5.4 Hazard assessment

    • 5.5 Risk assessment of carcinogens

    • 5.6 Risk control

    • 5.7 Control of substances hazardous to health

    • 5.8 Specific precautions

  • 6 Flammable chemicals

    • 6.1 Ignition and propagation of a flame front

    • 6.2 Control mechanisms

    • 6.3 Fire extinguishment

    • 6.4 Fire precautions

  • 7 Reactive chemicals

    • 7.1 Water-sensitive chemicals

    • 7.2 Toxic hazards from mixtures

    • 7.3 Reactive hazards from mixtures

    • 7.4 Oxidizing agents

    • 7.5 Explosive chemicals

    • 7.6 General principles for storage

    • 7.7 Hazards arising in chemical processing

  • 8 Cryogens

    • 8.1 Liquid oxygen

    • 8.2 Liquid nitrogen and argon

    • 8.3 Liquid carbon dioxide

    • 8.4 Liquefied natural gas

  • 9 Compressed gases

    • 9.1 Acetylene

    • 9.2 Air

    • 9.3 Ammonia

    • 9.4 Carbon dioxide

    • 9.5 Carbon monoxide

    • 9.6 Chlorine

    • 9.7 Hydrogen

    • 9.8 Hydrogen chloride

    • 9.9 Hydrogen sulphide

    • 9.10 Liquefied petroleum gases (LPG)

    • 9.11 Methane

    • 9.12 Nitrogen

    • 9.13 Nitrogen oxides

    • 9.14 Oxygen

    • 9.15 Ozone

    • 9.16 Sulphur dioxide

  • 10 Monitoring techniques

    • 10.1 Selected general analystical techniques for monitoring environmental pollution

    • 10.2 Gases and vapours

    • 10.3 Particulates

    • 10.4 Monitoring water quality

    • 10.5 Monitoring land pollution

    • 10.6 Monitoring air pollution

    • 10.7 Flammable gases

    • 10.8 Toxic particulates

    • 10.9 Official methods

    • 10.10 Sampling strategies

    • 10.11 Selected strategies for determining employees' exposure to airbourne chemicals

    • 10.12 Pollution monitoring strategies in incident investigation

  • 11 Radioactive chemicals

    • 11.1 Hazards

    • 11.2 Types of radiation

    • 11.3 Control measures

  • 12 Safety by design

    • 12.1 Design procedures

    • 12.2 Layout

    • 12.3 Storage

    • 12.4 Equipment design

    • 12.5 Piping arrangements

    • 12.6 Fire protection

    • 12.7 Installation and operation

  • 13 Operating procedures

    • 13.1 Commissioning

    • 13.2 Operation

    • 13.3 Maintenance

    • 13.4 Pressure systems

    • 13.5 Emergency procedures

    • 13.6 Spillage

    • 13.7 First aid

    • 13.8 Personal protection

    • 13.9 Medical screening

    • 13.10 Monitoring standards

    • 13.11 Training

  • 14 Marketing

    • 14.4 Information

    • 14.3 Labelling

    • 14.2 Packaging

    • 14.1 Classification

  • 15 Transport of chemicals

    • 15.7 Container filling/discharging

    • 15.6 Loading and unloading

    • 15.5 Modes of transport for liquids, gases and solids

    • 15.4 Sea transport

    • 15.3 Air transport

    • 15.2 Rail transport

    • 15.1 Road transport

  • 16 Chemicals and the environment: sources and impact

    • 16.1 Atmospheric emissions

    • 16.2 Liquid effluents

    • 16.3 Solid wastes

  • 17 Chemicals and the environment: monitoring and protection

    • 17.7 Monitoring and auditing

    • 17.6 Control of solid waste

    • 17.5 Liquid effluent treatment operations

    • 17.4 Control of atmospheric emissions

    • 17.3 Environmental impact assessment

    • 17.2 Waste management

    • 17.1 Legislative control

  • 18 Conversion tables and measurement data

  • 19 Bibliography

    • 19.1 Selected textbooks

    • 19.2 UK legislation on dangerous substances

    • 19.3 European legislation on dangerous substances

    • 19.4 UK legislation on air pollution

    • 19.5 European legislation on air pollution

    • 19.6 UK water legislation

    • 19.7 European legislation on water pollution

    • 19.8 UK legislation on land pollution

    • 19.9 Health and Safety Executive publications

    • 19.10 HSE guidance notes

    • 19.11 Miscellaneous

    • 19.12 Publications by the Environment Agency relating to chemicals

    • 19.13 Selected British standards

  • Appendix: Selected UK legislation

  • Index

Nội dung

Hazardous Chemicals Handbook [...]... with risk phrases (i) R14: Reacts violently with water (including R15) (ii) R29: In contact with water, liberates toxic gas 7 8 INTRODUCTION Table 1.7 Planning (Hazardous Substances) Regulations 1992 Hazardous substances and controlled quantities Hazardous substance Controlled quantity Part A Toxic substances 1 Acetone cyanohydrin (2-cyanopropan-2-ol) 2 Acrolein (2-propenal) 3 Acrylonitrile 4 Allyl alcohol... chemicals, may also be related to these operations Working with pathogenic micro-organisms bears passing similarity to chemicals Hence, in the UK micro-organisms are classified as hazardous substances under the Control of Substances Hazardous to Health Regulations and there is an accompanying Code of Practice However, biological hazards arising from the working environment or from more specialized activities,... exceeds that listed in column 3 The special considerations with such installations are detailed in specialist texts noted in the Bibliography In the UK the Planning (Hazardous Substances) Regulations 1992 also require the holder to obtain a hazardous substances consent’ for any site on which it is intended to hold a bulk quantity of any of 71 substances above a ‘controlled quantity’ (Table 1.7) Table... prediction, the reader is referred to standard textbooks (see Bibliography) such as: The Safe Handling of Chemicals in Industry (Carson and Mumford) Dangerous Properties of Industrial Materials (Sax and Lewis) Handbook of Reactive Chemical Hazards (Bretherick) Handbook of Toxic and Hazardous Materials (Sittig) Patty’s Industrial Hygiene and Toxicology (Clayton and Clayton) The identification, assessment,... any quantity or description A substance that chemically attacks a material with which it has contact (body cells, materials of construction) CORROSIVE COSHH (CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH) The Control of Substances Hazardous to Health Regulations 1999 establish the responsibilities of employers with regard to all substances which pose a health hazard in the workplace CRYOGEN A substance used... the mass of material to inflame STEAM EXPLOSION Overpressure associated with the rapid expansion in volume on instantaneous conversion of water to steam SUBSTANCE HAZARDOUS TO HEALTH As defined in Regulation 2 of the Control of Substances Hazardous to Health Regulations 1999, (a) a substance which is listed in Part 1 of the approved supply list as dangerous for supply within the meaning of the Chemicals... spilled liquid chemicals and vapours from them, leaking gases, and the pyrolytic and combustion products generated from chemical mixtures together with oxygen deficient atmospheres However, whether a hazardous condition develops in any particular situation also depends upon the physical properties of the chemical (or mixture of chemicals), the scale involved, the circumstances of handling or use, e.g... are discussed in Chapter 7 The special problems with cryogenic materials and chemicals under pressure, typified by compressed 4 INTRODUCTION Table 1.3 Comprehensive information possibly required for a hazardous chemical Name of chemical; other names Uses General description of hazards General description of precautions Fire-fighting methods Regulations Sources of advice on precautions Characteristics:... are, of course, required under a wide range of statutory legislation, dependent upon the country concerned For example, in the UK the Health and Safety at Work etc Act 1974, the Control of Substances Hazardous to Health Regulations 1988, the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972, the Control of Pollution Act 1974 and the Environmental Protection Act 1990 are supplemented... xii PREFACE to chemical safety data sheets, detailed texts, library facilities or computerized databanks It also provides a useful summary for those who may need to make only passing reference to the hazardous properties and potential effects of chemicals, such as general engineering students and occupational health nurses P.A.C C.J.M 1 Introduction Industrial hazards cover a wide spectrum including . Hazardous Chemicals Handbook

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