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Contents
Preface to the second edition
Preface to the first edition
1 Introduction
2 Terminology
3 General principles of chemistry
3.1 Introduction
3.2 Atoms and molecules
3.3 Periodic table
3.4 Valency
3.5 Chemical bonds
3.6 Oxidation/reduction
3.7 Physical state
3.8 Acids
3.9 Bases
3.10 Halogens
3.11 Metals
3.12 Oxygen and suphur
3.13 Nitrogen, phsphorus, arsenic and antimony
3.14 pH
3.15 Salts
3.16 Organic chemistry
3.17 Combustion chemistry
3.18 Chemical reactivity
4 Physicochemistry
4.1 Vapour pressure
4.2 Gas-liquid solubility
4.3 Liquid-to-vapour phase change
4.4 Solid-to-liquid phase change
4.5 Density differences of gases and vapours
4.6 Density differences of liquids
4.7 Immiscible liquid-liquid systems
4.8 Vapour flashing
4.9 Effects of particle or droplet size
4.10 Surface area effects in mass transfer or heterogeneous reactions
4.11 Enthalpy changes on mixing of liquids
4.12 Critical temperature of gases
4.13 Chemical reaction kinetics
4.14 Corrosion
4.15 Force and pressure
4.16 Expansion of contraction of solids
5 Toxic chemicals
5.1 Introduction
5.2 Hazard recognition
5.3 Types of toxic chemicals
5.4 Hazard assessment
5.5 Risk assessment of carcinogens
5.6 Risk control
5.7 Control of substances hazardous to health
5.8 Specific precautions
6 Flammable chemicals
6.1 Ignition and propagation of a flame front
6.2 Control mechanisms
6.3 Fire extinguishment
6.4 Fire precautions
7 Reactive chemicals
7.1 Water-sensitive chemicals
7.2 Toxic hazards from mixtures
7.3 Reactive hazards from mixtures
7.4 Oxidizing agents
7.5 Explosive chemicals
7.6 General principles for storage
7.7 Hazards arising in chemical processing
8 Cryogens
8.1 Liquid oxygen
8.2 Liquid nitrogen and argon
8.3 Liquid carbon dioxide
8.4 Liquefied natural gas
9 Compressed gases
9.1 Acetylene
9.2 Air
9.3 Ammonia
9.4 Carbon dioxide
9.5 Carbon monoxide
9.6 Chlorine
9.7 Hydrogen
9.8 Hydrogen chloride
9.9 Hydrogen sulphide
9.10 Liquefied petroleum gases (LPG)
9.11 Methane
9.12 Nitrogen
9.13 Nitrogen oxides
9.14 Oxygen
9.15 Ozone
9.16 Sulphur dioxide
10 Monitoring techniques
10.1 Selected general analystical techniques for monitoring environmental pollution
10.2 Gases and vapours
10.3 Particulates
10.4 Monitoring water quality
10.5 Monitoring land pollution
10.6 Monitoring air pollution
10.7 Flammable gases
10.8 Toxic particulates
10.9 Official methods
10.10 Sampling strategies
10.11 Selected strategies for determining employees' exposure to airbourne chemicals
10.12 Pollution monitoring strategies in incident investigation
11 Radioactive chemicals
11.1 Hazards
11.2 Types of radiation
11.3 Control measures
12 Safety by design
12.1 Design procedures
12.2 Layout
12.3 Storage
12.4 Equipment design
12.5 Piping arrangements
12.6 Fire protection
12.7 Installation and operation
13 Operating procedures
13.1 Commissioning
13.2 Operation
13.3 Maintenance
13.4 Pressure systems
13.5 Emergency procedures
13.6 Spillage
13.7 First aid
13.8 Personal protection
13.9 Medical screening
13.10 Monitoring standards
13.11 Training
14 Marketing
14.4 Information
14.3 Labelling
14.2 Packaging
14.1 Classification
15 Transport of chemicals
15.7 Container filling/discharging
15.6 Loading and unloading
15.5 Modes of transport for liquids, gases and solids
15.4 Sea transport
15.3 Air transport
15.2 Rail transport
15.1 Road transport
16 Chemicals and the environment: sources and impact
16.1 Atmospheric emissions
16.2 Liquid effluents
16.3 Solid wastes
17 Chemicals and the environment: monitoring and protection
17.7 Monitoring and auditing
17.6 Control of solid waste
17.5 Liquid effluent treatment operations
17.4 Control of atmospheric emissions
17.3 Environmental impact assessment
17.2 Waste management
17.1 Legislative control
18 Conversion tables and measurement data
19 Bibliography
19.1 Selected textbooks
19.2 UK legislation on dangerous substances
19.3 European legislation on dangerous substances
19.4 UK legislation on air pollution
19.5 European legislation on air pollution
19.6 UK water legislation
19.7 European legislation on water pollution
19.8 UK legislation on land pollution
19.9 Health and Safety Executive publications
19.10 HSE guidance notes
19.11 Miscellaneous
19.12 Publications by the Environment Agency relating to chemicals
19.13 Selected British standards
Appendix: Selected UK legislation
Index
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Hazardous Chemicals Handbook
[...]... with risk phrases (i) R14: Reacts violently with water (including R15) (ii) R29: In contact with water, liberates toxic gas 7 8 INTRODUCTION Table 1.7 Planning (Hazardous Substances) Regulations 1992 Hazardous substances and controlled quantities Hazardous substance Controlled quantity Part A Toxic substances 1 Acetone cyanohydrin (2-cyanopropan-2-ol) 2 Acrolein (2-propenal) 3 Acrylonitrile 4 Allyl alcohol... chemicals, may also be related to these operations Working with pathogenic micro-organisms bears passing similarity to chemicals Hence, in the UK micro-organisms are classified as hazardous substances under the Control of Substances Hazardous to Health Regulations and there is an accompanying Code of Practice However, biological hazards arising from the working environment or from more specialized activities,... exceeds that listed in column 3 The special considerations with such installations are detailed in specialist texts noted in the Bibliography In the UK the Planning (Hazardous Substances) Regulations 1992 also require the holder to obtain a hazardous substances consent’ for any site on which it is intended to hold a bulk quantity of any of 71 substances above a ‘controlled quantity’ (Table 1.7) Table... prediction, the reader is referred to standard textbooks (see Bibliography) such as: The Safe Handling of Chemicals in Industry (Carson and Mumford) Dangerous Properties of Industrial Materials (Sax and Lewis) Handbook of Reactive Chemical Hazards (Bretherick) Handbook of Toxic and Hazardous Materials (Sittig) Patty’s Industrial Hygiene and Toxicology (Clayton and Clayton) The identification, assessment,... any quantity or description A substance that chemically attacks a material with which it has contact (body cells, materials of construction) CORROSIVE COSHH (CONTROL OF SUBSTANCES HAZARDOUS TO HEALTH) The Control of Substances Hazardous to Health Regulations 1999 establish the responsibilities of employers with regard to all substances which pose a health hazard in the workplace CRYOGEN A substance used... the mass of material to inflame STEAM EXPLOSION Overpressure associated with the rapid expansion in volume on instantaneous conversion of water to steam SUBSTANCE HAZARDOUS TO HEALTH As defined in Regulation 2 of the Control of Substances Hazardous to Health Regulations 1999, (a) a substance which is listed in Part 1 of the approved supply list as dangerous for supply within the meaning of the Chemicals... spilled liquid chemicals and vapours from them, leaking gases, and the pyrolytic and combustion products generated from chemical mixtures together with oxygen deficient atmospheres However, whether a hazardous condition develops in any particular situation also depends upon the physical properties of the chemical (or mixture of chemicals), the scale involved, the circumstances of handling or use, e.g... are discussed in Chapter 7 The special problems with cryogenic materials and chemicals under pressure, typified by compressed 4 INTRODUCTION Table 1.3 Comprehensive information possibly required for a hazardous chemical Name of chemical; other names Uses General description of hazards General description of precautions Fire-fighting methods Regulations Sources of advice on precautions Characteristics:... are, of course, required under a wide range of statutory legislation, dependent upon the country concerned For example, in the UK the Health and Safety at Work etc Act 1974, the Control of Substances Hazardous to Health Regulations 1988, the Highly Flammable Liquids and Liquefied Petroleum Gases Regulations 1972, the Control of Pollution Act 1974 and the Environmental Protection Act 1990 are supplemented... xii PREFACE to chemical safety data sheets, detailed texts, library facilities or computerized databanks It also provides a useful summary for those who may need to make only passing reference to the hazardous properties and potential effects of chemicals, such as general engineering students and occupational health nurses P.A.C C.J.M 1 Introduction Industrial hazards cover a wide spectrum including . Hazardous Chemicals Handbook