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SUNY COLLEGE AT ONEONTA BIOLOGICAL FIELD STATION SAFETY AND HEALTH MANUAL Willard N Harman Biological Field Station Cooperstown, New York Occasional Paper No 25 May, 1994 Biology Department State University College at Oneonta CONTENTS Introduction Responsibilities Supervisors Employees Accident Investigation and Reporting Enforcement Definitions Recommended First Aid Kit Contents 4 Boating Safety Prerequisites to Any Boating Activities General Procedures Equipment Design and Construction Vehicle Operation Prerequisites for Vehicle Operation General Procedures Car and Truck Safety Trailer Safety 4 5 7 9 10 12 Electrofishing Safety Prerequisites to Electrofishing Activities General Equipment Design and Construction Recommended Safety Tips 13 13 13 Chemical Handling Safety Prerequisites for Chemical Handling General Procedures Required Safety Equipment 16 16 16 16 Non-BFS Employee Participation 20 Table - Chemicals Routinely Used in Fisheries Operations 21 14 15 SUNY ONEONTA BIOLOGICAL FIELD STATION POLICY AND PROCEDURES REGARDING EMPLOYEE SAFETY AND HEALTH I Background As an essential part of the Biological Field Station's (BFS) Safety Program, we have developed a Safety and Health Policy and related Field Manual for all BFS activities II III Objectives A To authorize and provide generic means and methods for the safe operation of equipment, handling of chemicals, and to provide a safe and healthful environment in which to conduct daily activities B To provide and maintain safe and healthful working conditions, provide and maintain equipment and supplies necessary to carry out assigned program objectives in a safe manner, and to initiate and maintain operating practices that will safeguard all employees Applicability We believe the safety and health of students and staff and the environment in which they work are of primary importance The Administration recognizes that the efficiency of any operation can be measured by its ability to prevent accidents and reduce loss of time The safety program is designed not only to provide and maintain safe and healthful working conditions but to improve morale and well-being and the efficiency of BFS operations IV V Authority A Article 2, Section 27-a, New York State Labor Law (State OSHA) B Article 48, Public Health Law; Article 28 New York State Labor Law (Toxic-Substance Act - Right to Know Law) Policy A Ensure that all faculty staff and students understand and follow the written policy and field manual instructions regarding safety and health B Stimulate, promote, and enforce safety consciousness and safe work habits VI C Provide guidelines for planning, development, and construction projects where safety and health need special consideration D Safety training programs will be established with assistance and guidance from the SUNY Oneonta Safety Coordinator Procedures A The attached Field Safety and Health Manual is to be followed and used by all Biological Field Station personnel B Use those procedures which best apply to your situation Remember that safety policies, rules, and regulations cannot replace common sense, good judgment, and safety awareness in avoiding accidents Willard N Harman 1/6/94 Willard N Harma P f & Director SUNY Oneonta Bi gical Field Station INTRODUCTION This manual has been prepared with your (the employee's) safety and 11ealth as our primary concern Your awareness is important in assuring a safe working environment, alerting you of safety hazards and how to cope with them, and providing the necessary equipment and training for you to carry out your work safely and efficiently You are encouraged to make suggestions for improvement as the manual will be updated if required RESPONSIBILITIES SUPERVISORS Each faculty, staff, or student supervisor is directly responsible for the health and safety of all persons under their immediate supervision including permanent, temporary, and seasonal employees, as well as official volunteers To this end, supervisors shall: (1) provide all employees with formal safety instructions including a complete review of the BFS Safety Policy at least once annually; (2) provide employees with complete safety instructions prior to assignment of duties; (3) assure that all required safety equipment is available for use by employees and properly maintained; (4) provide required first aid and safety training as described herein to all permanent, temporary, and seasonal employees; (5) inspect work areas and equipment for unsafe practices and conditions; (6) take prompt corrective action to eliminate any hazards; (7) report all accidents and conduct any necessary investigations; (8) and enforce all safety rules and regulations Supervisors should remember that their attitude and the example they set for subordinates may be the two most important factors in promoting job safety EMPLOYEES Each employee shall: (1) observe all written and oral safety instructions; (2) wear or use required safety equipment; (3) report unsafe conditions; and (4) report all accidents and injuries that occur to their immediate supervisor It is the responsibility of the employee to report an unsafe condition to his supervisor or the Director He may refuse to work under known unsafe conditions or to work without required safety equipment without fear of reprisal If the employee is not satisfied with the disposition of the complaint, he should contact the Director following which he may also contact The SUNY Oneonta Safety Coordinator, or his union representative, or the Department of Labor ACCIDENT INVESTIGATION AND REPORTING Responsibility for investigation of accidents lies with the supervisor If he needs assistance due to the nature of the accident, he should contact the Director Any accidents resulting in personal injury must be documented and reported to the supervisor Any accident involving motor vehicles must be reported on NYS Department of Motor Vehicles No MV-104 within 48 hours Accidents and injuries should be reported to help avoid further accidents, to assure that available benefits are obtained by qualified employees, and to determine government liability ENFORCEMENT Enforcement of the BFS Safety Policy is the responsibility of all personnel with full support of the Director The Supervisor has the responsibility of enforcing all requirements of the Safety Policy in accordance with administrative procedures DEFINITIONS Personal Flotation Devices (PFD's) Wherever reference to this is made, item will be U.S Coast Guard approved Fuel Containers - Gas Cans - Gas Tanks Reference to any of the above will mean fuel containers that are F.M labeled Fire Extinguishers Except for special situations noted, extinguishers will be for A.S.C class fires First Aid Kits See Page for recommended contents RECOMMENDED FIRST AID KIT CONTENTS Small 10 unit (#/Units) Medium 17 unit (#/Units) - 4" compress bandage - 2" compress bandage - Band Aid - 40 11 triangular bandage - Merthiolate swabs - Antiseptic swabs - Eye Dressing - Foille Burn Ointment 1/8 oz - Stingkill swabs - Poison Ivy Large 23 unit (#/Units) 2 2 1 1 1 - wire splint - 2" stretch bandage - 3x3" compress 3 2 1 1 1 1 - 4" roll bandage Recommend blanket in plastic bag for boats Recommend a package of needles and aspirin in all kits Suggestion: A gallon plastic bottle half filled with water and attached rope for lifeline BOATING SAFETY A PREREQUISITES TO ANY BOATING ACTIVITIES SUPERVISORS WILL ENCOURAGE ALL EMPLOYEES TO BECOME COMPETENT SWIMMERS For the purpose of this policy, a "competent swimmer" is defined as someone who can swim at least 50 yards and float (in motion) for a period of minutes, is a certified SCUBA diver or has passed an American Red Cross swimming or life saving course at or above the Intermediate Swimmer, Basic Rescue or Basic Survival levels B GENERAL PROCEDURES PERSONAL FLOTATION DEVICES (PFD's) must be worn at all times while vessels less than 24 ft are underway, during §ll boat electrofishing operations, during night work or at periods of low visibility (500' or less), during helicopter-boat surveys, on all boats, at all times when water temperatures are less than 60 o F, on all boats while operating any gear, and during any other conditions deemed hazardous to vessel and/or crew A CREW LEADER WILL BE DESIGNATED FOR ALL OPERATIONS INVOLVING BOATS He is responsible for the safety of the crew and enforcement of safety guidelines IT IS THE RESPONSIBILITY OF THE CREW LEADER TO DETERMIt\IE IF A SITUATION CAN BE DEALT WITH CONFIDENTLY AND SAFELY This judgment will take into consideration weather forecast, lake conditions, type of boat, the load, the type of operation, and the ability and opinion of the crew ALL BFS BOATS WILL BE OPERATED ACCORDING TO RULES AND REGULATIONS OF THE U.S COAST GUARD AND THE NYS NAVIGATION LAW C EQUIPMENT DESIGN AND CONSTRUCTION BOAT LOADS WILL NOT EXCEED MAXIMUM BIA LOAD LIMITS indicated on the manufacturer's identification plate If any boat does not have the manufacturer's recommended load limit, a reasonable approximation may be determined by: Maximum Load = 7.5 x L x B x De Where L = length of the boat B = beam (width) of the boat De = depth of the boat measured from the bottom to the lowest point that water can gain entry into the hull (all measurements are in feet) SUPERVISORS SHALL ENSURE THAT ALL BOATS AND MOTORS ARE ANNUALLY INSPECTED BY A COMPETENT MECHANIC ALL BOATS PURCHASED AFTER SEPT 1, 1982 SHALL HAVE UPRIGHT FLOTATION (flotation capable of supporting the boat in an upright position when swamped), except for large vessels where survival suits are required ALL BOATS USED IN WATER WITH A TEMPERATURE LESS THAN 60 F OR AT A DISTANCE OF MORE THAN 0.25 MILES FROM THE NEAREST SHORE SHALL HAVE UPRIGHT FLOTATION or all crew members must have either PFD or survival suits NO BOAT SHOULD BE POWERED BY AN ENGINE THAT EXCEEDS THE MANUFACTURER'S (BIA) RECOMMENDED HORSEPOWER LIMIT A SECONDARY POWER SUPPLY (Le paddles, oars, small outboard) SHALL BE ON BOARD FOR EACH BOAT FIRST AID KITS WILL BE AVAILABLE FOR ALL TRAILERED BOATS, and must be carried as part of the survey gear and maintained annually BOAT TRAILER LOADS SHALL NOT EXCEED RATED LIMITS, AND TRAILERS WILL BE CHECKED BEFORE EACH USE to make sure lights are working, safety chains are attached, tires are properly inflated, the trailer hitch is secure and the boat is secure ANY AUXILIARY FUEL TANKS OR EXTRA FUEL CONTAINERS MUST BE FM LABELED MAINTENANCE SCHEDULES FOR STATE-OWNED VEHICLES shall comply with those recommended by the vehicle manufacturer, or Division of Operations ANY DRIVER WHO IN THE OPINION OF THE SUPERVISOR IS HABITUALLY CARELESS, repeatedly uses poor judgment, or repeatedly violates driving regulations may be grounded by his supervisor and may face disciplinary action WHEN AN OPERATOR IS INVOLVED IN AN ACCIDENT where there is an indication of negligence, the operator will be grounded by his supervisor pending final case disposition 10 ANY DRIVER OF A VEHICLE INVOLVED IN AN ACCIDENT may be recommended to attend a DMV drivers' clinic and/or for disciplinary action warranted by the circumstances C CAR AND TRUCK SAFETY ALL BFS PERSONNEL WILL ALWAYS USE SEAT BELTS WHILE OPERATING BFS VEHICLES DAILY, BEFORE DRIVING ANY ASSIGNED VEHICLE, THE DRIVER SHOULD CHECK FOR mirror alignments, adequate brakes, steering, windshield wipers, windshield washer, tires, lights, horn, and tight exhaust system Keep vehicle windows clear of dirt, grease, steam, or snow AVOID LONG DRIVING PERIODS, ESPECIALLY AT NIGHT No one will be authorized to drive, unless he has had at least hours of sleep in the previous 24 hours New York State Transportation Law states that an employee can only drive ten hours per day Avoid driving continuously more than hours Take a short break or change drivers NO MORE THAN TWO PERSONS SHALL OCCUpy THE FRONT SEAT UI\ILESS THERE ARE SEAT BELTS FOR EACH OCCUPANT AND THERE IS SUFFICIENT ROOM TO SAFELY OPERATE CONTROLS PASSENGERS WILL NOT RIDE on the hood, fender, running boards, or bumpers of any vehicle DO NOT OVERFILL GASOLINE TANKS Allow for temperature expansion and tilting Vehicles shall not be operated without properly fitted metal gas caps Never use a rag as a temporary replacement for a gas/filler cap VEHICLES COMMONLY PARKED NOT TOTALLY OUT OF TRAFFIC must be equipped with a permanent or portable yellow flashing (revolving) warning light that must be used by the vehicle operator in combination with vehicle hazard warning flashes when necessary 10 GUIDELINES AND SAFETY TIPS FOR CAR AND TRUCK SAFETY a All car and truck drivers shall adopt a policy of defensive driving, which means driving to avoid accident situations created by other drivers or by weather and road conditions b Drivers on official business shall at all times drive with consideration for other drivers and obey all traffic laws c Operators will be especially courteous to pedestrians Honor their right-of-way privileges Watch particularly for erratic pedestrian behavior especially by children and the elderly d Operators will drive at a speed that permits full control of the truck, allowing for all factors, such as posted speed limits, stop signs, weather, visibility, traffic and road conditions, and safe stopping distance Do not exceed posted highway speed limits No job urgency transcends traffic safety e On narrow roads either surfaced or unsurfaced and on blind curves, operators will keep well to the right and be able to stop the vehicle within less than half of the visible distance f Before starting downgrade, shift into a lower gear if steepness or sharp curves indicate prolonged brake pressure will be needed to maintain control g Park vehicles off the traveled portion of the highway When necessary to park near or partly on the traveled portion of the highway, place warning devices in accordance with State or local regulations, or use hazard warning flashers and/or yellow rotating/flashing emergency light h When using expressways, study maps in advance and know where you expect to leave and how to identify the exit in advance Also, have ample fuel or plan intermediate stops i Where there is danger of the vehicle rolling, such as when jacked up or parked: 1) Block wheels 2) Place vehicle in lowest gear in direction of roll Automatic transmission must be left in "park" position 3) Set handbrake 4) Turn wheels into bank or curb if present (downgrade toe into curb, upgrade toe away from curb) j When operating trucks equipped with vacuum-hydraulic brakes, if the engine stalls, be prepared for brake failure k Park, if possible, off roadway and visible for a reasonable distance in both directions 11 D TRAILER SAFETY TRAILERS AND TOWING VEHICLES SHALL BE EQUIPPED WITH BRAKES, LIGHTS, COUPLING, SAFETY CHAIN and other devices prescribed by New York State law GROSS TRAILER WEIGHT SHALL NOT EXCEED 75% OF GROSS VEHICLE WEIGHT PERSONNEL SHALL NOT RIDE IN TRAILERS DURING TRANSPORT VEHICLES TOWING TRAILERS SHALL BE EQUIPPED WITH DUAL, SIDE MOUNTED REARVIEW MIRRORS TRAILERS WITH A LOADED TONGUE WEIGHT EXCEEDING 100 LBS MUST be equipped with a wheel jack to aid in trailer hook-up BOAT AND CARGO TRAILERS SHALL HAVE LOADS SECURED AND BALANCED OVER THEIR AXLE(S) to avoid undue vehicle leverage at the coupling BOAT KEELS SHOULD BE SUPPORTED EVENLY ON ROLLERS OR SKIDS FROM TRANSOM FORWARD TRAILERED BOATS WITH OUTBOARD DRIVES SHOULD BE CHECKED FOR ADEQUATE GROUND CLEARANCE of the prop and/or skeg Maximum clearance is obtained with the lower unit in a securely raised position, where it should remain for all launchings BOAT LAUNCHING TRAILERS REQUIRE EXTRA MAINTENANCE CHECKS OF WHEELS, WHEEL BEARINGS, AND BRAKE LIGHTS DUE TO EXPOSURE OR IMMERSION 10 BOATS SHOULD BE LAUNCHED FROM TRAILERS ONLY AFTER SECURING THE TOWING VEHICLE FROM ROLLING 12 ELECTROFISHING SAFETY A PREREQUISITES TO ELECTROFISHING ACTIVITIES ALL ELECTROFISHING BOATS AND STREAM ELECTROFISHING UNITS SHALL BE INSPECTED ANNUALLY before the beginning of the field season to assure that all equipment meets the safety standards set herein B GENERAL A CREW LEADER WILL BE DESIGNATED FOR ALL ELECTROFISHING ACTIVITIES The Crew Leader is responsible for the safety of the crew and enforcement of safety regulations EACH CREW MEMBER SHALL WEAR PROTECTIVE HAND AND FOOT GEAR Crew members will wear lineman's gloves (Desc) Rubber soled boots at least 6" high must be worn during boat electrofishing Rubber hip boots with non-slip soles are a minimum requirement for stream electrofishing; however, waders are recommended because of their added safety margin (canvas or nylon covered rubber hipboots and waders meet requirements) GASOLINE ENGINE OPERATED GENERATORS SHALL NOT BE REFUELED WHILE IN OPERATION An adequate amount of time shall be taken after refueling to allow gasoline vapors to dissipate, and any spilled fuel will be cleaned up before starting the generator ALL ELECTROFISHING EQUIPMENT SHALL BE TURNED OFF BEFORE MAKING ANY CONNECTIONS, DISCONNECTIONS, OR PART REPLACEMENTS A FIELD ELECTROFISHING CHECK LIST SHALL BE USED BEFORE EACH OPERATION to assure that all required equipment is available and all safety procedures are followed NO FIELD MODIFICATIONS TO ELECTROFISHING UNITS WILL BE PERMITfED STREAM ELECTROFISHING: a ALL ELECTROFISHING BRAIL SUPPORT HANDLES AND ALL WAND-TYPE ELECTRODE HANDLES SHALL HAVE INDIVIDUAL WATER TIGHT PRESSURE SENSITIVE SWITCHES powered by no more than 24 volts (ac or dc) Whenever possible, a second level of electrical interruption should be maintained between source (georator) and electrodes b A STREAM ELECTRO FISHING CREW SHALL CONSIST OF NO LESS THAN TWO CREW MEMBERS Hip boots or waders (with nonskid felt-type soles) must be worn by all crew members c PFD'S SHALL BE WORN WHEN WORKING IN SITUATIONS WHERE CURRENT, DEPTH, AND STREAMBOnOMS MAY CREATE HAZARDOUS CONDITIONS 13 d e f g h BACK PACK UNITS SHALL BE SHUT OFF PRIOR TO ENTERING OR LEAVING A STREAM, and the battery termina.ls disconnected when not in use A CREW MEMBER WHO GETS EXCESS WATER IN BOOTS OR WADERS SHALL IMMEDIATELY LEAVE THE OPERATION and remove water from his gear before returning and, if temperature dictates, obtain dry clothing and boots CREW MEMBERS SHALL ALWAYS MAKE SURE THAT ALL PERSONNEL ARE CLEAR OF THE ANODE BEFORE TURNING ON THE POWER CREW MEMBERS SHALL NOT REACH INTO THE WATER WITH A HAND in vicinity of an electrode even if rubber gloves are being worn A CREW MEMBER CARRYING A HEAVY BACK PACK UNIT with an overall weight exceeding approximately 20 pounds will not be allowed to simultaneously operate a shocking wand (in hazardous conditions) C EQUIPMENT DESIGN AND CONSTRUCTION ELECTROFISHING CONTROL UNITS SHALL HAVE BUILT-IN LOW VOLTAGE SAFETY FACTORS Units of this type include the Coffelt model WP-2C, the Bureau of Electronics "blue box" or "black box" and the "orange ll or "green" backpack shockers THE ALTERNATOR OUTPUT MUST BE ELECTRONICALLY ISOLATED Do not tie the neutral wire to the chassis ground on the generator THE VOLTAGE AND AMPERAGE RATING OF WIRING MUST BE ADEQUATE The rated voltage of insulation on conductors used to deliver output current from the pulsator to the electrodes must exceed the maximum potential voltage of the pulsator or generator by the next higher rating as follows: Pulsator/Generator 0-249 volts 250-599 volts 600-899 volts Minimum Insulation Rating of Conductor 250 volts 600 volts 900 volts Conductor size shall be approved for rated amperage of equipment as follows: Amperage 0-15 16-20 21-30 Conductor Size 14AWG 12AWG 10AWG Note: These ratings apply to standed wire which will be used exclusively on all electrofishing boats 14 WIRING MUST HAVE ADEQUATE MECHANICAL PROTECTION Conductors used shall meet the requirements for dampness All conductors in electrofishing boats shall be enclosed in conduit or Iiquid tight flexible conduit except that appropriate heavy duty rubber cord can be used if greater flexibility in installation is necessary CONNECTORS AND INTERLOCKING MUST BE ADEQUATE No splices of wire shall be permitted If connections are necessary, the rating of the connector (plastic wire nut) must be at least equal to that of the wire Connectors used in association with flexible cords shall be of the locking weatherproof type D RECOMMENDED SAFETY TIPS STREAM ELECTROFISHING: a ALL CREW MEMBERS MUST BE ALERT, but the brail operator who controls the power switch must be constantly aware of netters in the electrical field, especially when working in deep water b OPERATE SLOWLY AND CAREFULLY Footing in most streams is poor and most falls often occur when crew members are hurrying c TAKE FREQUENT BREAKS Don't let stress and fatigue endanger your safety d BEWARE OF TURBID WATER where unseen subsurface obstacles or dropoffs could be hazardous e A GASOLINE POWERED GENORATOR SHOULD NOT BE IN OPERATION WHILE ON A CREW MEMBER'S BACK The Genorator should be operated while secured to the stream bank or in a tow boat 15 CHEMICAL HANDLING SAFETY A PREREQUISITES FOR CHEMICAL HANDLING ALL BFS PERSONNEL SHALL RECEIVE CHEMICAL FIRST AID TRAINING INCLUDING THE USE OF SAFETY EQUIPMENT, FIRST AID KITS, AND FIRE EXTINGUISHERS REQUIRED PERSONAL PROTECTIVE SAFETY EQUIPMENT MUST BE PROVIDED to each individual involved This includes gear like goggles, gloves, respirators, protective clothing, etc as specified in Table B GENERAL PROCEDURES PERSONNEL SHALL READ LABELS ON CONTAINERS BEFORE OPENING Manufacturer's instructions regarding handling, storage, and use must be followed unless they have been altered in writing only by an employee's supervisor PERSONNEL MUST BE FAMILIAR WITH CHEMICALS THEY WILL BE HANDLING including general hazards, safety precautions, allowable limits, safe exposure levels, and associated first aid procedures The chemicals listed in Table 1, p 21, include most of these that may be encountered by BFS personnel Assume any chemical is dangerous unless one knows differently CHEMICALS MUST NOT BE HANDLED OR USED WITHOUT REQUIRED EQUIPMENT such as gloves, goggles, respirators, etc as listed in Table In some cases (as listed), the use of equipment is recommended, but not required, for your protection when handling chemicals which are not normally considered hazardous Bare hands should not be placed into wet or dry chemicals Remember that clotrling and safety equipment will not provide complete protection ONLY APPROVED CHEMICAL CARTRIDGE RESPIRATORS SHALL BE USED Boxes containing respirators and cartridges must be stamped with a certification of approval by NIOSH (National Institute for Occupational Safety and Health) or MESA (Mining Enforcement and Safety Administration) Clean and disinfect the facepiece of the regulator before using Cartridge type must match the chemical being used and be replaced as needed IN CASE OF ACCIDENT OR SPILLAGE, DANGEROUS FUMES, VAPORS OR DUST SHOULD NOT BE INHALED Eyes or areas of skin in contact with chemicals should be flushed with eyewash or clean water for at least 20 minutes Contaminated clothing should be changed as soon as possible, and contaminated protective clothing should be placed in a container prior to washing All permanent personnel shall complete a basic course in chemical first aid 16 NO SMOKING DURING OR IMMEDIATELY AFTER USE OF SPECIFIED CHEMICALS (Table 1) The heat from a lighted cigarette vaporizes chemicals in contact with it and passes the chemical(s) directly to your lungs and also could be a fire hazard After handling chemicals, both hands and face must be washed before smoking Also, remember that cigarettes can be contaminated while being carried in your pocket FIRST AID KITS MUST BE AVAILABLE during any operations where chemicals listed in Table are handled First aid kits will include one pint bottle of eye wash and a five gallon can of clean water (if not available on-site) PERSONS WITH DOCUMENTED ALLERGIES TO CERTAIN CHEMICALS SHALL NOT BE ASSIGNED TO WORK WITH THOSE CHEMICALS Written documentation of the allergy from either one's supervisor or a physician is adequate CHEMICALS THAT REACT DANGEROUSLY WHEN MIXED WITH OTHERS will not be stored next to each other so that mixing cannot occur if their containers leak or break 10 CHEMICALS WHICH ARE FIRE HAZARDS BY CHEMICAL REACTION (exothermic) will not be stored near flammable substances 11 PROLONGED PERIODS OF CHEMICAL STORAGE WILL BE AVOIDED Care should be taken to purchase only enough chemicals to satisfy reasonably current demands, especially when using highly poisonous, corrosive, or flammable chemicals 12 EMPLOYEES MUST WASH HANDS BEFORE HANDLING FOODS after working with poisons, acids, or caustics Food shall not be stored in contaminated work areas or eaten while wearing contaminated c1othings 13 CHEMICALS SHALL NOT BE STORED IN POORLY VENTILATED ROOMS, or where food can be contaminated Local fire codes must be checked for chemical storage regulations 14 CHEMICAL CONTAINERS MUST BE CLEARLY LABELED as to contents and whether poisonous, flammable, or corrosive Unidentifiable contents of unlabeled containers shall be properly disposed of 15 DANGEROUS, POISONOUS, FLAMMABLE, REACTIVE, OXIDIZING, CORROSIVE, AND EXPLOSIVE CHEMICALS must be kept in the laboratory when not in use 16 STRONG ACIDS OR ALKALIES SHALL BE HANDLED only if protective gloves are available Wash gloves before removing If skin contact occurs, wash contaminated areas with soap and water and apply lanolin products If irritation persists, a physician should be consulted 17 17 CONTAMINATED EQUIPMENT such as rain gear, goggles, packboards, etc shall be cleaned thoroughly with soap and water immediately after use 18 CLOTHING CONTAMINATED WITH DANGEROUS CHEMICALS SHOULD BE REMOVED AS SOON AS POSSIBLE, followed by a shower and a clean change of clothes before continuing work A hat with a sweaty or contaminated sweat band should not be worn 19 EMPLOYEES WILL NOT INVESTIGATE OR WORK AT THE SITE OF A CHEMICAL SPILL UNTIL THE CHEMICAL INVOLVED HAS BEEN IDENTIFIED 20 CHEMICALS FROM LARGE CONTAINERS WILL BE REMOVED BY PUMPS OR SIPHONS SIPHON TUBES MUST NEVER BE PRIMED WITH YOUR MOUTH 21 CHEMICALS MUST ALWAYS BE DILUTED BY POURING INTO THE DILUTING SOLUTION, never the reverse, e.g acid into water, etc 22 WORKERS WHO COMPLAIN OF HEADACHE, NAUSEA, GIDDINESS, BODY PAINS, OR NUMBNESS during or after the use of chemicals shall be removed from the work area and taken to a doctor 23 A FIELD PRO, IECT SUPERVISOR THOROUGHLY TRAINED IN CHEMICAL HANDLING SAFETY WILL BE DESIGNATED IN CHARGE of 'field operations where hazardous chemicals will be used 24 USED CHEMICALS AND CONTAINERS SHALL BE DISPOSED OF AS FOLLOWS: a Used chemicals shall be placed in appropriate "waste chemical containers ll for special disposal Special waste containers are available for flammable waste in the Volatile Storage Room Toxic and nontoxic waste containers are available for aqueous chemical wastes Chemical wastes should not be poured down the drain b A NYS DEC Regional Solid Waste Engineer should be consulted for information on disposal of other chemicals c Containers, liners, and debris from toxic chemicals shall be punctured or crushed to render them useless and then transferred to a sanitary landfill Paper bags remaining after liming operations may be burned on-site in accordance with local or DEC regulations regarding open burning 18 C REQUIRED SAFETY EQUIPMENT The following list includes equipment that is required for the safe handling of various types of chemicals as listed in Table 1 Goggles, chemical splash Dust/mist respirators, full face dust/mist respirators, chemical cartridge respirators Protective aprons Protective gloves Fire extinguishers Eye wash solution, clean water (if not available on-site) Impervious coveralls First Aid Kits Special protective boots if warranted 19 NON-BFS EMPLOYEE PARTICIPATION During the course of routine operations, including various types of field surveys, fish stocking, meeting attendance, etc individuals not employed by the BFS or the State of New York commonly participate in these activities strictly on a volunteer basis wiU"1 no renumeration involved In some cases, individuals previously designated for specific work assignments for a specified period are considered "official" volunteers after SUNY Oneonta administrative recognition In these cases, liability and compensation coverage is identical to that of permanent employees Generally, however, most volunteer participation is not pre-planned and, especially in the case of fish stocking assistance, paperwork is seldom submitted in advance In these cases where volunteer participation is condoned and often even encouraged, there is no formal arrangement for liability and compensation coverage For the safety of the volunteers involved as well as for the protection of the BFS or SUNY Oneonta against liability claims: NO VOLUNTEERS WILL BE ALLOWED IN BOATS, CARS, TRUCKS, AIRCRAFT, OR MOTORIZED VEHICLES Uf\ILESS ADMINISTRATIVE APPROVAL HAS BEEN PROPERLY SUBMITIED AND APPROVED BY THE PRESIDENT OR HIS DESIGNATED AGENT(S) Except as noted in item 3, NO VOLUNTEERS WILL BE ALLOWED TO PARTICIPATE IN EITHER BOAT OR STREAM ELECTROFISHING SURVEYS, CHEMICAL HANDLING OPERATIONS, OR ANY OPERATIONS INVOLVING THEIR TRANSPORT BY BOAT, CAR, TRUCK, AIRCRAFT, OR OTHER VEHICLE UNLESS: a Administrative recognition forms have been submitted and approved b Any safety equipment required for use by permanent employees will be provided for and used by volunteers Individuals will be permitted to observe electrofishing operations from a safe distance (25 feet or greater) as determined by the supervising crew leader VOLUNTEER PARTICIPATION WITHOUT SUBMITIAL AND APPROVAL WILL BE PERMITrED ONLY BY INDIVIDUALS NOT INVOLVED WITH ELECTROFISHING, CHEMICAL HANDLING, OR VEHICLE TRANSPORT, however, a Volunteers will be familiar with and abide by the BFS safety policy b Any safety equipment required for use by permanent employees will be provided for and used by volunteers c Volunteers must be advised by the crew leader or supervisor of potential safety hazards and necessary safety precautions prior to participation in field or laboratory activities BFS personnel involved in field or laboratory activities cannot be held liable for the safety of non-BFS employee volunteers 20 TABLE Chemicals Routinely Used in Fisheries Operations NAME (FORMULATION) KETHOD OF EXPOSURE FISHERIES USE HEALTH HAZARD *Rotenone (emulsified liquid) Fish toxicant Irritant poison (est lethal dose 200 mq/kg, or 13.6 g for a 150 lb person *m (liquid) Lampricide No known toxicity to man; physical eye irritant Liming Irritant Inhalation, skin & mucous membrane contact Disinfectant, detoxifying agent Flamable, strong irritant Inhalation, inges tion skin and mucous membrane contact - *Bayer 73 (coated qranulesl Hydrated Lime (powder) Potassium Permanganate (crystal! ine/ powder) SYMPTOKS - Numbness, nausea, Inhalation, ingestion, skin vomiting, tremors, skin & eye contact irritation Eye irritation SAFETY PRECAUTIONS AND PROTECTIVE EQUIPKENT Wear impervious coveralls or raingear, rubber gloves and gogg Ies if direct & repeated or prolonged contact is unavoidable Use a chemical cartridge respirator with an organic vapor cart ridge when prolonged inhalation of mist or spray is unavoidable No smoking during and irrmediately after application until hands are washed After use place protective clothing in a container for future washing Change clothing and shower daily during application period Wear impervious coveralls or raingear, rubber gloves, headgear, rubber framed goggles and a dust/mist respirator if prolonged contact is unavoidable During helicopter applications wear garments with full hoods and elastici&ed ankle, wrist and face openings Use a full face dust/mist respirator (Helicopter application creates increased ha&ards from rotor wash and swirling dust.) After use place protective clothing in a container for future washing Irritation of eyes, Wear rubber gloves, goggles Use dust/ skin, respiratory mist respirator when working with powder system formulation Do not store near com bustible substances Do not mix or store in close proximity with glycerine or ethylene glycol Impervious coveralls, apron or raingear recommended to protect clothing Irritation of eyes, skin, and respiratory system *Application must be under supervision of a certified pesticide applicator 21 FIRST AID Remove contami nated clothing Flush contami nated areas of the body with soap and water or eyewash FI ush eyes with eyewash Remove tami nated cl othing Flush tami nated areas of the body with soap and water or eyewash Apply lanolin products to irritated areas Flush affected areas with water or eyewash - TABLE Chemicals Routinely Used in Fisheries Operations (cant.) NAKE Ji'ORMULATI~_.llSHERI~~E_ -.JIEALTH Formal dehyde (aqueous sol ution) HAZARD Fish disease Irritant control, specimen preservation -~~ -1f + -I Korpholine (liquid) Imprintinq aqent Irritant, flananable (95\ flash point) poisonous Chlorine (aqueous solution) Hatchery disinfectant Stronq irritant sui furic Acid Water Chemistry Hydrochloric Acid Nitric Acid Potassium Hydroxide Sodium Hydroxide Isopropanol, Specimen ethanol preservation (I iquid) Autimycin (I iquid) other Chemicals Fish toxicant METHOD OF ,EXPOSURE Inhal ation, ingestion, skin and mucous membrane contact SYMPTOMS I I SAFETY PRECAUTIONS AND J) RPTECJIVUQ.UJPKE~L Adequately ventilate work areas; wear qoggl es and use rubber gloves or a barrier cream Irritation of eyes, skin and respiratory system I Corrosive, stronq irritant Skin or mucous membrane contact Irritation of eyes, skin Skin and eye irritant, toxicant, flananable Inqestion, inhalation, skin or eye contact Irritation of eyes, skin; headache, drowsiness, fatique Very caustic, skin & eye irritant Eye and skin contact Irritation of eyes, skin; blindness Adequatel y ventil ate work area; wear goggles and rubber gloves; not store near combusible material or in areas of excessi ve heat Contaminated cl othing should not be worn No smokinq Fire extinquisher must be available in work area Adequately ventilate work area, wear rubber gloves and goqqles, and impervious coveralls, apron or rainqear Cant ami nated clothing should not be worn After use, place protective clothinq in a container for future washing Rinse hands after use to prevent accidental eye contact Rec01lllllend eye protection (rubber framed qoqql es) durinq use Label containers clearly Work in a well ventilated area; wear plastic gloves or a barrier cream as needed; fire extinguisher must be available in work area No smokinq ~_fIRSll!L FI ush affected areas with water or eyewash Ventilate work Iarea Flush affected areas with water or eyewash for up to 15 minutes FI ush affected areas with water or eyewash for up 15 minutes ventilate work area FI ush affected areas with water or eyewash for up to 15 minutes Wear impervious coveralls or rainqear, rubber qloves, rubber framed qoqqles Rinse rubber qloves and hands iImllediately after use with soap and water After use place protective cl othing in a container for future washing Additional chemicals not listed here may be encountered or used by fisheries personnel during routine operatlons or emergencles like accidental chemical spills Read the manufacturer's label or take other measures to identify the chemical and follow the instructions regarding hazards handlinq, storage, use and first aid procedures I I 22 _ TABLE Chemicals Routinely Used in Fisheries Operations (cont.) NAME ~ORM~~ATIONL L~ Roccal (l iquid) Hyamine (I iquid) Purina 4X (liquid) Chloramine T {powder l _ Dy Iox (powder) SYMPTOMS HEALTH HAZARD chI orophy11 extraction Flammable, Irritant! Narcotic Inhalation, ingestion, skin contact Fish disease control Mil d irritant Fish disease control Skin and eye irritant, toxicant Inhalation, Slight irritation ingestion, skin of eyes, skin, and and mucous and respiratory membrane system conlliL Inhalation, Irritation of eyes, inges tion, skin skin and respiratory system, and mucous membrane uncontrolled contact muse! e spaslllS - < Other Chemicals METHOD OF EXPOSURE FISHERIES USE Irritant of upper respiratory tract Throat irritant Central nervous sys tem depressant SAFETY PRECAUTIONS AND PROTECTIVE EQUIPMENT - - - - - - Protective equipment Work in well ventilated area Avoid contact with sparks, flames or other sources of ignition Hear protective (impervious) gloves to prevent contact Hear rubber gloves and goggles if dlrect and repeated or prolonged contact is unavoidable, FIRST AID Inhalation Remove frorr exposure ar to fresh iImnediately Skin contac_ Remove contami nated cI othing & wash affected area with soap & 1arge amoun ts of water fu'e ta~t Hash eyes immediately with large amounts of water Fl ush affected areas with water or eyewash as needed ' - Remove contami Wear impervious coverall s or raingear, rubber gloves, headgear, and goggl es nated cI othing Use a chemical cartridge respirator FI ush affected with an organic vapor cartridge when areas with soap & water or eyewash inhalation is possible No smoking or eating inmediately after application until hands are washed After use place protective clothing in a container for future washing Additional chemicals not listed here may be encountered or used by fisheries personnel during routine operations or emergencies like accidental chemical spills Read the manufacturer s label or take other measures to identify the chemical and foil ow the instructions regarding hazards hand Iing, storage, use and first aid procedures I 23 TABLE Chemicals Routinely Used in Fisheries Operations (cant.) KAME v wv _ ~ SAFETY PRECAUTIONS AND METHOD OF "" Irritation of eyes and skin _ - Wear rubber gloves and goggles if direct and repeated or prolonged contact is unavoidabl e n Fl ush affected areas with water or eyewash as needed Remove contami nated cl othing FI ush affected areas of the body wi th soap and water or eyewash as needed Terramycin (powder) Sui famerazine (powder) Chi oro tone (powder) MS-22 (powder) Methyl Pentynol (liquid) Quinaldine SulDhate ma.) Fish disease control Mil d irritant Skin and mucous membrane contact Fish anesthetic Kot established Inhalation, Unknown ingestion, skir and mucous membrane contact Other chemicals Additional chemicals not listed here may be encountered or used by fisheries personnel during routine operations or emergencies like accidental chemical spills Read the manufacturer's label or take other measures to identify the chemical and follow the instructions regarding hmrds handling, storage, use and first aid procedures _c 24 Although toxicity to humans is unknown, adequate precautions should be taken by employees commonly using them to prevent inhalation, ingestion or skin contact _ ... Station's (BFS) Safety Program, we have developed a Safety and Health Policy and related Field Manual for all BFS activities II III Objectives A To authorize and provide generic means and methods... accidents and reduce loss of time The safety program is designed not only to provide and maintain safe and healthful working conditions but to improve morale and well-being and the efficiency of BFS operations... and field manual instructions regarding safety and health B Stimulate, promote, and enforce safety consciousness and safe work habits VI C Provide guidelines for planning, development, and construction