Synthetic and structural studies of copper, gold and palladium heterocyclic carbene complexes

... ferrocene-derivatized carbene and palladium( I) complexes have been very limited In view of the significance of copper, gold and palladium carbene complexes in organic synthesis, materials and medicine, ... enriching the knowledge of copper, gold and palladium NHC complexes, the results of this research will be instructive for mechanistic study and futu...

Ngày tải lên: 11/09/2015, 09:12

... STRUCTURAL STUDIES OF GLYCOGEN BRANCHING ENZYME (GLGB) AND CRFR2α:UROCORTIN COMPLEXES KUNTAL PAL (M.Tech Biotech And Biochem Engg.) A THESIS SUBMITTED FOR THE DEGREE OF DOCTOR OF PHILOSOPHY ... molecules Inclusion of a branching pattern into the linear form of a polysaccharide is catalyzed by the glycogen branching enzyme (glgB) This transglycosylase enz...

Ngày tải lên: 10/09/2015, 15:52

... structure of dNK has previously been determined in complexes with substrates and a feedback inhibitor [12,13] It has a structure similar to that of the human dGK and dCK and belongs to a structural ... specificity of dNK Earlier crystallographic studies of substrates dT and dC and on the structure of the feedback inhibitor complex with dTTP, as well as mutat...

Ngày tải lên: 16/03/2014, 06:20

... this study, we describe the structures of two homologues, TKs from B anthracis and B cereus, in complex with substrate dT and phosphate donormimicking dTTP Because of the high sequence identity ... expression and purification of human thymidine kinase 1: quaternary structure, stability, and kinetics Protein Expr Purif 47, 506–515 20 Black ME & Hruby DE (1990) Quatern...

Ngày tải lên: 23/03/2014, 09:21

... 271) strain 80204-1 produced under in vitro growth conditions on tryptic soy agar (TSA) and in vivo and have demonstrated that their structures are chemically and antigenically distinct from the ... TOF Analysis of the in vivo cultured A salmonicida strain 80204-1 cells In vivo culture was performed using ligated dialysis tubing bags filled with ba...

Ngày tải lên: 23/03/2014, 13:20

... Dissertation Topic: Biochemical and Structural Studies of Escherichia coli Leucine-responsive Regulatory Protein Experience 1997-1998 Teaching Assistant Department of Chemistry University of North Carolina, ... Biochemical and structural studies of Escherichia coli Lrp Transcriptional regulation of gene expression is an essential component for the life o...

Ngày tải lên: 14/11/2014, 06:09

... mechanism of cysteine proteases 14 1.3.3 Inhibitors of Cysteine proteases 16 1.3.4 Endogenous inhibitors: Cystatin superfamily 1.3.5 Synthetic inhibitors of Cysteine proteases 1.4 Serine proteases ... mechanism of Serine proteases 23 1.4.2 Serine protease inhibitors 26 1.4.3 Serpins 27 1.4.4 Canonical serine protease inhibitors 29 1.4.5 Non canonical serine...

Ngày tải lên: 14/09/2015, 14:09

Ngày tải lên: 14/11/2014, 09:26

... DISCUSSIONS 2.1 Synthesis and characterization of p- cymene Ru(II) NHC complexes 2.1.1 p- cymene Ru(II) NHC complexes bearing monodentate NHC ligands The synthesis of the p- cymene Ru(II) NHC complexes ... late-transition Page 11 Conversion of LA to GVL using p- cymene Ru(II) NHC Complexes metal series On another hand, the nucleophilic carbene carbon...

Ngày tải lên: 01/10/2015, 17:27

... DISCUSSIONS 2.1 Synthesis and characterization of p- cymene Ru(II) NHC complexes 2.1.1 p- cymene Ru(II) NHC complexes bearing monodentate NHC ligands The synthesis of the p- cymene Ru(II) NHC complexes ... late-transition Page 11 Conversion of LA to GVL using p- cymene Ru(II) NHC Complexes metal series On another hand, the nucleophilic carbene carbon...

Ngày tải lên: 03/10/2015, 21:57

... DISCUSSIONS 2.1 Synthesis and characterization of p- cymene Ru(II) NHC complexes 2.1.1 p- cymene Ru(II) NHC complexes bearing monodentate NHC ligands The synthesis of the p- cymene Ru(II) NHC complexes ... late-transition Page 11 Conversion of LA to GVL using p- cymene Ru(II) NHC Complexes metal series On another hand, the nucleophilic carbene carbon...

Ngày tải lên: 04/10/2015, 07:59

... understanding of the effect of co-ligands in Ru complexes on the ease of ring slippage of the indenyl ligand, on the catalytic activity of [(Ind)Ru] complexes and the redox potentials of the ... metal complexes, but are common in complexes of group 10 25 Chapter Reactivity studies of [(Ind)Ru] complexes with P-, N- and S-containing ligands Table 2.1 Common c...

Ngày tải lên: 15/09/2015, 17:09

... S103 G145/D137 Y 112 D2 01/ 193 L75/67 G145/D137 E1 41/ 133 K173 /16 5 R207 /19 9 G77/69 D142 /13 4 G197 /18 9 Fig Superposition of PRTFDC1 with HPRT-ImmGP (Protein Data Bank code: 1BZY) (A) Residues in the ... Welin et al Studies of the human PRTFDC1 B A PRTFDC1 25 HPRT 20 10 00 0.2 800 600 400 0 .1 200 –50 50 10 10 50 10 015 0 200 250 S 200 –50 250 50 12 00 10 0 15 0 [H...

Ngày tải lên: 15/02/2014, 01:20

... understand which factors are predictive of good fluency The distribution of fluency scores in the dataset is rather skewed, with the majority of the sentences rated as being of average fluency as ... assess the content of the sentence compared to a human gold-standard Yet, the assessments of the two aspects were often the same—readability /fluency o...

Ngày tải lên: 22/02/2014, 02:20

... various systems comprised 3899 and 4516 SPC molecules for the agonist and the antagonist in water, respectively, and 817 and 927 Me2SO molecules for the agonist and the antagonist, respectively, corresponding ... the binding and affinity for I-Au because of occupation of the P1 pocket Recent thermodynamic and kinetic studies of the binding of TCRs...

Ngày tải lên: 07/03/2014, 16:20