Platinum pps
... on Nanosurfaces The applicability of the DamjanovicBrusic Temkintype sideways repulsion mechanism for the reduction of DGads of reaction intermediates on nanosurfaces deserves comment A (111) nanosurface ... only part of the electrocatalyst nanocrystallite surface may be used, the amount being reduced as d becomes less, all other factors remaining the same Platinum Nanocrystallites Introduction It ... The purpose of this section is to look at the possible lower limit for nanocrystallite preparation Geometric Considerations Nano-sized Pt electrocatalyst particles on high-surfacearea carbon and...
Ngày tải lên: 06/07/2014, 23:20
... although their ellipticities were considerably different Whereas their CD spectra in water predominantly showed a random conformation characterized by a negative peak at % 197 nm, the spectra in...
Ngày tải lên: 23/03/2014, 12:20
Ngày tải lên: 14/11/2014, 07:13
Synthesis and reactivity studies of cyclopentadienyl derivatives of ruthenium iridium and osmium iridium mixed metal clusters 5
... resonances each at high field, indicative of bridging metal hydrides Two methyl signals were observed for 27 and 29 and one for 28, consistent with their solid-state structures The aromatic resonances ... Ru (CO)2 toluene reflux Ru3(CO)12 + SPh2 Ru (CO)3 (CO)3 Ru SPh Major product Os3(CO)12 + MeSPh nonane reflux Os Os MeS H Os Scheme 5.3 The chemistry of tellurium-containing clusters can be quite ... Zhang, and W.K Leong, Journal of the Chemical Society, Dalton Transactions, 2000, 1249 18 N Petragnani, Tellurium in Organic Synthesis, Academic: London, 1994 203 ...
Ngày tải lên: 16/09/2015, 08:30
Synthesis and reactivity studies of cyclopentadienyl derivatives of ruthenium iridium and osmium iridium mixed metal clusters 1
... from η5- η3- η1 Typical η5- Cp 1H resonance occurs between δ 3.5 – 5.5 ppm For η1-Cp, the α hydrogen resonance occurs at about δ 3.5 ppm, and the β and γ resonances occur between δ 5-7 ppm The most ... they resonate to high field of TMS in a region (δ to 60 ppm) normally free of other ligand resonances Hydrides couple with phosphines which serve as a valuable tool in elucidating the structure ... others, have reported that high nuclearity mixed-metal clusters can act as precursors for bimetallic nanoparticle catalysts that can be anchored inside mesoporous silica [14-17] 1.5 Synthetic strategies...
Ngày tải lên: 16/09/2015, 08:32
Synthesis and reactivity studies of cyclopentadienyl derivatives of ruthenium iridium and osmium iridium mixed metal clusters 2
... sharp hydride signal at δ -18.21 ppm A VT 1H NMR experiment showed broadening of the hydride resonance on cooling, but no decoalescence was observed even down to 190 K 34 Figure 2.2 ORTEP diagram ... which is that observed in the solid state In solution, structure (II) appears to be the predominant isomer (Figure 2.11) The two isomers are present in a 1.0:3.7 ratio in solution The chemical ... in d8-toluene (τm = 0.1 sec) at 200 K, exchange cross peaks were seen between all the five resonances indicative of hydride exchange that results in isomerisation between the two isomers as well...
Ngày tải lên: 16/09/2015, 08:32
Synthesis and reactivity studies of cyclopentadienyl derivatives of ruthenium iridium and osmium iridium mixed metal clusters 3
... peaks at 2066m, 2040vs, 1996s, 1967sh, 1942sh and 1701br cm-1 and the 1H NMR spectrum showed resonances at δ 1.92 (s, 15H, Cp*) which was assigned to Cp* protons an -18.85 (s, 2H OsHOs) Removal...
Ngày tải lên: 16/09/2015, 08:32
Synthesis and reactivity studies of cyclopentadienyl derivatives of ruthenium iridium and osmium iridium mixed metal clusters 4
... of four resonances; one doublet at δ -19.94 ppm (2JP-H = 9.0 Hz) and three broad singlets On lowering the temperature to 233 K, the 1H NMR spectrum consisted of well-resolved resonances at δ ... resonances supported the existence of two isomers in the ratio 1:0.14 (at 233 K) in solution A 31 P selective decoupling experiment performed on 17a by irradiating at the phosphorous resonances ... constants further suggested that one of the hydride resonances was coupled to a phosphorous (2JP-H = 9.1 Hz) whereas the other hydride resonance was not 300 K 273 K 253 K 233 K -15.6 -16.0 -16.4...
Ngày tải lên: 16/09/2015, 08:32
Báo cáo khoa học: An NMR study of the interaction between the human copper(I) chaperone and the second and fifth metal-binding domains of the Menkes protein pot
... obtained using standard strategies based on triple resonance experiments [23] In 15N-heteronuclear single quantum coherence (HSQC) spectra the resonances of the backbone amide moieties of residues ... interaction does occur Indeed, formation of an adduct can be detected through surface plasmon resonance measurements, with a kon for formation of the adduct of the order of 102)103 m)1Æs)1 [28] ... protein and that the solution structure of MNK5 is not sensitive to the presence of the tag Recombinant protein characterization, NMR frequency assignments and solution structure determination of...
Ngày tải lên: 30/03/2014, 15:20
dialogue with bakhtin on second and foreign language dialogue with bakhtin on second and foreign language
... antigenic deletion The cellular loss of antigenic determinants, or the masking of existing cellular antigenic determinants antigenic determinant That portion of the antigen molecule that is responsible ... dissimilar Combining form referring to an isomeric form such as an enantiomer of a compound that has more than one pair of enantiomers, or the more stable form of two geometrical isomers Combining ... antigenic gain The cellular acquisition of new antigenic determinants, or the unmasking of existing cellular antigenic determinants antigenicity The capacity of an antigen to stimulate the formation...
Ngày tải lên: 01/06/2014, 01:10
Báo cáo y học: "Characteristics of repair tissue in second-look and third-look biopsies from patients treated with engineered cartilage: relationship to symptomatology and time after implantation" ppsx
... Research & Therapy Vol 10 No Brun et al materials derived from the total esterification of hyaluronan with benzyl alcohol and constructed with a nonwoven configuration (Hyaff-11) have been successfully ... of collagen type II that distinguishes hyaline cartilage from the type I collagen found predominantly in fibrocartilage [17,18] In that study, tissue engineered grafts induced cartilage regeneration ... into a threedimensional biodegradable material derived from the total esterification of hyaluronan with benzyl alcohol and constructed with a non-woven configuration (Hyaff 11) Briefly, cells...
Ngày tải lên: 09/08/2014, 13:22
The Scientist and Engineer's Guide to Digital Signal Processing Second Edition
Ngày tải lên: 13/09/2012, 10:21
Techniques for developing content reading skills for the third year students at the university of odonto and stomatology
... explanation can be everyone’s satisfaction According to Harmer, it is the eyes and the brain to dominantly participate in the reading process The eyes are on messages and the brain then has to identify ... I.3.2.1 The roles of reading students In a language classroom, it is not the teacher who takes dominant roles but the student to play a reciprocal role such as “active learning, monitoring comprehension,...
Ngày tải lên: 07/11/2012, 14:50
Motivation in learning english speaking of the second year tourism major students at tourism and foreign language department, sao do college of industry
... a list of general principles or features One of the most recognized of These lists are David Nunan’s (1991) five features of CLT: An emphasis on learning to communicate through interaction in ... as requests, apologies, thanks, and invitations; - Knowing how to use language appropriately Nunan, D., 1999, p.226 Accordingly, in the speaking class, teachers need provide their students with ... Motivation as a contributing factor in Second Language Acquisition Cambridge University Press 24 Nunan, D.(1992) Research Methods in Language Learning Cambridge University Press 25 Nhung, Nguyen...
Ngày tải lên: 07/11/2012, 15:01
A study on oral presentation difficulties of second year english majors of phuong dong university in the speaking lessons and solutions
Ngày tải lên: 07/09/2013, 13:02
TECHNIQUES FOR DEVELOPING CONTENT READING SKILLS FOR THE THIRD YEAR STUDENTS AT THE UNIVERSITY OF ODONTO AND STOMATOLOGY
... explanation can be everyone’s satisfaction According to Harmer, it is the eyes and the brain to dominantly participate in the reading process The eyes are on messages and the brain then has to identify ... I.3.2.1 The roles of reading students In a language classroom, it is not the teacher who takes dominant roles but the student to play a reciprocal role such as “active learning, monitoring comprehension,...
Ngày tải lên: 07/09/2013, 13:45