h het and the e2 sn2 competition

... (H3 C) 2HC H (H3 C) 3C H 98 96 Hb Hb Hb Hb Hb Hb H H H H Hb Hb Hb H H i.e., no-bond resonance form per Hb Hb Hb Hb no-bond resonance forms H Hb Hb Hb no-bond resonance forms Hb Hb Hb In the VB model, ... standard heats of reaction DH0 of the homolytic dissociation reaction R H Æ R• + H It reflects, on the one hand, the strength of this C H bond and, on the other hand, the stability of the radical ... + R R R OH OH OH Net equation: Σ Propagation steps: + Hg R OH R + Hg OH R + OH OH R Hg R OH OH R OH H + R Hg R R Hg OH H OH Termination steps, for example: H + R Hg R OH H Hg H Hg R OH Initiation...

Ngày tải lên: 02/04/2014, 16:01

... to the home Certainly the question surrounding this architecture is whether 80 Mbits/sec will be adequate and for how long At the end of the day, the key consideration in choosing which architecture ... sees as the real demand for customer bandwidth – and where that demand will be five to ten years from now The biggest unknown in the broadband services equation lies in how much bandwidth will ... future-proofing the network against any future bandwidth demand? White Paper There is no “one size fits all” solution when transforming the traditional switched approach network into a high-speed, high-capacity...

Ngày tải lên: 10/12/2013, 17:15

... announcements even though the state of the economy has changed in ways that were then unpredictable The risk is that either the central bank validates the pre-announced path, and enacts suboptimal ... of this shock, which it knows will lead to the choice of the future interest rate As they swap signals, both the central bank and the private sector learn from each other As a consequence, the ... increases, the curve that marks the frontier between transparency and opacity in figure shifts up on the left where k is small (the intercept with the horizontal axis is + 2κ) and down on the right where...

Ngày tải lên: 17/02/2014, 03:20

... that of the intact parent antibody The conformation of the light or heavy chains could be more flexible when they were isolated than when they existed in the whole antibody This difference in the ... heavy chain (HpU-9 -H) and the light chain (HpU-9-L) isolated from the parent HpU-9 mAb primarily reacted with the b-subunit but only scarcely with the a-subunit (lane 2) In this experiment, the a-subunit ... chains change their specificity In the case of HpU-17 and )20 mAb (a series of mAbs obtained along with HpU-9) [17], their heavy or light chains showed the same specificity (to the b-subunit) as their...

Ngày tải lên: 07/03/2014, 21:20

... better emphasize the role of each of these residues on protein stability The results highlight the importance of the hydrogen- HO P O HO P O HO O NH2 O HO N OH O O O N N O HO CMP OH NH O UMP D129 ... parentheses represent values in the highest resolution shell (last of 20 shells) b Rsym ẳ ShSi |I (h, i) ) < I (h) > | ShSi I (h, i) where I (h, i) is the intensity value of the i-th measurement of h and ... with R110 make the pKa value for H1 32 far below the physiological pH and thus turn off the His charge Because the pKa of isolated His is 6.5, the difference in ionization energy of His in the...

Ngày tải lên: 16/03/2014, 10:20

... to induce the formation of the 1D nanostructures of h- WO3 Thus, the size and the yield of the rod-like nanostructures increase with increasing the amount of the salt As a result, the presence ... homogenous phase with uniform particles which display nanorods morphology sizing about lm in length TEM image (Fig 2e) shows that the as-synthesized product exhibits the same rod-like morphology These ... nanostructure having unique morphology Furthermore, this synthetic method is simple, mild, and controllable, and it provides a novel method for direct solution growth of highly oriented and hierarchical...

Ngày tải lên: 19/03/2014, 16:47

Ngày tải lên: 20/03/2014, 22:20

... He made himself susceptable to Iago and the jealousy within him begins to lead to the demise of others By his actions Othello has isolated himself from everyone except Iago This gives Iago the ... Iago takes the opportunity to strengthen Othello's views of honesty and trust towards him by saying ironically, "Men should be what they seem; / Or those that be not, would they might seem none! ... considering the atmosphere Ironically, the venetians feel the Turks are their only enemy while in fact Iago is in hindsight the one man who destroys their stable state Act II Scene III shows Iago's...

Ngày tải lên: 21/03/2014, 22:48

... alternative hypothesis for the proton transport pathway This hypothesis is based on the assumption that as in the case of the well-known bacteriorhodopsin proton pump, H+ ions would be the relevant ... segments of the transmembrane domain, hence these cavities have been discussed in light of several independent mutational studies On the other hand, the phosphorylation domain where we locate the proposed ... bacteriorhodopsin [45] To lend support to our hypothesis, we therefore applied the same approach to the high-resolution structure of bacteriorhodopsin and the closely related structure of halorhodopsin,...

Ngày tải lên: 23/03/2014, 21:20

... coast runs into another bight; and the first opening after the termination of the high land is the mouth of the river Seboo Then comes another river; after which the land rises into hills, gradually ... with heads raised above the general mass, can scarce be seen through the foliage of those beneath; but here and there the touch of time has cast his withering hand upon their leafy brow, and ... in the neighborhood of the Dyak tribes, dance these dances; but they are unknown to Borneo Proper, and the other Malay islands; and although the names may be given by the Malays, I think there...

Ngày tải lên: 29/03/2014, 22:20

... mCherry-HpSSB protein is shown as described earlier for the HpSSB protein The arrowhead indicates the position of the ssDNA in the absence of SSB protein and the subsequent retardation of the ... of the major replicative helicase DnaB from H pylori [13] We were interested to see whether HpSSB would modulate the enzymatic activities of HpDnaB One of the hallmarks of the replicative helicases ... Moreover, both DNAdependent ATPase and helicase activity of HpDnaB can be modulated by HpSSB Whether the modulation effect is due to the titration of ssDNA in the presence of HpSSB, or due to the possible...

Ngày tải lên: 30/03/2014, 02:20

... are the heights of the “downstairs” (in decreasing order), N1, N2, N3 are the frame positions at which the step changes occur, and ri is the number of bits at ith frame, then the step heights ... every step This average is the minimum bandwidth required to transmit all the frames of that step As the SP-frame has a higher bit rate than all the other frames of the step and it is the first ... used only once at the switching instant) will be much higher than the bandwidth derived from the FOR with SP-frames This high bit rate of the SSP-frame can be reduced by changing the (QPSP, QPSP2)...

Ngày tải lên: 20/06/2014, 22:20

... from the Israeli standpoint, participated in the design of the study, and helped draft the manuscript SW conceived of the study from the United States standpoint, participated in the design of the ... performed the statistical analysis, and participated in the drafting of the manuscript All authors read and approved the final manuscript Competing interests The authors declare that they have no ... sensitivity, there are at least three problems with abdominal CT The first is that the test involves subjecting the patient to iatrogenic ionizing radiation, which carries a notable, though theoretical...

Ngày tải lên: 20/06/2014, 23:20

... their responses to the stimuli The result of the test for both the resolutions indicates that the the null hypothesis cannot be rejected, as a further proof of the fact that the two datasets of ... familiarize with the assessment procedure and the software user interface The contents shown in the training session were not used in the test sessions and the data gathered during the training ... to the results of the CIF and the 4CIF experiments, to understand whether the data of the two laboratories could be merged to compute overall MOS and associated CI values to be used as benchmark...

Ngày tải lên: 21/06/2014, 07:20

... advice improved the final version of this paper The research of the second and third authors was supported by the Croatian Ministry of Science, Education and Sports, under the Research Grant no 117-1170889-0888 ... Inequalities and Applications Proof We will prove only inequality 2.21 , since the proof of 2.22 is analogous We have ≤ α Ia f x x Γα x−t f t α−1 2.23 dt a Then by the Holder inequality, the right-hand ... Kilbas, and O I Marichev, Fractional Integral and Derivatives : Theory and Applications, Gordon and Breach Science Publishers, Yverdon, Switzerland, 1993 H. G Hardy, “Notes on some points in the integral...

Ngày tải lên: 21/06/2014, 07:20

... significantly larger than the RTP/UDP/IP overheads Other than adding the MAC and PHY headers to the packet, the increase in the number of packets results in increased contention attempts and higher collision ... noted that the performance gain in the case of NAL aggregation is due to the reduction of the MAC and PHY overhead This is based on the fact that the MAC and PHY layers add considerable overhead ... for this flow changes to C < C, the scheduler reduces the flow’s guaranteed throughput to R = R·C /C in order to ensure that the time share τ of the flow is maintained at the same level and other...

Ngày tải lên: 21/06/2014, 23:20

... whereas the negative contours (dashed lines) represent the charge depletion The charge density depletes around the H atom and transfer toward the Si adatom when the H sits on the Si adatom There ... around the H atom at the Si adatom removes toward the adsorbed Ag atom and forms a covalent-like Ag -H bond Due to the charge transfer from the H to the Si adatom on the 1 9H- Si(111)7 surface, the H ... covalent bond between the H and the Si rest atom when the H locates on the Si rest atom These results indicate that due to the strong charge transfer from adsorbed H to the Si adatom, a local...

Ngày tải lên: 22/06/2014, 00:20

... in the above equation, we have the following theorem Theorem 2.1 For positive integers n, v, and h ∈ Z, then h, v En,w q ··· Zp wq Zp h n v v v j xj xj j j dμ−1 xj 2.3 h, v By 2.1 , twisted h, ... coefficients of tn /n! in the above equation, we arrive at the following theorem Hacer Ozden et al Theorem 2.2 Witt-type formula For z ∈ Cp and positive integers n, v, and h ∈ Z , then h, v En,w z, q Zp ... a x 1.2 representing the q-analogue of the Riemann sums for f The integral of f on Zp is defined as the limit N → ∞ of the above sums when it exists Thus, Kim 1, defined the p-adic invariant q-integral...

Ngày tải lên: 22/06/2014, 18:20

... transmitted over channels which exhibit various packet error rates The results show that the proposed full scheme is superior to the method in [5] and the other variants of the full scheme When the transmission ... Among the paths converging to a node, the path attaining the lower expected distortion is retained (survivor) while the rest are pruned In the final stage, among the survivor paths, the one with the ... and determines their optimal channel protection As it can be seen, the choice of the classification thresholds is an important issue When the thresholds are close to the optimal values, the channel...

Ngày tải lên: 22/06/2014, 23:20

Ngày tải lên: 05/08/2014, 10:20