c integration of smart materials

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 1 potx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 1 potx

... Effects in Ceramic Materials Measurements of Piezoelectric and Electrostrictive Effects Common Piezoelectric and Electrostrictive Materials Piezoelectric Composites Applications of Piezoelectric ... Introduction Electrically Conductive Adhesives (ECAs) Improvement of Electrical Conductivity of ICAs Improvement of Contact Resistance Stability Improvement of Impact Performance High-Performance Conductive ... PTC Behavior Effect of Conductive Fillers on PTC Conductive Polymer Effect of Polymer Matrix on PTC Behavior Effect of Processing Condition and Additives Application of PTC Conductive Polymer Composite...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 2 docx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 2 docx

... numerical methods (27) OVERVIEW OF SMART STRUCTURAL CONCEPTS FOR AIRCRAFT CONTROL Classification of Concepts Active structural concepts for aircraft control can be subdivided into these categories: ... Thermodynamics of Electrochemical Cells Electrochemical Cells The driving force for an electrochemical cell to de trical energy to an external circuit is the decre standard free energy Go of the cell ... nF Consequently, the theoretical capacity Q of the e given by Q = It = nF Nm ELECTROCHEMICAL CONCEPTS A battery is an electrochemical cell that converts the chemical energy of a reaction directly...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 3 pot

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 3 pot

... piezoelectric (PZT) and electrostrictive (PMN) ceramics Processing of Piezoelectric Ceramics The electromechanical properties of piezoelectric ceramics are largely influenced by their processing conditions ... semiconductor render surface susceptible to nucleophilic attack Nu such as H2 O and CH3 OH react with this surface o biased PSi (20) Less active nucleophiles such roacetic, acetic, and formic acids, ... effectiveness of the electromechanical energy conversion is the electromechanical coupling factor k, which measures the fraction of electrical energy converted to mechanical energy when an electric...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 4 pptx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 4 pptx

... because it is important commercially and is central to chronicling the evolution of a branch of materials science This class of modern materials is the advanced composites These engineered materials ... anisotropic character can be made more isotropic by field application which restores 0.0 1.0 Figure 22 Magnetic and electronic phase d Sm1−x Cax MnO3 as a function of x controlling t lency CG is for cluster-glass ... different concentrations of ECH Electromechanochemical (EMC) behavior d contraction of polymers in an electric field The an electric field on polyelectrolyte hydrogels rel protonation of its alkaline...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 5 ppt

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 5 ppt

...        C1 1 C1 2 C2 2 C1 3 C2 3 c3 3 C1 4 C2 4 C3 4 C4 4 C1 5 C2 5 C3 5 C4 5 C5 5 (SYM)  C1 6 C2 6   C3 6   C4 6   C5 6  C6 6   ε1  ε2     ε3     γ23     γ31  γ12 The constitutive relations ... structures such as dendrites, and the macroscopic level has a typical length scale of centimeters Clearly, the term “microscopic” in alloy casting picks up where the macroscopic level of fracture ... simple mechanisms for small PTC behavior of conductive polymer composites: reduction of the contact area of neighboring conductive particles and an increase in the junction distance in electric tunneling...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 7 pps

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 7 pps

... = CH2CH2CO2Et R1 = CHMe2, R2 = CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CO2CH2CH2CHMeCH2CH2CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CO2CH2CHEtCH2CH2CH2Me R1 = CH2CHMe2, R2 = CH2CH2CO2CH2Me ... R2 = CH2CH2CO2CH2Me R1 = CH2CO2CH2CH2CH2Me, R2 = CH2Ph R1 = CH2CO2CH2CH2CH2CHMeCH2CH2CH2CHMe2, R = CH2Ph R1 H O N N O H R2 Figure 35 Cyclo(dipeptides) can gel a variety of organic solvents O O ... R = CH2(CH2)4CH3 22; R = CH2(CH2)10CH3 23; R = CH2(CH2)16CH3 24; R = CH2CH2CH(CH3)(CH2)3CH(CH3)2 Figure 14 Long alkyl chain organogelators deriva hydrogen bonding groups around a cyclic core...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 8 pptx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 8 pptx

... of spinless (S = 0) [CoCp∗ ]+ for [FeCp∗ ].+ in [FeCp∗ ].+ [TCNE].− leads to a rapid 2 of Tc as a function of the fraction of spinless sit occurs, such as 2.5% substitution of [FeCp∗ ].+ [CoCp∗ ... ferromagnetically coupled Heisenberg chain with J/kB = 27 K (6) Below that temperature, the susceptibility (a) (b) (c) N N N N C C C C C C C C Fe N N N N Figure Molecular structures of FeCp∗ (a), TCNE ... (CVD), and sol-gel processing The sol-gel process of piezoceramics has had increasing applications because the chemical composition can be controlled precisely Of particular concern here is whether...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 9 pps

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 9 pps

... the truncated center contact can then function as a center resistance contact, center contact, some other kind of readout implement, or some combination thereof The truncated center contact should ... Moreover, noncircu tubes or microchannels can certainly be used in tion with circular microtubes or microchannels in microdevice In fact, there is very good reason Noncircular microtubes or microchannels ... the microtube device and establishes electrical contact with the nonwetting droplet This center contact can be a wire, tube, trical contact with the conductive droplet, but direct contact with...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 10 ppt

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 10 ppt

... expense of the electric field that acts on the ceramic particles As a result, the piezoelectric activity of the ceramic/polymer composite specimen is very low, compared with a pure piezoceramic specimen ... electric field that acts on the ceramic particles is very low compared with that applied externally to the composite specimen (14,32) This occurs because the electrical conductivity of polymeric ... space charge accumulated at the PZT/epoxy interface Electrical Conductivities of Constituent Materials It is now well established that in poling a composite specimen made of piezoceramic particles...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 11 pdf

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 11 pdf

... H 3C Si CH3 O H 2N H 3C Si (CH2)11 NH2 THF 2.7 n O OH O 1n H 3C Si O Cl CH3 + O HO C CH ∗ CH3 CH ∗ 2.7 n + HO C C 2H5 H O (CH2)5 N C DCC, DMAP, THF, CH2Cl2 O O O H3 C Si CH2 (CH2)10 O O Cl CH3 C CH ... nylons) in 1970 (19) CH2 CH2 O NH H 2C CH H 2C C H2 C H 2C CH2 H 2C O C CH NH O C NH Nylon Figure Schematic depiction of hydrogen-bonded sh ing dipole directions in the crystal lattices of (a) even (n ... electromechanical coupling coefficient ki j represents the conversion of electrical energy into mechanical energy and vice versa The electromechanical coupling can be considered a measure of transduction...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 12 doc

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 12 doc

... resistance The electrical conductive FRP and CMC signed and produced by adding a conductive Load / N and performance of the composites when embedde tar/concrete blocks and concrete piles 100 Specimen ... using microelectronic fabrication techniques SAW devices fit this description because they have acoustic waves (mechanical) that are launched and detected electrically Commercial SAW microsensor ... the crack propagation in the surface of the concrete specimen The R/R0 of the CP composite is initiated at about 300 s, which corresponds to the stage of crack formation The R/R0 of the CP composite...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 13 pdf

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 13 pdf

... fields can be discontinuous Lattice Cell Mechanics In this approach, the macroscopic response of the material is determined by studying the behavior of a collection of lattice cells that can be ... for cancellation among the dipoles, the crystal has a macroscopic dipole The two opposite faces of the crystal have opposite electric charges This is an electromechanical transducer that converts ... converse effect relates strain to electric field an in actuators If the piezoelectric coefficient d is constant, the direct and converse effect can be w D = d·X + εX ·E, activity The dielectric...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 14 docx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 14 docx

... also excite other luminescent centers, such as impurity ions or defect centers Even in the absence of microdischarging, local concentrations of surface charge accelerate previously emitted electrons ... four mechanisms of triboexcitation that are currently under active consideration can be broadly categorized as electrically induced, thermally induced, chemically induced and mechanically induced ... electrons, which leads to the emission of photons by electron collision with molecules, recombination luminescence of cations and anions, or electroluminescence (EL) Piezoelectricity in a crystal...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 15 pps

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) WW Part 15 pps

... electrical conductors, which allows fabrication of polymeric solidstate electrochromic devices (59) Control of Electrochromic Smart Windows The application of electrochromic smart windows in architectural ... Reduction of organic species— e.g., viologen Electrochromic (inorganic) Reduction of electrochromic (e.g., WO3 ) by electrochemical ion insertion Thermochromic Operational Switching Parameter Control ... inorganic electrochromic devices provide the most linear response with respect to the control parameter, which in this case is injected charge density Electrochromic Smart Windows Electrochromic materials...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 2 potx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 2 potx

... Thermodynamics of Electrochemical Cells Electrochemical Cells The driving force for an electrochemical cell to de trical energy to an external circuit is the decre standard free energy Go of the cell ... nF Consequently, the theoretical capacity Q of the e given by Q = It = nF Nm ELECTROCHEMICAL CONCEPTS A battery is an electrochemical cell that converts the chemical energy of a reaction directly ... respectively, the disch charge capacities The reciprocal of the coulom ciency is the charging factor f : f = qC Energy efficiency qE is defined as qE = qc Ed , Ec where Ed and Ec are, respectively,...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 3 pps

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 3 pps

... piezoelectric (PZT) and electrostrictive (PMN) ceramics Processing of Piezoelectric Ceramics The electromechanical properties of piezoelectric ceramics are largely influenced by their processing conditions ... effectiveness of the electromechanical energy conversion is the electromechanical coupling factor k, which measures the fraction of electrical energy converted to mechanical energy when an electric ... rect piezoelectric effect The direct piezoelectric e ways accompanied by the converse piezoelectric ef a solid becomes strained when placed in an ele The microscopic origin of the piezoelectric...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 4 pot

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 4 pot

...        C1 1 C1 2 C2 2 C1 3 C2 3 c3 3 C1 4 C2 4 C3 4 C4 4 C1 5 C2 5 C3 5 C4 5 C5 5 (SYM)  C1 6 C2 6   C3 6   C4 6   C5 6  C6 6   ε1  ε2     ε3     γ23     γ31  γ12 The constitutive relations ... principles of thermodynamics and continuum mechanics, such as the theories of elasticity (1), fluid mechanics (2), classical electromagnetic field theory (3), chemical equilibrium and kinetics, ... in character, whereas surface acidic are electronegative in character Accordin should be some strength of attraction between t surfaces, with the greatest adhesion by electrosta action occurring...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 5 ppsx

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 5 ppsx

... damage C/ C composites is a matrix crack, which affects th cal resistance due to the conductivity of the carbo The electrical resistance of C/ C composites is m tive to fatigue damage than that of CFRP ... ruggedness of conventional ceramics and the exceptional functionality of select electroceramic materials that make electroceramics particularly attractive as smart materials and as components of smart ... sections IMPROVEMENT OF ELECTRICAL CONDUCTIVITY OF ICAs The electrical conductivity of ICAs is inferior to that of solders (24) Even though the conductivity of ICAs is adequate for most applications,...

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Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 6 pot

Encyclopedia of Smart Materials (Vols 1 and 2) - M. Schwartz (2002) Episode 6 pot

... = CH2CH2CO2Et R1 = CHMe2, R2 = CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CO2CH2CH2CHMeCH2CH2CH2CHMe2 R1 = CHMe2, R2 = CH2CH2CO2CH2CHEtCH2CH2CH2Me R1 = CH2CHMe2, R2 = CH2CH2CO2CH2Me ... R2 = CH2CH2CO2CH2Me R1 = CH2CO2CH2CH2CH2Me, R2 = CH2Ph R1 = CH2CO2CH2CH2CH2CHMeCH2CH2CH2CHMe2, R = CH2Ph R1 H O N N O H R2 Figure 35 Cyclo(dipeptides) can gel a variety of organic solvents O O ... R = CH2(CH2)4CH3 22; R = CH2(CH2)10CH3 23; R = CH2(CH2)16CH3 24; R = CH2CH2CH(CH3)(CH2)3CH(CH3)2 Figure 14 Long alkyl chain organogelators deriva hydrogen bonding groups around a cyclic core...

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