Tài liệu hạn chế xem trước, để xem đầy đủ mời bạn chọn Tải xuống
1
/ 25 trang
THÔNG TIN TÀI LIỆU
Thông tin cơ bản
Định dạng
Số trang
25
Dung lượng
267,59 KB
Nội dung
38.1:
Hz105.77
m
10
5.20
sm103.00
λ
14
7
8
c
f
eV.2.40J103.84)sm10(3.00s)mkg10(1.28
smkg101.28
m105.20
sJ106.63
λ
19827
27
7
34
pcE
h
p
38.2: a)
eV.107.49J0.0120s)10(20.0W)(0.600
163
Pt
b)
eV.1.90J103.05
λ
19
hc
hf
c)
.1094.3
16
hf
Pt
38.3: a)
Hz.105.91
sJ106.63
eV)J10(1.60eV)10(2.45
20
34
196
h
E
fhfE
b)
m.105.08
Hz105.91
sm103.00
λ
13
20
8
f
c
c)
λ
is of the same magnitude as a nuclear radius.
38.4:
hc
W
hc
P
hf
P
dNdE
dtdE
dt
dN
m)10(2.48)(12.0λ
)(
)(
7
sec.photons101.50
19
38.5:
hfmv
2
max
2
1
J
10
3.04
eVJ10(1.60eV)(5.1
m102.35
sJ10(6.63
20
19
7
34
))
c
.sm102.58
kg109.11
J)102(3.04
5
31
20
max
v
38.6:
m102.72
Hz101.45
λ
7
15
0
c
h
hc
hfhfE
eV.1.44J102.30
19
38.7: a)
Hz105.0λ
14
cf
b) Each photon has energy
J.10.313
19
hfE
Source emits
sphotons102.3photons/s)10(3.31)sJ(75sosJ75
2019
c) No, they are different. The frequency depends on the energy of each photon and the
number of photons per second depends on the power output of the source.
38.8: For red light
nm700λ
eV1.77
J101.6
1eV
J102.84
m)10(700
)sm10(3.00s)J10(6.626
λ
19
19
9
834
hc
hf
38.9: a) For a particle with mass,
.4means2.2
1212
2
KKppmpK
b) For a photon,
.2means2.
1212
EEpppcE
38.10:
hfK
max
Use the information given for
:findtonm400λ
J
10
3.204
eV)J10(1.602eV)(1.10
m10400
)sm10(2.998s)J10(6.626
19
19
9
834
max
Khf
Now calculate
:nm300λfor
max
K
eV2.13J103.418
J103.204
m10300
)sm10(2.998s)J10(6.626
19
19
9
834
max
hfK
38.11: a) The work function
00
eV
λ
eV
hc
hf
J.107.53
V)(0.181C)10(1.60
m102.54
s)m10(3.00s)J10(6.63
19
19
7
834
The threshold frequency implies
hchc
hf
th
th
th
λ
λ
m.102.64
J107.53
)sm10(3.00s)J10(6.63
λ
7
19
834
th
b)
eV,4.70J107.53
19
as found in part (a), and this is the value from Table
38.1.
38.12:
a) From Eq. (38.4),
V.2.7V2.3
m)10(2.50
s)m10(3.00s)eV10(4.136
λ
1
7
815
hc
e
V
b) The stopping potential, multiplied by the electron charge, is the maximum kinetic
energy, 2.7 eV.
c)
s.m109.7
kg)10(9.11
V)(2.7C)102(1.6022
5
31
19
m
eV
m
K
v
38.13: a)
)sm10(3.00)smkg10(8.24
828
pcE
eV1.54
eVJ101.60
J102.47
J102.47
19
19
19
b)
m.108.05
s)mkg10(8.24
s)J10(6.63
λ
λ
7
28
34
p
hh
p
This is infrared radiation.
38.14: a) The threshold frequency is found by setting V = 0 in Eq. (40.4),
.
0
hf
b)
eV.3.34105.35
m1072.3
λ
19
7
0
hchc
hf
38.15: a)
.eV1.44J102.31
m108.60
)sm10(3.00s)J10(6.63
λ
19
7
834
hc
E
So the internal energy of the atom increases by
eV1.44eV6.52toeV44.1 E
eV.5.08
b)
eV.2.96J104.74
m
10
4.20
s)m10(3.00s)J10(6.63
λ
19
7
834
hc
E
So the final internal energy of the atom decreases to
eV.5.64eV2.96eV2.68
E
38.16: a)
eV.20
1
E
b) The system starts in the n = 4 state. If we look at all paths
to n = 1 we find the 4-3, 4-2, 4-1, 3-2, 3-1, and 2-1 transitions are possible (the last three
are possible in combination with the others), with energies 3 eV, 8 eV, 18 eV, 5 eV, 15
eV, and 10 eV, respectively. c) There is no energy level 8 eV above the ground state
energy, so the photon will not be absorbed. d) The work function must be more than 3
eV, but not larger than
5 eV.
38.17: a)
22
1
2
1
λ
1
n
R
(Balmer series implies final state is n = 2)
nm433m104.33m
)1021(1.10
100
21
100
λ
100
21
25
1
4
1
λ
1
:5
7
7
R
RRnH
b)
Hz106.93
m104.33
sm103.00
λ
14
7
8
c
f
c)
eV.2.87
hfE
38.18: Lyman: largest is
nm,122
)m10(1.097
)34()34(
λ,2
17
R
n
in the ultraviolet.
Smallest is
nm,91.2
1
λ,
R
n
also ultraviolet. Paschen: largest is
nm,1875
)7144(
λ,4
R
n
in the infrared. Smallest is
nm,820
9
λ,
R
n
also
infrared.
38.19:
m105.890
)sm10(3.000s)J10(6.626
λ
7
834
1
2
3
hc
E
g
eV.102.00
.eV2.107J103.371
m105.896
)sm10(3.000s)J10(6.626
λ
eV.2.109J103.375
3
19
7
834
2
19
2
1
2
3
2
1
E
hc
E
g
38.20:
a) Equating initial kinetic energy and final potential energy and solving for the
separation radius r,
m.105.54
C)J10(4.78
C)10(1.60(184)
4
1
)2()92(
4
1
14
6
19
0
0
ε
K
ee
ε
r
b) The above result may be substituted into Coulomb’s law, or, the relation between
the magnitude of the force and the
magnitude of the potential energy in a Coulombic field
is
N.13.8
m)10(5.54
)evJ10(1.6eV)10(4.78
14
196
r
K
F
38.21: a)
)m1050.6(4
C)1060.1(164
4
)82()2(
4
14
0
219
00
21
εrε
ee
r
ε
qq
U
MeV.3.63eV103.63J105.81
613
U
b)
MeV.3.63J105.81
13
212211
UKUKUK
c)
.sm101.32
kg106.64
J)102(5.812
2
1
7
27
13
2
m
K
vmvK
38.22:
Hz.103.09
λ
andnm97.0λso,
)4(
1
1
λ
1
15
2
c
fR
38.23: a) Following the derivation for the hydrogen atom we see that for
3
Be
all we
need do is replace
Then.4by
22
ee
.
eV13.60
16)(Be)H(16
8
)4(1
)(Be
2
3
22
22
2
0
3
n
EE
hn
em
ε
E
nnn
So for the ground state,
eV.218)(Be
3
1
E
b) The ionization energy is the energy difference between the
1and
nn
levels.
So it is just 218 eV for
3
Be
, which is 16 times that of hydrogen.
c)
.
11
)m10(1.74
11
8
)4(
λ
1
2
2
2
1
18
2
2
2
1
32
0
22
nnnnch
em
So for
m101.31
4
1
1)m10(1.74
λ
1
,1to2
818
nn
m.107.63λ
9
This is 16 times shorter than that from the hydrogen atom.
d)
(H).
4
1
)4(
)(Be
2
22
0
3
nn
r
em
hn
ε
r
38.24: a), b) For either atom, the magnitude of the angular momentum is
2
h
s.mkg101.05
234
38.25:
,)eV6.13(
2
nE
n
so this state has
.351.16.13 n
In the Bohr model.
nL
so for this state
.smkg103.163
234
L
38.26:
a) We can find the photon’s energy from Eq. 38.8
J.104.58
5
1
2
1
)m10(1.097)sm10(3.00s)J10(6.63
1
2
1
19
22
17834
22
n
hcRE
The corresponding wavelength is
nm.434λ
hc
E
b) In the Bohr model, the angular momentum of an electron with principal quantum
number n is given by Eq. 38.10
.
2
h
nL
Thus, when an electron makes a transition from n = 5 to n = 2 orbital, there is the
following loss in angular momentum (which we would assume is transferred to the
photon):
s.J103.17
2
s)J103(6.63
2
)52(
34
34
π
h
L
However, this prediction of the Bohr model is wrong (as shown in Chapter 41).
38.27: a)
m/s1018.2
)sJ1063.6(2
C)1060.1(
1:
2
1
6
34
0
219
1
2
0
vn
nh
e
v
n
.sm1027.7
3
3
sm1009.1
2
2
5
1
3
6
1
2
v
vh
v
vh
b) Orbital period
4
332
0
2
0
222
0
4
21
22
me
hn
ε
nhe
mehn
v
r
n
n
.s1013.4)3(:3
s1022.1)2(:2
s1053.1
C)1060.1(kg)1011.9(
)sJ1063.6(4
1
153
13
153
12
16
41931
3342
0
1
TTn
TTn
Tn
c) number of orbits
.102.8
s1022.1
s100.1
6
15
8
38.28:
a) Using the values from Appendix F, keeping eight significant figures, gives
.m100973731.1
17
R
(Note: On some standard calculators, intermediate values in the
calculation may have exponents that exceed 100 in magnitude. If this is the case, the
numbers must be manipulated in a different order.)
b) Using the eight-figure value for
18
101798741.2
λ
gives
hcR
hc
ER
eV.605670.13J
c)
Using the value for the proton mass as given in Appendix F gives
.m5970so,m100967758.1
117
RR
38.29:
kTEE
p
s
ps
e
n
n
)(
3
5
35
But
J10306.3eV66.20
18
5
s
E
J103.14
J10992.2eV70.18
19
18
3
E
E
p
a)
.1015.1
33)K300KJ1038.1()J1014.3(
3
5
2319
e
n
n
p
s
b)
.1039.3
17)K600KJ1038.1()J1014.3(
2319
e
c)
.1082.5
9)K1200KJ1038.1()J1014.3(
2319
e
d) The
s5
state is not highly populated compared to the
p3
state, so very few atoms
are able to make the required energy jump to produce the 632.8 nm light.
38.30:
.
)(
2
2
212232
2/1
23
KTEE
p
p
pp
e
n
n
From the diagram
.J10375.3
m10890.5
s)m10000.3()J10626.6(
λ
19
7
834
1
2/3
hc
E
g
.J1000.4J10371.3J10375.3so
.J10371.3
m10896.5
s)m10000.3()J10626.6(
λ
221919
2/12/3
19
7
834
2
21
E
hc
E
g
.944.0
K).500K/1038.1()J1000.4(
2
2
2322
2/1
2/3
J
p
p
e
n
n
So more atoms are in the
21
2 p
state.
38.31:
.J1088.1
m1006.1
s)m1000.3()sJ1063.6(
λ
20
5
834
hc
E
Total energy in 1 second from the laser
.J1050.7
3
PtE
So the number of
photons emitted per second is
.1000.4
J101.88
J1050.7
17
20
3
E
E
38.32: 20.66
nm,632λandJ,103.14eV1.96eV18.70eV
19
E
hc
f
c
in good
agreement.
38.33:
min
max
λ
hc
hfeV
AC
m1011.3
)V4000)(C1060.1(
)sm10s)(3.00J1063.6(
λ
10
19
834
min
AC
eV
hc
This is the same answer as would be obtained if electrons of this energy were used.
Electron beams are much more easily produced and accelerated than proton beams.
38.34: a)
kV.8.29V1029.8
λ
3
e
hc
b) The shortest wavelength would correspond
to the maximum electron energy,
,eV
and so
.nm0414.0λ
eV
hc
38.35: An electron’s energy after being accelerated by a voltage V is just
.eVE
The
most energetic photon able to be produced by the electron is just:
V
λ
e
hc
E
hc
.nm0829.0m1029.8
V)105.1)(C1060.1(
)sm1000.3)(sJ1063.6(
λ
11
419
834
38.36: a) From Eq. (38.23),
,
)(
λ
1cos
mch
and so a)
nm,0.0500nm0542.0λ
.137and,731.0
nm002426.0
nm0042.0
1cos
b)
.3.82.134.0
nm002426.0
nm0021.0
1cos.nm0500.0nm0521.0
λ
c)
,0λ
the photon is undeflected,
1cos
and
.0
38.37:
)cos1(λλ
mc
h
.)λmaximizetois180))(1(1(λλ
max
chosen
mc
h
mc
h2
λ
.m1014.7m)102(2.426m1065.6λ
111211
max
38.38: a)
m)10426.2()cos)(1λλb)nm.0691.0λ
12
mc(h
eV
hc
.nm0698.0λsom,1011.7)0.45cos1(
13
c)
.keV8.17
λ
hc
E
38.39:
)cos1(λλ
mc
h
mc
h
λ
2
λ;180,λλ
6
1070.9
λ
2
λ
λ
mc
hΔ
38.40:
The change in wavelength of the scattered photon is given by Eq. 38.23
).cos1(λ)cos1(
λλ
Δλ
λ
Δλ
mc
h
mc
h
Thus,
.m1065.2)11(
)100.0)(m/s1000.3)(kg1067.1(
)sJ1063.6(
λ
14
827
34
38.41:
The derivation of Eq. (38.23) is explicitly shown in Equations (38.24) through
(38.27) with the final substitution of
).cos1(λλyieldingλandλ
mc
h
hphp
38.42:
.K1025.7
m10400
Km1090.2m1090.2
3
9
33
m
λ
K
T
38.43:
mm.06.1m1006.1
K728.2
Km1090.2Km1090.2
λ
3
33
m
T
This is in
the microwave part of the electromagnetic spectrum.
38.44:
From Eq. (38.30),
a)
m
c
f
λ
and,mm966.0
K00.3
Km10898.2
λ
3
m
.Hz1010.3
11
Note that a more precise value of the Wien displacement law constant has been used. b)
A factor of 100 increase in the temperature lowers
m
λ
by a factor of 100 to 9.66
m
and
raises the frequency by the same factor, to
.Hz1010.3
13
c) Similarly,
nm966λ
m
.Hz1010.3and
14
f
[...]... to the visible luminosity Rstar Rsun 38. 47: Eq (38. 32): I ( λ) x2 2hc 2 but e x 1 x 1 x for 2 λ 5 (e hc λkT 1) 2hc 2 2ckT x 1 I ( λ) 5 Eq (38. 31), which is Rayleigh’s distribution λ (hc λkT ) λ4 38. 48: a) As in Example 38. 10, using four-place values for the physical constants, hc 95.80, from which λkT I (λ)λ 6.44 10 38 4 σT b) With T 2000 K and the same... s)(3.00 108 m s) hc b) λ mT 2.90 10 3 m K (4.965)k (4.965)(1 .38 10 23 J K) Solve 5 x 5e x where x 38. 50: Combining Equations (38. 28) and (38. 30), 2.90 10 3 m K λm ( I σ)1/4 (2.90 10 3 m K) (6.94 10 6 W/m 2 5.67 10 8 W m 2 K 4 )1/4 8.72 10 7 m 872 nm E (mole) 1.00 10 5 J 38. 51: a) Energy to dissociate an AgBr molecule is just E 1 mole 6.02... 6 4 2 (4.00 10 m )(5.67 10 8 W m 2 K 4 )(473 K) 4 AT 38. 78: 8.81 103 s 2.45 hrs 38. 79: a) The period was found in Exercise 38. 27b: T 2 4ε 0 n 3 h 3 and frequency is me 4 just f 1 me 4 2 3 3 T 4 0 n h b) Eq (38. 6) tells us that f 1 me 4 1 1 ( E 2 E1 ) So f 2 3 2 2 n h 8 0 h 2 n1 (from Eq (38. 18)) If n2 n and n1 n 1, then 1 1 1 1 2 2 2 n2 n1... given by 38. 68: ( Eex Eg ) n2 ( E E ) kT e ex g T n1 n2 kln n 1 13.6 eV Eex E 2 3.4 eV 4 E g 13.6 eV E ex E g 10.2 eV 1.63 10 18 J a) n2 10 12 n1 (1.63 10 18 J) T 4275 K (1 .38 10 23 J K ) ln(10 12 ) b) n2 10 8 n1 (1.63 10 18 J) T 6412 K (1 .38 10 23 J K ) ln(10 8 ) c) n2 10 4 n1 (1.63 10 18 J) 12824 K (1 .38 10... 10 34 J s)(3.00 108 m s) 1 1 V0 11 2.65 10 7 m 2.95 10 7 m 0.477 V (1.60 10 C) So the change in the stopping potential is an increase of 0.739 V 38. 57: a) Recall eV0 38. 58: From Eq (38. 13), the speed in the ground state is v1 Z (2.19 10 6 m s) Setting c v1 gives Z = 13.7, or 14 as an integer b) The ionization energy is E Z 2 (13.6 10 mc 2 eV), and the rest... λ mc p h λ 6.99 10 24 kg m s b) E E Ee ; hc λ hc λ Ee λ λ 1 1 Ee hc (hc) 1.129 10 16 J 705 eV λλ λ λ 38. 59: λ λ 38. 60: a) The change in wavelength of the scattered photon is given by Eq 38. 23 h h (1 cos ) λ λ (1 cos ) λ λ mc mc (6.63 10 34 J s) (0.0830 10 9 m) (1 1) 0.0781 nm (9.11 10 31 kg)(3.00 108... wavelength interval would decrease From the Wien displacement law, the temperature that has the peak of the corresponding distribution in this wavelength interval is 5800 K (see Example 38. 10), close to that used in part (c) 38. 49: a) To find the maximum in the Planck distribution: dI d 2hc 2 (2hc 2 ) 2hc 2 ( λ 2 ) 5 0 5 5 5 λ dλ dλ λ (e 1) λ (e 1) λ (e 1) 2 .. .38. 45: a) H Aeσ T 4 ; A r 2l 14 14 100 W (0.20 10 3 m) 2 (0.30 m)(0.26)(5.671 10 8 W m 2 K 4 ) 4 T 2.06 10 K b) λ mT 2.90 10 3 m K; λ m 141 nm Much of the emitted radiation is in the ultraviolet H T Aeσ 38. 46: (a) Wien’s law: λ m k T 2.90 10 3 K m 9.7 10 8 m ... 23 23 1.65 10 kg m s 2 10 kg m s c) Since the electron is non relativistic ( 0.06), pe2 Ke 1.49 10 16 J 10 16 J 2m 38. 61: a) mr 207me m p m1m2 1.69 10 28 kg m1 m2 207me m p b) The new energy levels are given by Eq (38. 18) with me replaced by mr En 1 mr e 4 mr 13.60 eV 02 8n 2 h 2 me n2 1.69 10 28 kg 13.60 eV ... E2 ) λ hc (6.63 10 34 J s) (3.00 108 m s) 1.53 10 9 m 1 λ 6.55 10 10 m 38. 62: a) The levels are E 4 1.0 eV, E3 5.0 eV, E 2 8.0 eV, and E1 10.0 eV b) We can go from 4-3(4 eV), 4-2(7 eV), and 4-1(9 eV) directly, but also 3-2(3 eV), 3-1(5 eV), and 2-1(2 eV) after starting from 4 38. 63: a) The maximum energy available to be deposited in the atom is hc (6.63 10 34 J .
).cos1(λ)cos1(
λλ
Δλ
λ
Δλ
mc
h
mc
h
Thus,
.m1065.2)11(
)100.0)(m/s1000.3)(kg1067.1(
)sJ1063.6(
λ
14
827
34
38. 41:
The derivation of Eq. (38. 23) is explicitly shown in Equations (38. 24) through
(38. 27) with the final substitution. b)
.Km1090.2
K)J1 038( 4.965)(1.
)sm1000.3)(sJ1063.6(
)965.4(
λ
3
23
834
m
k
hc
T
38. 50:
Combining Equations (38. 28) and (38. 30),
nm.872m1072.8
)KmW1067.5W/m10(6.94
K)m1090.2(
(
Km1090.2
λ
7
1/442826
3
1/4
3
m
σ)I
38. 51: