This plot option can be extracted from the plot menu with a right or control click on the plot to be modified to open the menu and select Style for the type of plot to be rendered The op[r]
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This plot option can be extracted from the plot menu with a right or control click on the plot to be modified to open the menu and select Style for the type of plot to be rendered The op[r]
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Nguồn tham khảo
| Tài liệu tham khảo | Loại | Chi tiết | ||
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| 176. This is not such a bold assumption. Looking at Figures 8-1 and 8-6 one sees that when [H + ] approaches the “last” K an , the totally deprotonated congener begins to dominate. That is a An - begins to approach 1 | Sách, tạp chí |
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| 180. There is no need to report, for example, K f5 and b 5 because it can be shown that K f5 = b 5 ÷ b 4 . 181. It is difficult to prepare any solution to a concentration more than about 10 M | Sách, tạp chí |
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| 182. The logic of the coefficients is presented with Equations 3-7 and 3-8. It should seem reasonable that to have a 1 M solution of Fe(CN) 3 , it would be necessary to have at least 3 M total CN - in solution | Sách, tạp chí |
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| 173. Notice the use of full quotation marks here to protect the subscript. Normally single quotations are sufficient, but if ‘NH4’ is used, an Error, recursive assignment warning is produced | Khác | |||
| 174. The reader should remember that the maximum value for an a is one, and that log(1) is zero | Khác | |||
| 175. The reader is welcome to verify this by creating an a vs. pH plot for this acid. The solution to this problem is found where the two a ’s cross | Khác | |||
| 177. K w will not be required if our presumption about the pH of the solution and the alphas is correct | Khác | |||
| 183. These are taken from the Fe 3+ complex with the oxalate ion, C 2 O 4 2- (Appendix VIa). A pH large enough to assure that a H2Ox and a HOx are negligible is presumed. The output here has been reformatted | Khác | |||
| 184. Recall how the placement of single quotation marks in the input will create the labels in the output above | Khác | |||
| 186. a L q-×K f,n and a L q-× b n are known as conditional formation constants, K' f,n and b ' n , respectively | Khác | |||
| 187. That is, there will be no need to look for b 1 , b 2 etc | Khác | |||
| 188. The gridlines = true command is used here in lieu of the practice of adding gridlines from the plot menu | Khác | |||
| 190. Recall (Problem 2, Chapter 8) that EDTA is so important that it has its own symbol, H 4 Y | Khác | |||
| 191. This concept was introduced in Chapter 1 in the context of the reaction quotient, Q. It was discussed again in Chapter 4 (page 78) in the context of a A -, and it is most recently addressed as C EqPt in Problem 3 in Chapter 7 | Khác | |||
| 192. When a formation constant becomes this large, constants like b 3 , b 2 , and b 1 are unnecessary because Ni(CN) 4 2- so dominates the solution makeup | Khác |
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