ÔN TẬP HÓA HỮU CƠ 11

s www.TOPPER.com.vn | (04) 6680.0464 10 http://boxtailieu.net http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 vòng (1 + k=1 VD: (1 + ) k=1 k=2 CH3–CH2–CH3 k = CH=CH2 k = xHyOzNtXv k (2x t) (y v) (*) * • • • k' = k + khơng xHyOz: k VD: 3H8 có k 2x y http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 R—G VD: Trong C6H5CH2OH C6H5CH2– VD: CH2=CHCH2—Cl + NaOH CH2=CHCH2—OH + NaCl CTCT CTCT –X halogen (X = halogen) Ancol –O—H O –C—H –X halogen CH3Cl –OH CH3OH –CHO CH3CHO Axit cacboxylic O –C—OH –COOH cacboxyl CH3COOH Este O –C—OH –COO– este CH3COOCH3 –NH2 amin CH3NH2 Amin H –N—H – k = kR + kG kG VD: HD: k = http://boxtailieu.net k R s www.TOPPER.com.vn | (04) 6680.0464 VD: CH3CH2OH, CH3COOH, … • VD: CH2=CHCH2OH, HCOOCH=CH2, … • VD: C6H5COOH, … • VD: CH3OH, C6H5COOCH3, … • • VD: HOCH2CH2OH, (COOH)2, … • VD: H2NCH2COOH, … –OH "ol" –CHO "al" –COOH "oic" –COO– "oat" Ancol Anđehit Axit cacboxylic Este CH4 metan – C2H6 etan C3H8 propan C4H10 butan C5H12 pentan http://boxtailieu.net C6H14 hexan C7H16 heptan s www.TOPPER.com.vn | (04) 6680.0464 (a) CH2=CH–CH3 (b) CH2=CH–C–CH3 (c) CH3–C (d) CH2=CH–CH=O O (e) O=C—OH (f) (a) C3H8O (d) C2H5OH (g) C3H7Cl O CH2—O—C—CH3 O CH—O—C—CH3 O CH2—O—C—CH=CH2 (b) C3H6 (e) (CH3)3COH (h) C2H7N 3CH2OH + Na B) OH (c) C4H8O2 (f) C6H12O6 (i) C2H5NO2 CH3CH2ONa + ½H2 3CH2OH A) CH3 3CHO C) ONa + Ag2O CH3COOH + 2Ag 3CHO A) CH3 B) CHO D) CHO C) CH3COOH A) HCOOC2H5 C) CH3CH2COOH B) CH3CH2OH D) HCHO A) HCOOCH3 C) CH3COOCH3 B) CH3COOH D) CH3COOC2H5 (A) HCOOH (C) HCOOCH3 không (B) CH3COOH (D) HOOC–COOH http://boxtailieu.net D) OH s www.TOPPER.com.vn | (04) 6680.0464 A) HCOOCH3, CH3CH2OH, CH3COOCH=CH2 B) HCOOH, HCHO, HCOOCH3 C) HCOOCH3, CH3COOCH3, CH3COOCH=CH2 D) CH3COOH, CH2=CHCOOH, C6H5COOCH3 (a) (b) (c) (d) A HOOC–CH2CH2– A) C) B B) D) 2=CHCOOH X axit A) B) C) D) C (A) propanal (C) axit propanoic D (A) 2–metylpropan–3–ol (C) 2–metylpropan–1–ol 3CH2CHO (B) etanal (D) propanol 3)2CH–CH2OH (B) butan–1–ol (D) butan–2–ol E (A) etyl fomat (C) metyl fomat (B) metyl axetat (D) etyl axetat F (A) HCOOCH3 (C) CH3COOCH=CH2 (B) CH3COOCH3 (D) CH2=CH – COOCH3 http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 VD1: (a) C4H10 (b) C3H6O2 k 4H10 (a) 2.4 10 C4H10 CH3 – CH2 – CH2 – CH3 (2) CH3 – CH – CH3 CH3 3H6O2 (b) k 2.3 (3) CH3 – C – CH3 CH3 3H6O2 C3H6O2 C3H6O2 – CH2 – COOH 2H5; CH3COOCH3 G (a) C5H12 (b) C4H8 (c) C4H10O (d) C4H8O2 H (a) C3H8 (b) C3H7Cl (c) C3H8O (d) C3H9N http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 CnH2n+2–2kOa VD2: a = CnH2nO VD3: kR = kG • CnH2n–4O4 VD4: 2H3 2H3O)n hay C2nH3nOn 2n 3n k kR = có n nhóm CHO k=2 n 1 kG =n C4H6O2 http://boxtailieu.net k n s www.TOPPER.com.vn | (04) 6680.0464 I J K L (a) (b) (c) (d) (e) (f) (g) (h) (i) (j) M http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 Câu Câu A B B B A B C A D D C B E C C F C C (a) k = 1; (b), (c) (d) k=2; (e) k = 5; (f) k = (a), (d), (e), (g), (h) k = 0; (b), (c), (f), (i) k = (a) k = 0; (b) k = 1; (c) k = 0; (d) k = G (a) C5H12 C C–C–C–C–C C–C–C–C C C–C–C C–C–C=C C–C=C–C C – C – C – C – OH C – C – C – OH C (b) C4H8 (c) C4H10 C–C–C–C OH C–O–C–C–C C OH C–C–C C C–O–C–C C C–C–O–C–C http://boxtailieu.net C–C=C C s www.TOPPER.com.vn | (04) 6680.0464 (d) C4H8O2 C – C – C – COOH C – C – COOH HCOO – C – C – C C HCOO – C – C C – COO – C – C C C – C – COO – C H (a) C3H8 C–C–C (b) C3H7 C – C – C – Cl C – C – Cl C (c) C3H8 C – C – C – OH C–O–C–C C – C – OH C C – C – C – NH2 C – C – NH2 C C–N–C C (d) C3H9 C – C – NH – C I CnH2n – J CnH2n – 2O2 K CnH2n – 8O L (a) CnH2n + 2O (b) CnH2nO (c) CnH2n + 2O3 (d) CnH2n – 2O2 (e) CnH2n – 2O (f) CnH2n – 4O4 (g) CnH2nO2 (h) CnH2n – 4O4 (i) CnH2n + 3N (j) CnH2n + 2N2 M C2H2O4 http://boxtailieu.net ... k=1 VD: (1 + ) k=1 k=2 CH3–CH2–CH3 k = CH=CH2 k = xHyOzNtXv k (2x t) (y v) (*) * • • • k' = k + không xHyOz: k VD: 3H8 có k 2x y http://boxtailieu.net s www.TOPPER.com.vn | (04) 6680.0464 R—G VD:... CH3CH2COOH B) CH3CH2OH D) HCHO A) HCOOCH3 C) CH3COOCH3 B) CH3COOH D) CH3COOC2H5 (A) HCOOH (C) HCOOCH3 không (B) CH3COOH (D) HOOC–COOH http://boxtailieu.net D) OH s www.TOPPER.com.vn | (04) 6680.0464