The organometallic chemistry of the transition metals 4ed crabtree

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The organometallic chemistry of the transition metals 4ed   crabtree

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... concern for the environment has led to the rise of green chemistry, with the object of minimizing both energy use and chemical waste in industry The Organometallic Chemistry of the Transition Metals, ... electrons in their valence shell distinguishes the organome­ tallic chemistry of the elements of groups 3–12 of the periodic table, the transition elements, from that of groups 1–2 and 12–18, the main-group... by the crystal field model The idea is to find out how the d orbitals of the transition metal are affected by the presence of the ligands To this, we make the simplest possible assumption about the

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  • Cover

  • CONTENTS.

  • PREFACE

  • LIST OF ABBREVIATIONS.

  • 1. INTRODUCTION.

  • 2. GENERAL PROPERTIES OF ORGANOMETALLIC COMPLEXES

  • 3. METAL ALKYLS, ARYLS, AND HYDRIDES AND RELATED σ -BONDED LIGANDS

  • 4. CARBONYLS, PHOSPHINE COMPLEXES, AND LIGAND SUBSTITUTION REACTIONS

  • 5. COMPLEXES OF π-BOUND LIGANDS

  • 6. OXIDATIVE ADDITION ANDREDUCTIVE ELIMINATION

  • 7. INSERTION AND ELIMINATION

  • 8. NUCLEOPHILIC AND ELECTROPHILIC ADDITION AND ABSTRACTION

  • 9. HOMOGENEOUS CATALYSIS

  • 10.PHYSICAL METHODS IN ORGANOMETALLIC CHEMISTRY∗

  • 11.METAL–LIGAND MULTIPLE BONDS

  • 12.APPLICATIONS OF ORGANOMETALLIC CHEMISTRY

  • 13.CLUSTERS AND THE METAL–METAL BOND

  • 14.APPLICATIONS TO ORGANIC SYNTHESIS

  • 15.PARAMAGNETIC, HIGH-OXIDATION-STATE, AND HIGH-COORDINATION-NUMBER COMPLEXES

  • 16.BIOORGANOMETALLIC CHEMISTRY

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